[0001] The present invention concerns a method of emptying flasks containing specific products,
such as in particular products intended for photographic development, and a stoppering
element designed for its implementation.
[0002] Certain chemical products must, prior to their use, be specially mixed with other
products of the same nature. For shelf-life reasons or so that the product will be
"fresh", it is often important for the mixing to be carried out just before use; this
is particularly the case with chemical products in photographic processing. At the
present time, each product forming part of such a combination is stored in a plastic
flask closed by a liquidtight stopper having on the inside a metallised (aluminium)
cap and, between the top part of the stopper and the said cap, an insulating washer,
made from cardboard for example, which, through its compressible nature, ensures that
the stopper is liquidtight. The flask can therefore, because of its liquidtight stopper,
be opened and closed as many times as desired before it is used for carrying out the
mixing.
[0003] When the mixing is carried out, the flask, once filled and stoppered, is then subjected
to heating by induction, which has the effect of heating the metallised cap, the part
of which in contact with the top of the spout of the flask is thus welded because
of the heating whilst the insulating washer prevents welding to the fabric of the
stopper. All that needs to be done then is to unscrew the stopper, revealing the welded
cap, the latter affording a temporary seal sufficient to be able to tip up the flask.
In this position, the flask can then be used by means of a known emptying support
including an orifice fitted on the inside with a pyramidal element which, simply by
pressure, pierces the metal cap. The flask, once totally emptied, is then removed
and is generally recycled, as is increasingly obligatory in many countries.
[0004] This stopping solution has many drawbacks: first of all, the stopper as described
below is relatively expensive, since it includes at least three parts, the body of
the stopper itself, the insulating washer and the metal cap. In addition, it is relatively
expensive to utilise since it requires the use of an induction heating device. Finally,
and above all, the flask cannot be recycled easily with plastic materials because
of the metallised cap attached to its spout.
[0005] The present invention aims to remedy these drawbacks by affording an inexpensive
emptying method which is simple to implement and, especially, which allows easily
recycling, not only of the flask but also of the stoppering element implementing it,
the latter being moulded in a single piece and therefore simple to manufacture.
[0006] To this end, the invention concerns a method of emptying a flask closed by a liquidtight
removable stoppering element, obtained from a single material which can be recycled,
comprising at least one closure sheet fixed to a lateral skirt enabling the said stoppering
element to be mounted on the spout of the said flask, for example by screwing, the
emptying being effected by tipping over onto a perforation means disposed inside an
emptying orifice, characterised in that the emptying is effected directly through
the closure sheet of the said stoppering element held in the closed position on the
spout of the flask, after tearing on the projection on the said means of perforating
the said sheet, the said tearing causing the opening of the said sheet over the entire
cross section of the said spout. The present invention also concerns a stoppering
element implementing the method. This element may consist of a single-piece plastic
stopper, allowing repeated stoppering and unstoppering of a flask whilst providing
a perfect seal.
[0007] In addition, the flask closed by the stopper according to the invention in question
may, after stoppering, be tipped over onto a suitable perforation means disposed at
the centre of an emptying orifice. The closure sheet providing the seal on the stopper
will then be perforated by the means disposed at the centre of the orifice.
[0008] The emptying method according to the invention in question therefore does indeed
provide the functions as the one using a stoppering element including a metal cap,
but is much less expensive since it makes it possible to use a stoppering element
consisting of a single piece obtained by moulding which does not require any sealing
joint, and it requires no special equipment for its use. In addition handling is simplified
since it is no longer necessary to remove the stoppering element before carrying out
the emptying. Finally, this method allows easy recycling of the flask from which any
dissimilar material has thus been removed. A particularly advantageous form of recycling
of the flask then consists purely and simply of reuse of the said flask after cleaning.
[0009] A preferential embodiment of the present invention will be described below, by way
of non-limitative example, with reference to the accompanying drawing in which:
- Figure 1 is a view in axial section of the stoppering element according to the invention,
- Figure 2 is a plan view of the inside of a first variant of the stoppering element
according to the invention,
- Figure 3 is a plan view of the inside of a second variant of the stoppering element
according to the invention,
- Figure 4 is a schematic view in partial section of an installation allowing mixing
of the products contained in two flasks closed off by stoppering elements according
to the invention,
- Figure 5 is a plan view of the installation shown in Figure 3, on which a single flask
is depicted,
- Figure 6 is a section view along line 6-6 of fig 3 for another embodiment of the stoppering
element according to the invention.
[0010] The emptying method according to the invention uses a flask 1 closed by a stoppering
element 2 comprising at least one closure sheet 3 fixed to a lateral skirt 4 for mounting
the said stoppering element on the spout of the said flask 1, by any means known to
persons skilled in the art, for example by screwing. Emptying is obtained by tipping
the flask 1 onto a perforation means 5 disposed inside an emptying orifice 6. An installation
for mixing the contents of the two flasks 1 closed with the stoppering elements 2
according to the invention in question is shown in Figures 4 and 5. In these figures,
the emptying orifices 6 are shown fitted with perforation means 5, pyramidal in shape.
It is clear than any other equivalent perforation device 5 would also be suitable.
[0011] The two flasks 1 are tipped over and fitted into troughs 7 of corresponding shape.
After perforation of the stoppering elements 2 on each flask 1, the liquids contained
in the said flasks 1 flow through the emptying orifices 6 into the mixing tank 8.
[0012] The method according to the invention is therefore characterised in that the emptying
is effected directly through the closure sheet 3 of the stoppering element 2 held
in the closed position on the spout of the flask 1. It is therefore no longer necessary
to remove the stoppering element 2 in order to effect the emptying of the flask 1.
It is the tearing of the closure sheet 3 on the projection on the said perforation
means 5 which causes the opening of the said sheet 3 over the entire cross section
of the spout of the flask 1. According to a preferential variant, the rupture of the
closure sheet 3 is initiated at at least one point in the weakened area by puncturing
on the projection on the perforation means 5 and this rupture is propagated by tearing
along the said area, thus causing the opening of the spout over the entire cross section
of the said closure sheet 3. A stoppering element 2 implementing this variant is shown
in Figure 1; it is preferentially obtained by moulding from a single recyclable material
and its closure sheet 3 has at least one weakened area. The said element 2 has an
internal skirt 9 concentric with the lateral skirt 4 extending from the closure sheet
3 in order to bear, during stoppering, on the peripheral lip of the spout of the flask
1.
[0013] According to a preferential variant, the weakened area of the closure sheet 3 has
radial or peripheral lines of lesser thickness or a combination of the two. These
lines of lesser thickness are obtained by forming grooves preferably situated on the
internal face of the stoppering element 2, so as to maximise the stresses causing
the rupture of the closure sheet 3 during puncturing by the puncturing means 5. This
weakened area may then extend to the periphery of the closure sheet 3 on the stoppering
element 2 in the general shape of an open ring 10 connected to the centre of the said
sheet 3 by a radial line 11 of lesser thickness. If the opening in the ring 10 is
diametrically opposite the radial line 11 of lesser thickness, as depicted in Figure
3, the tear, when the closure sheet 3 is punctured by the perforation means 5, will
propagate from the centre, along the radial line 11 of lesser thickness, and continue
along the part of the weakened area in the form of an open ring 10, thus opening the
entire cross section of the closure sheet 3. The latter will be attached to the body
of the stoppering element 2 by means of the part of the said closure sheet 3 corresponding
to the opening in the ring 10, which will then fulfil the role of a hinge.
[0014] The radial and peripheral lines of lesser thickness may also define angular sectors
12 attached at the periphery to the body of the stoppering element 2 by attachment
areas 13. A particular example of a closure sheet 3 having three angular sectors 12
defined by three radial lines 14 of lesser thickness and three peripheral lines 15
of lesser thickness, and attached by three attachment areas 13, is shown in Figure
2. In this case, the tear propagates from the centre of the closure sheet 3 along
radial lines 14 of lesser thickness and then along the peripheral lines 15 of lesser
thickness so as to open the said closure sheet 3 over its entire cross section, the
angular sectors 12 remaining attached to the stoppering element 2 by means of the
attachment areas 13. The peripheral lines of lesser thickness 15 could be either an
arc of a circle or an arc of an ellipse or an arc of a parabola or an arc of a hyperbola.
The radial lines of lesser thickness 11, 14 could be either straight or curved. In
the preferred embodiment, the attachment areas 13 provides hinge of a length in the
range of 3mm to 10mm.
[0015] In another more preferred embodiment, the closure sheet, instead of being flat as
represented on fig 1, takes a conical shape as shown on fig 6. This specific configuration
permits to lessen the force to be applied for rupturing the stoppering element. The
angle at the apex of the conical shape is advantageously comprised in the range of
120° to 160° and preferably about 140°.
[0016] The stoppering element according to the invention could be made of any polymer materials
or mixture of them. Polymer materials could comprise polyacrylamid, polypropylene,
polycarbonate and high or low density polyethylene. In a preferred embodiment the
stoppering element is made of a mixture of 80% of HDPE and 20% of LDPE. The lines
of lesser thickness presents a thickness in the range of 0.1mm to 0.3mm and preferably
of 0.2mm. A stoppering element manufactured according to the more preferred caracteristics
and having a flat closure sheet requires a force in the range of 17 daN to 20 daN
to be ruptured. The same stoppering element with a conicaly shaped closure element
requires a force in the range of 9.5 daN to 13 daN.
[0017] The stoppering element 2 according to the invention is in particular applicable to
flasks 1 containing photographic products.
1. Method of emptying a flask (1) closed by a liquidtight removable stoppering element
(2), obtained from a single material which can be recycled, comprising at least one
closure sheet (3) fixed to a lateral skirt (4) enabling the said stoppering element
(2) to be mounted on the spout of the said flask (1), for example by screwing, the
emptying being effected by tipping over onto a perforation means (5) disposed inside
an emptying orifice (6), characterised in that the emptying is effected directly through
the closure sheet (3) of the said stoppering element (2) held in the closed position
on the spout of the flask (1), after tearing on the projection on the said means (5)
of perforating the said sheet (3), the said tearing causing the opening of the said
sheet (3) over the entire cross section of the said spout.
2. Method of emptying a flask (1) closed by a stoppering element (2) according to claim
1, characterised in that the tearing is facilitated by at least one weakened area
provided on the internal and/or external face of the said closure sheet (3).
3. Method of emptying a flask (1) closed by a stoppering element (2) according to claim
1 or 2, characterised in that the rupture of the sheet (3) is initiated at at least
one point in the weakened area by puncturing on the projection on the perforation
means (5) and in that the said rupture is propagated by tearing along the said area,
thus causing the opening of the said sheet (3) over the entire cross section of the
spout.
4. Liquidtight and removable stoppering element (2) for a flask (1), comprising at least
one closure sheet (3) fixed to a lateral skirt (4) for mounting the said stoppering
element (2) on the spout of the said flask (1), for example by screwing, characterised
in that the stoppering element (2) is obtained by moulding from a single material
which can be recycled and in that the closure sheet (3) of the said stoppering element
(2) is provided on its internal and/or external face with at least one weakened area.
5. Stoppering element (2) according to claim 4, characterised in that the weakened area
includes radial (11, 14) or peripheral (10, 15) lines of lesser thickness or a combination
of the two.
6. Stoppering element (2) according to claim 4, characterised in that the weakened area
extends to the periphery of the closure sheet (3) of the stoppering element (2) in
the general shape of an open ring (10) connected to the centre of the said sheet (3)
by a radial line (11) of lesser thickness.
7. Stoppering element (2) according to claim 6, characterised in that the opening in
the ring (10) is diametrically opposite the radial line (11) of lesser thickness.
8. Stoppering element (2) according to Claim 5, characterised in that the radial (14)
and peripheral (15) lines of lesser thickness define angular sectors (12) attached
at the periphery to the body of the stoppering element (2) by attachment areas (13).
9. Stoppering element (2) according to Claim 5, characterised in that the closure sheet
is conically shaped.
10. Stoppering element (2) according to any one of Claims 4 to 9, characterised in that
the seal is provided by an internal skirt (9) concentric with the lateral skirt (4)
and extending from the closure sheet (3) in order to bear, during stoppering, on the
top lip of the spout of the flask (1).
11. Application of the stoppering element (2) according to any one of Claims 4 to 10 to
flasks (1) containing photographic products.