[0001] The present invention relates to high-strength steels for large-scaled forgings,
such as for manufacturing an integrated type of forged steel assembled large-scaled
crankshaft, which is suitable for use in a diesel engine or the like used in a ship
or generator, and to crankshafts using the same. More particularly, the invention
relates to a high-strength steel for a large-scaled forging with the small content
of Ni, which is an expensive alloying element, and having high strength at low cost,
and to a large-scaled crankshaft which exhibits such properties.
[0002] To improve outputs from diesel engines of ships or generators, and to achieve downsizing
of these engines, it is required to strengthen steels, which is to be used for components
thereof. Such components are generally produced by forged steels. This kind of steel
for crankshafts has the maximum tensile strength of about 950 N/mm
2, while steels for crankshafts having the strength of 1000 N/mm
2 or more are required in order to meet such a requirement.
[0003] As the steel for large-scaled forgings with the strength of 1000 N/mm
2 or more, 3.5NiCrMo steel or the like is known which is used in rotors (see, for example,
"Tetsu to Hagane", vol. 89 (2003) No. 6) . This steel has the most excellent strength,
toughness, and the like, and is used as a rotor (rotating shaft) for a generator which
is put under high load.
[0004] The above type of steel, however, contains the large amount of Ni, which is very
expensive, as an alloying element for strengthening and toughing the steel, and is
preferably subjected to a two-stage tempering process to ensure toughness, or to a
specific prehardening process to minimize the grain size, resulting in a problem of
high cost.
[0005] On the other hand, Cr-Mo steels, notably 34CrNiMo6 as defined in a DIN specification,
32CrMo12 as defined in the same, 42CrMo4 as defined in an ISO specification, have
been hitherto used as steels for large-scaled crankshafts, which are used for parts
of an engine and a transmission mechanism in the ships or the like. These types of
steels have the advantage of relatively low cost because they have less content of
Ni compared to the above-mentioned 3.5NiCrMo steel. In fact, however, these steels
do not meet the recent requirements in terms of strength and toughness, as compared
to the above type of steel.
[0006] The present invention has been accomplished in view of the above-mentioned problems,
and it is an object of the invention to provide a high-strength steel for a large-scaled
forging which is low in cost as compared to the 3. SNiCrMo steel proposed as the steel
for the high-strength Ni-Cr-Mo steel, and which has excellent strength and toughness
as compared to the 34CrNiMo6 as defined in the DIN specification which has been put
to practical use. Alternatively, it is an object of the invention to provide a low-cost
large-scaled crankshaft with excellent strength and toughness, utilizing the same.
[0007] A high-strength steel for a large-scaled forging according to the invention, which
has solved the above-mentioned problems, has the principle that the steel consists
essentially of, by mass, (the contents of the following components being expressed
in mass % in the same manner) C: 0.30 to 0.50 %, Si: more than 0.15 %, but not more
than 0.40 %, Mn: 0.80 to 1.20 %, Ni: 0.80 to 2.5 %, Cr: 1.0 to 3.0%, Mo: 0.35 to 0.70
%, V: 0.10 to 0.25%, and balance: Fe and unavoidable impurities.
[0008] In the high-strength steel for a large-scaled forging of the invention, a grain size
in a metal structure of the steel is preferably an ASTM grain size number ranging
from 2 to 6. Further, the high-strength steel for a large-scaled forging of the invention
is preferably produced by quenching under 200 °C from austenitizing-temperature and
then tempering.
[0009] By forging the above-mentioned high strength steel for a large-scaled forging, a
large-scaled crankshaft with desired properties is obtained. Such a crankshaft is
useful as a crankshaft for a diesel engine used in a ship or generator.
[0010] In the high-strength steel for a large-scaled forging according to the invention,
the Ni content is reduced as compared to that of the 3.5NiCrMo steel which has been
proposed as steel for a high-strength Ni-Cr-Mo forging, leading to reduction in cost,
while predetermined contents of Si, Mn, Cr, and the like are contained therein, enhancing
the strength. Thus, the invention can provide the steel for forgings of high quality
at low cost. Further, this steel for forgings has very excellent hardenability (quenching
ability). That is, this steel has an excellent property that the microstructure can
be controlled to that consisting only of bainite and martensite. Using the excellent
hardenability, the steel can be effectively utilized as material for large-scaled
forged products. In particular, the steel is extremely useful as material for large-scaled
crankshafts, including a crankshaft for a diesel engine used in a ship or generator.
Fig.1 is a graph showing a relation between an absorbed energy at the strength of
1000 N/mm2, into which the determined absorbed energy is converted, and the Ni content.
Fig.2 is a graph showing a relation between the Ni content and the grain size number.
Fig. 3 is a graph showing a relation between the tempering start temperature and the
tensile strength TS.
Fig. 4 is a graph showing a relation between the tempering start temperature and the
impact value (absorbed energy).
[0011] Under these problems, the inventors have been dedicated themselves to studying the
development of steel for a forging in which the amount of Ni contained as an alloying
element is reduced as compared to, in particular, 3.5NiCrMo steel known as the high-strength
steel for forgings, leading to reduction in cost, and further which has the strength
and toughness equivalent to those of the known steel, while being capable of exhibiting
excellent hardenability, which is important in manufacturing the large-scaled high-strength
forgings.
[0012] As a result, the inventors have found that the amount of Ni serving as a strengthening
element in the above-mentioned steel for Ni-Cr-Mo based steels should be reduced as
much as possible, while the elements including Si, Mn, Cr, and the like, should be
added in appropriate amounts, thereby providing the steel for forgings with extremely
excellent hardenability and with the improved strength and toughness to compensate
for the shortage of strength caused by the decreased Ni amount, so that the invention
has been accomplished.
[0013] That is, Ni is a very useful element for enhancing the strength and toughness of
the Cr-Mo based steel, which has been used as the steel for forgings for multipurpose
applications as mentioned above, and for improving the hardenability. For this reason,
the Ni is the extremely useful element to the high-class Cr-Mo based steel for forging.
However, since the Ni is the expensive element, an excessive increase in the Ni content
would lead to an increase in cost of the steel, whereby the consumer' s requirements
regarding prices cannot be satisfied. Accordingly, the invention has been developed
to achieve the following most important aims: to reduce the Ni content as much as
possible, and to be capable of ensuring the strength and quenching properties equivalent
to those of the conventional steel for Ni-Cr-Mo based steels. In order to accomplish
the object of reducing cost by decreasing the amount of Ni, the Ni content is desirably
reduced to not more than 2.5 %.
[0014] The steel for forgings according to the invention is characterized by that the Ni
content is restricted as mentioned above, and that instead the alloying elements including
Si, Mn, Cr, and the like are added in appropriate amounts. The reasons for restriction
of a chemical component composition defined by the invention, including the above-mentioned
elements, are as follows:
C: 0.30 to 0.50 %
[0015] C is an element contributing to enhancement of the hardenability and improvement
of the strength. To ensure enough strength and hardenability, the C needs to be contained
in an amount of 0. 30 % or more. The excessive C content, however, extremely decreases
the toughness, while enhancing formation of an inverse V-segregation in a large-scaled
ingot. Accordingly, the C content is preferably reduced to not more than 0.50 %.
Si: more than 0.15 %, but not more than 0.40 %
[0016] The element Si acts as a strength improving element, and needs to be contained in
an amount exceeding 0.15 % in order to ensure enough strength. The excessive amount
of Si, however, results in formation of the significant inverse V-segregation, making
it difficult to obtain clean ingots. Accordingly, the Si content should be not more
than 0.40 %.
Mn: 0.80 to 1.20 %
[0017] The element Mn is an element contributing to enhancement of the hardenability and
improvement of the strength. To ensure enough strength and hardenability, the Mn needs
to be contained in an amount of 0.80 % or more. The excessive Mn content, however,
enhances the tempering embrittlement. Accordingly, the Mn content needs to be not
more than 1.20 %.
Cr: 1.0 to 3.0 %
[0018] The element Cr is an element which is useful for enhancement of the hardenability
and improvement of the toughness. To sufficiently exhibit these effects, the Cr needs
to be contained in an amount of 1.0% or more. The excessive Cr content, however, forms
inhomogeneous solidification, making it difficult to manufacture the clean steel.
Accordingly, the Cr content needs to be not more than 3.0 %.
Mo: 0.35 to 0.70 %
[0019] The element Mo is an element which effectively acts to improve all of the hardenability,
strength, and toughness. To sufficiently exhibit these effects, the Mo needs to be
contained in an amount of 0.35 % or more. If the Mo content is less than the above-mentioned
amount, the inverse V-segregation is formed, which is not desirable. In contrast,
since the excessive Mo content promotes micro-segregation in the ingots, and the Mo
is a heavy element, gravity segregation tends to occur. Accordingly, the Mo content
needs to be not more than 0.70 %.
V: 0.10 to 0.25 %
[0020] The element V is an element which effectively acts to improve the hardenability and
strength even in a small amount. To exhibit these effects, the V needs to be contained
in an amount of 0.10% or more. However, since the element V has a low equilibrium
distribution coefficient, the excessive V content tends to cause the micro-segregation
(normal segregation). Accordingly, the V content needs to be not more than 0.25 %.
[0021] In the steel for forgings used in the invention, preferable basic components are
as mentioned above. The balance consists essentially of Fe, but the minute amounts
of unavoidable impurities (including, for example, P, O, N, Al, or the like) may be
allowed to be contained in the steels. It should be noted that the steel for forgings
positively containing another element within a range that does not adversely affect
the effects of the invention can be employed. The other elements that are allowed
to be included in the steel are, for example, Ti, Ca, Mg, S, and the like. From a
viewpoint of prevention of formation of rough inclusions, these elements are desirably
reduced to not more than about 0.5 % in total.
[0022] It is well known that minimizing the grain size improves the toughness of the steel
material. To minimize the grain size, it is necessary to perform an austenitizing
process as a precondition. That is, the austenitizing process is carried out for fining
and uniforming the grain size, preceding the quenching. In the austenitizing process
of the large-scaled forging, a holding time becomes long so that austenite transformation
can take place inside the steel. Thus, the larger the product, the larger the difference
in grain size between inside and outside tends to be, where a special process, such
as multi-stage, namely, two or more stage, austenitizing process is often carried
out to minimize the grain size.
[0023] On the other hand, it is well known that inclusion of the element Ni is effective
in improving the toughness of the steel. The excessive Ni content, however, tends
to increase the grain size, and austenite tends to remain in quenching. If the large
amount of remaining austenite exists in quenching, then it is transformed into martensite
in tempering, resulting in a hard and brittle structure mixed in, thus leading to
deterioration in the toughness. This needs to temper again the martensite which has
already been produced in the first tempering process, in a case where the certain
toughness is strictly required. This is why the two-stage tempering process is often
carried out.
[0024] From this viewpoint, the inventors have fully considered aiming for development of
the steel which can ensure enough toughness even in coarse grains, and which suppresses
the formation of the remaining austenite in quenching, without needing the special
process, such as the two-stage tempering process, for the purpose of ensuring the
toughness. As a result, it has been clearly found that the high-strength steel for
forgings with the above chemical composition ensures enough toughness even in the
metal structure having the grain size of the ASTM grain size No.6 or less, and has
only to be subjected to only one-time tempering process. Note that the steel with
the ASTM grain size number less than two, the grain size is significantly increased,
resulting in degradation in toughness of the forged steel. Accordingly, the ASTM grain
size number is preferably at least two.
[0025] A crankshaft for a diesel engine used in a ship or generator has a journal diameter
of at least about 150 mm, which is extremely large as compared to that of the vehicle
(for example, about 15 mm). Since water quenching leads to a danger of cracking and
breaking down in manufacturing the large-scaled forging, quenching of the large-scaled
crankshaft is generally performed by oil quenching, polymer quenching, air cooling
or the like. In manufacturing the large-scaled crankshaft of interest in the invention,
although cooling rate in the quenching depends on a diameter of the crankshaft, it
is not more than 50 °C/min in the oil quenching. More specifically, for a crankshaft
with a diameter of 500 mm grade, the cooling rate is about 20 °C/min. For a crankshaft
with a larger diameter than this (for example, 1000 mm), the cooling rate is much
lower.
[0026] To obtain the high-strength steel for large-scaled forgings with both excellent strength
and toughness, the microstructure is preferably controlled to consist of bainite and
martensite. As a result of studying a condition in which such a structure is achieved
even at the quenching cooling rate of about 20 °C/min (in the case of oil quenching)
so as to apply the steel to the large-scaled crankshaft with a diameter of 150 mm
or more, the inventors have found out the aforesaid chemical composition.
[0027] Note that since, for a crankshaft with a much larger diameter, the desired cooling
rate (20 °C/min) in the oil quenching is not often reached, the above "polymer quenching"
is recommended to be carried out in this case. This polymer quenching involves cooling
the steel by use of cooling solution which is produced by dissolving organic solvent,
such as glycols (for example, diethylene glycol, polyethylene glycol, or the like),
into water. Such polymer quenching is capable of achieving cooling rate higher than
that in the oil quenching. Therefore, the polymer quenching is a cooling system useful
for prevention of cracks, which might occur in the water quenching, and for achieving
the higher cooling rate, for example, the cooling rate of more than 20 °C/min for
the relatively large-scaled forgings.
[0028] In the quenching, preferably, the austenitized steel is subjected to quenching to
under 200 °C, and then tempering from a viewpoint of completion of the transformation.
If the quenching temperature (namely, tempering start temperature) exceeds 200 °C,
partially austenite remains without transformation to bainite and martensite, which
causes variations in properties.
[0029] A method of manufacturing the steel for the forging according to the invention is
not particularly limited. The steel has only to be adjusted to predetermined chemical
compositions, and then to be cast using a high-frequency melting furnace, an electric
furnace, a converter, or the like in a normal manner. Performing a vacuum process
after adjustment of the compositions is also effective. In the case of the steel for
the large-scaled forging, ingot casting is mainly employed, while, in the case of
the relatively small-scaled forging, a continuous casting method can be employed.
[0030] Further, a method of manufacturing, for example, a crankshaft or the like, using
the steel for forgings, is not particularly limited. For example, the method may comprise
the following steps of: melting steel with a predetermined composition in the electric
furnace; removing an impurity element, such as S, and a gas component, such as O,
by vacuum refining; ingot-making; forging to a bar after heating the ingot; heating
the forged bar after an intermediate inspection and forging it into a shape of a crankshaft;
performing heat treatment for obtaining required properties such as quench-hardening
and tempering; and finish machining, wherein these steps are carried out in this order.
[0031] It should be noted that a free forging method (which involves forging a crank arm
and a crank pin into one block, and finishing the forged block into the crankshaft
shape by gas cutting and machining), and RR and TR forging methods (which involves
performing forge processing in such a manner that the center axis of an ingot is aligned
with a center axis of a crankshaft) are exemplified as a forge processing method for
forging the material into the crankshaft. Inparticular, the latter is more preferable
because high cleanness level without segregation can be obtained in the near surface
region where high stress is loaded in operation, easily obtaining the crankshaft with
excellent strength and fatigue property. The thus-obtained crankshaft is very useful
as a crankshaft for a diesel engine used in a ship or generator.
[0032] Now, the effects and advantages of the invention will be hereinafter described more
specifically by way of examples. It is understood that the invention is not to be
limited to the following specific examples, and that various appropriate modifications
can be devised and carried out within the applicable scope of the invention mentioned
above and below, and are intended to be included in the technical scope of the invention.
[Example]
Example 1
[0033] Steels with chemical compositions given in the following Table 1 were melted using
a high-frequency melting furnace, and then cast into ingots (40 kg) each having a
diameter of 132 to 158 mm and a length of 323 mm. A feeder-head part of each of the
obtained ingots was cut off, and then the ingot was heated at 1230 °C for five to
ten hours. Thereafter, the ingot was pressed into one second in height using an open-die
forging press, and stretched to 90 mm x 90 mm x 600 mm after changing the forging
direction to the transversal direction against the center line of the ingot. The thus-obtained
billet was cooled in air.
[Table 1]
[0034] After the steel was cooled to room temperature, a quenching process was carried out
which simulated respective heating and cooling rates at a point located 50 mm (which
is one tenth of the diameter) below the surface of the crankshaft having the diameter
of 500 mm. More specifically, the steel was heated up to 870 °C at a rate of temperature
increase of 40 °C/hr using a small-scaled simulate furnace, and kept at the temperature
for one hour. (austenitizing process) Then, the steel was cooled at an average cooling
rate of 20 °C/min to a temperature ranging from 500 to 870 °C to perform a quenching
process. A tempering process was carried out at a temperature ranging from 580 to
630 °C for 13 hours, and cooling was performed by furnace cooling. Thereafter, mechanical
properties of each of the thus-obtained steels were evaluated in the following manner.
The grain size of the steel was measured based on the ASTM (grain size number).
[Measurement Method of Mechanical Properties]
[0035]
(A) Tensile tests were performed for each of the steels based on JIS Z2241, wherein
the shape of a test piece, which is the JIS Z2201 No.14 specimen, is Φ6 × G.30. The
mechanical properties [yield stress (YS), tensile stress (TS), elongation (EL), reduction
of area (RA)] of the steel were measured.
(B) A Charpy impact test was performed for the type of steel with a tensile strength
TS of not less than 1000 N/mm2 . The Charpy impact test was carried out based on JIS Z2242 to measure its absorbed
energy vE, wherein the shape of a test piece employed is 2 mm V-notch based on JIS
Z2202. In order to evaluate toughness at the same strength, the absorbed energy vEat
(1000 N/mm2) at the strength of 1000 N/mm2 was calculated by the following calculation method to evaluate the toughness.
[0036] The absorbed energies at tempering temperatures which brought about the strength
of around 1000 N/mm
2 are designated as Eu and Ed, and the respective tensile strengths as Su and Sd.
Eu: Absorbed energy at an tempering temperature (Td) at which the strength of not
less than 1000 N/mm2 was obtained
Su: Tensile strength on the above condition
Ed: Absorbed energy at an tempering temperature (Td) at which the strength of not
more than 1000 N/mm2 was obtained
Sd: Tensile strength on the above condition

[0037] These results were given in the following Table 2, together with the quenching and
tempering temperatures. From the results, the following can be shown. First, it has
shown that in samples of tests No.1 to 3, 13, and 14, any of chemical components thereof
deviates from a range specified by the invention, and that the tensile strength TS
of each of these samples does not reach 1000 N/mm
2 (unachievable strength).
[0038] In contrast, it has shown that samples of tests No. 4 to 12, which meet the range
specified by the invention, have the tensile strength of not less than 1000 N/mm
2. Moreover, it has found that a Charpy absorbed energy of each of these samples vE
tends to depend on the Ni content.
[0039] Note that, after the austenitizing, quenching and tempering processes, a cross section
of each sample was etched by natal, and then two or more views thereof were photographed
by an optical microscope with a magnification of 100 times. From the photographs,
area fractions of respective areas classified into ferrite and pearlite were determined
to examine the metal structure of each sample. It has found that the area fractions
of ferrite and pearlite in each sample are substantially zero, and the structure thereof
consists essentially of bainite and martensite.
[Table 2]
[0040] Based on such results, a relation between an absorbed energy at the strength of 1000
N/mm
2, into which the determined absorbed energy is converted, and the Ni content is shown
in Fig.1. Further, a relation between the Ni content and the grain size number is
shown in Fig.2. Fig.1 shows clearly that the steel with the Ni content of not less
than 0.80 % and not more than 2.5 % has good impact property. It is generally known
that increase in the Ni content improves the toughness of the steel. That is, it has
shown that the effect of Ni is not exhibited markedly until the Ni content reaches
0.80 % or more. In contrast, it has shown that when the Ni content is more than 2.5
%, the toughness is lowered. This indicates, as shown in Fig.2, that the grain size
increases with increase in the Ni content, and that such increase in the grain size
lowers the toughness. Further, as can be seen from Figs. 1 and 2, the steel with the
grain size number of two or more can ensure the good toughness. In a steel for forging
in general, toughness improves monotonously as Ni content increases. However, in a
combination of a composition and conditions of heat treatment, a suitable range of
Ni content exists so as to maintain high toughness, as shown in this example. And
the upper limit of the range of Ni content 2.5% equals by chance the aforementioned
upper limit of Ni content to be considered in terms of cost.
Example 2
[0041] Generally, in manufacturing a large-scaled forging, the steel is cooled not to room
temperature, but to a temperature ranging from 200 to 300 °C, and then a tempering
process is successively carried out, from a viewpoint of preventing cracking, which
might be caused by deforming and thermal stresses in the quenching and tempering processes.
[0042] From this viewpoint, in the samples of the tests No. 1 and 9 as shown in Table 2
(the steels of the types A and I as shown in Table 1), influences of the tempering
start temperature (quenching end temperature) on the mechanical properties [tensile
strength (TS), 0.2 % proof strength (0.2PS), elongation (EL), reduction of area (RA),
absorbed energy (vE)] were examined (other conditions being the same as those of the
inventive examples). The results are shown in the following Table 3. Further, based
on the results, a relation between the tempering start temperature and the tensile
strength TS is shown in Fig. 3, and a relation between the tempering start temperature
and the impact value (absorbed energy) is shown in Fig.4.
[Table 3]
[0043] From these results, the following can be shown. In the sample of the test No.1, the
tempering start temperature does not have so much influence on the mechanical properties,
while in the sample of the test No.9, the tempering start temperature has significant
influence on the properties. Such results have shown that setting the tempering start
temperature (quenching end temperature) to not more than 200 °C can ensure the stabilized
strength without degradation in toughness.
[0044] A cause of the influence of the tempering start temperature on the tensile strength
in the chemical compositions specified by the invention is not clearly known, but
it is considered that the chemical compositions limited within a range specified by
the invention form a partial martensitic structure, and not a complete bainitic structure,
and that the tempering start temperature has the influence on formation of such a
transformed structure.
Table 1
| Type of steel |
Chemical composition (mass %) |
| |
C |
Si |
Mn |
P |
S |
Cu |
Ni |
Cr |
Mo |
V |
Al |
| A |
0.35 |
0.24 |
0.62 |
0.004 |
0.003 |
0.03 |
1.51 |
1.49 |
0.22 |
0.081 |
0.003 |
| B |
0.28 |
0.23 |
1.05 |
0.005 |
0.003 |
0.03 |
1.52 |
2.03 |
0.52 |
0.21 |
0.004 |
| C |
0.38 |
0.26 |
0.77 |
0.003 |
0.003 |
0.03 |
1.54 |
2.03 |
0.53 |
0.19 |
0.006 |
| D |
0.36 |
0.22 |
0.99 |
0.005 |
0.003 |
0.03 |
0.22 |
2.92 |
0.47 |
0.1 |
0.005 |
| E |
0.36 |
0.24 |
0.94 |
0.005 |
0.003 |
0.03 |
3.05 |
0.21 |
0.49 |
0.11 |
0.026 |
| F |
0.36 |
0.23 |
0.98 |
0.005 |
0.003 |
0.03 |
1.63 |
1.58 |
0.48 |
0.11 |
0.022 |
| G |
0.39 |
0.2 |
0.94 |
0.008 |
0.003 |
0.04 |
0.52 |
2.9 |
0.48 |
0.15 |
0.018 |
| H |
0.38 |
0.21 |
1.02 |
0.008 |
0.003 |
0.05 |
0.82 |
2.8 |
0.47 |
0.16 |
0.030 |
| I |
0.34 |
0.22 |
0.98 |
0.007 |
0.003 |
0.04 |
1.58 |
1.59 |
0.49 |
0.16 |
0.020 |
| J |
0.36 |
0.25 |
1.03 |
0.006 |
0.003 |
0.05 |
2.01 |
1.55 |
0.48 |
0.17 |
0.022 |
| K |
0.37 |
0.23 |
0.99 |
0.007 |
0.003 |
0.04 |
2.41 |
1.62 |
0.51 |
0.17 |
0.023 |
| L |
0.34 |
0.22 |
0.97 |
0.007 |
0.003 |
0.04 |
2.98 |
1.6 |
0,49 |
0.11 |
0.023 |
| M |
0.39 |
0.2 |
0.94 |
0.008 |
0.003 |
0.04 |
0.52 |
2.9 |
0.27 |
0.15 |
0.018 |
| N |
0.39 |
0.2 |
0.94 |
0.008 |
0.003 |
0.04 |
0.52 |
2.9 |
0.48 |
0.88 |
0.018 |
Table 2
| Test No. |
Type of steel |
Quenching temperature |
Tempering temperature |
Grain size No. |
YS (N/mm2) |
TS (N/mm2) |
EL (%) |
RA (%) |
vE Ave. |
vE at (1000N/mm2) |
Remarks |
| 1 |
A |
870 |
590 |
5 |
885 |
988 |
17.8 |
65.1 |
Unadvevable strength |
Conventional steel 34CrNiMo6 |
| 610 |
5 |
804 |
948 |
18.6 |
65.7 |
| 630 |
5 |
718 |
873 |
19.9 |
69.4 |
| 2 |
B |
870 |
590 |
3.3 |
829 |
982 |
17.1 |
63.6 |
Unachievable strength |
Influence of C |
| 610 |
3.3 |
769 |
917 |
20 |
70.2 |
| 630 |
3.3 |
709 |
860 |
20.5 |
71.1 |
| 3 |
C |
870 |
590 |
3.9 |
817 |
992 |
17.7 |
65.9 |
Unachievable strength |
Influence of Mn |
| 610 |
3.9 |
720 |
886 |
20.1 |
70.6 |
| 630 |
3.9 |
683 |
853 |
19.9 |
70.8 |
| 4 |
D |
870 |
580 |
6.2 |
959 |
1122 |
16.9 |
61.8 |
22.5 |
40.5 |
Influences of Ni and Cr |
| 600 |
6.2 |
840 |
987 |
16.6 |
65.9 |
42.4 |
| 620 |
6.2 |
776 |
923 |
19.5 |
70.3 |
82.1 |
| 5 |
E |
870 |
580 |
1.15 |
986 |
1122 |
17.6 |
58.6 |
21.7 |
39.0 |
Ni,Cr |
| 600 |
1.15 |
939 |
1067 |
17.3 |
58.7 |
23.1 |
| 620 |
1.15 |
898 |
1016 |
17.9 |
61.4 |
35.2 |
| 6 |
F |
870 |
580 |
2.6 |
1048 |
1190 |
16.3 |
59.3 |
20.4 |
87.3 |
- |
| 600 |
2.6 |
915 |
1060 |
16.9 |
61.1 |
57.6 |
| 620 |
2.6 |
848 |
998 |
19.3 |
65.6 |
86.3 |
| 7 |
G |
870 |
580 |
5.15 |
976 |
1133 |
14.8 |
60.7 |
31.5 |
66.7 |
- |
| 600 |
5.15 |
874 |
1033 |
17.1 |
63.4 |
62.3 |
| 620 |
5.15 |
741 |
897 |
21.1 |
69.5 |
83.3 |
| 8 |
H |
870 |
580 |
4.05 |
994 |
1138 |
15.4 |
59.5 |
36.7 |
86.4 |
- |
| 600 |
4.05 |
877 |
1041 |
17.7 |
64.5 |
78.7 |
| 620 |
4.05 |
740 |
901 |
19.3 |
68.9 |
105 |
| 9 |
I |
870 |
580 |
4.1 |
1083 |
1214 |
16.9 |
60.4 |
25.7 |
103.1 |
- |
| 600 |
4.1 |
988 |
1111 |
17 |
61.7 |
79.7 |
| 620 |
4.1 |
860 |
986 |
19.9 |
66.1 |
106 |
| 10 |
J |
870 |
580 |
2.8 |
984 |
1103 |
15.4 |
59.5 |
33.4 |
86.6 |
- |
| 600 |
2.8 |
867 |
1061 |
17.7 |
64.5 |
70.7 |
| 620 |
2.8 |
733 |
931 |
19.3 |
68.9 |
105 |
| 11 |
K |
870 |
580 |
2.4 |
989 |
1152 |
15.4 |
59.5 |
28.7 |
76.2 |
- |
| 600 |
2.4 |
876 |
1053 |
17.7 |
64.5 |
64.7 |
| 620 |
24 |
743 |
923 |
19.3 |
68.9 |
93 |
| 12 |
L |
870 |
580 |
1.5 |
1106 |
1218 |
15.4 |
50.6 |
19 |
45.0 |
Influence of Ni |
| 600 |
1.5 |
1001 |
1125 |
16.5 |
57.7 |
27.3 |
| 620 |
1.5 |
861 |
998 |
19.2 |
62.7 |
45.3 |
| 13 |
M |
870 |
580 |
7.85 |
976 |
993 |
14.8 |
60.7 |
Unachievable strength |
Influence of Mo |
| 600 |
7.85 |
874 |
936 |
17.1 |
63.4 |
| 620 |
7.85 |
741 |
897 |
21.1 |
69.5 |
| 14 |
N |
870 |
580 |
7.85 |
976 |
975 |
14.8 |
60.7 |
Unachievable strength |
Influence of V |
| 600 |
7.85 |
874 |
923 |
17.1 |
63.4 |
| 620 |
7.85 |
741 |
885 |
21.1 |
69.5 |
