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EP 1 663 809 B1 |
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EUROPEAN PATENT SPECIFICATION |
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Mention of the grant of the patent: |
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15.10.2008 Bulletin 2008/42 |
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Date of filing: 26.06.2003 |
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International Patent Classification (IPC):
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International application number: |
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PCT/EP2003/007798 |
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International publication number: |
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WO 2004/005156 (15.01.2004 Gazette 2004/03) |
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WATER SOLUBLE CONTAINER
WASSERLÖSLICHER BEHÄLTER
RECIPIENT SOLUBLE DANS L'EAU
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Designated Contracting States: |
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AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR |
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Priority: |
03.07.2002 EP 02254680
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Date of publication of application: |
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07.06.2006 Bulletin 2006/23 |
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Proprietor: Obrist Closures Switzerland GmbH |
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4153 Reinach (CH) |
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Inventors: |
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- RAMSAY, Christopher Paul
Wantage, Oxfordshire OX12 8DP (GB)
- GUGLIELMINI, Bernard
21800 Crimolois (FR)
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Representative: Greenwood, Matthew David et al |
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K.R. Bryer & Co.
7 Gay Street Bath BA1 2PH Bath BA1 2PH (GB) |
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References cited: :
EP-A- 0 593 952 WO-A-01/83668 DE-C- 809 896
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WO-A-01/36290 WO-A-03/016165 GB-A- 2 356 842
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| Note: Within nine months from the publication of the mention of the grant of the European
patent, any person may give notice to the European Patent Office of opposition to
the European patent
granted. Notice of opposition shall be filed in a written reasoned statement. It shall
not be deemed to
have been filed until the opposition fee has been paid. (Art. 99(1) European Patent
Convention).
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[0001] The present invention relates generally to a water-soluble container.
[0002] Water-soluble containers as such are well-known and have a variety of uses, such
as in clothes washing. For example,
CA 1112534 describes a water-soluble container for a detergent composition. The water-soluble
material may be, for example, polyvinyl alcohol (PVOH). This document describes a
single chamber with a film form wall of constant thickness. Because the chamber wall
is of constant thickness, the entire wall must be dissolved before any product can
escape. In certain circumstances product may be required quickly, before the time
when the entire container has dissolved.
WO 01/83668,
EP 593 952,
GB 2 356 842 and
WO 01/36290 all disclose prior art containers in accordance with the preamble of appended claim
1. According to the present invention there is provided a water-soluble container
comprising one ore more discrete chambers for containing product, wherein at least
part of a wall of the or at least one of the chamber/s is adapted to dissolve before
the remainder of the chamber to allow product to escape, characterised in that the
at least part of the wall adapted to dissolve before the remainder of each chamber
defines a panel and the at least part of the wall at least partly surrounds the panel,
such that when the at least part of the wall dissolves the panel is either partly
or completely released undissolved. This means that product can escape from a chamber
without requiring complete dissolution of the chamber. This can be useful for decreasing
the time taken for product to be released. It can also allow for a greater degree
of control over when product is released because the area required to be dissolved
is reduced.
[0003] A container according to the present invention for a system combining the advantage
of not requiring a whole chamber to dissolve before a product is released, together
with the possibility of sequential release of products. In its simplest form a chamber
provided with the means for allowing product to escape before complete dissolution
could be associated with a chamber not having those means. More complicated systems
could involve chambers which allow products to escape after different times before
complete dissolution.
[0004] The ability of such containers to provide for sequential release of multiple products
is extremely useful. For example, clothing washing usually includes a detergent stage
and a stage later in the washing cycle in which a softening agent is introduced. Dish-washing
sometimes includes a detergent stage and a separate rinsing stage. In many cases it
would be preferable and sometimes essential for different stages of washing operations
to be kept completely separate.
[0005] By providing for sequential release of products the present invention removes the
need for manual intervention at different stages of washing cycles and allows the
complete washing product to be packaged and supplied together.
[0006] The at least part of the wall will most usually be an exterior surface of the container
thereby releasing product from the container when it dissolves. However, it is also
possible that the at least part of the wall forms part of a chamber which is housed
within another chamber which itself includes water, whereby the contents of the chambers
are mixed when the at least part of the wall dissolves. This might be useful, for
example, if the product in the inner chamber is activated by product in the outer
chamber. This allows activation in a controlled environment before the activated product
is released into the exterior of the container and could be useful for products which
become unstable once activated.
[0007] There are many ways in which the container could be formed in order that product
is released from the chamber when the part of the wall dissolves.
[0008] The part of the wall may comprise one or more clip elements, such as a hook. The
clip elements initially clip the closure part to the container but then dissolve and
release the releasable panel. In this way only a small section of the wall dissolves
and yet a large opening can be provided quickly.
[0009] There are many ways in which the part of the wall could be formed in order that it
dissolves before the remainder of the container. For example, the at least part of
the wall could be made from a thinner section of material and/or from a different
material with a faster rate of dissolution than the remainder of the container.
[0010] In embodiments where the at least part of the wall is thinner than the remainder
of the container the material thinning may be arranged on the interior surface of
the chamber wall. This is particularly relevant when the at least part of the wall
defines a thin channel, because if the material thinning was arranged on the exterior
surface the channel could become saturated with dissolved material, which would impede
further dissolution.
[0011] In order to simplify production and allow for high volume production the container
may be formed by injection moulding. In embodiments where the at least part of the
wall is a thin section surrounding a panel, the area of the panel may form the gate
region for injection moulding. This ensures that the thin section is correctly moulded
by avoiding problems with moulded regions which are remote from the injection point.
[0012] As stated above, differential dissolution characteristics may be achieved by forming
the container from two or more different materials at least some of which are water-soluble.
It may, however, be preferable for simplification of the production process for the
whole of the container to be formed from the same material.
[0013] In some embodiments at least part of the material from which the container is formed
is a polyvinyl alcohol. Alternatively at least part of the material may be a polylactic
acid or a starch based material.
[0014] The container may be flexible. This may be as a result of the choice of material
and/or the thickness of the walls.
[0015] Where a container has several walls, the term "wall" can refer to any one or more
of the walls. A spherical container, for example, has a single wall whereas a cube
has six walls. The term is therefore generic and could refer to any part of the material
defining the chamber.
[0016] The present invention will now be more particularly described, by way of example,
with reference to the accompanying drawings, in which:
Fig 1 is a perspective view of a housing formed as part of a container according to
a first embodiment;
Fig 2 is a section along line II - II of Fig 1,
Fig 3 shows the housing of Fig 2 with a lid component attached;
Fig 4 shows the container of Fig 3 following an initial exposure to water;
Fig 5 is a section through a container according to an alternative arrangement not
covered by the appended claims; and
Fig 6 is a section of a container according to an alternative embodiment.
[0017] Referring first to Figs 1 and 2 there is shown a housing 10 of generally parallelepiped
shape comprising a base wall 11, side walls 12,13 and end walls 14,15. The housing
is hollow and is open opposite the base 11 to form a tray-like structure. The housing
10 is formed from a water-soluble material. The material could be, for example, a
grade of PVOH which dissolves at approximately 50°C. The interior of the housing 10
is divided into two discrete chambers 30, 31 by spaced parallel partition side walls
16, 17 which extend from end wall 15 and are joined at their ends by a partition end
wall 18. Each of the partition walls 16, 17, 18 extends the full height of the housing
walls 11, 12, 13, 14, 15. The portion of the base wall 14 which is bounded by the
partition walls 16, 17, 18 includes a panel 19 surrounded by a region of material
thinning 20 the purpose of which will be described in more detail below.
[0018] Referring now to Fig 3 the housing of Figs 1 and 2 is shown forming part of a container
1. The housing 10 is closed by a lid 25. The chambers 30, 31 are filled with different
products before the lid 25 is applied. The lid 25 includes a panel 26 and region of
material thinning 27 opposite and identical to those of the housing 10. The lid 25
may be secured to the housing 10 by any convenient means such as welding adhesion,
interference fit or clipping. In this embodiment the seal is a face seal bond which
is chemically activated, in this case by water, and supported internally by a wall
28 depending from the lid 25.
[0019] In this embodiment the thickness of the housing walls and the lid is approximately
0.4mm. This is about the thinnest that material can be without a risk of 'pin holes'
i.e. tiny holes in the material which could compromise the integrity of the chamber.
The material thinnings are approximately 0.15mm thick and are formed by reducing a
small part of the uniform thickness of the container.
[0020] In use, the container 1 is placed in an aqueous environment and the temperature is
raised beyond the dissolution temperature of the container material. As the container
1 begins to dissolve the material thinned regions 20, 27 will completely dissolve
before the remainder of the container. As a result, the panels 19, 26 are released
from the lid 25 and the base wall 14 such that product can escape from the chamber
31. Of course, the panels 19, 26 do not have to be completely released to be effective.
For example the material thinned regions 20, 27 could extend part way round the panels
19, 26 such that the panels 19, 26 become flaps which hinge open. Product from the
chamber cannot escape until the remainder of the container has dissolved.
[0021] Referring now to Fig 5 there is shown an alternative arrangement. In this arrangement
two discrete chambers 130, 131 are formed from two separate, hollow cube-shape housings
110a, 110b which are bonded together along adjacent side walls 112a, 112b. Each housing
110a, 110b is open along one side by closed by a lid 125a, 125b in this embodiment
sealed to the housings by adhesion. The lids 125a, 125b are formed from different
grades of PVOH which dissolve at different rates, with the material of the lid 125a
having the faster dissolution rate. In this embodiment therefore the lid 125a of the
housing 110a dissolves before the lid of housing 110b, to allow its product to escape
first.
[0022] Referring to Fig 6 there is shown a container 201 with a single chamber 230. A generally
cuboid housing 210 comprises a base wall 211 and side walls 214, 215. An open side
of the housing 210 is closed by a lid 225.
[0023] The lid 225 is held onto the housing 210 by a clip 220 extending from its periphery.
The clip 220 engages under a bead 235 formed around the open side of the housing 210.
[0024] The clip 220 is thinner than the remainder of the container 201. Accordingly, in
use of the container the clip 220 dissolves before the remainder of the container
so that the bead 235 no longer retains the lid 225, and therefore allows the lid 225
to be released from the housing 210.
1. A water-soluble container (1) comprising one ore more discrete chambers (30, 31) for
containing product, wherein at least part (20, 27) of a wall (11, 25) of the or at
least one of the chamber/s is adapted to dissolve before the remainder of the chamber
to allow product to escape,
characterised in that
the at least part (20, 27) of the wall (11, 25) adapted to dissolve before the remainder
of each chamber defines a panel (19, 26) and the at least part of the wall at least
partly surrounds the panel, such that when the at least part of the wall dissolves
the panel is either partly or completely released undissolved.
2. A container (201) according to Claim 1, wherein the at least part of the wall (225)
comprises one or more clip elements (220) adapted to retain the panel (225) until
dissolved.
3. A container (1) according to Claim 1 or Claim 2, wherein the at least part (20, 27)
of the wall is thinner than the remainder of the container.
4. A container (1) according to Claim 3, wherein the material thinning (20, 27) is arranged
on the interior surface of the chamber wall.
5. A container (1) according to any preceding claim, wherein the container is formed
by injection moulding.
6. A container (1) according to any preceding claim, wherein at least part of the material
from which the container is formed is a polyvinyl alcohol.
7. A container (1) according to any preceding claim, wherein at least part of the material
from which the container is formed is a polylactic acid.
8. A container (1) according to any preceding claim, wherein at least part of the material
from which the container is formed is starch-based.
9. A container (1) according to any preceding claim, wherein the whole of the container
is formed from the same material.
10. A container (1) according to any preceding claim, wherein the container is flexible.
11. A container according to any preceding claim, comprising two or more chambers, wherein
each chamber has a panel and the at least parts of the wall for each panel dissolve
at different rates so that the products contained in the chambers are allowed to escape
sequentially.
1. Wasserlöslicher Behälter (1) bestehend aus einer oder mehreren ein Produkt enthaltenden
eigenständigen Kammern (30, 31), wobei mindestens ein Teil (20, 27) einer Wand (11,
25) der Kammer/n so beschaffen ist, dass er sich vor dem Rest der Kammer auflöst,
damit das Produkt auslaufen kann,
dadurch gekennzeichnet, dass
mindestens ein Teil (20, 7) der Wand (11, 25) so ausgebildet ist, dass er sich auflöst,
bevor der Rest jeder Kammer eine Platte (19, 26) bildet und mindestens ein Teil der
Wand die Platte zumindest teilweise umgibt, sodass mindestens ein Teil der Platte
entweder teilweise oder ganz in ungelöster Form freigegeben wird, wenn sich mindestens
ein Teil der Wand auflöst.
2. Behälter (201) gemäß Anspruch 1, dadurch gekennzeichnet, dass mindestens ein Teil der Wand (225) ein oder mehrere Klemmelemente (220) aufweist,
die so eingerichtet sind, dass sie die Platte (22) bis zur Auflösung festhalten.
3. Behälter (1) gemäß Anspruch 1 oder 2, dadurch gekennzeichnet, dass mindestens ein Teil (20, 27) der Wand dünner ist als der Rest des Behälters.
4. Behälter (1) gemäß Anspruch 3, dadurch gekennzeichnet, dass die dünneren Stellen (20, 27) des Materials an der Innenfläche der Kammerwand angeordnet
sind.
5. Behälter (1) gemäß einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass der Behälter im Spritzgießverfahren geformt wird.
6. Behälter (1) gemäß einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass mindestens ein Teil des Materials, aus dem der Behälter geformt ist, Polyvinyllkohol
darstellt.
7. Behälter (1) gemäß einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass mindestens ein Teil des Materials, aus dem der Behälter geformt ist, eine Polyaktidsäure
darstellt.
8. Behälter (1) gemäß einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass mindestens ein Teil des Materials, aus dem der Behälter geformt ist, stärkebasiert
ist.
9. Behälter (1) gemäß einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass der gesamte Behälter aus demselben Material geformt ist.
10. Behälter (1) gemäß einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass der Behälter flexibel ist.
11. Behälter gemäß einem der vorhergehenden Ansprüche mit zwei oder mehreren Kammern,
dadurch gekennzeichnet, dass jede Kammer eine Platte aufweist und dass sich mindestens Teile der Wand jeder Platte
zu verschiedener Zeit auflösen, sodass die in den Kammern enthaltenen Produkte der
Reihe nach freigegeben werden können.
1. Récipient soluble dans l'eau (1) comprenant une ou plusieurs chambres discrètes (30,
31) pour contenir un produit, dans lequel au moins une portion (20, 27) d'une paroi
(11, 25) de la ou des chambre(s) ou d'une au moins parmi les chambres est apte à se
dissoudre avant le reste de la chambre pour permettre au produit de s'échapper,
caractérisé en ce que
la au moins une portion (20, 27) de la paroi (11, 25) apte à se dissoudre avant le
reste de chaque chambre définit un panneau (19, 26) et la au moins une portion de
la paroi entoure au moins partiellement le panneau, de sorte que le panneau soit partiellement
ou entièrement libéré sans être dissout lorsque la au moins une portion de la paroi
se dissout.
2. Récipient (201) selon la revendication 1, dans lequel la au moins une portion de la
paroi (225) comprend un ou plusieurs éléments d'agrafage (220) qui est apte à retenir
le panneau (225) jusqu'à dissolution.
3. Récipient (1) selon la revendication 1 ou la revendication 2, dans lequel la au moins
une portion de la paroi (20, 27) est plus mince que le reste du récipient.
4. Récipient (1) selon la revendication 3, dans lequel l'amincissement du matériau (20,
27) est situé sur la surface intérieure de la paroi de la chambre.
5. Récipient (1) selon l'une des revendications précédentes, dans lequel le récipient
est formé par moulage par injection.
6. Récipient (1) selon l'une des revendications précédentes, dans lequel au moins une
partie du matériau dans lequel le récipient est formé est un polyalcool de vinyle.
7. Récipient (1) selon l'une des revendications précédentes, dans lequel au moins une
partie du matériau dans lequel le récipient est formé est un acide polylactique.
8. Récipient (1) selon l'une des revendications précédentes, dans lequel au moins une
partie du matériau dans lequel le récipient est formé est amylacée.
9. Récipient (1) selon l'une des revendications précédentes, dans lequel l'intégralité
du récipient est formée avec le même matériau.
10. Récipient (1) selon l'une des revendications précédentes, dans lequel le récipient
est flexible.
11. Récipient selon l'une des revendications précédentes, comprenant deux chambres ou
davantage, dans lequel chaque chambre possède un panneau et les au moins une portion
de la paroi de chaque panneau se dissolvent selon différents taux, de sorte que les
produits contenus dans les chambres puissent s'échapper séquentiellement.
REFERENCES CITED IN THE DESCRIPTION
This list of references cited by the applicant is for the reader's convenience only.
It does not form part of the European patent document. Even though great care has
been taken in compiling the references, errors or omissions cannot be excluded and
the EPO disclaims all liability in this regard.
Patent documents cited in the description