(19) |
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(11) |
EP 0 866 084 A3 |
(12) |
EUROPEAN PATENT APPLICATION |
(88) |
Date of publication A3: |
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27.02.2002 Bulletin 2002/09 |
(43) |
Date of publication A2: |
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23.09.1998 Bulletin 1998/39 |
(22) |
Date of filing: 17.03.1998 |
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(84) |
Designated Contracting States: |
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AT BE CH DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE |
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Designated Extension States: |
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AL LT LV MK RO SI |
(30) |
Priority: |
21.03.1997 JP 6818597 21.03.1997 JP 6818697 18.04.1997 JP 10208297 18.04.1997 JP 10208397 18.04.1997 JP 10208497 24.04.1997 JP 10777097
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(71) |
Applicant: MITSUI CHEMICALS, INC. |
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Tokyo (JP) |
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(72) |
Inventors: |
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- Irizato, Yoshihiro
Yokohama-shi, Kanagawa (JP)
- Sukegawa, Makoto
Yokohama-shi, Kanagawa (JP)
- Katoh, Toshio
Kawaguchi-shi, Saitama (JP)
- Tamatani, Hiroaki
Yokohama-shi, Kanagawa (JP)
- Nagatomo, Akinori
Omuta-shi, Fukuoka (JP)
- Wada, Masaru
Omuta-shi, Fukuoka (JP)
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(74) |
Representative: Strehl Schübel-Hopf & Partner |
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Maximilianstrasse 54 80538 München 80538 München (DE) |
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(54) |
Production process of cross-linked polyaspartic acid resin |
(57) A process is disclosed for producing with good productivity a cross-linked polyaspartic
acid resin having biodegradability and high water absorbency. The process features
inclusion of one of the following steps: (a) a polysuccinimide, which has been brought
into a dispersed state by a dispersant, and a cross-linking agent are reacted to produce
the cross-linked polyaspartic acid resin; (b) imide rings of a cross-linked polysuccinimide
are subjected to a hydrolysis reaction while controlling a swelling degree of a resulting
gel, whereby the cross-linked polyaspartic acid resin is produced; and (c) a gel of
a cross-linked polysuccinimide, which has been obtained by reacting a cross-linking
agent to a solution of a polysuccinimide in an organic solvent, is disintegrated to
subject imide rings of the cross-linked polysuccinimide to a hydrolysis reaction,
so that the cross-linked polyaspartic acid resin is produced. The process may also
include one or both of the following steps as needed: (d) a gel of the cross-linked
polyaspartic acid resin is washed with water and/or a water-miscible organic solvent;
and (e) the polysuccinimide is produced using a basic amino acid as a cross-linking
agent.