Crack and shatter resistant well cement

Description

[0001] The present invention relates generally to a well cement composition which sets to a crack and shatter resistant mass.

[0002] Hydraulic cement compositions are commonly utilized in subterranean well completion and remedial operations. For example, hydraulic cement compositions are used in primary cementing operations whereby pipe strings such as casings and liners are cemented in well bores. In performing primary cementing, a hydraulic cement composition is pumped into the annular space between the walls of a well bore and the exterior surfaces of a pipe string disposed therein. The cement composition is permitted to set in the annular space thereby forming an annular sheath of hard substantially impermeable cement therein. The cement sheath physically supports and positions the pipe string in the well bore and bonds the exterior surfaces of the pipe string to the walls of the well bore whereby the undesirable migration of fluids between zones or formations penetrated by the well bore is prevented.

[0003] Multi-lateral wells have recently been developed which include vertical or deviated principal well bores having one or more ancillary laterally extending well bores connected thereto. Drilling and completion equipment is available which allows multiple laterals to be drilled from a principal cased and cemented well bore. Each of the lateral well bores can include a liner cemented therein which is tied into the principal well bore. The lateral well bores can be drilled into predetermined producing formations or zones at any time in the productive life cycle of the well.

[0004] In both conventional wells having single well bores and multi-lateral wells having several bores, the cement compositions utilized for cementing casings or liners in the well bores must have sufficient ductility and toughness to resist cracking or shattering as a result of pipe movements, impacts and/or shocks subsequently generated by drilling and other well operations. Set cement in wells, and particularly, a set cement sheath in the annulus between a pipe string and the walls of a well bore often fails by cracking or shattering during perforating and/or drilling operations. When the set cement cracks or shatters, rubble is often produced in the well or annulus.

[0005] Various types of fibers have been utilized in construction cement compositions heretofore including fibers formed of glass, steel, graphite, polyesters, polyamides and polyolefins. Polyolefin fibers are generally the most preferred in that they are readily available, are low in cost and have high resistance to corrosion and degradation. Fibrillated net-shaped polyolefin fibers are particularly suitable for use in cement compositions because they resist being pulled out of the set cement. The fibers function to control shrinkage cracking in the early stages of the cement setting process, and after setting, the fibers provide ductility and toughness to the cement composition whereby it resists cracking or shattering. When cracking or shattering does occur, the fibers hold the cracked or shattered set cement together and prevent the formation of rubble.

[0006] A problem heretofore experienced in the use of fibers in well cement compositions is that the fibers are hydrophobic and are difficult to dry blend with cement. The fibers agglomerate in the dry cement when it is conveyed causing plugging to occur, and when the cement and fibers are combined with mixing water, the fibers form mats which prevent their dispersion into and throughout the cement slurry. The lack of dispersion of the fibers in the cement slurry make it difficult to pump.

[0007] JP 10 236 855 discloses the use of a specific detergent that can be adsorbed onto polypropylene fibers so as to improve their dispersibility in cement.

[0008] Thus, there are needs for improved well cement compositions and methods wherein the cement compositions contain fibrillated fibers which can be easily mixed and conveyed with dry cement and subsequently dispersed in the aqueous cement slurries formed.

[0009] We have now devised some improved cement compositions and methods of cementing a subterranean zone which meet the needs described above and reduce or overcome the deficiencies of the prior art. The methods of the invention are basically comprised of the steps of introducing a crack and shatter resistant cement composition into a subterranean zone to be cemented and allowing the cement composition to set therein. The crack and shatter resistant cement compositions utilized in accordance with this invention are basically comprised of a hydraulic cement, sufficient hydrophilic fibers to make the cement composition crack and shatter resistant upon setting and sufficient water to form a pumpable slurry of the cement and fibers. The hydrophilic fibers utilized in accordance with this invention are hydrophilic fibrillated net-shaped polyolefin fibers.

[0010] The methods of this invention are particularly suitable for cementing a pipe string such as casing or a liner in a well bore whereby the set cement can withstand the formation of perforations therein as well as other impacts and shocks subsequently generated by drilling and other well operations without cracking or shattering and forming rubble. Such methods are basically comprised of the following steps. A crack and shatter resistant cement composition of this invention is pumped into the annulus between the pipe string and the walls of the well bore. The cement composition is then allowed to set into a hard crack and shatter resistant impermeable mass having ductility and toughness.

[0011] The expression "crack and shatter resistant cement composition" is used herein to mean a cement composition that sets into a hard impermeable mass having ductility and toughness and that resists cracking and/or shattering as a result of perforating operations, pipe movements, impacts, shocks and the like. If cracking or shattering does occur, the pieces formed are held together by the hydrophilic fibers in the cement composition.

[0012] While the cement compositions and methods of this invention are useful in a variety of well completion and remedial operations, they are particularly useful in primary cementing, i.e. cementing casings and liners in well bores. The crack and shatter resistant cement compositions of this invention are readily and easily prepared without the conveying, mixing, fiber dispersal and pumping problems encountered heretofore.

[0013] A variety of hydraulic cements can be utilized in the crack and shatter resistant cement compositions of this invention including those comprised of calcium, aluminum, silicon, oxygen and/or sulfur which set and harden by reaction with water. Such hydraulic cements include Portland cements, pozzolana cements, gypsum cements, high aluminum content cements, silica cements and high alkalinity cements. Portland cements are generally preferred for use in accordance with the present invention. Portland cements of the types defined and described in the API Specification For Materials And Testing For Well Cements, API Specification 10, Fifth Edition, dated July 1, 1990 of the American Petroleum Institute are particularly suitable. Preferred API Portland cements include classes A, B, C, G and H, with API classes G and H being the most preferred.

[0014] While fibers formed of various materials can be utilized in accordance with the present invention, the fibers utilized must resist degradation in a hydraulic cement composition. For example, fibers formed of polyesters, polyamides and glass suffer from the disadvantage that they degrade in the presence of hydrated lime. Hydrated lime is released in a cement composition as the cement therein is hydrated. Polyolefin fibers are suitable for use in cement compositions in that polyolefin fibers do not degrade or otherwise loose their strength over time in a set cement composition. However, fibers formed from polyolefins are hydrophobic and are very difficult to dry blend with hydraulic cements and disperse in water. Because they are hydrophobic, the polyolefin fibers cluster together when mixed with water and do not disperse therein. When cement slurries containing such non-dispersed fibers are pumped in high pressure pumps, difficulties are encountered due to the fiber clusters plugging off lines, valves and the like.

[0015] In accordance with the present invention, hydrophilic polyolefin fibres are included in the crack and shatter resistant cement compositions. The hydrophilic polyolefin fibres do not degrade in cement compositions and are readily dry mixed with cement and dispersed in the cement mixing water. Particularly suitable such hydrophilic polyolefin fibres are commercially available from the Forta Corporation of Grove City, Pennsylvania.

[0016] The preferred polyolefin fibres are polypropylene or polyethylene fibres which are in a fibrillated net configuration which maximizes the long term durability and toughness of a cement composition including the fibres. The fibrillated net-shaped fibres function exceptionally well in preventing cracking or shattering of cement compositions containing them, and if cracking or shattering does occur, in holding the cracked or shattered cement together, i.e., the individual pieces produced are held together by the fibres thereby preventing rubble formation.

[0017] The normally hydrophobic polyolefin fibres are converted to hydrophilic fibres by treating the hydrophobic fibres with a surface active agent. The most preferred hydrophilic fibres for use in accordance with the present invention are hydrophilic polypropylene fibrillated net-shaped fibres having lengths in the range of from 0.5 inch to 1.5 inches (1.27cm to 3.81cm).

[0018] Generally, the hydrophilic fibres utilized are included in a cement composition of this invention in an amount in the range of from 0.1% to 1% by weight of hydraulic cement in the composition, more preferably in an amount in the range of from 0.125% to 0.5%.

[0019] The water utilized in the cement compositions of this invention can be fresh water, unsaturated aqueous salt solutions or saturated aqueous salt solutions such as brine or seawater. The water is generally present in the cement compositions in an amount in the range of from 30% to 100% by weight of hydraulic cement in the compositions, more preferably in an amount in the range of from 35% to 60%.

[0020] As will be understood by those skilled in the art, the crack and shatter resistant cement compositions of this invention can include a variety of additives for improving or changing the properties of the cement compositions. Examples of such additives include, but are not limited to, set retarding agents, fluid loss control agents, dispersing agents, set accelerating agents and formation conditioning agents.

[0021] Set retarding agents are included in the cement compositions when it is necessary to extend the time in which the cement compositions can be pumped so that they will not thicken or set prior to being placed at a desired location in a well. Examples of set retarding agents which can be used include, but are not limited to, lignosulfonates such as calcium and sodium lignosulfonate, organic acids such as tartaric acid and gluconic acid, copolymers and others. The proper amount of set retarding agent required for particular conditions can be determined by conducting a "thickening time test" for the particular retarder and cement composition. Such tests are described in the API Specification 10 mentioned above. A particularly preferred set retarder for use in accordance with the present invention is a copolymer or copolymer salt of 2-acrylamido-2-methylpropane sulfonic acid and acrylic acid. The copolymer comprises from about 40 to about 60 mole percent 2-acrylamido-2-methylpropane sulfonic acid with the balance comprising acrylic acid, and the copolymer or salt thereof preferably has an average molecular weight below 5,000. When used, a set retarder is included in the cement composition of this invention in an amount in the range of from 0.1% to 2% by weight of hydraulic cement in the composition.

[0022] Examples of fluid loss control agents which can be used include, but are not limited to, cellulose derivatives, modified polysaccharides, polyacrylamides, guar gum derivatives, 2-acrylamido-2-methylpropane sulfonic acid copolymers, polyethyleneimine and the like.

[0023] An example of a dispersing agent which can be utilized is comprised of the condensation polymer product of an aliphatic ketone, an aliphatic aldehyde and a compound which introduces acid groups into the polymer, e.g., sodium bisulfite. Such a dispersant is described in U.S. Patent No. 4,557,763 issued to George et al. on December 10, 1985.

[0024] Examples of set accelerating agents which can be utilized include, but are not limited to, calcium chloride, zinc formate and triethanolamine, and examples of formation conditioning agents include, but are not limited to, potassium chloride and sodium chloride.

[0025] A method of the present invention for cementing a subterranean zone penetrated by a well bore comprises the steps of:

(a) introducing a crack and shatter resistant cement composition into the zone by way of the well bore, the cement composition comprising a hydraulic cement, sufficient hydrophilic fibers to make the cement composition crack and shatter resistant upon setting and sufficient water to form a pumpable slurry of the cement and fibers; and

(b) allowing the cement composition to set in the zone.

[0026] A more preferred method of cementing a subterranean zone penetrated by a well bore comprises the steps of:

(a) pumping a crack and shatter resistant cement composition into the zone by way of the well bore, the cement composition comprising Portland cement, sufficient hydrophilic polyethylene fibrillated net-shaped fibers to make the cement composition crack and shatter resistant upon setting and sufficient water to form a pumpable slurry of the cement and fibers; and

(b) allowing the cement composition to set in the zone.

[0027] A preferred method of this invention for cementing a pipe string, such as casing or a liner, in a well bore whereby the set cement can withstand the formation of perforations therein as well as other impacts and shocks subsequently generated by drilling or other well operations without cracking or shattering and forming rubble is comprised of the steps of:

(a) pumping a crack and shatter resistant cement composition into the annulus between the pipe string and the walls of the well bore, the cement composition comprising Portland API Class G or H cement, hydrophilic polyethylene fibrillated net-shaped fibres present in an amount in the range of from 0.125% to 0.5% by weight of cement in the composition and water present in an amount in the range of from 38% to 46% by weight of cement in the composition; and

(b) allowing the cement composition to set into a hard crack and shatter resistant impermeable mass having ductility and toughness.

[0028] In order to further illustrate the methods of the present invention the following example is given.

Example

[0029] A base cement composition comprised of Portland API Class H cement and fresh water present in an amount of 38% by weight of the cement having a density of 16.4 pounds per gallon (1965 kg/m³) was prepared. A portion of the base cement composition without fibres as well as portions thereof with hydrophobic polypropylene fibres and hydrophilic polypropylene fibres were tested for mechanical properties in accordance with API RP 10B. The fibres utilized and their quantities along with the results of the tests are set forth in the Table below.

TABLE

Mechanical Properties1 Of Fibre Containing Cement Compositions
					Plastic Failure Tests
Test No.	Type of Fibres	Quantity of Fibres, % by weight of cement	Compressive Strength, psi (x1000 kg/m2)	Tensile Strength2, psi (x1000 kg/m2)	Unconfined Strength, psi (x1000 kg/m2)	1000 psi Confined Strength, psi (x1000 kg/m2)	Brazilian Tensile (x1000 kg/m2)	Young's Modulus (Ex 106)	Poisson's Ratio
1*	None	-	4120 (2897)	467 (328)	6810 (4858)	8286 (5826)	292 (205)	1.91	0.193
2*	Hydrophobic Polypropylene	0.125	3610 (2538)	504 (354)	6639 (4668)	8541 (6005)	837 (588)	1.67	0.138
3*	Hydrophobic Polypropylene	0.25	3590 (2524)	512 (360)	6006 (4223)	7972 (5605)	635 (446)	1.48	0.14
4°	Hydrophobic Polypropylene	0.5	3760 (2644)	492 (346)	5523 (3883)	7444 (5234)	645 (453)	1.47	0.11
5**	Hydrophilic Polypropylene	0.125	3970 (2791)	556 (391)	5523 (3883)	8805 (6050)	727 (511)	1.5	0.13
6**	Hydrophilic Polypropylene	0.25	3750 (2637)	493 (347)	5373 (3778)	7623 (5359)	705 (496)	1.45	0.124
7**	Hydrophilic Polypropylene	0.5	3280 (2306)	456 (321)	4933 (3468)	7025 (4939)	669 (470)	1.53	0.117

1 The test samples were cured at 140°F (60.0°C) for 72 prior to testing 2 Briquetts were prepared for tensile strength measurements . *Examples 1 to 4 are comparative examples and do not exemplify the present invention **Examples 5 to 7 exemplify the present invention

[0030] From the Table it can be seen that the mechanical properties of the test cement portions containing hydrophilic fibers are essentially the same as the test cement portions containing hydrophobic polypropylene fibers. In addition, the hydrophilic fibers were easily dry blended with the cement and readily dispersed in the mixing water while the hydrophobic fibers were not.

Claims

1. A cement composition which comprises a hydraulic cement; hydrophilic fibrillated net-shaped polyolefin fibers to make said cement composition crack and shatter resistant upon setting; and water to form a pumpable slurry of said cement and fibers.

2. A composition according to claim 1, wherein said hydraulic cement is selected from Portland cements, pozzolona cements, gypsum cements, slag cements, silica cements and high aluminium content cements.

3. A composition according to claim 2, wherein said hydraulic cement is Portland cement.

4. A composition according to any of claims 1 to 3, wherein said hydrophilic fibers in said composition are polyolefin fibers coated with a hydrophilic surface active agent.

5. A composition according to any of claims 1 to 4, wherein said polyolefin fibers are polypropylene fibers or polyethylene fibers.

6. A composition according to any of claims 1 to 5, wherein said hydrophilic fibers are present in said cement composition in an amount of from 0.1 to 1% by weight of hydraulic cement in said composition.

7. A composition according to any of claims 1 to 6, wherein said water in said composition is fresh water, an unsaturated aqueous salt solution or a saturated aqueous salt solution.

8. A composition according to any of claims 1 to 7, wherein said water is present in said cement composition in an amount of from 30% to 100% by weight of said hydraulic cement in said composition.

9. A composition according to any of claims 1 to 8, which further comprises one or more additives selected from set retarding agents, fluid loss control agents, set accelerating agents, dispersing agents and formation conditioning agents.

10. A method of cementing a subterranean zone penetrated by a well bore, which method comprises introducing a cement composition, as claimed in any of claims 1 to 9, into said zone by way of said well bore, and allowing the composition to set to be crack and shatter resistant.

11. A method according to claim 10, of cementing a pipe string in a well bore whereby the set cement can withstand the formation of perforations therein as well as other impacts and shocks subsequently generated by drilling and other well operations without cracking or shattering and forming rubble, which method comprises: pumping a cement composition, as claimed in any of claims 1 to 9, into the annulus between said pipe string and the walls of said well bore, and allowing said cement composition to set.

12. The use of a composition according to any of claims 1 to 9 as a well cement composition which sets to a crack and shatter resistant mass.

Ansprüche

1. Eine Zementmischung enthaltend einen hydraulischen Zement; hydrophile, fibrillierte, netz-förmige Polyolefin-Fasern, damit die Zementmischung beim Abbinden Bruch- und Erschütterungssicher wird; und Wasser zur Bildung eines pumpbaren Schlamms aus dem Zement und den Fasern.

2. Eine Mischung nach Anspruch 1, wobei der hydraulische Zement ausgewählt ist aus Portlandzement, Puzzolanzement, Gipszement, Schlackenzement, Silikazement und Zement mit hohem Aluminiumgehalt.

3. Eine Mischung nach Anspruch 2, wobei der hydraulische Zement Portlandzement ist.

4. Eine Mischung nach einem der Ansprüche 1 bis 3, wobei die hydrophilen Fasern in der Mischung Polyolefin-Fasern sind, die mit einem hydrophilen, oberflächenaktiven Mittel beschichtet sind.

5. Eine Mischung nach einem der Ansprüche 1 bis 4, wobei die Polyolefin-Fasern Polypropylen-Fasern oder Polyethylen-Fasern sind.

6. Eine Mischung nach einem der Ansprüche 1 bis 5, wobei die hydrophilen Fasern in der Zementmischung in einer Menge von 0,1 bis 1 Gew.-% des hydraulischen Zements in der Mischung vorhanden sind.

7. Eine Mischung nach einem der Ansprüche 1 bis 6, wobei das Wasser in der Mischung Frischwasser, eine ungesättigte wässrige Salzlösung oder eine gesättigte wässrige Salzlösung ist.

8. Eine Mischung nach einem der Ansprüche 1 bis 7, wobei das Wasser in der Zementmischung in einer Menge von 30 Gew.-% bis 100 Gew.-% des hydraulischen Zements in der Mischung vorhanden sind.

9. Eine Mischung nach einem der Ansprüche 1 bis 8, die weiterhin enthält einen oder mehrere Zusätze, die ausgewählt sind aus abbindeverzögernden Mitteln, Fluidverlust-steuernden Mitteln, Abbindebeschleunigern, Dispergiermitteln und Formationsbehandlungsmitteln.

10. Ein Verfahren zum Zementieren einer unterirdischen Zone, die von einem Bohrloch durchdrungen wird, wobei das Verfahren umfasst: Einführen einer Zementmischung nach einem der Ansprüche 1 bis 9 durch das Bohrloch und Abbinden-lassen der Mischung, damit sie bruch- und erschütterungsresistent ist.

11. Ein Verfahren nach Anspruch 10 zum Zementieren eines Rohrstrangs in einem Bohrloch, wodurch der abgebundene Zement der Bildung von Perforierungen widerstehen kann und anderen Einflüssen und Schocks, die nachfolgend durch Bohren und andere Bohroperationen erzeugt werden, ohne zu brechen oder zu erschüttern und Schutt zu bilden, wobei das Verfahren umfasst: Pumpen einer Zementmischung nach einem der Ansprüche 1 bis 9 in den Ringraum zwischen dem Rohrstrang und der Wandung des Bohrlochs und Abbinden lassen der Zementmischung.

12. Die Verwendung einer Mischung nach einem der Ansprüche 1 bis 9 als Zementmischung für Bohrlöcher, die zu einer Bruch- und Erschütterungsresistenten Masse abbindet.

Revendications

1. Composition de ciment qui comprend un ciment hydraulique ; des fibres de polyoléfine fibrillées et hydrophiles en forme de filet afin de rendre ladite composition de ciment résistante à la fissuration et aux chocs lors de la prise, et de l'eau afin de former une suspension qui peut être pompée, composée dudit ciment et desdites fibres.

2. Composition selon la revendication 1, dans laquelle ledit ciment hydraulique est choisi parmi les ciments Portland, les ciments pouzzolaniques, les plâtres, les ciments de laitier à la chaux, les ciments siliceux et les ciments riches en aluminium.

3. Composition selon la revendication 2, dans laquelle ledit ciment hydraulique est le ciment Portland.

4. Composition selon l'une quelconque des revendications 1 à 3, dans laquelle lesdites fibres hydrophiles dans ladite composition sont des fibres de polyoléfine revêtues d'un agent de surface hydrophile.

5. Composition selon l'une quelconque des revendications 1 à 4, dans laquelle lesdites fibres de polyoléfine sont des fibres de polypropylène ou des fibres de polyéthylène.

6. Composition selon l'une quelconque des revendications 1 à 5, dans laquelle lesdites fibres hydrophiles sont présentes dans ladite composition de ciment en une quantité allant de 0,1 % à 1 % en poids du ciment hydraulique dans ladite composition.

7. Composition selon l'une quelconque des revendications 1 à 6, dans laquelle ladite eau dans ladite composition est de l'eau douce, une solution saline aqueuse non saturée ou une solution saline aqueuse saturée.

8. Composition selon l'une quelconque des revendications 1 à 7, dans laquelle ladite eau est présente dans ladite composition de ciment en une quantité allant de 30 % à 100 % en poids dudit ciment hydraulique dans ladite composition.

9. Composition selon l'une quelconque des revendications 1 à 8, qui comprend en outre un ou plusieurs additifs choisis parmi des agents retardateurs de prise, des agents régulateurs de perte de fluide, des agents accélérateurs de prise, des agents de dispersion et des agents de conditionnement de formation.

10. Procédé pour cimenter une zone souterraine traversée par un puits de forage, lequel procédé comprend les étapes consistant à introduire une composition de ciment, telle que revendiquée dans l'une quelconque des revendications 1 à 9, dans ladite zone par l'intermédiaire dudit puits de forage, et à permettre à la composition de prendre de sorte à être résistante aux fissures et aux chocs.

11. Procédé selon la revendication 10, pour cimenter un train de tiges dans un puits de forage, moyennant quoi le ciment après durcissement peut supporter la formation de perforations dans ce dernier ainsi que d'autres impacts et chocs générés par la suite par des forages et autres opérations liées au forage sans fissurer ou se détruire en formant des gravats, lequel procédé comprend les étapes consistant à : pomper une composition de ciment, telle que revendiquée dans l'une quelconque des revendications 1 à 9, dans l'espace annulaire entre ledit train de tiges et les parois dudit puits de forage, et permettre à ladite composition de ciment de prendre.

12. Utilisation d'une composition selon l'une quelconque des revendications 1 à 9 en tant que composition de ciment pour puits qui, lors de la prise, devient une masse résistante aux fissures et aux chocs.