(19) |
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(11) |
EP 0 807 616 A3 |
(12) |
EUROPEAN PATENT APPLICATION |
(88) |
Date of publication A3: |
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26.11.1997 Bulletin 1997/48 |
(43) |
Date of publication A2: |
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19.11.1997 Bulletin 1997/47 |
(22) |
Date of filing: 14.05.1997 |
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(84) |
Designated Contracting States: |
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DE FR GB NL |
(30) |
Priority: |
14.05.1996 US 645972
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(71) |
Applicant: CHEVRON CHEMICAL COMPANY |
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San Francisco,
California 94120-7027 (US) |
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(72) |
Inventors: |
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- Harris, Thomas V.
Benicia CA 94510 (US)
- Habib, Mohammed B.
Benicia CA 94510 (US)
- Campbell, Curtis B.
Hercules CA 94547 (US)
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(74) |
Representative: Nash, David Allan |
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Haseltine Lake & Co.,
Imperial House, 15-19 Kingsway London WC2B 6UD London WC2B 6UD (GB) |
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(54) |
Process for procucing an alkylated, non-oxygen-containing aromatic hydrocarbon |
(57) The application relates to a process for the preparation of alkylated aromatic hydrocarbons
by isomerisation of a normal alpha-olefin having preferably 20 to 28 carbon atoms
in the presence of a first acidic catalyst which can be a molecular sieve with a one-dimensional
pore system; the isomerised olefin is then used as alkylating agent for a non-oxygen-containing
aromatic hydrocarbon such as benzene, toluene, xylene or cumene, in the pressence
of a second acidic catalyst selected from the group consisting natural zeolites, synthetic
zeolites and clays, preferably zeolite Y.
The prepared compound, which forms a further aspect of the invention, has less than
40 wt.% of components characterised by having 2-aryl attachment, at least 20 wt.%
(preferably at least 75 wt.%) monoalkylate, and not more than 80% of the alkyl groups
are branched.