(19)
(11) EP 0 841 410 A1

(12) EUROPEAN PATENT APPLICATION
published in accordance with Art. 158(3) EPC

(88) Date of publication A3:
30.01.1997

(43) Date of publication:
13.05.1998 Bulletin 1998/20

(21) Application number: 96925205.5

(22) Date of filing: 09.07.1996
(51) International Patent Classification (IPC)6C22C 38/24
(86) International application number:
PCT/RU9600/184
(87) International publication number:
WO 9703/217 (30.01.1997 Gazette 1997/06)
(84) Designated Contracting States:
DE FR GB IT SE

(30) Priority: 11.07.1995 RU 95110850
11.07.1995 RU 95110851
11.07.1995 RU 95110852

(71) Applicants:
  • Fedchun, Vladimir Alexeevich
    Moscow 111116 (RU)
  • Aslibekyan, Felix Surenovich
    Moscow 117071 (RU)
  • Prokofiev, Vladimir Konstantinovich
    Moscow 117419 (RU)

(72) Inventors:
  • Fedchun, Vladimir Alexeevich
    Moscow 111116 (RU)
  • Aslibekyan, Felix Surenovich
    Moscow 117071 (RU)
  • Prokofiev, Vladimir Konstantinovich
    Moscow 117419 (RU)

(74) Representative: Allen, William Guy Fairfax 
J.A. KEMP & CO. 14 South Square Gray's Inn
London WC1R 5LX
London WC1R 5LX (GB)

   


(54) ALLOYED CONSTRUCTION STEEL


(57) Alloyed construction steel containing carbon, silicon, manganese, chromium, vanadium and iron, and containing in addition a plasticity-enhancing and nitration-boosting chemical element, the relative proportions of components being (wt. %):
Carbon 0.10-0.63
Silicon 0.20-1,20
Manganese 0.40-0.60
Chromium 0.60-3.00
Plasticity-enhancing and nitration-boosting chemical element 0.40-1.50
Vanadium 0.15-0.35
Iron Rem.

The plasticity-enhancing and nitration-boosting chemical element used is copper or germanium.


Description

Scope of Application



[0001] The invention pertains to metallurgy, in particular, compositions of steels used for fabrication of critical parts for machine-building industry.

Previous Technology Level



[0002] The alloyed construction steel with the composition (wt. %) shown below is known:
Carbon 0.4 max
Silicon 0.56-1.5
Manganese 0.30-2.0
Chromium 0.71-3.0
Vanadium 0.21-1.0
Aluminum 0.3 max
Iron Rem.
(JP, A, # 52-27584)  


[0003] This steel does not offer the required complex of properties, especially plasticity, elimination of intercrystalline brittleness and boosted nitration process.

[0004] Also known is the alloyed construction steel that has the following components, wt. %:
Carbon 0.30-0.45
Manganese 0.30-0.60
Silicon 0.17-0.37
Chromium 1.50-2.50
Vanadium 0.20-0.50
Germanium 0.20-0.80
Iron Rem.
(SU, A, # 926060)  


[0005] The advantage of this steel is low strength at satisfactory plasticity across the cross section of the part made thereof following both traditional hardening methods and low-temperature nitration. Besides, there is a likelihood of temper brittleness typical of nitrided steels that are currently used.

[0006] The alloyed construction steel that contains carbon, silicon, manganese, chromium, molybdenum, nickel, vanadium and iron in proportions shown below (wt. %) is the closest from the point of view of the technological content and result sought:
Carbon 0.27-0.34
Silicon 0.17-0.60
Manganese 0.30-0.60
Chromium 2.30-2.70
Molybdenum 0.20-0.30
Nickel 0.12-0.30
Vanadium 0.06-0.12
Iron Rem.
(Steel 30X3MΦ, GOST 4543-71. Alloyed construction steel, grades and specifications).


[0007] The disadvantage of this steel are low yield and hardness, slow rate of saturation during nitrating and presence of scarcely available molybdenum arid nickel that results in high production costs. Besides, there is a likelihood of temper brittleness typical of nitrided steels that are currently used.

Disclosure Of The Invention



[0008] This invention is based on the objective to ensure high physical and mechanical properties of steel combined with high plasticity across the cross section of the part made thereof, following both traditional hardening techniques (quenching, tempering) and low-temperature nitration at 470-520°C, with minimum tendency for temper brittleness, as well as fabrication cost reduction.

[0009] The nature of the invention lies in the fact that, besides carbon, silicon, manganese, chromium, vanadium and iron, the alloyed construction steel additionally contains a chemical element that enhances plasticity and boosts the nitration process. The content of components is as follows, wt. %:
Carbon 0.10-0.63
Silicon 0.20-1.20
Manganese 0.40-0.60
Chromium 0.60-3.00
Plasticity-enhancing and nitration-boosting chemical element 0.40-1.50
Vanadium 0.15-0.35
Iron Rem.


[0010] Also, either copper or germanium are used as the chemical element that enhances plasticity and boosts the nitration process.

[0011] The copper content is 0.40-0.80 wt. %, provided the silicon/copper ratio is 1.5-2.5.

[0012] The germanium content is 0.60-1.50 wt. %, provided the silicon content is 0.20-0.40 wt. %.

[0013] The combination of essential features described above is aimed at achieving the technical result sought and is related to it through cause and consequence, as it makes it possible to:
  • ensure superior strength and hardness properties of the alloyed construction steel that has high plasticity across the entire cross section of the part made thereof, due to the chemical composition of the steel, shown above;
  • boost the nitration process and ensure high plasticity across the cross section of parts;
  • bring the steel making cost down by eliminating scarcely available components.


[0014] Besides, the invention may be used commercially in various industries for fabrication of critical parts and components.

[0015] Thus, a conclusion may be drawn that the technical invention claimed meets the requirements of its patentability.

The Best Way to Exercise The Invention



[0016] An experimental batch of alloyed construction steel is produced in an induction furnace. This experimental batch is then used to fabricate blanks that are to be exposed to quenching for 20 minutes at 890°C and to oil cooling and tempering for 3 hrs at 200°C and air cooling.

[0017] Standard mechanical properties are to be determined, i.e.: ultimate tensile strength σB, yield point σ0.2, elongation δ, reduction ψ, impact strength KCV+20 and Rockwell hardness, HRC, as well as surface hardness HV, layer thickness up HV-400, comparative wear resistance, fatigue strength of nitrided samples σ-1, endurance strength of nitrided samples σk-1 and impact strength of nitrided samples KCV+20.

[0018] Table 1 shows steel compositions which use copper as the plasticity-enhancing and nitration-boosting the element; Table 2 contains steel compositions in which germanium is used as the plasticity-enhancing and nitration-boosting element. Mechanical properties of steels listed in Table 1 are shown in Table 3; operational properties of steels included in Table 1, after nitration, are described in Table 4; mechanical properties of steels listed in Table 2 are summarized in Table 5 and operational properties of steels included in Table 2, after nitration, are included in Table 6.

Commerical Use



[0019] Use of the alloyed construction steel in question will help to ensure superior physical and mechanical properties combined with high plasticity across the entire cross section of the part made thereof, with minimum tendency for temper brittleness, and reduce the steel making cost by 30-40%.
Table 1
Component Composition, mass %
  1 2 3 Prototype
Carbon 0.10 0.35 0.63 0.30
Silicon 0.80 0.90 1.20 0.27
Manganese 0.40 0.50 0.60 0.45
Chromium 0.60 1.80 3.00 2.50
Chemical element that enhances plasticity and boosts 0.40 0.50 0.80 -
nitration - copper 0.15 0.25 0.35 0.09
Vanadium Rem. Rem. Rem. Rem.
Iron        


2.0 1.8 1.5 -
Table 2
Component Composition, mass %
  1 2 3 Prototype
Carbon 0.10 0.35 0.63 0.30
Silcon 0.20 0.29 0.40 0.27
Manganese 0.40 0.50 0.60 0.45
Chromium 0.60 1.80 3.00 2.50
Chemical element that enhances plasticity and boosts 0.60 1.02 1.50 -
nitration - germanium 0.15 0.20 0.35 0.09
Vanadium Rem. Rem. Rem. Rem.
Iron        






Table 6
Steel Nitration conditions Nitrided layer depth, mm Surface hardness HV, N/mm2 Comparative wear resistance, Fatigue strength σ-1, N/mm2 Endurance strength N/mm2
Offered            
1 500°C 36 hrs 0.98 580 1.02 530 1420
2 500°C 36 hrs 0.87 7800 1.31 890 2320
3 500°C 36 hrs 0.74 7950 1.28 780 2200
Prototype 500°C 36 hrs 0.40 7150 1.18 620 1300



Claims

1. Alloyed construction steel containing carbon, manganese, chromium, vanadium and iron, characterized by containing, in addition, a chemical element that enhances plasticity and boosts the nitration process, the component ratio being (wt/%):
Carbon 0.10-0.63
Silicon 0.20-1.20
Manganese 0.40-0.60
Chromium 0.60-3.00
Plasticity-enhancing and nitration-boosting chemical element 0.40-1.50
Vanadium 0.15-0.35
Iron Rem.

 
2. Alloyed construction steel according to claim 1, characterized by the use of copper or germanium or as the plasticity-enhancing and nitration-boosting chemical element.
 
3. Alloyed construction steel according to claims 1 and 2, characterized in that the copper content is 0.40-0.80 wt.%, provided the silicon copper ratio is maintained at 1.5-2.5.
 
4. Alloyed construction steel according to claims 1 and 2, characterized in that the germanium content is 0.60-1.50 wt.%, provided the silicon content is 0.20-0.40 wt.%.
 





Search report