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Designated Contracting States: |
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AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT SE SI SK TR |
| (30) |
Priority: |
01.02.2002 US 353849 P
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| (43) |
Date of publication of application: |
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27.10.2004 Bulletin 2004/44 |
| (73) |
Proprietor: Picometrix, LLC |
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Ann Arbor, MI 48104 (US) |
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| (72) |
Inventors: |
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- KO, Cheng, C.
Ann Arbor, MI 48105 (US)
- LEVINE, Barry
Livingston, NJ 07039 (US)
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| (74) |
Representative: Patent- und Rechtsanwälte
Dr. Solf & Zapf |
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Candidplatz 15 81543 München 81543 München (DE) |
| (56) |
References cited: :
JP-A- 2001 077 401 US-A- 4 597 004 US-A- 5 576 559 US-A- 6 081 019 US-A1- 2001 042 869
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US-A- 4 068 252 US-A- 4 686 550 US-A- 5 818 096 US-A- 6 107 652 US-A1- 2003 021 322
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- NICCOL GBP O RINALDI: "Analysis of the Depletion Layer of Exponentially Graded P-N
Junctions with Nonuniformly Doped Substrates", IEEE TRANSACTIONS ON ELECTRON DEVICES,
IEEE SERVICE CENTER, PISACATAWAY, NJ, US, vol. 47, no. 12, 1 December 2000 (2000-12-01),
XP011017449, ISSN: 0018-9383
- TADAO ISHIBASHI ET AL: "High-Speed Response of Uni-Traveling-Carrier Photodiodes",
JAPANESE JOURNAL OF APPLIED PHYSICS, vol. 36, no. Part 1, No. 10, 15 October 1997
(1997-10-15), pages 6263-6268, XP055091594, ISSN: 0021-4922, DOI: 10.1143/JJAP.36.6263
- STREIT D C ET AL: "Effect of exponentially graded base doping on the performance of
GaAs/AlGaAs heterojunction bipolar transistors", IEEE ELECTRON DEVICE LETTERS, IEEE
SERVICE CENTER, NEW YORK, NY, US, vol. 12, no. 5, 1 May 1991 (1991-05-01), pages 194-196,
XP011406118, ISSN: 0741-3106, DOI: 10.1109/55.79553
- JORDAN A G ET AL: "Photoeffect on diffused P-N junctions with integral field gradients",
IRE TRANSACTIONS ON ELECTRON DEVICES, IEEE, USA, vol. 2, no. 4, 1 October 1960 (1960-10-01)
, pages 242-251, XP011221859, ISSN: 0096-2430
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FIELD OF THE INVENTION
[0001] The present invention relates to a semiconductor-based photodetector, and in particular
to a high-speed, broad bandwidth photodetector having enhanced absorption characteristics.
BACKGROUND AND SUMMARY OF THE INVENTION
[0002] There is a well-known tradeoff between high speed and sensitivity in a photodetector.
High bandwidth signal detection requires a short transit time of the carriers and
thus a thin absorption layer. However, the geometrical constraints on the absorption
layer thickness results in a reduced absorption and lower responsivity.
[0003] One type of semiconductor-based photodetector is termed a p-i-n junction diode, or
a PIN diode. This type of structure is generally composed of a number of solid semiconductive
sandwiched together in an epitaxial structure. In particular, a p-type semiconductor
material and an n-type semiconductor region are separated by an intrinsic semiconductor.
[0004] In a PIN diode, the depletion layer extends into each side of junction by a distance
that is inversely proportional to the doping concentration. Thus, the p-i depletion
layer extends well into the intrinsic material, as does the depletion layer of the
i-n junction. Accordingly, a PIN diode functions like a p-n junction with a depletion
layer that encompasses the entirety of the intrinsic material. The primary advantages
inherent to this structure are twofold. First, the addition of the intrinsic layer
permits a fractional increase in the amount of light to be captured by the diode.
Secondly, due to the extended depletion layer, the PIN diode has a very small junction
capacitance and corresponding fast response.
[0005] Most attempts at increasing the speed of PIN diodes have focused on reducing the
capacitance at the junction. At least one proposed design has included an undoped
drift region for this purpose, effectively increasing the size of the intrinsic portion
of the diode. Although this solution is suitable for decreasing the junction capacitance,
it unfortunately increases the transit time for the carriers and thus reduces the
response time of the photodetector. As such, there is a need in the art for an improved
photodetector that strikes the proper balance between capacitance and response time,
while increasing the responsivity of the device.
[0007] Accordingly, the present invention refers to a PIN photodiode in accordance with
the subject-matter of claim 1. The photodiode has a first p-type semiconductor layer
and an n-type semiconductor layer coupled by a second p-type semiconductor layer.
The second p-type semiconductor layer has graded doping along the path of the carriers.
In particular, the doping is concentration graded from a high value near the anode
to a lower p concentration towards the cathode. By grading the doping in this way,
an increase in absorption is achieved, improving the responsivity of the device. Although
this doping increases the capacitance relative to an intrinsic semiconductor of the
same thickness, the pseudo electric field that is created by the graded doping gives
the electrons a very high velocity which more than compensates for this increased
capacitance. Further embodiments and advantages of the present invention are discussed
below with reference to the figures.
BRIEF DESCRIPTION OF THE DRAWINGS
[0008]
Figure 1 is an energy band diagram of a pin photodiode in accordance with the present
invention.
Figure 2 is a cross-sectional view of a basic configuration of a pin photodiode in
a surface illuminated structure in accordance with the present invention.
Figure 3 is a graph representing the relationship between the electric field and the
electron velocity according to an aspect of the present invention.
Figure 4 is a graph representing the relationship between the doping concentration
and the relative depth of a semiconductor layer of the present invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
[0009] In accordance with the present invention, an epitaxial structure is provided for
photoconductive purposes. The photoconductive structure is a modified PIN diode that
is optimized for increased performance through an enhanced layer having a graded doping
concentration. The particulars of the structure and method of manufacture of the present
invention are discussed further herein.
[0010] Referring to Figure 1, an energy band diagram of a PIN photodiode 10 shows the relative
energy levels of the semiconductor materials that form the photodiode 10. In particular,
the photodiode 10 is comprised of a group of semiconductor materials, including a
first p-type semiconductor layer 14, a second p-type semiconductor layer 16, and an
n-type semiconductor layer 18. An anode layer 12 is shown adjacent to the first p-type
semiconductor layer 14 to collect holes.
[0011] The first p-type semiconductor layer 14 is selected from a group comprising tertiary
semiconductors, or group III-V semiconductors. Accordingly, the first p-type semiconductor
layer 14 is either two elements from group III combined with one element from group
V or the converse, two elements from group V combined with one element from group
III. A table of representative groups of the periodic table is shown below.
| GROUP II |
GROUP III |
GROUP IV |
GROUP V |
| Zinc (Zn) |
Aluminum (Al) |
Silicon (Si) |
Phosphorus (P) |
| Cadmium (Cd) |
Gallium (Ga) |
Germanium (Ge) |
Arsenic (As) |
| Mercury (Hg) |
Indium (In) |
|
Antimony (Sb) |
[0012] In the preferred embodiment, the first p-type semiconductor layer 14 is InAlAs. However,
it is understood that the first p-type semiconductor layer 14 may be any tertiary
semiconductor that provides the necessary bandgap for optimized operation of the photodiode
10.
[0013] The n-type semiconductor layer 18 is also selected from a group comprising tertiary
semiconductors, or group III-V semiconductors. As before, the n-type semiconductor
layer 18 is either two elements from group III combined with one element from group
V or the converse, two elements from group V combined with one element from group
III. In the preferred embodiment, the n-type semiconductor layer 18 is InAlAs. However,
it is understood that the n-type semiconductor layer 18 may be any tertiary semiconductor
that provides the necessary bandgap for optimized operation of the photodiode 10.
[0014] The second p-type semiconductor layer 16 is also selected from a group comprising
tertiary semiconductors, or group III-V semiconductors. In the preferred embodiment,
the second p-type semiconductor layer 16 is InGaAs with a graded doping concentration.
However, it is understood that the second p-type semiconductor layer 16 may be any
tertiary semiconductor that provides the necessary low bandgap for optimized operation
of the photodiode 10.
[0015] In order to achieve a graded doping concentration, the second p-type semiconductor
layer 16 is not doped in a typical manner. In general, a p-type semiconductor is fabricated
by using dopants with a deficiency of valence electrons, also known as acceptors.
The p-type doping results in an abundance of holes. For example, in a type III-V semiconductor,
some of the group III atoms may be replaced with atoms from group II, such as Zn or
Cd, thereby producing a p-type material. Similarly, as group IV atoms act as acceptors
for group V atoms and donors for group III atoms, a group IV doped III-V semiconductor
will have an excess of both electrons and holes.
[0016] Figure 2 is a cross-sectional view of a basic configuration of a photodiode 10 in
a surface illuminated structure designed in accordance with the present invention.
A substrate layer 20 is provided for growing the semiconductor structure. The n-type
semiconductor layer 18 is deposited upon the substrate. The first p-type semiconductor
layer 14 and the second p-type semiconductor layer 16 are deposited in a manner such
that the second p-type semiconductor layer 16 is directly adjacent to the n-type semiconductor
layer 18. As before, an anode layer 12 is deposited on the first p-type semiconductor
layer 14 for collecting holes. Also shown is a cathode layer 22, or n-type contact
layer, for collecting electrons.
[0017] As noted, it is a feature of the second p-type semiconductor layer 16 that it includes
a graded doping concentration. The presence of dopants in the second p-type semiconductor
layer 16 is controlled in order to optimize the performance of the photodiode. A first
concentration 15 is located near the first p-type semiconductor 14, and a second concentration
17 is directly adjacent to the n-type semiconductor 18. Preferably, a depth D of the
second p-type semiconductor layer 16 is between 800 and 1,000 angstroms deep, i.e.
the dimension parallel to the travel of the carriers.
[0018] In the preferred embodiment, the first concentration 15 is greater than the second
concentration 17. In particular, the first concentration 15 is located at a position
x
o and defines a dopant concentration p
o. A preferred doping concentration gradient is governed by the following equation:

over the depth D of the second p-type semiconductor layer 16 for all x and D greater
than zero. A generic representation of the dopant concentration p is shown in Figure
4.
[0019] The graded doping structure of the second p-type semiconductor layer 16 results in
improved performance of the photodiode 10. During operation, incident light is absorbed
in the second p-type semiconductor layer 16 of the photodiode 10. The light that is
absorbed in the second concentration 17 part of the second p-type semiconductor layer
16 produces electrons and holes which drift to the anode 12 and cathode 22 under the
influence of the large drift electric field. Although this is the usual situation
in standard uniformly low doped absorber PIN photodetectors, in the present invention,
the photoresponse of the carriers is more complex.
[0020] The electrons generated in the second concentration 17 part of the second p-type
semiconductor layer 16 reach the cathode with their saturation velocity and are collected.
The holes generated in the second concentration 17 part of the second p-type semiconductor
layer 16 travel to the anode 12, thus entering the first concentration 15 where the
concentration of dopants is relatively high and where they are collected, thus ending
their transit time.
[0021] By way of comparison, the light that is absorbed in the first concentration 15 part
of the second p-type semiconductor layer 16 also produces electrons and holes. In
this case however, the holes are readily collected in the first concentration 15 and
thus do not add substantially to the transit time of the carriers or reduce the bandwidth
of the photodiode 10. Accordingly, insofar as the holes are concerned, the graded
doping concentration of the photodiode 10 does not add to their transit time or reduce
the detector bandwidth in either in the first concentration 15 or the second concentration
17.
[0022] Another aspect of the graded doping concentration of the second p-type semiconductor
layer 16 is the creation of a pseudo-electric field. The electrons generated in the
first concentration 15 region are subject to this pseudo-field shown below as

where k is Boltzman's constant, T is the temperature, q is the charge of an electron,
and the value

is the doping concentration gradient.
[0023] The pseudo-field E produces an "overshoot" electron velocity, i.e. the electron velocity
is potentially many times faster than the saturation velocity. A typical electron
saturation velocity is on the order of 5x10
6 cm/sec. However, the exponential gradient shown in Equation (1) with D=1,000 angstroms
yields a field E=2.5kV/cm, which corresponds to an electron overshoot velocity as
large as 3x10
7 cm/sec. A graph depicting the relationship between the magnitude of the pseudo-field
E and the electron velocity is shown in Figure 3.
[0024] As described, the present invention improves upon the state of the art in photodiodes
by implementing a graded doping concentration in the intrinsic region of a PIN photodiode.
In such a manner, the net absorption of a photodiode can be increased without substantially
reducing the overall bandwidth of the device. It is further understood that it may
be advantageous to optimize the overall speed by adjusting the doping concentration,
the capacitance of the device, and the total thickness of the absorption region. It
should be apparent to those skilled in the art that the above-described embodiments
are merely illustrative of but a few of the many possible specific embodiments of
the present invention.
1. A PIN photodiode (10) comprising:
a first p-type semiconductor layer (14);
an n-type semiconductor layer (18);
a second p-type semiconductor layer (16) disposed between the first p-type semiconductor
layer (14) and the n-type semiconductor layer (18) such that the second p-type semiconductor
(16) is directly adjacent to the n-type semiconductor (18), the second p-type semiconductor
layer (16) having a graded doping concentration;
a substrate (20), the n-type semiconductor layer (18) being grown on the substrate
(20);
an anode layer (12) for collecting holes;
a cathode layer (22) for collecting electrons;
wherein the graded doping concentration defines a first concentration (15) adjacent
to the first p-type semiconductor layer (14) and a second concentration (17) adjacent
to the n-type semiconductor layer (18), and further wherein the first concentration
(15) is greater than the second concentration (17);
wherein incident light is absorbed in the second p-type semiconductor layer (16),
the incident light that is absorbed in the second concentration (17) part of the second
p-type semiconductor layer (16) produces electrons and holes which drift to the anode
and cathode;
wherein electrons generated in the second concentration (17) part of the second p-type
semiconductor layer (16) reach the cathode with their saturation velocity and are
collected, the holes generated in the second concentration (17) part of the second
p-type semiconductor layer (16) travel to the anode (12),
wherein the incident light that is absorbed in the first concentration (15) part of
the second p-type semiconductor layer (16) produces electrons and holes, wherein the
holes are collected in the first concentration (15) part;
and wherein said electrons in the first concentration (15) part are subject to a pseudo
field capable of providing them with an overshoot electron velocity, the pseudo field
being governed by the following equation:

where k is Boltzman's constant, T is the temperature, q is the charge of an electron,
and the value

is the doping concentration gradient, and
wherein the first concentration (15) is located at a position xo and defines a concentration po, and further wherein the graded doping concentration is governed by the following
equation:

over the depth D of the second p-type semiconductor layer (16) for all x and for
D greater than zero.
2. The photodiode of claim 1 wherein the first p-type semiconductor layer (14) is InAlAs.
3. The photodiode of claim 1 wherein the n-type semiconductor layer (18) is InAlAs.
4. The photodiode of claim 1 wherein the second p-type semiconductor layer (16) is InGaAs.
5. The photodiode of one of the foregoing claims wherein the depth D is between 800 and
1000 angstroms in length.
1. PIN-Photodiode (10), die folgendes aufweist:
eine erste p-Typ-Halbleiterschicht (14);
eine n-Typ-Halbleiterschicht (18);
eine zweite p-Typ-Halbleiterschicht (16), die zwischen der ersten p-Typ-Halbleiterschicht
(14) und der n-Typ-Halbleiterschicht (18) so angeordnet ist, dass die zweite p-Typ-Halbleiterschicht
(16) direkt an die n-Typ-Halbleiterschicht (18) anschließt, wobei die zweite p-Typ-Halbleiterschicht
(16) eine abgestufte Dotierungskonzentration aufweist;
ein Substrat (20), wobei die n-Typ-Halbleiterschicht (18) auf dem Substrat (20) gezüchtet
wurde;
eine Anodenschicht (12) zum Sammeln von Löchern;
eine Kathodenschicht (22) zum Sammeln von Elektronen;
wobei die abgestufte Dotierungskonzentration eine erste Konzentration (15) anschließend
an die erste p-Typ-Halbleiterschicht (14) und eine zweite Konzentration (17) anschließend
an die n-Typ-Halbleiterschicht (18) definiert, und weiterhin wobei die erste Konzentration
(15) größer ist als die zweite Konzentration (17);
wobei einfallendes Licht in der zweiten p-Typ-Halbleiterschicht (16) absorbiert wird,
das einfallende Licht, das in dem zweiten Konzentrations (17)-Abschnitt der zweiten
p-Typ-Halbleiterschicht (16) absorbiert wird, Elektronen und Löcher erzeugt, die zur
Anode und Kathode wandern;
wobei im zweiten Konzentrations (17)-Abschnitt der zweiten p-Typ-Halbleiterschicht
(16) erzeugte Elektronen die Kathode mit ihrer Sättigungsgeschwindigkeit erreichen
und gesammelt werden, die in der zweiten Konzentrations (17)-Abschnitt der zweiten
p-Typ-Halbleiterschicht (16), erzeugten Löcher zur Anode (12) wandern;
wobei das einfallende Licht, das im ersten Konzentrations (15)-Abschnitt der zweiten
p-Typ-Halbleiterschicht (16) absorbiert wird, Elektronen und Löcher erzeugt, wobei
die Löcher im ersten Konzentrations (15)-Abschnitt gesammelt werden;
wobei die Elektronen im ersten Konzentrations (15)-Abschnitt einem Pseudo-Feld unterzogen
werden, das in der Lage ist, ihnen eine Elektronen-Überhöhungsgeschwindigkeit zu verleihen,
wobei das Pseudofeld durch die folgende Gleichung vorgegeben wird:

wobei k die Boltzmann-Konstante ist, T die Temperatur ist, q die Ladung eines Elektrons
ist, und der Wert
dp/
dx der Dotierungskonzentrationsgradient ist, und
wobei die erste Konzentration (15) an einer Position x
0 liegt und eine Konzentration p
0 definiert, und weiterhin wobei die abgestufte Dotierungskonzentration durch die folgende
Gleichung:

über die Tiefe D der zweiten p-Typ-Halbleiterschicht (16) für alle x und für D größer
als Null vorgegeben wird.
2. Photodiode nach Anspruch 1, wobei die erste p-Typ Halbleiterschicht (14) InAlAs ist.
3. Photodiode nach Anspruch 1, wobei die n-Typ Halbleiterschicht (18) InAlAs ist.
4. Photodiode nach Anspruch 1, wobei die zweite p-Typ Halbleiterschicht (16) InGaAs ist.
5. Photodiode nach einem der vorangehenden Ansprüche, wobei die Tiefe D in der Länge
zwischen 800 und 1000 Å beträgt.
1. Photodiode PIN (10), comprenant :
une première couche de semi-conducteur de type p (14) ;
une couche de semi-conducteur de type n (18) ;
une seconde couche de semi-conducteur de type p (16) disposée entre la première couche
de semi-conducteur de type p (14) et la couche de semi-conducteur de type n (18) de
telle sorte que le second semi-conducteur de type p (16) est directement adjacente
au semi-conducteur de type n (18), la seconde couche de semi-conducteur de type p
(16) ayant une concentration de dopage graduée ;
un substrat (20), la couche de semi-conducteur de type n (18) étant développée sur
le substrat (20) ;
une couche d'anode (12) pour collecter des trous;
une couche de cathode (22) pour collecter des électrons ;
dans laquelle la concentration de dopage graduée définit une première concentration
(15) adjacente à la première couche de semi-conducteur de type p (14) et une seconde
concentration (17) adjacente à la couche de semi-conducteur de type n (18), et en
outre dans laquelle la première concentration (15) est supérieure à la seconde concentration
(17) ;
dans laquelle la lumière incidente est absorbée dans la seconde couche de semi-conducteur
de type p (16), la lumière incidente qui est absorbé dans la partie de seconde concentration
(17) de la seconde couche de semi-conducteur de type p (16) produit des électrons
et des trous qui dérivent vers l'anode et la cathode ;
dans laquelle des électrons générés dans la partie de seconde concentration (17) de
la seconde couche de semi-conducteur de type p (16) atteignent la cathode à leur vitesse
de saturation et sont collectés, les trous générés dans la partie de seconde concentration
(17) de la seconde couche de semi-conducteur de type p (16) se déplacent jusqu'à l'anode
(12),
dans laquelle la lumière incidente qui est absorbée dans la partie de première concentration
(15) de la seconde couche de semi-conducteur de type p (16) produit des électrons
et des trous, dans laquelle les trous sont collectés dans la partie de première concentration
(15) ; et
dans laquelle lesdits électrons dans la partie de première concentration (15) sont
soumis à un pseudo champ capable de leur fournir une vitesse d'électrons de dépassement,
le pseudo champ étant régi par l'équation suivante :

où k est la constante de Boltzman, T est la température, q est la charge d'un électron,
et la valeur

est le gradient de concentration de dopage, et
dans laquelle la première concentration (15) est située à une position x
o et définit une concentration p
o, et dans lequel, en outre, la concentration de dopage graduée est régie par l'équation
suivante :

sur la profondeur D de la seconde couche de semi-conducteur de type p (16) pour tout
x et pour D supérieur à zéro.
2. Photodiode selon la revendication 1, dans laquelle la première couche de semi-conducteur
de type p (14) est de type InAIAs.
3. Photodiode selon la revendication 1, dans laquelle la couche de semi-conducteur de
type n (18) est de type InAIAs.
4. Photodiode selon la revendication 1, dans laquelle la seconde couche de semi-conducteur
de type p (16) est de type InGaAs.
5. Photodiode selon l'une des revendications précédentes, dans laquelle la profondeur
D est comprise entre 800 et 1000 angströms de longueur.