[0001] This invention concerns a continuous-casting crystalliser with increased heat exchange
and also a method to increase the heat exchange in a continuous-casting crystalliser,
as set forth in the respective main claims.
[0002] The invention is employed in association with a mould used in a continuous casting
plant for the production of billets, blooms or slabs of any desired type and section.
[0003] The field of continuous casting still entails a plurality of problems which have
not yet been overcome and which are linked to the high temperatures to which the sidewalls
of the crystalliser are subjected.
[0004] To be more exact, it is known that the temperature of the sidewalls of the crystalliser,
notwithstanding the circulation of cooling fluid, changes in the direction of the
casting with a maximum value reached in the vicinity of the meniscus of the molten
metal.
[0005] The uneven temperature along the sidewalls of the crystalliser causes an uneven deformation
of those sidewalls together with their outward displacement in relation to their initial
position in the cold state, this deformation being due to the thermal expansion of
the material, with resulting problems linked to the surface faults caused by this
uneven deformation on the billets/ blooms/slabs being formed.
[0006] Moreover, it is known that the skin of the solidifying billets/ blooms/slabs during
their descent in the crystalliser shrinks according to a law which differs from one
material to another.
[0007] The combination of these two factors causes, at least in the lower zone of the crystalliser,
a separation of the skin of the billet/bloom/slab from the sidewalls of the crystalliser
and reduces considerably the heat exchange between the billet/ bloom/slab and the
crystalliser to the extent that the cooling and therefore the formation of the skin
are practically halted with very severe results for the billet/bloom/slab being formed.
[0008] In the crystallisers of the state of the art the coefficient of heat exchange between
the forming skin and the sidewalls of the crystalliser, at least in the lower zone
of the crystalliser, takes on values which are lower than 36000 W/m² K and which are
therefore not acceptable for an efficient action of cooling and therefore of solidification
of the skin being formed.
[0009] The article of J.K. BRIMACOMBE "Empowerment with Knowledge - Towards the Intelligent
Mould for the Continuous Casting of Steel Billets", METALLURGICAL TRANSACTIONS B,
Volume 24B, DECEMBER 1993, pages 917-930, shows clearly that in crystallisers of the
state of the art the heat flux in the zone of the exit of the cast product from the
crystalliser is between about 1.2 and 1.4 MW/m², whereas it does not exceed 2 MW/m²
in the zone where the separation of the skin from the sidewalls of the crystalliser
begins.
[0010] In the crystallisers of the state of the art, therefore, the heat exchange has acceptable
values only along the first segment of the crystalliser, which extends along about
a quarter of the length of a crystalliser and normally about 200 mm. below the meniscus;
in this first segment the skin of the billet/bloom/slab is substantially in contact
with the sidewalls of the crystalliser.
[0011] So as to ensure that the billet/bloom/slab leaving the crystalliser has a thickness
of skin such as to prevent its breakage and the resulting break-out of liquid metal,
it is therefore necessary to employ a reduced casting speed.
[0012] Where the billets or blooms have a square, rectangular or generally polygonal cross-section,
another problem is linked to the fact that the corners of the billet or bloom undergo
a more intense cooling since at those corners the heat is removed on both sides of
the corner.
[0013] The result is that at the corners of the billet or bloom the skin forms more quickly
and the resulting shrinkage of the material has the effect that the billet or bloom
is separated very soon from the sidewalls of the crystalliser, thus interrupting the
cooling and solidifying process.
[0014] For this reason the skin of the billet or bloom at the corners is less thick than
along the sidewalls of the billet or bloom, and gradients of temperature between the
corners and the sides of the billet or bloom are created.
[0015] These temperature gradients generate tensions both within the sidewalls of the crystalliser
and within the billet or bloom being cooled, and these tensions lead to the formation
of cracks and other surface faults which reduce the quality of the outgoing product.
[0016] The present applicants have designed, tested and embodied this invention to overcome
the shortcomings of the state of the art and to achieve further advantages.
[0017] This invention is set forth and characterised in the respective main claims, while
the dependent claims describe variants of the idea of the main embodiment.
[0018] The purpose of this invention is to obtain a crystalliser for the continuous casting
of billets/blooms/slabs which enables the extraction speed to be increased owing to
an increased heat exchange between the sidewalls of the crystalliser and the cooling
fluid.
[0019] A further purpose is to provide a crystalliser in which the thermal deformation of
that crystalliser is reduced to a minimum.
[0020] Yet another purpose is to provide a method which enables the heat exchange to be
increased between the sidewalls of the crystalliser and the skin being formed in a
continuous-casting crystalliser.
[0021] The crystalliser according to the invention has sidewalls of a reduced thickness,
between 4 and 15 mm., but advantageously between 4 and 10 mm., which enable their
behaviour to be made resilient.
[0022] This resilient behaviour of the crystalliser enables a greater quantity of heat to
be extracted than with rigid crystallisers of the state of the art since this behaviour
enables the sidewalls to be displaced inwards, thus cancelling the deformation due
to the thermal field, which instead expands the sidewalls outwards.
[0023] In this way the interspace of air between the sidewalls and the skin being formed
is cancelled, thus reducing the very high thermal resistance, calculated as being
about 84% of the total thermal resistance, which this interspace creates in the heat
exchange between the sidewalls of the crystalliser and the cast product.
[0024] This reduction or cancellation of the interspace makes possible, even in the lower
zone of the crystalliser, an extraction of a very great heat flux between 2.5 and
5 MW/m².
[0025] Such a heat flux would entail very high temperatures of the sidewalls of the crystalliser,
temperatures which could lead to plastic deformation of the sidewalls.
[0026] Since it is necessary in that lower zone to stay in a condition of resilience of
the sidewalls so as to be able to cancel the air interspace created with the forming
skin, it becomes necessary to increase the coefficient of heat exchange between the
cooling fluid and the sidewalls of the crystalliser to a value between 40,000 and
100,000 W/m² K so as to be able to remove the very high heat flux which is created.
[0027] The sidewalls of the crystalliser cooperate externally with cooling chambers, which
contain a specific intermediate wall for each sidewall of the crystalliser for the
purpose of defining together with that sidewall a circulation channel for the cooling
fluid.
[0028] According to one form of embodiment of the invention the circulation channels have,
perpendicular to the axis of the crystalliser, a section having a transverse length
shorter than the sidewalls of the crystalliser and a transverse width, or span, of
the passage for the cooling fluid having a maximum value of 3 millimetres.
[0029] The scope of the invention comprises the correlation of the pressure or range of
pressures of the cooling fluid circulating in the relative circulation channels with
the value of the coefficient of heat exchange to be achieved between the sidewalls
of the crystalliser and the cooling fluid.
[0030] The invention arranges that by acting on the pressure of the cooling fluid it is
possible to deform the sidewalls of the crystalliser in the desired zones in the desired
manner.
[0031] In this invention, by cooling fluid is meant water for industrial use, at any rate
water which is normally used in moulds to cool the crystalliser.
[0032] According to a variant the invention arranges to employ as a cooling fluid water
to which has been added substances which enable that water to be used even at temperatures
of entry into the mould lower than
"0" and down to -25°C/-30°C.
[0033] A variant of the invention arranges for the use, as a cooling fluid, of other liquid
substances such as glycol, for instance, at a temperature between -10°C/-15°C and
-70°C/-80°C upon entry into the mould.
[0034] A further variant of the invention covers the use, as a cooling fluid, of liquefied
gases, whether pure or combined with other gases or liquids, at a temperature between
-3°C and -270°C upon entry into the mould.
[0035] Hereinafter, the various parameters given refer to a cooling fluid consisting of
one of the various types of water, also called normal water, as normally used to cool
continuous casting moulds in an industrial process.
[0036] According to the invention, depending on the case in question, the cooling fluid
can flow in the same direction as, or in the opposite direction to, the direction
of feed of the billet/bloom within the casting chamber.
[0037] The combination of the resiliently working sidewalls and the differentiated pressure
of the cooling fluid acting on those sidewalls makes possible a considerable reduction,
or even the elimination, of the separation of the skin of the solidifying billet/bloom/slab
from the sidewalls of the crystalliser, thus ensuring a constantly great heat exchange.
[0038] Since the thickness of the skin of the billet/bloom/slab is in proportion to the
quantity of heat removed, the greater the heat exchange is, the greater the casting
speed will be.
[0039] When other conditions are equal, the crystalliser according to the invention therefore
makes possible an increase of the casting speed, with a resulting increase of the
output of the plant.
[0040] According to a possible form of embodiment of the crystalliser according to the invention
the circulation channels do not affect the corner zones of the crystalliser so as
to prevent causing an excessive cooling of the corners of the billet/bloom/slab being
formed in cooperation with those corner zones.
[0041] In that case the crystalliser according to the invention includes at the corners
stiffening elements suitable at least to control the deformations of the crystalliser
caused by the thermal expansion as a result of the heating of the crystalliser.
[0042] These stiffening elements are wholly or partially embodied directly in the crystalliser
itself or are auxiliary external elements which are secured to, or are caused to cooperate
with, the corners of the crystalliser.
[0043] The stiffening elements may be in contact with the corners of the crystalliser so
as to determine a no transit area therefore not lapped by the circulation of the cooling
fluid.
[0044] According to a variant a passage is included between the stiffening elements and
the corners of the crystalliser so as to permit the passage of the cooling fluid in
a smaller quantity than at the remaining parts of the sidewalls of the crystalliser.
[0045] According to another variant the stiffening elements determine at the corners a particular
geometry suitable to increase the turbulence of the cooling fluid and to optimise
the alignment of the crystalliser.
[0046] According to the invention, so as to increase the heat exchange between the cooling
fluid and the sidewalls of the crystalliser, the cross-section of the passage of the
cooling fluid is reduced in such as way as to leave a transverse width, or span, between
1.5 and 2.5 millimetres for instance, such as will create a required turbulence and
stirring in cooperation with the induced differences of pressure.
[0047] According to the invention, so as to increase the heat exchange between the cooling
fluid and the sidewalls of the crystalliser, at least part of at least one face of
each circulation channel includes means to disturb the flow of cooling fluid, these
disturbing means being suitable to break up the fluid streams and to maintain a condition
of great turbulence.
[0048] According to one embodiment of the invention at least part of the outer surface of
the sidewalls of the crystalliser in contact with the cooling fluid cooperates by
means of its own flow disturbing means which, by breaking up the fluid streams of
the outermost layer running against the sidewalls of the crystalliser, cause the cooling
fluid to run in a turbulent manner with a resulting increase of heat exchange.
[0049] The disturbing means can be embodied by means of rough areas, hollows or ridges provided
on the outer surface of the sidewalls of the crystalliser and/or on the inner surface
of the intermediate walls.
[0050] These hollows may be substantially horizontal or inclined in relation to the direction
of flow of the cooling fluid, depending on the effect to be achieved.
[0051] According to the invention the hollows can have a development parallel or not parallel
to each other.
[0052] According to a variant at least part of the inner surface of the intermediate walls
facing the crystalliser and defining the circulation channels contains alternate narrowings
and enlargements, which compel the cooling fluid to carry on a turbulent and swirling
motion that assists in breaking up the fluid streams of the outermost layer of the
fluid and improves the heat exchange with the sidewalls of the crystalliser.
[0053] According to a variant the rough surface areas can be produced by sanding, shot-blasting
or an analogous treatment applied to the inner surface of the intermediate walls and/or
to the outer surface of the sidewalls of the crystalliser.
[0054] In a particular form of embodiment of the crystalliser according to the invention
the intermediate walls in the circulation channels are movable perpendicularly to
the sidewalls of the crystalliser and cooperate with adjustment means for their approach
to, or distancing from the sidewalls of the crystalliser so as to alter the transverse
width or span of the circulation channels and therefore the cross-section of the passage
for the cooling fluid when that fluid cooperates directly with the outer surface of
the sidewalls of the crystalliser.
[0055] It is possible in this way to adjust the pressure and speed of the cooling fluid
within the circulation channels.
[0056] According to the invention, when the cooling fluid consists of normal water, the
pressure of the cooling fluid is between 5 and 20 bar at least at the inlet of the
circulation channel at the lower zone of the crystalliser, where the forming skin
is detached from the sidewalls of the crystalliser, whereas in the segment of the
circulation channel in the upper zone of the crystalliser the pressure is between
about 3 and 15 bar.
[0057] The attached figures are given as a non-restrictive example and show some preferred
embodiments of the invention as follows:-
- Fig.1
- shows a longitudinal section of a mould employing a crystalliser according to the
invention;
- Figs.2a and 2b
- show in an enlarged scale two different partial vertical sections of the crystalliser
of Fig.1;
- Fig.3
- shows the outer surface of the crystalliser of Fig.2 along the line A-A of Fig.2;
- Fig.4
- shows a partial cross-section of a variant of the crystalliser of Fig.3;
- Figs.5a, 5b and 5c
- show possible forms of embodiment of the corners of the crystalliser according to
the invention;
- Figs.6a to 6f
- show partial cross-sections of six of the possible forms of embodiment of the stiffening
elements associated with the corners of the crystalliser;
- Fig.7
- shows in an enlarged scale a cross-section of a crystalliser according to the invention.
[0058] The reference number 10 in the attached figures denotes generally a mould according
to the invention, with which a nozzle 25 to discharge molten metal is caused to cooperate.
[0059] The mould 10 can have a square, rectangular or polygonal cross-section or any desired
cross-section.
[0060] The mould 10 according to the invention comprises a crystalliser 11 the sidewalls
of which have a thickness between 4 and 15 mm., but advantageously between 4 and 10
mm.
[0061] The thickness of the sidewalls is always correlated with the range of pressures of
the cooling fluid which are used to obtain a substantially resilient behaviour.
[0062] The crystalliser 11 comprises substantially an upper zone 34, which corresponds to
the vicinity of the meniscus 33 and to the zone therebelow as far as the skin being
formed of the bloom/billet/slab 24 is supported substantially against the inner surfaces
of the crystalliser 11.
[0063] According to the invention the cooling fluid, when it is normal water, has a pressure
between 3 and 15 bar in the upper zone 34.
[0064] The crystalliser 11 includes therebelow a lower zone 26, which begins substantially
in the vicinity of the point where the forming skin of the bloom/billet/slab 24 being
extracted begins to be separated from the inner surfaces of the crystalliser 11 and
extends to the end of the crystalliser 11.
[0065] The mould 10 according to the invention comprises containing walls 13 positioned
outside the crystalliser 11 and defining therewith one or more cooling chambers 14
in which a cooling fluid under pressure is caused to run.
[0066] According to the requirements of heat exchange between the cooling fluid and the
crystalliser 11 and therefore in relation to the process of cooling and solidification
of the billet/bloom/slab 24 being formed, the cooling fluid can be caused to run in
the opposite direction to, or in the same direction as, the direction of feed of the
billet/bloom/slab 24 being formed.
[0067] In this case the cooling chambers 14 include a feeder conduit 22a equipped with an
adjustment valve 23a and a discharge conduit 22b also equipped with an adjustment
valve 23b.
[0068] In the mould 10 according to the invention these cooling chambers 14 contain, for
each side of the crystalliser 11, specific intermediate walls 20, which in the example
of Fig.1 are movable transversely according to the arrows 17.
[0069] These intermediate walls 20 may also contain holes, which have the purpose of controlling
the pressure of the cooling fluid in circulation channels 21.
[0070] The circulation channels 21 are included, at least one per each side of the crystalliser
11, between the intermediate walls 20 and the outer surface 12 of the sidewalls of
the crystalliser 11.
[0071] By positioning the intermediate walls 20 perpendicularly to the axis of the crystalliser
it is possible to alter the transverse width, or span, of the respective circulation
channels 21 and therefore the hydraulic conditions of the flow of cooling fluid.
[0072] The crystalliser 11, being heated by the effect of the liquid metal running within
the casting chamber 31, is outwardly deformed resiliently, and the pressure of the
cooling fluid acts to compensate this deformation by displacing the sidewalls of the
crystalliser 11 inwards.
[0073] By changing the pressure of the cooling fluid circulating within the cooling chambers
14 and therefore within the circulation channels 21, it is possible to cause the sidewalls
of the crystalliser 11 to adhere substantially to the skin of the billet/bloom/slab
24 even in the lower zone 26 of the crystalliser 11, thus eliminating the air space
being created and thus ensuring a high coefficient of heat exchange along the whole
length of the crystalliser 11.
[0074] According to the invention by varying the difference of the pressure of the cooling
fluid between the inlet and outlet of the circulation channels 21 it is possible to
alter the heat exchange between the sidewalls of the crystalliser 11 and the cooling
fluid.
[0075] According to a variant, where the crystalliser 11 has a rectangular cross-section,
at least its wider sidewalls face independent cooling chambers 14 and circulation
channels 21 having independent pressures and differences of pressures of the cooling
fluid.
[0076] According to one form of embodiment of the invention (see Figs.6 and Fig.7 regarding
the corners 15a), the circulation channels 21 do not cooperate directly with the corners
15 of the crystalliser 11, which are not cooled by the cooling fluid running within
the cooling chambers 14.
[0077] According to the invention a segment of an increased thickness 32 is included at
the corners 15 of the crystalliser 11 so as to reduce the heat exchange with the cooling
fluid.
[0078] In the embodiments shown in Figs.5a, 5b and 5c the circulation channels 21 cooperate
with those segments 32 of an increased thickness included directly in the sidewalls
of the crystalliser 11 so as to provide cooling also at the corners 15, but a cooling
less intense than at the remaining parts of the sidewalls of the crystalliser 11.
[0079] According to the variant shown in Fig.7 relating to the corner 15b, an auxiliary
stiffening and/or alignment element 16 is included and cooperates with the corner
15b and defines therewith a channel 21 of reduced dimensions for circulation of the
cooling fluid.
[0080] According to the variant shown in Fig.7 relating to the corner 15c, the auxiliary
stiffening and/or alignment element 16 defines with that corner 15c a geometry suitable
to increase the turbulence of the circulating cooling fluid and to facilitate the
alignment of the crystalliser 11.
[0081] In Fig.7 at the corners 15a, and in Fig.6f, the circulation channels 21 have at their
lateral ends inclined walls 30 having an inclination which can be varied as required
so as to modulate and graduate the heat exchange at the corners 15 of the crystalliser
11.
[0082] The segment 32 of an increased thickness can be embodied by means of stiffening and/or
alignment elements 16 obtained wholly (16a - Fig.6c) or partly (116a - Figs.6b and
6d) directly from the sidewalls of the crystalliser 11 or may consist of independent
stiffening elements 16b (Figs.6a, 6e and 6f).
[0083] The stiffening and/or alignment elements 16, may also consist of a plurality of pieces.
[0084] The independent stiffening and/or alignment elements 16b can be associated with or
rigidly connected to, by brazing for instance, the corners 15 of the crystalliser
11 according to the invention.
[0085] The stiffening and/or alignment elements 16a-116a provided in the sidewall of the
crystalliser 11 can be conformed as a solid polygon or have a T-shape or another form.
[0086] Where the stiffening and/or alignment elements 16b are independent, they can be conformed
as a
"T", or an
"L" or an
"Ω" or can have other forms.
[0087] In the form of embodiment shown in Figs.6d and 6f the stiffening and/or alignment
element, which in Fig.6d is provided (116a) from the sidewall of the crystalliser
11, whereas in Fig.6f it is an independent element 16b, is T-shaped and is inserted
in a space 29 defined in the segment 32 of an increased thickness.
[0088] The cooling fluid may or may not run through the space 29.
[0089] The stiffening and/or alignment elements 16 perform the triple task of stiffening
and of clamping the deformations of the crystalliser 11, of reducing the heat exchange
at the corners 15 of the crystalliser 11 and of aligning the crystalliser 11.
[0090] The walls of the circulation channel 21 include disturbing elements 18 to increase
the heat exchange between the cooling fluid and the crystalliser 11 in relation to
the increase of heat flux to be removed which arises from elimination of the air interspaces
between the sidewalls of the crystalliser 11 and the skin.
[0091] These disturbing elements 18 break up the fluid streams of the outermost layer of
the fluid running against the sidewalls of the crystalliser 11 and cause the cooling
fluid to run with a turbulent motion in the circulation channels 21 with a resulting
increase of the heat exchange.
[0092] The disturbing elements 18 can be embodied with rough areas or hollows made in the
outer surface 12 of the sidewalls of the crystalliser 11 and/or with rough areas or
hollows made in the inner surface of the intermediate walls 20.
[0093] In this case the disturbing elements 18 contain a plurality of hollows 19 into which
the cooling fluid penetrates and causes the breaking up of the outermost layer of
the cooling fluid running against the outer surface 12 of the sidewalls of the crystalliser
11.
[0094] These hollows 19 may have a substantially horizontal or an inclined development (Fig.3).
[0095] The hollows 19 are defined by a height and by a depth
"a" of ≦ 0.5 mm. and by a distance of ≧ 5 mm. between one hollow and another.
[0096] According to another embodiment of the invention (Figs.2a and 2b) the intermediate
walls 20 have, on their inner surface facing the sidewalls of the crystalliser 11,
disturbing elements 18 comprising alternate enlargements 27 and narrowings 28 for
the purpose of causing in the circulating cooling fluid a required turbulence
[0097] These enlargements 27 and narrowings 28 may have a polygonal development (Fig.2b)
or may have a development producing a Venturi effect (Fig.2a), which makes the motion
of the cooling fluid swirling and turbulent and thus enhances the heat exchange.
[0098] According to a further variant these rough surface areas on the outer surface 12
of the sidewalls of the crystalliser 11 and/or on the inner surface of the intermediate
walls 20 are obtained by a treatment of sanding, shot-blasting or an analogous treatment.
1. Method to increased the heat exchange in the cooling and removal of heat from at least
one sidewall of a crystalliser (11) employed in the continuous casting of billets,
blooms or slabs (24) and associated with a mould (10), the crystalliser (11) cooperating
externally with a box-shaped structure (13) creating cooling chambers (14), in which
a cooling fluid circulates, and cooperating internally with the skin of the billets,
blooms or slabs (24) being formed, the cooling chambers (14) containing intermediate
walls (20) creating circulation channels (21) in cooperation with the outer surface
(12) of the sidewalls of the crystalliser (11), at least one upper zone (34) being
included in cooperation at least with the vicinity of the meniscus and with the portion
below the meniscus (33) of liquid metal, a lower zone (26) being also included and
beginning in the vicinity of the zone of separation of the forming skin from the inner
surfaces (12) of the crystalliser (11) and extending towards the outlet of the crystalliser
(11), the method being characterised in that, by acting on the cross-section and/or
conformation of at least one longitudinal portion of at least one side of the cross-section
of the circulation channels (21) and on the different pressures of the cooling fluid
present between the inlet and outlet of that longitudinal portion of the circulation
channels (21) a desired turbulence of the cooling fluid is created which is such as
to increase the coefficient of heat exchange to a value greater than 40,000 W/m² K.
2. Method as in Claim 1, in which the pressure of the cooling fluid at the inlet of the
circulation channels (21) is between 5 and 20 bar.
3. Method as in Claim 1 or 2, in which the pressure of the cooling fluid in the upper
zone (34) is between 3 and 15 bar.
4. Method as in any claim hereinbefore, in which at least part of the lower zone (26)
of the sidewalls of the crystalliser (11) has a thickness consistent with the pressure
of the cooling fluid and such as to make possible the resilient deformation of the
sidewalls by this pressure until those sidewalls take up a position close to, or in
contact with, the skin of the solidifying product.
5. Method as in any claim hereinbefore, in which the average heat flux removed in the
lower zone (26) of the crystalliser (11) is always greater than 2.5 MW/m².
6. Crystalliser for the continuous casting of billets, blooms or slabs (24), which is
associated with a mould (10) and cooperates externally with a box-shaped structure
(13) creating cooling chambers (14), in which a cooling fluid circulates, and cooperates
internally with the skin of the billets, blooms or slabs (24) being formed, the cooling
chambers (14) containing intermediate walls (20) creating circulation channels (21)
in cooperation with the outer surfaces (12) of the crystalliser (11), there being
included at least one upper zone (34) cooperating at least with the vicinity of, and
with the part below, the meniscus (33) of liquid metal, and a lower zone (26) beginning
in the vicinity of the zone of separation of the forming skin from the inner surfaces
of the crystalliser (11) and extending towards the outlet of the crystalliser (11),
the crystalliser (11) being characterised in that it employs the method of one or
another of the claims hereinebfore and in that the crystalliser (11) has sidewalls
of a thickness between 4 and 15 mm., and in that at least part of at least one wall
of the circulation channels (21) includes elements (18) to disturb the flow of cooling
fluid.
7. Crystalliser as in Claim 6, in which at least part of the outer surfaces (12) of the
sidewalls of the crystalliser (11) in contact with the cooling fluid includes a plurality
of hollows (19), which are perpendicular or inclined to the direction of feed of the
cooling fluid and are such as to have a height and a depth "a" ≦ 0,5 mm. and are at a distance apart "b" ≧ 5 mm.
8. Crystalliser as in Claim 6 or 7, in which the disturbing elements (18) are included
in the inner surface of the intermediate walls (20) facing towards the crystalliser
(11) and comprise alternate enlargements (27) and narrowings (28).
9. Crystalliser as in any of Claims 6 to 8 inclusive, in which the inner surface of the
intermediate walls (20) and/or the outer surface (12) of the sidewalls of the crystalliser
(11) include rough surface areas produced by a treatment of sanding, shot-blasting
or the like.
10. Crystalliser as in any of Claims 6 to 9 inclusive, in which the transverse width or
span of passage of the circulation channels (21) is 3 mm. at the most.
11. Crystalliser as in any of Claims 6 to 10 inclusive, in which the geometry of the circulation
channels (21) in their cross-section can be varied at least at the corners (15) of
the crystalliser (11).
12. Crystalliser as in any of Claims 6 to 11 inclusive, which includes stiffening and/or
alignment elements (16) associated with the corners (15) of the crystalliser (11).
13. Crystalliser as in any of Claims 6 to 12 inclusive, in which the stiffening and/or
alignment elements (16a-116a) are obtained directly from the sidewalls of the crystalliser
(11).
14. Crystalliser as in any of Claims 6 to 13 inclusive, in which the stiffening and/or
alignment elements (16b) are auxiliary external elements which cooperate with the
corners (15) of the crystalliser (11).
15. Crystalliser as in any of Claims 6 to 14 inclusive, in which at least part of the
intermediate walls (20) can be moved as required in relation to the sidewalls of the
crystalliser (11).
16. Crystalliser as in any of Claims 6 to 15 inclusive, in which the cooling fluid which
laps the sidewalls of the crystalliser (11) is normal water.
17. Crystalliser as in any of Claims 6 to 15 inclusive, in which the cooling fluid which
laps the sidewalls of the crystalliser (11) is water containing additives at a temperature
down to -25°C/-30°C.
18. Crystalliser as in any of Claims 6 to 15 inclusive, in which the cooling fluid which
laps the sidewalls of the crystalliser (11) is glycol or another substance which can
be likened thereto, at a temperature between -10°C/-80°C.
19. Crystalliser as in any of Claims 6 to 15 inclusive, in which the cooling fluid which
laps the sidewalls of the crystalliser (11) is pure liquid gas, or liquid gas to which
another gas or liquid has been added, at a temperature between -3°C and -270°C.