[0001] The invention relates to a loudspeaker diaphragm of an injection foam molded body.
[0002] Materials for loudspeaker diaphragms generally require small density, rigidity, appropriate
internal loss, and environmental resistance.
[0003] Of conventional materials for loudspeaker diaphragms, polypropylene (PP) is excellent
in environmental resistance (particularly, in water resistance) and large in internal
loss. Liquid crystal polymer is high in rigidity.
[0004] Besides, for realizing light-weight and high-rigidity diaphragms by structural means,
those in honeycomb structure and in three layer structure in which a foamed body is
sandwiched between flat skin layers have been proposed.
[0005] In the conventional examples as described above, it is difficult to select a perfect
diaphragm material for satisfying all the aforementioned requirements; that is, PP
is higher in specific gravity as compared to paper and lower in Young's modulus, and
liquid crystal polymer is higher in specific gravity and smaller in internal loss
than PP, for example.
[0006] Accordingly, there have been made some approaches in which physical properties such
as density and Young's modulus are adjusted by structural means as described above,
and the other requirements are satisfied by the selection of the material. However,
the structural adjusting of the physical properties requires additional processes
such as adhesive bonding of respective layers in the three layer structure. This gives
rise to a problem in higher cost in manufacturing processes.
[0007] In order to solve the aforementioned problem, the inventors of the present invention
have precedently proposed, in Japanese Patent Application No. Hei 7-14782 (Japanese
Patent Application Laid-open No. Hei 8-340594), a loudspeaker diaphragm which is formed
in three layer structure having a foamed layer at its inside and unfoamed layers at
its surfaces by injection molding a resin containing a foaming agent. In the diaphragm,
the three layer structure is formed without adhesive bonding the layers. This improves
the physical properties by structural means with no increase in cost in manufacturing
processes, thereby obtaining lighter weight, higher internal loss, higher rigidity,
and improved environmental resistance.
[0008] An object of the present invention is to further enhance the aforesaid proposal to
improve the physical properties and appearance quality, in consideration of the influence
of the content of resin in an integral molded article of three layer structure having
a foamed layer at its inside and unfoamed layers at its surfaces as described above.
[0009] The foregoing object and other objects of the present invention have been achieved
by the provision of a loudspeaker diaphragm of an injection foam molded body which
is formed in three layer structure composed of a foamed layer at the inside thereof
and unfoamed layers at the surfaces thereof by injection molding a resin containing
a foaming agent, characterized in that the aforesaid resin contains an inorganic or
organic filler of 3-30% by weight.
[0010] According to the present invention, a resin containing a foaming agent is injection
molded into an injection foam molded body in three layer structure having a foamed
layer 3 at its inside and unfoamed skin layers 2 at its surfaces. This allows both
low specific gravity and large thickness, thereby obtaining a light-weight and high-rigidity
diaphragm. Since being covered with the unfoamed layers at the surfaces, the diaphragm
has excellent environmental resistance. Besides, no adhesive bonding is needed unlike
conventional three layer structure, so that the cost in manufacturing can be lowered.
Moreover, an inorganic or organic filler of 3-30% by weight is contained in the resin
to be injection molded, which improves the appearance quality with keeping the aforesaid
physical properties favorable. In this connection, it should be noted that too small
content of the filler causes the easy shrinking of the surface unfoamed layers, which
deteriorates the appearance quality; too large content of the filler affects the foaming
state, resulting in low rigidity.
[0011] Hereinafter, preferred embodiments of the present invention will be described with
reference to the accompanying drawings in which:
Fig. 1 is an explanatory diagram showing an embodiment of a loudspeaker diaphragm
of an injection foam molded body according to the present invention;
Fig. 2 is an explanatory diagram showing an injection molding machine for producing
the loudspeaker diaphragm of an injection foam molded body shown in Fig. 1;
Figs 3(a), 3(b), and 3 (c) are explanatory diagrams showing a method for producing
the loudspeaker diaphragm by the injection molding machine shown in Fig. 2;
Fig. 4 is an explanatory diagram showing molding characteristics of the injection
molding machine in Fig. 2;
Fig. 5 is a table showing the changes in the properties of the speaker diaphragm of
an injection foam molded body shown in Fig. 1, depending on foaming magnification;
Fig. 6 is an explanatory diagram showing the change in Young's modulus of the loudspeaker
diaphragm of an injection foam molded body shown in Fig. 1, depending on foaming magnification;
Fig. 7 is an explanatory diagram showing the change in internal loss of the loudspeaker
diaphragm of an injection foam molded body shown in Fig. 1, depending on foaming magnification;
and
Fig. 8 is an explanatory diagram showing the change in modulus of rigidity of the
loudspeaker diaphragm of an injection foam molded body shown in Fig. 1, depending
on foaming magnification.
[0012] Fig. 1 shows an embodiment of a loudspeaker diaphragm of an injection foam molded
body according to the present invention. The shown loudspeaker diaphragm 1 of an injection
foam molded body has three layer structure composed of a foamed layer 3 at its inside
and skin layers (unfoamed layer) 2 at its surfaces. In forming the three layer structure,
a resin mixture material of polypropylene (PP) containing a foaming agent is injected
into a mold. Immediately after the injection, the mold is separated so that the material
starts to foam at its inside to form the foamed layer 3. Since being in contact with
the inner surfaces of the mold in the injection, the surfaces of the resin mixture
material have solidified before the foaming, so as to form the unfoamed skin layers
2. It should be noted that the resin mixture material also contains an inorganic or
organic filler of 3-30% by weight. Here, too small content of the filler causes the
easy shrinking of the surface unfoamed layers, which deteriorates the appearance quality;
too large content of the filler affects the foaming state, resulting in low rigidity.
Through experience, the most appropriate content of 3-30% by weight is determined.
[0013] Examples of the inorganic filler to be contained in the resin include: silica; diatomaceous
earth; oxides such as alumina, titanium oxide, iron oxide, zinc oxide, and magnesium
oxide; hydroxides such as aluminum hydroxide, calcium hydroxide, and basic magnesium
carbonate; carbonates such as calcium carbonate, magnesium carbonate, and dolomite;
sulphates and sulphites such as calcium sulphate, barium sulphate, and calcium sulphite;
talc; clay; mica(phlogopite, biotite, muscovite, and the like); asbestos; glass fibers;
glass balloon; glass beads; silicates such as calcium silicate, montmorillonite, and
bentonite; and silicon carbide monocrystal. Of organic fillers, crystalline cellulose
fine powders and urea resin fine powders may be cited. Each of the fillers may be
used by itself, or a plurality of the fillers may be mixed for use. In addition, appropriate
coupling materials may be applied to the fillers so as to improve the interaction
with the resin.
[0014] The loudspeaker diaphragm 1 is 0.17mm to 1.8mm in thickness, and the skin layer 2
is 0.05mm to 0.20mm in thickness. These dimensions are required for well-balanced
properties of the loudspeaker diaphragm 1. This will be described for details, later.
[0015] Fig. 2 shows an injection molding machine for producing the loudspeaker diaphragm
1 of an injection foam molded body in Fig. 1. The injection molding machine has the
molding characteristics as shown in Fig. 4.
[0016] In the shown injection molding machine, a mold 20 comprises a moving-side mold 21
held with a moving platen 24 and a stationary-side mold 22 held with a stationary
platen 25. The clamping pressure between the moving-side mold 21 and the stationary-side
mold 22 is controlled with a clamping cylinder 10 which is controlled by a mold clamping
pressure control unit 30.
[0017] Into an injection opening of the stationary-side mold 22 is inserted a nozzle of
an injection apparatus 40 for injecting a resin mixture material of polypropylene
(PP) containing a foaming agent. An injection process control unit 31 controls injection
conditions to control the injection apparatus 40. In the meantime, the injection apparatus
40 outputs information on the molding process. According to the information and other
information such as on the distance of the moving platen 24, the mold clamping pressure
control unit 30 controls the clamping pressure.
[0018] Next, a method for producing a loudspeaker diaphragm by the injection molding machine
in the above-mentioned configuration will be described below.
[0019] First, as shown in Fig. 3(a), the clamping cylinder 10 closes the moving- and stationary-side
molds 21 and 22 into the mold 20. Into a cavity of the mold 20, a resin mixture material
of PP containing a foaming agent and an inorganic or organic filler is injected by
the injection apparatus 40.
[0020] The resin mixture material in the injection apparatus 40 is kept at a temperature
of approximately 230°C. The cavity surfaces of the mold 20 are kept at a temperature
of approximately 90°C. The mold clamping pressure control unit 30 controls the clamping
cylinder 10 to keep a clamping pressure of approximately 100 t. The cavity formed
between the moving- and stationary-side molds 21 and 22 in the mold 20 is approximately
0.3 mm in general thickness.
[0021] Here, as shown in Fig. 3(b), the resin mixture material filled into the cavity between
the moving- and stationary-side molds 21 and 22 starts to solidify at the portions
in contact with the mold 20, thereby forming skin layers 2. In the other molten portions,
a gas released by the decomposition of the foaming agent is constricted under an extrusive
pressure of a screw in the injection apparatus 40 and the clamping pressure between
the moving- and stationary-side molds 21 and 22, so that the foaming is confined in
the course of solidification.
[0022] Then, as shown in Fig. 3(c), the mold clamping pressure control unit 30 controls
the clamping cylinder 10 to instantly reduce the clamping pressure down to approximately
0 t immediately after the completion of the filling of the resin mixture material.
At this point, the foaming agent in the molten portions still holds a foaming pressure
enough to extend the surrounding skin layers (solidified portions) 2. This allows
the constricted decomposed gas in the molten portions to expand with extending the
resin around so that the foaming starts.
[0023] Hereinafter, the timing of the mold opening in the moving-side mold 21 will be described.
[0024] When the mold opening is done before the filling of the resin mixture material is
completed, the resin mixture material is excessively injected into the cavity between
the moving- and stationary-side molds 21 and 22 of the mold 20, thereby increasing
the weight of the resultant product. Conversely, the mold opening in belated timings
advances the solidification of the resin excessively, so that the solidification is
completed before the foaming agent foams. In this embodiment, the mold opening is
favorably done in 0.3-0.4 second after the beginning of the injection. It should be
noted that the appropriate time depends on such conditions as the resin temperature
of the resin mixture material, the temperature of the mold 20, the thickness of the
product, and the amount of the foaming agent content.
[0025] The mold 20 is opened by approximately 0.1-1.5 mm. Since the mold 20 needs to be
opened in a short time of 0.04-0.05 second, the foaming agent and the clamping pressure
are controlled so as to open the mold 20 at a speed of approximately 0.0020-0.0375
mm/ms. In molding a foam molded diaphragm of thin-type, the mold is satisfactorily
opened at speeds above approximately 0.001 mm/ms.
[0026] By mounting a spring between the moving-side mold 21 and the stationary-side mold
22, the opening force of the moving-side mold 21 on reducing the clamping pressure
can be increased to further increase foaming magnification.
[0027] To take a concrete example of the injection molding machines and the foaming agent
employed in this embodiment, polypropylene (PP) is MA06, a trade name of MITSUBISHI
CHEMICAL CORPORATION, containing 7% carbon fibers, and the foaming agent is EE-205,
a trade name of EIWA CHEMICAL IND. CO., LTD., which was used in compounding ratio
of 0.1 parts by weight. For the injection molding machine, Ultra 220, a trade name
of Sumitomo Heavy Industries, Ltd., is used.
[0028] Properties of the product obtained by the aforementioned producing method of a foam
molded body are shown in Figs. 5-8.
[0029] More specifically, Fig. 5 shows the measurements in specific gravity, Young's modulus,
internal loss, total thickness, and modulus of rigidity under a constant product weight
and varied foaming magnifications. Fig. 6 shows the change in Young's modulus depending
on the foaming magnifications, Fig. 7 the change in internal loss depending on the
same, and Fig. 8 the change in the modulus of rigidity depending on the same, respectively.
[0030] As shown in the drawings, a rise in foaming magnification decreases Young's modulus
and specific gravity, but increases total thickness. Since rigidity is in inverse
proportion to Young's modulus and in proportion to the cube of total thickness, a
rise in foaming magnification increases rigidity.
[0031] A foaming magnification of approximately 1.1 provides rigidity equivalent to existing
PP cones (Young's modulus of 6.4E+9 N/m
2 and thickness of 0.3 mm) and increased internal loss. An additional increase in foaming
magnification further raises rigidity.
[0032] At foaming magnifications above approximately 3.0, however, excessively grown foam
cells produce irregular foaming, and increase the dispersion in properties of the
diaphragm. Therefore, foaming magnifications of 1.1-3.0 are appropriate.
[0033] Besides, at foaming magnifications above 1.5, the foam cells in the foamed layer
3 are oriented along the total thickness direction as shown in Fig. 1 to reinforce
the skin layers 2, thereby slowing the decrease of Young's modulus and boosting the
increasing rate of rigidity. This partly results from that the foam molding is performed
with separating the mold 20 at higher speeds.
[0034] However, at foaming magnifications above 2.5, the resin in the foamed layer 3, which
reinforces the skin layers 2, becomes too small in density. This increases the decreasing
rate of Young's modulus, and thereby the dispersion in the rigidity of the products
rises gradually. Hence, foaming magnifications of 1.5-2.5 are appropriate to utilize
the structural increase of rigidity by the foam molding to obtain stable products.
[0035] For light-weight and high-rigidity structural body of a sandwich structure of the
skin layers 2 and the foamed layer 3, the skin layers 2 are favorably made as thin
as possible within the limits of the strength. However, in injection foam molding,
excessive thinning produces problems such as in deformation of the skin layers 2 in
separating the mold 20 for foaming, and in easy breakage.
[0036] However, too thick skin layers decrease the amount of the resin for forming the foamed
layer 3, preventing effective foaming magnifications (in other words, decreasing the
foaming magnifications). Accordingly, the skin layers 2 are best balanced in a thickness
of approximately 1/3 of the total thickness before foaming. Unfoamed PP plates of
a thickness of 0.15-0.6 mm are generally used for loudspeaker diaphragms; therefore,
favorable skin layers have a thickness of 0.05-0.20 mm.
[0037] As described above, in this embodiment, a resin containing a foaming agent is injection
molded into an injection foam molded body in a three layer structure in which a foamed
layer 3 is covered with unfoamed skin layers 2. This allows the resultant articles
to be low in specific gravity and thick in total thickness, obtaining a light-weighted
and high-rigiditied diaphragm. The diaphragm has excellent environmental resistance
since the skin layers 2 cover its surface. In addition, no adhesive bonding is needed
unlike conventional three layer structures, thereby lowering the cost in production.
[0038] Besides, the whole loudspeaker diaphragm 1 including the unfoamed skin layers 2 is
provided within average foaming magnifications of approximately 1.1-3.0 so that the
dispersion in the properties of the loudspeaker diaphragm 1 can be diminished by effectively
using the features of higher rigidity and higher internal loss resulting from the
foaming.
[0039] Moreover, as mentioned above, the skin layers 2 are provided in a thickness of approximately
0.05-0.20 mm to make the properties of the loudspeaker diaphragm 1 well balanced.
[0040] Furthermore, immediately after the resin mixture material containing the foaming
agent is injected into the cavity of the mold 20, the mold 20 is separated at a high
speed so that the foam cells in the foamed layer 3 are oriented along the total thickness
direction to reinforce the skin layers 2, thereby slowing the decrease of Young's
modulus and boosting the increasing rate of rigidity.
[0041] This embodiment has been described the case of a producing method in which the loudspeaker
diaphragm 1 is formed in a sandwich structure of the skin layers 2 and the foamed
layer 3 by the mold opening immediately after the resin mixture material of PP containing
the foaming agent is injected into the cavity of the mold 20. However, the present
invention is not limited thereto, but may be embodied using a producing method in
which, for example, the resin mixture material is injection molded at temperatures
for keeping the foaming agent unfoamed before the resin mixture material is heated
to foam at temperatures above the decomposing temperature of the foaming agent in
a mold such as a hot press mold or a vacuum forming mold.
[0042] While there has been described what are at present considered to be preferred embodiments
of the invention, it will be understood that various modifications may be made thereto,
and it is intended that the appended claims cover all such modifications as fall within
the true spirit and scope of the invention.
1. A loudspeaker diaphragm (1) of an injection foam molded body, wherein the diaphragm
is formed in a three layer structure composed of a foamed layer (3) at the inside
thereof and unfoamed layers (2) at the surfaces thereof by injection molding a resin
containing a foaming agent, characterized in that the resin contains an inorganic or organic filler.
2. The diaphragm (1) according to claim 1,
wherein the inorganic or organic filler is contained in an amount of 3 to 30 % by
weight.
3. The diaphragm (1) according to claim 1 or 2,
wherein a foaming magnification of the foamed layer (3) is 1.1 to 3.0.
4. The diaphragm (1) according to any of claims 1 to 3,
wherein each of the unfoamed layers (2) has a thickness of approximately 1/3 of the
total thickness of the molded body before foaming.
5. The diaphragm (1) according to any of claims 1 to 4,
wherein the thickness of the respective unfoamed layer (2) is 0.05 to 0.20 mm.
6. The diaphragm (1) according to any of claims 1 to 5,
wherein the resin used for making the diaphragm is polypropylene.
7. The diaphragm (1) according to any of claims 1 to 6,
wherein the filler is an inorganic filler selected from the group comprising silica;
diatomaceous earth; oxides such as alumina, titanium oxide, iron oxide, zinc oxide,
and magnesium oxide; hydroxides such as aluminum hydroxide, calcium hydroxide, and
basic magnesium carbonate; carbonates such as calcium carbonate, magnesium carbonate,
and dolomite; sulphates and sulphites auch as calcium sulphate, barium sulphate, and
calcium sulphite; talc; clay; mica (phlogopite, biotite, muscovite, and the like);
asbestos; glass fibers; glass balloon; glass beads; silicates such as calcium silicate,
montmorillonite, and bentonite; and silicon carbide monocrystal, or an inorganic filler
selected from crystalline cellulose fine powders and urea resin fine powders or a
mixture thereof.