USE OF LUBRICANT COMPOSITIONS FOR LUBRICATION OF BEARINGS

Description

TECHNICAL FIELD

[0001] The present invention relates to the use of a lubricant composition, and more particularly to the use of a lubricant composition with a distinguished rust inhibition, particularly even after having been subjected to heat hysteresis for lubrication of bearings in automobile auxiliary equipment.

BACKGROUND ART

[0002] Lubricants such as grease, etc. are widely used in lubrication of various machines including automobiles, construction machines, industrial machines, machine tools, etc., and also various parts as members of the machines. The machines have a possibility of water intrusion, depending on the locations where they are used, and thus requirements for the rust inhibition thereof are more and more strict. Furthermore, recent trends towards higher speed, much more size reduction, higher performance, lighter weight, etc. have made service temperatures of these peripheral equipment higher and higher, so the rust inhibition after having been subjected to such heat hysteresis has been also an important requirement.

[0003] To improve the rust inhibition use of some of additives have been studied. A grease composition for ball-and-roller bearings, which comprises a grease composition containing silicone oil- or fluorocarbon oilbased lubricating oil as a base oil, and a rust inhibitor comprising a magnesium compound and a volatile rust inhibitor as essential components has been so far proposed, where triazole-based compound such as benzotriazole, methylbenzotriazole, etc., or dicyclohexyl ammonium nitrite have been recommended as preferable volatile rust inhibitors.

Patent Literature 1 : JP-A-9-59664

[0004] The proposed grease composition for ball-and-roller bearings is said to have a distinguished rust inhibitive action in addition to a high durability at elevated temperatures, but it contains a volatile rust inhibitor as one of rust inhibitor components, so a long term rust inhibition at elevated temperatures is not satisfactory, and as to the alkaline component such as magnesium oxide, etc., their influence on the environments must be taken into consideration.

[0005] A heat-resistant grease composition, which comprises fluorosilicone oil, a fluororesin-based thickener, and an additive such as calcium alkylsulfonate, etc., and which can also contain other well known thickeners such as calcium stearate, etc. has been also proposed, where it is shown by evaporation tests or engine tests that the heat resistance is distinguished and also stable for a long time, but no mention is made of the rust inhibition, particularly even after having been subjected to heat resistance tests.

Patent Literature 2 : JP-A-8-143883

[0006] The present applicant has previously proposed a lubricating grease composition, which comprises perfluoropolyether base oil, and a metal salt of aliphatic dicarboxylic acid as a thickener, where the applicant shows that the composition can further contain a powdery fluororesin to attain improvements of abrasion resistance of mating material, leakage resistance, detergency, etc.

Patent Literature 3 : JP-A-2001-354986

[0007] It is recommended that in the proposed lubricating grease composition a mixing proportion of the metal salt of aliphatic dicarboxylic acid used as a thickener is about 1 to about 50% by weight, preferably 3 to 35% by weight, on the basis of the composition. In the disclosed Examples 1 to 14 relate to lubricating grease compositions consisting of two components, i.e. the thickener and perfluoropolyether oil, the thickener is used in such preferable mixing proportions.

[0008] As to the powdery fluororesin as an admixable component, it is recommended that the admixing proportion is not more than about 50% by weight, preferably about 3 to about 35% by weight, on the basis of the composition. In the disclosed Examples 15 to 17 relate to lubricating grease composition consisting of these three components, it is recommended that the admixing proportion of powdery fluororesin is 5% by weight, whereas that of metal salt of aliphatic dicarboxylic acid as a thickener is 15-25% by weight. As is known from such results, an increase in the admixing proportion of metal salt of aliphatic dicarboxylic acid as a thickener will inhibit any increase the admixing proportion of powdery fluororesin.

DISCLOSURE OF THE INVENTION

PROBLEM TO BE SOLVED BY THE INVENTION

[0009] An object of the present invention is to provide a lubricant composition with a distinguished rust inhibition, particularly even after having been subjected to heat hysteresis, which comprises a fluoro-oil and an appropriate admixing proportion of powdery fluororesin as a thickener for lubrication of bearings in automobile auxiliary equipment:

MEANS FOR SOLVING THE PROBLEM

[0010] The object of the present invention can be attained by the use of a lubricant composition, which comprises a perfluoropolyether oil, a powdery fluororesin thickener, and Ca salt or Na salt of aromatic sulfonic acid or saturated aliphatic dicarboxylic acid as a rust-inhibitive additive, where the thickener is in a proportion of 10-40% by weight, and the rust-inhibitive additive is in a proportion of 0.3-10% by weight on the basis of total weight of the composition, the balance being the perfluoropolyether oil, wherein the perfluoropolyether oil is selected from perfluoropolyether oils having the following formulae (1) to (4)

        (1)     RfO(CF₂CF₂O)_m(CF2O)_nRf

wherein in the formula (1) m+n=3-200, and m:n=10-90:90-10, and the CF₂CF₂O group and the CF₂O group are in random combination in the main chain,

        (2)     RfO[CF(CF₃)CF₂O]_p(CF₂CF₂O)_q(CF₂O)_rRf

wherein in the formula (2) p+q+r=3-200, q and r can be 0, respectively, and (q+r)/p=0-2, and the CF(CF₃)CF₂O group, the CF₂CF₂O group, and the CF₂O group are in random combination in the main chain,

        (3)     RfO[CF(CF₃)CF₂O]_s(CF₂CF₂O)_t(Rf

wherein in the formula (3) s+t=2-200, t can be 0, and t/s=0-2, and the CF(CF₃)CF₂O group and the CF₂CF₂O group are in random combination in the main chain, and

        (4)     F(CF₂CF₂CF₂O)_2-100C₂F₅

for lubrication of bearings in automobile auxiliary equipment,
wherein Rf in formulae (1) to (3) is a perfluoroalkyl group having 1 to 5 carbon atoms.

EFFECT OF THE INVENTION

[0011] The present lubricant composition has a distinguished rust inhibition, particularly even after having been subjected to heat hysteresis, and thus can be used widely in lubrication of machines and their parts to be used particularly outdoors, and specifically used in effective lubrication of bearings requiring substantial rust inhibition, heat resistance, low-temperature characteristics, load-carrying capacity, etc. in automobile auxiliary equipment such electric fan motors, fuel injector equipments, alternators, etc. of automobiles. Furthermore, the present lubricant composition can be used for lubrication of solid-solid contacts such as sliding parts of ball-and-roller bearings, slide bearings, sintered bearings, gears, valve, cocks, oil seals, rolls, electric contacts, etc.

BEST MODES FOR CARRYING OUT THE INVENTION

[0012] The perfluoropolyether oil used according to the present invention is represented by the following formulae (1)-(4),
where Rf is a perfluoro lower alkyl groups having 1-5 carbon atoms, preferably 1-3 carbon atoms, such as a perfluoromethyl group, a perfluoroethyl group, perfluoropropyl group, etc.

        (1)     RfO(CF₂CF₂O)_m(CF₂O)_nRf

[0013] In the formula (1), m+n=3-200, and m:n=10-90:90-10, and the CF₂CF₂O group and the CF₂O group are in random combination in the main chain. The perfluoropolyether (1) can be obtained by complete fluorination of a precursor formed by photo-oxidation polymerization of tetra-fluoroethylene.

        (2)     RfO[CF(CF₃)CF₂O]_p(CF₂CF₂O)_q(CF₂O)_rRf

[0014] In the formula (2), p+q+r=3-200, q and r can be 0, respectively, and (q+r)/p=0-2 , and the CF(CF₃)CF₂O group, the CF₂CF₂O group, and the CF₂O group are in random combination in the main chain. The perfluoropolyether (2) can be obtained by complete fluorination of a precursor formed by photo-oxidation polymerization of hexafluoropropene and tetra-fluoroethylene.

        (3)     RfO[CF(CF₃)CF₂O]_s(CF₂CF₂O)_tRf

[0015] In the formula (3), s+t=2-200, t can be 0, and t/s=0-2 , and the CF(CF₃)CF₂O group and the CF₂CF₂O group are in random combination in the main chain, and the perfluoropolyether (3) can be obtained by complete fluorination of a precursor formed by photo-oxidation polymerization of hexafluoropropene and tetrafluoroethylene, or by anionic polymerization of hexafluoropropylene oxide or tetrafluoroethylene oxide in the presence of a cesium fluoride catalyst, followed by successive treatment of the resulting acid fluoride compound having a terminal-CF(CF₃)COF group with a fluorine gas.

        (4)     F(CF₂CF₂CF₂O)_2-100C₂F₅,

[0016] The perfluoropolyether (4) can be obtained by anionic polymerization of 2,2,3,3-tetrafluorooxetane in the presence of a cesium fluoride catalyst, followed by treatment of the resulting fluorine -containing polyether (CH₂CF₂CF₂O)_n under ultraviolet irradiation at about 160° to about 300°C with a fluorine gas.

[0017] These perfluoropolyether base oils can be used alone or in a mixture thereof, and when used as a lubricating oil the viscosity (40°C) is desirably about 5 to about 2,000mm²/sec, preferably about 10 to about 1,500mm²/sec. When the viscosity is less than about 5mm²/sec., the evaporation rate will be increased, and will fail to satisfy the requirements for evaporation rate of 1.5% or less set forth in JIS ball-and-roller bearing grease, class 3 as a heat-resistant grease, whereas when the viscosity is more than about 2, 000mm²/sec, the pour point (JIS K-2283) will be more than 10 °C , and bearings, gears, chains, etc. fail to start at low temperatures in the ordinary manner, resulting in necessary heating for starting, that is, a failure to meet the admissible limit to use as the ordinary grease.

[0018] Fluororesin for use herein as a thickener includes polytetrafluoroethylene [PTFE], tetrafluoroethylene-hexafluoropropene copolymer [FEP], perfluoroalkylene resin, etc., so far used as a lubricant. Polytetrafluoroethylene obtained by subjecting tetrafluoroethylene to such a process as emulsion polymerization, suspension polymerization, solution polymerization, or the like, thereby preparing polytetrafluoroethylene, followed by subjecting it to a treatment by such a process as heat decomposition, decomposition using electron beam irradiation, physical pulverization, or the like, thereby reducing the number average molecular weight Mn from about 1,000- 1,000,000 to about 1,000- 500,000, can be used. Tetrafluoroethylene-hexafluoropropene copolymer having a number average molecular weight of about 1,000 to about 600,000, obtained by conducting copolymerization reaction of tetrafluoroethylene and hexafluoropropene and treatment to reduce the molecular weight, in the same manner as in the case of polytetrafluoroethylene can be used. To obtain PTFE having a melting point of 300°C or higher, which is suitable for use in the present invention, it is desirable that Mn is about 10,000 or more. Control of molecular weight can be also carried out by using a chain transfer agent during the copolymerization reaction. The resulting powdery fluororesin having, among others, an average primary particle size of generally about 500 µm, preferably about 0.1 to about 30 µm, can be used.

[0019] The powdery fluororesin is used in a proportion of 10-40% by weight, preferably 15-35% by weight, on the basis of total weight with base oil and rust-inhibitive additive. When the fluororesin thickener is used in a proportion of above 40% by weight, the composition will be too hard, whereas in a proportion below 10% by weight, no satisfactory thickening capacity of fluororesin etc. can be obtained, resulting in deterioration such as oil separation, and any increase in scattering prevention and leakage prevention can be no more expected.

[0020] The powdery fluororesin can be used together with other thickeners, which include metal soaps such as Li soap, etc., urea resin, minerals such as bentonite, silica, clay, graphite, carbon, zinc oxide, etc., organic pigments, polyethylene, polypropylene, and polyamide. From the viewpoints of heat resistance and lubricability, it is preferable to use monoamide monocarboxylic acid metal salts, monoester carboxylic acid metal salts, diurea, triurea, tetraurea, etc. These other thickeners having a melting point of 300°C or higher can be preferably used.

[0021] Aromatic sulfonic acid salts for use herein as a rust-inhibitive additive include, for example, Ca salts or Na salts of petroleum sulfonic acid, alkylbenzene sulfonic acid, dialkylnaphtharene sulfonic acid, etc. The sulfonic acid salts having an aromatic ring are distinguished in both heat resistance and rust inhibition.

[0022] Saturated aliphatic dicarboxylic acid salts, for use herein as a rust-inhibitive additive include, for example, Ca salts or Na salts of oxalic acid, malonic acid, succinic acid, methylsuccinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, nonamethylenedicarboxylic acid, decamethylenedicarboxylic acid, undecamethylenedicarboxylic acid, dodecamethylenedicarboxylic acid, tridecamethylnenedicarboxylic acid, tetradecamethylenedicarboxylic acid, pentadecamethylenedicarboxylic acid, hexadecamethylenedicarboxylic acid, heptadecamethylenedicarboxylic acid, octadecamethylenedicarboxylic acid, etc. These with an aliphatic group having 6-12 carbon atoms are preferably used particularly in respect to the distinguished rust inhibition.

[0023] These rust-inhibitive additives are used in a proportion of 0.3-10% by weight, preferably 0.3-5% by weight, on the basis of total weight with base oil and powdery fluororesin thickener. In a proportion below 0.3% by weight no desired rust-inhibitive effect can be obtained, whereas in a proportion above 10% by weight no desired proportion of the thickener can be admixed, and no thickening effect can be expected.

[0024] Even among these aromatic sulfonic acid salts and saturated aliphatic dicarboxylic acid salts, the amine salts have no satisfactory heat resistance, whereas the Ba salts and Zn salts have satisfactory rust inhibition and heat resistance, but must be labeled from the viewpoint of recent environmental problem.

[0025] The lubricant composition can further contain other additives so far used in the conventional lubricant, such as an antioxidant, other rust-inhibitors, a corrosion inhibitor, an extreme pressure additive, an oiliness agent, a solid lubricant, etc., when required. The antioxidant includes, for example phenol-based antioxidants such as 2,6-di-t-butyl-4-methylphenol, 4,4' -methylenebis(2,6-di-t-butylphenol), etc. and amine-based antioxidants such as alkyldiphenylamine, triphenylamine, phenyl- a -naphthylamine, phenothiazine, alkylated phenyl- a -naphtylamine, alkylated phenothiazine, etc.

[0026] Other rust inhibitors include, for example, fatty acids, fatty acid amines, alkylsulfonic acid metal salts, alkylsulfonic acid amine salts, oxidiged paraffin, polyoxyalkylethers, etc. The corrosion inhibitors include, for example, benzotriazole, benzoimidazole, thiadiazole, etc.

[0027] The extreme pressure agent includes, for example, phosphorus-based compounds such as phosphoric acid esters, phosphorous acid esters, phosphoric acid ester amine salts, etc., sulfur-based compounds such as sulfides, disulfides, etc., and sulfur-based compound metal salts, such as dialkyldithiophosphoric acid metal salts, dialkyldithiocarbamic acid metal salts, etc.

[0028] The oiliness agent includes, for example, fatty acids, or their esters, higher alcohols, polyhydric alcohols, or their esters, aliphatic amines, fatty acid monoglycerides, etc. The other solid lubricant includes, for example, molybdenum disulfide, graphite, boron nitride, silane nitride, etc.

[0029] The composition can be prepared by adding predetermined amounts of a powdery fluororesin thickener, a rust-inhibitive additive and other necessary additives to perfluoropolyether base oil, followed by through stirring in a stirring kettle, etc. and then by homogenization treatment through three-rolls, or in a high pressure homogenizer.

EXAMPLES

[0030] The present invention will be described below, referring to Examples.

[0031] EXAMPLES 1 TO 25 AND COMPARATIVE EXAMPLES 1 TO 7

[0032] The following base oils, thickeners, and rust-inhibitive additives could be easily mixed together only by stirring, thereby preparing lubricant compositions.

[Base oil]

[0033] 

A-1 : RfO(CF2CF2O)m(CF2O)nRf	Viscosity (40°C) 85mm2/sec:
A-2 : RfO(CF2CF2O)m(CF2O)nRf	Viscosity (40°C) 150mm2/sec.
A-3 : RfO[CF(CF3)CF2O]pRf	Viscosity (40°C)390mm2/sec.
A-4 : RfO[CF(CF3)CF2O]p(CF2O)rRf	Viscosity (40°C)230mm2/sec.
A-5 : F(CF2CF2CF2O)2-100C2F5	Viscosity (40°C)200mm2/sec.

[Thickener]

[0034] 

B-1 : Emulsion-polymerized PTFE (molecular weight: 100-200 × 10³; melting point:330°C; average primary particle size:0.2 µm)

B-2 : Suspension-polymerized PTFE (molecular weight:10-100 × 10³; melting point:318°C; average primary particle size:5 µm)

B-3 : Solution polymerized FEP (molecular weight:50-150 × 10³; melting point:256°C; average primary particle size:0.2 µm)

[Rust-inhibitive additive]

[0035] 

C-1 : Ca dinonylnaphthalene sulfonate

C-2 : Na petroleum sulfonate

C-3 : Na sebacate

C-4 : RfO[CF(CF₃)CF₂O]_nCF(CF₃)COOH

C-5 : Benzotriazole

C-6 : Octylamine salt of dinonylnaphthalene sulfonic acid

[0036] The resulting lubricant compositions were subjected to MKO test (corrosion degree). The test included, in addition to the test under the following ordinary conditions, comparison of corrosion degrees after having been subjected to heat hysteresis at 180°C for 500 hours as to heating grease-sealed test bearings, followed by similar test to the above.

<EKO test (corrosion degree) according to DIN 51802 >

[0037] 1306K bearings were sealed with grease, amounted on an EKO tester, and tested under such cycle conditions as revolution rate : 80rpm ; revolution cycle : revolution for 8 hours→stoppage for 16 hours→revolution for 8 hours→stoppage for 16 hours→revolution for 8 hours→stoppage for 108 hours (total 164 hours) to evaluate corrosion states on the outer race track surface of the bearing according to the following basis.

[0038] In the test, distilled water was used.

Corrosion

[0039] 

degree	Appearance	Evaluation basis
0	No corrosion	No changes
1	Traces of corrosion	Up to 3 corrosion points in sizes of 1mm or less
2	Weakly corroded	Corroded portions at corrosion degree of 1 or more being within 1% of the surface
3	Corroded	Corrosion extended in a range of 1-5% of the surface
4	Strongly corroded	Corrosion extended in a range of 5-10% of the surface
5	Much strongly corroded	Corrosion extended in a range of 10% or more of the surface

[0040] The results are shown in the following Table together with components of the lubricant compositions.

Table

								EMK Test
Example No.		Base oil		Thickener		Rust-inhibitive additive		Normal corrosion degree	After heating corrosion degree
		Species	wt.%	Species	wt.%	Species	wt.%
Example	1	A-1	74.2	B-1	24	C-1	1.8	0	0
"	2	"	74	"	"	C-2	2.0	0	1
"	3	"	72.6	"	"	C-3	3.4	0	0
"	4	"	67.2	B-2	31	C-1	1.8	0	0
"	5	"	67	"	"	C-2	2.0	0	1
"	6	"	65.6	"	"	C-3	3.4	0	0
"	7	"	77.2	B-3	21	C-1	1.8	0	0
"	8	"	77	"	"	C-2	2.0	0	1
"	9	"	75.6	"	"	C-3	3.4	0	0
"	10	A-2	74.2	B-1	24	C-1	1.8	0	0
"	11	"	74	"	"	C-2	2.0	0	1
"	12	"	72.6	"		C-3	3.4	0	0
"	13	"	67.2	B-2	31	C-1	1.8	0	0
"	14	"	67	"	"	C-2	2.0	0	1
"	15	"	65.6	"	"	C-3	3.4	0	0
"	16	A-3	74.2	B-1	24	C-1	1.8	0	0
"	17	"	74	"	"	C-2	2.0	0	0
"	18	"	67.2	B-2	31	C-1	1.8	0	0
"	19	"	67	"	"	C-2	2.0	0	0
"	20	A-4	74.2	B-1	24	C-1	1.8	0	0
"	21	"	74	"	"	C-2	2.0	0	0
"	22	"	72.6	"	"	C-3	3.4	0	0
"	23	A-5	74.2	"	"	C-1	1.8	0	0
"	24	"	74	"	"	C-2	2.0	0	0
"	25	"	72.6	"	"	C-3	3.4	0	0
Comp.Ex.	1	A-1	73	"	"	C-4	3.0	4	5
"	2	"	75	"	"	C-5	1.0	2	5
"	3	"	74	"	"	C-6	2.0	0	5
"	4	A-2	73	"	"	C-4	3.0	4	5
"	5	"	75	"	"	C-5	1.0	2	5
"	6	"	74	"	"	C-6	2.0	0	4
"	7	A-1	61	"	"	C-3	15	-	-

[0041] Lubricant composition of Comparative Example 7 had a consistency number (JIS K2220 7 ; corresponding to DIN ISO 2137) of No. 4 and therefore too hard impossible to test and to use as a practical grease. The lubricating oil composition of all the Examples had consistency numbers of Nos. 1-3, and could form greases successfully.

Claims

1. Use of a lubricant composition, which comprises a perfluoropolyether oil, a powdery fluororesin thickener, and Ca salt or Na salt of aromatic sulfonic acid or saturated aliphatic dicarboxylic acid as a rust-inhibitive additive, where the thickener is in a proportion of 10-40% by weight, and the rust-inhibitive additive is in a proportion of 0.3-10% by weight on the basis of total weight of the composition, the balance being the perfluoropolyether oil, wherein the perfluoropolyether oil is selected from perfluoropolyether oils having the following formulae (1) to (4)

        (1)     RfO(CF₂CF₂O)_m(CF₂O)_nRf

wherein in the formula (1) m+n=3-200, and m:n=10-90:90-10, and the CF₂CF₂O group and the CF₂O group are in random combination in the main chain,

        (2)     RfO[CF(CF₃)CF₂O]_p(CF₂CF₂O)_q(CF₂O)_rRf

wherein in the formula (2) p+q+r=3-200, q and r can be 0, respectively, and (q+r) /p=0-2, and the CF(CF₃)CF₂O group, the CF₂CF₂O group, and the CF₂O group are in random combination in the main chain,

        (3)     RfO [CF (CF₃) CF₂O] _s (CF₂CF₂O) tRf

wherein in the formula (3) s+t=2-200, t can be 0, and t/s=0-2, and the CF(CF₃)CF₂O group and the CF₂CF₂O group are in random combination in the main chain, and

        (4)     F(CF₂CF₂CF₂O)_2-100C₂F₅

for lubrication of bearings in automobile auxiliary equipment,
wherein Rf in formulae (1) to (3) is a perfluoroalkyl group having 1 to 5 carbon atoms.

2. The use according to claim 1, wherein another thickener is further contained in the lubricant composition.

Ansprüche

1. Verwendung einer Schmiermittelzusammensetzung, welche Folgendes umfasst: ein Perfluorpolyetheröl, ein pulverförmiges Fluorharz-Verdickungsmittel sowie ein Ca-Salz oder Na-Salz einer aromatischen Sulfonsäure oder gesättigten aliphatischen Dicarbonsäure als rostvorbeugendem Additiv, wobei das Verdickungsmittel in einem Verhältnis von 10-40 Gew.-% vorliegt und das rostvorbeugende Additiv in einem Anteil von 0, 3-10 Gew.-%, auf Basis des Gesamtgewichts der Zusammensetzung, vorliegt, wobei der verbleibende Teil das Perfluorpolyetheröl ist, wobei das Perfluorpolyetheröl ausgewählt ist aus Perfluorpolyetherölen mit den folgenden Formeln (1) bis (4):

        (1)     RfO(CF₂CF₂O)_m(CF₂O)_nRf

wobei in der Formel (1) m+n=3-200 ist und m:n=10-90:90-10 ist, und die CF₂CF₂O-Gruppe und die CF₂O-Gruppe in zufälliger Kombination in der Hauptkette vorliegen,

        (2)     RfO[CF(CF₃)CF₂O]_p(CF₂CF₂O)_q(CF₂O)_rRf

wobei in der Formel (2) p+q+r=3-200 ist, q bzw. r 0 sein können, und (q+r)/p=0-2 ist, und die CF(CF₃)CF₂O-Gruppe, die CF₂CF₂O-Gruppe und die CF₂O-Gruppe in zufälliger Kombination in der Hauptkette vorliegen,

        (3)     RfO[CF(CF₃) CF₂O]_s(CF₂CF₂O)_tRf

wobei in der Formel (3) s+t=2-200 ist, t 0 sein kann und t/s=0-2 ist und die CF(CF₃)CF₂O-Gruppe und die CF₂CF₂O-Gruppe in zufälliger Kombination in der Hauptkette vorliegen, und

        (4)     F(CF₂CF₂CF₂O)_2-100C₂F₅

zum Schmieren von Lagern in Kraftfahrzeug-Nebenaggregaten, wobei Rf in den Formeln (1) bis (3) eine Perfluoralkylgruppe mit 1 bis 5 Kohlenstoffatomen ist.

2. Verwendung gemäß Anspruch 1, wobei ein weiteres Verdickungsmittel in der Schmiermittelzusammensetzung des Weiteren enthalten ist.

Revendications

1. Utilisation d'une composition de lubrifiant, qui comprend une huile de perfluoropolyéther, un épaississant de fluororésine pulvérulent et un sel de Ca ou un sel de Na d'acide sulfonique aromatique ou d'acide dicarboxylique aliphatique saturé en tant qu'adjuvant antirouille, où l'épaississant est dans une proportion de 10 à 40 % en poids, et l'adjuvant antirouille est dans une proportion de 0,3 à 10 % en poids sur la base du poids total de la composition, le reste étant l'huile de perfluoropolyéther, dans laquelle l'huile de perfluoropolyéther est choisie parmi des huiles de perfluoropolyéther répondant aux formules (1) à (4) suivantes

        (1)     RfO(CF₂CF₂O)_m(CF₂O)_nRf

dans laquelle dans la formule (1) m + n = 3 à 200, et m : n = 10 à 90 : 90 à 10, et le groupe CF₂CF₂O et le groupe CF₂O sont en combinaison aléatoire dans la chaîne principale,

        (2)     RfO[CF(CF₃)CF₂O]_p(CF₂CF₂O)_q(CF₂O)_rRf

dans laquelle dans la formule (2) p + q + r = 3 à 200, q et r peuvent valoir 0, respectivement, et (q + r)/p = 0 à 2, et le groupe CF(CF₃)CF₂O, le groupe CF₂CF₂O, et le groupe CF₂O sont en combinaison aléatoire dans la chaîne principale,

        (3)     RfO[CF(CF₃)CF₂O]_s(CF₂CF₂O)_tRf

dans laquelle dans la formule (3) s + t = 2 à 200, t peut valoir 0, et t/s = 0 à 2, et le groupe CF(CF₃)CF₂O et le groupe CF₂CF₂O sont en combinaison aléatoire dans la chaîne principale, et

        (4)     F(CF₂CF₂CF₂O)_{2 à 100}C₂F₅

pour la lubrification de paliers dans un équipement auxiliaire automobile,
dans laquelle Rf dans les formules (1) à (3) est un groupe perfluoroalkyle ayant 1 à 5 atomes de carbone.

2. Utilisation selon la revendication 1, dans laquelle un autre épaississant est en outre contenu dans la composition de lubrifiant.