(19)
(11) EP 0 807 616 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
26.11.1997 Bulletin 1997/48

(43) Date of publication A2:
19.11.1997 Bulletin 1997/47

(21) Application number: 97303282.4

(22) Date of filing: 14.05.1997
(51) International Patent Classification (IPC)6C07C 2/70, C07C 5/25, C07C 15/107
(84) Designated Contracting States:
DE FR GB NL

(30) Priority: 14.05.1996 US 645972

(71) Applicant: CHEVRON CHEMICAL COMPANY
San Francisco, California 94120-7027 (US)

(72) Inventors:
  • Harris, Thomas V.
    Benicia CA 94510 (US)
  • Habib, Mohammed B.
    Benicia CA 94510 (US)
  • Campbell, Curtis B.
    Hercules CA 94547 (US)

(74) Representative: Nash, David Allan 
Haseltine Lake & Co., Imperial House, 15-19 Kingsway
London WC2B 6UD
London WC2B 6UD (GB)

   


(54) Process for procucing an alkylated, non-oxygen-containing aromatic hydrocarbon


(57) The application relates to a process for the preparation of alkylated aromatic hydrocarbons by isomerisation of a normal alpha-olefin having preferably 20 to 28 carbon atoms in the presence of a first acidic catalyst which can be a molecular sieve with a one-dimensional pore system; the isomerised olefin is then used as alkylating agent for a non-oxygen-containing aromatic hydrocarbon such as benzene, toluene, xylene or cumene, in the pressence of a second acidic catalyst selected from the group consisting natural zeolites, synthetic zeolites and clays, preferably zeolite Y.
The prepared compound, which forms a further aspect of the invention, has less than 40 wt.% of components characterised by having 2-aryl attachment, at least 20 wt.% (preferably at least 75 wt.%) monoalkylate, and not more than 80% of the alkyl groups are branched.





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