Water soluble package

Description

INTRODUCTION

[0001] The invention relates to a water soluble package according to claim 1, to a process for producing a water soluble package and to a process for washing of laundry.

[0002] Detergent compositions for the machine washing of laundry are provided in many forms. Probably the most prevalent form of laundry detergent is washing powder or granules.
A problem with the use of these forms of detergent is that the product needs to be dosed into the machine in such a way that the detergent is quickly and thoroughly dissolved in the wash water of the machine without coming into contact with the laundry in a solid form. In this regard many dosing devices which seek to overcome this problem have been proposed. One such device disclosed in European Patent Nos. 0 343 070 and 0 343 069 teaches the use of a flexible fabric sock which holds the particulate detergent in the machine, the fabric of the sock being permeable to water so as to allow water enter the sock and carry the detergent out of the sock through the fabric walls in the form of an aqueous solution. More recently unit dose forms of detergent have been proposed in the form of compressed tablets of detergent powder. A problem encountered with the provision of detergent tablets is that the tablets need to be strong enough to withstand storage and transport, yet weak enough to disintegrate and dissolve quickly in the washing machine. A further problem is the need to prevent the tablets "posting" in the porthole and between the drums of conventional washing machines.

[0003] More recently these problems have been addressed by the provision of detergent tablets having specific chemical disintegrants which allow quick disintegration of the tablets in the aqueous environment of a washing machine, and by the provision of loosely fitting net bags which aid tablet disintegration and prevent "posting". However, as many of the current detergent tablets contain bleach and other irritant substances, the problem of handling the tablets remains.

[0004] The provision of detergent compositions in water-soluble films has been known for some time. Most of the documents relating to this subject describe water soluble film envelopes formed using a vertical form-fill-seal (VFFS) route. A problem with envelopes produced using this VFFS method is that, due to the constraints of the process, the resultant envelopes have seals which incorporate defined weak points where the seals overlap at corners. This results in envelopes which are easily corrupted as a result of impacts suffered during transport. In an attempt to overcome the problems associated with such VFFS envelopes, European Patent Application No. 0 608 910 describes thermoformed water soluble packages for pesticidal compositions. While this specification attempts to provide a solution to the problem of weak seals, the packages of EP-A-0608910 have other weak points and are designed specifically for containing pesticidal compositions. US 4973416 discloses a water soluble package according to the preamble of claim 1.

[0005] The packaging and transport of water soluble packages containing fluid substances subjects the formed packages to considerable impact forces. A particular problem is that when a number of such packages are loose packed in a larger container which is then transported, the impact forces suffered by the packages within the container can be severe. The difficulty is that in such a situation it only takes one package in the larger container to break for the whole product to be ruined as far as the consumer is concerned because the fluid contents of the broken package may leak over any unbroken packages. Consumer confidence in a product is likely to be badly damaged by such an occurrence. The problem of minimising breakage to an acceptable level is particularly acute in the area of laundry detergents and other domestic consumer products and has not been solved until now.

[0006] It is an object of the invention to overcome at least some of the above disadvantages. It is a particular object of the invention to provide a water soluble package containing a fluid substance for release on dissolution of the package, which package has greater rupture resistance compared to known water-soluble packages.

STATEMENT OF INVENTION

[0007] According to the invention, there is provided a water soluble package according to claim 1, a process for producing a water soluble package and to a process for washing of laundry.

[0008] Preferably, the thermoformed body wall of a package according to the invention is of substantially uniform thickness. By "substantially uniform" it is meant that at any measured point the thickness of the thermoformed film is preferably less than about ±25%, even more preferably less than about ±20% and most preferably less than about ±15%, different from the original thickness of the film pre-thermoforming.

[0009] Preferably the film has a thickness of between 10 and 1000 microns. More preferably the film has a thickness of between 20 and 80 microns, most preferably between 40 and 60 microns.

[0010] In one preferred process the first sheet of water-soluble material is thermoformed by means of a heating plate. Preferably, the sheet of water-soluble material intimately contacts the heating plate, typically by applying a vacuum between the heating plate and the sheet of water-soluble material. Generally, the vacuum applied will be of less than 6000 Pa (0.6 Bar). Alternatively the sheet may be blown into contact with the heating plate. The thermoforming sheet can be blown or sucked off the heating plate and into a suitable dome-shaped mould. In one aspect of the invention, the process includes an additional step of, prior to the addition of the fluid substance, applying a vacuum to the thermoformed body wall to maintain the shape of the body portion at least until after the heat sealing step.

Detailed Description of the Invention

[0011] The packages of the invention are illustrated with reference to the drawings in which:

Figures 1a, 1b, 1c and 1d show different views of a first package according to the invention in which the base wall of the body portion is circular.

Figures 2a, 2b, 2c and 2d show different views of a second package according to the invention in which the base wall of the body portion is square.

Figures 3a, 3b, 3c and 3d show different views of a third package according to the invention in which the base wall of the body portion is oval.

Figures 4a, 4b, 4c and 4d show different views of a fourth package according to the invention in which the base wall of the body portion is triangular.

Figures 5a, 5b, 5c and 5d show different views of a fifth package according to the invention in which the base wall of the body portion is rectangular.

EXAMPLE

[0012] In this example a thermoforming process is described where a number of packages according to the invention are produced from two sheets of water soluble material. In this regard recesses are formed in the sheet using a forming die having a plurality of cavities with dimensions corresponding generally to the dimensions of the packages to be produced. Further, a single heating plate is used for thermoforming the film for all the cavities, and in the same way a single sealing plate is described.

[0013] A first sheet of polyvinyl alcohol film is drawn over a forming die so that the film is placed over the plurality of forming cavities in the die. Each cavity is generally dome shape having a round edge, the edges of the cavities further being radiussed to remove any sharp edges which might damage the film during the forming or sealing steps of the process. Each cavity further includes a raised surrounding flange. In order to maximise package strength; the film is delivered to the forming die in a crease free form and with minimum tension. In the forming step, the film is heated to 100 to 120°C, preferably approximately 110°C, for up to 5 seconds, preferably approximately 700 micro seconds. A heating plate is used to heat the film, which plate is positioned to superpose the forming die. During this preheating step, a vacuum of 0.5. MPa (0.5 bar) is pulled through the pre-heating plate to ensure intimate contact between the film and the pre-heating plate, this intimate contact ensuring that the film is heated evenly and uniformly (the extent of the vacuum is dependant of the thermoforming conditions and the type of film used, however in the present context a vacuum of less than 0.6 MPa (0.6 bar) was found to be suitable) Non-uniform heating results in a formed package having weak spots. In addition to the vacuum, it is possible to blow air against the film to force it into intimate contact with the preheating plate.

[0014] The thermoformed film is moulded into the cavities blowing the film off the heating plate and/or by sucking the film into the cavities thus forming a plurality of recesses in the film which, once formed, are retained in their thermoformed orientation by the application of a vacuum through the walls of the cavities. This vacuum is maintained at least until the packages are sealed. Once the recesses are formed and held in position by the vacuum, the composition, in this case a non-aqueous liquid detergent is added to each of the recesses. A second sheet of polyvinyl alcohol film is then superposed on the first sheet across the filled recesses and heat-sealed thereto using a sealing plate. In this case the heat sealing plate, which is generally flat, operates at a temperature of about 140 to 160°C, and contacts the films for 1 to 2 seconds and with a force of 8 to 30kg/cm², preferably 10 to 20kg/cm². The raised flanges surrounding each cavity ensure that the films are sealed together along the flange to form a continuous seal. The radiussed edge of each cavity is at least partly formed by a resiliently deformable material, such as for example silicone rubber. This results in reduced force being applied at the inner edge of the sealing flange to avoid heat/pressure damage to the film.

[0015] Once sealed, the packages formed are separated from the web of sheet film using cutting means. At this stage it is possible to release the vacuum on the die, and eject the formed packages from the forming die. In this way the packages are formed, filled and sealed while nesting in the forming die. In addition they may be cut while in the forming die as well.

[0016] During the forming, filling and sealing steps of the process, the relative humidity of the atmosphere is controlled to ca. 50% humidity. This is done to maintain the heat sealing characteristics of the film. When handling thinner films, it may be necessary to reduce the relative humidity to ensure that the films have a relatively low degree of plasticisation and are therefore stiffer and easier to handle.

EXPERIMENTAL DETERMINATION OF OPTIMUM PACKAGE SHAPE

i) Film Thinning During Thermoforming

[0017] The objective of this experimental work was to create thermoformed packages different shapes from the same material under the same conditions with the same depth of draw and approximately the same volume.

[0018] The formed packages were then tested for thickness at specific points using a micrometer. The results were then compared between shapes,

[0019] The conditions used were:

Film	Polyvinyl alcohol (supplied By Chris Craft under Reference CC8534)
Thickness	75µm
Volume of cavity	Approx. 30ml
Atmospheric condition	17°C, 46% RH
Micrometer sensitivity	5µm

[0020] The rectangular shape shown is used only as an example to show the various points.

[0021] For a dome shaped package only points A & E are the same. Points B, C and D are all equivalent in the dome shape and they were represented by Point F below.

[0022] The results were as follows:

			Measurement in microns
Shape	Sample	Draw Depth	A	B	C	D	E	F
Dome	1	20mm	60				70	65
	2	"	65				60	65
	3	"	65				60	60
Triangle	1	"	50	50	45	30	65
	2	"	55	55	40	25	55
	3	"	55	55	40	25	60
Dome	4	25mm	60				70	70
	5	"	65				70	70
	6	"	65				65	70
Cube	1	"	55	40	20	15	35
	2	"	65	35	25	20	35
	3	"	60	40	25	20	40

[0023] These results show that while thinning always takes place on thermoforming:

a) for the dome shape thinning is uniform over the test points; and

b) the dome has a lower level of thinning than the others over the test points.

ii) Impact Testing

[0024] The objective of this test was to show any differences, which exist, between the impact resistance of the dome shape and other shapes.

[0025] A falling dart impact test was used.

[0026] The test specimen was placed on a hard surface immediately below the suspended dart. The dart was allowed to fall, striking the specimen centrally. The specimen was then examined and any rupture or leak recorded. If there was no rupture or leak, the specimen was subjected to successive impacts, each at a higher dart weight, until rupture did occur.

[0027] Three shapes of package were used, all of the same material, fill and approximate weight and size. The test was repeated on both sides of the package (base side up and base side down) and several replicates were tested and a mean taken.

[0028] Before testing all specimens were exposed to the conditions of the test site for 12 hours to reach equilibrium. Test details were:

Dart:

smooth hemispherical impact surface of 38mm diameter

Drop height:

615mm

Surface:

Smooth non-resilient plate

Conditions:

20°C, 70% RH

[0029] Dome, triangle (ie triangular pyramid) and cube shapes were tested.

[0030] Each package was formed from polyvinyl alcohol supplied by Chris Craft under reference CC8534. The film thickness was 75µm.

[0031] Results were as follows:

Sample	Shape	Orientation	No. of Drops	Dart Weight to Rupture	Observations
1	Dome	Base Up	3	250g	Small hole mid base
2	Triangle	"	2	150g	2 holes in edges
3	Cube	"	2	150g	3 or more holes in corners & edge
4	Dome	Base Down	4	350g	hole in base

[0032] The above results show that the impact resistance of dome is greater than the cube or triangle.

iii) Secondary Packaging Test

[0033] This experimental test was designed to establish any difference in impact survival between dome shaped packages and triangular packages of a liquid detergent product when multiple packages are contained in fibreboard box

[0034] 22 dome-shaped packages according to the invention, containing a liquid laundry detergent, were placed randomly in a fibreboard box. The box was made of "M-flute" material of dimensions 170 x 85 x 54 mm which had a total filled weight of 609g.

[0035] The box was sealed closed and subjected to a vertical drop of 1.2 m on to a hard flat surface on the short dimensions.

[0036] This test was repeated for triangular packages of the same weight and film.

[0037] The results of the test were that 3 out of the 22 dome shaped packages were found to have a small amount of leakage but with the triangular packages, 7 of the 22 were leaking and in 5 cases leakage was very severe.

Claims

1. A water soluble package containing a laundry detergent for release on dissolution of the package, characterised in that:

- the package has a body portion for containing the laundry detergent fluid comprising a first sheet of a water soluble material thermoformed to form a body wall of the body portion, and a second sheet of water soluble material superposed on the first sheet and sealed thereto along a continuous region of the superposed sheets to form a generally rectangular or square base wall of the body portion,

- the body portion of the package is generally dome shaped,

- first and second sheets of water soluble material comprise a polyvinyl alcohol or a polyvinyl alcohol derivative,

- the maximum height of the body wall above the base wall is less than or equal to the maximum width of the base wall,

- the laundry detergent is a liquid or gel having a viscosity of between 0,1 and 1 Pa.s (100 and 1000 centipose) when measured at 20°C and 105s^-1

2. A package according to claim 1 characterised in that the base wall is convex.

3. A package according to claim 1 or claim 2 characterised in that the viscosity of the laundry detergent is between 0,3 and 0,8 Pa.s (300 and 800 centipose) when measured at 20°C and 105s^-1

4. A package according,to claim 3 characterised in that the viscosity of the laundry detergent is between 0,5 and 0,7 Pa.s (500 and 700 centipose) when measured at 20°C and 105s^-1

5. A package according to claim 3 characterised in that the viscosity is about 0,3 Pa.s (300 centipose) when measured at 20°C and 105s^-1.

6. A package according to claim 4 characterised in that the viscosity is about 0,6 Pa.s (600 centipose) when measured at 20°C and 105S^-1.

7. A package according to any preceding claim characterised in that the thermoformed body wall is of substantially uniform thickness.

8. A package according to any preceding claim characterised in that the material has a thickness of between 20 and 80 microns.

9. A package according to claim 8 characterised in that the material has a thickness of between 40 and 60 microns.

10. A package according.to any preceding claim characterised in that the laundry detergent comprises of between 1 and 5% water.

11. A process for producing a water soluble package having a body portion containing a laundry detergent liquid or gel having a viscosity of between 0,1 and 1 Pa.s (100 and 1000 centipose) when measured at 20°C and 105s^-1 for release on dissolution of the package, characterised in that the process comprises the steps of:

• thermoforming a first sheet of a water soluble material comprising a polyvinyl alcohol or.a polyvinyl alcohol derivative to form a domed body wall of the body portion;

• placing the laundry detergent liquid or gel having a viscosity of between 0,1 and 1 Pa.s (100 and 1000 centipose) when measured at 20°C and 105 s^-1 and in the body portion;

• superposing a second sheet of a water soluble material comprising a polyvinyl alcohol or a polyvinyl alcohol derivative over the first sheet; and

• sealing the first and second sheets along a continuous region of the superposed sheets surrounding the laundry detergent to form a generally rectangular or square base wall of the body portion.

12. A process according to claim 11, characterised in that the first sheet of water-soluble material is thermoformed by means of a heating plate.

13. A process according to claim 11 or claim 12, characterised in that prior to the addition of the substance a vacuum is applied to the thermoformed body wall to maintain the shape of the body portion at least until after the sealing step.

14. A process according to any preceding claim characterised in that the first and second sheets are heat sealed.

15. A process for the machine washing of laundry by employing a package according to any of claims 1 to 9 comprising the steps of:

• placing at least one package according to any of claims 1 to 9 into the machine along with the laundry to be washed; and

• carrying out a washing operation.

Ansprüche

1. Wasserlösliche Verpackung, die ein Waschmittel zur Freisetzung bei Auflösung der Verpackung enthält, dadurch gekennzeichnet, dass:

- die Verpackung einen Körperteil zum Enthalten des Waschmittelfluids hat, umfassend eine erste Folie eines wasserlöslichen Materials, die unter Bildung einer Körperwand des Körperteils thermogeformt ist, und eine zweite Folie eines wasserlöslichen Materials, die über die erste Folie gelegt ist und entlang eines kontinuierlichen Bereichs der übereinander gelegten Folien an diese gesiegelt ist, um eine im Allgemeinen rechteckige oder quadratische Basiswand des Körperteils zu bilden;

- der erste Körperteil der Verpackung im Allgemeinen kuppelförmig ist,

- die erste und zweite Folie aus wasserlöslichem Material einen Polyvinylalkohol oder ein Polyvinylalkoholderivat umfassen,

- die maximale Höhe der Körperwand über der Basiswand weniger oder gleich der maximalen Breite der Basiswand ist,

- das Waschmittel eine Flüssigkeit oder ein Gel mit einer Viskosität von zwischen 0,1 und 1 Pa.s (100 und 1000 Centipoise) bei Messung bei 20 °C und 105 s^-1 ist.

2. Verpackung gemäß Anspruch 1, dadurch gekennzeichnet, dass die Basiswand konvex ist.

3. Verpackung gemäß Anspruch 1 oder Anspruch 2, dadurch gekennzeichnet, dass die Viskosität des Waschmittels zwischen 0,3 und 0,8 Pa.s (300 und 800 Centipoise) bei Messung bei 20 °C und 105 s^-1 ist.

4. Verpackung gemäß Anspruch 3, dadurch gekennzeichnet, dass die Viskosität des Waschmittels zwischen 0,5 und 0,7 Pa.s (500 und 700 Centipoise) bei Messung bei 20 °C und 105 s^-1 ist.

5. Verpackung gemäß Anspruch 3, dadurch gekennzeichnet, dass die Viskosität etwa 0,3 Pa.s (300 Centipoise) bei Messung bei 20 °C und 105 s^-1 ist.

6. Verpackung gemäß Anspruch 4, dadurch gekennzeichnet, dass die Viskosität etwa 0,6 Pa.s (600 Centipoise) bei Messung bei 20 °C und 105 s^-1 ist.

7. Verpackung gemäß einem vorangehenden Anspruch, dadurch gekennzeichnet, dass die wärmegeformte Körperwand eine im Wesentlichen gleichmäßige Dicke hat.

8. Verpackung gemäß einem vorangehenden Anspruch, dadurch gekennzeichnet, dass das Material eine Dicke von zwischen 20 und 80 Mikrometer hat.

9. Verpackung gemäß Anspruch 8, dadurch gekennzeichnet, dass das Material eine Dicke von zwischen 40 und 60 Mikrometer hat.

10. Verpackung gemäß einem vorangehenden Anspruch, dadurch gekennzeichnet, dass das Waschmittel zwischen 1 und 5 % Wasser umfasst.

11. Verfahren zur Herstellung einer wasserlöslichen Verpackung, die einen Körperteil hat, der ein(e) Waschmittelflüssigkeit oder -gel mit einer Viskosität von zwischen 0,1 und 1 Pa.s (100 bis 1000 Centipoise) bei Messung bei 20 °C und 105 s^-1 zur Freisetzung bei Auflösung der Verpackung enthält, dadurch gekennzeichnet, dass das Verfahren die Schritte:

• Thermoformen einer ersten Folie eines wasserlöslichen Materials, das einen Polyvinylalkohol oder ein Polyvinylalkoholderivat umfasst, unter Bildung einer kuppelförmigen Körperwand des Körperteils;

• Platzieren der/des Waschmittelflüssigkeit oder -gels mit einer Viskosität von zwischen 0,1 und 1 Pa.s (100 und 1000 Centipoise) bei Messung bei 20 °C und 105 s^-1 in dem Körperteil;

• Legen einer zweiten Folie eines wasserlöslichen Materials, das ein Polyvinylalkohol oder ein Polyvinylalkoholderivat umfasst, über die erste Folie und

• Aneinandersiegeln der ersten und der zweiten Folie entlang eines kontinuierlichen Bereichs der übereinander gelegten Folien, der das Waschmittel umgibt, unter Bildung einer im Allgemeinen rechteckigen oder quadratischen Basiswand des Körperteils
umfasst.

12. Verfahren gemäß Anspruch 11, dadurch gekennzeichnet, dass die erste Folie aus wasserlöslichem Material mit Hilfe einer Heizplatte thermogeformt wird.

13. Verfahren gemäß Anspruch 11 oder 12, dadurch gekennzeichnet, dass vor Zugabe der Substanz ein Vakuum an die wärmegeformte Körperwand angelegt wird, um die Form des Körperteils wenigstens bis nach dem Versiegelungsschritt aufrechtzuerhalten.

14. Verfahren gemäß einem vorangehenden Anspruch, dadurch gekennzeichnet, dass die erste und zweite Folie heißgesiegelt werden.

15. Verfahren zum Maschinenwaschen von Wäsche durch Verwenden einer Verpackung gemäß einem der Ansprüche 1 bis 9, das die Schritte:

• Platzieren wenigstens einer Verpackung gemäß einem der Ansprüche 1 bis 9 zusammen mit der zu waschenden Wäsche in der Maschine und

• Durchführen eines Waschvorgangs
umfasst.

Revendications

1. Emballage hydrosoluble contenant un détergent pour linge à libérer lors de la dissolution de l'emballage, caractérisé en ce que :

• l'emballage possède une portion corps pour contenir le fluide détergent pour linge, comprenant une première feuille d'un matériau hydrosoluble thermoformée pour former une paroi de la partie corps, et une seconde feuille de matériau hydrosoluble superposée sur la première feuille et scellée à celle-ci le long d'une zone continue des feuilles superposées pour former une paroi de base de la portion corps généralement rectangulaire ou carrée,

• la portion corps de l'emballage a généralement la forme d'un dôme,

• les première et seconde feuilles de matériau hydrosoluble comprennent un alcool polyvinylique ou un dérivé d'un alcool polyvinylique,

• la hauteur maximale de la paroi du corps au-dessus de la paroi de base est inférieure ou égale à la largeur maximale de la paroi de base,

• le détergent pour linge est un liquide ou un gel ayant une viscosité comprise entre 0,1 et 1 Pa.s (100 et 1000 centipoises) lorsqu'elle est mesurée à 20°C et 105 s^-1.

2. Emballage selon la revendication 1, caractérisé en ce que la paroi de base est convexe.

3. Emballage selon la revendication 1 ou la revendication 2, caractérisé en ce que la viscosité du détergent pour linge est comprise entre 0,3 et 0,8 Pa.s (300 et 800 centipoises) lorsqu'elle est mesurée à 20°C et 105 s^-1.

4. Emballage selon la revendication 3, caractérisé en ce que la viscosité du détergent pour linge est comprise entre 0,5 et 0,7 Pa.s (500 et 700 centipoises) lorsqu'elle est mesurée à 20°C et 105 s^-1.

5. Emballage selon la revendication 3, caractérisé en ce que la viscosité est d'environ 0,3 Pa.s (300 centipoises) lorsqu'elle est mesurée à 20°C et 105 s^-1.

6. Emballage selon la revendication 4, caractérisé en ce que la viscosité est d'environ 0,6 Pa.s (600 centipoises) lorsqu'elle est mesurée à 20°C et 105 s^-1.

7. Emballage selon l'une quelconque des revendications précédentes, caractérisé en ce que la paroi du corps thermoformée a une épaisseur uniforme dans l'ensemble.

8. Emballage selon l'une quelconque des revendications précédentes, caractérisé en ce que le matériau a une épaisseur comprise entre 20 et 80 microns.

9. Emballage selon la revendication 8, caractérisé en ce que le matériau a une épaisseur comprise entre 40 et 60 microns.

10. Emballage selon l'une quelconque des revendications précédentes, caractérisé en ce que le détergent pour linge comprend entre 1 et 5 % d'eau.

11. Procédé de production d'un emballage hydrosoluble ayant une partie corps contenant un liquide ou un gel détergent pour linge ayant une viscosité comprise entre 0,1 et 1 Pa.s (100 et 1000 centipoises) lorsqu'elle est mesurée à 20°C et 105 s^-1, à libérer lors de la dissolution de l'emballage, caractérisé en ce que le procédé comprend les étapes :

• thermoformer une première feuille d'un matériau hydrosoluble comprenant un alcool polyvinylique ou un dérivé d'un alcool polyvinylique pour former une paroi de la partie corps ayant la forme d'un dôme;

• placer dans la partie corps le liquide ou le gel de détergent pour linge ayant une viscosité comprise entre 0,1 et 1 Pa.s (100 à 1000 centipoises) lorsqu'elle est mesurée à 20°C et 105 s^-1 ;

• superposer une seconde feuille d'un matériau hydrosoluble comprenant un alcool polyvinylique ou un dérivé d'un alcool polyvinylique sur la première feuille ; et

• sceller les première et seconde feuilles le long d'une zone continue des feuilles superposées entourant le détergent pour linge, de sorte à former une paroi de base généralement rectangulaire ou carrée de la partie corps.

12. Procédé selon la revendication 11, caractérisé en ce que la première feuille de matériau hydrosoluble est thermoformée au moyen d'une plaque chauffante.

13. Procédé selon la revendication 11 ou la revendication 12, caractérisé en ce qu'avant l'ajout de la substance un vide est appliqué à la paroi du corps thermoformée pour maintenir la forme de la partie corps au moins jusqu'à la fin de l'étape de scellage.

14. Emballage selon l'une quelconque des revendications précédentes, caractérisé en ce que les première et seconde feuilles sont thermoscellées.

15. Procédé pour laver le linge en machine en utilisant un emballage selon l'une quelconque des revendications 1 à 9, comprenant les étampes :

• placer au moins un emballage selon l'une quelconque des revendications 1 à 9 dans la machine avec le linge à laver ; et

• effectuer une opération de lavage.

Drawing