(19)
(11) EP 0 675 191 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
13.12.1995 Bulletin 1995/50

(43) Date of publication A2:
04.10.1995 Bulletin 1995/40

(21) Application number: 95104736.4

(22) Date of filing: 30.03.1995
(51) International Patent Classification (IPC)6C10L 1/18, C10M 159/22, C07C 51/41
// C10N70:00
(84) Designated Contracting States:
DE FR GB NL

(30) Priority: 30.03.1994 JP 85857/94

(71) Applicants:
  • COSMO RESEARCH INSTITUTE
    Tokyo (JP)
  • COSMO OIL COMPANY, LTD
    Tokyo (JP)

(72) Inventors:
  • Ueda, Sanae, c/o Cosmo Res. Inst.
    Satte-shi, Saitama (JP)
  • Takagi, Yukio, c/o Cosmo Res. Inst.
    Satte-shi, Saitama (JP)
  • Yamaoka, Shinji, c/o Cosmo Res. Inst.
    Satte-shi, Saitama (JP)

(74) Representative: Hansen, Bernd, Dr. Dipl.-Chem. et al
Hoffmann, Eitle & Partner, Patentanwälte, Arabellastrasse 4
81925 München
81925 München (DE)


(56) References cited: : 
   
       


    (54) Petroleum additive and process for producing alkaline earth metal salt of an aromatic hydroxy-carboxylic acid


    (57) A petroleum additive containing an alkaline earth metal salt of an aromatic hydroxy-carboxylic acid, wherein the alkaline earth metal salt is substantially free of an alkali metal and the ratio of salicylic acid skeleton to total benzene nuclei is 0.4:1 to 0.95:1. Also, a process for producing an alkaline earth metal salt of an aromatic hydroxy-carboxylic acid involving: i) reacting an alkaline earth metal salt of a phenol with carbon dioxide; ii) reacting the resulting free phenol with an alkaline earth metal reagent in the presence of 2.0 to 15.0 mol of a dihydric alcohol per 1 mol of the alkaline earth metal reagent (when no water is added) or in the presence of 0.01 to 10.0 mol of water and 1.5 to 10.0 mol of a dihydric alcohol each per 1 mol of the alkaline earth metal reagent; and iii) repeating the reaction with carbon dioxide.





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