(19) |
 |
|
(11) |
EP 0 691 399 A3 |
(12) |
EUROPEAN PATENT APPLICATION |
(88) |
Date of publication A3: |
|
22.05.1996 Bulletin 1996/21 |
(43) |
Date of publication A2: |
|
10.01.1996 Bulletin 1996/02 |
(22) |
Date of filing: 05.07.1995 |
|
|
(84) |
Designated Contracting States: |
|
AT BE CH DE DK ES FR GB GR IE IT LI NL PT SE |
(30) |
Priority: |
06.07.1994 US 271299
|
(71) |
Applicant: Colgate-Palmolive Company |
|
New York, N.Y. 10022-7499 (US) |
|
(72) |
Inventors: |
|
- Repinec, Stephen Thomas, Jr.
Flemington,
New Jersey (US)
- Zappone, Marianne
Princeton,
New Jersey (US)
- Fuller, Robert Langley
Asbury,
New Jersey (US)
- Krishnan, Santhana Vaidyanathan
Randolph,
New Jersey (US)
|
(74) |
Representative: Smulders, Theodorus A.H.J., Ir. et al |
|
Vereenigde Octrooibureaux
Nieuwe Parklaan 97 NL-2587 BN 's-Gravenhage NL-2587 BN 's-Gravenhage (NL) |
|
|
|
(54) |
Aqueous liquid detergent compositions containing deflocculating polymers |
(57) The present invention provides for concentrated, structured liquid detergent compositions
in the form of lamellar surfactant droplets dispersed in an aqueous electrolytic continuous
phase comprising a mixture of:
a) from about 10 to about 45% by weight of a surfactant;
b) at least one detergent builder;
c) from about 0.01 to about 5% by weight of a deflocculating polymer composition having
a weight average molecular weight in the range of from about 1500 to about 50,000
and containing polymer chains of the structure P-SR, wherein P represents a polymer
chain segment of a hydrophilic polymer and SR represents a mercapto end-cap group,
R being an organic hydrophobic radical containing from about 4 to 28 carbon atoms;
and
d) water.
The presence of the deflocculating polymer in the composition both stabilizes the
detergent composition and retards the propensity of the lamellar droplets dispersed
in the aqueous phase to flocculate, particularly where the droplets occupy a higher
volume ratio as the result of high concentrations of surfactant present in the detergent.
The invention also provides both phosphate built and non-phosphate built detergent
compositions having a viscosity in the range of from about 500 to 20,000 cps, more
preferably from about 2,000 to 10,000 cps, having improved flowability and stability.
