| (19) |
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(11) |
EP 0 860 252 B1 |
| (12) |
EUROPEAN PATENT SPECIFICATION |
| (45) |
Mention of the grant of the patent: |
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13.11.2002 Bulletin 2002/46 |
| (22) |
Date of filing: 11.02.1998 |
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| (54) |
A method for supplying a fluid
Verfahren zur Abgabe einer Flüssigkeit
Procédé pour delivrer un fluide
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| (84) |
Designated Contracting States: |
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AT BE CH DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE |
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Designated Extension States: |
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AL LT LV RO SI |
| (30) |
Priority: |
21.02.1997 EP 97850029
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| (43) |
Date of publication of application: |
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26.08.1998 Bulletin 1998/35 |
| (73) |
Proprietors: |
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- AKZO NOBEL N.V.
6800 SB Arnhem (NL)
- Casco Products AB
100 61 Stockholm (SE) Designated Contracting States: FI SE
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| (72) |
Inventors: |
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- Vesterlund, Lennart
129 36 Hägersten (SE)
- Andersson, Sven-Erik
131-34 Nacka (SE)
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| (74) |
Representative: Jönsson, Christer et al |
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Eka Chemicals AB,
Patent Department,
Box 11556 100 61 Stockholm 100 61 Stockholm (SE) |
| (56) |
References cited: :
EP-A- 0 131 883 DE-A- 3 937 862
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WO-A-88/00498
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- PATENT ABSTRACTS OF JAPAN vol. 002, no. 043 (C-008), 23 March 1978 & JP 52 151325
A (DENKI KAGAKU KOGYO KK;OTHERS: 01), 15 December 1977,
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| |
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| Note: Within nine months from the publication of the mention of the grant of the European
patent, any person may give notice to the European Patent Office of opposition to
the European patent
granted. Notice of opposition shall be filed in a written reasoned statement. It shall
not be deemed to
have been filed until the opposition fee has been paid. (Art. 99(1) European Patent
Convention).
|
[0001] The present invention relates to a device for supplying a multicomponent fluid thermosetting
resin gluing system. Furthermore, it also relates to use of the device particularly
for production of laminated wood or glue laminated timber.
[0002] Production of laminated wood and glue-laminated timber usually involves agglutination
of (i.e. gluing together) two or more wooden members surfaces by means of a multicomponent
thermosetting resin gluing system, such as gluing systems based on urea-formaldehyde
resins, melamine-formaldehyde resins, phenol-formaldehyde resins, phenol-resorcinol-formaldehyde
resins, isocyanate resins, polyurethane resins, polyvinyl acetate resins, etc. Such
gluing systems are based on at least two components, a resin component and a hardener
component A device used for such a system is known for example from WO 88/00 498.
In the exemplified gluing systems the hardener component is based on formaldehyde,
organic isocyanates, or acids like formic acid, i.e. substances known to evaporate
into gaseous emissions giving rise to unpleasant odours or even respiratory irritation.
This emission problem is particularly evident when the gluing system or its components
are applied by means of some curtain coating technique, at which the evaporating substance
falls freely through the ambient air down to one of the surfaces to be agglutinated.
The problem is particularly outspoken when the evaporating component is applied separate
from the other components, as in that case neither the evaporating component nor the
emitted vapours may react with any other gluing system component. On the other hand,
if the hardener is mixed with the resin component prior to application, the pot life
of the gluing system as applied is considerably reduced. Such pre-mixing usually also
entails palpable problems regarding cleaning the application equipment, as cured resin
may clog the nozzles of the apparatus. This latter problem may of course also reside
with resin-hardener system that does not involve any component causing emission problems.
[0003] Various solutions have been proposed to the above problems. In the case of pre-mixing,
cooling of the mixture has been utilised in order to decrease the reaction rate as
well as the vapour pressure of the evaporating substance. This is apparently a technologically
complicated solution. In other cases the proposed solutions relate to lowering the
content of the evaporating component in the gluing system, or providing additives
that may absorb any excess of the evaporating component. Drawbacks of these solutions
are that they imply that part of the evaporating component is withdrawn from the intended
glue-curing reaction, which in turn means longer curing times or inferior adhesion
properties of the cured resin, or both.
[0004] The above problems are overcome by the present invention as defined by appended claim
1. More specifically the present invention relates to a device for supplying a multicomponent
fluid thermosetting resin gluing system, which comprises a first hollow body provided
with outlet conduits, a second hollow body having at least as many outlet apertures
as there are outlet conduits of the first hollow body, whereby each conduit is introduced
into one aperture, there being an interspace between the conduit and the edges of
the aperture.
[0005] One embodiment (not shown in the drawings) of the present device furthermore comprises
an intermediate hollow body having at least one outlet conduit, whereby substantially
all of the conduits of the first hollow body are introduced into one of the conduits
in the intermediate hollow body and each conduit of the intermediate hollow body is
introduced in the same aperture in the second hollow body as the first hollow body
conduit is introduced into itself, and there being an interspace between the conduits
of the intermediate and the first hollow body and an interspace between the conduit
of the intermediate hollow body and the edges of said aperture. The device may be
equipped with additional intermediate hollow bodies arranged in a way corresponding
to said intermediate body, the upper number being limited by requirement/demand and
economy only.
[0006] The first hollow body is preferably provided with an inlet duct, and the outlet conduit
has suitably an outlet nozzle. The second hollow body is preferably provided with
an inlet duct and comprises suitably a shell having interior and exterior surfaces
enveloping the first hollow body. Said nozzle is preferably flushed with the interior
or the exterior surface of the second hollow body shell or extends beyond said exterior
surface, each conduit being introduced into different apertures. The intermediate
hollow body, if any, is preferably provided with an inlet duct and the outlet conduit
has suitably an outlet nozzle. The intermediate hollow body may envelope the first
hollow body and may itself be enveloped by the second hollow body.
[0007] The shape of the first hollow body, the intermediate hollow body, and the second
hollow body is preferably substantially tubular.
[0008] In a preferred embodiment at least one of the apertures in the second hollow body
shell is fitted with an externally protruding outlet conduit having an outlet nozzle.
The length of substantially all of the conduits of the second hollow body measured
from the nozzle thereof to the exterior side of the shell of the second hollow body
is preferably less than about 50%, in particular less than 20%, of the overall cross-sectional
dimension of the second hollow body.
[0009] In one embodiment of the present device substantially all of the nozzles of the conduits
of the first and any intermediate bodies introduced into the same aperture are flushed
with the nozzle of the second hollow body conduit fitted to that same aperture. This
embodiment is advantageous in that it provides good mechanical stability: all nozzles
are flushed with each other, the conduits of the inner and intermediate bodies being
protected from externally inflicted strains and impacts.
[0010] According to another embodiment at least one of the conduits of the first and any
intermediate bodies introduced into the same aperture extends beyond the nozzle of
the second hollow body conduit fitted to that same aperture. This embodiment is advantageous
in that it provides an improved possibility to diminish of prevent clogging of the
interspaces between the conduits when the device is used for supplying a resin-hardener
system if the resin is supplied from the second hollow body and the hardener through
the extending conduit, or vice versa. If clogging appears it will be at the nozzle
of the extending conduit, not in said interspaces; such clogging is clearly much easier
to attend to than clogging in the interspaces. The surface of the extending conduit
may also treated in such away that is not wetted by the second fluid component (i.e.
the component exiting the nozzle of the second hollow body conduit); said surface
may thus be made hydrophobic, e.g. by means of some hydrophobic coating, when the
second fluid component is aqueous. In this way the risk of clogging at the nozzle
of the extending conduit will also be diminished.
[0011] According to a further embodiment at least one conduit of the first hollow body or
of an intermediate hollow body, if any, extend beyond the exterior surface of the
second hollow body shell, whereby the conduit of the first hollow body or the intermediate
hollow body comprises openings substantially transverse to the longitudinal axis of
the conduits, positioned in the part of the conduit extending between the second hollow
body conduit nozzle and the interior surface of the second hollow body shell. This
embodiment is advantageous in those cases when some premixing is necessary, as the
absence of the same would lead to unacceptable long curing times, e.g. when applying
emulsion polymer isocyanate (EPI) or polyvinyl acetate (PVAc) gluing systems. In this
embodiment the transverse openings cause or contribute to some turbulence in the co-flowing
resin and hardener streams.
[0012] The present invention also relates to the use of a device according to the present
invention for supplying a multicomponent fluid thermosetting gluing system.
[0013] In particular, the use of the device involves a first fluid component being brought
to flow in a first stream, and a second fluid component being brought to flow in a
second stream, whereby the flow of the second stream is brought to essentially encircle
the flow of the first stream.
[0014] In the present context the term "stream" refers to a stream as well as to a jet or
a ray. The flow of each or both of the component streams may be pumped or propelled
by gravitational forces, or a combination thereof. The term "encircle" means that
the second stream encircles, encompasses, or circumvents, the first stream, or in
other words that the second stream flows in a circumjacent relation to the first stream.
[0015] If one of the ingredients of the multicomponent fluid thermosetting resin gluing
system causes nauseous or noxious gas emissions this ingredient is suitably comprised
in the first fluid component. By encircling the first fluid component with a second
fluid component the vapours emitted from the first fluid component is then shielded
from the ambient air. In this way it is also possible to use resin-hardener systems
with high proportions of hardener.
[0016] Although the stream of the first fluid component may be discontinuous or comprise
regular or irregular dripping, whereby the portions or droplets are essentially completely
encircled by the second fluid component, the stream is preferably continuous, i.e.
unbroken, whereby said first stream is encircled by the second stream in the direction
transverse to the flow direction of both streams.
[0017] The present use of the device is particularly suited for supplying thermosetting
resin gluing systems chosen from a group comprising urea-formaldehyde resin gluing
systems, melamine-formaldehyde resin gluing systems, melamine-urea-formaldehyde resin
gluing systems, phenol resin gluing systems, phenol-formaldehyde resin gluing systems,
resorcinol-phenol-formaldehyde resin gluing systems, polyurethane resin gluing systems,
polyvinyl acetate gluing systems, emulsion and dispersion isocyanate resin gluing
systems, and various combinations of two or more of these gluing systems.
[0018] The hardener components of these gluing systems are preferably used as the first
fluid component.
[0019] In the present context the term "hardener" refers both to catalytic hardeners and
reactive curing agents.
[0020] As the resin component is not brought in contact with the hardener component until
the components exit the supply device, the pot life is prolonged, compared with prior
art in which the components are premixed in or prior to entering the supply device.
Consequently the clogging problem is also strongly diminished or even removed.
[0021] In a particularly preferred embodiment the present method is applied in a process
for production of laminated wood or glue-laminated timber by agglutinating surfaces
of two or more wooden members. In this process a multicomponent gluing system is prepared
by mixing a hardener component and a resin component, whereupon the freshly prepared
gluing system is applied on at least one of the surfaces to be agglutinated, whereby
the hardener component is brought to flow in a first stream from an application device
to said surface and the resin component is brought to flow in a second stream, whereby
the second stream is brought to essentially encircle the first stream in the direction
transverse to the direction of flow of the first as well as of the second stream.
[0022] In one embodiment of the use of the device according to the present invention at
least one of the apertures in the second hollow body shell is fitted with an externally
protruding outlet conduit having an outlet nozzle, the length of substantially all
conduits of the second hollow body measured from the nozzle thereof to the exterior
side of the shell of the second hollow body being less than about 50% of the overall
cross-sectional dimension of the second hollow body, and at least one of the conduits
introduced into the same aperture extending beyond the nozzle of the conduit fitted
to that same aperture, for supplying a multicomponent fluid thermosetting resin gluing
system by means of a method in which a first fluid component is brought to flow in
a first stream, and a second fluid component is brought to flow in a second stream,
wherein the second stream is brought to essentially encircle the first stream.
[0023] The present invention is illustrated in more detail below by means of examples and
with reference to the appended drawing, in which Fig 1 shows an embodiment of the
device according to the invention which comprises a first hollow body 10 provided
with three outlet conduits 20, 21, 22, a second hollow body 30 having as many outlet
apertures 40, 41, 42 as there are outlet conduits of the first hollow body. Each conduit
is introduced into one aperture, there being an interspaces 50, 51, 52 between the
conduit and the edges 60, 61, 62 of the apertures. The first hollow body 10 is provided
with an inlet duct 70 and the outlet conduits 20, 21 have outlet nozzles 80, 81. The
second hollow body 30 is provided with an inlet duct 90 and comprises a shell 100
having one interior 110 and one exterior 120 surface, and envelopes the first hollow
body. Nozzles 80, 81 extend beyond said exterior surface 120, and each conduit 20,
21, 22 is introduced into different apertures 40, 41, 42. The first hollow body as
well as the second hollow body both have tubular form. All the apertures in the second
hollow body shell is fitted with externally protruding outlet conduits 130, 131, 132
having outlet nozzles 140, 141, 142. Nozzle 80 of conduit 20 is flushed with nozzle
140 of conduit 130, which is fitted to aperture 40, i.e. the same aperture into which
conduit 20 is introduced. Nozzle 81 of conduit 21 extends beyond nozzle 141 of conduit
131, which is fitted to aperture 41, i.e. the same aperture into which conduit 21
is introduced. Conduit 22 comprises openings 150 which are substantially transverse
to the longitudinal axis of conduits 22 and 130, which openings are positioned in
the part of conduit 22 extending between the nozzle 142 and the shell interior surface
110.
[0024] Comparative Example 1: A resorcinol-phenol-formaldehyde gluing system was prepared according to conventional
technology by stirring 100 parts by weight of a resorcinol-phenol mixture and 20 parts
by weight of an aqueous formaldehyde solution containing 40 percent by weight of formaldehyde.
After said stirring the glue was applied to a surface in an amount of 400g/m
2. The formaldehyde concentration above said surface was analysed by sucking air through
a filter impregnated with dinitrophenylhydrazine, leaching the filter with acetonitrile,
and then analysing the extract, by means of HPLC, with regard to the content of HCHO.
The volume of analysed air was 28.42 litres, which passed the filter with a flow of
0.98 litres/minute. The results of the analysis are set forth in the Table below.
[0025] Comparative Example 2: A resorcinol-phenol-formaldehyde gluing system was prepared in the same manner and
according to the same recipe as in Comparative Example 1. The glue was applied to
a surface in an amount of 400g/m
2. The formaldehyde concentration above said surface was analysed by sucking air through
a filter impregnated with dinitrophenylhydrazine, leaching the filter with acetonitrile,
and then analysing the extract, by means of HPLC, with regard to the content of HCHO.
The volume of analysed air was 14.79 litres, which passed the filter with a flow of
0.51 litres/minute. The results of the analysis are set forth in the Table below.
[0026] Example 1: A resorcinol-phenol-formaldehyde gluing system was prepared using a device according
to the present invention equipped with conduits having flushed nozzles (corresponding
to nozzles 80 and 140 of conduits 20 and 130, respectively, in Fig 1) and using the
same component recipe as in Comparative Example 1. The glue was applied to a surface
in an amount of 400g/m
2. The formaldehyde concentration above said surface was analysed by sucking air through
a filter impregnated with dinitrophenylhydrazine, leaching the filter with acetonitrile,
and then analysing the extract, by means of HPLC, with regard to the content of HCHO.
The volume of analysed air was 28.42 litres, which passed the filter with a flow of
0.98 litres/minute. The results of the analysis are set forth in the Table below.
[0027] Example 2: A resorcinol-phenol-formaldehyde gluing system was prepared in the same way, using
the same kind of equipment and the same amounts of components as in Example 1. The
glue was applied to a surface in an amount of 400g/m
2. The formaldehyde concentration above said surface was analysed by sucking air through
a filter impregnated with dinitrophenylhydrazine, leaching the filter with acetonitrile,
and then analysing the extract, by means of HPLC, with regard to the content of HCHO.
The volume of analysed air was 14.79 litres, which passed the filter with a flow of
0.51 litres/minute. The results of the analysis are set forth in the Table below.
| Example |
Amount of HCHO in air sample, µg |
Concentration of HCHO in air sample, mg/m3 |
| Comparative Example 1 |
255.53 |
9.0 |
| Example 1 |
69.96 |
2.5 |
| Comparative Example 2 |
183.08 |
12.4 |
| Example 2 |
74.23 |
5.0 |
[0028] As evident from the results presented in the above Table, the present invention has
a most pronounced effect on the formaldehyde emissions.
1. A device for supplying a multicomponent fluid thermosetting resin gluing system comprising
a first hollow body (10) provided with outlet conduits (20,21,22); and a second hollow
body (30), characterised in that the second hollow body has at least as many outlet apertures (40,41,42) as there
are outlet conduits of the first hollow body; whereby each conduit is introduced into
one aperture, there being an interspace (50,51,52) between the conduit and the edges
(60,61,62) of the aperture.
2. A device according to claim 1, characterised in that the first hollow body (10) is provided with an inlet duct (70); the outlet conduit
(20,21,) has an outlet nozzle (80,81); the second hollow body (30) is provided with
an inlet duct (90), comprises a shell (100) having one interior (110) and one exterior
(120) surface, and envelopes the first hollow body; whereby the nozzle is flushed
with the interior or the exterior surface of the second hollow body shell or extends
beyond said exterior surface, each conduit being introduced into different apertures.
3. A device according to any of claims 1-2, characterised in that the first hollow body (10) and/or the second hollow body (30) have/has tubular form.
4. A device according to any of claims 1-3, characterised in that at least one of the apertures (40,41,42) in the second hollow body shell is fitted
with an externally protruding outlet conduit (130,131,132) having an outlet nozzle
(140,141,142).
5. A device according to claim 4, characterised in that the length of substantially all of the conduits (130,131,132) of the second hollow
body (30) measured from the nozzle thereof to the exterior side of the shell of the
second hollow body is less than about 50% of the overall cross-sectional dimension
of the second hollow body.
6. A device according to any of claims 2-5, characterised in that substantially all of the nozzles (80,81) of the conduits (20,21) introduced into
the same aperture (40,41) are flushed with the nozzle (141,142) of the conduit (130,131)
fitted to that same aperture.
7. A device according to any of claims 4-6, characterised in that at least one of the conduits (21) introduced into the same aperture (41) extends
beyond the nozzle (141) of the conduit (131) fitted to that same aperture.
8. A device according to any of claims 4-7, characterised in that at least one conduit of the first hollow body (10) extends beyond the exterior surface
of the second hollow body shell, whereby the conduit (22) of the first hollow body
comprises openings (150) substantially transverse to the longitudinal axis of the
conduits, positioned in the part of the conduit extending between the second hollow
body conduit nozzle (142) and the interior surface of the second hollow body shell.
9. Use of the device according to any of claims 1-8 for supplying a multicomponent fluid
thermosetting resin gluing system.
10. Use according to claim 9, characterised in that a first fluid component that emits vapours is brought to flow in a first stream,
and a second fluid component is brought to flow in a second stream, wherein the second
stream is brought to essentially encircle the first stream such that the vapours emitted
from the first component are shielded from the ambient air by the second stream.
11. Use according to claim 10, characterised in that the second stream is brought to essentially encircle the first stream in the direction
transverse to the flow direction.
12. Use according to any of claims 10-11, characterised in that the first fluid component comprises a hardener.
13. Use according to any of claims 9-12, characterised in that the multicomponent fluid thermosetting resin gluing system is a urea-formaldehyde
resin gluing system, a melamine-formaldehyde resin gluing system, a melamine-urea-formaldehyde
resin gluing system, a phenol resin gluing system, a phenol-formaldehyde resin gluing
system, a resorcinol-phenol-formaldehyde resin gluing system, a polyurethane resin
gluing system, a polyvinyl acetate gluing system, an emulsion or dispersion isocyanate
resin gluing system, or a combination of two or more of these gluing systems.
14. Use according to any of claims 9-13, characterised in that the multicomponent fluid thermosetting resin gluing system is a emulsion polyisocyanate
resin gluing system.
15. Use according to any of claims 9-14, characterised in that the gluing system is further supplied onto at least one surface of a wooden member
which is agglutinated with one or more other wooden members forming laminated wood,
or glue-laminated timber, in which the gluing system is prepared by mixing a hardener
component and a resin component
1. Vorrichtung zum Liefern eines flüssigen wärmehärtenden Mehrkomponenten-Kunstharz-Leimsystems,
das aufweist: einen ersten Hohlkörper (10), der mit Auslaßrohrkanälen (20, 21, 22)
versehen ist, und einen zweiten Hohlkörper, dadurch gekennzeichnet, daß der zweite Hohlkörper (30) mindestens so viele Auslaßöffnungen (40, 41, 42) hat,
wie es Auslaßrohrkanäle des ersten Hohlkörpers gibt, wobei jeder Rohrkanal in eine
Öffnung eingeführt ist, wobei es einen Zwischenraum (50, 51, 52) zwischen dem Rohrkanal
und den Rändern (60, 61, 62) der Öffnung gibt.
2. Vorrichtung nach Anspruch 1, dadurch gekennzeichnet, daß der erste Hohlkörper (10) mit einer Einlaßrohrleitung (70) versehen ist, der Auslaßrohrkanal
(20, 21) eine.Auslaßdüse (80, 81) hat, der zweite Hohlkörper (30) mit einer Einlaßrohrleitung-
(90) ausgestattet ist und eine Schale (100) aufweist, die eine innere (110) und eine
äußere (120) Oberfläche hat und den ersten Hohlkörper umhüllt, wobei die Düse mit
der inneren oder der äußeren Oberfläche der zweiten Hohlkörperschale bündig ist oder
sich über die äußere Oberfläche hinaus erstreckt, wobei jeder Rohrkanal in verschiedene
Öffnungen eingeführt ist.
3. Vorrichtung nach einem der Ansprüche 1 bis 2, dadurch gekennzeichnet, daß der erste Hohlkörper (10) und/oder der zweite Hohlkörper (30) eine rohrförmige Form
haben.
4. Vorrichtung nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß in mindestens eine der Öffnungen (40, 41, 42) in der zweiten Hohlkörperschale ein
nach außen vorstehender Auslaßrohrkanal (130, 131, 132) eingepaßt ist, der eine Auslaßdüse
(140, 141, 142) hat.
5. Vorrichtung nach Anspruch 4, dadurch gekennzeichnet, daß die Länge im wesentlichen aller Rohrkanäle (130, 131, 132) des zweiten Hohlkörpers
(30) von deren Düse bis zur Außenseite der Schale des zweiten Hohlkörpers gemessen
weniger als etwa 50% der gesamten Querschnittabmessung des zweiten Hohlkörpers ist.
6. Vorrichtung nach einem der Ansprüche 2 bis 5, dadurch gekennzeichnet, daß im wesentlichen alle Düsen (80, 81) der in die gleiche Öffnung (40, 41) eingeführten
Rohrkanäle (20, 21) mit der Düse (141, 142) des Rohrkanals (130, 131) bündig sind,
welcher in diese gleiche Öffnung eingepaßt ist.
7. Vorrichtung nach einem der Ansprüche 4 bis 6, dadurch gekennzeichnet, daß mindestens einer der in die gleiche Öffnung (41) eingeführten Rohrkanäle (21) sich
über die Düse (141) des in die gleiche Öffnung eingepaßten Rohr--Kanals (131) hinaus
erstreckt.
8. Vorrichtung nach einem der Ansprüche 4 bis 7, dadurch gekennzeichnet, daß mindestens ein Rohrkanal des ersten Hohlkörpers (10) sich über die äußere Oberfläche
der zweiten Hohlkörperschale hinaus erstreckt, wobei der Rohrkanal (22) des ersten
Hohlkörpers Öffnungen (150) aufweist, die im wesentlichen quer zur Längsachse der
Rohrkanäle sind und die in dem Teil des Rohrkanals positioniert sind, der sich zwischen
der zweiten Hohlkörper-Rohrkanaldüse (142) und der inneren Oberfläche der zweiten
Hohlkörperschale erstreckt.
9. Verwendung der Vorrichtung nach einem der Ansprüche 1 bis 8 zum Liefern eines wärmehärtenden
flüssigen Mehrkomponenten-Kunstharz-Leimsystems.
10. Verwendung nach Anspruch 9, dadurch gekennzeichnet, daß eine erste flüssige Komponente, die Dämpfe emittiert, dazu gebracht wird, in einem
ersten Strom zu fließen, und eine zweite flüssige Komponente dazu gebracht wird, in
einem zweiten Strom zu fließen, wobei der zweite Strom dazu gebracht wird, den ersten
Strom derart zu umschließen, daß die von der ersten Komponente emittierten Dämpfe
durch den zweiten Strom von der Umgebungsluft abgeschirmt werden.
11. Verwendung nach Anspruch 10, dadurch gekennzeichnet, daß der zweite Strom dazu gebracht wird, den ersten Strom im wesentlichen in der Richtung
quer zu der Flußrichtung zu umschließen.
12. Verwendung nach einem der Ansprüche 10 bis 11, dadurch gekennzeichnet, daß die erste flüssige Komponente einen Härter aufweist.
13. Verwendung nach einem der Ansprüche 9 bis 12, dadurch gekennzeichnet, daß das wärmehärtende flüssige Mehrkomponenten-Kunstharz-Leimsystem ein Harnstoff-Formaldehydharz-Leimsystem,
ein Melaminharz-Leimsystem, ein Melamin-Harnstoff-Formaldehydharz-Leimsystem, ein
Phenolharz-Leimsystem, ein Phenolformaldehydharz-Leimsystem, ein Resorcinol-Phenol-Formaldehydharz-Leimsystem,
ein Polyurethanharz-Leimsystem, ein Polyvinylazetat-Leimsystem, ein Isocyanatharz-Emulsions-
oder Dispersions-Leimsystem oder eine Kombination aus zwei oder mehr dieser Leimsysteme
ist.
14. Verwendung nach einem der Ansprüche 9 bis 13, dadurch gekennzeichnet, daß das wärmehärtende flüssige Mehrkomponenten-Kunstharz-Leimsystem ein Polyisocyanatharz-Emulsionsleimsystem
ist.
15. Verwendung nach einem der Ansprüche 9 bis 14, dadurch gekennzeichnet, daß das Leimsystem ferner auf mindestens eine Oberfläche eines hölzernen Elements aufgebracht
wird, das mit einem oder mehreren anderen hölzernen Elementen, die ein Schichtholz
oder schichtverleimtes Bauholz bilden, verkittet wird, wobei das Leimsystem hergestellt
wird, indem eine Härterkomponente und einer Harzkomponente gemischt werden.
1. Dispositif pour délivrer un système adhésif fluide multicomposant à base de résine
thermodurcissable comprenant un premier corps creux (10) muni de conduits de sortie
(20, 21, 22), et un deuxième corps creux (30), caractérisé en ce que le deuxième corps creux comporte au moins autant d'ouvertures de sortie (40, 41,
42) qu'il y a de conduits de sortie dans le premier corps creux, grâce à quoi chaque
conduit est introduit dans une ouverture, un interstice (50, 51, 52) existant entre
le conduit et les bords (60, 61, 62) de l'ouverture.
2. Dispositif selon la revendication 1, caractérisé en ce que le premier corps creux (10) est muni d'une conduite d'entrée (70), le conduit de
sortie (20, 21) comporte un ajutage de sortie (80, 81), le deuxième corps creux (30)
est muni d'une conduite d'entrée (90), comprend une coque (100) ayant une surface
intérieure (110) et une surface extérieure (120), et enveloppe le premier corps creux,
grâce à quoi l'ajutage est à niveau avec la surface intérieure ou extérieure de la
coque du deuxième corps creux ou bien s'étend au-delà de ladite surface extérieure,
chaque conduit étant introduit dans des ouvertures différentes.
3. Dispositif selon l'une quelconque des revendications 1 à 2, caractérisé en ce que le premier corps creux (10) et/ou le deuxième corps creux (30) est/sont de forme
tubulaire.
4. Dispositif selon l'une quelconque des revendications 1 à 3, caractérisé en ce que au moins l'une des ouvertures (40, 41, 42) de la coque du deuxième corps creux est
munie d' un conduit de sortie faisant saillie à l'extérieur (130, 131, 132) ayant
un ajutage de sortie (140, 141, 142).
5. Dispositif selon la revendication 4, caractérisé en ce que la longueur de sensiblement tous les conduits (130, 131, 132) du deuxième corps creux
(30) mesurée de leur ajutage à la face extérieure de la coque du deuxième corps creux
est inférieure à environ 50 % de la dimension transversale totale du deuxième corps
creux.
6. Dispositif selon l'une quelconque des revendications 2 à 5, caractérisé en ce que sensiblement tous les ajutages (80, 81) des conduits (20, 21) introduits dans la
même ouverture (40, 41) sont à niveau avec l'ajutage (141, 142) du conduit (130, 131)
placé sur cette même ouverture.
7. Dispositif selon l'une quelconque des revendications 4 à 6, caractérisé en ce qu'au moins l'un des conduits (21) introduits dans la même ouverture (41) s'étend au-delà
de l'ajutage (141) du conduit (131) placé sur cette même ouverture.
8. Dispositif selon l'une quelconque des revendications 4 à 7, caractérisé en ce qu'au moins un conduit du premier corps creux (10) s'étend au-delà de la surface extérieure
de la coque du deuxième corps creux, grâce à quoi le conduit (22) du premier corps
creux comprend des ouvertures (150) sensiblement transversales à l'axe longitudinal
des conduits, positionnées dans la partie du conduit s'étendant entre l'ajutage (142)
du deuxième corps creux et la surface intérieure de la coque du deuxième corps creux.
9. Utilisation du dispositif selon l'une quelconque des revendications 1 à 8 pour délivrer
un système adhésif fluide multicomposant à base de résine thermodurcissable.
10. Utilisation selon la revendication 9, caractérisée en ce que l'on fait s'écouler en un premier courant un premier composant fluide. qui émet des
vapeurs, et en ce que l'on fait s'écouler en un deuxième courant un deuxième composant fluide, le deuxième
courant étant amené à globalement encercler le premier courant de telle manière que
les vapeurs émises par le premier composant sont protégées de l'air ambiant par le
deuxième courant.
11. Utilisation selon la revendication 10, caractérisée en ce que le deuxième courant est amené à globalement encercler le premier courant dans la
direction transversale à la direction d'écoulement.
12. Utilisation selon l'une quelconque des revendications 10 à 11, caractérisée en ce que le premier composant fluide comprend un durcisseur.
13. Utilisation selon l'une quelconque des revendications 9 à 12, caractérisée en ce que le système adhésif fluide multicomposant à base de résine thermodurcissable est un
système adhésif à base de résine urée-formaldéhyde, un système adhésif à base de résine
mélamine-formaldéhyde, un système adhésif à base de résine mélamine-urée-formaldéhyde,
un système adhésif à base de résine phénolique, un système adhésif à base de résine
phénol-formaldéhyde, un système adhésif à base de résine résorcinol-phénol-formaldéhyde,
un système adhésif à base de résine polyuréthane, un système adhésif à base de poly(acétate
de vinyle), un système adhésif à base de résine isocyanate en émulsion ou en dispersion,
ou une combinaison de deux, ou plus, de ces systèmes adhésifs.
14. Utilisation selon l'une quelconque des revendications 9 à 13, caractérisée en ce que le système adhésif fluide multicomposant à base de résine thermodurcissable est un
système adhésif à base de résine polyisocyanate en émulsion.
15. Utilisation selon l'une quelconque des revendications 9 à 14, caractérisée en ce que le système adhésif est en outre délivré sur au moins une surface d'un élément en
bois qui est agglutiné avec un ou plusieurs autres éléments en bois formant du bois
stratifié, ou du bois de construction stratifié-collé, dans laquelle le système adhésif
est préparé en mélangeant un composant durcisseur et un composant résine.
