ELECTROCHEMICAL CELL COMPRISING CARBONACEOUS MATERIAL AND MOLYBDENUM CARBIDE AS ANODE

Description

Technical Field

[0001] The present invention relates to non-aqueous secondary lithium-ion electrochemical cells and batteries.

Background Art

[0002] Lithium-ion batteries are considered to be the rechargeable batteries of the future for portable electronics to aerospace to vehicular applications. In a known construction for a lithium-ion battery, carbon or graphite is used as an anode, a lithiated transition metal intercalation compound is used as a cathode and LiPF₆ is used as an electrolyte in carbonate-based nonaqueous solvents.

[0003] The electrochemical process is the uptake of lithium ions at the anode during charge and their release during discharge, rather than lithium plating and stripping as occurs in metallic lithium rechargeable battery systems. As metallic lithium is not present in the cell, lithium-ion cells have enhanced safety and a longer cycle life than the cells containing metallic lithium.

[0004] At present, disordered carbon (hard carbon) and ordered carbon (graphite) are used as anodes in commercial lithium-ion batteries. The carbonaceous materials can deliver a reversible specific capacity of 372 mAh/g, corresponding to the chemical formula LiC₆ as compared to 3830 mAh/g for metallic lithium. The practical reversible capacity of these carbonaceous materials is even lower in the range of 300-340 mAh/g.

[0005] Other carbonaceous materials, also of disordered structure and are known as "soft carbon", of high reversible capacity have been prepared by pyrolysis of suitable starting materials. Sato et al (Science, 264, 556, 1994) disclosed a carbonaceous material prepared by heating polyparaphenylene at 700°C which has a reversible capacity of 680 mAh/g. Mabuchi et al (Seventh International Meeting on Lithium Batteries, Extended Abstracts, Page 212, Boston, Massachusetts, 1994) disclosed a low density carbonaceous material prepared by heating coal tar pitch at 700°C which has a reversible capacity of about 750 mAh/g. Yamada et al (U. S. Patent, 5,834,138, Nov. 10, 1998) disclosed a carbonaceous material prepared by heat treatment of coffee beans, tea leaves, corns, etc. at 1100-1200°C. The carbonaceous material delivers a reversible capacity of 500 mAh/g.

[0006] These values of reversible capacities are much greater than that of the carbonaceous materials used in commercial lithium-ion cells. However, low density and very high irreversible capacity loss of the above carbonaceous materials limit their commercial use as anodes for lithium-ion batteries.

[0007] It has been suggested that the reversible capacity of anodes formed of carbonaceous materials can be increased by the addition of other elements to the carbonaceous materials. For example, the addition of small amounts of phosphorous (European Patent Application No. EP 486950) and boron (Japanese Application Laid-Open No. 03-245458) are alleged to enhance the specific capacity of a carbonaceous anode. Moreover, Canadian Application Serial No. 2,098,248 discloses that substituting electron acceptors (such as boron, aluminum, etc.) for carbon atoms in the structure of the carbonaceous materials will enhance anode capacity.
Toyoguchi (Japanese Publication No. 10-05299) discloses a secondary battery that includes a carbide compound containing an alkali metal in a charged state. Saito (Japanese Publication No. 06-290782) discloses an electrolyte leak proof secondary battery containing an electrode material consisting of at least one carbide of chromium, silicon, colbalt, zirconium, tungsten, germanium, tantalum, titanium, iron, niobium, nickel, vanadium, boron, halfnium, and molybdenum.
Nagamine et al. (U.S. Patent No. 5,932,373) disclose a non-aqueous electrolyte secondary cell comprising (i) a positive electrode including a lithium-transition metal composite oxide material, (ii) a negative electrode including a graphite material prepared by carbonizing an organic compound to form a carbide, and (iii) an electrolyte solution comprising a lithium salt dissolved in a non-aqueous solvent. Okamura et al. (Japanese Publication No. 10-112316) disclose a non-aqueous electrolyte secondary battery for portable equipment, wherein the negative electrode comprises a carbide material of formula M_XC wherein x = 1-4 and M is a transition metal element substituted by Li. The negative electrode is made by mixing metal carbide with polyvinylidene fluoride as a binding agent. Bito et al (U.S. Patent No. 5,939,224) disclose a nonaqueous electrolyte secondary battery employing a carbide containing an alkali metal in a charged stage as a negative electrode active material wherein the carbide is an ionic bond type carbide, a covalent bond type carbide, or an intermetallic compound.
Choi et al (U.S. Publication No. 2002-0012845 A1) disclose a negative active material for rechargeable lithium battery and a method of preparing the same, wherein the negative active material comprises crystalline carbon having a dispersed element serving as graphitization catalyst selected from the group consisting of transition metals, alkaline metals, alkaline earth metals, semi-metals of Group 3A, Group 3B, Group 4A and Group 4B of the periodic table, elements of Group 5A, and elements of Group 5B, and carbides thereof. Sheem et al (U.S. Patent No. 6,355,377 Bl) disclose a negative active material for a rechargeable lithium battery comprising a crystalline carbon core, and semi-crystalline carbon shell including metal boride and metal carbide serving as graphitization catalyst and changing the structure of the surrounding carbon. Idota et al (U.S. Patent No. 5,686,203) disclose a non-aqueous secondary battery comprising a positive electrode, a negative electrode and a non-aqueous electrolyte. The electrode mixture for positive electrode contains the positive electrode active material comprising a compound in which anions can be inserted and at least one member selected from group consisting of transition metals, elements of Group IIIB and IVB (except C) and carbides thereof.

Disclosure of Invention

[0008] The present invention provides a new and different concept for enhancing the reversible capacity of the carbonaceous material forming the active material of an anode in a lithium ion cell or battery. Specifically, the present invention provides a lithium-ion cell in which molybdenum carbide is combined with the carbonaceous material of the anode to enhance the reversible capacity of the carbonaceous material. This concept is also believed to promote the development of high specific energy and energy density lithium-ion cells and batteries.

[0009] Accordingly, it is the principal objective of the present invention to improve the reversible capacity of carbonaceous material forming the active material of an anode of a lithium-ion cell or battery.

[0010] Another objective of the present invention is to provide a novel and improved rechargeable lithium-ion cell and/or battery having high specific energy and energy density.

[0011] Further features of the present invention will become apparent from the following detailed description and the accompanying drawings.

Brief Description of the Drawings

[0012] Illustrative and presently preferred embodiments of the invention are shown in the accompanying drawing in which:

Figure 1 is a graph representing the discharge charge characteristics of a carbonaceous material containing 8% molybdenum carbide additive in demonstrating the principle of the present invention;

Figure 2 is a graph representing the charge capacity of a carbonaceous material containing 8% molybdenum carbide additive in demonstrating the principles of the present invention;

Figure 3 is a graph representing the discharge charge characteristics of a carbonaceous material without molybdenum carbide;

Figure 4 is a graph representing the charge capacity of a carbonaceous material without molybdenum carbide;

Figure 5 shows the cycling behavior of a lithium-ion cell made with molybdenum carbide added to carbonaceous anode material, in accordance with the present invention;

Figure 6 shows the cycling behavior of a lithium-ion cell made in accordance with known prior techniques; and

Figure 7 is a schematic representation of a lithium-ion cell (both in assembled and exploded stages) embodying an anode in accordance with the present invention.

Best Mode for Carrying Out the Invention

[0013] According to the present invention, a lithium-ion cell or battery comprises a negative electrode (anode) formed of carbonaceous materials combined with molybdenum carbide in an amount of less than 20% (by weight), and a positive electrode (cathode) containing LiCoO₂, LiNiCoO₂, LiNiCoAlO₂, LiNiO₂, LiMn₂O₄, LiMnO₂, LiV₂O₅, LiV₆O₁₃, LiTiS₂, Li₃FeN₂, Li₇VN₄ or combinations of these materials. The substrates for the negative and positive electrodes are preferably copper and aluminum foils, respectively.

[0014] The electrolyte used in a lithium-ion cell and/or battery of the present invention is a non-aqueous aprotic organic electrolyte and preferably a non-aqueous solution consisting of a solute, such as LiPF₆, LiBF₄, LiASF₆, LiCF₃SO₃, LiN(CF₃SO₂)₂ or LiClO₄, dissolved in a solvent such as propylene carbonate, ethylene carbonate, diethyl carbonate, ethyl methyl carbonate, and dimethyl carbonate as well as combinations of such materials.

[0015] The high reversible capacity of the lithium-ion cell or battery embodying an anode made of carbonaceous material combined with molybdenum carbide, in accordance with the present invention, provides ease of cell balance with high capacity cathode and results in a high capacity and high energy density lithium-ion cell. The present invention, however, is not limited to that theory. Suffice it to say, as shall become more apparent in the following Examples, it has been surprisingly discovered that a significant improvement in performance, beyond what might normally be expected, is possible with the lithium-ion cell and/or battery of the present invention.

[0016] There are a number of known approaches suitable for producing molybdenum carbide as described in the review article; E. R. Braithwaite and J. Haber, "Molybdenum: An Outline of its Chemistry and Uses" Studies in Inorganic Chemistry 19, Elsevier, 1994. The present invention is not limited to any specific approach to produce molybdenum carbide.

[0017] A preferred form of lithium-ion cell embodying a carbonaceous anode combined with molybdenum carbide is shown at 101 in Figure 7. The assembled cell 101 is shown with the anode, cathode, and electrolyte not shown but enclosed in a sealed sandwich structure with the anode electrically accessible by means of protruding conductive copper tab 102 and the lithiated intercalation compound cathode electrically accessible by means of a protruding conductive aluminum tab 103. The anode and cathode of the assembled cell 101 are separated by a porous separator that is permeated with an aprotic non-aqueous electrolyte that is in effective contact with both the anode and cathode.

[0018] More specifically, as shown in the exploded component portion of Figure 7, a pair of one-sided anodes 104A and 104B and a two-sided cathode 105, are configured to be assembled as a sandwich (cell 101) with the two-sided cathode 105 positioned between and separated from the respective anodes 104A and 104B by respective porous separators 106A and 106B that are permeated with an aprotic, non-aqueous electrolyte that is in effective contact with both the cathode and the facing anodes. Conductive copper tabs 102A and 102B are provided for the respective anodes 104A and 104B and an aluminum tab 103A is provided for the two-sided cathode 105, whereby the respective electrodes of the cell 101 are electrically accessible when assembled as a sandwich and enclosed within a sealed enclosure (not shown).

[0019] In the cell 101, the anodes 104A, 104B each comprises carbonaceous material (e.g of an ordered carbon such as graphite, or of a disordered carbon such as 'soft carbon' combined with molybdenum carbide and supported by a copper foil substrate. The cathode 105 may be formed of LiCoO₂, LiNiCoO₂, LiNiCoAlO₂, LiNiO₂, LiMn₂O₄, LiMnO₂, LiV₂O₅, LiV₆O₁₃, LiTiS₂, Li₃FeN₂, Li₇VN₄ or a combination of such materials, supported by an aluminum foil substrate. The respective anode and cathode electrodes are maintained spaced from one another by a respective electrically non-conductive separator that is permeable whereby the aprotic, non-aqueous electrolyte is carried by the separators 106A, 106B, and maintained in effective electrochemical contact with both the cathode and facing anode. The permeable separators may each be formed of a micro-porous poly-olefin film.

[0020] Although the respective anodes and cathodes of the cell 101 are shown as flat plates, it is to be understood that other configuration can be used, such as spiral or so-called jelly-roll configuration, wherein the respective anode and cathode electrodes are nevertheless maintained physically and electrically spaced from one another by a permeable spacer that carries the electrolyte and maintains it in effective electrochemical contact with the respective anode and cathode surfaces.

[0021] Moreover, there are different ways to form the anode of carbonaceous material and to combine the carbonaceous material with molybdenum carbide. For example, one way of combining the carbonaceous material with molybdenum carbide is to thoroughly mix molybdenum carbide with the carbonaceous material. Another way is to add molybdenum compound to carbonaceous material and heat-treat to convert the added molybdenum compound to molybdenum carbide. The present invention is directed to an anode for a lithium ion cell, in which carbonaceous material is combined with molybdenum carbide, but is not intended to be limited to any particular way of combining the carbonaceous material with the molybdenum carbide.

[0022] Also, it should be noted that it is preferred that a relatively small amount (by weight) of the molybdenum carbide is combined with the carbonaceous material. More specifically, it is preferred that the molybdenum carbide be in the range of 0.1 % to 15% (by weight). In addition, it is preferred that the particle size of molybdenum carbide in the second electrode is in the range of 0.05 µm to 3 µm.

[0023] It is to be understood that a plurality of electrochemical cells as described above can be used to assemble a battery of such cells by connecting the respective electrodes of the assembly of cells in an electrical circuit defining a battery (in a known manner) to produce a battery with the voltage or current characteristics as determined by the number of cells connected in series or parallel circuit relationship.

[0024] The following specific examples are given to illustrate the practice of the invention, but are not to be considered as limiting in any way. Examples 1 and 2 demonstrate the proof of principle of the present invention, and Examples 3, cells B1 and B2, and the first cell described in Example 4 (whose performance is illustrated in Figure 5) relate to lithium ion cells made according to the principles of the present invention.

Examples 1

[0025] 0.465 g of molybdenum carbide (of particle size of about 1µm) obtained from Climax Molybdenum Company, Tucson, Arizona was thoroughly mixed with 5.00 g of S26813 graphite obtained from Superior Graphite Co, Chicago, Illinois. The mixture was then used as the active material of the working electrode of a half-cell to evaluate the concept of the present invention. The half-cell included a working electrode made from the mixture of the graphite and molybdenum carbide, a metallic lithium counter electrode and 1M LiPF₆ electrolyte in a mixture (2:1 w/w) of ethylene carbonate/dimethyl carbonate (EC/DMC) solvents. A micro-porous poly-olefin (Celgard 2400) separator was used in between the working and counter electrodes to isolate them electronically. A slurry of the graphite-molybdenum carbide mixture and 6% poly(vinyledene fluoride) was prepared in dimethyl formamide (DMF) and coated on to a copper foil to make the working electrode. The counter electrode was made of metallic lithium of 50 µm thick press fitted to the expanded nickel mesh substrate.

[0026] The aprotic, non-aqueous 1M LiPF₆ electrolyte mixture permeated the micro-porous poly-olefin separator, whereby the electrolyte was in effective contact with both the positive and negative electrodes, which were nevertheless maintained space and electrically isolated from one another.

[0027] The developed half-cell was discharged (intercalation of lithium-ions) at a constant current of 2 mA to 0.00 V and then charged (de-intercalation of lithium-ions) at the same current rate to a cut-off voltage of 1.0 V. The discharge charge process was repeated several times (usually 2-5) until a fairly constant capacity value of discharge charge was obtained. Figure 1 shows the discharge charge characteristics of the developed half-cell containing the mixture of the graphite and molybdenum carbide according to the present invention. The charge capacity (de-intercalation of lithium ions) of the cell was 425 mAh/g as shown in Fig. 2, which is considered to be the reversible capacity of the working electrode (i.e. the electrode containing carbonaceous material and molybdenum carbide).

[0028] A half-cell was made with the same components as described above except the active material of the working electrode was S26813 graphite (Superior Graphite Co) without molybdenum carbide. The half-cell was discharged and charged under the same conditions as the previous half-cell. Figure 3 shows the discharge charge behavior of this half-cell containing the electrode material. The charge capacity of the cell was 330 mAh/g as shown in Fig. 4, which is almost 30% lower than that obtained in accordance with the present invention.

Example 2

[0029] Several half-cells were made as in Example 1 with as received BG39 graphite (Superior Graphite Co) and varying amounts of molybdenum carbide (Climax Molybdenum Co.) mixed with BG39 graphite as working electrodes and metallic lithium counter electrodes and an electrolyte comprising 1M LiPF₆ in a mixture of ethylene carbonate and diethyl carbonate (2:1 w/w). The half-cells were first discharged at a constant current to 0.00 V and then charged at the same current rate to a cut-off voltage of 1.0 V. The discharge charge process was repeated several times (usually 2-5) until a fairly constant capacity value of discharge charge was obtained. The charge capacities of these half-cells are shown in Table 1. The results indicate that the addition of molybdenum carbide increases the charge capacity of BG39 graphite. Thus, addition of only 5% molybdenum carbide to BG39 graphite increases its charge capacity from 334 mAh/g to 464 mAh/g.

Table 1: Effect of the Addition of Molybdenum Carbide on Charge Capacity of BG39 Graphite

Amount of Mo2C (%)	Charge Capacity (mAh/g)	Increase in Capacity (%)
0.0	334	0
5.0	464	39
8.0	460	38
15.0	391	17

Example 3

[0030] Two lithium-ion cells designated A1 and A2 were made according to known prior techniques with LiCoO₂ as cathode material and F399 graphite supplied by Alumina Trading Company, New Jersey (No molybdenum carbide added) as anode material in 1M LiPF₆ electrolyte in a mixture of EC/DMC solvents (1:1 v/v). Two similar type of lithium-ion cells designated B 1 and B2 were also built but the F399 graphite anodes of these cells contained 8% of molybdenum carbide of about 1µm (Climax Molybdenum Co) additive. The four lithium-ion cells were charged first at 0.5 mA/cm² to 4.2 V and then at constant voltage (4.2 V) for 3 hours or until the residual current dropped to 0.025 mA/cm². The cells were then discharged at 0.5 mA/cm² to a cut-off voltage of 3.0 V. The cells were charged and discharged for several times until a fairly constant values of charge and discharge capacities were obtained. The observed electrochemical performance of the cells is shown in Table 2. Again, the results demonstrate capacity improvement due to molybdenum carbide additive to the graphite anodes of cells B1 and B2 as compared with cells A1 and A2 having no molybdenum carbide additive to graphite anodes.

Table 2: Effects of Molybdenum Carbide Additive to Graphite Anode on Capacity of Lithium-ion Cell

Cell #	Molybdenum carbide Additive (%)	Cathode Weight (g)	Anode Weight (g)	Cell Capacity (mAh)	Specific Capacity of Anode (mAh/g)
A1	0	0.446	0.113	35	333
A2	0	0.446	0.117	36	331
B1	8	0.446	0.115	48	449
B2	8	0.446	0.112	47	451

Example 4

[0031] SFG44 graphite (Timcal Corporation, New Jersey) mixed with 5% molybdenum carbide (of about 2µm particle size) was used as an anode of a lithium-ion cell to evaluate the concept of the present invention. The lithium-ion cell included a negative electrode made from the mixture of SFG44 graphite and 5% molybdenum carbide (about 2 µm), a lithiated nickel cobalt dioxide positive electrode and 1M LiPF₆ electrolyte in a mixture (1:1 v/v) of ethylene carbonate/dimethyl carbonate (EC/DMC) solvents. A micro-porous poly-olefin (Celgard 2400) separator was used in between the positive and negative electrodes to isolate them electronically. The positive electrode was made from a mixture of 85% LiNi_0.8Co_0.2O₂, 6% carbon black and 9% PVDF in DMF by coating on to an aluminum foil.

[0032] The aprotic, non-aqueous 1M LiPF₆ electrolyte mixture permeated the micro-porous poly-olefin separator, whereby the electrolyte was in effective contact with both the positive and negative electrodes, which were nevertheless maintained space and electrically isolated from one another.

[0033] The developed cell was charged at a constant current of 0.5 mA/cm² to 4.0 V and then at a constant voltage (4.1 V) for 3 hours or until the current dropped to 0.02 mA/cm². The cell was then discharged at a constant current of 0.5 mA/cm² to a cut-off voltage of 2.75 V. The charge discharge process was repeated in order to evaluate the cycle life. Figure 5 shows the cycling characteristics of the developed cell according to the present invention. The cell delivered 80 cycles with 93% capacity retention. The initial anode capacity of the cell was 439 mAh/g and after 80 cycles the anode capacity was 412 mAh/g.

[0034] A lithium-ion cell was made with the same components as described above except the negative electrode was made from a mixture of 90% MCMB 2528 carbon and 10% PVDF in DMF (NO molybdenum carbide) by coating on to a copper foil. It is noteworthy to mention that MCMB 2528 carbon is used as an active material of anode for commercial lithium-ion cell. The cell was charged and discharged under the same conditions as the previous cell. Figure 6 shows the cycling behavior of this cell. The cell lost 9% capacity after delivering only 80 cycles. The initial anode capacity of the cell was only 327 mAh/g and after 80 cycles, the anode capacity dropped to 296 mAh/g.

[0035] Thus, according to the foregoing description, applicant has provided a concept for enhancing the reversible capacity of the carbonaceous anode of a lithium ion cell and/or battery, by combining the carbonaceous material with molybdenum carbide. It is believed that with the foregoing description in mind, the manner in which various types of lithium ion cells and/or batteries, with enhanced reversible capacity of the carbonaceous material(s) of the anode(s) of the cells and/or batteries, will become apparent to those skilled in the art.

Claims

1. A rechargeable electrochemical cell comprising a body of aprotic, non-aqueous electrolyte, first and second electrodes in effective contact with said electrolyte, the first electrode comprising a lithiated intercalation compound, and the second electrode comprising carbonaceous material combined with molybdenum carbide in an amount of less than 20% (by weight).

2. An electrochemical cell as defined in claim 1, wherein the amount of molybdenum carbide in the second electrode is in the range of 0. 1% to 15% (by weight).

3. An electrochemical cell as defined in claim 1, wherein the particle size of molybdenum carbide in the second electrode is in the range of 0.05 µm to 3 µm.

4. An electrochemical cell as defined in claim 1, wherein the lithiated intercalation compound of the first electrode is selected from the group consisting of LiCoO₂, LiNiCoO₂, LiNiCoAlO₂, LiNiO₂, LiMn₂0₄, LiMnO₂, LiV₂0₅, LiV₆O₁₃, LiTiS₂, Li₃FeN₂, Li₇VN₄ and combinations of the foregoing.

5. An electrochemical cell as defined in claim 1, wherein the electrolyte comprises a lithium compound solute dissolved in a non-aqueous solvent.

6. An electrochemical cell as defined in claim 4, wherein the electrolyte comprises a solute selected from the group consisting of LiPF₆, LiBF₄, LiAsF₆, LiCF₃SO₃, LiN (CF₃SO₂)₂, LiCl0₄, and combinations of the foregoing.

7. An electrochemical cell as defined in claim 5, wherein the electrolyte comprises a solvent selected from the group consisting of propylene carbonate, ethylene carbonate, diethyl carbonate, ethyl methyl carbonate, dimethyl carbonate, and combinations of the foregoing.

8. An electrochemical cell as defined in claim 1, wherein the first electrode is a cathode having a first metal substrate having a high stability in the operating voltage of the electrochemical cell.

9. An electrochemical cell as defined in claim 8, wherein said first metal substrate comprises aluminum.

10. An electrochemical cell as defined in claim 8, wherein said second electrode is an anode having a second metal substrate having a high stability in the operating voltage of the electrochemical cell.

11. An electrochemical cell as defined in claim 10, wherein said second metal substrate comprises copper.

12. An electrochemical cell as defined in claim 1, wherein the first electrode is a cathode that comprises a metal substrate having the lithiated intercalation compound affixed to a surface thereof, wherein the second electrode is an anode that comprises a second metal substrate having affixed to a surface thereof the carbon mixed with molybdenum carbide material thereon, and wherein said respective surfaces of the cathode and anode are separated from one another by a micro-porous electrically non-conductive separator that is permeated by said aprotic, non-aqueous electrolyte which is in effective contact with said respective surfaces of the anode and cathode.

13. An electrochemical cell as defined in claim 12, wherein the metal substrate of the cathode comprises aluminum and the metal substrate of the anode comprises copper.

14. An electrochemical cell as defined in claim 12, wherein the separator comprises a micro-porous poly-olefin film.

15. An electrochemical cell as defined in claim 12, wherein the cathode and anode and their respective substrates and the electrolyte permeated separator are all contained within a sealed enclosure and wherein means including the respective substrates of the cathode and anode are provided for connecting said cell to an external electric circuit.

16. A battery comprising a plurality of electrochemical cells as defined in one of claims 1, 12 and 14, having their respective electrodes connected in an electric circuit defining a battery of said cells.

Ansprüche

1. Aufladbare elektrochemische Zelle, die einen protonenfreien, nicht-wässrigen Elektrolytkörper, eine erste und eine zweite Elektrode umfasst, die mit dem Elektrolyt in einem wirksamen Kontakt stehen, wobei die erste Elektrode eine lithiierte Zwischenschichtverbindung umfasst und die zweite Elektrode ein kohlenstoffhaltiges Material umfasst, das mit einem Molybdäncarbid in einer Menge von weniger als 20 % (Massenanteil) kombiniert ist.

2. Elektrochemische Zelle nach Anspruch 1, wobei die Menge des Molybdäncarbids in der zweiten Elektrode im Bereich von 0,1 % bis 15 % (Massenanteil) liegt.

3. Elektrochemische Zelle nach Anspruch 1, wobei die Partikelgröße des Molybdäncarbids in der zweiten Elektrode im Bereich von 0,05 µm bis 3 µm liegt.

4. Elektrochemische Zelle nach Anspruch 1, wobei die lithiierte Zwischenschichtverbindung der ersten Elektrode aus der Gruppe ausgewählt ist, die aus LiCoO₂, LiNiCoO₂, LiNiCoAl0₂, LiNiO₂, LiMn₂O₄, LiMnO₂, LiV₂0_5, LiV₆O₁₃, LiTiS₂, Li₃FeN₂, Li₇VN₄ und Kombinationen der Vorhergehenden besteht.

5. Elektrochemische Zelle nach Anspruch 1, wobei das Elektrolyt einen aufgelösten Lithiumverbindungstoff umfasst, der in einem nicht-wässrigen Lösungsmittel gelöst ist.

6. Elektrochemische Zelle nach Anspruch 4, wobei das Elektrolyt einen aufgelösten Stoff umfasst, der aus der Gruppe ausgewählt ist, die aus LiPF₆, LiBF₄, LiAsF₆, LiCF₃SO₃, LiN (CF₃SO₂)₂, LiCl0₄, und Kombinationen der Vorhergehenden besteht.

7. Elektrochemische Zelle nach Anspruch 5, wobei das Elektrolyt ein Lösungsmittel umfasst, das aus der Gruppe ausgewählt ist, die aus Propylencarbonat, Ethylencarbonat, Diethylcarbonat, Ethylmethylcarbonat, Dimethylcarbonat und Kombinationen der Vorhergehenden besteht.

8. Elektrochemische Zelle nach Anspruch 1, wobei die erste Elektrode eine Kathode mit einem ersten Metallsubstrat mit einer hohen Stabilität in der Betriebsspannung der elektrochemischen Zelle ist.

9. Elektrochemische Zelle nach Anspruch 8, wobei das erste Metallsubstrat Aluminium umfasst.

10. Elektrochemische Zelle nach Anspruch 8, wobei die zweite Elektrode eine Anode mit einem zweiten Metallsubstrat mit einer hohen Stabilität in der Betriebsspannung der elektrochemischen Zelle ist.

11. Elektrochemische Zelle nach Anspruch 10, wobei das zweite Metallsubstrat Kupfer umfasst.

12. Elektrochemische Zelle nach Anspruch 1, wobei die erste Elektrode eine Kathode ist, die ein Metallsubstrat umfasst, wobei die lithiierte Zwischenschichtverbindung an eine Oberfläche davon angebracht ist, und die zweite Elektrode eine Anode ist, die ein zweites Metallsubstrat umfasst, wobei an eine Oberfläche davon der Kohlenstoff angebracht ist, der darauf mit dem Molybdäncarbidmaterial gemischt ist, und wobei die entsprechenden Oberflächen der Kathode und der Anode voneinander durch einen mikroporösen elektrisch nicht-leitenden Separator getrennt sind, der von dem protonenfreien nicht-wässrigen Elektrolyt durchdrungen ist, das mit den entsprechenden Oberflächen der Anode und der Kathode im wirksamen Kontakt steht.

13. Elektrochemische Zelle nach Anspruch 12, wobei das Metallsubstrat der Kathode Aluminium umfasst und das Metallsubstrat der Anode Kupfer umfasst.

14. Elektrochemische Zelle nach Anspruch 12, wobei der Separator eine mikroporöse Polyolefinschicht umfasst.

15. Elektrochemische Zelle nach Anspruch 12, wobei die Kathode und die Anode und ihre entsprechenden Substrate und der von Elektrolyt durchdrungene Separator alle innerhalb einer versiegelten Umhüllung aufgenommen sind und wobei Mittel, die die entsprechenden Substrate der Kathode und der Anode aufweisen, zum Verbinden der Zelle mit einer externen elektrischen Schaltung bereitgestellt sind.

16. Batterie, die eine Vielzahl von elektrochemischen Zellen nach einem der Ansprüche 1, 12 und 14 umfasst, wobei ihre entsprechenden Elektroden in einer elektrischen Schaltung verbunden sind, die eine Batterie dieser Zellen definiert.

Revendications

1. Cellule électrochimique rechargeable comportant un corps d'électrolyte non aqueux, aprotique, des première et seconde électrodes en contact effectif avec ledit électrolyte, la première électrode comportant un composé d'intercalation lithié, et la seconde électrode comportant une matière carbonée combinée avec du carbure de molybdène dans une quantité inférieure à 20 % (en poids).

2. Cellule électrochimique telle que définie dans la revendication 1, dans laquelle la quantité de carbure de molybdène dans la seconde électrode est dans la gamme de 0,1 % à 15 % (en poids).

3. Cellule électrochimique telle que définie dans la revendication 1, dans laquelle la taille de particule du carbure de molybdène dans la seconde électrode est dans la gamme de 0,05 µm à 3 µm.

4. Cellule électrochimique telle que définie dans la revendication 1, dans laquelle le composé d'intercalation lithié de la première électrode est choisi dans le groupe constitué de LiCoO₂, LiNiCoO₂, LiNiCoAlO₂, LiNiO₂, LiMn₂O₄, LiMnO₂, LiV₂O₅, LiV₆O₁₃, LiTiS₂, Li₃FeN₂, Li₇VN₄ et de combinaisons de ce qui précède.

5. Cellule électrochimique telle que définie dans la revendication 1, dans laquelle l'électrolyte comporte un soluté de composé de lithium dissous dans un solvant non aqueux.

6. Cellule électrochimique telle que définie dans la revendication 4, dans laquelle l'électrolyte comporte un soluté choisi dans le groupe constitué de LiPF₆, LiBF₄, LiAsF₆, LiCF₃SO₃, LiN(CF₃SO₂)₂, LiClO₄, et leurs combinaisons.

7. Cellule électrochimique telle que définie dans la revendication 5, dans laquelle l'électrolyte comporte un solvant choisi dans le groupe constitué de carbonate de propylène, de carbonate d'éthylène, de carbonate de diéthyle, de carbonate d'éthylméthyle, de carbonate de diméthyle, et de leurs combinaisons.

8. Cellule électrochimique telle que définie dans la revendication 1, dans laquelle la première électrode est une cathode ayant un premier substrat de métal ayant une stabilité élevée dans la tension de fonctionnement de la cellule électrochimique.

9. Cellule électrochimique telle que définie dans la revendication 8, dans laquelle ledit premier substrat de métal comporte de l'aluminium.

10. Cellule électrochimique telle que définie dans la revendication 8, dans laquelle ladite seconde électrode est une anode ayant un second substrat de métal ayant une stabilité élevée dans la tension de fonctionnement de la cellule électrochimique.

11. Cellule électrochimique telle que définie dans la revendication 10, dans laquelle ledit second substrat de métal comporte du cuivre.

12. Cellule électrochimique telle que définie dans la revendication 1, dans laquelle la première électrode est une cathode qui comporte un substrat de métal ayant le composé d'intercalation lithié fixé sur une surface de celui-ci, dans laquelle la seconde électrode est une anode qui comporte un second substrat de métal ayant, fixé sur une surface de celui-ci, le carbone mélangé avec du carbure de molybdène sur celui-ci, et dans laquelle lesdites surfaces respectives de la cathode et de l'anode sont séparées l'une de l'autre par un séparateur microporeux, électriquement non conducteur qui est infiltré par ledit électrolyte non aqueux, aprotique qui est en contact effectif avec lesdites surfaces respectives de l'anode et de la cathode.

13. Cellule électrochimique telle que définie dans la revendication 12, dans laquelle le substrat de métal de la cathode comporte de l'aluminium et le substrat de métal de l'anode comporte du cuivre.

14. Cellule électrochimique telle que définie dans la revendication 12, dans laquelle le séparateur comporte un film de polyoléfine microporeux.

15. Cellule électrochimique telle que définie dans la revendication 12, dans laquelle la cathode et l'anode et leurs substrats respectifs et le séparateur infiltré par l'électrolyte sont tous contenus à l'intérieur d'une enceinte scellée, et dans laquelle des moyens incluant les substrats respectifs de la cathode et de l'anode permettent de relier ladite cellule à un circuit électrique externe.

16. Batterie comportant une pluralité de cellules électrochimiques telles que définies dans l'une des revendications 1, 12 et 14, ayant leurs électrodes respectives reliées dans un circuit électrique définissant une batterie desdites cellules.

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