ATBECHDEDKESFRGBGRITLILUNLSEMCPTIESILT..FIRO..CY..TRBGCZEEHU..SK................*JDIM360 (Ver 1.5 21 Nov 2005) - 2500000/0 2999001/01537374CORRECTED EUROPEAN PATENT SPECIFICATIONB9B120071010W1deZeichnung(en) gestrichenenDrawing(s) deletedfrFigure(s) supprimée(s)deZeichnungenenDrawingsfrFiguresEP03750474.3200309022005040620060124enenen0202002720020906EP2007101020074120050608200523200702072007062006072420070508BG20071010200741F41H 5/04 20060101AFI20040325BHEP dePENETRATIONSRESISTENTES MATERIAL UND DARAUS HERGESTELLTE GEGENSTÄNDEenPENETRATION-RESISTANT MATERIAL AND ARTICLES MADE OF THE SAMEfrMATERIAU RESISTANT A LA PENETRATION ET ARTICLES FABRIQUES AVEC CELUI-CIWO-A-00/42246US-A- 4 608 717US-A- 5 344 956US-A- 5 556 695US-A- 6 034 004DATABASE EPODOC [Online] EUROPEAN PATENT OFFICE, THE HAGUE, NL; XP002231859 & KR 9 401 038 B (KOLON INC) 8 February 1994 (1994-02-08)BÖTTGER, Christian, KurtGeschwister Scholl-Strasse 2542897 RemscheidDEHARTERT, RüdigerFischertal 9542287 WuppertalDESTOLZE, Kurt, RainerAsternweg 142799 LeichlingenDEFELS, Achim, GustavAdalbert-Stifter Weg 842109 WuppertalDETeijin Twaron GmbH03361210CQD2569 P1/EPKasinostrasse 19-2142103 WuppertalDEHeimann, Anette00080891CPW GmbH Patentabteilung Kasinostrasse 19-2142103 WuppertalDEATBEBGCHCYCZDEDKEEESFIFRGBGRHUIEITLILUMCNLPTROSESISKTRLT20050406EP200300970920030902enWO20040230602004031820041220050608200523

The invention pertains to a penetration-resistant material and to articles made of the same.

Penetration-resistant articles such as bulletproof vests, helmets, vehicle panels and shields prepared from high strength fibers are known in the art. For many applications, in particular for ballistic vests, the fibers are used in a woven or knitted fabric. This fabrics may be coated or impregnated in a matrix to obtain hard ballistic materials, or may be used free from matrix to obtain soft ballistic materials.

Bulletproof fabrics are known, inter alia, from EP 310 199. The fabrics disclosed therein are composed of filament yarns of ultrahigh molecular weight polymer having high strength and high modulus, with the warp threads being of a different polymeric material than the weft threads.

In Russian Patent RU 2 096 542 a ballistic fabric for bulletproof jackets was disclosed having warp and weft threads of poly para-phenyleneterephthalamide (PPTA) wherein the ratio of the warp to the weft linear density is smaller than 4.17. Typically, warp threads having a linear density of 143 to 588 dtex and weft threads having a linear density of 588 to 930 were disclosed, the weft threads having equal or higher linear density than the warp threads. It is particularly contended that ballistic fabrics having warp to weft linear density ratios between 1.59 and 4.17 have improved deflection properties.

In WO 00/42246 a penetration-resistant material is disclosed comprising at least a double layer of fabric composed of two layers of woven fabric which are cross-plied at an angle wherein the fabric is composed of a first set of threads comprising 3.5 to 20 threads/cm and having a linear density of at least 420 dtex, and a second set of threads comprising 0.5 to 8 threads/cm and having a linear density of at least 50 dtex, with the second set of threads being transverse to the first set of threads and wherein the ration of the linear density of the first set of threads to the linear density of the second set of threads is > 4.2, more preferably > 7.5. In a preferred embodiment the first set of threads is warp threads made of p-aramid yarn and the second set of threads ist weft threads made of polyester yarn, and the ratio of the number of threads/cm of the first set to that of the second set is > 1. Although the ballistic performance of this material is excellent, the necessity of cross-plying the layers is a disadvantage in terms of ease and simplicity of the manufacture and the danger of creating weak points that inherently to the process of cross-plying can occur.

So, the problem underlying the present invention is to provide a penetration-resistant material which does not exhibit the disadvantages of the prior art.

Some penetration-resistant materials exhibit a high uptake of water resulting in a decrease of ballistic performance. Therefore, another problem underlying the present invention is to reduce this drawback.

These problems are solved by a penetration-resistant material comprising at least a double layer of woven fabric wherein the double layer comprises a first layer of fabric composed of a first set of threads comprising 3.5 to 20 threads/cm, having a linear density of at least 210 dtex, and comprising at least 65 % of the fabric weight, and a second set of threads comprising 0.5 to 16 threads/cm and having a linear density of at least 50 dtex, with the second set of threads being transverse to the first set of threads, and the ratio of the number of threads/cm of the first set to that of the second set is > 1, and a second layer of fabric composed of a first set of threads comprising 0.5 to 16 threads/cm and having a linear density of at least 50 dtex, and a second set of threads comprising 3.5 to 20 threads/cm, having a linear density of at least 210 dtex, and comprising at least 65 % of the fabric weight, with the second set of threads being transverse to the first set of threads, and the ratio of the number of threads/cm of the second set to that of the first set is > 1, and wherein the first and second sets of threads of the first layer have a parallel orientation towards the first and second sets, respectively, of threads of the second layer, and wherein the first set of threads of the first layer and the first set of threads of the second layer are warp threads and the second set of threads of the first layer and the second set of threads of the second layer are weft threads and wherein in the first layer of fabric at least the first set of threads and in the second layer of fabric at least the second set of threads are treated with a water-repellant.

Within the scope of the present invention the term "thread" means any sort of thread such as staple yarn, twisted staple yarn, twisted filament yarn, non-twisted intermingled yarn, and preferably, untwisted filament yarn.

In a preferred embodiment of the penetration-resistant material according to the present invention in the first layer of fabric the first and the second set of threads and in the second layer of fabric the first and the second set of threads are treated with a water-repellant.

Within the scope of the present invention in principle any substance which repells water and which can be applied to the threads with known methods can be used as the water-repellant. However, because of it's high water-repellant efficiency a water-repellant comprising fluor and carbon atoms, e.g. a fluoropolymer, and especially a mixture of fluoroacrylate polymers, is preferred. Said mixture is for example contained in OLEOPHOBOL SM® from Ciba Spezialitätenchemie Pfersee GmbH, Langweid am Lech, DE.

In a preferred embodiment of the penetration-resistant material according to the present invention the water-repellant treated threads comprise about 0.1 to about 2 weight % fluoroacrylate polymers with respect to the weight of the water-repellant treated threads. Especially preferred is about 1 weight % fluoroacrylate polymers with respect to the weight of the water-repellant treated threads.

Preferably, in the penetration-resistant material according to the present invention at least the ratio of the linear density of the first set of threads to the linear density of the second set of threads of the first layer and of the linear density of the second set of threads to the linear density of the first set of threads of the second layer is > 1, more preferably > 4.2 and most preferably > 5.9. A particular effective ratio is 6 - 6.6.

In a preferred embodiment of the penetration-resistant material according to the present invention at least one of the second set of threads of the first layer and the first set of threads of the second layer comprises 0.5 to 8 threads/cm.

in each layer the threads having a linear density of at least 210 dtex comprise at least 65 % of the fabric weight of that layer. Preferably, these threads comprise at least 70 % and more preferably 75 % of the fabric weight of that layer.

The second set of threads is transverse to the first set of threads in each of the two layers. Usually these sets are about perpendicular to each another, but this is not necessary. The second set of threads may be provided under an angle other than 90° to the first set of threads. The two layers are secured together without cross-plying.

In a preferred embodiment of the penetration-resistant material according to the present invention the threads of the layers of the double layer are bonded together, for instance, by stich bonding, or preferably with an adhesive material. The adhesive material may be adhesive material provided onto the threads or onto the fabric, for instance as a finish.

The adhesive material can also be an adhesive layer provided between the two fabric layers of the double layer.

Adhesive materials include

It is also possible to use for at least part of the second set of threads of the first layer and the first set of threads of the second layer a material that melts under pressure and/or heating, thereby accomplishing binding the threads of the first set, respectively second set of threads to those of the second set, respectiveley first set of threads, and optionally also binding the two fabric layers together.

The number of threads per cm in the first set of threads of the first layer and the second set of threads of the second layer is 3.5 to 20 threads/cm, more preferably 4 to 15 threads/cm and most preferably 5 to 12 threads/cm.

The number of threads per cm in the second set of threads of the first layer and the first set of threads of the second layer is 0.5 to 16 threads/cm, preferably 0.5 to 8 threads/cm, more preferably 1 to 6 threads/cm and most preferably 2 to 4 threads/cm.

The first set of threads of the first layer (preferably warp threads) and the second set of threads of the second layer (preferably weft threads) are of high strength and high modulus.

In a preferred embodiment of the penetration-resistant material according to the present invention the first set of threads of the first layer and the second set of threads of the second layer consist of high tenacity threads selected from aramid, polyethylene and poly-p-phenylenebenzobisoxazole (PBO) threads, whereby for the aramide more particularly p-aramid threads and most preferred poly paraphenyleneterephthalamide (PPTA) is used, for example Twaron® threads manufactured by Teijin Twaron.

The penetration-resistant material according to the present invention also consists of a second set of threads of the first layer (preferably weft threads) and a first set of threads of the second layer (preferably warp threads), the yarn composition of which is not decisive for the present invention. Preferably, however, these threads exhibit a high strength and a high modulus. This is particularly the case when the second set of threads of the first layer and the first set of threads of the second layer are selected from polyester, polyethylene, polypropylene and aramid threads, for example Twaron® threads manufactured by Teijin Twaron. Most preferably, the second set of threads of the first layer and the first set of threads of the second layer is made of polyester thread.

In a peferred embodiment of the penetration-resistant material according to the present invention the warp and the weft threads are selected to be made of different polymers, for instance a fabric having warp threads of p-aramid yarn and weft threads of polyester yarn, or reversed, is preferred. An example for such a preferred embodiment is a penetration-resistant material wherein the first set of threads of the first layer and the second set of threads of the second layer consist of aramid threads, and the second set of threads of the first layer and the first set of threads of the second layer consist of polyester threads.

As long as the required linear density ratio is satisfied, the linear density of the first set of threads of the first layer and of the second set of threads of the second layer is selected to be at least about 210 dtex, preferably between 210 and 6720 dtex, more preferably between 420 and 3360 dtex, even more preferable between 420 and 1680 dtex and most preferably between 840 and 1100 dtex.

The linear density of the second set of threads of the first layer and the first set of threads of the second layer is at least 50 dtex. In a preferred embodiment of the penetration-resistant material according to the present invention the linear density of the second set of threads of the first layer and of the first set of threads of the second layer is between about 50 and 280 dtex and most preferably between 80 and 140 dtex.

In a peferred embodiment of the penetration-resistant material according to the present invention the double layer exibits two outer sides and at least one of the outer sides of the double layer is provided with a protective layer which can be a thermoplastic, thermoset or an elastomeric material or a mixture of these materials. The protective layer is applied to protect the fabric from damage by excessive abrasion and to improve the ballistic performance.

The penetration-resistant material according to the present invention comprises at least one double layer consisting of two layers of woven fabric, which are non-cross-plied and optionally bonded together. The term "woven" includes all types of weaves, such as plain weave, satin weave, basket weave, twill weave and the like. Preferred fabrics are plain woven.

The penetration-resistant material according to the present invention may contain as little as one double layer consisting of two layers of woven fabric, but usually more double layers are applied. Suitable numbers of double layers are 5 to 100. Most preferably 6 to 35 double layers are used. The first set of threads of the first fabric layer of a double layer may be parallel to, or at an angle to the first set of threads of the first fabric layer of the adjacent double layer. If these sets are secured together under an angle, such an angle is preferably 90°.

As mentioned before, the double layers may be secured together using an adhesive layer or by stiching. Such adhesive layer may be made of the previously mentioned adhesive materials and has a thickness between 4 and 36 µm, preferably between 8 and 20 µm.

Methods of manufacture of the double layers are well known in the art. Usually the fabric is made by warping the warp yarn on a beam, followed by weaving on a loom. The single layer may optionally be impregnated or laminated and be subjected to a calendering or lamination process. At least two fabric layers can be bonded together by stiching, heating or applying pressure.

The invention pertains also to an article made of the penetration-resistant material of the present invention according to the methods known to the skilled man. Examples for such an article are bullet proof vests and armor plates.

The invention is further illustrated with the following examples.

Example

A penetration-resistant material containing 22 double layers was manufactured by the following procedure.

The first layer of each double layer was produced from Twaron® 930 dtex ex Teijin Twaron in warp direction (9.5 threads/cm, water-repellant treated with OLEOPHOBOL SM® ex Ciba Spezialitätenchemie Pfersee GmbH, Langweid am Lech, DE) and polyester 140 dtex (Trevira® 710, ex Hoechst) in weft direction (2 threads/cm).

The second layer of each double layer was produced from polyester 140 dtex (Trevira® 710, ex Hoechst) in warp direction (4 threads/cm) and Twaron® 930 dtex ex Teijin Twaron in weft direction (9.5 threads/cm, water-repellant treated with OLEOPHOBOL SM® ex Ciba Spezialitätenchemie Pfersee GmbH, Langweid am Lech, DE). The warp/weft ratio of the first layer and the weft/warp ratio of the second layer was 6.6.

To prepare a double layer the first and second layer were laminated together with 3 plies of a polyethylene film (LDPE, ex EKB) having a thickness of 10 µm, one sheet of polyethylene film being placed on both outer sides of the double layer and one sheet of polyethylene film being placed in-between each of the two fabric layers of the double layer. 22 double layers were prepared in this way.

Said 22 double layers separated from each other by a release paper were superimposed, placed in a press and pressed at a temperature of 120 °C and at a pressure of 25 bar during 25 minutes. Then, the heating of the press was switched of. Afterwards, the 22 double layers were seperated from each another, the release paper was removed, and the 22 double layers were superimposed again to result in a penetration resistant material with a weight of about 4730 g/m2.

Comparative example

A penetration-resistant material with a weight of about 4730 g/m2 was manufactured as in the example with the only difference that none of the threads were water-repellant treated.

v50 - determination

v50 - values were determined with 9 x 19 Para type DM 11 A1B2 DAG bullets, wherein v50 is the velocity at which 50 % of the bullets are stopped and 50 % of the bullets give full penetration. The penetration resistant material subjected to the v50-determination was in the dry state. That means that said material was tested at room temperature and at a relative humidity of about 60 %.

With each penetration-resistant material two v50 measurements were performed the results of which were averaged as shown in the following table. Penetration-resistant material of v50 (m/s) 1st measurement v50 (m/s) 2nd measurement v50 (m/s) averaged example 496 505 501 comparative example 483 492 488

The table shows that the penetration-resistant material of the example exhibits an averaged v50 - value which is 2.7 % higher than that of the penetration-resistant material of the comparative example. Said difference in v50 corresponds to a 5.4 % higher energy absorption of the penetration-resistant material of the example if compared with the penetration-resistant material of the comparative example without any water-repellant treated threads.

Bundesmann rain-shower test

The penetration-resistant materials according to the example and the comparative example were subjected to the Bundesmann rain-shower test (ISO 9865). The following table shows the weight percentage of water uptake after 10 minutes. Penetration-resistant material of weight % water uptake example 10.5 comparative.example 34.4

The table shows that the penetration-resistant material of the example exhibits a water uptake which is only about a third of the water uptake of the penetration-resistant material of the comparative example without any water-repellant treated threads.

 A penetration-resistant material comprising at least a double layer of woven fabric wherein the double layer comprises a first layer of fabric composed of a first set of threads comprising 3.5 to 20 threads/cm, having a linear density of at least 210 dtex, and comprising at least 65 % of the fabric weight, and a second set of threads comprising 0.5 to 16 threads/cm and having a linear density of at least 50 dtex, with the second set of threads being transverse to the first set of threads, and the ratio of the number of threads/cm of the first set to that of the second set is > 1, and a second layer of fabric composed of a first set of threads comprising 0.5 to 16 threads/cm and having a linear density of at least 50 dtex, and a second set of threads comprising 3.5 to 20 threads/cm, having a linear density of at least 210 dtex, and comprising at least 65 % of the fabric weight, with the second set of threads being transverse to the first set of threads, and the ratio of the number of threads/cm of the second set to that of the first set is > 1, and wherein the first and second sets of threads of the first layer have a parallel orientation towards the first and second sets, respectively, of threads of the second layer, and wherein the first set of threads of the first layer and the first set of threads of the second layer are warp threads and the second set of threads of the first layer and the second set of threads of the second layer are weft threads, and wherein in the first layer of fabric at least the first set of threads and in the second layer of fabric at least the second set of threads are treated with a water-repellant. The penetration-resistant material of claim 1 wherein in the first layer of fabric the first and the second set of threads and in the second layer of fabric the first and the second set of threads are treated with a water-repellant. The penetration-resistant material of claim 1 or 2 wherein the water-repellant comprises fluor and carbon atoms. The penetration-resistant material of claim 3 wherein the water-repellant comprises a mixture of fluoroacrylate polymers. The penetration-resistant material of any one of claims 1 to 4 wherein the water-repellant treated threads comprise about 0.1 to about 2 weight % fluoroacrylate polymers with respect to the weight of the water-repellant treated threads. The penetration-resistant material of any one of claims 1 to 5 wherein at least the ratio of the linear density of the first set of threads to the linear density of the second set of threads of the first layer and of the linear density of the second set of threads to the linear density of the first set of threads of the second layer is > 1. The penetration-resistant material of claim 6 wherein at least the ratio of the linear density of the first set of threads to the linear density of the second set of threads of the first layer and of the linear density of the second set of threads to the linear density of the first set of threads of the second layer is > 4.2 . The penetration-resistant material of claim 6 or 7 wherein at least the ratio of the linear density of the first set of threads to the linear density of the second set of threads of the first layer and of the linear density of the second set of threads to the linear density of the first set of threads of the second layer is > 5.9 . The penetration-resistant material of any one of claims 1 to 8 wherein at least one of the second set of threads of the first layer and the first set of threads of the second layer comprises 0.5 to 8 threads/cm. The penetration-resistant material of any one of claims 1 to 9 wherein the threads of the layers of the double layer are bonded together. The penetration-resistant material of claims 10 wherein the threads of the layers of the double layer are bonded together with an adhesive material. The penetration-resistant material of any one of claims 1 to 11 wherein the first set of threads of the first layer and the second set of threads of the second layer consist of high tenacity threads selected from aramid, polyethylene and poly-p-phenylenebenzobisoxazole (PBO) threads. The penetration-resistant material of any one of claims 1 to 12 wherein the second set of threads of the first layer and the first set of threads of the second layer are selected from polyester, polyethylene, polypropylene and aramid threads. The penetration-resistant material of any one of claims 1 to 13 wherein the first set of threads of the first layer and the second set of threads of the second layer consist of aramid threads, and the second set of threads of the first layer and the first set of threads of the second layer consist of polyester threads. The penetration-resistant material of any one of claims 1 to 14 wherein the linear density of the first set of threads of the first layer and of the second set of threads of the second layer is 210 to 6720 dtex. The penetration-resistant material of claim 15 wherein the linear density of the first set of threads of the first layer and of the second set of threads of the second layer is 420 to 3360 dtex. The penetration-resistant material of claims 15 or 16 wherein the linear density of the first set of threads of the first layer and of the second set of threads of the second layer is 420 to 1680 dtex. The penetration-resistant material of claims 15, 16 or 17 wherein the linear density of the first set of threads of the first layer and of the second set of threads of the second layer is 840 to 1100 dtex. The penetration-resistant material of any one of claims 1 to 18 wherein the linear density of the second set of threads of the first layer and of the first set of threads of the second layer is 50 to 280 dtex. The penetration-resistant material of claim 19 wherein the linear density of the second set of threads of the first layer and of the first set of threads of the second layer is 80 to 140 dtex. The penetration-resistant material of any one of claims 1 to 20 wherein the double layer exibits two outer sides and at least one of the outer sides of the double layer is provided with a protective layer. An article made of the penetration-resistant material of any one of claims 1 to 21. Durchdringungshemmendes Material, welches mindestens eine Doppellage eines Gewebes umfasst, wobei diese Doppellage eine erste Gewebelage umfasst, die aus einer ersten Fadengruppe mit 3,5 bis 20 Fäden/cm mit einem Titer von mindestens 210 dtex, die mindestens 65 % des Gewichts dieser Gewebelage ausmacht, und aus einer zweiten Fadengruppe mit 0,5 bis 16 Fäden/cm mit einem Titer von mindestens 50 dtex besteht, wobei die zweite Fadengruppe quer zur ersten Fadengruppe verläuft und das Verhältnis von Anzahl Fäden/cm der ersten Fadengruppe zu Anzahl Fäden/cm der zweiten Fadengruppe > 1 ist, sowie eine zweite Gewebelage, die aus einer ersten Fadengruppe mit 0,5 bis 16 Fäden/cm und einem Titer von mindestens 50 dtex und aus einer zweiten Fadengruppe mit 3,5 bis 20 Fäden/cm und einem Titer von mindestens 210 dtex besteht, die mindestens 65 % des Gewichts dieser Gewebelage ausmacht, wobei die zweite Fadengruppe quer zur ersten Fadengruppe verläuft und das Verhältnis von Anzahl Fäden/cm der zweiten Fadengruppe zu Anzahl Fäden/cm der ersten Fadengruppe > 1 ist, und wobei die erste und zweite Fadengruppe der ersten Lage zur ersten bzw. zweiten Fadengruppe der zweiten Lage parallel verlaufen und die erste Fadengruppe der ersten Lage sowie die erste Fadengruppe der zweiten Lage Kettfäden und die zweite Fadengruppe der ersten Lage sowie die zweite Fadengruppe der zweiten Lage Schussfäden sind, und wobei in der ersten Gewebelage zumindest die erste Fadengruppe und in der zweiten Gewebelage zumindest die zweite Fadengruppe mit einem wasserabweisenden Mittel behandelt sind. Durchdringungshemmendes Material nach Anspruch 1, bei dem die erste und die zweite Fadengruppe in der ersten Gewebelage und in der zweiten Gewebelage mit einem wasserabweisenden Mittel behandelt sind. Durchdringungshemmendes Material nach Anspruch 1 oder 2, bei dem das wasserabweisende Mittel Fluor- und Kohlenstoffatome umfasst. Durchdringungshemmendes Material nach Anspruch 3, bei dem das wasserabweisende Mittel ein Gemisch von Fluoracrylatpolymeren umfasst. Durchdringungshemmendes Material nach einem der Ansprüche 1 bis 4, bei dem die mit wasserabweisendem Mittel behandelten Fäden ca. 0,1 bis ca. 2 Gew.-% Fluoracrylatpolymere umfassen, bezogen auf das Gewicht der mit wasserabweisendem Mittel behandelten Fäden. Durchdringungshemmendes Material nach einem der Ansprüche 1 bis 5, bei dem zumindest das Verhältnis von Titer der ersten Fadengruppe zu Titer der zweiten Fadengruppe der ersten Lage und von Titer der zweiten Fadengruppe zu Titer der ersten Fadengruppe der zweiten Lage > 1 ist. Durchdringungshemmendes Material nach Anspruch 6, bei dem zumindest das Verhältnis von Titer der ersten Fadengruppe zu Titer der zweiten Fadengruppe der ersten Lage und von Titer der zweiten Fadengruppe zu Titer der ersten Fadengruppe der zweiten Lage > 4,2 ist. Durchdringungshemmendes Material nach Anspruch 6 oder 7, bei dem zumindest das Verhältnis von Titer der ersten Fadengruppe zu Titer der zweiten Fadengruppe der ersten Lage und von Titer der zweiten Fadengruppe zu Titer der ersten Fadengruppe der zweiten Lage > 5,9 ist. Durchdringungshemmendes Material nach einem der Ansprüche 1 bis 8, bei dem mindestens eine aus der zweiten Fadengruppe der ersten Lage und der ersten Fadengruppe der zweiten Lage 0,5 bis 8 Fäden/cm umfasst. Durchdringungshemmendes Material nach einem der Ansprüche 1 bis 9, bei dem die Fäden der Lagen der Doppellage miteinander verbunden sind. Durchdringungshemmendes Material nach Anspruch 10, bei dem die Fäden der Lagen der Doppellage mit einem adhäsiven Material miteinander verbunden sind. Durchdringungshemmendes Material nach einem der Ansprüche 1 bis 11, bei dem die erste Fadengruppe der ersten Lage und die zweite Fadengruppe der zweiten Lage aus hochfesten Fäden, ausgewählt aus Aramid, Polyethylen und Poly-p-phenylenbenzobisoxazol (PBO), bestehen. Durchdringungshemmendes Material nach einem der Ansprüche 1 bis 12, bei dem die zweite Fadengruppe der ersten Lage und die erste Fadengruppe der zweiten Lage aus Polyester-, Polyethylen-, Polypropylen- und Aramidfäden ausgewählt sind. Durchdringungshemmendes Material nach einem der Ansprüche 1 bis 13, bei dem die erste Fadengruppe der ersten Lage und die zweite Fadengruppe der zweiten Lage aus Aramidfäden und die zweite Fadengruppe der ersten Lage und die erste Fadengruppe der zweiten Lage aus Polyesterfäden bestehen. Durchdringungshemmendes Material nach einem der Ansprüche 1 bis 14, bei dem der Titer der ersten Fadengruppe der ersten Lage und der zweiten Fadengruppe der zweiten Lage 210 bis 6720 dtex beträgt. Durchdringungshemmendes Material nach Anspruch 15, bei dem der Titer der ersten Fadengruppe der ersten Lage und der zweiten Fadengruppe der zweiten Lage 420 bis 3360 dtex beträgt. Durchdringungshemmendes Material nach Anspruch 15 oder 16, bei dem der Titer der ersten Fadengruppe der ersten Lage und der zweiten Fadengruppe der zweiten Lage 420 bis 1680 dtex beträgt. Durchdringungshemmendes Material nach Anspruch 15, 16 oder 17, bei dem der Titer der ersten Fadengruppe der ersten Lage und der zweiten Fadengruppe der zweiten Lage 840 bis 1100 dtex beträgt. Durchdringungshemmendes Material nach einem der Ansprüche 1 bis 18, bei dem der Titer der zweiten Fadengruppe der ersten Lage und der ersten Fadengruppe der zweiten Lage 50 bis 280 dtex beträgt. Durchdringungshemmendes Material nach Anspruch 19, bei dem der Titer der zweiten Fadengruppe der ersten Lage und der ersten Fadengruppe der zweiten Lage 80 bis 140 dtex beträgt. Durchdringungshemmendes Material nach einem der Ansprüche 1 bis 20, bei dem die Doppellage zwei Außenseiten aufweist und mindestens eine der Außenseiten der Doppellage mit einer Schutzschicht versehen ist. Matériau résistant à la pénétration, comprenant au moins une double couche de tissu tissé, dans lequel la couche comprend une première couche de tissu composée d'un premier jeu de fils comptant 3,5 à 20 brins/cm, avec une densité linéaire d'au moins 210 dtex et faisant au moins 65 % du poids du tissu, et un second jeu de fils comptant 0,5 à 16 brins/cm et avec une densité linéaire d'au moins 50 dtex, le second jeu de fils étant transversal au premier jeu de fils et le rapport du nombre de brins/cm du premier jeu à celui du second est > 1, et une seconde couche de tissu composée d'un premier jeu de fils comptant 0,5 à 16 brins/cm et avec une densité linéaire d'au moins 50 dtex, et un second jeu de fils comptant 3,5 à 20 brins/cm, avec une densité linéaire d'au moins 210 dtex, et faisant au moins 65 % du poids du tissu, le second jeu de fils étant transversal au premier jeu de fils, et le rapport du nombre de brins/cm du second jeu à celui du premier jeu est > 1, et dans lequel le premier et le second jeux de fils de la première couche ont une orientation parallèle, respectivement par rapport au premier et au second jeux de fils de la seconde couche, et dans lequel le premier jeu de fils de la première couche et le premier jeu de fils de la seconde couche sont des fils de chaîne, et le second jeu de fils de la première couche et le second jeu de fils de la seconde couche sont des fils de trame, et dans lequel, dans la première couche de tissu, au moins le premier jeu de fils et, dans la seconde couche de tissu, au moins le second jeu de fils sont traités avec un produit hydrophobe. Matériau résistant à la pénétration selon la revendication 1 dans lequel, dans la première couche de tissu, le premier et le second jeux de fils et, dans la seconde couche de tissu, le premier et le second jeux de fils, sont traités avec un produit hydrophobe. Matériau résistant à la pénétration selon la revendication 1 ou 2, dans lequel le produit hydrophobe comprend du fluor et des atomes de carbone. Matériau résistant à la pénétration selon la revendication 3, dans lequel le produit hydrophobe comprend un mélange de polymères de fluoroacrylate. Matériau résistant à la pénétration selon l'une quelconque des revendications 1 à 4, dans lequel les fils traités avec le produit hydrophobe comprennent environ 0,1 à environ 2 % en poids de polymères de fluoroacrylate, par rapport au poids des fils traités avec le produit hydrophobe. Matériau résistant à la pénétration selon l'une quelconque des revendications 1 à 5, dans lequel au moins le rapport de la densité linéaire du premier jeu de fils à la densité linéaire du second jeu de fils de la première couche, et de la densité linéaire du second jeu de fils à la densité linéaire du premier jeu de fils de la seconde couche est > 1. Matériau résistant à la pénétration selon la revendication 6, dans lequel au moins le rapport de la densité linéaire du premier jeu de fils à la densité linéaire du second jeu de fils de la première couche, et de la densité linéaire du second jeu de fils à la densité linéaire du premier jeu de fils de la seconde couche est > 4,2. Matériau résistant à la pénétration selon la revendication 6 ou 7, dans lequel au moins le rapport de la densité linéaire du premier jeu de fils à la densité linéaire du second jeu de fils de la première couche, et de la densité linéaire du second jeu de fils à la densité linéaire du premier jeu de fils de la seconde couche est > 5,9. Matériau résistant à la pénétration selon l'une quelconque des revendications 1 à 8, dans lequel au moins l'un parmi le second jeu de fils de la première couche et le premier jeu de fils de la seconde couche compte 0,5 à 5 brins/cm. Matériau résistant à la pénétration selon l'une quelconque des revendications 1 à 9, dans lequel les fils des couches de la double couche sont liés ensemble. Matériau résistant à la pénétration selon la revendication 10, dans lequel les fils des couches de la double couche sont liés ensemble par un adhésif. Matériau résistant à 1a pénétration selon l'une quelconque des revendications 1 à 11, dans lequel le premier jeu de fils de la première couche et le second jeu de fils de la seconde couche consistent en fils de haute ténacité choisi parmi des fils en aramide, polyéthylène et poly-p-phénylènebenzoxazole (PBO). Matériau résistant à la pénétration selon l'une quelconque des revendications 1 à 12, dans lequel le second jeu de fils de la première couche et le premier jeu de fils de la seconde couche sont choisis parmi des fils de polyester, polyéthylène, polypropylène et aramide. Matériau résistant à la pénétration selon l'une quelconque des revendications 1 à 13, dans lequel le premier jeu de fils de la première couche et le second jeu de fils de la seconde couche consistent en fils d'aramide, et le second jeu de fils de la première couche et le premier jeu de fils de la seconde couche consistent en fils de polyester. Matériau résistant à la pénétration selon l'une quelconque des revendications 1 à 14, dans lequel la densité linéaire du premier jeu de fils de la première couche et du second jeu de fils de la seconde couche est de 210 à 6720 dtex. Matériau résistant à la pénétration selon la revendication 15, dans lequel la densité linéaire du premier jeu de fils de la première couche et du second jeu de fils de la seconde couche est de 420 à 3360 dtex. Matériau résistant à la pénétration selon la revendication 15 ou 16, dans lequel la densité linéaire du premier jeu de fils de la première couche et du second jeu de fils de la seconde couche est de 420 à 1680 dtex. Matériau résistant à la pénétration selon la revendication 15, 16 ou 17, dans lequel 1a densité linéaire du premier jeu de fils de la première couche et du second jeu de fils de la seconde couche est de 840 à 1100 dtex. Matériau résistant à la pénétration selon l'une quelconque des revendications 1 à 18, dans lequel la densité linéaire du second jeu de fils de la première couche et du premier jeu de fils de la seconde couche est de 50 à 280 dtex. Matériau résistant à la pénétration selon la revendication 19, dans lequel la densité linéaire du second jeu de fils de la première couche et du premier jeu de fils de la seconde couche est de 80 à 140 dtex. Matériau résistant à la pénétration selon l'une quelconque des revendications 1 à 20, dans lequel 1a double couche présente deux faces externes et au moins l'une des faces externes de la double couche est pourvue d'une couche de protection. Article fabriqué avec le matériau résistant à la pénétration selon l'une quelconque des revendications 1 à 21. REFERENCES CITED IN THE DESCRIPTION

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Patent documents cited in the description