NAPHTHA AROMATIZATION PROCESS

Description

BACKGROUND OF THE INVENTION

Field of the Invention

[0001] The invention relates to a process for reforming a naphtha stream using a surface treated zeolite catalyst.

Description of Related Art

[0002] Naphtha streams emerging from petrochemical refining processes generally comprise a mixture of C₅ to C₁₃ hydrocarbons which include about 15 to 40 wt.% of C₆ to C₁₁ aromatic compounds and the balance mostly a mixture of c₅ to C₁₁ aliphatic hydrocarbons, including mixed paraffins and mixed olefins.

[0003] It is well known in the art that such streams may be subjected to catalytic reforming to further enhance the more valuable aromatics content of the naphtha. In a typical reforming process, naphtha is passed over an acidic, medium pore zeolite catalyst, such as ZSM-5, which may also contain one or more dehydrogenation metals such as noble metals, under reforming conditions which include a temperature of from 400 to 1000°F (204 to 540°C), pressures of 0.345 - 2.068 MPag (50-300 psig), weight hourly space velocity of 0.5-25 and in the optional presence of hydrogen (H₂ to oil mole ratio of about 0-10). In a typical reforming process, the reactions include dehydrogenation, dehydrocyclization, isomerization and hydrocracking. For example, the use of a zinc-modified ZSM-5 aluminosilicate as a reforming catalyst for light naphtha feedstock is disclosed by Fukase et al, "Catalysts in Petrochemical Refining and Petrochemical Industries 1995", 1996, pp 456-464.

[0004] The dehydrogenation reactions typically include dehydroisomerization of alkylcyclopentanes to aromatics, the dehydrogenation of paraffins to olefins, the dehydrogenation of cyclohexanes to aromatics and the dehydrocyclization of acyclic paraffins and acyclic olefins to aromatics. The aromatization of the n-paraffins to aromatics is generally considered to be the most important because of the high octane rating of the resulting aromatic product. The isomerization reactions include isomerization of n-paraffins to isoparaffins, the hydroisomerization of olefins to isoparaffins, and the isomerization of substituted aromatics. The hydrocracking reactions include the hydrocracking of paraffins and hydrodesulfurization of sulfur compounds in the feed stock.

[0005] Acidic zeolites of the HZSM-5 type are also well known catalysts for use in toluene disproportionation reactions wherein toluene or mixtures of toluene and methanol are fed over the catalyst under disproportionation/alkylation conditions. In many such processes, the catalyst is first treated with a silicon-containing compound or other material to reduce the surface acidity of the catalyst. This technique has been found to enhance selectivity of the disproportionation process towards the production of the more valuable para-xylene isomers, in contrast with the meta or ortho isomers. Examples of such processes are found in U.S. Patents 4,950,835, 5,321,183 and 5,367,099.

[0006] U.S. Patent 5,371,312 discloses a process for the conversion of hydrocarbons comprising passing a hydrocarbon stream over a zeolite which has been treated with an amino silane. When the conversion process is toluene disproportionation, the patent indicates that the catalyst may also contain a dehydrogenation metal such as platinum to reduce the amount of ethyl benzene by-product formed in the process.

[0007] In addition, U.S. Patent 5,202,513 discloses the use of a galloalumino silicate catalyst of the ZSM-5 type containing gallium as part of the crystal structure which is treated with an alkali hydroxide, used as a reforming catalyst for naphtha-type feeds.

[0008] In an article by Y.S. Bhat et al., Appl. Catal. A, 130 (1995) L1-L4, it is disclosed that n-pentane aromatization over an MFI catalyst which has been silylated by vapor deposition of an organosilicone compound gives increased selectivity towards para-xylene production.

[0009] WO 96/03209 discloses a reforming process wherein a C₅-C₉ paraffin or olefin feedstock is contacted under reforming conditions with a zeolite catalyst which has been modified with a platinum group component metal and a second metal selected from gallium, zinc, indium, iron, tin and boron. The publication indicates that the process leads to an increased yield of para-xylene and that the yield of para-xylene is further enhanced by pre-coking the catalyst prior to use in the reforming process.

[0010] One of the major drawbacks associated with the use of acidic medium pore zeolite catalysts in reforming process, as contrasted with disproportionation processes, is that an undesirable amount of molecular cracking takes place wherein a significant portion of molecules having 5 or more carbon atoms are degraded, rather than upgraded into more valuable products. As a result, quantities of low value C₁ to C₄ gases are produced, often in quantities of greater than about 25 wt.% of the initial naphtha feedstream.

[0011] Accordingly, it is an object of this invention to provide a process for reforming a naphtha feed using a modified zeolite catalyst wherein the quantity of low value C₁ to C₄ gas by-product produced in the process is markedly reduced.

[0012] Another object of the invention is to provide a process for reforming a naphtha feed using a modified zeolite catalyst wherein the para-xylene content of the C₈ aromatic product present in the reformate is produced in greater than an equilibrium-amount.

SUMMARY OF THE INVENTION

[0013] The present invention provides a process for reforming a naphtha hydrocarbon stream containing at least 25 wt.% of C₅ to C₉ aliphatic and cycloaliphatic hydrocarbons comprising contacting said stream under reforming conditions with a modified reforming catalyst comprising an intermediate pore size acidic aluminosilicate support impregnated with at least one dehydrogenation metal selected from the group consisting of gallium, zinc, indium, iron, tin and boron, and oxides or sulfides thereof, said catalyst modified by (a) contact of said impregnated aluminosilicate support with a Periodic Table Group IIA metal hydroxide or an organosilicon compound in an amount sufficient to neutralize at least a portion of the acid sites present on the surface of said support and (b) calcination of said support, the reformed naphtha product of said process containing less than 25 wt.% of C₁-C₄ gas.

[0014] The process of the invention provides a reformate product which on the one hand, contains a reduced content of low value C₁ to C₄ gases which are primarily the by-product of cracked C₄+ aliphatic and cycloaliphatic compounds while, on the other hand, maintaining a high yield of more valuable C₆ to C₉ aromatics in the reformate, and greater than equilibrium-amount yields of para-xylene in the C₈ aromatic component of the reformate.

DETAILED DESCRIPTION OF THE INVENTION

[0015] Zeolites which may be used as molecular sieve support material for the catalyst of the present invention include intermediate pore size zeolites having an average pore size in the range of about 5 to about 7 Angstroms and a SiO₂/Al₂O₃ ratio of at least 10. These include zeolites having a MFI, MEL, TON, MTT or FER crystalline structure. Preferred such zeolites include ZSM-5, silicalite (a high silica to alumina ratio form of ZSM-5), ZSM-11, ZSM-12, ZSM-21, ZSM-22, ZSM-23, ZSM-35 and ZSM-38, with ZSM-5 being most preferred. The zeolite is preferably used in its highly acidic form, e.g. HZSM-5. Where the zeolite, as synthesized, contains alkali or alkaline earth metal cations, these can be exchanged with ammonium cations, followed by calcination in air at 600°F (315°C) to 1000°F (540°C) by techniques well known in the art to produce the acid form of the zeolite.

[0016] The dehydrogenation metals may be incorporated into the zeolite structure by any suitable method such as impregnation (incipient wetness method) or by ion exchange.

[0017] In the preferred embodiment, the zeolite is impregnated with the metal by well known methods such as by contacting a solution of a metal salt dissolved in an aqueous or alcoholic medium with the zeolite particles for a period of time sufficient to allow the cations to penetrate the zeolite pore structure. Suitable salts include the chlorides and nitrates. After drying the resulting zeolite precursor, it is preferably calcined at temperatures of from 300°C to 600°C for a period of 1 to 6 hours. In most cases, the metal will be present in the zeolite structure in the form of the oxide. However, where the feed naphtha contains significant levels of sulfur, hydrogen sulfide may form under reforming conditions which may, in turn, react with the metal oxide to form at least some metal sulfide. Thus, the metal may be in the form of the oxide, the sulfide or mixtures of these during the reforming process. The preferred metal loading may range from about 0.1 to 10 wt.%, most preferably from about 0.5 to 5 wt.%.

[0018] In the preferred embodiment of the invention, the dehydrogenation metal present in the zeolite consists essentially of one or a mixture of gallium, zinc, indium, iron, tin or boron metal compounds, and does not contain a noble metal such as platinum, platinum/rhenium or platinum/iridium which tend to be more sensitive to deactivation by sulfur poisoning and/or coke build-up under reforming conditions. Thus, naphtha feedstreams containing 10 to 500 ppm of sulfur or sulfur-containing compounds need not necessarily be subjected to a dehydrosulfurization treatment prior to contact with the catalyst of this invention.

[0019] The aluminosilicate support impregnated with the dehydrogenation metal is then modified by contact of the support with a hydroxide of a Group IIA metal or an organosilicon compound in an amount sufficient to neutralize at least a portion of the acid sites present on the surface of the support, after which the catalyst is dried and calcined in air to provide the modified catalyst of this invention. The term "neutralized" as used herein is intended to mean not only chemical neutralization of the support such as displacement of H⁺ cations by alkaline earth metal ions, but also blocking of surface H⁺ cations by silicon compounds deposited on the surface of the support and within the channels of the support.

[0020] Where the neutralizing agent is a Group IIA metal hydroxide, the aluminosilicate support may be modified by dispersing the aluminosilicate in an about 0.1 to 2 normal aqueous solution of the hydroxide for a period of from about 0.2 to 1 hour. Preferably the dispersion is heated at 25°C up to reflux temperature for a period of about 1/2 to one hour. Thereafter, the modified aluminosilicate is separated from the solution, dried and calcined in air at a temperature of up to 1000°C, preferably from about 300°C to 600°C for a period of 1 to 24 hours.

[0021] Organosilicon compounds which may be used to modify the catalyst include compounds selected from the group consisting of silanes, silicones, and alkylsilicates. Suitable silanes include alkoxy silanes such as tetramethoxy or tetraethyoxy silane. Suitable silicones and silicone polymers include compounds having the formula -[R₁R₂SiO]_n wherein R₁ and R₂ are the same or different C₁ to C₄ alkyl groups, phenyl groups, halogen, hydrogen, hydroxy, alkoxy, aralkyl and the like with at least one of R₁ or R₂ being an organic group, and n ranges from 2 to 1,000. Examples of preferred silicones include dimethylsilicone, copolymers of dimethylsiloxane and a lower alkylene oxide such as ethylene oxide, diethylsilicone, methyl hydrogen silicone and the like. Suitable alkyl silicates include C₁ to C₄ alkyl silicates such as methyl silicate or ethyl silicate.

[0022] The silicon compound may be deposited on the surface of the aluminosilicate by any suitable method. For example, the silicon compound may be used in liquid heat form or may be dissolved or dispersed in a solvent or aqueous medium to form a solution, dispersion or emulsion, mixed with the aluminosilicate to form a paste, dried and calcined. This deposition process can be repeated one or more times to provide a more uniformly coated product. Alternatively, the silicon compound may be deposited on the aluminosilicate surface by well known vapor deposition techniques. The deposited silicon compound extensively covers and resides on the external surface of the aluminosilicate molecular sieve and on surfaces within the molecular sieve channels. The silicon treated aluminosilicate is then calcined in air at a temperature of up to 1000°C, preferably from 300°C to 600°C, for a period of 1 to 24 hours.

[0023] Neutralization methods as described above should be sufficient to neutralize at least about 50%, more preferably at least about 75%, and most preferably at least about 90% of the acidic sites present on the surface of the catalyst.

[0024] The zeolite may be used in the catalytic process in its crystalline particulate form or it may be combined with 50 to 90 wt.% of a binder material such a silica, alumina or various clay materials as is known in the art to form molded pellets or extrudates. A zeolite-bound ZSM-5-free extrudate can also be used in the process. The metal impregnation and/or silicon compound deposition process described above may be carried out before or after the zeolite is composited with the binder, preferably before.

[0025] As indicated above, the content of cracked C₁-C₄ paraffin gases produced in the naphtha reforming process of this invention is significantly lower than that produced in conventional naphtha reforming, generally less than 25 wt.% and often less than 20 wt.% of the reformate product.

[0026] Typical naphtha feeds which may be processed in accordance with this invention are refinery products containing at least about 25 wt.%, more usually at least about 35 wt.%, and most usually about 50 wt.% of C₅ to C₉ aliphatic and cycloaliphatic hydrocarbons such as olefins and paraffins, about 30 to 40 wt.% of C₆ to C₁₃ aromatics, of which at least 5 wt.%, more usually at least 10 wt.% constitutes C9+ aromatics and roughly 10 to 20 wt.% of which constitutes C₆-C₈ aromatics (BTX). These naphtha feeds may also contain 50 to 500 weight ppm sulfur and about 10 to 100 weight ppm of nitrogen compounds. The term "sulfur" as used herein refers to elemental sulfur as well as sulfur compounds such as organosulfides or heterocyclic benzothiophenes. Typical examples of aliphatic hydrocarbons present in the naphtha stream include paraffins such as n-hexane, 2-methylpentane, 3-methylpentane, n-heptane, 2-methylhexane, 3-methylhexane, 3-ethylpentane, 2,5-dimethylhexane, n-octane, 2-methylheptane, 3-ethylhexane, n-nonane, 2-methyloctane, 3-methyloctane and n-decane, as well as corresponding C₅ to C₉ cycloparaffins. Typical olefins include 1-hexene, 2-methyl-1-pentene, 1-heptene, 1-octene and 1-nonene. Aromatics include benzene, toluene, xylenes as well as C₉ to C₁₁ aromatics.

[0027] The naphtha is upgraded by passing it through one or more catalyst beds positioned in a reforming reactor. Suitable reforming conditions are as follows:

	General	Preferred
Temp (°C)	204-540	427-540
Press. (MPag) [psig]	0.069-2.07 [10-300]	0.345-2.068 [50-300]
WHSV	0.5-25	0.5-3
H2/oil mole ratio	0.10	1-10

[0028] The following examples are illustrative of the invention.

EXAMPLE 1

[0029] The catalyst modified in accordance with Examples 2 and 3 was prepared by impregnating 40.33 grams of calcined H+ZSM-5 powder with a solution of 2.76 grams of Zn(NO₃)₂ and 37.97 grams of water. After drying at 120°C for 2 hours, the catalyst precursor was calcined at 500°C for 4 hours to give a ZnO/HZSM-5 catalyst (ZnZSM-5).

EXAMPLE 2

[0030] 13.76 g of the ZnZSM-5 catalyst prepared in Example 1 was mixed with a solution of 4.77g of tetraethyl orthosilicate (ethyl silicate) dissolved in 9g of n-heptane. The wet paste was dried at ambient conditions for 4 hours, pelletized to 1.05 - 0.37 mm (16/45 mesh) and calcined at 500°C with 502 ml/min air flow rate for 8 hours to yield a silica coated, modified ZnZSM-5 catalyst [Si]ZnZSM-5.

EXAMPLE 3

[0031] A mixture of 20.46g of the ZnZSM-5 catalyst prepared in Example 1, 0.59g of barium hydroxide and 200 ml. of water were heated under reflux for 0.5 hour. After centrifuging, the wet solid was dried in a vacuum at 50°C for 5 hours and at 120°C for 3 hours. The dried product was pelletized to 1.05 - 0.37 mm (16/45 mesh) and calcined in air at 500°C for 2.5 hours to yield a barium neutralized ZnZSM-5 catalyst [Ba]ZnZSM-5.

EXAMPLES 4-6: EVALUATION OF CATALYSTS

[0032] The catalytic test was conducted in a fixed bed at reactor 476.7°C (890°F), 0.689 MPag (100 psig), 2 WHSV, 2 H₂/feed and using a C₅- 105°C (221°F) CAT naphtha as the feed. The CAT naphtha feed contained 460 ppm sulfur, 76 ppm nitrogen, 38.1 wt.% paraffins, 11.4 wt.% cycloparaffins, 16.1 wt.% olefins and 34.4 wt.% aromatics. The experimental results of these tests are as shown in Table 1.

Table 1

				―			% Yield at 21 hr			―
EX	CATALYST	FEED CONV.	A6	A7	A8	A9	A10	C2=	C3=	C4=	C5-C9	GAS (C1--C4)
4	ZnZSM-5	88.5	7.1	19.5	16.3	4.6	1.0	0.4	0.7	0.3	7.1	42.9
5	[Si]ZnZSM-5	45.3	2.2	10.7	14.9	13.6	5.3	1.5	3.8	4.7	33.4	9.9
6	[Ba]ZnZSM-5	57.8	3.2	11.8	17.6	10.9	1.7	1.5	3.9	4.0	25.8	19.6

[0033] As can be seen in the results of Table 1, coating or neutralizing the ZnZSM-5 reduced the gas make to 9.9 or 19.6 wt.%, respectively, down from 42.9 wt.% achieved using the non-modified catalyst, while maintaining a 45 to 47 wt.% aromatics yield.

Example 7

[0034] The ZnZSM-5 catalyst from Example 1 (25.93 g) was mixed with a dimethylsiloxane-ethylene oxide copolymer (30.64 g) in neat, liquid form at room temperature for 1 hr and dried in vacuum at 60°C for 4 hr and then calcined at 530°C for 8 hr to give a one time silica coated ZnZSM-5 catalyst [i.e.(Si)ZnZSM-5]. The above procedure was repeated 3 more times to give a 4x(Si)ZnZSM-5 catalyst.

Examples 8-9

[0035] The CAT naphtha used in Examples 4-6 was reformed over the non-silica containing catalyst prepared in Example 1 and the silica-containing catalyst as prepared in Example 7 under the following conditions: 0.345 MPag (50 psig), 500°C, 2 WHSV and 4 H₂/molar feed ratio. Results are shown in Table 2.

Table 2

		Yield (wt.%) at 21 hr
Example	Catalyst	A6	A7	A8	A9	A10	Olefins1	C5-C92	C1-C42
8	ZnZSM-5	8.7	25.0	19.9	4.7	1.1	2.7	3.1	34.8
9	4x(Si)Zn ZSM-5	6.4	23.4	19.7	3.7	1.8	9.8	11.7	23.5

1. C2-C4 light olefins

2. Paraffins

[0036] The results of Table 2 show a marked decrease in the production of C₁ to C₄ paraffin gas and increase in the production of more valuable olefins and C₅-C₉ paraffins associated with the use of the silicon treated catalyst (Ex. 9) vs. the non-treated catalyst (Ex. 9).

Examples 10-11

[0037] Examples 8 and 9 were repeated except that the naphtha stream used was a light virgin C₅-C₁₂ naphtha containing 81 wt.% paraffins and 19 wt.% of aromatics. Reforming was conducted under the following low pressure conditions: 0.069 MPag (10 psig), 527°C, 2 WHSV and 4 H₂/molar feed ratio. Results are shown in Table 3.

Table 3

		Yield (wt.%) at 1 hr
Example	Catalyst	A6	A7	A8	A9	A10	Olefins1	C5-C92	C1-C42
10	ZnZSM-5	16.3	29.0	16.4	1.8	0.3	0.6	7.1	28.5
11	4x(Si)ZnZ SM-5	11.7	19.5	11.1	2.5	0.4	19.2	15.8	19.8

[0038] Once again the data in Table 3 shows that the catalyst of the invention gives rise to marked reduction in the content of C₁-C₄ paraffin gases and an enhancement of the light olefin and C₅-C₉ paraffin content of the reformate.

[0039] Another advantage associated with the use of the catalysts of this invention as naphtha reforming catalysts is that the catalyst is more highly selective towards the production of the para-xylene component of the mixed C₈ aromatics product produced of the four main C₈ products, para-xylene is considerably more valuable as a chemical intermediate than ethyl benzene or the meta and ortho-xylene isomers. Para-xylene occurs in approximately equilibrium amounts, about 20 to 25 wt.%, depending on the temperature, in the C₈ aromatics fraction of a typical reformate stream produced using conventional noble metal-containing catalysts or using ZSM-5 catalysts modified with a dehydrogenation metal such as zinc. Reformate produced using the neutralized catalysts of this invention contains a C₈ aromatic fraction which can have a content of para-xylene considerably higher than the equilibrium amount, as illustrated in Example 12 below.

Example 12

[0040] The liquid products from Examples 8-11 were analyzed by GC to determine the distribution of C₈- aromatics as shown in below:

Ex. No.	Temp. (°F)	% of Isomer in A Product
		EB	MX	PX	OX
8	500	10.3	46.2	22.7	20.8
9	500	11.5	37.3	32.8	18.4
Equilibrium	500	10.2	46.5	20.9	22.4
10	527	1.0	51.1	23.4	24.5
11	527	12.3	28.6	42.9	16.2
Equilibrium	527	10.8	46.0	20.7	22.5

[0041] The above data clearly demonstrates that the silica coated ZnZSM-5 catalyst produced 157% and 207% of the equilibrium p-xylene in Example 9 and 11 respectively.

Claims

1. A process for reforming a naphtha hydrocarbon stream containing at least 25 wt.% of C₅ to C₉ aliphatic and cycloaliphatic hydrocarbons comprising contacting said stream under reforming conditions with a modified reforming catalyst comprising an intermediate pore size acidic aluminosilicate support impregnated with at least one dehydrogenation metal selected from the group consisting of gallium, zinc, indium, iron, tin and boron, and oxides or sulfides thereof, said catalyst modified by (a) contact of said impregnated aluminosilicate support with a Periodic Table Group IIA metal hydroxide or an organosilicon compound in an amount sufficient to neutralize at least a portion of the acid sites present on the surface of said support and (b) calcination of said support, the reformed naphtha product of said process containing less than 25 wt.% of C₁-C₄ gas.

2. The process recited in Claim 1 wherein said aluminosilicate support comprises a zeolite having a MFI, MEL, TON, MTT or FER crystalline structure.

3. The process recited in Claim 1 or 2 wherein said aluminosilicate support is a ZSM-5 zeolite.

4. The process recited in any preceding Claim wherein said dehydrogenation metal is zinc.

5. The process recited in any preceding Claim wherein said catalyst is modified by contact with a Group IIA metal hydroxide.

6. The process recited in any preceding Claim wherein said aluminosilicate support is combined with a binder material selected from the group consisting of silica, alumina, clay or zeolite to form catalyst pellets.

7. The process recited in any preceding Claim wherein said Group IIA metal is selected from the group consisting of barium, calcium and magnesium.

8. The process recited in any preceding Claim wherein said catalyst is modified by contact with an organosilicon compound.

9. The process recited in any preceding Claim wherein said organosilicon compound is selected from the group consisting of silanes, silicones, and alkyl silicates.

10. The process recited in any preceding Claim wherein at least 50% of the acid sites present on the surface of said support are neutralized.

11. The process recited in any preceding Claim wherein said reforming conditions comprise a temperature of 205 to 540°C, a pressure of 0.069 - 2.07 MPag (10-300 psig), a weight hourly space velocity of 0.5-25 and a hydrogen to hydrocarbon molar ratio of 0 to 10.

12. The process recited in any preceding Claim wherein said naphtha stream contains at least 35 wt.% of said C₅ to C₉ aliphatic and cycloaliphatic hydrocarbons.

13. The process recited in any preceding Claim wherein the reformed naphtha product of said process contains less than 20 wt.% of C₁ to C₄ gas.

14. The process recited in any preceding Claim wherein the reformed naphtha product of said process contains a C₈ aromatic product containing at least 25 wt.% more than the equilibrium amount of para-xylene.

Ansprüche

1. Verfahren zum Reformieren eines Naphthakohlenwasserstoffstroms, der mindestens 25 Gew.% aliphatische und cycloaliphatische C₅- bis C₉-Kohlenwasserstoffe enthält, bei dem der Strom unter Reformierbedingungen mit modifiziertem Reformierkatalysator kontaktiert wird, der sauren Aluminiumsilikatträger mit mittlerer Porengröße umfasst, der mit mindestens einem Dehydriermetall ausgewählt aus der Gruppe bestehend aus Gallium, Zink, Indium, Eisen, Zinn und Bor sowie Oxiden oder Sulfiden davon imprägniert ist, wobei der Katalysator durch (a) Kontakt des imprägnierten Aluminiumsilikatträgers mit Hydroxid von Metall der Gruppe IIA des Periodensystems oder Organosiliciumverbindung in einer ausreichenden Menge, um mindestens einen Teil der auf der Oberfläche des Trägers vorhandenen Säurestellen zu neutralisieren, und (b) Calcinieren des Trägers modifiziert worden ist, wobei das reformierte Naphthaprodukt des Verfahrens weniger als 25 Gew.% C₁- bis C₄-Gas enthält.

2. Verfahren nach Anspruch 1, bei dem der Aluminiumsilikatträger Zeolith mit MFI-, MEL-, TON-, MTT- oder FER-Kristallstruktur umfasst.

3. Verfahren nach Anspruch 1 oder 2, bei dem der Aluminiumsilikatträger ZSM-5-Zeolith ist.

4. Verfahren nach einem der vorhergehenden Ansprüche, bei dem das Dehydriermetall Zink ist.

5. Verfahren nach einem der vorhergehenden Ansprüche, bei dem der Katalysator durch Kontakt mit Hydroxid von Metall der Gruppe IIA modifiziert ist.

6. Verfahren nach einem der vorhergehenden Ansprüche, bei dem der Aluminiumsilikatträger mit Bindemittelmaterial ausgewählt aus der Gruppe bestehend aus Siliciumdioxid, Aluminiumoxid, Ton oder Zeolith unter Bildung von Katalysatorpellets kombiniert wird.

7. Verfahren nach einem der vorhergehenden Ansprüche, bei dem das Metall der Gruppe IIA ausgewählt ist aus der Gruppe bestehend aus Barium, Calcium und Magnesium.

8. Verfahren nach einem der vorhergehenden Ansprüche, bei dem der Katalysator durch Kontakt mit Organosiliciumverbindung modifiziert ist.

9. Verfahren nach einem der vorhergehenden Ansprüche, bei dem die Organosiliciumverbindung ausgewählt ist aus der Gruppe bestehend aus Silanen, Silikonen und Alkylsilikaten.

10. Verfahren nach einem der vorhergehenden Ansprüche, bei dem mindestens 50 % der auf der Oberfläche des Trägers vorhandenen Säurestellen neutralisiert werden.

11. Verfahren nach einem der vorhergehenden Ansprüche, bei dem die Reformierbedingungen eine Temperatur von 205 bis 540°C, einen Druck von 0,069 bis 2,07 MPa Überdruck (10 bis 300 psig), einen stündlichen Massendurchsatz von 0,5 bis 25 und ein Molverhältnis von Wasserstoff zu Kohlenwasserstoff von 0 bis 10 umfassen.

12. Verfahren nach einem der vorhergehenden Ansprüche, bei dem der Naphthastrom mindestens 35 Gew.% der aliphatischen und cycloaliphatischen C₅- bis C₉-Kohlenwasserstoffe enthält.

13. Verfahren nach einem der vorhergehenden Ansprüche, bei dem das reformierte Naphthaprodukt des Verfahrens weniger als 20 Gew.%- C₁- bis C₄-Gas enthält.

14. Verfahren nach einem der vorhergehenden Ansprüche, bei dem das reformierte Naphthaprodukt des Verfahrens aromatisches C₈-Produkt enthält, das mindestens 25 Gew.% mehr als die Gleichgewichtsmenge para-Xylol enthält.

Revendications

1. Procédé de reformage d'un courant de naphta contenant au moins 25 % en poids d'hydrocarbures aliphatiques et cycloaliphatiques en C₅ à C₉, comprenant la mise en contact dudit courant dans des conditions de reformage avec un catalyseur de reformage modifié, comprenant un support consistant en aluminosilicate acide de diamètre des pores intermédiaire imprégné d'au moins un métal de déshydrogénation choisi dans le groupe consistant en le gallium, le zinc, l'indium, le fer, l'étain et le bore et leurs oxydes ou sulfures, ledit catalyseur étant modifié par (a) contact dudit support consistant en aluminosilicate imprégné avec un hydroxyde de métal du Groupe IIA du Tableau Périodique ou un composé organique de silicium en quantité suffisante pour neutraliser au moins une partie des sites acides présents à la surface dudit support et (b) calcination dudit support, le produit consistant en naphta reformé dudit procédé contenant moins de 25 % en poids de gaz en C₁ à C₄.

2. Procédé selon la revendication 1, dans lequel ledit support consistant en aluminosilicate comprend une zéolite possédant une structure cristalline MFI, MEL, TON, MTT ou FER.

3. Procédé selon la revendication 1 ou 2, dans lequel ledit support consistant en aluminosilicate est une zéolite ZSM-5.

4. Procédé selon l'une quelconque des revendications précédentes, dans lequel ledit métal de déshydrogénation est le zinc.

5. Procédé selon l'une quelconque des revendications précédentes, dans lequel ledit catalyseur est modifié par contact avec un hydroxyde de métal du Groupe IIA.

6. Procédé selon l'une quelconque des revendications précédentes, dans lequel ledit support consistant en aluminosilicate est combiné avec un liant choisi dans le groupe consistant en la silice, l'alumine, l'argile ou une zéolite, pour former des pastilles de catalyseur.

7. Procédé selon l'une quelconque des revendications précédentes, dans lequel ledit métal du Groupe IIA est choisi dans le groupe constitué du baryum, du calcium et du magnésium.

8. Procédé selon l'une quelconque des revendications précédentes, dans lequel ledit catalyseur est modifié par contact avec un composé organique de silicium.

9. Procédé selon l'une quelconque des revendications précédentes, dans lequel ledit composé organique de silicium est choisi dans le groupe constitué de silanes, silicones et silicates d'alkyle.

10. Procédé selon l'une quelconque des revendications précédentes, dans lequel au moins 50 % des sites acides présents à la surface dudit support sont neutralisés.

11. Procédé selon l'une quelconque des revendications précédentes, dans lequel lesdites conditions de reformage comprennent une température de 205 à 540 °C, une pression de 0,069 à 2,07 MPag (10 à 300 psig), une vitesse spatiale horaire pondérale de 0,5 à 25 et un rapport molaire entre hydrogène et hydrocarbure de 0 à 10.

12. Procédé selon l'une quelconque des revendications précédentes, dans lequel ledit courant de naphta contient au moins 35 % en poids desdits hydrocarbures aliphatiques et cycloaliphatiques en C₅ à C₉.

13. Procédé selon l'une quelconque des revendications précédentes, dans lequel le produit consistant en naphta reformé dudit procédé contient moins de 20 % en poids de gaz en C₁ à C₄.

14. Procédé selon l'une quelconque des revendications précédentes, dans lequel le produit consistant en naphta reformé dudit procédé contient un produit aromatique en C₈ contenant au moins 25 % en poids de plus que la quantité à l'équilibre de paraxylène.