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(11) | EP 0 690 262 B1 |
| (12) | EUROPEAN PATENT SPECIFICATION |
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| (54) |
Waste heat boiler Abhitzekessel Chaudière de récupération |
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| Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention). |
[0001] The present invention is directed to recovery of waste heat from chemical processes. More particular, the invention relates to a waste heat boiler with improved control of cooling effect.
[0002] Waste heat boilers are generally used for the generation of steam by waste heat recovered from hot process streams. Typically, those boilers are designed as shell-and-tube exchangers with a plurality of heat exchanging tubes arranged within a cylindrical shell.
[0003] Two basic types of shell-and-tube exchangers are employed in the industry, the watertube type, in which water/steam mixtures flow through the tubes, and the fire tube type having the heating process stream inside the tubes.
[0004] The characteristic components of boilers are tubes mounted in tubesheets at a front-end head and a rear-end head within the shell. In the firetube boilers steam, production is accomplished on the shell side of the tubes by indirect heat exchange of a hot process stream flowing through the boiler tubes. The shell side is through a number of risers and downcomers connected to a steam drum, which may be arranged at the top of the boiler shell.
[0005] The mechanical design and, in particular, dimensioning of the heat exchanging surface in shell-and-tube exchanger type boilers represent certain problems. Boiler applications involve high pressures on the shell side and considerable temperature differences between the shell and tube side. Particular considerations have to be given to fouling and corrosion characteristics of the process stream.
[0006] Boilers for handling fouling or corrosion prove process streams are usually designed to a higher duty than required in order to allow for satisfying lifetime under serious fouling and corroding conditions.
[0007] The heat transferring surface of the boiler tubes is, thereby, adapted to expected corrosion and fouling factors in the stream. To provide for a desired and substantially constant cooling effect during long term operation of the boilers, appropriate heat transfer and temperature control are required.
[0008] Conventionally designed boilers are equipped with a by-pass of a large diameter tube, which may be internal or external to the boiler shell. The by-pass is usually construed as an insulated tube provided with a flow control valve. During initial operation of the boilers, part of the hot process stream is by-passed the heat transferring tubes to limit the heat transfer to the required level.
[0010] After a certain time on stream, increase of fouling and corrosion of the tubes leads to decreased heat transfer. The amount of by-passed process stream is then reduced, which allows for higher flow of the process stream through the heat transferring tubes to maintain the required cooling effect.
[0011] A major drawback of the known boilers of the above type is vigorous corrosion on metallic surfaces of the flow control valve, which is in contact with uncooled process stream having temperatures as high as 1000°C.
[0012] Use of an injection nozzle arrangement for flow control through a tube is mentioned in US-A-3548851. The nozzle arrangement is, thereby, built inside the tube. A disadvantage of this arrangement is that the arrangement creates a considerable pressure drop in the tube and will, furthermore, still be exposed to the hot environment of the hot fluid stream flowing through the tube.
[0013] The main object of this invention is to avoid the above drawback of the known waste heat boilers by providing a boiler of the shell-and-tube exchanger type with improved temperature control.
[0014] Accordingly, the invention is directed towards a waste heat boiler for cooling a hot process stream comprising within a cylindrical shell a plurality of heat exchanging tubes having an inlet end and outlet end;
an outlet chamber for withdrawing the cooled process stream;
attached to the shell, means for introducing water on shell side of the tubes;
means for introducing the hot process stream into the inlet end of the tubes and passing the process stream through the tubes in indirect heat exchange with the water on shellside of the tubes to produce steam and to cool the introduced process stream;
means for withdrawing produced steam, and means for withdrawing the cooled gas stream,
which waste heat boiler being further equipped with an insulated by-pass tube having an outlet end in the boiler outlet chamber, the outlet chamber being provided with an injection nozzle for control of flow of the hot process stream through the by-pass tube by injection of a fluid into the by-pass tube outlet end, wherein the injection nozzle is installed in the outlet chamber at the centre line of the by-pass tube spaced apart from the outlet end and having its injection muzzle directed towards the outlet end of the by-pass tube.
[0015] The nozzle may be made from any material being able to withstand the environment in the chamber. Useful materials are selected from metal alloys and ceramic materials.
[0016] When exposed to very high temperatures, it may be advantageous to build in the nozzle in temperature resistant material like refractory concrete or preformed alumina bricks protecting the nozzle surface against degradation.
[0017] By the inventive boiler design, problems through severe corrosion occurring on valves and other parts for controlling flow of hot process stream being in contact with the corroding hot stream as in the known boilers are completely avoided, which results advantageously in a longer operation time of the boiler.
[0018] The amount of by-passed stream is in the inventive boiler adjusted by the flow of non-corroding fluid, which is injected into the by-passed stream at the outlet of the by-pass tube. Thereby, the pressure at the by-pass tube outlet is controlled by the amount of the injected fluid depending on the derived flow of hot process stream through the by-pass tube. Thus, by proper adjustment of flow of injected fluid, it is possible to adapt heat transfer to changes in fouling and load of the boiler without severe corrosion of control equipment.
[0019] The fluid used for controlling the flow of hot process stream may be a cooled process stream from the outlet of the boiler, steam or an inert gas, such as nitrogen or purge gas from another process unit, which is cycled to the injection nozzle.
[0020] The actual kind of fluid utilized for flow control depends on the further use of the cooled process stream.
[0021] In the attached drawing, a waste heat boiler according to a specific embodiment of the invention is shown.
[0022] The boiler comprises a cylindrical shell or body 1 having thereon means 10 (usually referred to as "downcomers") for introducing water into the boiler on the shell side of heat exchanging tubes 2 and insulated by-pass tube 4 located in the boiler, and means 8 (usually referred to as "risers") for withdrawing steam produced in the boiler.
[0023] Heat exchanging tubes 2 and by-pass tube 4 are mounted in the boiler between inlet end 12 and outlet end 14 of the boiler. Inlet end 12 is connected to means 16 for introducing hot process stream into tubes 2 and 4 and outlet end 14 is provided with boiler outlet chamber 18 for withdrawing the cooled process stream from the boiler.
[0024] Outlet chamber 18 is equipped with injection nozzle 20, mounted spaced apart from outlet end of by-pass tube 4 on center line 22 of tube 4. The flow of the hot process gas stream within the tubes is from inlet end 12 through the tubes to the outlet end 14. Flow through by-pass tube 4 is controlled by injection of a fluid through nozzle 20 into the outlet end of tube 4.
[0025] By use of e.g. steam as control fluid, the amount of steam necessary to inject into the outlet of the by-pass tube 4 for control of flow of hot process stream through the by-pass tube within a value of zero and unhindered flow is determined by the following formula:
an outlet chamber for withdrawing the cooled process stream;
attached to the shell, means for introducing water on shell side of the tubes;
means for introducing the hot process stream into the inlet end of the tubes and passing the process stream through the tubes in indirect heat exchange with the water on shellside of the tubes to produce steam and to cool the introduced process stream;
means for withdrawing produced steam, and means for withdrawing the cooled gas stream,
which waste heat boiler being further equipped with an insulated by-pass tube having an outlet end in the boiler outlet chamber, the outlet chamber being provided with an injection nozzle for control of flow of the hot process stream through the by-pass tube by injection of a fluid into the by-pass tube outlet end, wherein the injection nozzle is installed in the outlet chamber at the centre line of the by-pass tube spaced apart from the outlet end and having its injection muzzle directed towards the outlet end of the by-pass tube.
eine Vielzahl von Wärmeaustauschrohren mit einem Einlaßende und einem Auslaßende;
eine Auslaßkammer zum Ableiten des gekühlten Prozeßstroms;
eine an der Ummantelung angebrachte Einrichtung zum Einleiten von Wasser an der Ummantelungsseite der Rohre;
eine Einrichtung zum Einleiten des heißen Prozeßstroms in das Einlaßende der Rohre und zum Durchleiten des Prozeßstroms durch die Rohre in indirektem Wärmeaustausch mit dem Wasser an der Ummantelungsseite der Rohre, um Dampf zu erzeugen und den eingeleiteten Prozeßstrom abzukühlen;
eine Einrichtung zum Ableiten des erzeugten Dampfes, und eine Einrichtung zum Ableiten des gekühlten Gasstroms,
wobei der Abhitzekessel des weiteren mit einem isolierten Ausweichrohr versehen ist, das ein Auslaßende in der Kesselauslaßkammer aufweist, wobei die Auslaßkammer mit einer Einspritzdüse versehen ist, um den Strom des heißen Prozeßstroms durch das Ausweichrohr durch das Einspritzen eines Fluids in das Auslaßende des Ausweichrohrs zu steuern, wobei die Einspritzdüse in der Auslaßkammer auf der Mittellinie des Ausweichrohrs von dem Auslaßende beabstandet angebracht ist und ihre Einspritzmündung auf das Auslaßende des Ausweichrohrs zu gerichtet ist.
une chambre de sortie pour l'extraction du courant de traitement refroidi ;
fixés à la coquille, des moyens pour introduire de l'eau du côté coquille des tubes ;
des moyens pour introduire le courant de traitement chaud dans l'extrémité d'entrée des tubes et faire passer le courant de traitement au travers des tubes, en échange de chaleur indirect avec l'eau introduite du côté coquille des tubes pour produire de la vapeur et refroidir le courant de traitement introduit ;
des moyens pour extraire la vapeur produite, et des moyens pour extraire le courant de gaz refroidi ;
laquelle chaudière de récupération étant en outre munie d'un tube de dérivation isolé ayant une extrémité de sortie débouchant dans la chambre de sortie de la chaudière, la chambre de sortie étant munie d'une buse d'injection pour réguler le débit du courant de traitement chaud au travers du tube de dérivation grâce à l'injection d'un fluide dans l'extrémité de sortie du tube de dérivation, la buse d'injection étant installée dans la chambre de sortie, au niveau de la ligne centrale du tube de dérivation et à distance de l'extrémité de sortie, et ayant sa tubulure d'injection dirigée vers l'extrémité de sortie du tube de dérivation.