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(11) | EP 0 678 391 B1 |
| (12) | EUROPEAN PATENT SPECIFICATION |
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Thermal transfer recording device Thermisches Übertragungsaufzeichnungssystem Système pour l'enregistrement par transfert thermique |
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| Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention). |
BACKGROUND OF THE INVENTION
[0001] This invention relates to a thermal transfer recording device in which a transferred image having a continuous gradient may be formed by transferring a transfer dye to an object by a suitable heat source depending in image signals.
[0002] Up to now, a thermal transfer recording device, in which an object, such as a photographic paper, and a thermal transfer recording medium, such as an ink sheet, are superimposed one on the other and selectively heated, depending on image signals, using heating means, such as laser or a thermal head, for transferring the transfer dye from the recording medium to the object for recording an image thereon, has been used extensively.
[0003] Above all, the so-called sublimation thermal transfer recording device, employing a thermally diffusible dye, such as sublimable dye, as the transfer dye, is small-sized, and permits facilitated maintenance and instantaneous recording. In addition, the device gives a recorded image exhibiting a sufficient gradient and high quality comparable to a halide color photograph. For this reason, the device is attracting attention in connection with the technology of providing a hard copy of an image of a video camera, television or computer graphics.
[0004] An ink ribbon so far used for thermal transfer recording comprises a transfer dye mixed with a suitable binder resin at a mixing ratio by weight of 1 : 1 to give a coating which is applied on a substrate of e.g., a polyester film to a thickness on the order of 1 µm. However, since the ink ribbon is usually discarded after use, a large quantity of waste material is produced thus raising a problem in connection with environmental protection.
[0005] Thus an attempt has been made for improving the utilization efficiency of the thermal transfer recording medium. The demand may be met by, for example, the transfer dye layer regenerating method or the repeated rotational transfer dye layer constituting method, in which the transfer dye layer of the thermal transfer recording layer is regenerated and repeatedly utilized, and a relative speed method, in which the thermal transfer recording medium may be utilized effectively.
[0006] However, since the above methods are of the type in which the dye is transferred by the transfer dye layer being pressed against the photographic paper, there is unavoidably presented a problem that, for producing a color image, the dye transferred to the object is transferred back to the transferred dye layer thus deteriorating the picture quality and marring the image.
[0007] A device has been proposed in which a gap is provided between the transfer dye layer and the photographic paper for transferring the dye without contacting the transfer dye layer with the photographic paper. The transfer dye is supplied to the transferred area by being allowed to flow in the molten state or by being continuously applied on a suitable substrate and thence moved to the transferred area. The transfer dye is vaporized by heating means, such as laser, based on image signals, so as to be transferred to the photographic paper.
[0008] However, for carrying out transfer recording by such device, since no binder is contained in the transfer dye, laser radiation leads to generation of the surface wave due to difference in surface tension between the heated portion and the non-heated portion of the transfer dye, thus allowing the dye to be deviated to a surrounding region to render it difficult to vaporize the transfer dye appropriately.
[0009] In the thermal transfer recording device in which the gap is formed between the transfer dye layer and the photographic paper and the molten transfer dye is vaporized by heating means, such as laser, so as to be transferred to and recorded on the photographic paper, considerable difficulties are met in vaporizing the transfer dye in the desired manner, although there is no risk of the transferred dye being transferred back to the transfer dye layer.
[0010] Document JP-A-63 183 860 discloses a thermal recording head according to the preambles of claims 1 and 2 in which dye is sublimated by the energy of a thermal resistor, when fed to a dye holder through a feed port and a supply port, and used for printing a receptor paper through microholes of a filter.
SUMMARY OF THE INVENTION
[0011] In view of the foregoing, it is an object of the present invention to provide a thermal transfer recording device in which the transfer dye may be satisfactorily vaporized depending on image signals so as to be transferred to and recorded on the photographic paper in order to permit a high-quality color image to be produced easily.
[0012] To solve this object the present invention provides a thermal transfer recording device as specified in claim 1 or claim 2.
[0014] The present invention provides a thermal transfer recording device in which a gap is provided between a layer of a transfer dye and an object of transfer recording and in which the transfer dye is supplied to a transfer section and subsequently vaporized by heating means so as to be transferred onto the object of transfer recording. According to the present invention, the transfer section in which the molten transfer dye is vaporized has a spatial structure having a unit width d defined by the equation:
where ρ, γ and ω are the density of the transfer dye, surface tension of the transfer dye and the period of heating of the transfer dye by the heating means, respectively, and n is an odd integer.
[0015] That is, the thermal transfer recording device according to the present invention has the spatial structure having the unit width d represented by the equation (1).
[0018] Since the thermal transfer recording device of the present invention has the spatial structure having the unit width d represented by the equation (1), it becomes possible to suppress the generation of the surface wave on vaporization of the transfer dye melted by the heating means.
[0019] That is, a gap is provided between the transfer dye layer and the photographic paper in order to prevent contact therebetween, and the molten transfer dye is vaporized by being heated by the semiconductor laser so as to be transferred as an image from the transfer section via the gap onto the photographic paper. Since the transfer dye needs to be vaporized by being heated instantaneously, the surface wave is generated due to the difference in surface tension between the heated and unheated portions of the transfer dye. However, since the unit width d of the spatial structure formed in the transfer section is within an allowable range of an odd integer number times the half-wavelength of the surface wave, the surface wave and the spatial structure cooperate to cancel the surface wave, thus promptly attenuating the surface wave. Consequently, the surface wave unavoidably generated by instantly heating the transfer dye may be promptly suppressed substantially completely, thus prohibiting the transfer quantity of the transfer dye to the photographic paper from being lowered.
DESCRIPTION OF THE DRAWINGS
[0020] Fig.1 is a schematic cross-sectional view showing essential parts of a thermal transfer recording device according to a first embodiment of the present invention.
[0022] Fig.3 is a schematic plan view showing a partial construction of a transfer portion of the thermal transfer recording device.
[0023] Fig.4 is a schematic cross-sectional view showing a partial construction of a transfer portion of the thermal transfer recording device.
[0024] Fig.5 is a schematic cross-sectional view showing essential parts of a thermal transfer recording device according to a second embodiment of the present invention.
[0025] Fig.6 is a cross-sectional view showing essential portions of a thermal transfer recording device employing a thermal head according to the present invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0026] Referring to the drawings, preferred embodiments of the present invention will be explained in detail. With the thermal transfer recording device, an object to be transferred, such as a photographic paper, and a thermal transfer recording medium, such as an ink sheet, are superimposed one on the other, and are selectively heated by heating means, such as laser or thermal head, in accordance with image signals, for transferring the transfer dye from the thermal transfer recording medium to the object in accordance with image signals for image recording.
[0027] The thermal transfer recording device according to the first embodiment includes, as main components, a semiconductor laser 1 as heating means for vaporizing the transfer dye in the molten state, and a dye vat 2 of glass for containing the transfer dye therein.
[0028] The transfer dye is prepared by adding 2 wt% of a laser light absorber to a dispersion dye exhibiting physical properties of the density ρ = 1.0 g/cm2 and the surface tension γ = 20 dyne/ cm at a temperature of 250° C and by heating the resulting mixture to 160° C to a molten state.
[0029] The semiconductor laser 1 is adapted for radiating a pulsed laser beam with a period of 2 µs, a light emission wavelength of 780 nm and an output of 40 mW, as shown in Fig.2. The focal length of a lens 11, an optical system for the laser light beam, is set to 5 × 10 µm. The state of dispersion of the surface wave, generated at this time by the difference in surface tension between the portions of the transfer dye heated and not heated by the laser light, is shown by the equation
where k stands for the number of waves and ω stands for the pulse period of the laser light. Thus the wavelength λ of the surface wave may be represented by the equation
[0030] From the above equation (2), the angular frequency of the surface wave becomes
rad/s. The transfer dye is instantaneously heated to 250° C on laser radiation, so that, from the equation (3), the wavelength λ of the surface wave becomes equal to 8.0 µm.
[0031] The dye vat 2 is in the shape of a shallow casing in which a molten transfer dye is stored to form a transfer dye layer 22. The upper surface of the dye vat 2 is partially opened to form an aperture 2a of a pre-set area, while the lower surface thereof has a transfer section 3 in registration with the aperture 2a. A spacer 12 is formed around the rim of the aperture 2a for defining a gap 13 and a photographic paper 14 as an object of transfer recording is placed on the spacer 12. Thus the transfer section 3 is arranged with a pre-set distance corresponding to the gap 13 from the photographic paper 14 without being in physical contact therewith.
[0032] The transfer section 3 has a periodic spatial structure comprising plural pillars 21 of a substantially square cross-section set upright at equal intervals from one another on the portion of the lower surface of the dye vat 2 in registration with the aperture 2a. Each pillar 21 has a height above the liquid surface of the transfer dye in the dye vat 2 and faces the aperture 2a, as shown in Fig.3.
[0033] Referring to the spatial structure of the transfer section 3, as shown in Fig.4, the width of each pillar 21 and the interval between adjacent pillars 21 are both set to 2 µm. That is, the unit width d1 (= 4 µm), which is equal to the sum of the width of each pillar and the interval between the pillars, and which corresponds to a period of the spatial structure, is selected to be equal to one-half the wavelength λ of the surface wave generated by the difference in surface tension between the heated and non-heated portions of the transfer dye on laser light radiation.
[0034] With the above-described thermal transfer recording device of the above-described first embodiment, having the spatial structure having the unit width d1 corresponding to one period as represented by the equation (1), it becomes possible to inhibit generation of the surface wave on vaporizing the transfer dye melted by laser radiation from the laser semiconductor 1.
[0035] More specifically, with the above arrangement in which the gap 13 is provided between the transfer dye layer 22 and the photographic paper 14 in order to prevent contact therebetween, and in which the molten transfer dye is vaporized by being heated by the semiconductor laser 1 so as to be transferred as an image from the transfer section 3 via the gap 13 onto the photographic paper 14, since the transfer dye needs to be vaporized by being heated instantaneously, the surface wave is generated due to the difference in surface tension between the heated and unheated portions of the transfer dye. However, since the unit width d1 corresponding to one period of the spatial structure formed in the transfer section 3 is equal to an odd integer number times, herein 1 times the half-wavelength of the surface wave, the surface wave and the pillars 21 cooperate to cancel the surface wave, thus promptly attenuating the surface wave. Consequently, the surface wave unavoidably generated by instantly heating the transfer dye may be suppressed substantially completely in a short time, thus preventing the transfer quantity of the transfer dye to the photographic paper 14 from being lowered.
[0036] Referring to the spatial structure, it is essential for the unit width d1 to be in an allowable range of 0.8 to 1.2 times the integer odd number times the half wavelength of the surface wave. If the unit width d1 exceeds the above range, the surface wave attenuating effect is lowered significantly since it becomes impossible to disregard the deviation between the wavelength λ of the surface wave and the unit width d1.
[0037] Measurements of the image transfer quantity were conducted using the thermal transfer device according to the first embodiment. It was found that the transfer dye was transferred to an area of 80 µs × 80 µm of the photographic paper 14 per msec in an amount of OD 2.2 as measured with a Macbeth densitometer. In addition, the transferred quantity was increased in proportion to the transfer time.
[0038] Several comparative examples are now given in connection with the measurement of the image transfer quantity in the first embodiment. In the first comparative example, the image transfer quantity was measured under the condition that the unit width d1 corresponding to one period of the spatial structure of the transfer section 3 was set to 3 µm, that is the width of each pillar 21 and the interval between the pillars 21 were both set to 1.5 µm, with the remaining values being the same as those of first embodiment. It was found that only the transfer dye corresponding to OD 1.2 as measured by the Macbeth densitometer was transferred per msec on an area of 80 µm × 80 µm. It was also found that the dot OD was not changed with prolonged transfer time, although the dot diameter on the photographic sheet 14 was increased.
[0039] Then, by way of a second comparative example, the image transfer quantity was measured under the condition that the pulse period of the laser light of the semiconductor laser 1 was set to 20 µs, that is the wavelength λ of the surface wave was set to 3.7 µm, with the remaining values being the same as those of the first embodiment. It was found that only the transfer dye corresponding to OD 1.1 as measured by the Macbeth densitometer was transferred per msec on an area of 80 µm × 80 µm. It was also found that the dot OD was not changed with prolonged transfer time, although the dot diameter on the photographic sheet 14 was increased.
[0040] Thus, with the above-described first embodiment of the thermal transfer recording device, the image transfer quantity is substantially twice that in case the spatial structure in the transfer section 3 is outside the range of the equation (1), thus enabling the high-quality color image to be produced easily.
[0041] The thermal transfer recording device according to the second embodiment is now explained. The parts and components similar to those of the previous embodiment are correspondingly numbered.
[0042] The second embodiment is substantially similar to the first embodiment, with the exception that the spatial structure of the transfer section is different from that of the previous embodiment.
[0043] The transfer section 3 of the thermal transfer recording device of the present embodiment has a groove 31 in the lower bottom surface of the dye vat 2 in registration with the aperture 2a, as shown in Fig.5.
[0044] The groove 31 has a width d2, equal to 75 µm, and a depth of 20 µm, and is filled with the transfer dye in the molten state. The semiconductor laser 1, as heating means for the transfer dye, is so set that the pulse period of the laser light id 20 µs, that is the wavelength λ of the surface wave, as derived from the equations (1) and (2), is equal to 3.7 µm.
[0045] With the above-described thermal transfer recording device of the second embodiment, having the spatial structure with the unit width 2d2 as represented by the equation (1), it becomes possible to inhibit generation of the surface wave on vaporizing the transfer dye melted by laser radiation from the laser semiconductor 1.
[0046] More specifically, with the above arrangement in which the gap 13 is provided between the transfer dye layer 22 and the photographic paper 14 in order to prevent contact therebetween, and in which the molten transfer dye is vaporized by being heated by the semiconductor laser 1 so as to be transferred as an image from the transfer section 3 via the gap 13 onto the photographic paper 14, since the transfer dye needs to be vaporized by being heated instantaneously, the surface wave is generated due to the difference in surface tension between the heated and unheated portions of the transfer dye. However, since the unit width 2d2 of the spatial structure having the groove 31 with width d2 formed in the transfer section 3 is equal to an integer odd number times the half-wavelength of the surface wave, the surface wave and the groove 31 cooperate to cancel the surface wave, thus promptly attenuating the surface wave. Consequently, the surface wave unavoidably generated by instantly heating the transfer dye may be suppressed substantially completely in a short time, thus prohibiting the transfer quantity of the transfer dye to the photographic paper 14 from being lowered.
[0047] Measurements of the image transfer quantity were conducted using the thermal transfer device according to the second embodiment. It was found that the transfer dye was transferred to an area of 80 µs × 80 µm of the photographic paper 14 per msec in an amount of OD 2.0 as measured with a Macbeth densitometer. In addition, the transferred quantity was increased in proportion to the transfer time.
[0048] Another comparative example (third comparative example) is now given in connection with measurement of the image transfer quantity in the second embodiment. In the third comparative example, the image transfer quantity was measured under the condition that the width d2 of the groove 31 of the transfer section 3 was set to 65 µm, in this case the unit width 2d2 of the spatial structure was not an odd integer number times the half wavelength of the surface wave, with the remaining values being the same as those of second embodiment. It was found that only the transfer dye corresponding to OD 1.4 as measured by the Macbeth densitometer was transferred per msec on an area of 80 µm × 80 µm. It was also found that the dot OD was not changed with prolonged transfer time, although the dot diameter on the photographic sheet 14 was increased.
[0049] Thus, with the above-described second embodiment of the thermal transfer recording device, the image transfer quantity is slightly less than twice that in case the spatial structure in the transfer section 3 is outside the range of the equation (1), thus enabling the high-quality color picture to be produced easily.
[0050] The present invention is not limited to the above-described first or second embodiments. For example, a thermal head may be employed in place of the semiconductor laser as heating means for the transfer dye. Fig.6 shows an embodiment of the present invention in which the thermal bead is employed. The thermal head shown in Fig.6 has a heater 41, such as a resistor, below the pillar 21 provided in the dye vat 2.
a dye vat (2) containing the transfer dye therein, the upper surface of said vat (2) having an aperture (2a) while the lower surface of said vat (2) having a transfer section (3) in registration with the aperture (2a);
a heating means (1) for vaporizing the transfer dye in said transfer section (3) and
transferring it onto the object of transfer recording (14),
characterized in that
with the density of the transfer dye ρ, the surface tension of the transfer dye γ
at operating temperature, the frequency of heating ω, and with an odd positive integer
n, a unit width d1 of a spatial structure comprising plural pillars (21) set upright
at equal intervals from one another in the transfer section (3) is given by
a dye vat (2) containing the transfer dye therein, the upper surface of said vat (2) having an aperture (2a) while the lower surface of said vat (2) having a transfer section (3) in registration with the aperture (2a);
a heating means (1) for vaporizing the transfer dye in said transfer section (3) and
transferring it onto the object of transfer recording (14),
characterized in that
with the density of the transfer dye ρ, the surface tension of the transfer dye γ
at operating temperature, the frequency of heating ω, and with an odd positive integer
n, a unit width 2d2 of a spatial structure comprising a groove (31) with a width d2
in the transfer section (3) is given by
eine Farbstoffwanne (2), die dann den Übertragungsfarbstoff enthält, wobei die Oberseite der Wanne (2) eine Öffnung (2a) hat, während die Unterseite der Wanne (2) einen Übertragungsabschnitt (3) in Ausrichtung mit der Öffnung (2a) aufweist,
eine Heizeinrichtung (1) zum Verdampfen des Übertragungsfarbstoffes in dem Übertragungsabschnitt
(3) und zum Übertragen von diesem aufdas Objekt des Übertragungsaufzeichnens (14),
dadurch gekennzeichnet, daß
bei der Dichte ρ des Übertragungsfarbstoffes, der Oberflächenspannung γ des Übertragungsfarbstoffes
bei Betriebstemperatur, der Frequenz ω des Heizens und einer ungeraden positiven ganzen
Zahl n eine Einheitsbreite d1 einer räumlichen Struktur, die mehrere Säulen (21) aufweist,
die aufrecht in gleichen Intervallen voneinander in dem Übertragungsabschnitt (3)
eingestellt sind, gegeben ist durch:
eine Farbstoffwanne (2), die darin den Übertragungsfarbstoff enthält, wobei die Oberseite der Wanne (2) eine Öffnung (2a) hat, während die Unterseite der Wanne (2) einen Übertragungsabschnitt (3) in Ausrichtung mit der Öffnung (2a) aufweist,
eine Heizeinrichtung (1) zum Verdampfen des Übertragungsfarbstoffes in dem Übertragungsabschnitt
(3) und zum Übertragen von diesem auf das Objekt des Übertragungsaufzeichnens (14),
dadurch gekennzeichnet, daß
bei der Dichte ρ des Übertragungsfarbstoffes, der Oberflächenspannung γ des Übertragungsfarbstoffes
bei Betriebstemperatur, der Frequenz ω des Heizens und einer ungeraden positiven ganzen
Zahl n eine Einheitsbreite 2d2 der räumlichen Struktur, die eine Rille (31) mit einer
Breite d2 in dem Übertragungsabschnitt (3) aufweist, gegeben ist durch:
une cuve de colorant (2) dans laquelle est contenu le colorant de transfert, la surface supérieure de ladite cuve (2) comportant une ouverture (2a) tandis que la surface inférieure de ladite cuve (2) comporte une section de transfert (3) en correspondance avec l'ouverture (2a) ;
des moyens de chauffage (1) pour vaporiser le colorant de transfert dans ladite section
de transfert (3) et le transférer sur l'objet d'enregistrement par transfert (14),
caractérisé en ce que
avec la densité du colorant de transfert ρ, la tension superficielle du colorant
de transfert γ à la température de fonctionnement, la fréquence de chauffage ω et
avec un entier positif impair n, une largeur unitaire d1 d'une structure spatiale
comprenant de multiples supports (21) positionnés verticalement à intervalles réguliers
les uns des autres dans la section de transfert (3) est donnée par
une cuve de colorant (2) dans laquelle est contenu le colorant de transfert, la surface supérieure de ladite cuve (2) comportant une ouverture (2a) tandis que la surface inférieure de ladite cuve (2) comporte une section de transfert (3) en correspondance avec l'ouverture (2a) ;
des moyens de chauffage (1) pour vaporiser le colorant de transfert dans ladite section
de transfert (3) et le transférer sur l'objet d'enregistrement par transfert (14),
caractérisé en ce que
avec la densité du colorant de transfert ρ, la tension superficielle du colorant
de transfert γ à la température de fonctionnement, la fréquence de chauffage ω et
avec un entier positif impair n, une largeur unitaire 2d2 d'une structure spatiale
comprenant une rainure (31) d'une largeur d2 dans la section de transfert (3) est
donnée par