(19)
(11) EP 1 532 003 B1

(12) EUROPEAN PATENT SPECIFICATION

(45) Mention of the grant of the patent:
24.02.2016 Bulletin 2016/08

(21) Application number: 02779465.0

(22) Date of filing: 04.10.2002
(51) International Patent Classification (IPC): 
B42D 25/29(2014.01)
B42D 25/00(2014.01)
(86) International application number:
PCT/EP2002/011177
(87) International publication number:
WO 2004/014665 (19.02.2004 Gazette 2004/08)

(54)

SECURITY ELEMENT FOR DOCUMENTS IN GENERAL AND IN PARTICULAR BANKNOTES, SECURITY CARDS AND THE LIKE

SICHERHEITSELEMENT FÜR DOKUMENTE IN GENERAL UND INSBESONDERE FÜR BANKNOTEN, SICHERHEITSKARTEN UND DERGLEICHEN

ELEMENTS DE SECURITE POUR DOCUMENTS EN GENERAL, ET EN PARTICULIER POUR BILLETS DE BANQUE, CARTES DE SECURITE ET ANALOGUES


(84) Designated Contracting States:
AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LI LU MC NL PT SE SK TR
Designated Extension States:
SI

(30) Priority: 24.07.2002 IT MI20021640

(43) Date of publication of application:
25.05.2005 Bulletin 2005/21

(73) Proprietor: Fedrigoni S.p.A.
37135 Verona (IT)

(72) Inventor:
  • LAZZERINI, M., MANTEGAZZA ANTONIO ART GRAFICHI SRL
    I-20021 Bollate (Milano) (IT)

(74) Representative: TBK 
Bavariaring 4-6
80336 München
80336 München (DE)


(56) References cited: : 
EP-A- 0 319 157
WO-A-97/19820
   
       
    Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention).


    Description


    [0001] The present invention relates to a security element for documents in general and in particular banknotes, security cards and the like.

    [0002] As it is known, in order to avoid the counterfeiting of banknotes and documents in general, a presently very used technique consists in arranging some threads which can be inserted into the mixture of the paper of which the document is made, said threads being wholly inserted or partially fitted-in the paper, that is, having some parts inside and some parts outside of the paper.

    [0003] Typically, these threads are made of a support layer of flexible and transparent plastic material upon which metallic layers, magnetic elements, microprintings, fluorescent elements, magnetic codes and so on are deposited.

    [0004] To also allow the public and the common users to verify the authenticity of the documents, threads have been developed which allow the immediate and easy determination of the authenticity of the threads, together with the possibility to carry out the control through automatic devices which are suitably arranged for this purpose.

    [0005] One of these threads is illustrated in the European patent EP-0 319 157 which is substantially made of a layer of transparent and flexible plastic material upon which a vacuum-deposited aluminium layer is applied, upon which some zones, areas, texts or graphic signs are realised by means of demetallization that creates some zones without the metal, but they are entirely surrounded by metal that allows to keep the metallic continuity of the thread.

    [0006] This present kind of solution results in easily falsificating because it is possible to utilise transfer materials like materials which are printable on support which can be removed and positioned on other supports by means of the use of particularly precise dies manufactured by laser techniques.

    [0007] Furthermore, another easy possibility of counterfeiting derives from the use of usual polyester sheets metallized under vacuum, that are available on the market, from which the aluminium can be removed, for example, by means of an Nd-Yag laser ray with a wavelength around 100 nm that is with an equipment which is easily available.

    [0008] Another problem is constituted by the fact that in the solution described above, the different graphic signs are obtained by realising a complete removal of the metal, thereby causing in some cases, during the phase of lengthening of the threads which inevitably occurs at the time of its insertion into the paper, a break of the metallic layer around the cut zones which can strongly compromise the metallic continuity of the ensemble.

    [0009] Another problem is constituted by the fact that, at the time of the insertion of the thread into the paper, the thread is submitted to an acid environment or anyway aggressive agent which determines some corrosion especially in the zones of the corners which are obtained by demetallizing completely the thread.

    [0010] This fact causes both a degradation during the service-life of the product, and a possible difficulty in reading and checking of the thread or security element.

    [0011] European patent EP 0 536 855 B2 dislcoses a security strip for banknotes having the features of the preamble of claim 1.

    [0012] The object of the present invention is to eliminate the formerly described drawbacks, realising a security element for documents in general and in particular banknotes, security cards and the like, which gives the possibility to create an ensemble which is not reproducible with traditional techniques and, consequently, disposable by the possible counterfeiter.

    [0013] Within the object described above, a particular object of the invention is to manufacture a security element which doe not eliminate the metallic continuity on the whole surface of the support layer, thereby preventing any possible break, for example at the time of lengthening of the thread for the insertion into the paper, thereby maintaining in any condition the metallic continuity which is necessary for the detection of the security element by means of a reading equipment.

    [0014] A further object of the present invention is to manufacture a security element which is not subject to damage also in the case in which it is attacked in an acid environment, which is the typical environment at the time of the insertion of the thread into the paper, thereby maintaining constant its integrity in time.

    [0015] A further object of the present invention is to manufacture a security element which is applicable externally to the document, thereby creating a feature easily perceptible by the public.

    [0016] The above object, as well as the further objects briefly mentioned and others which will be apparent in the following, are achieved by a security element for documents in general and in particular banknotes, security cards and the like according to the invention which comprises a flexible support layer having, on at least one of its faces, a layer of metallic material, characterised in that said layer of metallic material comprises at least one zone having a metal thickness lower than 60% of the thickness of the layer of metallic material of the surrounding portions.

    [0017] Further characteristics and advantages will become apparent from the description of one preferred embodiment, but not exclusive, of a security element for documents in general and in particular banknotes, illustrated by purely a non limitative example, with reference to the attached drawings in which:
    • figure 1 schematically shows the security element according to the invention;
    • figure 2 represents the security element in an greatly enlarged scale and in cross-section;
    • figure 3 represents the security element according to the invention inserted into a document;
    • figure 4 represents the security element applied on the external face of the document.


    [0018] With reference to the drawings, the security element for documents in general and in particular banknotes, security cards and the like according to the invention, which is indicated in its entirety with the reference number 1, comprises a flexible support layer 2 which is advantageously obtained by polyester sheets and the like.

    [0019] On the support layer 2, upon one face but possibly also on both faces, a layer of metallic material 3 is provided, wherein the important peculiarity are zones, indicated with 10, which have a reduced thickness of the metal with respect to the surrounding zones and which is preferably, lower than 70% and greater than 25% of the thickness of the layer of metallic material of the surrounding portions; hence, with a thickness of the layer of 1,8 Optical Density, the zones of reduced thickness must have a thickness comprised between 0.45 and 1.26 Optical Density.

    [0020] In this way the metallic continuity is maintained on the whole surface of the support layer, and the distinctive elements which can be constituted by characters, graphical signs and anything else which can be considered as being suitable, are defined in practise by said zones having reduced thickness of the metal.

    [0021] The metallic layer can be obtained of aluminium being metallized under vacuum or other metal like chrome, nickel, copper or a combination of these materials.

    [0022] The partial removal allows to maintain the metallic continuity having as well a different amount of metal among the zones where the partial removal has been effected which allows to keep an element visually verifiable.

    [0023] The support layer can be made of a tape, as shown in the specific example, but, obviously, it can assume any other configuration as thread, stamp or any other configuration which is deemed to be suitable.

    [0024] The security element manufactured, as disclosed above, can either be wholly inserted into the paper of which the document is made, or partially inserted, that is, having some part that come out of the surface, or directly applied on the surface like schematically illustrated in figure 4.

    [0025] In a specific embodiment, the support layer is made of 15, 19 or 23 µm polyester which is metallized on its side by means of a vacuum metallizer, which deposits an aluminium layer of 1.8 Optical Density.

    [0026] A cleaner film can be obtained by plasma treatment which allows a better and more uniform adhesion.

    [0027] Preferably, the speed of application must not be more than 400-500 metres per minute, and a metallizer should be used having an advancing system for each aluminium thread and a system of automatic detection of metallization, so that a surface with a maximum variation of thickness lower than 3% is obtained.

    [0028] The tape treated as disclosed above is inserted into a chemical action demetallization device, possibly with the use of an acid.

    [0029] To perform the treatment, the metallic layer is previously submitted to a corona treatment which allows to simplify the anchoring of an ink which is used.

    [0030] Above the aluminium layer, a very transparent ink adapted to preserve the aluminium by the attacks of acid substances is printed with normal operations of printing, these inks are, for example, nitrocellulosic inks with the addition of a catalyst or anyway of a hardener with a percentage of 1%.

    [0031] Some tanks containing the chemical products for the demetallization of the tape and a subsequent washing and drying system are provided.

    [0032] A suitable method implies the metallization of a 23 µm polyester film with 1.8 Optical Density of aluminium +/- 3%, subsequently a corona treatment is performed on the metallic layer, thereby providing a superficial wettability of 54 +/- 4 dynes, subsequently the metallic layer is printed with an ink for metals, for example nitrocellulosic ink with a thickness of 1.2 - 2 µm.

    [0033] The film is then passed in a tank containing 47-48% phosphoric acid with a temperature of 40°C +/- 2 for about 40 - 45 seconds.

    [0034] The film is washed in a tank using water, and at the exit of the tank, the film is dipped in a tank with a buffer solution made of water and 3/5 % ammonia.

    [0035] Afterwards the treated film is submitted to an abundant rinse, keeping the pH value in each tank constant.

    [0036] At the exit of the last tank, the film is submitted to a gentle wringing by means of rubber rollers, and then it is passed in a hot air tunnel at the speed of 40 metres per minute and a hood temperature of about 90/100° C; the tunnel has a length of about 6 metres in such way to obtain a permanence time of about 10 seconds.

    [0037] The method described above allows to obtain security threads on which the deposited aluminium has been partially removed from 1.8 Optical Density to 0.7 Optical Density in the zones in which the ink has not been applied.

    [0038] Another possible solution to obtain the security element according to the invention consists in carrying out the complete demetallization in the zones where the characters, distinctive signs and the like must be printed, which is indicated by 10, and to apply afterwards a thickness of metal with a thickness lower than the thickness of the surrounding zones.

    [0039] In practise, a 23 µm polyester film is metallized with 1.8 Optical Density +/- 0.3%, and subsequently, as in the previous case, corona treatment is carried out bringing the superficially wettability to 54 +/- 4 dynes, and the print is carried out on the side of the metallic layer with cellulosic inks for a thickness of 1.2 - 2 µm. The film thus obtained is passed in a tank which contains 54/56 % phosphoric acid with a temperature of 55°C degrees +/- 2 with a permanence time of about 50 - 55 seconds.

    [0040] The film is then washed in a tank using water and afterwards, in another tank, it is dipped into a buffer solution with water and 3/5 % ammonia.

    [0041] After an abundant rinse, the film is submitted to spraying and drying like in the previous example.

    [0042] The film is subsequently submitted again to a full bottom metallization operation preferably with a thickness of 0.7 Optical Density.

    [0043] The metallic layer can be possibly applied also on the opposite face.

    [0044] From what is illustrated above, it can be seen that the invention reaches the proposed objects, and in particular it has been pointed out that a security element is provided which maintains a superficial metallic continuity which renders very complex counterfeiting, in addition to improving the mechanical and chemical characteristics of the ensemble by the fact that the metallic continuity prevents, in particular in the zones where the signs and distinctive characters are defined, successive breaks from occuring during the treatment phases.

    [0045] The invention so conceived is susceptible of various changes and modifications all within the scope of the present invention.

    [0046] To what illustrated above, it must be added that the ratio between the surfaces with reduced thickness and the surfaces with total thickness could be changed, so that it is possible to define the visually detectable characters by full thickness zones.

    [0047] The embodiments provided with their individual characteristics disclosed in connection with specific examples in practice can be interchanged with other different characteristics provided in the other embodiments.

    [0048] Furthermore, it is understood that anything what will appear to be part of the prior art during the examining procedure of this patent application is hereby disclaimed and removed from the claims.

    [0049] In practice, the used materials, as well as the dimensions and the forms could be varied according to the different needs.

    [0050] In particular, the metallic layer 3 may be made of a noble metal, aluminium, chrome, nickel, copper or a combination thereof. Preferably, the noble metal is gold.


    Claims

    1. Security element (1) for documents in general, in particular banknotes, security cards and the like, comprising a support layer (2) having, at least on one face, a continuous layer of metallic material (3), characterised in that said continuous layer of metallic material (3) comprises at least one zone (10) having a reduced thickness of metal with respect to surrounding portions so as to be visually distinctive from the surrounding portions or vice versa.
     
    2. Security element (1) according to claim 1, characterised in that said at least one zone (10) has a thickness of metal lower than 70% and greater than 25% of the thickness of the layer of metallic material (3) of the surrounding portions.
     
    3. Security element (1) according to any one of the previous claims, characterised in that said metallic layer (3) is made of a noble metal, aluminium, chrome, nickel, copper or a combination thereof.
     
    4. Security element (1) according to claim 3, characterised in that said noble metal is gold.
     
    5. Security element (1) according to one or more of the previous claims, characterised in that said metallic layer (3) has a thickness lower than 2.2 Optical Density.
     
    6. Method for manufacturing a security element (1) according to claim 1, characterised in that the method comprises the steps of
    metallizing at least one face of a polyester support layer (2),
    applying a printed layer of ink thereon to protect said metallic layer (3),
    demetallizing the tape in a tank containing 47-48% phosphoric acid with a temperature of 40°C +/- 2 for a period of 40-45 seconds,
    washing with a buffer solution made of water and ammonia, and
    rinsing the obtained product.
     
    7. Method according to previous claim, characterised in that the method comprises steps of drying the film by means of wringing and of passing it in a hot air tunnel with a speed of 40 meters per minute at a temperature of 90-100°C with a permanence time of substantially 10 seconds.
     
    8. Method according to the previous claims, characterised by a step of providing a corona treatment on the metallic layer (3) for anchoring the ink to be printed.
     
    9. Method for manufacturing a security element (1) according to claim 1, characterised in that the method comprises the steps of
    metallizing a polyester support layer (2),
    carrying out on the produced metallic layer (3) a printing with cellulosic inks,
    carrying out a demetallization with 54-56% phosphoric acid at a temperature of 55°C+/-2 for a time of 50-55 seconds,
    washing the obtained product with water and ammonia,
    rinsing, and
    applying by means of an operation of a full bottom metallization a metallic layer with a thickness lower than the already present layer.
     
    10. Document in general, characterised in that it comprises a wholly inserted security element (1) according to claim 1.
     
    11. Document in general, characterised in that it comprises at least one partially inserted security element (1) according to claim 1.
     
    12. Document in general, characterised in that it is provided on one of its external faces with a security element (1) according to claim 1.
     
    13. Security element (1) according to claim 1, characterised in that also the layer of metallic material (3) in the at least one zone (10) having the reduced layer thickness is continuously formed.
     
    14. Security element (1) according to one or more of the previous claims, characterised in that the support layer (2) is flexible.
     


    Ansprüche

    1. Sicherheitselement (1) für Dokumente im Allgemeinen, insbesondere Banknoten, Sicherheitskarten und dergleichen, mit einer Trägerschicht (2), die zumindest auf einer Seite eine durchgehende Schicht aus metallischem Material (3) aufweist, dadurch gekennzeichnet, dass die kontinuierliche Schicht aus metallischem Material (3) zumindest einen Bereich (10) mit einer verringerten Dicke des Metalls in Bezug auf die umgebenden Teile aufweist, um so optisch von den umgebenden Teilen unterscheidbar zu sein oder umgekehrt.
     
    2. Sicherheitselement (1) nach Anspruch 1, dadurch gekennzeichnet, dass der zumindest eine Bereich (10) eine Dicke des Metalls von weniger als 70% und mehr als 25% der Dicke der Schicht aus metallischem Material (3) der umgebenden Teile aufweist.
     
    3. Sicherheitselement (1) nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, dass die metallische Schicht (3) aus einem Edelmetall, Aluminium, Chrom, Nickel, Kupfer, oder einer Kombination daraus ausgebildet ist.
     
    4. Sicherheitselement (1) nach Anspruch 3, dadurch gekennzeichnet, dass das Edelmetall Gold ist.
     
    5. Sicherheitselement (1) nach einem oder mehreren der vorstehenden Ansprüche, dadurch gekennzeichnet, dass die metallische Schicht (3) eine Dicke mit weniger als 2,2 Optischer Dichte aufweist.
     
    6. Verfahren zur Herstellung eines Sicherheitselements (1) nach Anspruch 1, dadurch gekennzeichnet, dass das Verfahren die Schritte umfasst:

    Metallisierung zumindest einer Seite einer Polyesterträgerschicht (2)

    Aufbringen einer bedruckten Schicht aus Tinte darauf, zum Schützen der metallischen Schicht (3),

    Entmetallisierung des Bandes in einen Behälter mit 47 bis 48% Phosphorsäure bei einer Temperatur von 40°C +/- 2 über einen Zeitraum von 40 bis 45 Sekunden,

    Waschen mit einer Pufferlösung aus Wasser und Ammoniak, und

    Spülen des erhaltenen Produkts.


     
    7. Verfahren nach dem vorstehenden Anspruch, dadurch gekennzeichnet, dass das Verfahren die Schritte zum Trocknen des Films mittels Auswringen, und zum Einleitens desselben in einen Heißlufttunnel mit einer Geschwindigkeit von 40 Metern pro Minute bei einer Temperatur von 90 bis 100°C mit einer Permanenzzeit von im Wesentlichen 10 Sekunden enthält.
     
    8. Verfahren nach einem der vorstehenden Ansprüche, gekennzeichnet durch einen Schritt zur Bereitstellung einer Koronabehandlung auf der metallischen Schicht (3) für die Verankerung der zu druckenden Tinte.
     
    9. Verfahren zur Herstellung eines Sicherheitselements (1) nach Anspruch 1, dadurch gekennzeichnet, dass das Verfahren die Schritte umfasst:

    Metallisieren einer Polyesterträgerschicht (2),

    Ausführen eines Druckvorgangs mit Zellulosefarben auf der erzeugten metallischen Schicht (3),

    Ausführen eines Entmetallisierungsvorgangs mit 54 bis 56% Phosphorsäure bei einer Temperatur von 55°C +/- 2 über einen Zeitraum von 50 bis 55 Sekunden,

    Waschen des erhaltenen Produkts mit Wasser und Ammoniak,

    Spülen, und

    Aufbringen einer metallischen Schicht mit einer geringeren Dicke als die der bereits vorhandenen Schicht mittels eines Vorgangs einer vollen Grundmetallisierung.


     
    10. Dokument im Allgemeinen, dadurch gekennzeichnet, dass es ein vollständig eingefügtes Sicherheitselement (1) nach Anspruch 1 aufweist.
     
    11. Dokument im Allgemeinen, dadurch gekennzeichnet, dass es zumindest ein teilweise eingefügtes Sicherheitselement (1) nach Anspruch 1 aufweist.
     
    12. Dokument im Allgemeinen, dadurch gekennzeichnet, dass es auf einer seiner Außenflächen mit einem Sicherheitselement (1) nach Anspruch 1 ausgestattet ist.
     
    13. Sicherheitselement (1) nach Anspruch 1, dadurch gekennzeichnet, dass auch die Schicht aus metallischem Material (3) in dem zumindest einen Bereich (10) mit der reduzierten Schichtdicke kontinuierlich ausgebildet ist.
     
    14. Sicherheitselement (1) nach einem oder mehreren der vorstehenden Ansprüche, dadurch gekennzeichnet, dass die Trägerschicht (2) flexibel ist.
     


    Revendications

    1. Elément de sécurité (1) pour des documents en général, en particulier des billets de banque, cartes de sécurité et analogue, comprenant une couche de support (2) ayant, au moins sur une face, une couche continue de matériau métallique (3), caractérisé en ce que ladite couche continue de matériau métallique (3) comprend au moins une zone (10) ayant une épaisseur réduite de métal par rapport à des parties environnantes de manière à être visuellement distincte des parties environnantes ou vice versa.
     
    2. Elément de sécurité (1) selon la revendication 1, caractérisé en ce que ladite au moins une zone (10) a une épaisseur de métal inférieure à 70% et supérieure à 25% de l'épaisseur de la couche de matériau métallique (3) des parties environnantes.
     
    3. Elément de sécurité (1) selon l'une quelconque des revendications précédentes, caractérisé en ce que ladite couche métallique (3) est réalisée en un métal noble, aluminium, chrome, nickel, cuivre ou une combinaison de ceux-ci.
     
    4. Elément de sécurité (1) selon la revendication 3, caractérisé en ce que ledit métal noble est l'or.
     
    5. Elément de sécurité (1) selon l'une ou plusieurs des revendications précédentes, caractérisé en ce que ladite couche métallique (3) a une épaisseur de Densité Optique inférieure à 2,2.
     
    6. Procédé de fabrication d'un élément de sécurité (1) selon la revendication 1, caractérisé en ce que le procédé comprend les étapes qui consistent :

    à métalliser au moins une face d'une couche de support en polyester (2),

    à appliquer une couche imprimée d'encre sur celle-ci pour protéger ladite couche métallique (3),

    à démétalliser la bande dans un réservoir contenant 47 à 48% d'acide phosphorique avec une température allant de 40C°C +/- 2 pour une période allant de 40 à 45 secondes,

    à laver avec une solution tampon réalisée en eau et en ammoniac, et

    à rincer le produit obtenu.


     
    7. Procédé selon la revendication précédente, caractérisé en ce que le procédé comprend des étapes qui consistent à sécher le film au moyen d'essorage et à le faire passer dans un tunnel à air chaud avec une vitesse de 40 mètres par minute à une température allant de 90 à 100°C avec un temps de permanence substantiellement égal à 10 secondes.
     
    8. Procédé selon les revendications précédentes, caractérisé par une étape qui consiste à fournir un traitement corona sur la couche métallique (3) pour ancrer l'encre à imprimer.
     
    9. Procédé de fabrication d'un élément de sécurité (1) selon la revendication 1, caractérisé en ce que le procédé comprend les étapes qui consistent :

    à métalliser une couche de support en polyester (2),

    à effectuer sur la couche métallique produite (3) une impression avec des encres cellulosiques,

    à effectuer une démétallisation avec 54 à 56% d'acide phosphorique à une température de 55°C+/-2 pendant une durée allant de 50 à 55 secondes,

    à laver le produit obtenu avec de l'eau et de l'ammoniac,

    à rincer, et

    à appliquer au moyen d'une opération d'une métallisation de fond complète une couche métallique avec une épaisseur inférieure à celle de la couche déjà présente.


     
    10. Document en général, caractérisé en ce qu'il comprend un élément de sécurité totalement inséré (1) selon la revendication 1.
     
    11. Document en général, caractérisé en ce qu'il comprend au moins un élément de sécurité totalement inséré (1) selon la revendication 1.
     
    12. Document en général, caractérisé en ce qu'il est prévu sur l'une de ses faces externes avec un élément de sécurité (1) selon la revendication 1.
     
    13. Élément de sécurité (1) selon la revendication 1, caractérisé en ce qu'également la couche de matériau métallique (3) dans l'au moins une zone (10) ayant l'épaisseur de couche réduite est formée en continu.
     
    14. Élément de sécurité (1) selon l'une ou plusieurs des revendications précédentes, caractérisé en ce que la couche de support (2) est flexible.
     




    Drawing











    Cited references

    REFERENCES CITED IN THE DESCRIPTION



    This list of references cited by the applicant is for the reader's convenience only. It does not form part of the European patent document. Even though great care has been taken in compiling the references, errors or omissions cannot be excluded and the EPO disclaims all liability in this regard.

    Patent documents cited in the description