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<ep-patent-document id="EP98500006B1" file="EP98500006NWB1.xml" lang="en" country="EP" doc-number="0853948" kind="B1" date-publ="20040407" status="n" dtd-version="ep-patent-document-v1-1">
<SDOBI lang="en"><B000><eptags><B001EP>ATBECHDEDK..FRGBGRITLILUNLSEMCPTIE..............................................</B001EP><B005EP>J</B005EP><B007EP>DIM350 (Ver 2.1 Jan 2001)
 2100000/0</B007EP></eptags></B000><B100><B110>0853948</B110><B120><B121>EUROPEAN PATENT SPECIFICATION</B121></B120><B130>B1</B130><B140><date>20040407</date></B140><B190>EP</B190></B100><B200><B210>98500006.6</B210><B220><date>19980115</date></B220><B240><B241><date>19990415</date></B241><B242><date>20030120</date></B242></B240><B250>es</B250><B251EP>en</B251EP><B260>en</B260></B200><B300><B310>9700101</B310><B320><date>19970120</date></B320><B330><ctry>ES</ctry></B330></B300><B400><B405><date>20040407</date><bnum>200415</bnum></B405><B430><date>19980722</date><bnum>199830</bnum></B430><B450><date>20040407</date><bnum>200415</bnum></B450></B400><B500><B510><B516>7</B516><B511> 7A 61L   9/12   A</B511><B512> 7A 01M   1/20   B</B512></B510><B540><B541>de</B541><B542>Verfahren und Vorrichtungen zur Konstantverdünstung</B542><B541>en</B541><B542>Process and devices for the constant emission of volatile liquids</B542><B541>fr</B541><B542>Procédé et dispositifs d'émission constante de liquides volatiles</B542></B540><B560><B561><text>DE-C- 19 525 885</text></B561><B561><text>FR-A- 2 063 960</text></B561><B561><text>US-A- 3 587 968</text></B561><B561><text>US-A- 4 165 835</text></B561><B561><text>US-A- 4 286 754</text></B561><B561><text>US-A- 5 437 410</text></B561></B560><B590><B598>3</B598></B590></B500><B700><B720><B721><snm>Esteban Duran, Jose Rafael</snm><adr><str>Vallehermoso, 102</str><city>28003 Madrid</city><ctry>ES</ctry></adr></B721></B720><B730><B731><snm>INSTITUTO NACIONAL DE INVESTIGACION Y TECNOLOGIA, AGRARIA Y ALIMENTARIA</snm><iid>01658430</iid><irf>E/ 3.870</irf><syn>INVESTIGACION Y TECNOLOGIA, AGRARIA Y ALIMENTARIA, INSTITUTO NACIONAL DE</syn><syn>AGRARIA Y ALIMENTARIA, INSTITUTO NACIONAL DE INVESTIGACION Y TECNOLOGIA,</syn><adr><str>José Abascal 56</str><city>E-28003 Madrid</city><ctry>ES</ctry></adr></B731></B730><B740><B741><snm>Gonzalez Vacas, Eleuterio</snm><iid>00054341</iid><adr><str>Calle Sagasta, 4</str><city>28004 Madrid</city><ctry>ES</ctry></adr></B741></B740></B700><B800><B840><ctry>AT</ctry><ctry>BE</ctry><ctry>CH</ctry><ctry>DE</ctry><ctry>DK</ctry><ctry>FR</ctry><ctry>GB</ctry><ctry>GR</ctry><ctry>IE</ctry><ctry>IT</ctry><ctry>LI</ctry><ctry>LU</ctry><ctry>MC</ctry><ctry>NL</ctry><ctry>PT</ctry><ctry>SE</ctry></B840></B800></SDOBI><!-- EPO <DP n="1"> -->
<description id="desc" lang="en">
<heading id="h0001">OBJECT OF THE INVENTION</heading>
<p id="p0001" num="0001">The object of the invention is a "process and devices for the constant emission of volatile liquids".</p>
<p id="p0002" num="0002">The process proposed by the invention is based on the absorption of volatile liquids through solid absorbents made of diverse materials of a different nature and composition.</p>
<heading id="h0002">BACKGROUND OF THE INVENTION</heading>
<p id="p0003" num="0003">At present, volatile liquid products such as insecticides, aromatic substances, disinfectants, phytosanitary products, semochemicals, etc., are dispersed with the use of dispersing products or generally manually, mechanically, thermoelectrically or otherwise activated devices requiring permanent attention which in many case renders their use impracticable. On the other hand, these dispersing devices fail to provide a constant emission of the volatile product in question.</p>
<p id="p0004" num="0004">In specific cases where the product must be dispersed over extended areas of farm or woodland, applying these products requires a large number of special machines and propellents almost impossible to install, particularly in places that are not readily accessible.</p>
<p id="p0005" num="0005">Known dispersers of a scientific nature based on fluid mechanics or physics fail to provide satisfactory results in equatorial or tropical environments with extremely high diurnal temperatures, high levels of relative humidity, abrupt temperature falls during the dusk and night hours<!-- EPO <DP n="2"> --> and ambient humidities in the order of 100%.</p>
<p id="p0006" num="0006">On the other hand, the use of additional driving elements of a mechanical or thermoelectrical nature which could (and in cases do) solve this problem entails high operating costs and the difficulty of reaching almost inaccessible locations lacking electricity or fuel for driving the system.</p>
<p id="p0007" num="0007">The invention presents a simple and efficient solution to these problems and proposes the process and special devices described hereunder.</p>
<p id="p0008" num="0008">The use of dispersers heretofore available in the market and applied to agricultural and forestry research purposes in moderate continental climates presents several practical inconveniences which may be overcome by manual modifications varying from one case to the other. However, the use of known dispersers in wet equatorial forest environments fails to respond to the minimum expected operational requirements.</p>
<p id="p0009" num="0009">Bearing in mind that the research undertaken employed dispersers that were calibrated to some extent, solving the problems encountered in the putting into operation as a result of basic instrument failures was the first step toward executing the work.</p>
<p id="p0010" num="0010">As a first step, a thorough examination was carried out to establish the causes that led to known disperser failures essentially deriving from the critical ambient temperature and humidity conditions that prevailed, particularly in the Amazon forest. During diurnal hours, with a constant temperature of 30°C and a relative humidity never under 85%, dispersion of the volatile liquids took place at an extremely high (evaporated volume/time unit) rate. On the contrary, as from dusk, when the relative humidity reached 100% (condensation), the temperature dropped to under 18°C and the condensation water created a tight chamber around the disperser which fully inhibited<!-- EPO <DP n="3"> --> the evaporation of the volatile liquid to be dispersed.</p>
<p id="p0011" num="0011">Since the causes of known disperser failures could not be solved by modifying the dispersers, other devices had to be created.</p>
<p id="p0012" num="0012">A disperser was thus created capable of efficiently responding to the required demands.</p>
<p id="p0013" num="0013">The results obtained, which solve the problem involving a break in the dispersion caused by a relative humidity of almost 100%, in addition to continuous and regular daily dispersion rates which varied from 0.5 to more than 2 cc, led to the creation of the system proposed in this document.</p>
<p id="p0014" num="0014">It should be understood that the invention has multiple sanitary, cosmetic, agricultural, forestry, etc., applications.</p>
<heading id="h0003">DESCRIPTION OF THE INVENTION</heading>
<p id="p0015" num="0015">The device and method of the present invention are defined in appended claims 1 and 5, respectively.</p>
<p id="p0016" num="0016">In the process described, absorption of the volatile liquids, in particular volatile solvents (with or without accompanying solutes), is conducted through solid absorbents from which they emanate in the form of gas by a physical principle involving vapor pressures differences and air drawing, without the weight of the liquid or solvent intervening and resorting neither to motor and thermoelectrical means nor to compressed fluid dispersers.</p>
<p id="p0017" num="0017">Through the process of the present invention, constant dispersion of the substances is achieved in a free or controlled manner, depending on the selected option.</p>
<p id="p0018" num="0018">The following elements are foreseen for putting the described process to practical use:
<ul id="ul0001" list-style="none" compact="compact">
<li>a) A tank containing the liquid product or composition to be dispersed.</li>
<li>b) An absorbent-diffuser mass, duly conditioned and protected, contained in the above tank and totally or<!-- EPO <DP n="4"> --> partially immersed in the liquid product to be dispersed.</li>
<li>c) A tubular body, with multiple strategically distributed holes, for holding the absorbent mass.</li>
<li>d) A perpendicular tube or sleeve either incorporated or integral to the tank's closing lid, said sleeve having the absorbent mass-containing tubular body tightly adapted thereto in such a way that the mass is immersed in the liquid in the tank.</li>
<li>e) A tank closing lid providing a virtually impervious closure, said lid sustaining the perforated tubular element in an upright position, from the upper end of which flows, in its gaseous state, the liquid product contained in the tank.</li>
<li>f) The perforated tubular body holding the absorbent mass is free of absorbent material in its upper portion, which forms a chamber with unobstructed holes allowing the external gas- carrying air to flow therethrough, into the chamber and on to the outlet passage.</li>
<li>g) A disk-shaped, centrally perforated lid which tightly adapts to the upper end of the perforated tubular body and closes the chamber formed in said body.</li>
<li>h) A roof-shaped lid which closes the free upper end of the device and furthermore covers and protects the outlet passage of the product in its gaseous state, avoiding obstructions.</li>
</ul></p>
<p id="p0019" num="0019">The following description provides a better understanding of the object of the invention if contemplated jointly with the attached drawings that show, somewhat schematically and purely in the form of a non-limiting example, the preferred assemblies and details of the devices for a practical embodiment of said object of the invention.</p>
<p id="p0020" num="0020">In the drawings:</p>
<p id="p0021" num="0021">Figure 1 shows a half-section elevation view along a vertical plane of the perforated tubular element lodging<!-- EPO <DP n="5"> --> the absorbent mass.</p>
<p id="p0022" num="0022">Figure 2 shows an exploded view of the set of elements comprising the overall liquid product emission device.</p>
<p id="p0023" num="0023">Figure 3 shows a half-section elevation view along a vertical plane of the grouped set of elements forming the disperser, depicted in a fully assembled manner, its tank containing the liquid product to be dispersed.</p>
<p id="p0024" num="0024">Commenting on the drawings, number 1 identifies the tank containing the liquid product, the level of which is identified by 2. In the practical embodiment of the invention, this tank forms a vessel fitted with means 3 for receiving and securely retaining a disk-shaped lid 4 providing a virtually impervious closure; said lid 4 is fitted with a large central hole 5 surrounded by a neck 6 extending along both sides and forming a tubular housing for tightly lodging a tubular cylindrical element 7 endowed with strategically distributed holes 8 throughout its surface. The tubular element 7 contains an absorbent mass 9; said tubular element 7 penetrates perpendicularly in the tank 1, rests on the bottom thereof in a securely upright position and protrudes above the lid 4 along a portion devoid of absorbent mass 9; this free portion forms a chamber 10 into which ambient air penetrates through the holes 8 to displace the gases emitted from the absorbent mass, causing them to flow through the passage located on the center of a closing part 11 tightly adapted onto the upper end of tubular element 7; lastly, said closure part is covered by a bonnet supported by nerves 14 which emerge from an annular sector of base 15 fitted over the lid 11 providing the upper closure of perforated tube 7.</p>
<p id="p0025" num="0025">The tank 1 holds the liquid product or composition 2, which may additionally contain other finely divided or solid components, as indicated by number 16.</p>
<p id="p0026" num="0026">Following its preparation, the liquid product or composition to be dispersed is fed into the tank 1 up to a<!-- EPO <DP n="6"> --> specified level 2, optionally incorporating solid or powdered components 16. The tubular body 7 fitted with holes 8 and containing the absorbent mass 9 is inserted perpendicularly in an upright position and is immersed in the liquid which, through the holes 8, impregnates the overall absorbent mass 9, from which it flows in its gaseous state and penetrates the upper chamber 10, from where it is conveyed to passage 12 by the air entering the chamber 10 formed in the upper end of the perforated tubular body 7, to be finally dispersed in the external environment. Over the upper end of tubular body 7 and lid 11 is installed a covering element formed by a substantially conical bonnet 13 supported by vertical nerves 14 which extend from an annular base 15 securely adapted over the lid 11 which closes the upper end of central body 7.</p>
</description><!-- EPO <DP n="7"> -->
<claims id="claims01" lang="en">
<claim id="c-en-01-0001" num="0001">
<claim-text>A device for the constant emission of volatile liquids comprising:
<claim-text>- a tank (1) having a bottom and containing a volatile liquid product to be dispersed;</claim-text>
<claim-text>- an absorbent mass (9) for absorbing the product to be dispersed;</claim-text>
<claim-text>- a tubular body (7) having a plurality of holes (8) formed around and along the surface thereof, an upper end, a lower end, and an interior volume, the tubular body (7) arranged in a vertical position wherein the lower end of the tubular body (7) rests on the bottom of the tank (1), wherein the absorbent mass (9) fills the interior volume of the tubular body (7) except at the upper end of the tubular body (7) which is devoid of the absorbent mass (9) forming a chamber (10), and wherein the absorbent mass (9) is in contact with the liquid product contained in the tank (1) through the plurality of holes (8) in the tubular body (7);</claim-text>
<claim-text>- a tank closure lid (4) provided with a central hole (5) having a diameter which allows the tubular body (7) to be passed therethrough; and</claim-text>
<claim-text>- a tubular body closing element (11) provided with a central opening (12), the tubular body closing element (11) being tightly fitted on the upper end ofthe tubular body (7) such that the product to be dispersed is capable of flowing, in the form of a gas, through the central opening (12) for dispersion.</claim-text></claim-text></claim>
<claim id="c-en-01-0002" num="0002">
<claim-text>Device according to claim 1, wherein the chamber (10) devoid of absorbent mass (9) at the upper end of the tubular body (7) protrudes above said tank closure lid (4), such that air can penetrate into said chamber (10) through the plurality of holes (8) at the upper end of the tubular body (7) so that the product which flows in the form of a gas from the absorbent mass (9) into the chamber (10) is caused to flow through the central opening and out of the device.</claim-text></claim>
<claim id="c-en-01-0003" num="0003">
<claim-text>Device according to claim 1, further comprising a covering element (13) disposed above the upper end of the tubular body (7) and the tubular body closing element (11), the covering element (13) being shaped as a bonnet having a diameter bigger than the diameter of the tubular<!-- EPO <DP n="8"> --> body closing element (11) for protecting the central opening from potential obstructions.</claim-text></claim>
<claim id="c-en-01-0004" num="0004">
<claim-text>Device according to claim 1, wherein the liquid product includes a solid material in suspension.</claim-text></claim>
<claim id="c-en-01-0005" num="0005">
<claim-text>A process for the constant emission of volatile liquids using a device according to claim 1, wherein absorption of the volatile liquids contained in a tank is conducted via the absorbent mass contained in said tank, from which they flow in the form of gas, by virtue of vapour pressure differences and air drawing without intervention of the weight of the liquid.</claim-text></claim>
</claims><!-- EPO <DP n="9"> -->
<claims id="claims02" lang="de">
<claim id="c-de-01-0001" num="0001">
<claim-text>Eine Vorrichtung für die konstante Emission von flüchtigen Flüssigkeiten, bestehend aus:
<claim-text>- einem Tank (1) mit einem Boden, der eine flüchtige Flüssigkeit beinhaltet, die dispergiert werden muss;</claim-text>
<claim-text>- einer absorbierende Masse (9) für die Absorption des zu dispergierenden Produktes;</claim-text>
<claim-text>- einem röhrenförmigen Körper (7) mit einer Vielzahl an Löchern (8), die sich rundherum und entlang dessen Oberfläche befinden, ein oberes Ende, ein unteres Ende und ein inneres Volumen, wobei der röhrenförmige Körper (7) vertikal angebracht ist und das untere Ende des röhrenförmigen Körpers (7) auf dem Boden des Tanks (1) liegt, wobei die absorbierende Masse (9) das innere Volumen des röhrenförmigen Körpers (7) bis auf das obere Ende des röhrenförmigen Körpers (7) ausfüllt, welches nicht mit der absorbierenden Masse (9) gefüllt ist und eine Kammer (10) bildet, und wobei die absorbierende Masse (9) durch die Vielzahl der Löcher (8) in den röhrenförmigen Körper (7) in Kontakt mit dem flüssigen Produkt tritt, das sich im Tank (1) befindet;</claim-text>
<claim-text>- einen Tankverschlussdeckel (4), der mit einem zentralen Loch (5) ausgestattet ist, welches einen Durchmesser hat, der es ermöglicht, den röhrenförmigen Körper (7) durch das Loch zu führen; und</claim-text>
<claim-text>- einem Schließelement (11) für den röhrenförmigen Körper mit einer zentralen Öffnung (12), wobei dieses Schließelement (11) des röhrenförmigen Körpers fest an das obere Ende des röhrenförmigen Körpers (7) angepasst ist, so dass das zu dispergierende Produkt in Form von Gas durch die zentrale Dispersionsöffnung (12) strömen kann.</claim-text></claim-text></claim>
<claim id="c-de-01-0002" num="0002">
<claim-text>Vorrichtung nach Anspruch 1, wobei die Kammer (10)<!-- EPO <DP n="10"> --> am oberen Ende des röhrenförmigen Körpers (7), die nicht mit der absorbierenden Masse (9) gefüllt ist, über dem genannten Tankverschlussdeckel (4) hervorsteht, so dass Luft durch die Vielzahl der Löcher (8) am oberen Ende des röhrenförmigen Körpers (7) in die genannte Kammer (10) eindringen kann, was dazu führt, dass das Produkt, das in Form von Gas von der absorbierenden Masse (9) in die Kammer (10) fließt, durch die zentrale Öffnung aus der Vorrichtung heraus strömt.</claim-text></claim>
<claim id="c-de-01-0003" num="0003">
<claim-text>Vorrichtung nach Anspruch 1, die außerdem ein Abdeckungselement (13) umfasst, welches über dem oberen Ende des röhrenförmigen Körpers (7) und dem Schließelement (11) des röhrenförmigen Körpers angebracht ist, wobei das Abdeckungselement (13) wie eine Haube mit einem Durchmesser größer als der Durchmesser des Schließelementes (11) des röhrenförmigen Körpers geformt ist, um die zentrale Öffnung vor möglichen Verstopfungen zu schützen.</claim-text></claim>
<claim id="c-de-01-0004" num="0004">
<claim-text>Vorrichtung nach Anspruch 1, wobei das flüssige Produkt ein festes suspendiertes Material enthält.</claim-text></claim>
<claim id="c-de-01-0005" num="0005">
<claim-text>Ein Verfahren zur konstanten Emission von flüchtigen Flüssigkeiten, bei dem eine Vorrichtung nach Anspruch 1 genutzt wird, worin die Absorption der in einem Tank enthaltenen flüchtigen Flüssigkeiten über die absorbierende Masse in den genannten Tank geleitet wird, von wo aus sie aufgrund von Dampfdruckunterschieden und Luftzug ohne Eingriff des Gewichtes der Flüssigkeit in Form von Gas strömen.</claim-text></claim>
</claims><!-- EPO <DP n="11"> -->
<claims id="claims03" lang="fr">
<claim id="c-fr-01-0001" num="0001">
<claim-text>Un dispositif pour l'émission constante de liquides volatiles comprenant :
<claim-text>- un réservoir (1) équipé d'un fond et contenant un produit liquide volatile à disperser;</claim-text>
<claim-text>- une masse (9) absorbante servant à absorber le produit à disperser;</claim-text>
<claim-text>- un corps (7) tubulaire à multiples perforations (8) situées autour et le long de sa surface, une extrémité supérieure, une extrémité inférieure et un volume intérieur, le corps(7) tubulaire étant disposé dans une position verticale pour que l'extrémité inférieure du corps(7) tubulaire repose sur le fond du réservoir (1), et que la masse (9) absorbante remplisse le volume intérieur du corps(7) tubulaire, en laissant l'extrémité supérieure du corps (7) tubulaire sans contact avec la masse (9) absorbante pour former une chambre (10) ; la masse (9) absorbante est en contact avec le produit liquide contenu dans le réservoir (1) à travers les multiples perforations (8) du corps(7) tubulaire;</claim-text>
<claim-text>- un couvercle (4) de fermeture du réservoir pourvu d'une perforation (5) centrale d'un diamètre permettant au corps(7) tubulaire de la traverser; et</claim-text>
<claim-text>- un élément de fermeture (11) du corps tubulaire pourvu d'une ouverture (12) centrale, l'élément de fermeture (11) du corps tubulaire étant fortement serré sur l'extrémité supérieure du corps (7) tubulaire de sorte que le produit à disperser puisse s'écouler, sous forme de gaz, à travers l'ouverture (12) centrale et se disperser.</claim-text></claim-text></claim>
<claim id="c-fr-01-0002" num="0002">
<claim-text>Dispositif selon la revendication 1, <b>caractérisé en ce que</b> la chambre (10) hors contact avec la masse (9) absorbante à l'extrémité supérieure du corps (7) tubulaire - dépasse au-dessus dudit couvercle (4) de fermeture du<!-- EPO <DP n="12"> --> réservoir, de façon à ce que l'air puisse pénétrer dans ladite chambre (10) à travers de multiples perforations (8) à l'extrémité supérieure du corps(7) tubulaire afin que le produit s'écoulant sous forme de gaz depuis la masse (9) absorbante jusqu'à la chambre (10) passe à travers l'ouverture centrale et s'échappe du dispositif.</claim-text></claim>
<claim id="c-fr-01-0003" num="0003">
<claim-text>Dispositif selon la revendication 1, comprenant en outre un élément de couverture (13) placé sur l'extrémité supérieure du corps(7) tubulaire et sur l'élément de fermeture (11) du corps tubulaire, l'élément de couverture (13) étant conçu comme un chapeau de diamètre supérieur à celui de l'élément de fermeture (11) du corps tubulaire en vue de protéger l'ouverture centrale contre des possibles obstructions.</claim-text></claim>
<claim id="c-fr-01-0004" num="0004">
<claim-text>Dispositif selon la revendication 1, <b>caractérisé en ce que</b> le produit liquide est composé d'un matériau solide en suspension.</claim-text></claim>
<claim id="c-fr-01-0005" num="0005">
<claim-text>Une méthode pour l'émission constante de liquides volatiles réalisée à partir de l'utilisation d'un dispositif selon la revendication 1, <b>caractérisée en ce que</b> l'absorption de liquides volatiles contenus dans un réservoir s'effectue par le biais de la masse absorbante contenue dans ledit réservoir, duquel ils s'écoulent sous forme de gaz du fait des différences de pression de vapeur et du charriage par l'air sans que le poids du liquide intervienne.</claim-text></claim>
</claims><!-- EPO <DP n="13"> -->
<drawings id="draw" lang="en">
<figure id="f0001" num=""><img id="if0001" file="imgf0001.tif" wi="167" he="244" img-content="drawing" img-format="tif"/></figure><!-- EPO <DP n="14"> -->
<figure id="f0002" num=""><img id="if0002" file="imgf0002.tif" wi="148" he="183" img-content="drawing" img-format="tif"/></figure>
</drawings>
</ep-patent-document>
