Background of the Invention
(1) Field of the Invention
[0001] The present invention relates to a trap apparatus for installing an air conditioner
and particularly for connecting an indoor unit and an outdoor unit using connecting
pipes.
(2) Description of the Prior Art
[0002] Conventionally, an air conditioner is installed in such a manner that more than prescribed
amount of refrigerant gas is charged into an outdoor unit for purging air; the air
in the connecting pipes and an indoor unit is purged by the refrigerant gas introduced
from a liquid-side two-way valve, and the refrigerant gas is discharged into the atmosphere
from a valve called a service port of a gas-side three-way valve.
[0003] Further, conventionally, the air conditioner is installed in such a manner that after
the connecting pipes and the indoor unit are brought into a sufficiently evacuated
state using a vacuum pump from the valve called the service port of the gas-side three-way
valve, the refrigerant gas is introduced into the connecting pipes and the indoor
unit from the liquid-side two-way valve.
[0004] However, environmental regulations against destruction of the ozone layer, global
warming and the like are becoming strict in recent years; and discharging refrigerant
gas having high ozone layer destroying coefficient or high global warming coefficient
into the atmosphere when the air conditioner is installed is becoming a problem.
[0005] An installing method using a vacuum pump is recommended as an installing method which
does not discharge the refrigerant gas. However, it is difficult to use the vacuum
pump in the installing places having bad installation conditions such as on a roof.
[0006] Further, the installing method using the vacuum pump takes more time to install the
air conditioner as compared with a method using the conventional purging method using
refrigerant gas of the outdoor unit and discharging the refrigerant gas into the atmosphere.
[0007] The present invention has been accomplished in view of the problems that conventional
methods had;, and it is an object of the invention to provided an easy apparatus for
installing an air conditioner while taking an influence on environment into consideration.
[0008] Document US 5 718 119 describes a refrigeration system which includes an outdoor
unit having a refrigeration compressor and a heat exchanger, and an indoor unit having
a heat exchanger to be placed where air conditioning is desired. In installing the
refrigeration system, the outdoor unit is first connected with the indoor unit via
pipe lines, and an air absorbing device containing zeolite as an adsorbent is subsequently
placed on the outdoor unit, the indoor unit, or the pipe lines to remove air.
[0009] The air absorbing device is then separated from the refrigeration system, and refrigerant
is caused to circulate through the refrigeration system.
[0010] Subject matter of document JP 05 13 79 36 is a gas adsorbent and its method of production,
wherein thin plastic sheets of a molecular sieve and elastic bags are alternately
superposed and the molecular sieve is formed into a honeycomb shape by inflating the
bags by pressurisation to obtain a gas adsorbent. An electric resistance wire may
be inserted into the honeycomb-shaped gas adsorbent. The purpose of subject matter
of document
[0011] JP 05 13 79 36 is a production of a gas adsorbent having a large surface area and
high structural strength, hardly causing pressure drop and capable of efficiently
adsorbing and desorbing gas.
Disclosure of the Invention
[0012] To achieve the above and other objectives, according to the present invention, there
is provided a trap apparatus as claimed in claim 1.
[0013] According to this mode, the inside pressure is held at positive pressure when air
is replaced by carbon dioxide. Therefore, when the inside pressure is brought into
communication with the trap apparatus next, the positive pressure state of the inside
becomes a trigger of convection of gas, the carbon dioxide is swiftly absorbed by
the zeolite in the trap apparatus, and the carbon dioxide can be collected swiftly.
[0014] Further, according to the present invention, in the above trap apparatus for installing
an air conditioner, the structure body is a honeycomb structure body. With this mode,
it is possible to increase the contact area with the carbon dioxide, and to speed
up the collection of the carbon dioxide.
[0015] Further, according to the present invention, there is provided a trap apparatus for
installing an air conditioner comprising a structure body constructed with carriers
which are coated with a layer mainly made of calcium hydroxide. With this mode, since
calcium hydroxide exists on the surface of the structure body, it is possible to increase
the contact area for the chemical reaction with carbon dioxide.
[0016] Further, according to the present invention, in the above trap apparatus for installing
an air conditioner, the structure body is a honeycomb structure body. With this mode,
it is possible to increase the contact area for the chemical reaction with carbon
dioxide, and to prevent the flow path from being impaired by volume expansion at the
time of the chemical reaction.
[0017] Further, according to the present invention, in the above trap apparatus for installing
an air conditioner, water in the amount of 0.1 to 10 wt% of calcium hydroxide is included.
With this mode, by adding a small amount of water to calcium hydroxide, this becomes
a catalytic trigger, and the chemical reaction speed from the calcium hydroxide to
calcium carbonate can be accelerated, thereby, collection speed will be increased.
[0018] Further, according to the present invention, in the above trap apparatus for installing
an air conditioner, the calcium hydroxide is mixed with at least one of zeolite, activated
alumina and silica gel to form the coating layer. With this mode, it is possible to
hold water by zeolite, activated alumina or silica gel, and this water becomes a catalytic
trigger, and the chemical reaction speed from the calcium hydroxide to calcium carbonate
can be accelerated, thereby, collection speed will be increased.
[0019] Further, according to the present invention, in the above trap apparatus for installing
an air conditioner, a heat radiating portion or a cooling portion or radiating fins
are provided outside the trap apparatus with this mode, reaction heat generated by
the abrupt chemical reaction can efficiently be transmitted and diffused outside,
and it is possible to prevent the reaction speed from being lowered.
Brief Description of the Drawings
[0020]
Fig.1 is a block diagram of a refrigeration cycle of an air conditioner used in an
embodiment of the present invention to which a carbon dioxide cylinder is connected;
Fig.2 is a block diagram of the refrigeration cycle of the air conditioner used in
an embodiment of the present invention to which a trap apparatus is connected;
Fig.3 is a schematic view of a trap apparatus according to a first example of the
invention which is not subject to the claims;
Fig. 4 is a schematic view of a trap apparatus according to a second example of the
invention which is not subject to the claims;
Fig.5 is a schematicviewof trap apparatus according to a first embodiment;
Fig.6 is a sectional view taken along the line A-A in Fig.5;
Fig.7 is an enlarged sectional view of an essential portion of an inside structure
body in Fig.6;
Fig.8 is a schematic view of a trap apparatus according to a second embodiment;
Fig.9 is a sectional view taken along the line A-A in Fig.8;
Fig.10 is an enlarged sectional view of an essential portion of an inside structure
body in Fig.8; and
Fig.11 is a graph showing the relation between weight of zeolite charged in the trap
apparatus and pressure after ten minutes as a third example of the invention which
is not subject to the claims.
Description of the Preferred Embodiments
[0021] Embodiments of the present invention will be explained with reference to the drawings
below.
[0022] Figs.1 and 2 are block diagrams of a refrigeration cycle of an air conditioner used
in the embodiment. Fig.1 shows a state where a carbon dioxide cylinder is connected,
and Fig.2 shows a state where a trap apparatus is connected.
[0023] First, the entire structure of the refrigeration cycle constituting the air conditioner
will be explained using Figs.1 and 2.
[0024] The refrigeration cycle comprises a compressor 1, a four-way valve 2, an outdoor
unit heat exchanger 3, an expansion device 4, a dryer S and an indoor unit heat exchanger
6. The compressor 1, the four-way valve 2, the outdoor unit heat exchanger 3, the
expansion device 4 and the dryer 5 are disposed in an outdoor unit A, and the indoor
unit heat exchanger 6 is disposed in an indoor unit B.
[0025] The outdoor unit A is provided with a liquid-side two-way valve 7 and a gas-side
three-way valve 8. The outdoor unit A and the indoor unit B are connected to each
other through connection pipes 9 and 10 using the liquid-side two-way valve 7 and
the gas-side three-way valve 8. The liquid-side two-way valve 7 includes a screw portion
7a, and a pipe on the side of the outdoor unit A and a connecting pipe 9 are brought
into communication with each other by opening the screw portion 7a. The gas-side three-way
valve 8 includes a screw portion 8a and a service port 8b, and a pipe on the side
of the outdoor unit A and a connecting pipe 10 are brought into communication with
each other by opening this screw portion 8a.
[0026] As shown in Fig.1, a carbon dioxide cylinder 11 can be connected to the service port
8b using a connecting device 12, or as shown in Fig. 2, a trap apparatus 13 can be
connected to the service port 8b using a connecting device 14. The carbon dioxide
cylinder 11 or the trap apparatus 13 can be brought into communication with a connecting
pipe 10 through the connecting device 12 or 14.
[0027] Next, an embodiment of the trap apparatus which can be used in the present invention
will be explained using Figs.3 to 7.
[0028] Fig.3 is a schematic view of the trap apparatus according to the first embodiment.
[0029] Spherical shape zeolite particles 15A and 15B are charged in the trap apparatus 13A.
The zeolite particles 15A have 6 to 8 mesh diameter, and the zeolite particles 15B
have 4 to 6 mesh diameter. The trap apparatus 13A is provided therein with a baffle
16 for separating an inlet C and the zeolite particles 15A so that the zeolite particles
15A and 15B are securely held. This baffle 16 has holes of such diameters that the
zeolite particles 15A and 15B cannot pass through. In the present embodiment, an opening
ratio is set to 60%.
[0030] As shown in Fig.3, in the trap apparatus 13A of the present embodiment, the zeolite
particles 15A having greater diameter are charged closer to the inlet C, and the zeolite
particles 15B having smaller diameter is charged in the deep side of the trap apparatus
13A. With this layout, it is possible to form a flow path space which is greater on
the side of the inlet C than that of the bottom side. In the present embodiment, 100g
of zeolite particles 15A and 15B in total were charged.
[0031] Fig.4 is a schematic view of the trap apparatus according to the second embodiment.
[0032] Hollow cylindrical zeolite particles 15C are charged in the trap apparatus 13B. The
zeolite particles 15C has size of φ5×7mm, and thickness of 2mm. The trap apparatus
13B is provided therein with the baffle 16 for separating the inlet C and the zeolite
particles 15C so that the zeolite particles 15C is securely held. In the present embodiment
also, the opening ratio is set to 60%.
[0033] As shown in Fig.4, the hollow cylindrical zeolite particles 15C are charged in the
trap apparatus 13B. Therefore, the flow path space can be enlarged, and the contact
area can be increased. In the present embodiment, 100g of zeolite particles 15C were
charged in total.
[0034] Figs.5 to 7 show a trap apparatus according to the third embodiment. Fig.5 is a schematic
view of the trap apparatus used in the third embodiment, Fig. 6 is a sectional view
taken along the line A-A in Fig.5, and Fig.7 is an enlarged sectional view of an essential
portion of an inside structure body in Fig.6.
[0035] A trap apparatus 13C is provided therein with a honeycomb structure body 17. The
honeycomb structure body 17 has 400 cells/inch
2 (see Fig.6), and volume of 70φ ×90mm; and is coated on its surface with a coating
layer 15D that is mainly made of zeolite in the amount of 100g in total.
[0036] Figs.8 to 10 show the fourth embodiment. Fig.8 is a schematic view of a trap apparatus
according to the fourth embodiment, Fig.9 is a sectional view taken along the line
A-A in Fig.8, and Fig.10 is an enlarged sectional view of an essential portion of
an inside structure body in Fig.8.
[0037] A trap apparatus 13D is provided therein with a honeycomb structure body 18. An outer
periphery of a body of the trap apparatus 13D is provided with radiating fins 19.
The honeycomb structure body 18 has 200 cells/inch
2 (see Fig.9), and volume of 50φ×65mm.
[0038] The honeycomb structure body 18 is coated on its surface with a coating layer 18A
which is mainly made of calcium hydroxide in the amount of 10g in total. More specifically,
the coating layer 18A is made of 90 wt% of calcium hydroxide, and 10 wt% of A-type
zeolite. The A- type zeolite which easily absorbs water is allowed to hold 10 wt%
of water.
[0039] Chemical reaction from calcium hydroxide to calcium carbonate occurs very rapidly,
and a small amount of water is required as a catalytic trigger at that time. In order
to allow water to effectively act as the trigger, it is preferable to mix the calcium
hydroxide with a material which easily holds water, and the A-type zeolite is used
in the present embodiment.
[0040] During the chemical reaction from calcium hydroxide to calcium carbonate, since high
reaction heat is generated, it is necessary to diffuse this heat to the outside, and
the radiating fins 19 are provided in the present embodiment.
[0041] As in the present embodiment, since the zeolite is mixed in the coating layer 18A,
the water held by the zeolite is less prone to be disassociated even if abrupt reaction
heat is generated, and therefore, it acts effectively as a catalytic trigger.
[0042] Next, a method for installing the air conditioner will be explained in reference
to figs. 1 and 2.
[0043] Before the air conditioner is installed, refrigerant gas is charged in the outdoor
unit A including in the compressor 1 as well as in the outdoor heat exchange unit
3. At that time, in addition to the refrigerant gas which is necessary for operation,
the refrigerant gas to be used for purge operation is also charged in the outdoor
unit A. On the other hand, pipes in the indoor unit such as those in the indoor heat
exchanger 6 and the connecting pipes 9 and 10 are not hermetically sealed but are
opened to the atmosphere.
[0044] First, as shown Fig. 1, the outdoor unit A and the indoor unit B are connected through
the connecting pipes 9 and 10. At that time, a screw portion 7a of a liquid-side two-way
valve 7 and a screwportion 8a of agas-side three-way valve 8 are closed. The carbon
dioxide cylinder 11 is mounted to the service port 8b of the gas-side three-way valve
8 using the connecting device 12.
[0045] After the carbon dioxide cylinder 11 is mounted to the service port 8b, a flare portion
of the liquid-slide two-way valve 7 is slightly loosened. Then, the carbon dioxide
cylinder 11 is pushed against the connecting device 12 while being rotated, thereby
introducing the carbon dioxide contained in the carbon dioxide cylinder 11 into the
connecting pipe 10 and the indoor unit B and the connecting pipe 9. Air in the connecting
pipes 9 and 10 and the indoor unit B is discharged out into the atmosphere from the
loosened portion of flare portion of the liquid-side two-way valve 7 together with
the introduced carbon dioxide.
[0046] Thereafter, the flare portion of the liquid-side two-way valve 7 is tightly closed
keeping the pressure in the connecting pipes 9 and 10 and the indoor unit B at positive
pressure (about 0.1 kgf/cm
2).
[0047] Next, the connecting device 12 is removed from the service port 8b together with
the carbon dioxide cylinder 11.
[0048] Then, as shown in Fig.2, the trap apparatus 13 is mounted to the service port 8b
using the connecting device 14.
[0049] The trap apparatus 13 is mounted to the connection device 14 by being pushed to the
connection device 14 while being rotated. By this mounting operation, the interior
of the trap apparatus 13 is brought into communication with the connecting pipe 10.
[0050] By bringing the trap apparatus 13 into communication with the connecting pipe 10,
the carbon dioxide in the connecting pipes 9 and 10 and the indoor unit B is introduced
into the trap apparatus 13 through the service port 8b.
[0051] In the embodiments of the first to the third, the introduced carbon dioxide is physically
absorbed and collected by the zeolite in the trap apparatus 13, whereas in the fourth
embodiment, the introduced carbon dioxide becomes calcium carbonate by chemical reaction
with calcium hydroxide, and thereby, is collected.
[0052] After the carbon dioxide is collected, the screw portion 7a of the liquid-side two-way
valve 7 is slightly loosened, the refrigerant gas in the outdoor unit A is introduced,
thereby bringing the pressure in the connecting pipes 9 and 10 and the pipes in the
indoor unit B into positive pressure (about 0.2 kgf/cm
2).
[0053] Thereafter, the connecting device 14 is removed from the service port 8b together
with the trap apparatus 13, and the screw portion 7a of the liquid-side two-way valve
7 is completely opened.
[0054] Lastly, the screw portion 8a of the gas-side three-way valve 8 is also completely
opened, and the installation of the air conditioner is completed.
[0055] In the above embodiments, the volume of the pipe of the indoor unit B including the
indoor unit heat exchanger 6 and the connecting pipes 9 and 10 was 1.5 liters.
[0056] Using the trap apparatus 13A of the first embodiment shown in Fig.3, the above installing
operation was carried out.
[0057] As a result, the pressure in the pipe of the indoor unit B including the indoor unit
heat exchanger 6 and the connecting pipes 9 and 10 reached sufficient negative atmosphere
(10 mmHg or less) in four minutes.
[0058] Next, using the trap apparatus 13B of the second embodiment shown in Fig.4, the above
installing operation was carried out.
[0059] As a result, the pressure in the pipe of the indoor unit B including the indoor unit
heat exchanger 6 and the connecting pipes 9 and 10 reached sufficient negative atmosphere
(10 mmHg or less) in three minutes.
[0060] Next, using the trap apparatus 13C of the third embodiment shown in Figs.5 to 7,
the above installing operation was carried out.
[0061] As a result, the pressure in the pipe of the indoor unit B including the indoor unit
heat exchanger 6 and the connecting pipes 9 and 10 reached sufficient negative atmosphere
(10 mmHg or less) in two minutes.
[0062] Next, using the trap apparatus 13D of the fourth embodiment shown in Figs.8 to 10,
the above installing operation was carried out. As a result, the pressure in the connecting
pipes 9 and 10 and the pipe of the indoor unit reached a sufficient negative atmosphere
(50 mmHg or less) in three minutes.
[0063] When the above embodiments are compared, the honeycomb structure body coated with
zeolite, the third embodiment, reached the sufficient negative pressure fastest.
[0064] However, in the third embodiment, a trap apparatus body container required for accommodating
100g of zeolite is adversely increased in size as compared with those of the first
and second embodiments. The trap apparatus directly accommodating the spherical zeolite
particles as in the first embodiment was most compact. Therefore, it is preferable
to select a suitable trap apparatus while taking time required for installing operation
and a size of tool required for the operation into consideration.
[0065] In each of the embodiments, after the inside air was replaced by carbon dioxide,
next operation was carried out in a state where the pressure in each of the connecting
pipes 9, 10 and the pipe of the indoor unit B was kept at about 0.1 kgf/cm
2. The level of the positive pressure required at that time should be slightly positive
as compared with the atmospheric pressure, and it is preferable that this pressure
is 0.3 kgf/cm
2 or lower. With this pressure level, when the pipes are brought into communication
with the inside of the trap apparatus 13D, convection of gas is generated and carbon
dioxide can swiftly be collected. Further, even if the pressure is lower than the
atmospheric pressure, if the pressure is higher than a pressure in the trap apparatus
13, the same effect can be obtained. To achieve the same effect, the pressure in the
trap apparatus 13 can be set to negative pressure (e.g., 1 mmHg or lower) so that
the convection of gas from the connecting pipes 9, 10 and the pipe of the indoor unit
B to the trap apparatus 13 can be obtained.
[0066] Although the spherical zeolite particles were used in the first embodiment, the shape
of the zeolite particles may be oval spherical shape, and if the zeolite particles
are formed with bumps and dips so as to increase its surface area, higher effect can
be obtained. Further, although the spherical zeolite particles having different size
were used in the first embodiment, zeolite particles having different shape may be
used. In this case, it is preferable to dispose zeolite particles having greater surface
area at the place closer to the inlet.
[0067] In the third embodiment, a honeycomb structure body was used. The same effect can
be obtained if a corrugated structure body is used. A structure body which can be
used for the present invention should not be limited to the above embodiments, such
structure body is appropriate if it has sufficient communication holes from the inlet
to the bottom of the trap apparatus and zeolite can be supported on the surface or
inside of such structure body so as to have sufficiently great contact area. Further,
by employing the structure body such as honeycomb structure body or corrugated structure
body, the trap apparatus can be conveniently transported because even if an impact
is applied to the trap apparatus, the zeolite attached to the structure body is less
prone to be crushed into powder.
[0068] In the fourth embodiment, a honeycomb structure body was used. Here again, the same
effect can be obtained if a corrugated structure body is used. A structure body which
can be used for the present invention should not be limited to the above embodiments,
such structure body is appropriate if it has sufficient communication holes from the
inlet to the bottom of the trap apparatus and calcium hydroxide can be supported on
the surface or inside of such structure body so as to have sufficiently great contact
area for effective chemical reactions. Further, the structure body useable in this
embodiment should have such structure which does not cause gas passage impairment
even when the volume of the structure body is expanded due to the chemical reaction.
Further, in this embodiment, the radiation fins 19 are provided to the trap apparatus
13D. However, it is also effective if the inside heat generation is suppressed by
cooling from the outside. Affirmative cooling, for example, dipping the trap apparatus
partially in a water tank and blowing the air against the radiation fins 19, is effective.
[0069] In the first to third embodiments, although 100g of zeolite was used when the total
volume of the pipe of the indoor unit B and the connecting pipes 9 and 10 was 1.5
liters, the weight of zeolite with which the effect of these embodiments was achieved
was 60g or greater per one liter of the total volume of the pipe of the indoor unit
B and the connecting pipes 9 and 10. With this weight of zeolite, carbon dioxide was
trapped in two to five minutes and the negative pressure state of 10 to 30 mmHg was
obtained. Although there is no problem even if the amount of zeolite exceeds the above
value, if the zeolite is excessively increased, it is not preferable because the container
for accommodating the trap material becomes bulk. If the amount of zeolite is less
than 60g, the speed with which a pres sure reaches the suf f icient negative pressure
becomes slow, and one of the objects of the present invention may be sacrificed.
[0070] Fig.11 is a graph showing the relation between the weight of zeolite charged in the
trap apparatus and the pressure reached after ten minutes. In the experiment shown
in Fig.11, the pressure was measured when the volume of the pipe of the indoor unit
B and the connecting pipes 9 and 10 was 1.5 liters. Therefore, if the volume is 1
liter, sufficient effect should be obtained even with 60g or less of zeolite, but
since collection of carbon dioxide is hindered if water is absorbed, it is conceived
that 60 to 100g of zeolite per liter is practically preferable.
[0071] In the fourth embodiment, although 9g of calcium hydroxide was used when the volume
of the pipe of the indoor unit B and the connecting pipes 9 and 10 was 1.5 liters,
the weight of calcium hydroxide which could obtain the sufficient effect of the embodiment
was 6.6 to 16.5g. stoichiometry weight necessary for calcium hydroxide to trap 1.5
liters of carbon dioxide is 4.95g at 25C. Therefore, the weight of calcium hydroxide
per 1 liter of the volume of the pipe of the indoor unit B and the connecting pipes
9 and 10 is 3.30g. However, in the present invention, two to five times of calcium
hydroxide is necessary to collect the carbon dioxide swiftly. By using two to five
times of calcium hydroxide, the carbon dioxide was able to be collected in two to
five minutes and the negative pressure state of 10 to 50 mmHg level was obtained.
[0072] In the embodiment, the amount of water with respect to the calcium hydroxide was
1 wt%, but the amount of water applicable to the present invention was 0.1 to 10 wt%.
If the amount was less than 0.1 wt%, the amount of water is too small to effectuate
catalytic reaction trigger, and it took time to collect carbon dioxide. Further, if
the amount of water exceeds 10 wt%, water vapor was generated by chemical reaction;
and the vapor entered the connecting pipes, and it was not preferable in terms of
reliability. For purpose of holding water, zeolite was used in the present embodiment.
Similarly, as materials which can hold water and do not desorb water, activated alumina,
silica gel and the like was found applicable. As a factor of the applicable materials,
specific surface of 100m
2/g was preferable.
[0073] Although in connection with the explanation of the method for installing, the outdoor
unit having the normal two-way valve and three-way valve was used in the present embodiments,
the present invention can also be applied to an outdoor unit having a three-way valve
and another three-way valve. Further, although the installation was carried out using
two kinds connecting devices for the two-way valve, the connecting device may have
T-bifurcation shape; and carbon dioxide may be supplied from one of the connecting
portions, and the carbon dioxide can be collected from the other connecting portion.
It is preferable to commonly use the same connecting device.
[0074] In each of the above embodiments, a dryer 5 is disposed in the outdoor unit A. According
to an installing method using a vacuum pump, water existing in the indoor unit A and
the connecting pipes 9 and 10 can also be eliminated by increasing the operation time
of the vacuum pump, but it is difficult to sufficiently eliminate the water by a purge
method using refrigerant gas as in the present invention. Therefore, by providing
the dryer 5 in the refrigeration cycle, it is possible to ensure the long term reliability
of the air conditioner.
[0075] As apparent from the above embodiments, according to the present invention, since
the physical absorption or chemical reaction is used without using a power supply,
it is possible to complete the installing operation within a short time. Further,
since carbon dioxide is discharged into the atmosphere instead of refrigerant gas
having environmental problem, the influence on global warming is extremely small.
[0076] Further, according to the present invention, the inside pressure is heldpositive
after air has been replaced by carbon dioxide. Therefore, when the inside pressure
is brought into communication with the trap apparatus next, the positive pressure
state of the inside becomes a trigger of convection of gas so that the carbon dioxide
is swiftly absorbed by the zeolite (or collected as a result of calcium chemical reaction
from calcium hydroxide to calcium carbonate) in the trap apparatus.
[0077] Further, according to the present invention, the inside pressure is held at higher
pressure than that of the trap apparatus after air has been replaced by carbon dioxide.
Therefore, when the inside pressure is brought into communication with the trap apparatus
next, the higher pressure state of the inside becomes a trigger of convection of gas
so that the carbon dioxide is swiftly absorbed by the zeolite (or collected as a result
of calcium chemical reaction from calcium hydroxide to calcium carbonate) in the trap
apparatus.
[0078] Furthermore, according to the present invention, when the structure body is utilized,
since zeolite exists on the surface of the structurebody, it is possible to increase
the contact area with the carbon dioxide, and to swiftly collect the carbon dioxide.
[0079] Furthermore, according to the present invention, the trap apparatus having 60g or
more zeolite per one liter of volume of the pipe of the indoor unit and the connection
pipes is used. Therefore, if the weight of zeolite is set while taking the volume
of the pipe of the indoor unit and the connection pipes into consideration, it is
possible to collect the carbon dioxide with sufficient speed.
[0080] Furthermore, according to the present invention, the structure body comprising carriers
with the coated layer mainly made of zeolite is included inside. By this structure,
since zeolite exists on the surface of the structure body, it is possible to increase
the contact area with the carbon dioxide.
[0081] Furthermore, according to the present invention, by employing the honeycomb structure
body or the corrugated structure body, it is possible to increase the contact area
with the carbon dioxide, and to speed up the collection of the carbon dioxide.
[0082] Furthermore, according to the present invention, by forming the flow path space which
is greater on the side of the inlet than the bottom side, it is possible to smoothly
diffuse the carbon dioxide in the trap apparatus.
[0083] Furthermore, according to the present invention, by using a hollow cylindrical zeolite
particles, the flow path necessary for diffusing carbon dioxide can sufficiently be
ensured, and it is possible to speed up the trap of carbon dioxide.
[0084] Furthermore, according to the present invention, zeolite particles having greater
surface area is charged in the trap apparatus closer to its inlet than its bottom,
it is possible to smoothly diffuse the carbon dioxide in the trap apparatus.
[0085] Furthermore, according to the present invention, by using the spherical or columnar
zeolite particles, a flow path necessary for diffusing the carbon dioxide can sufficiently
be secured, and by charging zeolite particles having greater surface area into the
trap apparatus closer to its inlet than its bottom, it is possible to smoothly diffuse
the carbon dioxide in the trap apparatus.
[0086] Further, according to the present invention, since in the trap apparatus, a trap
material exists on the structure body having communication ports, it is possible to
increase the contact area for the diffusion reaction between the trap material and
carbon dioxide, and to prevent the flow path from being closed by volume expansion
at the time of the chemical reaction.
[0087] Further, according to the present invention, a heat radiating portion or a cooling
portion is provided outside the trap apparatus, reaction heat generated by the abrupt
chemical reaction can efficiently be transmitted and diffused outside, and a pressure
in the connecting pipes and the indoor unit can be brought into a negative state,
i.e., 50 mmHg or less.
[0088] Further, according to the present invention, by using the amount of trap material
which is two to five times of stoichiometry weight with respect to the volume in the
connecting pipes and the indoor unit, a pressure in the connectiag pipes and the indoor
unit can be brought into a negative state, i.e., 50 mmHg or less at a sufficient speed.
[0089] Further, according to the present invention, by adding a small amount of water to
calcium hydroxide, this becomes a catalytic trigger, the chemical reaction speed from
the calcium hydroxide to calcium carbonate is accelerated.
[0090] Further, according to the present invention, by collecting carbon dioxide replacing
air in the indoor unit heat exchanger and the connection pipes using the above-described
installation trap apparatus, the carbon dioxide can swiftly be collected, and the
installation operation can conveniently be carried out.