..BECHDE....FRGB..ITLI..NL......................................................JDIM360 Ver 2.15 (14 Jul 2008) - 2999001/0The file contains technical information submitted after the application was filed and not included in this specification0895992CORRECTED EUROPEAN PATENT SPECIFICATIONB8B120090902W154deBibliographieenBibliographyfrBibliographieEP98114643.4199808041999072020040908enenen2104179719970805JP2009090220093619990210199906200906102009242008103120090902200936C07D 263/12 20060101AFI19981215BHEP C07C 237/06 20060101ALI19981215BHEP C07C 69/747 20060101ALI19981215BHEP deKupferkomplexe optisch aktiver Bisoxazoline als enantioselektive Katalysatoren bei CyclopropanierungsreaktionenenCopper complexes of optically active bisoxazolines as enantioselective catalysts in cyclopropanation reactionsfrComplexes de cuivre de bisoxazolines optiquement actives comme catalyseurs énantiosélectives pour les réactions de cyclopropanationE. J. COREY, K. ISHIHARA: "Highly enantioselective catalytic Diels-Alder addition promoted by a chiral bis(oxazoline)-magnesium complex" TETRAHEDRON LETTERS, vol. 33, no. 45, 1992, pages 6807-6810, XP002087670S. E. DENMARK ET AL.: "Cyclopropanation with Diazomethane and Bis(oxazoline)palladium(II) Complexes" J. ORG. CHEM., vol. 62, no. 10, 1997, pages 3375-3389, XP000689793S. BENNETT ET AL.: "Structure and Mechanism in Aerobic Alkene Epoxidations promoted by Ruthenium Complexes of Bis(dihydrooxazole) Ligands" J. CHEM. SOC. DALTON TRANS., vol. 3, 1995, pages 367-376, XP002087671M. P. DOYLE ET AL.: "Enantioselektive Synthese von makrocyclischen Lactonen durch intramolekulare Cyclopropanierung von Diazoacetaten mit chiralen Cu(I)- und Rh(II)-Katalysatoren" ANGEW. CHEM., vol. 108, no. 12, 1996, pages 1439-1440, XP002087672A. V. BEDEKAR, P. G. ANDERSSON: "A New Class of Bis-Oxazoline Ligands for the Cu-Catalysed Asymmetric Cyclopropanation of Olefins" TETRAHEDRON LETTERS, vol. 37, no. 23, 1996, pages 4073-4076, XP004029302U. LEUTENEGGER ET AL.: "5-Aza-Semicorrins: A New Class of Bidentate Nitrogen Ligands for Enantioselective Catalysis" TETRAHEDRON, vol. 48, no. 11, 1992, pages 2143-2156, XP002087673R. E. LOWENTHAL, S. MASAMUNE: "Asymmetric Copper-Catalyzed Cyclopropanation of Ttrisubstituted and Unsymmetrical cis-1,2-Disubstituted Olefins: Modified Bis-Oxazoline Ligands" TETRAHEDRON LETTERS, vol. 32, no. 50, 1991, pages 7373-7376, XP002087674R. E. LOWENTHAL ET AL.: "Asymmetric Catalytic Cyclopropanation of Olefins: Bis-Oxazoline Copper Complexes" TETRAHEDRON LETTERS, vol. 31, no. 42, 1990, pages 6005-6008, XP002021203D. MÜLLER ET AL.: "C(2)-Symmetric 4,4',5,5'-Tetrahydrobis(oxazoles) and 4,4',5,5'-Tetrahydro-2,2'-methylenebis[oxa zoles] as Chiral Ligands for Enantioselective Catalysis" HELV. CHIM. ACTA, vol. 74, no. 1, 1991, pages 232-240, XP002083087A. BERNARDI ET AL.: "Enantioselective Mukaiyama-Michael Reactions of 2-Carbomethoxycyclopentenone Catalyzed by Chiral Bis(Oxazoline)-Cu(II) Complexes" TETRAHEDRON LETTERS, vol. 37, no. 49, 1996, pages 8921-8924, XP002087675H. BRUNNER ET AL.: "Asymmetric catalysis, part 108. Copper catalysts with optically active ligands in the enantioselective Meerwein arylation of activated olefins" J. ORGANOMET. CHEM., vol. 541, no. 1-2, 1997, pages 89-95, XP004093706J. M. TAKASC ET AL.: "Enantioselective Diels-Alder reactions: room temperature bis(oxazoline)-zinc, -magnesium, and -copper triflate catalysts" TETRAHEDRON: ASYMMETRY, vol. 8, no. 18, 1997, pages 3073-3078, XP004090515A. BERNARDI ET AL.: "Enantioselective Mukaiyama-Michael Reactions of 2-Carbomethoxycyclopentenone Catalyzed by Chiral Bis(Oxazoline)-Cu(II) Complexes" TETRAHEDRON LETTERS, vol. 37, no. 49, 1996, pages 8921-8924, XP004068814H. FALK, A. SUSTE: "On the Chemistry of Pyrrole Pigments, XCI: Copper Complexes of Pyridinologous Linear Tri- and Tetra-pyrroles as Cyclopropanation Catalysts" MONATSH. CHEM., vol. 125, no. 3, 1994, pages 325-334, XP002087676Itagaki, Makoto1-9-1, TamagawaTakatsuki-shi, OsakaJPSuzukamo, Gohfu19-10-1008, ShinashiyakamiSuita-shi, OsakaJPSumitomo Chemical Company, Limited00214352C 2181 EP27-1, Shinkawa 2-chome, Chuo-kuTokyo 104-8260JPVossius & Partner00103241Siebertstraße 481675 MünchenDEBECHDEFRGBITLINL19990217199907