FABRIC SOFTENING COMPOSITIONS CONTAINING CATIONIC SOFTENERS AND FATTY AMIDES

Description

Field of the Invention

[0001] This invention relates to liquid fabric softening compositions. More particularly, this invention relates to liquid fabric softening compositions which provide enhanced softening performance based on a combination of a cationic softener with a fatty amide type compound.

Background of the Invention

[0002] Compositions containing quaternary ammonium salts or imidazolinium compounds having at least one long chain hydrocarbyl group are commonly used to provide fabric softening benefits when used in a laundry rinse operation. Compositions of this type have been the focus of the patent literature for many years.

[0003] EP-A 634 475 relates to a concentrated liquid fabric softener composition comprising an amidoamine and a quaternary diester fabric softener.

[0004] WO 99/27046 relates to a rinse-added fabric softener comprising about 1-80 % fabric softening active, e.g. a quaternary ammonium compound, and about 0.5-10 wt. % polyoxyalkylene alkyl amide surface active agent.

[0005] EP-A 159 919 relates to an aqueous concentrated fabric softening composition comprising a cationic fabric softener, e.g. a quaternary ammonium compound or an alkylimidazolinium compound. It may further comprise an alkyl diethanol amide.

[0006] But, there remains an ongoing need to improve the feel of the clothes washed under domestic conditions, particularly where the clothes are washed more frequently with very effective detergents and washers. As a result, the textile finishes are progressively removed, the textile fibers are altered and the initial pleasant feel of the fabrics is progressively lost.

[0007] For more than 40 years now, fabric softening compositions have been used to restore a pleasant feel and provide a perfume to washed clothing. The most popular forms have been the liquid rinse cycle fabric softeners and the dryer softener sheet.

[0008] However, there is a continuing demand for better performing products. Better fabric softening can be achieved either by increasing the dose of the softener (either through higher use dosage or higher product concentration) or by identifying better softeners or combinations of softeners.

[0009] It is, therefore, an object of the present invention to provide aqueous softening compositions containing combinations of softeners with superior softening. The efficacy of these combinations is such that the active concentration of the compositions can be kept within reasonable, well accepted limits, thereby making the manufacture process easier and extending the shelf life of the finished product.

[0010] It is another object of the invention to provide a liquid rinse cycle fabric softener capable of imparting superior softening benefits to fabrics due to the synergistic combination of a conventional cationic softener compound with a fatty amide type compound.

Summary of the Invention

[0011] The above and other objects of the invention which will become apparent from the detailed description and Examples to follow is achieved by a stable, pourable and water dispersible fabric softening composition comprising:

(i) from 2% to 35%, by weight, of a combination of softening components (A) and (B) wherein:

(A) is a cationic fabric softening compound, selected from the group consisting of:

(i) dialkyl quaternary ammonium compounds;

(ii) dialkyl fatty ester quaternary ammonium compounds; and

(iii) alkyl imidazolinium compounds; and

(B) is a fatty amide compound; being an alkyl carbamidoethyl urea having the following structural formula:

wherein R is a C₁₂ to C₂₂ alkyl group;

(ii) from 0 to 10%, by weight, of a polysiloxane; and

(iii) balance water and optionally adjuvants selected from the group consisting of perfumes; dyes; sequestrants; thickeners; and anti dye-transfer polymeric materials.
Most preferably, R is C₁₇H₃₅.
Part of the fatty amide compound (B) may be provided for by a further alkyl diethanolamide having the following structural formula:

wherein R₁ is stearic (C₁₇H₃₅), or behenic (C₂₁H₄₃) or a mixture of both.

[0012] The present invention also provides a method of imparting softness to fabrics by contacting the fabrics with a softening effective amount of the fabric softening composition of the invention, and preferably in the rinse cycle of an automatic laundry washing machine. The compositions may be diluted with water prior to adding same to the washing machine (e.g. the rinse cycle dispenser), or may be added at reduced amount, without dilution, i.e., ready to use.

Detailed Description and Preferred Embodiments of the Invention

[0013] The cationic fabric softeners used in the present invention can be any of the commercially available and known cationic fabric softeners and preferably are of the water dispersible dialkyl quaternary ammonium compound salts, di(alkyl fatty ester) quaternary ammonium compound salts or alkyl imidazolinium salts.

[0014] The preferred cationic softening compound (A) for purposes of the present invention is a biodegradable fatty ester quaternary ammonium compound of the formula (III):

wherein R₄, independently, represents an aliphatic hydrocarbon group having from 8 to 22 carbon atoms; each of R₅ independently represent (CH₂)_s-R₇ (where R₇ represents an alkoxy carbonyl group containing from 8 to 22 carbon atoms, benzyl, phenyl, (C₁-C₄) alkyl substituted phenyl, OH or H); R₆ represents (CH₂)_t-R₈ (where R₈ represents benzyl, phenyl, (C₁-C₄) alkyl substituted phenyl, OH or H); r, s and t, each independently represent a number of from 1 to 3; and X^-1 is an anion of valence minus one.

[0015] Typical cationic fabric softener compounds include:

Distearyl dimethyl ammonium chloride
Ditallow dimethyl ammonium chloride

Dihexadecyl dimethyl ammonium chloride
Di (hydrogenated tallow) dimethyl ammonium chloride

N-Methyl-N,N-di(C₁₆-C₁₈-acyloxy)-ethyl-N-(2-hydroxyethyl)ammonium methosulfate
2, 3-di(C₁₆-C₁₈-acyloxy)propyltrimethylammonium chloride
N,N-dimethyl-N,N-di (C₁₆-C₁₈-acyloxy)-ethyl ammonium methosulfate

2-(C₁₆-C₁₈-alkyl)-3-(C₁₆-C₁₈-acyloxy)-ethylimidazolinium chloride
Methyl-1-tallow amido-ethyl-2-tallow imidazolinium methyl sulfate
Methyl-1-oleyl amido-ethyl-2-oleyl imidazolinium methyl sulfate

[0016] The fatty ester quaternary ammonium compound described in formula III above is preferably a diester quat of the formula IV:

where each R₄ independently represent an aliphatic hydrocarbon group having from 8 to 22 carbon atoms and, may be, for example, derived from hard or soft tallow, coco, stearyl, oleyl, and the like. Such compounds are commercially available, such as, for example, Tetranyl AT-75, from Kao Corp. Japan, which is di-tallow ester triethanol amine quaternary ammonium methyl sulfate. Tetranyl AT-75 is based on a mixture of about 25% hard tallow and about 75% soft tallow. Accordingly, this product contains about 34% of unsaturated alkyl chains. A second example would be Hipochem X-89107, from High Point Chemical Corp.; which is an analogue of the Tetranyl AT-75 with about 100% saturation in the tallow moieties.

[0017] Because of the industrial production scale aspect of such ester quat compounds, variation of the quatemization level will result in the presence of quaternary ammonium compounds as well as the presence of fatty amines, or variation in the degree of esterification will result in the presence of mono, di and tri -alkyl derivatives, such fatty amines and alkyl derivatives being clearly materials which may be present in the compositions of the invention.

[0018] It is understood that the nature of the counter ions is not essential to the nature of the invention. They can be halides, such as chlorides, iodides, bromides or methosulfate, though the commercially available materials are mostly the chlorides or the methosulfates compounds.

[0019] The fatty amide compounds of formula I above are generally described as condensation products of monobasic fatty acids having at least 8 carbon atoms with dipropylene triamine and or diethylene triamine. These condensates are subsequently reacted with urea. The resulting product is optionally methylolated by adding formaldehyde.

[0020] Typical compounds of this class are:

Bis/tetra stearyl carbamidoethyl urea.
Bis/tetra tallowyl carbamidoethyl urea.

[0021] The manufacture of such fatty amide compounds is described in U.S. Patent 3,956,350 to Ciba-Geigy.

[0022] The cationic compounds (A) and fatty amide compounds (B) are used in admixture, preferably at weight ratios of 5:1 to 1:5, more preferably from 2:1 to 1:2, and most preferably about 1:1 whereby both softening performance and stability and pourability are improved. The total amounts of components (A) and (B) is from 2 to 35 wt. percent, preferably from 3 to 30 wt%.

[0023] The compositions of this invention may optionally include an electrolyte to reduce dispersion viscosity. Generally, any of the alkaline metals or alkaline earth metal salts of the mineral acids can be used as electrolyte. In view of availability, solubility and low toxicity, NaCl, CaCl₂, MgCl₂ and MgSO₄ and similar salts of alkaline and alkaline earth metals are preferred, and CaCl₂ is especially preferred. The amount of the electrolyte will be selected to assure that the composition does not form a gel. Generally, amounts of electrolyte salt of from 0.05 to 2.0 wt%, preferably 0.1 to 1.5 wt%, especially preferably 0.25 to 1.4 wt%, will effectively prevent gelation from occurring.

[0024] Optional ingredients that are known in the art of treating textiles can be used to further improve the stability, the aesthetics or the performance of the compositions of this invention.

[0025] Perfumes are additions to fabric softening compositions to enhance the freshness of laundered clothing.

[0026] The compositions of the invention often contain a fatty alcohol ethoxylate nonionic surfactant to emulsify the perfume present in the composition. The presence of an emulsifier insures the physical stability of the composition which may otherwise be destabilized by the presence of perfume or fragrance in the composition. The fatty alcohol ethoxylates useful in the invention correspond to ethylene oxide condensation products of higher fatty alcohols, with the higher fatty alcohol being of from 9 to 15 carbon atoms and the number of ethylene oxide groups per mole being from 5 to 30.

[0027] As used herein, the term "perfume" is used in its ordinary sense to refer to and include any non-water soluble fragrant substance or mixture of substances including natural (i.e., obtained by extraction of flower, herb, blossom or plant), artificial (i.e., mixture of natural oils or oil constituents) and synthetically produced odoriferous substances. Typically, perfumes are complex mixtures of blends of various organic compounds such as alcohols, aldehydes, ethers, aromatic compounds and varying amounts of essential oils (e.g., terpenes), the essential oils themselves being volatile odoriferous compounds and also serving to dissolve the other components of the perfume.

[0028] In the present invention, the particular composition of the perfume is of no importance with regard to the performance of the liquid fabric softener composition so long as it meets the criteria of water immiscibility and having a pleasing odor.

[0029] To prevent gelation of super-concentrated liquid compositions, the compositions may contain a polyethylene glycol polymer or polyethylene glycol alkyl ether polymer. The polyethylene glycol polymers useful herein have a molecular weight of at least 200 up to a molecular weight of about 8,000. Useful polymers include the polyethylene glycol and polyethylene glycol methyl ether polymers marketed by Aldrich Chemical Company. Useful amounts of polymer in the composition range from 0.1% to 5%, by weight. A range of from 0.5 to 1.5%, by weight, is preferred.

[0030] Examples of optional rheology modifiers and thickeners for use herein are well known in the art and may be chosen from, for example, polymeric rheology modifiers and inorganic rheology modifiers. Examples of the former type include cationic polymers such as copolymers of acrylamide and quaternary ammonium acrylate and the like. Generally, only minor amounts, up to about 1.0%, preferably up to about 0.8%, such as, for example, 0.01 to 0.60 percent, by weight, provide acceptable viscosity levels over time.

[0031] Other optional co-softeners for use herein are fatty alcohols, glycerol monostearate (GMS) and glycerol monooleate (GMO).

[0032] Other optional ingredients which may be used to reduce fabric wrinkling and enhance ease of ironing are nonionic humectants, inorganic salts, film forming polymeric materials such as polyacrylates, polymethacrylates, silicones, starch derivatives and polyolefins waxes.

[0033] Anti dye transfer polymeric materials, such as polyvinylpyrrolidone type compounds may also be added to the present compositions.

[0034] Sequestering materials such as polyphosphonates, polycarboxylic materials can be used to neutralize water impurities such as mineral salts (calcium, magnesium, iron, copper) to protect the colors of the clothes.

[0035] Other optional components commonly used in fabric softening compositions may be added in minor amounts to enhance either the appearance or performance properties of the liquid fabric softener compositions of this invention. Typical components of this type include, but are not limited to colorants, e.g., dyes or pigments, bluing agents, preservatives, germicides, and perfumes.

[0036] The final product, whether in concentrated or diluted form must be easily pourable by the end user. Generally, therefore, final product viscosity (for a freshly prepared sample) should net exceed about 1500 mPa.s (centiposise), preferably not more than 1000 mPa.s (centipoise), but should not be too low, for example not less than about 50 mPa.s (centipoise). The preferred viscosity for the invention concentrated product is in the range of 120 to 1000 mPa.s (cps). As used herein, unless otherwise specified, viscosity is measured at 25°C (22-26°C) using a Brookfield RVTD Digital Viscometer with Spindle #2 at 50 rpm.

[0037] Concentrated compositions may be diluted by a factor of generally 4:1 or more, preferably up to about 8:1 or even 10:1. Concentrated products with up to about 35 weight percent of softeners may be prepared and will remain pourable and stable against phase separation or suspended particle agglomeration for extended periods of time. For example, a composition with about 28% of softeners can be diluted to about 5% actives to provide equivalent or superior softening performance to a product containing about 7% of DTDMAC (ditallow dimethyl ammonium chloride). After dilution, or for a ready-to-use product, the composition will normally contain sufficient softener to be effective when added to the rinse water in an amount of about 29.6 to 177 ml (one-eighth to three-quarters of a cup or 1 to 6 ounces) providing 50 ppm to 250 ppm of softener in the rinse water.

[0038] The compositions of the present invention are able to provide additional benefits beyond fabric softening to fabrics and laundry which are conditioned with such compositions. Principally, it is noted that these compositions provide improved color protection by dye transfer inhibition to treated fabrics, as well as improved care benefits by minimizing fabric abrasion. This has the effect of enhancing fabric appearance and extending fabric longevity.

[0039] The following formulas illustrate useful compositions in accordance with the invention. All mentioned ingredients are given as 100% active.

[0040] DTDMAC = Ditallow dimethyl ammonium chloride or di(alkyl fatty ester) quaternary ammonium.

[0041] Fatty amide mixture (FAM) = 59.5% of Bis/tetra stearyl carbamidoethyl urea / 40.5% of stearic/behenic acid diethanolamide.

[0042] Silicones were used as optional ingredients.

[0043] The balance of each formula consisted of water, dye, perfume and preservative.

Regular Concentration Formulas

[0044] 

Composition A
2% Cationic softener/3.2% Fatty amide mixture/1% Silicone
2% DTDMAC/3.2% Fatty amide mixture/1% Wacker VP1445E or Dow Corning X2-7589

Composition B
2% Cationic softener/3.2% Fatty amide urea/1% Silicone
2% DTDMAC/3.2% bis/tetra stearylcarbamidoethyl urea/1% VP1445E or Dow Corning X2-7589 Polysiloxane

Composition C
2% Cationic softener/3.2% Stearyl diethanolamide/1% Silicone
2% DTDMAC/3.2% stearyl/behenic diethanolamide/1% VP1445E or X2-7589 Polysiloxane

Concentrated Formulas

[0045] 

Composition D
4% Cationic softener/6.4% Fatty amide mixture/2% Silicone
4% DTDMAC, 6.4% Fatty amide mixture, 2% Wacker VP1445E or Dow Corning X2-7589

Composition E
6% cationic softener/9.6% Fatty amide mixture/3% Silicone
6% DTDMAC/9.6% Fatty amide mixture/3% Wacker VP1445E or Dow Corning X2-7589

Example 1

[0046] The evaluation of softness performance in the Examples herein was conducted under the following conditions: A mini-cycle softening test was used to duplicate the rinse cycle of a European washing machine with 3 kg fabric for 25 liters water. A rotating drum was used to treat the fabrics with the softener rinse liquor. Terry cloths were 2 times desized and 6 times hardened. Tap water had 300 ppm hardness and a pH of about 8.

Synergy Between DTDMAC and Fatty Amide Mixture

[0047] The softness of several compositions of the invention was compared. The test compositions contained 6% of total softening actives including combinations of the fatty amide mixture and DTDMAC versus the control composition which contained 6% of DTDMAC as the sole softening ingredient. Dosage was 110 ml. per wash.

[0048] A panel of 6 trained judges evaluated the softness of the treated towels and ranked them in the following order of decreasing softness.

1.	2% DTDMAC/4% Fatty amide mixture
2.	1% DTDMAC/5% Fatty amide mixture
3.	3% DTDMAC/3% Fatty amide mixture
4.	4% DTDMAC/2% Fatty amide mixture
5.	5% DTDMAC/1% Fatty amide mixture
6.	6% DMDTAC (comparative)

[0049] Based on the above data, mixtures of DTDMAC/Fatty amide mixture imparted greater softness to fabrics than an equivalent amount of DTDMAC alone. Further, the optimum ratio of cationic softener to fatty amide mixture was 2:4.

Example 2

[0050] Following the test methodology of Example 1 the performance of a mixture of DTDMAC/fatty amide mixture and silicone was compared to a control composition of DTDMAC.

[0051] The composition of the invention contained 2% DTDMAC, 3.2% fatty amide mixture and 1% Wacker polysiloxane. Dosage was 110 ml/wash for the composition of the invention and 275 ml/wash for the control composition of 5% DTDMAC which is equivalent to 12.5% DTDMAC at a dosage of 110 ml/wash.

[0052] A panel of 6 trained judges evaluated the softness of the towels and rated the composition of the invention as providing superior softness than the control composition.

Claims

1. A stable, pourable and water dispersible fabric softening composition comprising:

(i) from 2% to 35%, by weight, of a combination of softening components (A) and (B) wherein:

(A) is a cationic fabric softening compound selected from the group consisting of :

(i) dialkyl quaternary ammonium compounds;

(ii) dialkyl fatty ester quaternary ammonium compounds; and

(iii) alkyl imidazolinium compounds; and

(B) is a fatty amide compound, said fatty amide compound (B) being an alkyl carbamidoethyl urea having the following structural formula:

wherein R is a C₁₂ to C₂₂ alkyl group.

(ii) from 0 to 10% by weight, of a polysiloxane; and

(iii) balance water and optionally adjuvants selected from the group consisting of perfumes; dyes; sequestrants; thickeners; and anti dye-transfer polymeric materials.

2. The fabric softening composition of claim 1, wherein as part of component B a further fatty amide compound is present having the following structural formula:

wherein R₁ is stearic (C₁₇H₃₅) or behenic (C₂₁H₄₃) or a mixture of both.

3. The fabric softening composition of claim 2 wherein in formula (I) R is C₁₇H₃₅, to form the compound bis/tetra stearyl carbamidoethyl urea; and in formula (II) R₁ is a mixture of C₁₇H₃₅ and C₂₁H₄₃ to form the compound stearic/behenic diethanol amide.

4. The fabric softening composition of claim 1, wherein said cationic softening compound (A) is a biodegradable fatty ester quaternary ammonium compound of the formula (III):

wherein R₄, independently, represents an aliphatic hydrocarbon group having from 8 to 22 carbon atoms; each of R₅ independently represent (CH₂)_s-R₇ (where R₇ represents an alkoxy carbonyl group containing from 8 to 22 carbon atoms, benzyl, phenyl, (C_1-4) alkyl substituted phenyl, OH or H); R₆ represents (CH₂)_tR₈ (where R₈ represents benzyl, phenyl, (C_1-4) alkyl substituted phenyl, OH or H), r, s and t, each independently represent a number of from 1 to 3; and X^-1 is an anion of valence minus one.

5. The fabric softening composition of claim 4 wherein the fatty ester quaternary ammonium compound is a diester compound having the following structural formula IV:

wherein each R₄ independently represents the aliphatic hydrocarbon group as defined above.

6. A method of imparting softness to fabrics comprising contacting said fabrics with an effective amount of the fabric softening composition of claim 1.

7. The method of claim 6 wherein said fabrics are contacted during the rinse cycle of an automatic laundry washing machine.

Ansprüche

1. Stabile, gießfähige und in Wasser dispergierbare Textilgewebe weichmachende Zusammensetzung, die

(i) 2 bis 35 Gew.-% einer Kombination von weichmachenden Komponenten (A) und (B), wobei

(A) eine kationische gewebeweichmachende Verbindung ausgewählt aus der Gruppe bestehend aus

(i) quartären Dialkylammoniumverbindungen,

(ii) quartären Dialkylfettesterammoniumverbindungen, und

(iii) Alkylimidazoliniumverbindngen ist, und

(B) eine Fettamidverbindung ist, wobei die Fettamidverbindung (B) eine Alkylcarbamidoethylharnstoffverbindung mit der folgenden Strukturformel

ist, in der R eine C₁₂- bis C₂₂-Alkylgruppe ist,

(ii) 0 bis 10 Gew.-% Polysiloxan und

(iii) als Rest und gegebenenfalls Hilfsmittel ausgewählt aus der Gruppe bestehend aus Parfümen, Farbstoffen, Sequestriermitteln, Verdickungsmitteln und Farbstoffübertragung verhindernde polymere Materialien umfasst.

2. Textilgewebe weichmachende Zusammensetzung nach Anspruch 1, bei der als Teil von Komponente B eine weitere Fettamidverbindung vorhanden ist, die die folgende Strukturformel

aufweist, in der R₁ Stearin (C₁₇H₃₅) oder Behen (C₂₁H₄₃) oder eine Mischung aus beiden ist.

3. Textilgewebe weichmachende Zusammensetzung nach Anspruch 2, bei der in Formel (I) R C₁₇H₃₅ ist, um die Verbindung Bis/Tetrastearylcarbamidoethylharnstoff zu bilden, und in Formel (II) R₁ eine Mischung aus C₁₇H₃₅ und C₂₁H₄₃ ist, um die Verbindung Stearin/Behendiethanolamid zu bilden.

4. Gewebeweichmachende Zusammensetzung nach Anspruch 1, bei der die kationische weichmachende Verbindung (A) eine biologisch abbaubare quartäre Fettesterammoniumverbindung der Formel (III)

ist, in der R₄ jeweils unabhängig eine aliphatische Kohlenwasserstoffgruppe mit 8 bis 22 Kohlenstoffatomen darstellt, jedes R₅ jeweils unabhängig (CH₂)_s-R₇ ist (wobei R₇ eine Alkoxycarbonylgruppe mit 8 bis 22 Kohlenstoffatomen, Benzyl, Phenyl, (C_1-4)-alkylsubstituiertes Phenyl, OH oder H darstellt), R₆ (CH₂)_tR₈ ist (wobei R₈ Benzyl, Phenyl, (C_1-4)-alkylsubstituiertes Phenyl, OH oder H darstellt), r, s, und t jeweils unabhängig eine Zahl von 1 bis 3 darstellen und X^-1 ein Anion mit einer Wertigkeit von minus 1 ist.

5. Textilgewebe weichmachende Zusammensetzung nach Anspruch 4, bei der die quartäre Fettesterammoniumverbindung eine Diesterverbindung mit der folgenden allgemeinen Strukturformel IV:

ist, in der jedes R₄ jeweils unabhängig die aliphatische Kohlenwasserstoffgruppe darstellt, wie sie oben definiert ist.

6. Verfahren zur Vermittlung von Weichheit an Textilgewebe, bei dem das Textilgewebe mit einer wirksamen Menge der Textilgewebe weichmachenden Zusammensetzung gemäß Anspruch 1 in Kontakt gebracht wird.

7. Verfahren nach Anspruch 6, bei dem die Textilgewebe während des Spülgangs einer automatischen Wäschewaschmaschine in Kontakt gebracht werden.

Revendications

1. Composition adoucissante pour textiles stable, susceptible d'être versée et de se disperser dans l'eau comprenant :

(i) d'environ 2% à 35%, en poids, d'une combinaison de composants adoucissants (A) et (B) dans laquelle :

(A) est un composé cationique adoucissant pour textiles choisi dans le groupe consistant en :

(i) des composés dialkyle ammonium quaternaire ;

(ii) des composés ester gras dialkyle ammonium quaternaire ; et

(iii) des composés alkyle imidazolinium ; et

(B) est un composé amide gras, ledit composé amide gras (B) étant une alkyle carbamidoéthyle urée possédant la formule structurale suivante :

dans laquelle R est un groupe alkyle en C₁₂ à C₂₂.

(ii) de 0 à 10% en poids, d'un polysiloxane ; et

(iii) de l'eau en complément et éventuellement des adjuvants choisis dans le groupe consistant en des parfums ; des colorants ; des agents de séquestration; des épaississants ; et des matériaux polymères anti-transfert de coloration.

2. Composition adoucissante pour textiles selon la revendication 1, dans laquelle en tant que partie de composant B un composé amide gras supplémentaire est présent, celui-ci possédant la formule structurale suivante :

dans laquelle R₁ est le stéarique (C₁₇H₃₅) ou béhénique (C₂₁H₄₃) ou un mélange des deux.

3. Composition adoucissante pour textiles selon la revendication 2 dans laquelle dans la formule (I) R est C₁₇H₃₅, pour former le composé bis/tétra stéaryle caibamidoéthyle urée ; et dans la formule (II) R₁ est un mélange de C₁₇H₃₅ et C₂₁H₄₃ pour former le composé stéarique/béhénique diéthanol amide.

4. Composition adoucissante pour textiles selon la revendication 1, dans laquelle ledit composé cationique adoucissant (A) est un composé ester gras ammonium quaternaire biodégradable de formule (III) :

dans laquelle R₄, indépendamment, représente un groupe hydrocarboné aliphatique possédant de 8 à 22 atomes de carbone ; chaque R₅ représente indépendamment (CH₂)_s-R₇ (dans lequel R₇ représente un groupe alkoxy carbonyle contenant de 8 à 22 atomes de carbone, benzyle, phényle, phényle substitué par un alkyle en C₁ à C₄, OH ou H); R₆ représente (CH₂)_tR₈ (dans lequel R₈ représente benzyle, phényle, phényle substitué par un alkyle en C₁ à C₄, OH ou H), r, s et t, représentent chacun indépendamment un nombre de 1 à 3 ; et X^-1 est un anion de valence moins un.

5. Composition adoucissante pour textiles selon la revendication 4 dans laquelle le composé ester gras ammonium quaternaire est un composé diester possédant la formule structurale IV suivante :

dans laquelle chaque R₄ représente indépendamment le groupe hydrocarboné aliphatique tel que défini ci-dessus.

6. Procédé pour transmettre une douceur aux textiles comprenant une mise en contact desdits textiles avec une quantité efficace de la composition adoucissante pour textiles selon la revendication 1.

7. Procédé selon la revendication 6 dans lequel lesdits textiles sont mis en contact au cours du cycle de rinçage d'une machine à laver de blanchissage automatique.