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(11) | EP 0 865 876 B1 |
| (12) | EUROPEAN PATENT SPECIFICATION |
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| (54) |
Abrading method Schleifverfahren Procédé d'abrasion |
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| Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention). |
BACKGROUND OF THE INVENTION
[0001] This invention relates to a method of abrading a workpiece in a corrosive environment, as per the preamble of claim 1. An example of such a method is disclosed in EP-A-583 916.
[0002] Abrasive compacts are well known in the art and are used extensively in industry for the abrading of various workpieces. They consist essentially of a mass of abrasive particles present in an amount of at least 70 percent, preferably 80 to 90 percent, by volume of the compact bonded into a hard polycrystalline conglomerate. The abrasive particles are either diamond or cubic boron nitride.
[0003] Abrasive compacts may be used on their own or bonded to a suitable substrate. The substrate will generally be a cemented carbide substrate.
[0004] Diamond abrasive compacts have been used in a wide variety of abrading operations. These compacts may be produced using a second phase or bonding matrix which often contains a solvent/catalyst suitable for synthesising diamond. One such compact is described in EP-A-0 198 653. This compact is characterised by a second phase or bonding matrix which contains chromium and a second metal selected from the group nickel, iron and cobalt. The chromium is present in the form of the metal, chromium carbide and/or in the form of an intermetallic compound with the second metal. The second metal is present in the form of the metal and/or the intermetallic compound referred to above. In particular, the compact is useful in dressing tools or surface set drill bits. The abrasive compact is used and is not supported by a cemented carbide substrate.
[0005] Diamond abrasive compacts have been used in the abrading, e.g. cutting, of wood products. The hardness and abrasion resistance of a diamond compact are properties which are very useful in this application. The wood or wood products may contain resins and a whole range of organic binders which remain on the diamond table and have to be cleaned with corrosive cleaning products that leach the cobalt binder before EDM re-sharpening can commence. The loss of cobalt binder leads to undercutting when the cutting edge is EDM sharpened. This in turn leads to chipping of the cutting edge.
[0006] EP-A-0 583 916 discloses a method of producing an abrasive product comprising the steps of providing a mixture of diamond and discrete carbide particles, the diamond particles being smaller than the carbide particles and present in the mixture in an amount of more than 50 percent by volume, and subjecting the mixture to diamond synthesis conditions in the presence of a binder metal such as cobalt, nickel or iron. The abrasive product thus produced has a substantial amount of direct diamond-to-diamond bonding and many of the characteristics of a diamond compact, but improved impact resistance due to the presence of the carbide particles. The abrasive product has particular application in the machining of wood products such as natural wood, chipboard, fibreboard and hardboard.
SUMMARY OF THE INVENTION
[0007] The present invention describes a method of abrading a workpiece in a corrosive environment as per claim 1.
[0008] The diamond abrasive compact which is used in the invention is one which is a polycrystalline mass of diamond having a second phase, the diamond content of the compact comprising at least 70 percent by volume of the compact. The second phase consists of chromium and nickel with any other components being in trace amounts only. It has been found that such diamond compacts have excellent corrosion resistance, particularly in environments in which there is present binder and/or corrosive cleaning chemicals. In the method of the invention, the cutting point or edge on the compact is advanced into workpiece with an abrading action. Abrading in the context of the specification means cutting, drilling, routing, polishing, or any similar such abrading action. This action may take various forms, known in the art, such as rotation of the cutting edge or point, reciprocating movement of the cutting edge or point or the like. Of course, the abrading action can also be achieved by maintaining the edge or point stationary and moving the workpiece.
[0009] The invention provides, according to another aspect, the use of a diamond abrasive compact as defined above in a method of abrading a workpiece in a corrosive environment.
DESCRIPTION OF EMBODIMENTS
[0010] The mass ratio of chromium to nickel metal will typically be 10:90 to 25:75. In the second phase, the chromium and nickel will both exist in the form of the metal, in the form of carbides and/or in the form of an intermetallic compound of the chromium and the nickel.
[0011] The diamond abrasive compact has been found to have excellect corrosion resistance in environments in which there is present binder and/or corrosive cleaning chemicals.
[0012] The diamond abrasive compact may be bonded to a cemented carbide substrate or to a metal layer base such as molybdenum, tantalum or tungsten.
[0013] Thus, the invention has been found to have particular application in the abrading of products which contain wood. Examples of wood products are natural wood, either soft or hard wood, laminated and non-laminated chipboard and fibreboard, which contain wood chips or fibre bonded by means of binders, hardboard which is compressed fibre and sawdust and plywood. The wood products may have plastic or other coating applied to them. Some of these wood products may contain resins and organic binders. It has been found that the presence of the corrosive cleaning chemicals and/or binder does not result in any significant undercutting of the cutting edge or point of a diamond abrasive compact as described above, leading to a much lower incidence of chipping. The abrading may take the form of sawing, milling or profile cutting. The tools which are used in such applications are generally multi-tip rotary tools such as circular saws, profile cutters, end mills, milling cutters and routers.
[0014] An example of a method of producing a diamond abrasive compact containing a nickel/chromium second phase will now be described. A mass of diamond particles (16,0g) was placed in a tantalum cup. A disc (2,6g) of a nickel/chromium alloy was placed on top of the mass of diamonds. Thus, the mass ratio of nickel/chromium was 80:20. The nickel/chromium constituted 14 percent by mass of the contents of the loaded tantalum cup.
[0015] The loaded cup was placed in the reaction zone of a conventional high temperature/high pressure apparatus and subjected to 1500°C temperature and 5,5GPa (55 kilobars) pressure and these conditions were maintained for a period of 10 minutes. Recovered from the reaction zone was a disc-shaped abrasive body which comprised a polycrystalline mass of diamond particles having a second phase containing chromium and nickel, as metals and in various combined forms, uniformly distributed through the diamond mass.
1. A method of abrading a workpiece in a corrosive environment including the steps of
providing a diamond abrasive compact having a cutting edge or point, the compact being
a polycrystalline mass of diamond having a second phase and the diamond content comprising
at least 70 percent by volume of the compact, providing a workpiece, bringing the
point or edge of the diamond abrasive compact into contact with the workpiece and
advancing the edge or point into the workpiece in an abrading manner, characterised in that said second phase consists of chromium and nickel with any other components being
in trace amounts only.
2. A method according to claim 1 wherein the mass ratio of chromium to nickel is in the
range 10:90 to 25:75.
3. A method according to any one of the preceding claims wherein the workpiece is a product
which contains wood.
4. A method according to claim 3 wherein the wood product is selected from natural wood,
laminated and non-laminated chipboard and fibreboard, hardboard and plywood.
5. A method according to claim 3 or claim 4 wherein the wood product has a plastic or
other coating applied to it.
6. A method according to any one of claims 3 to 5 wherein the wood product contains a
resin or organic binder.
7. A method according to any one of the preceding claims wherein the abrading is selected
from cutting, drilling, routing and polishing.
1. Verfahren zum Abschleifen eines Werkstücks in einer korrosiven Umgebung, umfassend
die folgenden Schritte: Bereitstellen eines Diamantschleifkompakts mit einer schneidenden
Kante oder einem schneidenden Punkt, wobei der Kompakt eine polykristalline Masse
aus Diamant mit einer zweiten Phase ist und der Diamantgehalt wenigstens 70 Volumenprozent
des Kompakts ausmacht, Bereitstellen eines Werkstücks, In-Kontakt-Bringen des Punkts
oder der Kante des Diamantschleifkompakts mit dem Werkstück und abschleifendes Vorschieben
der Kante oder des Punkts in das Werkstück, dadurch gekennzeichnet, dass die zweite Phase aus Chrom und Nickel besteht, wobei alle anderen Komponenten nur
in Spuren vorliegen.
2. Verfahren gemäß Anspruch 1, wobei das Massenverhältnis von Chrom zu Nickel im Bereich
von 10:90: bis 25:75 liegt.
3. Verfahren gemäß einem der vorstehenden Ansprüche, wobei das Werkstück ein Produkt
ist, das Holz enthält.
4. Verfahren gemäß Anspruch 3, wobei das Holzprodukt aus natürlichem Holz, laminierter
und nichtlaminierter Spanplatte und Faserplatte, Hartfaserplatte und Sperrholz ausgewählt
ist.
5. Verfahren gemäß Anspruch 3 oder 4, wobei auf das Holzprodukt eine Kunststoff- oder
andere Beschichtung aufgetragen ist.
6. Verfahren gemäß einem der Ansprüche 3 bis 5, wobei das Holzprodukt ein Harz oder organisches
Bindemittel enthält.
7. Verfahren gemäß einem der vorstehenden Ansprüche, wobei das Abschleifen aus Schneiden,
Bohren, Fräsen und Polieren ausgewählt ist.
1. Procédé d'abrasion d'une pièce de fabrication dans un environnement corrosif comprenant
les étapes consistant à fournir un comprimé abrasif de diamant présentant un bord
ou une extrémité de coupe, le comprimé étant une masse polycristalline de diamant
présentant une seconde phase et la teneur en diamant étant d'au moins 70 pour cent
par volume du comprimé, fournir une pièce de fabrication, mettre en contact l'extrémité
ou le bord du comprimé abrasif de diamant avec la pièce de fabrication et avancer
le bord ou l'extrémité dans la pièce de fabrication d'une manière abrasive, caractérisé en ce que ladite seconde phase comprend du chrome et du nickel avec n'importe quels autres
composants uniquement sous forme de traces.
2. Procédé selon la revendication 1, dans lequel le rapport de masse entre le chrome
et le nickel est de l'ordre de 10:90 à 25:75.
3. Procédé selon l'une quelconque des revendications précédentes, dans lequel la pièce
de fabrication est un produit qui contient du bois.
4. Procédé selon la revendication 3, dans lequel le produit du bois est sélectionné à
partir du bois naturel, de panneau de particules constitués de plusieurs épaisseurs
et non constitués de plusieurs épaisseurs et de panneau de fibres de bois, de panneau
de fibres dur et de contreplaqué.
5. Procédé selon la revendication 3 ou 4, dans lequel le produit du bois est recouvert
d'une matière plastique ou d'un autre revêtement.
6. Procédé selon la revendication 3 à 5, dans lequel le produit du bois contient une
résine ou un liant organique.
7. Procédé selon l'une quelconque des revendications précédentes, dans lequel l'abrasion
est sélectionnée parmi la coupe, le perçage, le détourage et le polissage.