Technical Field
[0001] The present invention relates to a heat exchange element for exchanging heat between
two flows supplying and exhausting air for ventilation, used for air-conditioning
in, for example, buildings and motor vehicles, and to a heat exchange ventilator including
the same.
Background Art
[0002] Heat exchange ventilators generally used in the field of air conditioning use a variety
of heat exchange elements. There is a static type among the heat exchange elements.
The static heat exchange element, which itself does not operate, basically includes
partition members whose front and rear surfaces are in contact with respective two
air flows to exchange heat, and moisture (in total heat exchange ventilators), from
one air flow to the other, and spacing members for forming paths through which the
two air flows pass the front and rear surfaces of the partition members. Many of these
members are bonded with an adhesive or a pressure-sensitive adhesive and then stacked.
Such heat exchange elements include a cross-flow type as disclosed in Patent Document
1 and a counterflow type as disclosed in Patent Document 2.
[0003] Two blowers are installed in the paths for the two air flows of the heat exchange
element: one introduces air from the outdoors to one of the flow paths of the element;
the other introduces air from an indoor living space to the other flow path. When
the air flows pass through the heat exchange element, the heat and moisture in the
flows are exchanged in such a structure. Consequently, outdoor fresh air is introduced
with its temperature and moisture close to those of the air in the indoor living space,
and ventilation thus can be performed without impairing amenity.
Patent Document 1: Japanese Unexamined Patent Application Publication No. 2004-190921
Patent Document 2: Japanese Unexamined Patent Application Publication No. 2004-003824
[0004] Recently, living spaces in, for example, buildings have been made highly airtight
in order to save energy and increase the lifetime of the buildings, and chemical substance
are used more for the buildings and the equipment in the buildings. Accordingly, the
concentration of organic compounds (volatile organic compounds (VOC)) vaporizing from
the buildings and the equipment is an issue. The Ministry of Health, Labour and Welfare
of Japan specifies guideline values of concentrations in indoor air for 13 compounds
that are considered to be harmful to the human body. In order to reduce the concentration
of indoor chemicals including the 13 compounds, mechanical ventilation for clearing
indoor air becomes more important. A heat exchange ventilator is advantageous which
performs ventilation to introduce fresh air into a living space while heat is exchanged
between intake air and exhaust air, in view of minimizing the energy loss resulting
from the mechanical ventilation. Since the heat exchange ventilator can reduce the
concentration of volatile organic compounds in the air of the living space while ensuring
energy saving, harmful effects of the chemical compounds in question to the human
body can be reduced advantageously.
Disclosure of Invention
Problems to be Solved by the Invention
[0005] The heat exchange element contained in the heat exchange ventilator is intended to
exchange heat and moisture and generally designed so as to have an extremely large
contact area with air flow passing through it. Accordingly, even if a very small amount
of chemical substances, such as volatile organic compounds, are emitted from a component
of the heat exchange element, the total chemical concentration in the air flowing
into the living space is disadvantageously increased after ventilation.
[0006] For example, a heat exchange element of a heat exchanger uses a bonding agent (adhesive
or pressure-sensitive adhesive), and the bonding agent is generally of an emulsion
type using water as a principal solvent. Some of the emulsion-type bonding agents
emit a large amount of volatile organic compounds, such as the residue (unreacted
monomer) of the base resin, after drying. Part of the volatile organic compounds adheres
to the heat exchange element or the ventilator during manufacture and may be reemitted
from the element or the heat exchange ventilator in use. Some of the adhesives and
pressure-sensitive adhesives contain a plasticizer for ensuring that the resin has
film formability at low temperatures or flexibility after curing, or an organic solvent
for adjusting the viscosity. The plasticizer and the solvent are also emitted after
curing, consequently increasing the chemical emission from the heat exchanger.
[0007] In order to overcome these disadvantages, a device for removing or decomposing chemical
substances (for example, an activated carbon filter, a decomposition catalyst, a decomposition
device using electric discharge, etc.) can be provided downstream from the heat exchange
element, upstream from the outlet to the living space. Such a device must be large
in order to reduce the chemical substances in the air of the living space to a very
low concentration. Accordingly, a larger space is required and a higher energy must
be consumed. This is disadvantageous to the heat exchange ventilator intended for
energy saving ventilation.
[0008] It is therefore preferable that the reduction of indoor chemicals be performed by
introducing fresh air from the outdoors while the emission of chemical substances
from the heat exchange ventilator is minimized.
[0009] In view of the above-described disadvantages, the object of the present invention
is to provide a heat exchange element that minimizes the emission of chemical substances
whose presence in space, particularly in the living space of human beings and other
organisms, is unfavorable, and a heat exchange ventilator that is provided with the
heat exchange element to reduce the chemical emission, and thus to enhance the effect
of reducing the concentration of the chemical substances in the space equipped with
the ventilator.
GB 2407151 A describes a heat exchange element having spacing members and partition members, wherein
the partition members and the spacing members have moisture permeable portions and
flame resisting portions, the portions not overlapping with each other.
EP 1052 458 A2 disclose a method for producing a heat exchanger, wherein the spacing members are
corrugated and directly after corrugation bonded to the partition members.
JP 63 280635 A discloses a method for producing a heat exchange element, wherein unit members, each
of which comprises a string-shaped rib material adhered to a raw paper, are bonded
using a hot-melt adhesive comprising magnetic particulates.
JP 2001 241867 A discloses a heat exchanger having partition members made of moisture permeable material
and corrugated spacing members made of non-hygroscopic material.
JP 2000 502788 A describes a ceramic packing with channels for thermal and catalytic beads. Ceramic
plates with ribs are stacked one above another such that channels are constructed.
JP 2001 152116 A describes adhesives for wall papers.
It is the object of the present invention to provide a heat exchange element and a
heat exchanger, which have a reduced emission of vaporized chemicals such as VOC.
This object is solved by the heat exchange element according to claim 1 and the heat
exchanger according to claim 6. Advantageously improvements of the heat exchange element
are given in the dependent claims.
Means for Solving the Problems
[0010] A heat exchange element of the present invention exchanges heat between two flows
passing through an air supply space and an exhaust space partitioned with a plurality
of members. The plurality of members are bonded with a bonding agent (adhesive or
pressure-sensitive adhesive) which contains a volatile organic compound (VOC) or a
carbonyl compound but from which the total emission of such a chemical substance is
100 µg/hr or less per gram.
For the measurement, a bonding agent to be tested is dried in a clean container with
a cross section of about 2 to 3 cm
2 (for example, at 100°C for about 5 minutes), and then air over the bonding agent
is sampled. The chemical emission is then measured as the emission rate of total volatile
organic compounds collected and analyzed by the method specified in JIS A 1901 (Determination
method of the emission of volatile organic compounds (VOC), form aldehydes and other
carbonyl compounds for building productsSmall chamber method).
Advantages
[0011] In the heat exchange element of the present invention, the members constituting the
heat exchange element are bonded with a bonding agent from which the emission of volatile
organic compounds is reduced to a rate of 100 µg/hr or less per gram. Consequently,
the amount of chemical substances emitted from the heat exchange element and the heat
exchange ventilator including the heat exchange element can be reduced. Accordingly,
ventilation using the heat exchange ventilator of the present invention can reduce
the concentration of chemical substances in the living space effectively.
[0012] In the present invention, furthermore, by using a bonding agent from which the emission
of volatile organic compounds is low after drying and which contains no plasticizer
or organic solvent, for bonding the members constituting the heat exchange element,
the chemical emission from the heat exchange element and the heat exchange ventilator
including the heat exchange element can be greatly reduced.
Brief Description of the Drawings
[0013]
[Fig. 1] Fig. 1 is a perspective view of a heat exchange element according to Embodiment
1 of the present invention.
[Fig. 2] Fig. 2 is a perspective view of a unit component constituting the heat exchange
element shown in Fig. 1.
Reference Numerals
[0014]
1: heat exchange element
2: partition member
3: spacing member
4, 5: flow path
Best Mode for Carrying Out the Invention
Embodiment 1
[0015] Fig. 1 is a perspective view of a heat exchange element 1 having a cross-flow stack
structure, contained in a heat exchange ventilator of the present invention. For producing
the heat exchange element 1, a unit component is first prepared by bonding a planar
partition member 2 to a waved spacing member 3 as shown in Fig. 2, and then unit components
are stacked in the direction in which the partition member 2 is stacked on the spacing
member 3. In this instance, the unit components are stacked in such a manner as to
be turned 90 degree with respect to one another so that the spacing members 3 form
two gas flow paths 4 and 5 perpendicular to each other.
[0016] When the unit component shown in Fig. 2 is formed or stacked, a bonding agent (adhesive
or pressure-sensitive adhesive) is used and mainly applied to the ridge lines at the
summits of the spacing member 3. The application of the bonding agent, the formation
of the unit components, and the stacking for the heat exchange element can be performed
according to known methods.
[0017] In the present embodiment, an example of the heat exchange element 1 using an adhesive
is explained as a case where the unit component is formed with a machine (corrugator)
for manufacturing single-faced corrugated paper for packaging. In the corrugator,
material sheets for the partition member 2 and the spacing member 3 are used as the
liner and the corrugated portion, respectively, and a desired bonding agent, whose
viscosity may have been adjusted, is placed in the glue feeder of the corrugator.
Thus unit component is continuously formed. Then, a bonding agent is further applied
to the ridges at the summits of the resulting unit component using, for example, a
roll coater, and unit components are stacked while being turned 90 degree with respect
to one another. The heat exchange element 1 is thus produced.
[0018] The bonding agent for bonding the partition member 2 and the spacing member 3 used
in the manufacture of the heat exchange element 1 is often of a resin emulsion type
containing water as a principal solvent. For example, this type of adhesive contains
a base resin that is dispersed in particle form in water. The resin particles are
aggregated and cured to form film by drying to remove the water. At the same time,
the resin of the adhesive permeates into the asperities on the surfaces of the members
in contact with each other and hardens to exhibit an effect of adhesion. The adhesive
is selected from various types, depending on the compatibility with the materials
to be bonded, the presence or absence of water resistance, the degree of viscosity,
and other desired physical properties. Generally used adhesives include vinyl acetate
resin emulsion adhesives, acrylic resin emulsion adhesives, vinyl acetate-acrylic
ester copolymer resin emulsion adhesives, and ethylene-vinyl acetate copolymer resin
(EVA) emulsion adhesives. In addition, combined adhesives containing some of these
different types may be used.
Many pressure-sensitive adhesives are of an emulsion type containing water as a principal
solvent, as with the above-described adhesives. Generally used emulsion types include
epoxy, synthetic rubber, polyurethane, acrylic, ethylene-vinyl acetate copolymer (EVA),
and silicone pressure-sensitive adhesives.
[0019] However, these bonding agents may contain an unintended residue of the base resin.
The residue may be a unreacted residual monomer or a decomposition product produced
at the time of polymerization of monomers to prepare a polymer of the resin (for example,
a vinyl acetate monomer being a residual monomer, or acetic acid or acetaldehyde being
a decomposition product, in the preparation of vinyl acetate resin or ethylene-vinyl
acetate copolymer (EVA) resin)). The residual monomer and decomposition product contain
volatile organic compounds (defined as organic compounds generally having boiling
points in the range of 50 to 260°C, or defined in JIS A 1901 as organic compounds
having gas chromatographic peaks in the range between n-hexane and n-hexadecane) or
components having lower boiling points than the volatile organic compounds. JIS A
1901 specifies an example of a method for collecting and measuring these components
in detail.
[0020] In order to help the film formation by curing, or in order to maintain the flexibility
of the resin after curing, the emulsion-dispersed adhesive and pressure-sensitive
adhesive may contain a phthalate ester as a plasticizer, such as n-butyl phthalate
(DBP) or di-2-ethylhexyl phthalate (DOP). While some of the phthalate esters have
relatively high melting points and are not classified as volatile organic compounds,
the above-mentioned DBP and DOP in the phthalate ester are particularly designated
as compounds whose indoor concentration should be reduced and the Ministry of Health,
Labour and Welfare specifies guideline values for their indoor concentrations.
[0021] Some of the emulsion-dispersed adhesives containing water as a principal solvent
contain an organic solvent, such as toluene, xylene, ethylbenzene, or styrene, for
the purpose of, for example, adjusting the viscosity. After all, a major part of the
chemical substances emitted from adhesives at the time of drying results from the
chemical substances contained in aqueous emulsion adhesives, such as plasticizers
and organic solvents. It is therefore preferable to use adhesives not containing those
chemical substances. The above organic solvents have relatively low boiling points,
and accordingly almost all the organic solvent in an adhesive is emitted when the
adhesive is cured to form a film. However, part of the organic solvent remains in
the resin.
[0022] Some of the heat exchange ventilators are used under high-humidity conditions. The
heat exchange element used under these conditions requires that the partition members
2 and the spacing members 3 be water-resistant so as to prevent damage resulting from
water absorption, and that the bonding agent be also water-resistant so as to ensure
reliability for a long time. In order to enhance the water resistance, some of the
bonding agents contain formaldehyde or the like as a crosslinking agent for crosslinking
molecular chains during curing, in addition to a plasticizer which is generally contained
in bonding agents. Although formaldehyde has a very low boiling point (boiling point:
about -19 degree) and is not classified into the group of volatile organic compounds,
it is suspected to be a causative agent of the sick building syndrome or the like.
The Ministry of Health, Labour and Welfare specifies a guideline value for its concentration
in indoor air, as well as that for acetaldehyde.
[0023] The above solvent and chemical inclusions are not only left in the bonding agent
and emitted after curing and film formation, but also are emitted during drying or
curing in the preparation of the heat exchange element. The emitted chemical compounds
are absorbed by the partition members 2 and the spacing members 3 and, thus, contained
in the resulting product. When the product is used, the chemical compounds may be
reemitted by airflow passing through the element. It is therefore preferable to use
a bonding agent which does not include such chemical substances as far as possible.
[0024] Recently developed aqueous emulsion-dispersed adhesives include adhesives using a
resin whose residual monomer is reduced, adhesives containing no plasticizer or any
other chemical substance, but functioning in the same manner as known adhesives, and
adhesives containing no organic solvent. Examples of these adhesives are disclosed
in Japanese Patent No.
3299920 and Japanese Unexamined Patent Application Publication Nos.
2004-155997,
2001-152116,
2002-179719, and
2003-171639. These adhesives do not contain chemical substances likely to be emitted as main
constituents, and consequently they hardly emit the chemical substances during and
after drying.
[0025] By using the above-described adhesive as the bonding agent of the heat exchange element
to bond the members constituting the heat exchange element, chemical substances, such
as volatile organic compounds, plasticizers, and organic solvents, which are likely
to remain in and be emitted from the bonding agent or likely to be absorbed by and
emitted from the heat exchange element can be extremely reduced. Accordingly, the
heat exchange ventilator including the heat exchange element can further reduce the
chemical emission to fresh air introduced from the outdoors; hence, the heat exchange
ventilator can more enhance the effect of reducing the indoor concentration of the
chemical substances than the known products. In addition, since the volatile organic
compounds, plasticizers and organic solvents usually have foul odors, the effect of
reducing the foul odors emitted from the ventilator can be subsidiarily expected by
reducing emitted volume of such chemical substances.
[0026] When the bonding agent used in the present invention is used in the above-described
manufacturing process, the following should be noted. If a bonding agent not satisfying
the requirements for the bonding agent used in the present invention (adhesive or
pressure-sensitive adhesive emitting a large amount of volatile organic compounds,
or containing a plasticizer, an organic solvent, or the like) has been used in the
corrugator or the roll coater before feeding the bonding agent of the present invention
into the equipment, the chemical substances may be mixed with the bonding agent of
the present invention and contaminate it, and consequently the chemical emission from
the resulting heat exchange element may be extremely increased. In order to prevent
the contamination, the portion in the equipment coming into contact with the bonding
agent should be sufficiently cleaned before using the bonding agent.
[0027] The partition member 2 and the spacing member 3 are made of a variety of materials
according to the intended use or application of the heat exchange element 1. For example,
a total heat exchange element require that the partition member 2 has moisture permeability.
Accordingly, the partition member 2 is generally made of a specially-treated paper
prepared by applying a special treatment for improving the moisture permeability or
the elasticity to paper with various resins or chemical solutions, a resin having
an improved moisture permeability, or a sheet prepared by bonding or depositing the
resin onto a nonwoven fabric or any other reinforcing substrate. Sensible heat exchange
elements do not require such characteristics, and accordingly allow a wide range of
choices in materials. For example, a resin film or a thin metal plate (metal film)
can be used instead of paper. The spacing member 3, which maintains the space between
the partition members 2, is made of a wide variety of materials, such as a paper subjected
to a special treatment for reducing the elasticity with a resin, a resin film and
a reinforced resin film prepared by bonding or depositing the resin film onto a nonwoven
fabric or any other reinforcing substrate, a molded resin, a metal, and a metal thin
film bonded to paper.
[0028] Preferably, the partition member 2 and the spacing member 3 constituting the heat
exchange element 1 are preferably made of materials from which the emission of chemical
substances is minimized because the partition member 2 and the spacing member 3 also
have very large contact areas with air. However, natural materials, such as paper,
may originally contain some of the volatile organic compounds. Thus, it may be difficult
to prepare a material completely free from chemical substances. The materials of the
partition member 2 and the spacing member 3 are formed into sheets and wound into
rolls or cut into rectangular pieces. In this process, the sheets are often brought
into sufficient contact with air at relatively high temperature. Consequently, chemical
substances or the like may vaporize and completely dissipate or result in a similar
state.
Example
[0029] A heat exchange element 1 was prepared as an example of the heat exchange element
1 of the present inversion by the above-described method. In the preparation, a specially
treated paper with an inorganic agent was used for the partition members 2 and the
spacing members 3, and an adhesive from which residual monomers were reduced was used
as the bonding agent. The adhesive was prepared by partially introducing ethylene-vinyl
acetate polymer (EVA) resin emulsion to vinyl acetate resin aqueous emulsion, instead
of adding the above-described plasticizer, so as to exhibit the same characteristics.
On the other hand, another heat exchange element was prepared for a comparative example
by the above-described method using the same partition members and spacing members
as in the example. Only the adhesive was replaced with a vinyl acetate resin aqueous
emulsion adhesive which contains a plasticizer and from which the emission of total
volatile organic compounds defined by JIS A 1901 and measured in accordance with JIS
A 1901 was about 500 µg/hr per gram of the adhesive. The heat exchange elements of
the example and the comparative example were installed in the same type of heat exchange
ventilators and the chemical emissions from the ventilators were measured and compared
with each other. The results are shown in Table 1.
[0030]
[Table 1]
Chemical emission from adhesive
(per gram of adhesive) |
Chemical emission from heat exchange ventilator |
| less than or equal to detection limit |
8.7×102 µg/hr |
| about 500 µg/hr |
6.1×104 µg/hr |
[0031] Table 1 shows that the chemical emission rates of the heat exchange element and the
heat exchange ventilator depend on the chemical emissions from the adhesive. It has
also been found from the data that in order to achieve, for example, a total volatile
organic compound concentration of 400 µg/m
3, which is the provisional target value for total volatile organic compounds in indoor
air, currently specified by the Ministry of Health, Labour and Welfare, a preferred
chemical emission from the adhesive in general cases is about 50 to 100 µg/hr or less
per gram of the adhesive, though depending on the size of the heat exchange element,
the volume of the space where the heat exchange ventilator is used, and other factors.
Accordingly, by using an adhesive from which the chemical emission is in this range
or below to bond the partition member 2 and the spacing member 3 constituting the
heat exchange element 1, the heat exchange ventilator including the heat exchange
element 1 can provide a good environment to the user.
In addition, it is preferable that the total emission of volatile organic compounds
or carbonyl compounds from the entire heat exchange element 1 including the bonding
agent bonding the partition member 2 and the spacing member 3 be 100 µg/hr or less
per gram.
Industrial Applicability
[0032] The present invention can be applied to any heat exchange ventilator that uses a
bonding agent for bonding its components, and can promise to produce an effect.
Also, the heat exchange ventilator of the present invention can be used not only for
ventilation of rooms in buildings, but also for ventilation of various spaces, such
as automobiles, trains, and other vehicles.
1. A heat exchange element for ventilation in which heat is exchanged between two flows
passing through an air supply space and an air exhaust space partitioned with a plurality
of members based on paper or resin,
wherein in the heat exchange element, whose plurality of members are bonded with a
bonding agent
the bonding agent is an resin emulsion-dispersed adhesive containing water as an principal
solvent, selected from the group consisting of vinyl acetate resin emulsion adhesives,
acrylic resin emulsion adhesives, vinyl acetate-acrylic ester copolymer resin emulsion
adhesives, ethylene-vinyl acetate copolymer resin (EVA) emulsion adhesives, and polyurethane
adhesives, or prepared by mixing a plurality of adhesives selected from the same group,
or the bonding agent is a resin emulsion pressure-sensitive adhesive containing water
as a principal solvent, selected from the group consisting of epoxy resin pressure-sensitive
adhesives, synthetic rubber pressure-sensitive adhesives, polyurethane pressure-sensitive
adhesives, acrylic resin pressure-sensitive adhesives, ethylene-vinyl acetate copolymer
resin (EVA) pressure-sensitive adhesives, silicone pressure-sensitive adhesives, or
prepared by mixing a plurality of adhesives selected from the same group, characterised in that
the bonding agent contains a volatile organic compound or a carbonyl compound but
from which the total emission of such a chemical substance is 100 µg/hr or less per
gram.
2. The heat exchanger element for ventilation according to claim 1, wherein the bonding
agent is prepared by mixing vinyl acetate resin emulsion and ethylene-vinyl acetate
copolymer resin (EVA) emulsion.
3. The heat exchange element for ventilation according the proceeding claim, wherein
the bonding agent contains no plasticizer or organic solvent.
4. The heat exchange element for ventilation according to one of the proceeding claims,
wherein the bonding agent is water-resistant.
5. The heat exchange element for ventilation according to one of the proceeding claims,
wherein the total emission of volatile organic compounds or carbonyl compounds from
the entire element including the members and the bonding agent is 100 µg/hr or less
per gram.
6. A heat exchange ventilator including the heat exchange element according to one of
the proceeding claims.
1. Wärmeaustauschelement zur Belüftung, in welchem Wärme zwischen zwei Strömen ausgetauscht
wird, die durch einen Luftzuführungsraum und einen Luftabführungsraum hindurchgehen,
die durch mehrere Teile auf der Grundlage von Papier oder Harz geteilt sind,
wobei in dem Wärmeaustauschelement, dessen mehrere Teile mit einem Bindemittel verbunden
sind, das Bindemittel ein in einer Harzemulsion dispergierter Klebstoff enthaltend
Wasser als ein Hauptlösungsmittel ist, ausgewählt aus der Gruppe bestehend aus Vinylacetatharz-Emulsionsklebstoffen,
Acrylharz-Emulsionsklebstoffen, Vinylacetatacrylester-Copolymerharz-Emulsionsklebstoffen,
Ethylenvinylacetat(EVA)-Copolymerharz-Emulsionsklebstoffen und Polyurethan-Klebstoffen,
oder hergestellt durch Mischen mehrerer Klebstoffe, die aus derselben Gruppe ausgewählt
sind,
oder das Bindemittel ein druckempfindlicher Harz-Emulsionsklebstoff enthaltend Wasser
als ein Hauptlösungsmittel ist, ausgewählt aus der Gruppe bestehend aus druckempfindlichen
Epoxidharz-Klebstoffen, druckempfindlichen Kunstgummi-Klebstoffen, druckempfindlichen
Polyurethan-Klebstoffen, druckempfindlichen Acrylharz-Klebstoffen, druckempfindlichen
Ethylenvinylacetat(EVA)-Copolymerharz-Klebstoffen, druckempfindlichen Silikon-Klebstoffen,
oder hergestellt durch Mischen mehrerer Klebstoffe, die aus derselben Gruppe ausgewählt
sind,
wobei das Bindemittel eine flüchtige organische Verbindung oder eine Carbonylverbindung
enthält, von der die Gesamtemission einer derartigen chemischen Substanz 100 µg/h
oder weniger pro Gramm beträgt.
2. Wärmeaustauschelement zur Belüftung nach Anspruch 1, bei dem das Bindemittel hergestellt
ist durch Mischen von Vinylacetatharz-Emulsion und Ethylenvinylacetat(EVA)-Copolymerharz-Emulsion.
3. Wärmeaustauschelement zur Belüftung nach dem vorhergehenden Anspruch, bei dem das
Bindemittel keinen Weichmacher oder organisches Lösungsmittel enthält.
4. Wärmeaustauschelement zur Belüftung nach einem der vorhergehenden Ansprüche, bei dem
das Bindemittel wasserbeständig ist.
5. Wärmeaustauschelement zur Belüftung nach einem der vorhergehenden Ansprüche, bei dem
die Gesamtemission von flüchtigen organischen Verbindungen oder Carbonylverbindungen
von dem gesamten Element enthaltend die Teile und das Bindemittel 100 µg/h oder weniger
pro Gramm beträgt.
6. Wärmeaustauschventilator enthaltend das Wärmeaustauschelement gemäß einem der vorhergehenden
Ansprüche.
1. Elément d'échange de chaleur pour ventilation dans lequel de la chaleur est échangée
entre deux flux passant par un espace d'alimentation en air et un espace d'échappement
de l'air avisé par une pluralité d'organes à base de papier ou de résine,
Où, dans l'élément d'échange de chaleur, une pluralité d'organes est liée avec un
agent de liaison,
l'agent de liaison est un adhésif dispersé par émulsion de résine contenant de l'eau
comme solvant principal, choisi dans le groupe consistant en les adhésifs d'émulsion
de résine d'acétate de vinyle, les adhésifs d'émulsion de résine acrylique, les adhésifs
d'émulsion de résine de copolymère d'acétate de vinyle-ester acrylique, les adhésifs
d'émulsion de résine de copolymère d'éthylène-acétate de vinyle (EVA), et les adhésifs
de polyuréthane, ou préparé en mélangeant une pluralité d'adhésifs choisis dans le
même groupe,
ou l'agent de liaison est un adhésif sensible à la pression d'émulsion de résine contenant
de l'eau comme solvant principal, choisi dans le groupe consistant en les adhésifs
sensibles à la pression de résine époxy, les adhésifs sensibles à la pression de caoutchouc
synthétique, les adhésifs sensibles à la pression de polyuréthane, les adhésifs sensibles
à la pression de résine acrylique, les adhésifs sensibles à la pression de résine
de copolymère d'éthylène-acétate de vinyle (EVA), les adhésifs sensibles à la pression
de silicone, ou préparé en mélangeant une pluralité d'adhésifs choisis dans le même
groupe, caractérisé en ce que
l'agent de liaison contient un composé organique volatil ou un composé carbonyle,
mais duquel l'émission totale d'une telle substance chimique est de 100 µg/h
ou moins par gramme.
2. Elément d'échange de chaleur pour ventilation selon la revendication 1, dans lequel
l'agent de liaison est préparé en mélangeant une émulsion de résine d'acétate de vinyle
et une émulsion de résine de copolymère d'éthylène-acétate de vinyle (EVA).
3. Elément d'échange de chaleur pour ventilation selon la revendication précédente, dans
lequel l'agent de liaison ne contient aucun plastifiant ou solvant organique.
4. Elément d'échange de chaleur pour ventilation selon l'une des revendications précédentes,
dans lequel l'agent de liaison est résistant à l'eau.
5. Elément d'échange de chaleur pour ventilation selon l'une des revendications précédentes,
dans lequel l'émission totale de composés organiques volatils ou de composés carbonyle
de l'élément entier y compris les organes et l'agent de liaison est de 100 µg/h ou
moins par gramme.
6. Ventilateur d'échange de chaleur incluant l'élément d'échange de chaleur selon l'une
des revendications précédentes.