FIELD OF THE INVENTION
[0001] This invention relates to a electrical heating method and apparatus useful in a borehole.
BACKGROUND TO THE INVENTION
[0002] U.S. Patent Nos. 4,640,352 and 4,886,118 disclose conductive heating of subterranean
formations of low permeability that contain oil to recover oil therefrom. Low permeability
formations include diatomites, lipid coals, and oil shales. Formations of low permeability
are not amiable to secondary oil recovery methods such as steam, carbon dioxide, or
fire flooding. Flooding materials tend to Penetrate formations that have low permeabilities
preferentially through fractures. The injected materials bypass most of the formation
hydrocarbons. In contrast, conductive heating does not require fluid transport into
the formation. Oil within the formation is therefore not bypassed as in a flooding
process. Heat injection wells are utilized to provide the heat for such processes.
[0003] Heat injection wells can also be useful in decontamination of soils. U.S. patents
5,318,116 and 5,244,310, for example, disclose methods for decontamination of soils
wherein heat is injected below the surface of the soil in order to vaporize the contaminates.
The heaters of patent '310 utilize electrical resistance of spikes, with electricity
passing through the spikes to the earth. Patent '116 discloses heater elements passing
through the wellbore to the bottom of the formation to be heated. The wellbore surrounding
the heater includes a catalyst bed, which is heated by the heater elements. Heat conductively
passes through the catalyst bed to a casing surrounding the catalyst bed, and then
radiantly from the casing to the soil surrounding the wellbore. Typical alumina based
catalysts have very low thermal conductivities, and a significant temperature gradient
will exist through the catalyst bed. This significant temperature gradient will result
in decreased heat transfer to the earth being heated at a limited heater element temperature.
[0004] U.S. patent no. 5,065,818 discloses a heater well with sheathed and mineral insulated
("MI") heater cables cemented directly into the wellbore. The MI cables includes a
heating element surrounded by, for example, magnesium oxide insulation and a relatively
thin sheathing around the insulation. The outside diameter of the heater cable is
typically less than one half of an inch (1.25 cm). The heater well optionally includes
a channel for lowering a thermocouple through the cemented wellbore for logging a
temperature profile of the heater well. Being cemented directly into the wellbore,
a need for a casing (other than the sheathing of the cable) is eliminated, but the
outside diameter of the cable is relatively small. The small diameter of the heater
cable limits the amount of heat that can be transferred to the formation from the
heater cable because the area through which heat must pass at the surface of the cable
is limited. A cement will have a relatively low thermal conductivity, and therefore,
a greater heat flux at the surface of the cable would result in an unacceptably high
heater cable temperature. Multiple heater cables may be cemented into the wellbore
to increase the heat transfer to the formation above that which would be possible
with only one cable, but it would be desirable to further increase the heat that can
be transferred into earth surrounding the heaters.
[0005] U.S. patent 2,732,195 discloses an electrical heater well wherein an "electrically
resistant pulverulent" substance, preferably quartz sand or crushed quartz gravel,
is placed both inside and outside of a casing of a wellbore heater, and around an
electrical heating element inside of the casing. The quartz is placed there to reinforce
the casing against external pressures, and a casing that is sealed against the formation
is required. The casing adds considerable expense to the installation.
[0006] It is therefore an object of the present invention to provide a wellbore heater wherein
the heater has a greater surface area at the temperature of the electrical resistance
element than those of the prior art, and in which a substantial casing is not required.
This heater is useful as a well heater for such purposes as thermal recovery of hydrocarbons
and soil remediation.
SUMMARY OF THE INVENTION
[0007] These and other objects are accomplished by an electrical heater comprising an electrical
insulating material surrounding an annular heating element configuration, wherein
there is no casing surrounding the heating element configuration.
[0008] The casingless design of the present heater significantly reduces the cost of a heat
injection well, which is significant in an application such as heat injectors for
recovery of hydrocarbons from, for example, oil shales, tar sands, or diatomites.
Heat injection can also be used to remove many contaminates.
[0009] It is preferred that the annular heating element configuration is selected from the
group consisting of an annular porous metal sheet, one or more expanded metal plates,
a wire mesh, and strips wires, rods or filaments connected by spacers.
[0010] In accordance with another aspect of the invention there is provided a method to
heat a portion of the earth, the method comprising the steps of:
providing a borehole within the portion of the earth to be heated;
placing an annular heating element configuration within the borehole; and
supporting the heating element configuration within the borehole with electrically
insulating material,
wherein a metal casing is not provided between the heating element configuration and
the earth to be heated.
BRIEF DESCRIPTION OF THE DRAWINGS
[0011]
FIG. 1 shows first embodiment of a heater according to the present invention within
a wellbore.
FIGS. 2A, 2B, and 2C show details of an electrical cable attached to the top of a
heater according to the present invention.
FIG. 3 shows an alternative embodiment of a heater according to the present invention
within a wellbore.
FIG. 4 shows a cross sectional view of the heater of FIG. 3 in a borehole.
FIG. 5 shows an apparatus for installing the heater of the present invention.
DETAILED DESCRIPTION OF THE INVENTION
[0012] Optionally the annular heater of the present invention has a mesh heating element
which can be formed to conform to a wall of a wellbore to maximize the surface of
the heating element which is provided and to maximize the heat flux leaving the wellbore.
An electrically insulating filler is placed around and inside of the heating element
to essentially eliminate electrical shorting of the element to the formation. This
electrically insulating material could be a material that is initially wet, and therefore
electrically conducting until it is dried. The drying step could be accomplished by
passing electricity through the heating element and into the wet material, and heat
generated by the electrical energy would gradually heat the soil and eventually vaporize
liquid water initially present. The remaining dry sand is an acceptable electrical
insulator. Optionally, a hydraulic cement could be used in place of the sand. Hydration
of the cement reduces free liquid water, and the cured cement can be an acceptable
electrical insulator. Other materials could be used as the insulating material. Preferred
materials are easily placed and inexpensive. An ideal material would also either be
or readily become an electrically nonconducting material. A material such as sand
could be placed pneumatically or as a slurry.
[0013] A plurality of electrical heating elements are preferably placed in the wellbore
to form the heater, with the elements connected at the lower portion of the wellbore,
and different phases of alternating electrical power applied to each of the elements.
Two or three elements are preferred.
[0014] The heating elements can be expanded metal, or another porous metal element such
as a wire screen or wire mesh. A porosity of between about forty percent and about
eighty percent is preferred, where porosity is defined as the percent of open area
looking at the surface of the sheet of material. Providing this open area considerably
increases the total area contacted by the element, without reducing the thickness
of the element. A thicker element provided greater allowances for corrosion. Thickness
of the element is chosen to result in a voltage requirement at the targeted heat flux
which is not excessively low or high. For example, a voltage differential of about
120 to about 960 volts of alternating current between the upper ends of two elements
within a wellbore which have connected lower ends would be preferred. Generally, for
longer lengths of meter (100 to 700 meters) from 480 to 960 volts is preferred and
for shorter meters (2 to 200 meters) from 120 to 480 volts is preferred. To accommodate
greater thicknesses of elements, multiple heaters could be provided in series, but
the extent to which this can be done is limited by the expense of the cables leading
to the heater elements. Power is preferably applied between two symmetrical heater
elements wherein the net voltage is zero. Thus the voltage applied at one time to
one electrode is the negative with respect to ground of the voltage applied to the
other heater element.
[0015] The elements are preferably formed into a curved shape either at the surface or within
the borehole to conform to the walls of the wellbore. The curved shape could be provided
at the surface by a die through which the metal is passed as it is passed into the
wellbore. The curved shape could be provided within the wellbore by a passing a mandril
past the element. The mandril could, for example, be provided as a part of an apparatus
which spreads the elements and places the electrical insulating material around and
between the elements. When the elements are formed into a curved shape at the surface,
centralizers and spacers can be added to the elements to keep the elements separated
within the wellbore. Use of the mandrel as described above is preferred because centralizers
and spacers can be eliminated, reducing the cost of materials. Flat mesh-elements
could be provided. The advantage of providing curved elements is that heat could be
transferred from almost the entire circumference of the borehole, with two flat elements,
heat could be transferred from a surface area of only about twice the diameter of
the wellbore, but installation of the flat elements could be simplified compared to
the semicircular shaped elements.
[0016] Generally, heater elements of stainless steel of, for example, grades 304 or 316
are preferred. INCLOY 600 could also be useful (INCLOY is a trademark). 316 stainless
steel is preferred when the elements will be exposed to brines because of the greater
resistance of 316 stainless steel to chloride stress corrosion. Stainless steels are
not excessively expensive, and would withstand exposure to elements that may be present
during start-up phases for long enough to get the elements up to elevated temperatures,
and sufficiently low corrosion rates when exposed to most borehole environments for
extend periods of time at elevated temperatures. Typically, stainless steels are not
utilized as heater elements because of limited high temperature corrosion resistance,
but because of the relatively large surface area from which heat is transferred in
the heater of the present invention, the elements surface temperature can be suitable
for stainless steels. Carbon steels could also be used as heater elements for applications
where high levels of heat do not have to be provided for extended periods of time.
[0017] Although in a preferred embodiment of the present invention includes the use of stainless
steel as the heater element material, higher alloys could be useful in some applications
of the present invention. For example, when the heater is applied in a relatively
deep wellbore, the costs of providing the well could be much greater than the costs
of the heater element material, and therefore a higher alloy could reduce total costs
by permitting operation at higher temperatures and thus reducing the number of wells
required for the same total heat duty.
[0018] Alternatively, the heating elements could be coated with a more corrosion restive
metal surface, or a refractor surface to provide additional electrical insulation
and protection.
[0019] Thermocouples for control of the heaters could be provided within the wellbore, either
inside of curved heater elements, outside of the elements, or attached to the heater
elements (through an electrically insulating connection). The thermocouple could be
used to monitor the operation, or to control electrical power applied to the heater
element. When thermocouples are used to control the electrical power, multiple thermocouples
could be provided and the a control temperature selected from the thermocouples. The
selection could be based on a maximum temperature, an average temperature, or a combination
such as an average of the highest two or three temperatures.
[0020] The heat elements of the present invention can be made to a wide variety of lengths
because of the flexibility to select different combinations of voltages and porosities
of the heater elements. Heaters as short as two to six meters can be used, and as
long as two hundred to seven hundred meters could be provided.
[0021] A borehole within which the heater of the present invention is placed may be cased
and cemented for at least a portion of the borehole above the heater, to ensure isolation
of the formation to be heated. In a shallow well, the borehole may be filled with
sand to the surface.
[0022] Referring now to FIG. 1, a schematic drawing of the annular heater of the present
invention is shown. A mesh heater element 1 is shown as two semicircular expanded
metal plates within a wellbore 2. An electrically insulating filler 3 such as sand
is shown surrounding and between the heating elements. The borehole is within a portion
of the earth to be heated 4, such as a formation of oil containing diatomite, tar
sands or oil shale. Alternatively, the earth to be heated 4 could be contaminated
soil in a thermal desorption remediation process. Electrical leads 5 extend to each
of the heater elements and the heater elements are electrically connected at the lower
portion of the elements by connector 6. Alternatively, the elements could all be grounded
at the base of the borehole. Electrical leads extend through the portion of the overburden
which is not to be heated 7 through sheathed cables 8, the sheathed cables separated
by spacers 9. A transition portion of the wellbore will be heated by the heater elements,
but not to the temperatures that result in the portion of the borehole which contains
the heater elements. This transition portion of the borehole is shown as cased by
a casing 10, which may be of a metal such as stainless steel, which will have an acceptably
long useful life when exposed to elevated temperatures. The corrosion environment
within this transition volume may be more sever than the corrosion environment near
the heaters because of the dew point temperature being within this region. Above the
transition zone, the casing could be a carbon steel casing 11. The casing within the
transition zone and the overburden 7 could be filled with a filler 12 such as sand
or cement, or left void.
[0023] Referring now to FIG. 2A, 2B, and 2C, three views with partial cutaways are shown
of fittings for electrical cables and connections to the heater element of the present
invention. The top of the heater element 21 is connected to a high temperature lead
cable 22 by a weld connection 33. A waterproof interface between the cable and heater
A is within a transition zone. Above the transition zone, an inexpensive cable such
as a polyethylene coated copper wire could be used. An electrically insulated high
temperature section B extends from the waterproof interface to the heater element.
A stiffener 24 provides support for the electrical connection to the heater element.
The stiffener is attached to the cable by a collar 25. The collar is an electrically
insulating collar. The water proof interface includes a coupling 26 around a soldered
connection 27, the soldered connection providing continuity between the high temperature
lead cable 22 and a low temperature lead cable 28. The coupling is threaded to swedge
fittings 30, which may be brass fittings, and which provide a friction fitting to
each of the high temperature lead sheath 31 and the low temperature lead sheath 23.
Cable 23 goes from the surface to just above the top of the heater and cam be a copper
core-copper sheathed mineral insulated cable. This type of cable is preferred because
of its ability to carry very large amounts of electrical power, and because it is
waterproof. Although the cable can withstand high temperatures, it is used at temperatures
below the boiling point of water due to corrosion rates. A waterproof splice (A) terminates
the mineral insulated cable 23 and forms a transition to a nickel or nichrome clad-nickel
electrode 22 that is welded 33 to the upper part of the heater 21. The nickel hot
electrode 22 can be insulated with a TEFLON sleeve 31 to prevent corrosion of the
nickel electrode and provide a waterproof seal at the lower end of the cable transition
30 (TEFLON is a trademark). Stiffening arm 24 provides support to the TEFLON sleeved
nickel electrode 22 during installation of the heater into a wellbore. The waterproof
splice A can be about two to twenty feet above the top of the heater element. The
water proof splice is far enough away from the heater so that the water proof splice
remains at a temperature below the boiling point of water. The TEFLON coated high
temperature lead is, at one point, exposed to the boiling point of water, and is easily
capable of handling this environment. The lower (hotter) portion of the high temperature
lead sheath 31 will eventually melt away, leaving exposed high temperature lead. Providing
the TEFLON coating to this point ensures that the TEFLON extends past the point where
the temperature is at the boiling point of water.
[0024] The high temperature lead sheathing could be any coating which would protect the
high temperature lead from corrosion at temperatures of the boiling point of water
or less, and would either withstand higher temperatures or melt away and not cause
any corrosion at higher temperatures. Heat resistant resins are preferred because
they provide a greater length of protected high temperature lead which could be helpful
if the point at which the temperature is the boiling point of water moves. Acceptable
high temperature resins include polyimide, polyamide-imide, and polyetheretherketone.
[0025] The high temperature lead sheath is separated from the high temperature lead by mineral
insulation such as magnesium oxide. Copper leads are acceptable and effective for
the low temperature leads, but nickel or nickel-chromium clad nickel are preferred
for the high temperature leads.
[0026] Alternatively a plurality of elongate electrical heating elements are placed in the
wellbore to form the heater, with the elements connected at the lower portion of the
wellbore, and different phases of alternating electrical power applied the elements.
At least six elements are preferred in order to provide heat around the entire circumference
of the wellbore.
[0027] The heating elements can be, for example, stainless steel wire, nickel-chrome alloy
wire or carbon fiber elements. The wires are preferably between about 0.2 and about
0.8 mm in diameter and more preferably about 0.3 mm in diameter. Thicker elements
provided greater allowances for corrosion, but at the expense of greater current requirements
and greater material costs. Thickness of the element is chosen to result in a voltage
requirement at the targeted heat flux which is not excessively low or high. For example,
a voltage differential of about 60 to about 960 volts AC between the upper ends of
two elements within a wellbore which have connected lower ends would be preferred.
For shorter heaters (2 to 200 meters), voltages of 60 to 480 volts AC are preferred,
and for longer heaters (100 to 700 meters) a voltage of 480 to 960 volts AC is preferred.
To accommodate greater thicknesses of elements, multiple heaters could be provided
in series, but the extent to which this can be done is limited by the expense of the
cables leading to the heater elements.
[0028] Generally, heater elements of stainless steel of, for example, grades 304, 316, or
310 are preferred. Stainless steels are not excessively expensive, and would withstand
exposure to elements that may be present during start-up phases for long enough to
get the elements up to elevated temperatures, and sufficiently low corrosion rates
when exposed to most borehole environments for extend periods of time at elevated
temperatures. Carbon steels could be used as heater elements for applications where
heat does not have to be provided for extended periods of time. For shallow applications
such as soil remediation, nichrome 80 is preferred.
[0029] Thermocouples for control of the heaters could be provided within the wellbore, either
inside of the ring of heater elements, outside of the elements, or attached to the
heater elements. The thermocouples could be, for example, secured to one of the electrically
insulating spacers. The thermocouple could be used to monitor the operation, or to
control electrical power applied to the heater element. When thermocouples are used
to control the electrical power, multiple thermocouples could be provided and the
control temperature selected from the thermocouples. The selection could be based
on a maximum temperature, an average temperature, or a combination such as an average
of the highest two or three temperatures.
[0030] The heater elements of the present invention can be made to a wide variety of lengths
because of the flexibility to select different combinations of voltages and diameters
of the heater elements. Heaters as short as two meters can be used, and as long as
700 meters could be provided.
[0031] A borehole within which the heater of the present invention is placed may be cased
and cemented for at least a portion of the borehole above the heater, to ensure isolation
of the formation to be heated. In a shallow well, the borehole may be filled with
sand or a bentonite slurry to the surface. The bentonite slurry prevents water ingress
from above.
[0032] Referring now to FIG. 3, a schematic of the heater of the present invention is shown.
Heater elements 101 (two shown) are provided with electrical leads to the elements
102 which are larger in diameter than the heater elements, but can be of the same
material. The number of elements is preferably between two and six. The electrical
leads are shown extending to individual heater elements, but a spacer could be provided
wherein only one electrical lead is provided for each phase of electrical energy,
and the power is applied in parallel or series to different heater elements. The borehole
within which the heater is placed is preferably between about 5 and about 20 centimeters
in diameter, and the heater element are preferably placed between about one half and
about one centimeter from the wall of the borehole. The elements are preferably separated
by between about four and about eighteen centimeters. Fewer elements generally reduces
the cost of the heater, but a larger number of elements permits greater heat flux
into a formation from the heater at limited heater element temperature. The heater
elements are not individually electrically insulated, but rely on the electrical insulating
properties of electrically insulating filler material surrounding the elements. A
casing 103 is provided at the surface for isolation, but preferably does not extend
to the soil to be heated 104, but only through an overburden 106. Sand or a hydraulic
or ceramic cement 105 is shown surrounding the heater elements. When the soil is to
be heated to the surface, a short tube could be provided to provide a stable flange
for securing the tops of the heater elements.
[0033] A flange 107 is shown with insulating sleeves 108 around the electrical leads to
the heater elements. Power supply wires 109 provide electrical power to the electrical
leads, and are secured by nuts 110.
[0034] An electrical insulating spacer 111 provides separation of the electrical elements
within the borehole. One electrical insulating spacer is shown, but more than one
can be provided, and preferably, one is provided each three to ten meters within the
wellbore. Further, the electrical insulating spacer is shown within the heater section,
but one or more can also be provided in the electrical lead-in section about the heaters.
The electrical insulating spacers can be made from an inexpensive plastic, and do
not necessarily have to withstand the elevated operating temperatures. The spacers
only need to hold the heater elements in place while the filler material is placed
around the elements. Alternatively the spacers could be made from ceramics such as
alumina, or machineable ceramics such as MACOR (MACOR is a trademark).
[0035] The lower ends of the heater elements can be connected with an electrically conducting
connector 112. The electrically conducting connector can connect all of the elements,
or a combination of elements such that each of the elements has electrical continuity
necessary for current to pass through the elements. The electrically conducting connector
optionally has a cup 113 for securing the connector to a tube for lowering the elements,
connector and spacer down the borehole. A tubing from, for example, a coiled tubing
unit, could be placed within the cup 113, and the cup held to the coiled tubing either
by, for example, a friction fit which could be broken by pressure from with the coiled
tubing, or the tubing could be held to the cup by tension from the heater elements
as the connector is lowered into the borehole.
[0036] The electrically conducting connector is shown at the bottom of the wellbore, with
each heater element extending uniformly down the heated portion of the wellbore. But
the number and/or heat duties of the heater elements can vary along the length of
the heater. The diameters of the heating elements can vary along the length of the
heater to tailor the heat deposition to a desired profile.
[0037] Referring now to FIG. 4, a view looking down at the electrically insulating spacer
is shown. Heater elements 101 (six shown) are separated by insulating spacer 111,
with the electrically insulating filler such as sand or cement 105 surrounding the
spacer and heater elements. The soil to be heated 104 surrounds the heater. The electrically
insulating spacer 111 is shown as being in two parts, with mating tongues and groves
to allow the spacers to be slipped inside the heater elements and around a tube when
the tube is being used to lower the heater elements into the borehole. A tie wrap
201 can be used to secure the heater elements in notches within the spacer. The spacer
may be secured vertically to the heater elements by friction, or may be held vertically
by clamps (not shown) placed above, or above and below the spacer on one or more of
the heater elements.
[0038] Referring now to FIG. 5, an apparatus which can be used to place the heater of the
present system into a wellbore is shown. Heater elements 101 (two shown) are strung
over pullies 301, the pullies mounted on brackets 302 which are set on a flange 303.
The flange 303 is mounted on the casing 103, which is equipped with a mating flange.
The heater elements 101 are rolling off spools (not shown) and can be maintained in
slight tension to prevent entanglement of the heater elements within the borehole.
A coiled tubing 304 is shown extending into the borehole. The coiled tubing can be
used to place the heater elements and electrical leads within the borehole, and then
used to fill the borehole with the electrically insulating filler as it is removed.
[0039] The heating elements can be of a wide variety of lengths and a wide variety of distances
down a borehole. For example, for heating an oil shale formation, the heater may be
400 meters long. For remediation of contaminated soil, the heater may be only two
or three meters long, although longer heater elements are more advantageously provided
by the present invention. The heaters may be provided an extended distance down the
borehole. For example, an oil shale formation may be heated which lies under 400 meters
of overburden. As the length of the heater and electrical leads become very long,
the heater elements and/or electrical leads may be required to be of larger diameter
or may need to be made of a material which has greater strength because these elements
must be self supporting until the electrically insulating filler is placed around
the elements. The heater elements therefore do not have to be self supporting at operating
temperatures because friction with the electrically insulating filler will provide
vertical support for the elements.
1. A wellbore heater comprising:
an annular heating element configuration; and
an electrical insulating material surrounding the annular heating element configuration;
wherein there is no casing surrounding the annular heating element configuration.
2. The heater of claim 1 wherein the annular heating element configuration is selected
from the group consisting of an annular porous metal sheet, one or more expanded metal
plates, a wire mesh, and strips wires, rods or filaments connected by spacers.
3. The heater of claim 2 wherein the annular heating element configuration comprises
at least one expanded sheet which is rounded to essentially comply with a portion
of a wall of a wellbore.
4. The heater of claim 3 wherein a plurality of expanded slotted metal sheet heating
elements are provided and each expanded slotted metal sheet is separated from the
other expanded slotted metal sheets.
5. The heater of claim 4 wherein the plurality of expanded metal sheets are electrically
connected at a lower extremity.
6. The heater of claim 5 further comprising a power supply to each of the expanded metal
sheets at an upper extremity, and wherein each of the power supplies is a different
phase of electrical power.
7. The heater of claim 1 wherein the electrical insulating material comprises sand.
8. The heater of claim 1 wherein the electrical insulating material comprises cement.
9. The heater of claim 1 wherein a plurality of expanded metal heating elements are provided
and the plurality of heating elements are electrically connected to different phases
of alternating electrical power at a powered end and electrically connected to a common
ground at a ground end.
10. The heater of claim 2 wherein the heater comprises metal strips or rods which are
separated by at least one electrically insulating spacer maintaining a separation
between the elements and between the elements and the sides of the wellbore.
11. The heater of claim 10 further comprising an electrically conductive connector at
the lower extremity of the metal strips or rods, the electrically conductive connector
providing electrical continuity between the strips or rods.
12. A method to heat a portion of the earth, the method comprising the steps of:
providing a borehole within the portion of the earth to be heated;
placing an annular heating element configuration within the borehole; and
supporting the heating element configuration within the borehole with electrically
insulating material, wherein a metal casing is not provided between the heating element
configuration and the earth to be heated.
13. The method of claim 12 further comprising the step of initiating electrical flow through
the heating element configuration by passing electrical current from the heating element
to the portion of the earth to be heated at a current effective to remove liquid water
from the electrical insulating material; and increasing voltage applied to the heating
element configuration as a resistance increases through the electrical heating element
configuration.
14. The method of claim 12 wherein a plurality of heating elements are provided; the heating
elements are all electrically connected at a lower extremity of the heating elements;
and different phases of electrical power are applied to the heating elements at an
upper extremity of the heating elements.
15. The method of claim 14 wherein the heating elements are selected from the group consisting
of a stainless steel wire, nickel-chromium alloy wire, and carbon filament.