The invention concerns on the one hand a method of producing a fabric with insect repellent characteristics in which a solution comprising an insect repellent product and a binding agent is introduced onto the fabric as well as a fabric produced by a similar method on the other hand.
The invention concerns more particularly the enhancement of the retention of permethrin in fabrics during successive washes.
Permitrine is an insect repelling agent and is a member of the pyrethrum based substances. Because permitrine is quickly broken down, synthetic permitrine is often used in practice. It is principally used to repel or kill cold-blooded insects like mosquitoes.
Because of its insect repellent qualities, permitrine is often applied to fabrics, knitwear, non-woven, etc.... However, due to the weak permanence of permitrine, this insect repellent has the disadvantage that after only a few washes it is completely expelled from the fabric. Consequently, fabrics need to be re-treated with an insect repellent product after washing. This procedure has the disadvantage that it leads to increased costs as well as being damaging to the environment.
In order to retain permitrine longer in fabrics it is known from the
Another solution is described in the
The
In the American patent publications
While the solution described in the aforementioned publication is a good step forward, it still remains true that the insect repelling effect decreases after about twenty washes, because the permitrine slowly disappears out of the fabric, resulting in the need to treat the fabrics similarly once more.
The aim of the invention is to provide a method of producing a fabric with insect repellent properties whereby the insect repellent product stays active in the fabric even after a large number of washes. By a large number of washes this patent request means at least 60, preferably 60 to 100 washes and, in particular, to in excess of 100 washes.
The aim of the invention is accomplished by the application of a method for making fabrics with insect repellent properties in which a solution comprising an insect repellent product and a binding agent are applied to a fabric wherein said insect repellent product is permethrin and wherein in the solution a combination of an acrylate binding agent and a silicon elastomer is added in order to enhance the retention of the permethrin during successive washes of the fabric. Acrylate is the binding agent. The named solution is applied in a preferential operation on fabrics, knitwear or on non-wovens. By adding the combination elastomer/acrylate the insect repellent product remains much longer on the fabric during successive washes.
The specified solution should also contain an anti - foam agent, preferably on the basis of dimethylpolysiloxane and a moistening agent.
According to the invention, in a particular method for the manufacture of a fabric with insect repellent properties, the amount of acrylate in the solution amounts to at least 20 g/l, in particular at least 90 g/l acrylate. The quantity of acrylate in the solution lies in particular between 20 and 250 g/l.
The amount of elastomer in the solution amounts to at least 20 g/l and is preferably between 20 and 60 g/l and amounts to more by particular 50 g/l. Through the combination of silicon elastomer/acrylate the insect repellent product stays much longer on the fabric than with currently known and applied techniques.
In a more preferred method for the manufacture of a fabric with insect repellent properties according to the invention, the amount of permethrin in the solution should be between 10 and 250 g/l, preferably between 20 and 150 g/l, and more in particular between 20 and 50 g/l. Other insect repellent products that can be used by preference are cyfluthrine and deltamethrine.
According to invention, a particular preferential method for the manufacturing of a fabric with insect repellent properties is that the specified solution is applied to the fabric via impregnation, a spray, coating, lick roll or other known method whereby the fabric is preferably pressed out between two rolls. After this the fabric is dried in a dry unit at a minimum temperature of 110 °C. The method can by preference be applied to non-wovens, knitwear or fabrics such as cotton, polyester/cotton, flax, flax/cotton, polyamide, polyamide/cotton, polyester, polyester/viscose, meta aramide, meta aramide/cotton, modacryl, modacryl/cotton, viscose/cotton or combinations thereof.
Another subject of this invention is a fabric with insect repellent properties provided with a solution comprising an insect repellent product and a binding agent, wherein the said insect repellent product is permethrin and wherein the said solution has a combination of an acrylate binding agent and a silicon elastomer added in order to enhance the retention of the permethrin on the fabric. According to the invention, the fabric hereby retains its insect repellent properties during successive washes. Tests have shown that the fabric retains its insect repellent properties when washing at 60°C for at least 60 washes, by preference between 60 and 100 washes and more.
According to the invention the fabric is preferably manufactured by a method according to any one of the claims 2 up to and including 7.
This patent request further contains the use of the combination acrylate / elastomer, in particular silicon elastomer as a retention increasing agent in a solution comprising an insect repellent product. By adding this combination, the insect repellent product remains on the fabric much longer, especially the permethrin, during successive washes.
In order to clarify the properties of this invention further and to point out extra advantages and peculiarities, there now follows a more detailed description of the applied method of producing fabric according to this method. Nothing in the following description is to be interpreted as a limitation to the protection requested in the conclusions for this invention.
To make fabric, knitwear or non-woven wash permanent insect repellent, the fabric is impregnated, for example by means of dip coating with a solution comprising an insect repellent product, an acrylate and an elastomer, preferably a silicon elastomer, a moisture agent and an anti foam agent.
Below is a working example showing the composition of a solution that is applied to fabric in order to make this fabric wash permanent insect repellent (n.b. for example without anti foam agent). The usual quantity of permitrine, which generally is effectively regarded as 700 mg to 1300 mg/m2. The concentration on the fabric however, depends on the concentration in the bath, the throughput and the weight of the fabric. One can therefore establish that the concentration required on a certain fabric together with the weight of the fabric defines the concentration of permitrine in the application bath.
The above mentioned products are first dispersed in water that have been brought by the addition of acetic acid 80 % on a PH lying between 5 and 7, in particular 6.
The resulting solution is then continually fed in an application bath that allows the full breadth of the fabric to be impregnated. Here it should be noted that the solution can likewise be applied discontinued.
The application of the solution is 48 % (depending on the kind of fabric) in other words 1 kg. Of material takes 0,48 1 water and thus the following products are in the 0.48 1 (as shown in the example below):
There is therefore for 25 g/l permitrine in the bath per 1 kg fabric treated, 12 g permethrin. Assuming that the weight of the fabric is 210 g/m2, there is per m2; 12 g/kg x 0.210 kg/m2 = 2.52 g/m2 permitrine on the fabric. However, the used permitrine is a 50 % product where there is therefore 2.52 g/m2 x 50 % = 1.26 g of 1260 mg/m2 permitrine on the fabric.
After the fabric has been impregnated with the solution the specified fabric is uniformly pressed out between two rolls with a specific hardness. The hardness of the rolls similarly determines the absorption of the solution because the harder the rolls, the higher the pressing out level and the less the absorption.
After this the fabric is dried in a drying unit at a temperature of at least 110 °C. The drying unit consists of various units each with its own heating and air circulation with control aggregates. After drying, the fabric comes into a cooling zone with air followed by contact cooling.
The following example again shows the effect of the addition of the combination acrylate / silicon elastomer to a solution containing with an insect repellent product.
From the above example it seems clear that by the addition of the combination silicon elastomer/acrylate the insect repellent product is retained in the fabric much longer during successive washes than with the combinations (e.g. permitrine + silicon elastomer) as known in current techniques.
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