TECHNICAL FIELD
[0001] The present invention relates to a method of producing sintered ore to be used as
raw material of iron-making in which sintered ore of high quality can be provided
when iron ore is quickly dried and heated to high temperatures in a short period of
time by a Dwight Lloyd type sintering machine.
BACKGROUND OF THE INVENTION
[0002] In the iron and steel industry, Dwight Lloyd type sintering machines have come into
wide use. In this type sintering machine, a surface layer of blended raw material
is ignited in an ignition furnace, and the generated combustion gas is sucked downward,
so that the combustion zone is gradually moved from an upper layer to an intermediate
and to a lower layer. In this way, the entire sintering process is generally completed
in 25 to 35 minutes.
[0003] In the production process of sintered ore, the most important thing is to adopt a
production method by which the productivity can be maximized while the quality of
the sintered ore is maintained high, and the fuel consumption and the ignition fuel
consumption can be minimized. Accordingly, in the actual operation of the sintering
machine, it is desired that quantities of coke breeze and anthracite added to iron
ore as fuel are reduced to as small an amount as possible, and also it is desired
that quantities of coke oven gas and puevlrized coal are reduced to as small an amount
as possible while the quality of the sintered ore is maintained high. However, when
a blending proportion of fuel added to raw material to be sintered is simply decreased,
or alternatively when a quantity of fuel used in the ignition furnace is simply decreased,
it is impossible to provide good effects. When the quantity of fuel is greatly reduced,
the quality of the sintered ore is deteriorated and the quantity of returned ore is
increased. As a result, the fuel consumption and the ignition fuel consumption are
deteriorated.
[0004] In order to solve the above problems, for example, Japanese Examined Patent Publication
No. 54-24682 discloses the following method of producing sintered ore. In a Dwight
Lloyd type sintering machine, there is provided a hot blast feeding device between
an ore feeding device for feeding raw material to pallets, and an ignition furnace.
A blast of hot air is blown onto an upper surface of raw material so that only the
temperature of an upper layer of raw material is raised, and the upper layer of raw
material, the temperature of which has been raised, is successively ignited in the
ignition furnace. In this way, raw material is sintered while the thermal shock caused
in the process of ignition is reduced. According to the description of the above patent
publication, the following effects can be provided by this method of producing sintered
ore. According to this method, while the shatter test strength is maintained to be
constant, the productivity can be enhanced and the unit requirement of coke breeze
can be reduced, however, the product yield is a little lowered.
[0005] According to Japanese Examined Patent Publication No. 57-45296, the following method
of producing sintered ore is disclosed. In a sintering machine in which raw material
is formed into layers and an upper surface of the upper layer is ignited, there is
provided a hot blast feeding device between an ore feeding device and an ignition
furnace. A blast of hot air is blown onto an upper surface of raw material and sucked
downward, so that only an upper layer of raw material is dried and then ignited in
an ignition furnace. After the ignition furnace, there is provided a hot blast feeding
device, and a blast of hot air is fed from the hot blast feeding device and sucked
downward so that a sintering reaction can be conducted. The following are described
in the above patent publication. According to the above method, it is possible to
improve various factors, which are incompatible with each other, such as an improvement
of the productivity, reduction of the coke breeze consumption, improvement of the
quality of sintered ore, and suppression of the generation of NO
x gas. However, when only a blast of hot air is blown onto the upper surface of raw
material, it is difficult to enhance the product yield greatly.
SUMMARY OF THE INVENTION
[0006] According to the above preheating sintering method, when a thermal shock given to
the surface layer of raw material in the ignition surface is reduced and the dried
zone is extended, a moisture condensing zone is relatively reduced. Accordingly, a
quantity of combustion air to be sucked after the ignition is increased, so that the
sintering time can be reduced. Since the maximum temperature in the heat pattern of
the preheated upper layer of raw material is raised higher than that of the upper
layer of raw material which has not been preheated, the productivity, product yield
and sintered ore quality can be enhanced, and further the fuel consumption and the
ignition fuel consumption can be reduced. However, according to the above method,
it is difficult to dry and heat the raw material to be sintered provided on the pallets
without collapsing a portion of the pseudo particles in the blended raw material on
the surface layer, the thickness of which is 5 to 50 mm. Therefore, in the process
of drying and heating the surface layer of raw material, a portion of the pseudo particles
are collapsed, and the nonuniformity of drying and heating is caused on the surface
layer of raw material in the width direction of the pallets. Due to the above nonuniformity
of drying and heating, the sintering speed fluctuates after the raw material has been
ignited. As a result, it is difficult to greatly enhance the product yield, fuel consumption
and ignition fuel consumption. According to the drying and heating method conducted
only by sucking a hot blast downward, the space and time before the ignition furnace
are limited, so that it is difficult to dry and heat the raw material to be sintered
in a short period of time. Consequently, it is impossible to enhance the productivity
greatly. Also, it is difficult to greatly raise the preheating temperature of raw
material by sucking a hot blast. Accordingly, there is a limitation to the enhancement
of the product yield. In view of the above circumstances, it is an object of the present
invention to quickly dry and heat raw material to be sintered to high temperatures
in a short period of time without collapsing pseudo particles on the surface layer
of raw material to be sintered.
[0007] In this case, the pseudo particles are composed as follows. Raw materials of sintered
ore such as iron ore, coke breeze, lime stone and so forth are previously mixing in
a mixer while water is added to the mixture. Due to the foregoing, fine particles
adhere onto the periphery of a core particle which is a raw material grain formed
by the mixer. In this way, one pseudo particles are composed.
[0008] In the case of sintered ore, sintering is conducted when the fines, which adhere
to the pseudo particles, and the core particles are melted with each other in a very
short period of time. Therefore, it is important that the pseudo particles are held
as they are without collapsing in the sintering process, especially in the drying
zone.
[0009] As described before, the pseudo particles are made by pelletizing raw material and
water, wherein a binder is added to the raw material and water when necessary. The
particle diameter is increased when fines adhere to each other or alternatively fines
adhere to rough grains. Raw material to be sintered, the particle diameter of which
has been increased, is charged into the sintering machine so that a layer of raw material
of a predetermined height can be formed. After a sintering bed has been formed in
this way, sintering is conducted. However, when the pseudo particles collapse in the
process of drying and heating the surface layer of raw material, clearances formed
in the raw material to be sintered are filled with fines of the raw material. Therefore,
a uniform flow of hot blast is blocked.
[0010] In other words, according to the method of producing sintered ore in which a hot
blast is sucked, a hot blast flows smoothly in some portions and does not flow smoothly
in other portions. Accordingly, the surface layer of raw material is not heated uniformly
in the pallet width direction. Due to the foregoing, the sintering speed fluctuates
after the ignition, so that the raw material can not be sintered uniformly, which
deteriorates the product yield. Unless the pseudo particles collapse, sintering is
conducted uniformly, so that the yield can be enhanced.
[0011] The present inventors made investigation in earnest into a means for drying and heating
the surface layer of raw material to be sintered, in a short period of time without
collapsing the pseudo particles. As a result of the investigation, they found that
sintered ore of high quality can be produced at a high yield when high-frequency heating
is conducted on the raw material, especially when microwaves are irradiated alone,
or alternatively when microwaves and a hot blast are combined and given to the raw
material to be sintered.
[0012] The reason why microwaves are used in the present invention is described as follows.
It was found that the problem of collapse of pseudo particles cannot be solved as
long as heating is conducted from the outside of raw material. Accordingly, from the
idea of utilizing the surface layer of raw material as a heating unit, when the phenomenon
of polarization, which is peculiar to microwaves, is used, it becomes possible to
heat the raw material from the inside. Further, when microwaves are used, the thermal
efficiency is high in principle, and it is possible to heat the raw material to be
sintered in a short period of time even if the input of electric power to be given
is small. Utilizing the above knowledge, the inventors succeeded in solving the above
conventional problems by one effort.
[0013] The present invention is to provide a method of producing sintered ore comprising
the steps of: charging raw material of sintered ore in the form of a layer; heating
an upper surface of the layer of raw material to 120 to 600°C by microwaves generated
by a microwave generator arranged between a raw material feeding device and an ignition
furnace; igniting the upper surface of the layer of raw material in the ignition furnace;
and sintering the raw material.
[0014] The present invention is also to provide a method of producing sintered ore comprising
the steps of: charging raw material of sintered ore in the form of a layer; heating
an upper surface of the layer of raw material to 50 to 200°C by microwaves generated
by a microwave generator arranged between a raw material feeding device and an ignition
furnace; heating the upper surface of the layer of raw material to 150 to 600°C by
a hot blast fed by a hot blast feeding device arranged also between the raw material
feeding device and the ignition furnace; igniting the upper surface of the layer or
raw material in the ignition furnace; and sintering the raw material.
[0015] The present invention is also to provide a method of producing sintered ore comprising
the steps of: charging raw material of sintered ore in the form of a layer; heating
an upper surface of the layer of raw material to 150 to 600°C by microwaves generated
by a microwave generator arranged between a raw material feeding device and an ignition
furnace and simultaneously heating the upper surface of the layer of raw material
to 150 to 600°C by a hot blast fed by a hot blast feeding device also arranged between
the raw material feeding device and the ignition furnace; igniting the upper surface
of the layer or raw material in the ignition furnace; and sintering the raw material.
[0016] According to the microwave heating method, it is possible to quickly remove the moisture
of 6 to 7 wt% contained in the blended raw material, without the collapse of the pseudo
particles after pelletization. Therefore, nonuniformity of drying and heating the
surface layer of raw material in the pallet width direction can be reduced. Further,
it is possible to quickly preheat the blended raw material provided on the pallets
to a high temperature.
[0017] According to the conventional method in which a hot blast is sucked downward, a hot
blast flows smoothly in some portions and does not flow smoothly in other portions,
that is, the sintering speed fluctuates. Due to the foregoing, sintering can not be
conducted uniformly in the pallet width direction. However, as described before, according
to the present invention, nonuniformity of sintering in the pallet width direction
can be remarkably reduced. When the microwave heating is combined with the suction
of a hot blast, it is possible to quickly remove the moisture which has flowed onto
the surface of the iron ore. Accordingly, while the collapse of pseudo particles is
perfectly prevented, the blended raw material on the surface layer on the pallets
can be more quickly heated to a high temperature. As a result, the maximum temperature
of the sintered ore layer after the ignition can be raised, and the nonuniformity
of sintering speed in the pallet width direction can be reduced. Therefore, the following
effects can be simultaneously provided by this method. The productivity is enhanced
and the unit requirement of fuel is reduced, and further the generation of NO
x gas is reduced.
[0018] In this connection, the surface layer of raw material is defined as a region of the
raw material layer formed in the thickness direction, wherein the thickness of the
raw material layer is usually in a range from 350 to 500 mm, and the thickness of
the surface layer is in a range within 1/10 of the thickness of the raw material layer.
The reason why the microwave heating is conducted only on the surface layer of raw
material is described as follows.
[0019] In the iron ore sintering process, a blast of air or waste gas is sucked so as to
cause a sintering reaction. Accordingly, on the surface layer of raw material onto
which cooling air or cooling waste gas is immediately sucked, the temperature is not
sufficiently raised, that is, a sufficiently large quantity of heat is not fed. When
the maximum temperature of the surface layer, the thickness of which is approximately
1/10 of the raw material layer, is raised when the surface layer is heated by microwaves,
the product yield of this portion can be enhanced. Further, the heat given onto the
surface layer by the microwaves in this way is successively transferred to the lower
layers. Accordingly, the maximum temperature, heat level and product yield of the
upper and the intermediate layer can be enhanced by this transferred heat. In this
case, the lower layer is fed with a sufficiently large quantity of heat even when
the conventional method is adopted. Accordingly, it is impossible to expect a high
effect on the lower layer. Since the heat inputted onto the surface layer is successively
transferred onto the layer located immediately below the surface layer, the microwave
heating may be conducted only on the surface layer.
[0020] Concerning the wavelength of microwaves used for drying and heating the surface layer
of raw material on the pallets, it is allowed to use the ISN bands of 2450 MHz and
915 MHz. Either of them may be selected. In order to ensure a necessary intensity
of energy, for example, a plurality of microwave generators, The capacity of each
microwave generator is 5 kW or 25 kW, may be provided, and the microwaves generated
by each microwave generator are collected by a wave guide and irradiated. The optimum
range of irradiation of microwaves onto the surface layer of raw material on the pallets
is from 10 to 200 kW/m
2. The reason why the above optimum range of irradiation of microwaves is determined
is described as follows. When the range of irradiation of microwaves is lower than
10 kW/m
2, it is impossible to provide a sufficiently high effect of heating by microwaves.
When the range of irradiation of microwaves is higher than 200 kW/m
2, the effect of heating by microwaves reaches the upper limit. The optimum temperature
of a hot blast blown to the raw material on the pallets is 150 to 600°C, and the blowing
speed (sucking speed) of a hot blast is 0.3 to 3.0 m/sec. When the hot blast temperature
is lower than 150°C, it is impossible to provide a sufficiently high effect of drying
and heating. When the hot blast temperature is higher than 600°C, the effect of heating
reaches the upper limit. When the hot blast blowing speed is lower than 0.3 m/sec,
it is impossible to provide a sufficiently high effect of drying and heating. When
the hot blast blowing speed is higher than 3.0 m/sec, the pressure of a blast of air
is increased, and the raw material on the pallets contracts, which exerts a harmful
influence on the sintering process.
[0021] The reason why microwaves are irradiated before a hot blast is blown onto the surface
layer of raw material on the pallets is described as follows. When microwaves are
irradiated onto the surface layer of raw material on the pallets, the moisture in
the pseudo particles of blended raw material containing iron ore, limestone and coke
breeze can be made to flow quickly onto the surfaces of pseudo particles without the
collapse of the pseudo particles. Even when the microwave heating and the hot blast
blowing are simultaneously conducted, the moisture in the blended raw material flows
quickly by the action of microwave heating. Therefore, the collapse of pseudo particles
caused by the hot blast heating can be prevented. The above method in which the microwave
heating and the hot blast blowing are simultaneously conducted is very effective for
preventing the collapse of pseudo particles, because the moisture flowing onto the
surfaces of pseudo particles of blended raw material can be quickly evaporated.
[0022] In this connection, a method in which microwaves are irradiated after a hot blast
has been blown onto the surface layer of raw material on the pallets is disadvantageous
in that a portion of pseudo particles of blended raw material are collapsed in the
process of heating conducted by blowing a hot blast. To explain in detail, the moisture
in the pseudo particles is dried from the outside to the inside by the hot blast heating
method. Therefore, when the moisture inside the pseudo particles flows onto their
surfaces, a portion of raw material, which has already been dried, is collapsed by
the moisture. Due to the collapse of raw material, the gas permeability of the sintering
bed is deteriorated and the sintering time is extended. As a result, the productivity
is lowered. However, according to the method of the present invention in which the
raw material is heated by microwaves or alternatively the raw material is heated by
microwaves and then heated by a hot blast, the moisture in the pseudo particles first
absorbs the microwaves and heats up. Then the thus heated moisture first flows onto
the surfaces of pseudo particles. Accordingly, the surfaces of pseudo particles are
wet. These wet surfaces of pseudo particles are not collapsed. When the pseudo particles
are heated by blowing a hot blast after the moisture in the pseudo particles has already
been dried by the microwave heating, the pseudo particles are not collapsed because
no moisture evaporates in the process of blowing a hot blast.
[0023] The reason why the surface layer of the raw material located between the raw material
charging device and the ignition furnace is heated by microwaves to temperatures of
120 to 600°C is described as follows. In order to perfectly dry the blended raw material,
it is necessary to heat it to temperatures of not less than 120°C. when the heating
temperature exceeds 600°C, a portion of the blended raw material is overheated, so
that the pseudo particles of the blended raw material start collapsing, and the gas
permeability is deteriorated in the process of sintering.
[0024] In the case where both microwaves and a hot blast are successively used, the raw
material is first heated by the microwaves to temperatures of 50 to 200°C and then
heated by the hot blast to temperatures of 150 to 600°C. When heating is conducted
by the microwaves, it is possible to heat the raw material quickly. On the other hand,
when the raw material is heated by microwaves to temperature higher than 200°C, it
is necessary to increase an amount of energy to be inputted. When the surface layer
of raw material is heated by a hot blast after that, since the temperature rising
speed is not so high, the pseudo particles from which the moisture has already been
evaporated do not collapse, and it is possible to heat the pseudo particles to temperatures
of 150 to 600°C by inputting a smaller amount of energy. The reason why the heating
temperature of a hot blast is determined to be 150 to 600°C is described as follows.
When the heating temperature is lower than 150°C, it is impossible to provide a sufficiently
high effect corresponding to the inputted energy. When the heating temperature is
higher than 600°C, the effect of heating reaches the upper limit.
[0025] The reason why the surface layer of raw material located between the raw material
charging device and the ignition furnace is heated to temperatures of 150 to 600°C
by both microwaves and a hot blast is that the drying and heating time can be further
reduced when both microwaves and a hot blast are simultaneously used. When the surface
layer of raw material is heated to temperatures not less than 150°C, the effect of
combination of microwave heating with hot blast blowing is remarkably increased. However,
when the surface layer of raw material is heated to temperatures lower than 150°C,
the effect of combination of microwave heating with hot blast blowing is not so high.
On the other hand, when the temperature of the surface layer of raw material exceeds
600°C, a portion of the blended raw material is overheated by the microwaves, so that
the pseudo particles of the blended raw material start collapsing.
[0026] In any case, it is most preferable to heat the surface layer of raw material to temperatures
from 200 to 450°C. Since the blended raw material is ignited after the surface layer
of raw material has been uniformly heated, it is possible for the combustion zone
to spread from the upper layer to the lower layer uniformly with respect to the width
direction of the raw material layer. Accordingly, the quality of sintered ore can
be enhanced.
[0027] Next, referring to the accompanying drawings, an example of the sintering machine
to execute the present invention and its operation method will be explained below.
[0028] Fig. 1 is an arrangement view of a sintering machine illustrating its general construction
in accordance with the present invention. Blended raw material 1 to be sintered is
continuously fed from the surge hopper 2 onto the pallets 6 via the drum feeder 3
and raw material charging device 5. The thus fed raw material 1 is laminated on the
pallets 6. While the raw material is fed in this way, the sprocket 4 arranged on the
raw material feeding side is rotated so that the pallets 6 are moved at a predetermined
speed. At the same time, on the lower side of the pallets 6, waste gas is sucked by
the suction blower 13 via a plurality of wind boxes 8, the main duct 9 and the dust
collector 12. In the ignition furnace 14, an upper surface of the raw material layer
7 is ignited, and operation is continuously conducted while the pallet speed is controlled
so that the entire raw material layer 7 on the pallets 6 can be completely sintered
before it reaches the ore discharging section.
[0029] Between the raw material charging device 5 and the ignition furnace 14 of the above
Dwight Lloyd type sintering machine, there is provided a microwave generator 15, or
alternatively there are provided a microwave generator 15 and a hot blast feeding
device 16. In the case of microwave heating, the raw material layer 7 on the pallets
6 is heated in accordance with an amount of energy of the irradiated microwaves and
the irradiation time. Into this hot blast feeding device 16, it is possible to introduce
a hot blast discharged from the discharge pipe 18 of the cooling unit 17 composing
a portion of the sintering process. Also, into this hot blast feeding device 16, it
is possible to introduce a hot blast of gas at not lower than 100°C which has been
discharged from the wind boxes 8 and passed through the waste gas introducing pipe
10, flow rate adjusting valve 11, waste gas dust collector 12' and suction blower
13'. Both the hot blast discharged from the cooling unit 17 and the waste gas of not
lower than 100°C discharged from the wind boxes may be simultaneously fed to the hot
blast feeding device 16. However, it is possible to feed one of than alone. It is
also possible to feed the mixture of them, the temperature of which is adjusted to
a predetermined value.
[0030] Concerning the state in which the microwave irradiation and the hot blast blowing
are combined with each other, the following states may be adopted. It is possible
to arrange the microwave generator 15 alone. It is also possible to arrange the microwave
generator 15 and the hot blast feeding device 16 in series. Although not shown in
the drawing, it is possible to arrange the microwave generator in the first half of
the hot blast feeding device 16, or it is also possible to arrange the microwave generators
at regular intervals in the longitudinal direction of the pallets 6. Concerning the
temperature control method for heating the raw material layer 7 on the pallets 6 by
the irradiation of microwaves, it is possible to adopt a method in which an amount
of energy of irradiated microwaves is adjusted, and also it is possible to adopt a
method in which an area of irradiation of microwaves onto the raw material layer moving
at a predetermined speed is adjusted. This method may be adopted alone or combined
with another method.
BRIEF DESCRIPTION OF THE DRAWINGS
[0031] Fig. 1 is an arrangement view of an example of the equipment to execute the method
of the present invention.
[0032] Fig. 2a is a graph on which the productivity, sintering time and product yield of
examples and comparative examples are shown. Fig. 2b is a graph showing the shatter
strength (SI), low temperature reduction degradation index (RDI) and consumption of
generation of NO
x.
MOST PREFERRED EMBODIMENT
[0033] Referring to an example, the most preferred embodiment of the present invention will
be explained below.
EXAMPLES
[0034] A specific example will be explained in detail in accordance with the above exemplary
equipment and the operation method.
[0035] Table 1 shows a blending proportion of raw materials used in this example. Raw materials
were blended in such a manner that various iron ores and miscellaneous raw materials
such as limestone, quick lime, serpentine, scale and so forth were adjusted and blended
so that SiO
2 and Al
2O
3 in the sintered ore could be respectively 5.8% and 1.8% and so that the basicity
could be 1.7. In this case, a ratio of returned ore was determined to be a constant
value of 15% with respect to new raw material. A coke breeze blending ratio was determined
to be a constant value of 4.0% with respect to the total 100 of new raw materials.
Table 1
Brand of raw material |
Blending proportion (%) |
Newman fine ore |
10.0 |
Roberiver fine ore |
25.0 |
Yandicoogina fine ore |
10.0 |
Rio-Dose SSF powder ore |
5.0 |
Carol fine ore |
10.0 |
Yampi fine ore |
12.5 |
Iscole undersized ore |
6.0 |
Scale |
5.0 |
Serpentine fine |
2.5 |
Limestone fine |
12.0 |
Quick lime |
2.0 |
Total of new raw materials |
100.0 |
Returned ore (outer number) |
15.0 |
Coke breeze (outer number) |
4.0 |
[0036] Returned ore and coke breeze were blended with the above blended raw material, and
then addition water of 6 to 7 wt% was added to the blended raw material and mixed
by a mixer and pelletized. After that, it was put into a test pan, and the layer thickness
was set at 500 mm and the negative pressure was set at a constant value of 1200 mmAq.
Concerning the heating conducted by microwaves or the heating conducted by both microwaves
and a hot blast, a simulating method was adopted in which the surface layer of raw
material was dried and heated before the ignition in the Dwight Lloyd type sintering
machine. In Example 1, the ignition time was set at 1.5 min. Before the ignition,
microwaves, the intensity of which was 10 kW, were irradiated for 1.0 min, so that
the surface layer of raw material was heated to 150°C before the ignition. In Example
2, microwaves, the intensity of which was 10 kW, were irradiated for 1.0 min before
the ignition, so that the surface layer of raw material was heated to 150°C. After
that, a hot blast of 300°C was sucked for 1.0 min, so that the surface layer of raw
material was heated to 350°C before the ignition, and then the surface layer of raw
material was ignited for 1.5 min. In Example 3, before the ignition, microwaves, the
intensity of which was 10 kW, were irradiated for 1.0 min, and a hot blast of 300°C
was simultaneously sucked for 1.0 min, so that the surface layer of the raw material
was heated to 380°C and then ignited for 1.5 min. It should be noted that the temperature
of a hot blast, the sucking time of a hot blast and the heating time of microwaves
are not limited to the above specific values. It was more effective that the heating
time of microwaves was 0.2 to 1.5 min. Also, it was more effective that a hot blast
of 200 to 400°C was sucked for 0.5 to 3 min.
[0037] Comparative Example 1 was a conventional method in which drying and heating is not
conducted before the ignition. Comparative Example 2 was a method in which a hot blast
of 300°C was sucked for 1.0 min before ignition, and then microwaves, the intensity
of which was 10 kW, were irradiated for 1.0 min so as to heat the surface layer of
raw material.
[0038] In Comparative Example 2, with respect to Examples 1, 2 and 3, sampling was conducted
on the raw material on the surface layer of raw material before the ignition which
had already been dried and heated, and particles, the size of which was not more than
0.5 mm, were sifted out. The weight of thus sifted particles was measured and the
ratio was computed. In Comparative Example 2, the ratio of particles, the size of
which was not more than 0.5 mm, was 8.0 to 9.0%. However, in Examples 1, 2 and 3,
the ratio of particles, the size of which was not more than 0.5 mm, was not more than
1.0 %.
[0039] Fig. 2a is a graph showing the productivity, sintering time and product yield obtained
in the pan tests conducted in Examples 1, 2 and 3 and Comparative Examples 1 and 2.
Fig. 2b is a graph showing the shatter strength (SI), low temperature reduction degradation
index (RDI) and consumption of NO
x obtained in Examples 1, 2 and 3 and Comparative Examples 1 and 2.
[0040] As can be seen in Fig. 2a, the product yield in Examples 1, 2 and 3 of the present
invention is higher than that in Comparative Examples 1 and 2 by 2 to 3%, and the
sintering time including the heating time before the ignition in Examples 1, 2 and
3 of the present invention is shorter than that in Comparative Examples 1 and 2 by
1 to 3 minutes. Further, the productivity in Examples 1, 2 and 3 of the present invention
is higher than that in Comparative Examples 1 and 2 by 0.1 to 0.25 T/H/m
2. As can be seen in Fig. 2b, the shatter strength (SI) in Examples 1, 2 and 3 of the
present invention is higher than that in Comparative Examples 1 and 2 by 1 to 1.5%,
and the low temperature reduction degadation indexes (RDI) in Examples 1, 2 and 3
of the present invention are higher than those in Comparative Examples 1 and 2 by
1 to 3%. Furthermore, it can be understood that the NO
x discharge consumption is improved by 0.02 to 0.06 Nm
3/t-s. As described above, according to the present invention, it is possible to remarkably
enhance the product characteristic, and when the technique of the present invention
is executed, it is possible to provide excellent effects in the fields of operation
efficiency and environment protection.
[0041] The reason why an amount of NO
x to be discharged can be reduced is that NO
x generated in the sintering process is mainly composed of Fuel NO
x, and the generation of NO
x is suppressed when the temperature is raised, which is contrary to the phenomenon
of Thermal NO
x. It is considered that the generation of NO
x can be reduced since the maximum temperatures of the upper and the intermediate sintering
layer, which are layers from which a large amount of NO
x is generated, are raised according to the method of the present invention.
INDUSTRIAL APPLICABILITY
[0042] According to the method of the present invention, the following effects can be provided.
The product yield can be greatly enhanced as compared with the method of the prior
art. The productivity can be also enhanced, and SI and RDI can be improved. As a result,
the consumption of an amount of NO
x to be discharged can be greatly reduced. It is possible to change the combination
of electric power of microwaves, heating time, hot blast temperature and hot blast
suction time in accordance with the instruction of operation. The above degree of
freedom is one of the advantages of the method of the present invention. As described
above, according to the present invention, it is possible to simultaneously provide
effects which are not compatible with each other. Therefore, the present invention
can provide great effects.
DESCRIPTION OF REFERENCE NUMERALS
[0043]
- 1
- Blended raw material to be sintered
- 2
- Surge hopper
- 3
- Drum feeder
- 4
- Sprocket
- 5
- Raw material charging device
- 6
- Pallet
- 7
- Laminated raw material
- 8
- Wind box
- 9
- Main duct
- 10
- Waste gas introducing pipe
- 11
- Flow rate adjusting valve
- 12
- Waste gas dust collector
- 12'
- Waste gas dust collector
- 13
- Suction blower
- 13'
- Suction blower
- 14
- Ignition furnace
- 15
- Microwave generator
- 16
- Hot blast feeding device
- 17
- Cooler
- 18
- Waste gas pipe