(19)
(11) EP 0 866 084 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
27.02.2002 Bulletin 2002/09

(43) Date of publication A2:
23.09.1998 Bulletin 1998/39

(21) Application number: 98104815.0

(22) Date of filing: 17.03.1998
(51) International Patent Classification (IPC)7C08G 69/10, C08G 73/06, C08G 73/10
(84) Designated Contracting States:
AT BE CH DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE
Designated Extension States:
AL LT LV MK RO SI

(30) Priority: 21.03.1997 JP 6818597
21.03.1997 JP 6818697
18.04.1997 JP 10208297
18.04.1997 JP 10208397
18.04.1997 JP 10208497
24.04.1997 JP 10777097

(71) Applicant: MITSUI CHEMICALS, INC.
Tokyo (JP)

(72) Inventors:
  • Irizato, Yoshihiro
    Yokohama-shi, Kanagawa (JP)
  • Sukegawa, Makoto
    Yokohama-shi, Kanagawa (JP)
  • Katoh, Toshio
    Kawaguchi-shi, Saitama (JP)
  • Tamatani, Hiroaki
    Yokohama-shi, Kanagawa (JP)
  • Nagatomo, Akinori
    Omuta-shi, Fukuoka (JP)
  • Wada, Masaru
    Omuta-shi, Fukuoka (JP)

(74) Representative: Strehl Schübel-Hopf & Partner 
Maximilianstrasse 54
80538 München
80538 München (DE)

   


(54) Production process of cross-linked polyaspartic acid resin


(57) A process is disclosed for producing with good productivity a cross-linked polyaspartic acid resin having biodegradability and high water absorbency. The process features inclusion of one of the following steps: (a) a polysuccinimide, which has been brought into a dispersed state by a dispersant, and a cross-linking agent are reacted to produce the cross-linked polyaspartic acid resin; (b) imide rings of a cross-linked polysuccinimide are subjected to a hydrolysis reaction while controlling a swelling degree of a resulting gel, whereby the cross-linked polyaspartic acid resin is produced; and (c) a gel of a cross-linked polysuccinimide, which has been obtained by reacting a cross-linking agent to a solution of a polysuccinimide in an organic solvent, is disintegrated to subject imide rings of the cross-linked polysuccinimide to a hydrolysis reaction, so that the cross-linked polyaspartic acid resin is produced. The process may also include one or both of the following steps as needed: (d) a gel of the cross-linked polyaspartic acid resin is washed with water and/or a water-miscible organic solvent; and (e) the polysuccinimide is produced using a basic amino acid as a cross-linking agent.





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