COMPOSITION FOR OPTICAL DISK-PROTECTING FILM

Description

FIELD OF THE INVENTION

[0001] The present invention relates to resin compositions for protective films, particularly resin compositions for protective films used as protective films for optical discs such as compact discs (CDs), digital versatile discs (DVDs), and the like.

BACKGROUND ART

[0002] Typically, optical discs of this type are provided with hard coatings on the surfaces of their exterior parts to protect the surfaces of the exterior parts against scratches.

[0003] Effective materials for such coatings are inorganic materials having high scratch resistance, but the inorganic materials have the disadvantage that coating solutions thereof are difficult to apply in a small thickness because of high viscosities.

[0004] For this reason, studies have been recently conducted to achieve coatings of small thickness by using low-viscosity UV-curable coating materials.

[0005] In order to ensure both scratch resistance and good coating geometry in such UV-curable coating materials, it is effective to use coating materials having low shrinkage and low viscosity, but low-shrinkage UV-curable hard coating materials have the disadvantage that solutions thereof has high-viscosity.

[0006] A conventional approach to solve this problem is to lower the viscosity of coating solutions by solvent dilution, but this approach increases the number of processes because the step of diffusing diluted solutions is required.

[0007] Another possible approach is to prepare a low-viscosity hard coating solution by using a diluent monomer, but this approach may decrease scratch resistance or increase cure shrinkage (warp).

[0008] Moreover, it is necessary to select materials allowing light transmission in a necessary wavelength range when hard coating materials of this type are to be used in light-transmitting parts of optical discs.

DISCLOSURE OF THE INVENTION

[0009] The present invention was made to solve such problems of the conventional techniques and aims to provide a composition for protective films, particularly a composition for protective films for optical discs having low viscosity and low shrinkage without compromising scratch resistance even when a dilution solvent is not used.

[0010] As a result of careful studies to achieve the above object, we accomplished the present invention on the basis of the finding that the viscosity and shrinkage of compositions for protective films can be lowered without compromising scratch resistance and desired light transmittance can be attained by curing acrylic monomers and acrylic oligomers having specific functional groups
with specific photoinitiators.

[0011] The present invention made on the basis of the above finding provides a composition for protective films containing a UV-curable acrylic radical-based resin as the main component, including: a multifunctional acrylic monomer, a multifunctional acrylic oligomer and a bifunctional acrylic monomer containing repeating units including at least one of an ethoxy and propoxy group as starting materials for the acrylic radical-based resin; and an appropriate photoinitiator, whereby the composition for protective films comprises 4 parts by weight or more and 10 parts by weight or less of the multifunctional acrylic monomer, 10 parts by weight or more and 36 parts by weight or less of the multifunctional acrylic oligomer and 60 parts by weight or more and 80 parts by weight or less of the bifunctional acrylic monomer in 100 parts by weight of the starting materials for the acrylic radical-based resin and further comprises 5 parts by weight or more and 10 parts by weight or less of the photoinitiator.

[0012] In the present invention, the multifunctional acrylic monomer may have a functionality of 4 or more and 6 or less in the invention disclosed above.

[0013] In the present invention, the multifunctional acrylic oligomer may have a functionality of 6 or more and 10 or less in the invention disclosed above.

[0014] In the present invention, the bifunctional acrylic monomer may contain 2-4 repeating units of an ethoxy group in the invention disclosed above.

[0015] In the present invention, the bifunctional acrylic monomer may contain 2-4 repeating units of a propoxy group in the invention disclosed above.

[0016] In the present invention, the photoinitiator may have a long wavelength absorption edge at less than 405 nm in the invention disclosed above.

[0017] In the present invention, the composition for protective films may have a viscosity of 20 mPa·s or more and less than 50 mPa·s in the invention disclosed above.

[0018] The present invention also provides a composition for protective films for optical discs comprising the composition for protective films disclosed above. The present invention also provides a protective film for optical discs obtained by curing the composition for protective films for optical discs disclosed above.

[0019] The present invention also provides an optical disc having the protective film for optical discs disclosed above on the surface of the readout side of the substrate.

[0020] According to the present invention, the viscosity and shrinkage of the composition for protective films can be lowered without compromising scratch resistance and warp resistance can also be improved because flexible cured products with high surface hardness can be obtained by using starting materials for a acrylic radical-based resin comprising a multifunctional acrylic monomer, a multifunctional acrylic oligomer and a bifunctional acrylic monomer containing repeating units including at least one of an ethoxy and propoxy group.

ADVANTAGES OF THE INVENTION

[0021] According to the present invention, compositions for protective films for optical discs having high scratch resistance and warp resistance as well as good coating geometry and high light transmittance can be provided.

BRIEF DESCRIPTION OF THE DRAWINGS

[0022] Figure 1 is a schematic diagram showing an example of an optical disc to which a composition for protective films for optical discs of the present invention has been applied.

[0023] Numerical references represent the following elements:

1: optical disc

2: substrate

5: protective film for optical disc

20: readout side.

THE MOST PREFERRED EMBODIMENTS OF THE INVENTION

[0024] The most preferred embodiments of compositions for protective films according to the present invention are explained in detail below.

[0025] The compositions for protective films (for optical discs) of the present invention are based on a UV-curable acrylic radical-based resin, and include a multifunctional acrylic monomer, a multifunctional acrylic oligomer and a bifunctional acrylic monomer containing repeating units including at least one of an ethoxy and propoxy group as starting materials for the acrylic radical-based resin, and an appropriate photoinitiator.

[0026] The multifunctional acrylic monomer here is utilized to improve scratch resistance and preferably has an acrylic functionality of 4 or more and 6 or less to ensure necessary scratch resistance.

[0027] Such multifunctional acrylic monomers include ethoxylated pentaerythritol tetraacrylate, pentaerythritol tetraacrylate, ditrimethylolpropane tetraacrylate (DTMPTA), and the like.

[0028] Among these, ethoxylated pentaerythritol tetraacrylate is preferably used to improve scratch resistance.

[0029] According to the present invention, the multifunctional acrylic monomer is contained in an amount of, but not specifically limited to, 4 parts by weight or more and 10 parts by weight or less in 100 parts by weight of the starting materials for the acrylic radical-based resin.

[0030] If the multifunctional acrylic monomer is contained in an amount of less than 4 parts by weight per 100 parts by weight of the starting materials for the acrylic radical-based resin, scratch resistance cannot be sufficiently ensured, and if it is greater than 10 parts by weight, warp resistance disadvantageously decreases.

[0031] The multifunctional acrylic oligomer is contained to improve scratch resistance and preferably has an acrylic functionality of 6 or more and 10 or less to ensure necessary scratch resistance.

[0032] Such multifunctional acrylic oligomers include, for example, aromatic urethane acrylate oligomers, aliphatic urethane acrylate oligomers, and the like.

[0033] According to the present invention, the multifunctional acrylic oligomer is contained in an amount of, but not specifically limited to, 10 parts by weight or more and 36 parts by weight or less in 100 parts by weight of the starting materials for the acrylic radical-based resin.

[0034] If the multifunctional acrylic oligomer is contained in an amount of less than 10 parts by weight per 100 parts by weight of the starting materials for the acrylic radical-based resin, scratch resistance cannot be sufficiently ensured, and if it is greater than 36 parts by weight, viscosity disadvantageously becomes excessively high.

[0035] The bifunctional acrylic monomer containing repeating units including at least one of an ethoxy and a propoxy group is contained to achieve low viscosity and low shrinkage without using a solvent while retaining scratch resistance.

[0036] From this viewpoint, a monomer containing 2-4 repeating units of an ethoxy group is preferably used.

[0037] From a similar viewpoint, a monomer containing 2-4 repeating units of a propoxy group is preferably used.

[0038] Such bifunctional acrylic monomers include, for example, dipropylene glycol diacrylate, tripropylene glycol diacrylate, tetrapropylene glycol diacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, tetraethylene glycol diacrylate, hexanediol diacrylate, and the like.

[0039] In an embodiment of the present invention, the type of the photoinitiator is not specifically limited, but it is preferable to use a photoinitiator having a long wavelength absorption edge (e.g., the absorption edge of the absorption spectrum of a 0.1 % photoinitiator - acetonitrile solution) at a wavelength shorter than the wavelength of the laser light used for optical discs in order to ensure light transmission when it is used for protective films for optical discs.

[0040] For example, photoinitiators having a long wavelength absorption edge at less than 780 nm, less than 650 nm and less than 405 nm can be suitably used for CDs, DVDs and next-generation optical discs, respectively.

[0041] Especially, photoinitiators that can be suitably used for next-generation optical discs include 1-hydroxy-cyclohexyl-phenyl-ketone, 2-methyl-1-[4-(methylthio)phenyl]-2-morpholinopropane-1-one, 2-hydroxy-2-methyl-1-phenyl-propane-1-one, and the like.

[0042] Among these, 1-hydroxy-cyclohexyl-phenyl-ketone is preferred because it efficiently transmits laser light at a wavelength of 405 nm.

[0043] According to the present invention, the photoinitiator is contained in an amount of, but not specifically limited to, 5 parts by weight or more and 10 parts by weight or less to ensure scratch resistance.

[0044] In an embodiment of the present invention, the viscosity of the compositions for protective films is not specifically limited, but preferably 20 mPa·s or more and less than 50 mPa·s to improve the coating geometry of coating solutions on substrate surfaces.

[0045] The compositions for protective films for optical discs of the present invention may further contain other components such as UV absorbents, surface tension modifiers, and the like.

[0046] Figure 1 is a schematic diagram showing an example of an optical disc to which a composition for protective films for optical discs of the present invention has been applied.

[0047] As shown in Figure 1, an optical disc 1 of the present invention has a conventional structure, including a recording pattern 2a, a reflective film 3 and a protective film 4 formed on a disc-shaped substrate 2 made from a polycarbonate.

[0048] In an embodiment of the present invention, a protective film 5 for optical disc, obtained by curing a composition for protective films for optical discs as described above, is further provided on the readout side 20 of the substrate 2.

[0049] In an embodiment of the present invention, the thickness of the protective film 5 for optical disc is not specifically limited, but is preferably 3-6 µm to ensure scratch resistance and light transmission.

[0050] Embodiments of the present invention can be employed as compositions, not only for protective films for optical discs, but also for various protective films. However, they are most effectively when employed as compositions for protective films for optical components such as optical discs as described above.

EXAMPLES

[0051] Examples of the present invention are explained in detail below along with Comparative Examples.

<Example 1>

[0052] To a mixed solution of 4.5 parts by weight of a multifunctional acrylic monomer composed of ethoxylated pentaerythritol tetraacrylate (sold under the name "EB40" from Daicel UCB Co., Ltd.), 13. 5 parts by weight of a multifunctional acrylic oligomer composed of a hexafunctional aromatic urethane acrylate oligomer (sold under the name "CN975" from Kayaku Sartomer Co., Ltd.) and 72 parts by weight of a bifunctional acrylic monomer composed of triethylene glycol diacrylate (sold under the name "SR272" from Kayaku Sartomer Co. , Ltd.) was added 10 parts by weight of a photoinitiator composed of 1-hydroxy-cyclohexyl-phenyl-ketone (sold under the name "Irgacure 184" from Ciba Specialty Chemicals K. K.) as shown in Table 1 to prepare a coating solution.

<Example 1a>

[0053] A coating solution was prepared in the same manner as in Example 1 except that the amount of the multifunctional acrylic monomer was changed to 10 parts by weight.

<Example 1b>

[0054] A coating solution was prepared in the same manner as in Example 1 except that the amount of the multifunctional acrylic oligomer was changed to 30 parts by weight.

<Example 1c>

[0055] A coating solution was prepared in the same manner as in Example 1 except that the amount of the bifunctional acrylic monomer was changed to 60 parts by weight.

<Example 1d>

[0056] A coating solution was prepared in the same manner as in Example 1 except that the amount of the photoinitiator was changed to 5 parts by weight.

<Comparative Example 1a>

[0057] A coating solution was prepared in the same manner as in Example 1 except that the amount of the multifunctional acrylic monomer was changed to 15 parts by weight.

<Comparative Example 1b>

[0058] A coating solution was prepared in the same manner as in Example 1 except that the amount of the multifunctional acrylic oligomer was changed to 40 parts by weight.

<Comparative Example 1c>

[0059] A coating solution was prepared in the same manner as in Example 1 except that the amount of the bifunctional acrylic monomer was changed to 85 parts by weight.

<Comparative Example 1d>

[0060] A coating solution was prepared in the same manner as in Example 1 except that the amount of the photoinitiator was changed to 3 parts by weight.

<Example 2>

[0061] A coating solution was prepared in the same manner as in Example 1 except that 13.5 parts by weight of a hexafunctional aliphatic urethane acrylate oligomer (sold under the name "CN968" from Kayaku Sartomer Co. , Ltd.) was added as a multifunctional acrylic oligomer.

<Example 3>

[0062] A coating solution was prepared in the same manner as in Example 1 except that 13.5 parts by weight of another hexafunctional aromatic urethane acrylate oligomer (sold under the name "CN999" from Kayaku Sartomer Co. , Ltd.) was added as a multifunctional acrylic oligomer.

<Comparative Example 2>

[0063] A coating solution was prepared in the same manner as in Example 1 except that 13.5 parts by weight of a bifunctional aromatic urethane acrylate oligomer (sold under the name "CN973" from Kayaku Sartomer Co., Ltd.) was added as a multifunctional acrylic oligomer.

<Comparative Example 3>

[0064] A coating solution was prepared in the same manner as in Example 1 except that 13.5 parts by weight of a Bis-A epoxy acrylate oligomer (sold under the name "EB3700" from Daicel UCB Co., Ltd.) was added as a multifunctional acrylic oligomer.

<Example 4>

[0065] A coating solution was prepared in the same manner as in Example 1 except that 4.5 parts by weight of ditrimethylolpropane tetraacrylate (sold under the name "M-408" from Toagosei Co. , Ltd.) was added as a multifunctional acrylic monomer.

<Example 5>

[0066] A coating solution was prepared in the same manner as in Example 1 except that 4.5 parts by weight of pentaerythritol tetraacrylate (sold under the name "M-450" from Toagosei Co., Ltd.) was added as a multifunctional acrylic monomer.

<Example 6>

[0067] A coating solution was prepared in the same manner as in Example 1 except that 72 parts by weight of dipropylene glycol diacrylate (sold under the name "Laromer DPGDA" from BASF Corporation) was added as a bifunctional acrylic monomer.

<Example 7>

[0068] A coating solution was prepared in the same manner as in Example 1 except that 72 parts by weight of tripropylene glycol diacrylate (sold under the name "Laromer TPGDA" from BASF Corporation) was added as a bifunctional acrylic monomer.

<Example 8>

[0069] A coating solution was prepared in the same manner as in Example 1 except that 72 parts by weight of tetrapropylene glycol diacrylate (sold under the name "Blemmer ADP-200" from NOF Corporation) was added as a bifunctional acrylic monomer.

<Comparative Example 4>

[0070] A coating solution was prepared in the same manner as in Example 1 except that 72 parts by weight of heptapropylene glycol diacrylate (sold under the name "Blemmer ADP-400" from NOF Corporation) was added as a bifunctional acrylic monomer.

<Example 9>

[0071] A coating solution was prepared in the same manner as in Example 1 except that 72 parts by weight of diethylene glycol diacrylate (sold under the name "SR230" from Kayaku Sartomer Co., Ltd.) was added as a bifunctional acrylic monomer.

<Example 10>

[0072] A coating solution was prepared in the same manner as in Example 1 except that 72 parts by weight of tetraethylene glycol diacrylate (sold under the name "Blemmer ADE-200" from NOF Corporation) was added as a bifunctional acrylic monomer.

<Comparative Example 5>

[0073] A coating solution was prepared in the same manner as in Example 1 except that 72 parts by weight of trimethylolpropane triacrylate (sold under the name "Alonix M-350" from Toagosei Co., Ltd.) was added as a bifunctional acrylic monomer.

<Comparative Example 6>

[0074] A coating solution was prepared in the same manner as in Example 1 except that 72 parts by weight of neopentyl glycol diacrylate (sold under the name "Light Acrylate NP-A" from Kyoeisha Chemical Co., Ltd.) was added as a bifunctional acrylic monomer.

<Example 11>

[0075] A coating solution was prepared in the same manner as in Example 1 except that 72 parts by weight of hexanediol diacrylate (sold under the name "Laromer HDDA" from BASF Corporation) was added as a bifunctional acrylic monomer.

<Example 12>

[0076] A coating solution was prepared in the same manner as in Example 1 except that 10 parts by weight of 2-methyl-1-[4-(methylthio)phenyl]-2-morpholinopropane-1-one (sold under the name "Irgacure 907" from Ciba Specialty Chemicals) was added as a photoinitiator.

<Example 13>

[0077] A coating solution was prepared in the same manner as in Example 1 except that 10 parts by weight of 2-hydroxy-2-methyl-1-phenyl-propane-1-one (sold under the name "Darocure 1173" from Ciba Specialty Chemicals K.K.) was added as a photoinitiator.

<Comparative Example 7>

[0078] A coating solution was prepared in the same manner as in Example 1 except that 10 parts by weight of 2-benzyl-2-dimethylamino-1-(4-morpholinophenyl)-butanone-1 (sold under the name "Irgacure 369" from Ciba Specialty Chemicals K.K.) was added as a photoinitiator.

[Evaluation]

[0079] Evaluation items and results of the Examples and Comparative Examples are explained in detail below.

[Viscosity]

[0080] The average viscosity of each of the coating solutions of the Examples and Comparative Examples prepared by the methods described above was determined by a cone and plate viscometer. The results are shown in Tables 2 and 3.

[0081] Here, coating solutions having a viscosity of less than 50 mPa·s were evaluated as "o" and those having a viscosity of 50 mPa· s or more were evaluated as "×".

[Scratch resistance]

[0082] Each of the coating solutions of the Examples and Comparative Eexamples was applied on a low molecular weight polycarbonate substrate formed by injection molding into a thickness of 3 µm after drying.

[0083] This coating film was irradiated with UV rays at an integrated dose of 1000 mJ/cm using a high-pressure mercury lamp (120 W/cm).

[0084] Thus cured film was evaluated for scratch resistance. The results are shown in Tables 2 and 3.

[0085] Here, a Taber Abrasion Tester (CS-10F abrading wheels, load 250 g, 100 revolutions) was used to evaluate samples having a Δ haze value of less than 10 % after testing as "○" and samples having a Δ haze value of 10% or more after testing as "×".

[Warp resistance]

[0086] Each of the coating solutions of the Examples and Comparative Examples was applied on the low molecular weight polycarbonate substrate described above into a thickness of 3 µm after drying.

[0087] The warp angle was determined by measuring the variation in tilt (radial skew) of each substrate using an in-house warp angle meter provided with a laser displacement sensor to evaluate warp resistance.

[0088] Here, samples were evaluated as "o" or "x" according to whether the absolute value of the variation in tilt induced by the application of the coating solution is less than 0.1 degree or 0.1 degree or more. The results are shown in Tables 2 and 3.

[Light transmittance]

[0089] Each of the coating solutions of the Examples and Comparative Examples was applied on a transparent substrate of quartz glass, and this coating film was irradiated with the UV rays as described above to give a cured film having a thickness of 3 µm.

[0090] The light transmittance of the cured film was evaluated by a UV/visible spectrophotometer. The results are shown in Tables 2 and 3.

Table 1. Material used in the compositions of the Examples and Comparative Examples

	Proprietary name (manufacturer)	Chemical name
Multifuctional acrylic monomer	EB40 (Daicel UCB Co., Ltd.)	Ethoxylated pentaerythritol tetraacrylate
	M-408 (Toagosei Co., Ltd.)	Ditrimethylolpropane tetraacrylate
	M-450 (Toagosei Co., Ltd.)	Pentaerythritol tetraacrylate
Multifuctional acrylic oligomer	CN975 (Kayaku Sartomer Co., Ltd.)	Aromatic urethane acrylate oligomer, hexafunctional
	CN968 (Kayaku Sartomer Co., Ltd.)	Aliphatic urethane acrylate oligomer, hexafunctional
	CN999 (Kayaku Sartomer Co., Ltd.)	Aromatic urethane acrylate oligomer, hexafunctional
	CN973 (Kayaku Sartomer Co., Ltd.)	Aromatic urethane acrylate oligomer, bifunctional
	EB3700 (Daicel UCB Co., Ltd.)	Epoxy acrylate oligomer, bifunctional
Bifunctional acrylic monomer	Laromer DPGDA (BASF Corporation)	Dipropylene glycol diacrylate
	Laromer TPGDA (BASF Corporation)	Tripropylene glycol diacrylate
	Blemmer ADP-200 (N0F Corporation)	Tetrapropylene glycol diacrylate
	Blemner ADP-400 (N0F Corporation)	Heptapropylene glycol diacrylate
	SR230 (Kayaku Sartomer Co., Ltd.)	Diethylene glycol diacrylate
	SR272 (Kayaku Sartomer Co., Ltd.)	Triethylene glycol diacrylate
	Blemmer ADE-200 (N0F Corporation)	Tetraethylene glycol diacrylate
	Alonix M-350 (Toagosei Co., Ltd.)	Trimethylolpropane triacrylate
	Light Acrylate NP-A (Kyoeisha Chemicals Co., Ltd.)	Neopentyl glrcol diacrylate
	Laromer HDDA (BASF Corporation)	Hexanediol diacrylate
Photoinitiator	Irgacure 184 (Ciba Specialty Chemicals K.K.)	1-Hydroxy-cyclohexyl-phenyl-ketone
	Irgacure 907 (Ciba Specialty Chemical K.K.)	2-Methyl-1-[4-(methylthio)phenyl]-2-morpholinopropane-1-one
	Darocure 1173 (Ciba Specialty Chemicals K.K.)	2-Hydroxy-2-methyl-1-phenyl-propane-1-one
	Irgacure 369 (Ciba Specialty Chemicals K.K.)	2-Benzyl-2-dimethylamino-1-(4-morpholinophenyl)-butanone-1

Table 2. Evaluation results of the Examples and Comparative Examples

	Proprietary name	Ex. 1	Ex. 2	Ex. 3	C.E. 2	C.E. 3	Ex. 4	Ex. 5	Ex. 6	Ex. 7	Ex. 8	C.E. 4	Ex. 9	Ex. 10	C.E. 5	C.E. 6	Ex. 11	Ex. 12	Ex. 13	C.E. 7
Multifuctional acrylic monomer	EB 40	45	45	45	45	45	-	-	45	45	45	45	45	45	45	45	45	45	45	45
	M-408	-	-	-	-	-	45	-	-	-	-	-	-	-	-	-	-	-	-	-
	M-450	-	-	-	-	-	-	45	-	-	-	-	-	-	-	-	-	-	-	-
Multifuctional acrylic oligomer	CN975	135	-	-	-	-	135	135	135	135	135	135	135	135	135	135	135	135	135	135
	CN968	-	135	-	-	-	-	-	-	-	-	-	-	-	-	-	-	-	-	-
	CN999	-	-	135	-	-	-	-	-	-	-	-	-	-	-	-	-	-	-	-
	CN973	-	-	-	135	-	-	-	-	-	-	-	-	-	-	-	-	-	-	-
	EB3700	-	-	-	-	135	-	-	-	-	-	-	-	-	-	-	-	-	-	-
Bifunctional acrylic monomer	Laromer DPGDA	-	-	-	-	-	-	-	72	-	-	-	-	-	-	-	-	-	-	-
	Laromer TPGDA	-	-	-	-	-	-	-	-	72	-	-	-	-	-	-	-	-	-	-
	Blemmer ADP-200	-	-	-	-	-	-	-	-	-	72	-	-	-	-	-	-	-	-	-
	Blemmer ADP-400	-	-	-	-	-	-	-	-	-	-	72	-	-	-	-	-	-	-	-
	SR230	-	-	-	-	-	-	-	-	-	-	-	72	-	-	-	-	-	-	-
	SR272	72	72	T2	72	72	72	72	-	-	-	-	-	-	-	-	-	72	72	72
	Blemmer ADE-200	-	-	-	-	-	-	-	-	-	-	-	-	72	-	-	-	-	-	-
	Alonix M-350	-	-	-	-	-	-	-	-	-	-	-	-	-	72	-	-	-	-	-
	Light Acrylate NP-A	-	-	-	-	-	-	-	-	-	-	-	-	-	-	72	-	-	-	-
	Laromer HDDA	-	-	-	-	-	-	-	-	-	-	-	-	-	-	-	72	-	-	-
Photoinitiator	Irgacure 184	10	10	10	10	10	10	10	10	10	10	10	10	10	10	10	10	-	-	-
	Irgacure 907	-	-	-	-	-	-	-	-	-	-	-	-	-	-	-	-	10	-	-
	Darocure 1173	-	-	-	-	-	-	-	-	-	-	-	-	-	-	-	-	-	10	-
	Irgacure 369	-	-	-	-	-	-	-	-	-	-	-	-	-	-	-	-	-	-	10
Evaluation results	Scratch resistance	○	○	○	×	×	○	○	○	○	○	×	○	○	○	×	○	○	○	○
	Warp resistance	○	○	○	○	○	○	○	○	○	○	○	○	○	○	×	○	○	○	○
	Viscosity	○	○	○	○	○	○	○	○	○	○	○	○	○	×	○	○	○	○	○
	Light trasmittance	○	○	○	○	○	○	○	○	○	○	○	○	○	○	○	○	○	○	×

(Note) The figures in the table are expressed in parts by weight.

Table 3. Evaluation results of the Examples and Comparative Examples

	Proprietary name	Ex.1a	Ex.1b	Ex.1c	Ex.1d	C.E.1a	C.E.1b	C.E.1c	C.E.1d
Multifuctional acrylic monomer	EB 40	10	45	45	45	15	45	45	4.5
	M-408	-	-	-	-	-	-	-	-
	M-450	-	-	-	-	-	-	-	-
Multifuctional acrylic oligomer	CN975	135	30	135	13.5	135	40	135	13.5
	CN968	-	-	-	-	-	-	-	-
	CN999	-	-	-	-	-	-	-	-
	CN973	-	-	-	-	-	-	-	-
	EB3700	-	-	-	-	-	-	-	-
Bifunctional acrylic monomer	Laromer DPGDA	-	-	-	-	-	-	-	-
	Laromer TPGDA	-	-	-	-	-	-	-	-
	Blemmer ADP-200	-	-	-	-	-	-	-	-
	Blemmer ADP-400	-	-	-	-	-	-	-	-
	SR230	-	-	-	-	-	-	-	-
	SR272	72	72	60	72	72	72	85	72
	Blemmer ADE-200	-	-	-	-	-	-	-	-
	Alonix M-350	-	-	-	-	-	-	-	-
	Light Acrylate NP-A	-	-	-	-	-	-	-	-
	Laromer HDDA	-	-	-	-	-	-	-	-
Photoinitiator Photo Initiator	Irgacure 184	10	10	10	5	10	10	10	3
	Irgacure 907	-	-	-	-	-	-	-	-
	Darocure 1173	-	-	-	-	-	-	-	-
	Irgacure 369	-	-	-	-	-	-	-	-
Evaluation results	Scratch resistance	○	○	○	○	○	○	×	×
	Warp resistance	○	○	○	○	×	○	○	○
	Viscosity	○	○	○	○	○	×	○	○
	Light trasmittance	○	○	○	○	○	○	○	○

(Note) The figures in the table are expressed in parts by weight.

[0091] As shown in Tables 2 and 3, the viscosities of the coating solutions of Examples 1 to 13 were sufficiently low, i.e. less than 50 mPa·s.

[0092] The films after curing were good in both scratch resistance and warp resistance and had a light transmittance of 90 % or more, showing that they are well suited as protective films for optical discs.

[0093] However, the film of Comparative Example 1a containing 15 parts by weight of the multifunctional acrylic monomer was poor in warp resistance.

[0094] Comparative Example 1b containing 40 parts by weight of the multifunctional acrylic oligomer was defective in coating geometry because the viscosity of the coating solution exceeded 50 mPa·s.

[0095] Both of Comparative Example 1c containing 85 parts by weight of the bifunctional acrylic monomer and Comparative Example 1d containing 3 parts by weight of the photoinitiator were poor in scratch resistance.

[0096] The films of Comparative Examples 2 and 3 using bifunctional acrylic oligomers as multifunctional acrylic oligomers were poor in scratch resistance.

[0097] The film of Comparative Example 4 using a monomer containing seven repeating units of a propoxy group as a bifunctional acrylic monomer was poor in scratch resistance.

[0098] Comparative Example 5 using trimethylolpropane triacrylate as a bifunctional acrylic monomer was defective in coating geometry because the viscosity of the coating solution exceeded 50 mPa·s.

[0099] The film of Comparative Example 6 using neopentyl glycol diacrylate as a bifunctional acrylic monomer was poor in scratch resistance and warp resistance.

[0100] The film of Comparative Example 7 using 2-benzyl-2-dimethylamino-1-(4-morpholinophenyl)-butanone-1 as a photoinitiator was found to be unsuitable as a protective film for optical discs because the light transmittance was less than 90 %.

INDUSTRIAL APPLICABILITY

[0101] The resin compositions for protective films of the present invention can be used for protective films for optical discs such as compact discs (CDs), digital versatile discs (DVDs), next generation optical discs, and the like.

Claims

1. A composition for protective films containing a UV-curable acrylic radical-based resin as a main component, comprising:

a multifunctional acrylic monomer, a multifunctional acrylic oligomer and a bifunctional acrylic monomer containing repeating units including at least one of an ethoxy and a propoxy group as starting materials for the acrylic radical-based resin; and

an appropriate photoinitiator,

whereby

the composition for protective films comprises 4 parts by weight or more and 10 parts by weight or less of the multifunctional acrylic monomer, 10 parts by weight or more and 36 parts by weight or less of the multifunctional acrylic oligomer and 60 parts by weight or more and 80 parts by weight or less of the bifunctional acrylic monomer in 100 parts by weight of the starting materials for the acrylic radical-based resin and further comprises 5 parts by weight or more and 10 parts by weight or less of the photoinitiator.

2. The composition for protective films of claim 1 wherein the multifunctional acrylic monomer has a functionality of 4 or more and 6 or less.

3. The composition for protective films of claim 1 wherein the multifunctional acrylic oligomer has a functionality of 6 or more and 10 or less.

4. The composition for protective films of claim 1 wherein the bifunctional acrylic monomer contains 2 to 4 repeating units of an ethoxy group.

5. The composition for protective films of claim 1 wherein the bifunctional acrylic monomer contains 2 to 4 repeating units of a propoxy group.

6. The composition for protective films of claim 1 wherein the photoinitiator has a long wavelength absorption edge at less than 405 nm.

7. The composition for protective films of claim 1 having a viscosity of 20 mPa·s or more and less than 50 mPa·s.

8. A protective film for optical discs obtained by curing a composition for protective films for optical discs comprising a resin based composition containing a UV-curable acrylic radical-based resin as a main component, including a multifunctional acrylic monomer, a multifunctional acrylic oligomer and a bifunctional acrylic monomer containing repeating units including at least one of an ethoxy and a propoxy group as starting materials for the acrylic radical-based resin; and an appropriate photoinitiator, whereby
the resin based composition comprises 4 parts by weight or more and 10 parts by weight or less of the multifunctional acrylic monomer, 10 parts by weight or more and 36 parts by weight or less of the multifunctional acrylic oligomer and 60 parts by weight or more and 80 parts by weight or less of the bifunctional acrylic monomer in 100 parts by weight of the starting materials for the acrylic radical-based resin and further comprises 5 parts by weight or more and 10 parts by weight or less of the photoinitiator.

9. An optical disc having a protective film for the optical disc provided on a surface of a readout side of a substrate, wherein the protective film is obtained by curing a composition for protective films for optical discs comprising a resin based composition containing a UV-curable acrylic radical-based resin as a main component including a multifunctional acrylic monomer, a multifunctional acrylic oligomer and a bifunctional acrylic monomer containing repeating units including at least one of an ethoxy and a propoxy group as starting materials for the acrylic radical-based resin; and an appropriate photoinitiator,
whereby
the resin based composition comprises 4 parts by weight or more and 10 parts by weight or less of the multifunctional acrylic monomer, 10 parts by weight or more and 36 parts by weight or less of the multifunctional acrylic oligomer and 60 parts by weight or more and 80 parts by weight or less of the bifunctional acrylic monomer in 100 parts by weight of the starting materials for the acrylic radical-based resin and further comprises 5 parts by weight or more and 10 parts by weight or less of the photoinitiator.

Ansprüche

1. Zusammensetzung für Schutzüberzüge, die ein UV-aushärtbares Acrylradikal-basiertes Harz als eine Hauptkomponente enthalten, umfassend:

ein multifunktionales Acryl-Monomer, ein multifunktionales Acryl-Oligomer und ein bifunktionales Acryl-Monomer, welches sich wiederholende Einheiten enthält, die zumindest eine Gruppe aus einer Ethoxy- und einer Propoxygruppe als Ausgangsmaterialien für das Acrylradikal-basierte Harz enthalten;

und einen geeigneten Fotoinitiator,

wobei die Zusammensetzung für die Schutzüberzüge 4 Gewichtsanteile oder mehr und 10 Gewichtsanteile oder weniger des multifunktionalen Acryl-Monomers, 10 Gewichtsanteile oder mehr und 36 Gewichtsanteile oder weniger des multifunktionalen Acryl-Oligomers und 60 Gewichtsanteile oder mehr und 80 Gewichtsanteile oder weniger des bifunktionalen Acryl-Monomers in 100 Gewichtsanteilen der Ausgangsmaterialien für das Acrylradikal-basierte Harz und ferner 5 Gewichtsanteile oder mehr und 10 Gewichtsanteile oder weniger des Fotoinitiators aufweist.

2. Zusammensetzung für Schutzüberzüge nach Anspruch 1, wobei das
multifunktionale Acryl-Monomer eine Funktionalität von 4 oder mehr und 6 oder weniger aufweist.

3. Zusammensetzung für Schutzüberzüge nach Anspruch 1, wobei das multifunktionale Acryl-Oligomer eine Funktionalität von 6 oder mehr und 10 oder weniger aufweist.

4. Zusammensetzung für Schutzüberzüge nach Anspruch 1, wobei das bifunktionale Acryl-Monomer 2 bis 4 sich wiederholende Einheiten einer Ethoxygruppe aufweist.

5. Zusammensetzung für Schutzüberzüge nach Anspruch 1, wobei das bifunktionale Acryl-Monomer 2 bis 4 sich wiederholende Einheiten einer Propoxygruppe aufweist.

6. Zusammensetzung für Schutzüberzüge nach Anspruch 1, wobei der Fotoinitiator eine langwellige Absorptionsgrenze bzw. -kante von weniger als 405nm aufweist.

7. Zusammensetzung für Schutzüberzüge nach Anspruch 1, die eine Viskosität von 20mPa·s oder mehr und weniger als 50mPa·s aufweist.

8. Schutzüberzug für optische Disks, der durch Aushärten einer Zusammensetzung für Schutzüberzüge für optische Disks erhalten wird, umfassend
eine Harz-basierte Zusammensetzung, die ein UV-aushärtbares Acrylradikal-basiertes Harz als eine Hauptkomponente enthält, welches ein multifunktionales Acryl-Monomer, ein multifunktionales Acryl-Oligomer und ein bifunktionales Acryl-Monomer enthält, das sich wiederholende Einheiten aufweist, die zumindest eine Gruppe aus einer Ethoxy- und einer Propoxygruppe als Ausgangsmaterialien für das Acrylradikal-basierte Harz enthalten; und einen geeigneten Fotoinitiator,
wobei die Harz-basierte Zusammensetzung 4 Gewichtsanteile oder mehr und 10 Gewichtsanteile oder weniger des multifunktionalen Acryl-Monomers, 10 Gewichtsanteile oder mehr und 36 Gewichtsanteile oder weniger des multifunktionalen Acryl-Oligomers und 60 Gewichtsanteile oder mehr und 80 Gewichtsanteile oder weniger des bifunktionalen Acryl-Monomers in 100 Gewichtsanteilen der Ausgangsmaterialien für das Acrylradikal-basierte Harz und ferner 5 Gewichtsanteile oder mehr und 10 Gewichtsanteile oder weniger des Fotoinitiators aufweist.

9. Optische Disk mit einem Schutzüberzug für die optische Disk, der auf einer Oberfläche einer Leseseite eines Substrats vorgesehen ist,
wobei der Schutzüberzug durch Aushärten einer Zusammensetzung für Schutzüberzüge für optische Disks erhalten wird, umfassend
eine Harz-basierte Zusammensetzung, die ein UV-aushärtbares Acrylradikal-basiertes Harz als eine Hauptkomponente aufweist, welche ein multifunktionales Acryl-Monomer, ein multifunktionales Acryl-Oligomer und ein bifunktionales Acryl-Monomer enthält, das sich wiederholende Einheiten aufweist, die zumindest eine Gruppe aus einer Ethoxy- und einer Propoxygruppe als Ausgangsmaterialien für das Acrylradikal-basierte Harz enthalten; und einen geeigneten Fotoinitiator,
wobei die Harz-basierte Zusammensetzung 4 Gewichtsanteile oder mehr und 10 Gewichtsanteile oder weniger des multifunktionalen Acryl-Monomers, 10 Gewichtsanteile oder mehr und 36 Gewichtsanteile oder weniger des multifunktionalen Acryl-Oligomers und 60 Gewichtsanteile oder mehr und 80 Gewichtsanteile oder weniger des bifunktionalen Acryl-Monomers in 100 Gewichtsanteilen der Ausgangsmaterialien für das Acrylradikal-basierte Harz und ferner 5 Gewichtsanteile oder mehr und 10 Gewichtsanteile oder weniger des Fotoinitiators enthält.

Revendications

1. Composition pour des films de protection contenant une résine à base de radical acrylique durcissable par UV comme composant principal, comprenant:

un monomère acrylique multi-fonctionnel, un oligomère acrylique multi-fonctionnel et un monomère acrylique bifonctionnel contenant des unités de répétition incluant au moins un d'un groupe éthoxy et propoxy comme matériau de départ pour la résine à base de radical acrylique; et

un photoinitiateur approprié,

par quoi

la composition pour les films de protection comprend 4 parties en poids ou plus et 10 parties en poids ou moins du monomère acrylique multifonctionnel, 10 parties en poids ou plus et 36 parties en poids ou moins de l'oligomère acrylique multifonctionnel et 60 parties en poids ou plus et 80 parties en poids ou moins du monomère acrylique bifonctionnel pour 100 parties en poids des matériaux de départ pour la résine à base de radical acrylique, et comprend en outre 5 parties en poids ou plus et 10 parties en poids ou moins du photoinitiateur.

2. Composition pour des films de protection selon la revendication 1, dans laquelle le monomère acrylique multifonctionnel possède une fonctionnalité de 4 ou plus et de 6 ou moins.

3. Composition pour des films de protection selon la revendication 1, dans laquelle l'oligomère acrylique multifonctionnel a une fonctionnalité de 6 ou plus et de 10 ou moins.

4. Composition pour des films de protection selon la revendication 1, dans laquelle le monomère acrylique bifonctionnel contient 2 à 4 unités de répétition d'un groupe éthoxy.

5. Composition pour des films de protection selon la revendication 1, dans laquelle le monomère acrylique bifonctionnel contient 2 à 4 unités de répétition d'un groupe propoxy.

6. Composition pour des films de protection selon la revendication 1, dans laquelle le photoinitiateur présente une arête d'absorption de longueur d'onde longue inférieure à 405 nm.

7. Composition pour des films de protection selon la revendication 1, ayant une viscosité de 20 mPa.s ou plus et moins que 50 mPa.s.

8. Film de protection pour des disques optiques obtenus en durcissant une composition pour des films optique pour des disques optiques comprenant une composition à base de résine contenant une résine à base de radical acrylique durcissable par UV comme composant principal, incluant un monomère acrylique multifonctionnel, un oligomère acrylique multifonctionnel et un monomère acrylique bifonctionnel contenant des unités de répétition incluant au moins un d'un, groupe éthoxy et propoxy comme matériaux de départ pour la résine à base de radical acrylique; et un photoinitiateur approprié, par quoi
la composition à base de résine comprend 4 parties en poids ou plus et 10 parties en poids ou moins du monomère acrylique multifonctionnel, 10 parties en poids ou plus et 36 parties en poids ou moins de l'oligomère acrylique multifonctionnel et 60 parties en poids ou plus et 80 parties en poids ou moins du monomère acrylique bifonctionnel pour 100 parties en poids des matériaux de départ pour la résine à base de radical acrylique et comprend en outre 5 parties en poids ou plus et 10 parties en poids ou moins du photoinitiateur.

9. Disque optique ayant un film de protection pour le disque optique réalisé sur une surface d'un côté lecture d'un substrat, où le film de protection est obtenu en durcissant une composition pour des films de protection pour des disques optiques comprenant une composition à base de résine contenant une résine à base de radical acrylique durcissable par UV comme composant principal incluant un monomère acrylique multifonctionnel, un oligomère acrylique multifonctionnel et un monomère acrylique bifonctionnel contenant des unités de répétition incluant au moins un d'un groupe éthoxy et propoxy comme matériaux de départ pour la résine à base de radical acrylique; et un photoinitiateur approprié,
par quoi
la composition à base de résine comprend 4 parties en poids ou plus et 10 parties en poids ou moins du monomère acrylique multifonctionnel, 10 parties en poids ou plus et 36 parties en poids ou moins de l'oligomère acrylique multifonctionnel et 60 parties en poids ou plus et 80 parties en poids ou moins du monomère acrylique bifonctionnel pour 100 parties en poids des matériaux de départ pour la résine à base de radical acrylique, et comprend en outre 5 parties en poids ou plus et 10 parties en poids ou moins du photoinitiateur.

Drawing