[0001] The present invention relates to a vapour turbine which can be used for obtaining
energy from geothermal vapours.
[0002] Vapour turbines which operate with geothermal vapours come into contact with aggressive
and/or corrosive substances for the components of the turbine itself.
[0003] Even small quantities of aggressive substances such as chlorides and sulfides, cause
the corrosion of the vapour turbine components, such as rotor blades, stator blades
and sealing laminas.
[0004] The materials currently used for vapour turbine components are martensitic stainless
steels which are strongly subject to corrosion phenomena on the part of aggressive
and/or corrosive agents.
[0005] The corrosion is particularly high in the transition area between overheated vapour
and damp vapour (Dew Point).
[0006] In this area, the solid particles contained in the geothermal vapour form large deposits
on the surface of the blades.
[0007] During the functioning of the turbine, the deposits accelerate the corrosion process
under way, due to the increase in localized concentration of corrosive agents such
as chlorides and sulfides.
[0008] Corrosion of the turbine components jeopardizes the correct functionality of the
turbine itself as well as the preventive maintenance plan programmed for it.
[0009] In order to reduce maintenance interventions and consequently also substitution of
the components themselves, the geothermal vapours containing aggressive substances
in a higher quantity than a predetermined percentage, are "washed" with water.
[0010] This reduces the concentration of aggressive substances present in the geothermal
vapours.
[0011] A first disadvantage is that the washing operations of geothermal vapours causes
an increase in the running and maintenance costs of the piant, also increasing its
complexity.
[0012] Another disadvantage is that upon washing the vapour, the enthalpy available at the
turbine inlet is reduced and consequently the useful work of the turbine itself is
reduced.
[0013] An objective of the present invention is to provide a vapour turbine operating with
overheated geothermal vapours normally containing corrosive agents which avoids the
washing of said geothermal vapours.
[0014] A further objective is to provide a vapour turbine operating with overheated geothermal
vapours, which has a high conversion efficiency of the energy available at the inlet.
[0015] Another objective to provide a vapour turbine which operates with overheated geothermal
vapours and which has a high useful life.
[0016] Yet another objective to provide a vapour turbine operating with geothermal vapours,
containing corrosive agents, having reduced maintenance costs.
[0017] According to the invention, there is provided a vapour turbine operating with geothermal
vapours containing corrosive agents such as chlorides and/or sulfides in particular,
characterized in that it comprises a series of stator blades made of a nickel alloy
containing a quantity of nickel ranging from 54% to 58% by weight to avoid the washing
of said geothermal vapours, maintaining a high useful life of said series of stator
blades and said vapour turbine .
[0018] The nickel alloy may be a nickel-chromium-molybdenum alloy and may comprise a quantity
of chromium ranging from 21% to 23% by weight, a quantity of molybdenum ranging from
12% to 14.5% by weight.
[0019] The turbine may comprise a series of sealing laminas made of said nickel alloy to
avoid the washing of said geothermal vapours, maintaining a high useful life of said
series of sealing laminas and said vapour turbine.
[0020] The turbine may comprise a series of rotor blades made of a nickel-chromium-molybdenum-niobium
alloy to avoid the washing of said geothermal vapours, maintaining a high useful life
of said series of rotor blades and of said vapour turbine.
[0021] The nickel-chromium-molybdenum-niobium alloy preferably comprises a quantity of nickel
ranging from 55% to 59% by weight, a quantity of chromium ranging from 19% to 22.5%
by weight, a quantity of molybdenum ranging from 7.0% to 9.5% by weight, a quantity
of niobium ranging from 2.75% to 4% by weight.
[0022] The invention also includes the use of a series of stator blades made of a nickel-chromium-molybdenum
alloy for a vapour turbine operating with geothermal vapours containing corrosive
agents, such as chlorides and/or sulfides in particular, to avoid the washing of said
geothermal vapours, maintaining a high useful life of said series of stator blades.
[0023] The characteristics and advantages of a vapour turbine operating with geothermal
vapours will appear more evident from the following illustrative and non-limiting
description of the present invention.
[0024] According to the present invention, a vapour turbine is provided, operating with
geothermal vapours containing aggressive or corrosive agents such as chlorides and/or
sulfides in particular.
[0025] The vapour turbine comprises a series of stator blades made of a nickel alloy containing
a quantity of nickel ranging from 54% to 58% by weight to avoid the washing of said
geothermal vapours, at the same time maintaining a high useful life of said series
of stator blades and said vapour turbine.
[0026] It is advantageously possible to convert, by means of said turbine, a greater quantity
of energy as the non-washed geothermal vapours have a higher enthalpy with respect
to washed geothermal vapours.
[0027] Said turbine is advantageously particularly efficient for geothermal vapours containing
a quantity of chlorides higher than 2 ppm, avoiding the washing thereof.
[0028] Said nickel alloy is preferably a nickel-chromium-molybdenum alloy.
[0029] Said nickel alloy preferably comprises a quantity of chromium ranging from 21 % to
23% by weight, a quantity of molybdenum ranging from 12% to 14.5% by weight.
[0030] Said nickel alloy is preferably a super-alloy of nickel known commercially as HASTELLOY
C22.
[0031] Said turbine preferably also comprises a series of sealing laminas made of said nickel
alloy, in particular made of HASTELLOY C22.
[0032] This is to avoid the washing of said geothermal vapours, at the same time maintaining
a high useful life of said series of stator blades and sealing laminas and said vapour
turbine.
[0033] Said turbine preferably also comprises a series of rotor blades made of a nickel-chromium-molybdenum-niobium
alloy to avoid the washing of said geothermal vapours, at the same time maintaining
a high useful life of said series of rotor blades and the vapour turbine itself.
[0034] Said nickel-chromium-molybdenum-niobium alloy preferably comprises a quantity of
nickel ranging from 55% to 59% by weight, a quantity of chromium ranging from 19%
to 22.5% by weight, a quantity of molybdenum ranging from 7.0% to 9.5% by weight,
a quantity of niobium ranging from 2.75% to 4% by weight.
[0035] Said nickel-chromium-molybdenum-niobium alloy is preferably a nickel super-alloy,
commercially known as INCONEL 725.
[0036] According to a further aspect of the present invention, the use of a series of stator
blades made of a nickel-chromium-molybdenum alloy, in particular made of HASTELLOY
C22, for a vapour turbine operating with geothermal vapours containing corrosive agents,
such as chlorides and/or sulfides in particular, is evident, to avoid the washing
of said geothermal vapours, maintaining a high useful life of said series of stator
blades.
[0037] It can thus be seen that a vapour turbine according to the present invention achieves
the objectives specified above.
1. A vapour turbine operating with geothermal vapours containing corrosive agents such
as chlorides and/or sulfides in particular, characterized in that it comprises a series of stator blades made of a nickel alloy containing a quantity
of nickel ranging from 54% to 58% by weight to avoid the washing of said geothermal
vapours, maintaining a high useful life of said series of stator blades and said vapour
turbine .
2. The turbine according to claim 1, characterized in that said nickel alloy is a nickel-chromium-molybdenum alloy.
3. The turbine according to claim 1 or 2, characterized in that said nickel alloy comprises a quantity of chromium ranging from 21% to 23% by weight,
a quantity of molybdenum ranging from 12% to 14.5% by weight.
4. The turbine according to any of the claims from 1 to 3, characterized in that it comprises a series of sealing laminas made of said nickel alloy to avoid the washing
of said geothermal vapours, maintaining a high useful life of said series of sealing
laminas and said vapour turbine.
5. The turbine according to any of the claims from 1 to 4, characterized in that it comprises a series of rotor blades made of a nickel-chromium-molybdenum-niobium
alloy to avoid the washing of said geothermal vapours, maintaining a high useful life
of said series of rotor blades and of said vapour turbine.
6. The turbine according to claim 4, characterized in that said nickel-chromium-molybdenum-niobium alloy preferably comprises a quantity of
nickel ranging from 55% to 59% by weight, a quantity of chromium ranging from 19%
to 22.5% by weight, a quantity of molybdenum ranging from 7.0% to 9.5% by weight,
a quantity of niobium ranging from 2.75% to 4% by weight.
7. Use of a series of stator blades made of a nickel-chromium-molybdenum alloy for a
vapour turbine operating with geothermal vapours containing corrosive agents, such
as chlorides and/or sulfides in particular, to avoid the washing of said geothermal
vapours, maintaining a high useful life of said series of stator blades.