FIELD OF THE INVENTION
[0001] The present invention relates to refrigerators using non-azeotropic refrigerant,
wherein especially, like a large interior storage room at scale, they are necessary
to have big performance to reach a set interior temperature at starting up stage,
moreover they have large change of the interior temperature because of broadly open
doors for storing and taking out of storage goods.
BACKGROUND OF THE ART
[0002] As refrigerators for relatively longer period to keep freshness of such as meat,
fish and shellfish, wherein they are attainable ultra low temperature less than -50°C,
has been used at fishery ports and material handling bases, Currently as refrigerating
systems to realize such ultra low temperature, it has been conventionally used double-stage
refrigerators which have 2 compressors and 2 condensers with combination of low boiling
point refrigerant which has the boiling point is in the range of these low temperature
zone and high boiling point refrigerant which works in room temperature.
Inventors of this present invention had proposed the single-stage compressor type
refrigerator to realize such ultra low temperature using non-azeotropic refrigerant
with combination of low boiling point refrigerant and high boiling point refrigerant,
which is condensable at room temperature. (Japanese Patent Application No.
H 11-99498)
[0003] By the invented ultra low temperature refrigerating system, it has been realized
such ultra low temperature. The refrigerating system is a simple single-stage refrigerator,
which is assembled with single compressor and a condenser. The system exchanges heat
between returned refrigerant gas exhausted from the evaporator in low temperature
and high-pressure refrigerant gas toward the evaporator. The system condenses low
boiling point refrigerant in high-pressure refrigerant by vaporization heat of high
boiling point refrigerant in returned refrigerant gas. The system establishes condition
of vaporization and condensation cycle of non-azeotropic refrigerant at backward and
at forward of the single evaporator.
In the case of applying the above mentioned system to stoker which has relatively
smaller capacity, it is possible to keep relatively stable driving state because of
small heat capacity, few amount of ventilation of interior cool air during stock and
take out materials by horizontally open and close door type structure on the top face
of refrigerator in general, and small change of interior temperature.
[0004] However in the case of large interior storage room larger than several thousand liters
of interior capacity, like for use of storage whole body of tuna without cutting as
business use, it is necessary to enter and work for workers, because of space for
working zone and storage, vertical open and close door type is required and not only
it is necessary to enhance performance at starting up stage accompanied with enlarged
capacity but also it is necessary to enhance pull-down performance for keeping interior
temperature and quick recovery to storage temperature from rising temperature, because
of big amount of ventilated air of these opening and closing doors, and/or during
stocking and taking out storage materials operation work.
While coping with this enhancing performance by enlarging capacity of individual elements
of refrigerator such as a compressor and a condenser, not only it becomes to bear
higher cost accompanied with increase of capacity, but also it becomes unnecessary
exceed performance comparing with usual operating condition.
Moreover coping with enlarging output of compressor for temporal increase of load,
subordinating ability and catch up ability are not good to change of temperature;
it is not realized cooling ability coping with output.
Especially in the case of frequent works of storage and take out storage materials
and large change of interior temperature, it is difficult to keep stable interior
temperature and to get back usual state of temperature speedily.
Inventors of the present invention considered cause of this problem and traced following
specific characteristics of non-azeotropic refrigerant.
Namely, it is necessary to exercise full cooling ability of refrigerator, in the case
of starting up stage, and large rising change of interior temperature.
In such situation, temperature of returned refrigerant at heat exchangers is high
while under condition of high interior temperature until stable operating condition
and it is not enough to get cooling down though evaporated high boiling point constituent
in the non-azeotropic refrigerant cools high-pressure side refrigerant, low boiling
point constituent as state of not condensed circulates in the system. Hence, though
spouted out pressure from compressor does rise, low boiling point constituent does
not reach to condensation, since flux of it is restrained by resistance of decompress
like capillary tube, and heat radiation is also restrained.
Thus low boiling point constituent in the non-azeotropic refrigerant is not condensed,
as it circulates in the refrigerating system as gaseous state, though it is compressed
to high-pressure by a compressor, low boiling point constituent is kept as gaseous
state to an evaporator from a condenser through a heat exchanger, the working load
of compressor is large, since pressure raises by such over load of compressor, heat
radiation above mentioned is not increased, whole cooling ability is not increased,
and interior temperature would not get cooling down easily. Namely, since effect of
cooling is mainly based on condensation and evaporation of high boiling point constituent
in transition state, after all, so cooling ability is not kept and is not worked.
As low boiling point constituent is not cooled down enough in transition state, the
super low temperature ability of refrigerant does not work, also it is not condensed,
though pressure of it is raised by a compressor, therefore whole circulation of refrigerant
is restrained, increase of cooling ability and recovery to usual operating state are
restrained.
DISCLOSURE OF INVENTION
Problems To Be Solved By The Present Invention
[0005] On a single-stage type refrigerating system using non-azeotropic refrigerant, at
starting up and/or at interior temperature rising stage, while low boiling point constituent
does not reach to condensation, or, while interior temperature is getting cooling
down, it should be solved to be possible stable operation by restraining load fluctuation,
increasing amount of flux of refrigerant in order to enhance cooling performance.
How The Problems Are Solved
[0006] The present invention provides a single-stage type refrigerating system using non-azeotropic
refrigerant, wherein having a compressor, a condenser, an evaporator, wherein said
system exchange heat between returned refrigerant from the evaporator, and high-pressure
refrigerant toward the evaporator in a path from the condenser, comprising; open degree
of controllable expansion valves of the evaporator against pressure and flux of refrigerant
gas, at starting up stage and/or at state of not progressing condensation of low boiling
point constituent at high temperature of the interior storage room, enhancing cooling
performance by high temperature boiling point constituent, keeping pressure according
to condensation condition of high temperature boiling point constituent by the opening
expansion valves of evaporator, getting lower temperature of the interior storage
room according to progressing condensation of low boiling point constituent, closing
the said expansion valves of evaporator one by the other adjusting pressure to meet
to condensation condition of low boiling point constituent as usual operating state,
and a system, wherein the said expansion valves of evaporator, having plural parallel
capillaries, the system is featured in controlling amount of flux by number of opening
valves and by number of closing valves.
Advantages Of The Present Invention
[0007] According to the present invention, on a single-stage type refrigerating system using
non-azeotropic refrigerant, during higher operating temperature of the system like
at starting up and/or at rising stage of interior temperature, wherein low boiling
point-constituent in non-azeotropic refrigerant does not reach to condensation, it
is possible to get smoothly stable operation cooling down interior temperature, exercising
maximum cooling ability, moreover, it is possible to decrease load of compressor of
refrigeration system..
BRIEF DESCRIPTION OF DRAWINGS
[0008]
Fig. 1: Configuration of refrigerating system of the present invention
Fig. 2: Cooling Speed Curves showing relationship between number of capillary tubes
and cooling rate
Description of Reference Symbols
[0009]
- 1 :
- compressor
- 2:
- condensor
- 3: heat
- exchanger
- 5-1 to 5-5:
- electromagnetic valves
- 6-1 to 6-5:
- capillary
- 7:
- refrigerator
- 10:
- evaporator
- 11:
- sensor of temperature
- 12;
- controller
Description Of The Best Mode
[0010] Refrigerant using for the present invention is a mixture of non-azeotropic refrigerants,
especially in order to reach to lower than -50°C, wherein comprising of combination
of low boiling point-constituent with standard boiling point of lower than -50 °C
and high boiling point constituent which has high boiling point and high vapor pressure
enabling heat radiation from a condenser and condensation at room temperature, wherein
it exchanges heat between high temperature - high-pressure refrigerant from condenser
toward compressor and low temperature - low-pressure refrigerant from an evaporator
toward a compressor, wherein it is driven under condition as it cools high-pressure
refrigerant toward an evaporator under boiling point, it heats inhaling gas to a compressor
higher than dew point at the pressure.
Composing refrigerator, in order to attain above mentioned conditions, it is composed
with a compressor, a condenser, a throttle valve and an evaporator, it is set a heat
exchanger between a condenser - a throttle valve and an evaporator - a compressor
for meeting to above mentioned condition, it is designed to be possible to adjust
open degree of a throttle valve, it is designed control mechanism to be possible to
adjust open degree of a throttle valve depending on the sensed temperature by a sensor
to measure interior temperature of storage room. As starting up of the refrigerator,
or interior temperature is going up over a certain temperature during stock and take
out storage goods, the open degree of the throttle valve is controlled as the maximum,
corresponding to cooling of interior temperature, decreasing flux of refrigerant by
closing the open degree of the throttle valve gradually, as interior temperature reach
to a set temperature, it is controlled to be minimum open degree of the throttle valve.
As a throttle valve for non-azeotropic refrigerants, more preferable, it is set plural
parallel capillary tubes, corresponding to interior temperature, it is controlled
flux of refrigerant by using electromagnetic valves one after the other, opening and
closing these capillary tubes.
Embodiment Of The Present Invention
[0011] Hereinafter, the outline of embodiment of the present invention, and its parameters
are described. A conceptual configuration of refrigerating system of the present invention
is shown in Fig.1. Compressed refrigerant gas by a compressor (1) radiates heat to
the air at a condenser (2), is branched to four paths via a heat exchanger (3), and
it is expanding by guided capillary tubes with electromagnetic valve (5-1 to 5-5),
it is vaporized in an evaporator (10), and it cools the interior storage room (7).
In an evaporator, corresponding to interior temperature and pressure, a part of high
boiling point constituent sends itself to heat exchanger with returned gas as state
of condensation, cools high temperature and high-pressure refrigerant by evaporation
of itself mainly, condenses low boiling point constituent.
Temperature of the interior storage room is detected by a sensor of temperature (11),
number of capillary tubes passing refrigerant are controlled corresponding to preset
temperature by controller (12), by opening and/or closing electromagnetic valves (5-1
to 5-5)..
At a phase of starting up and/or a stage of higher temperature more than certain temperature
in the interior storage room, all electromagnetic valves are open, and refrigerant
goes through every capillary tube.
Temperature of interior storage room goes up more than higher over preset temperature,
electromagnetic valves are close one by the other, amount of circulation of refrigerant
corresponding to the temperature of interior storage room and exhaling pressure of
compressor are controlled.
When temperature of interior storage room reaches to stable condition at preset temperature,
the system is driven using only one capillary tube. Parameters of embodiment are shown
below:
Structure of storage room: prefabricated structure with double doors
Capacity of interior storage room: 4,275 liters
Operating temperature: lower than -50 °C, -60 °C maximum
Refrigerant: Used refrigerant was enclosed 4,400 grams of EP-53P. Parameters of non-azeotropic
refrigerants are shown in Table 1. Composition of non-azeotropic refrigerants EP-53P
is HFC-23: 40 weight %, HFC-134a: 60 weight % was used.
[0012]
[Table- 1]
| Composition of non-azeoiropic refrigerants and its physical characteristics |
| |
Chemical formula |
Boiling point (°C 1 atm) |
Critical Temperature (°C) |
Critical pressure (abs) (MPa) |
| HFC-23 |
CHF3 |
-82.03 |
25.9 |
4.83 |
| HFC-134a |
CH2FCF3 |
-26.18 |
101.5 |
4.065 |
[0013] In the case of using one capillary tube under configured structure shown in Fig.
1, the interior storage room temperature change from starting up is shown in Table
2. The interior temperature was measured at upper position of interior storage room.
The required time was about 5 hours from room temperature of 34°C to reach the set
temperature of -50°C.
[0014]
Table 2
| Operating Condition In The Case Of One Capillary Tube(Room Temperature : 31-34°C) |
| Hours of operation |
Interior room Temperature (° C) |
Exhaling pressure of compressor (MPa) |
Inhaling pressure of compressor (MPa) |
Exhaling temperature of compressor (°C) |
Inhaling temperature of compressor (°C) |
Inlet temperature of heat exchanger (°C) |
Outlet temperature of heat exchanger (°C) |
| 0:00 |
- |
- |
- |
- |
- |
- |
|
| 0:30 |
5.7 |
2.35 |
0.025 |
122.8 |
33.3 |
108.0 |
|
| 1:00 |
-8.4 |
2.42 |
0.050 |
134.2 |
32.8 |
116.0 |
|
| 1:30 |
-27.0 |
2.30 |
0.070 |
136.0 |
24.9 |
114.0 |
-30.7 |
| 2:00 |
-35.5 |
2.25 |
0.070 |
133.0 |
24.9 |
111.9 |
-37.9 |
| 2:30 |
|
2.23 |
0.070 |
- |
|
|
|
| 3:00 |
-44.6 |
2.20 |
0.060 |
120.0 |
9.6 |
107.0 |
-42.0 |
| 3:30 |
-47.2 |
1.95 |
0.050 |
118.0 |
5.8 |
107.0 |
-43.6 |
| 4:00 |
-48.5 |
1.95 |
0.040 |
119.0 |
5.1 |
103.0 |
-44.4 |
| 4:30 |
-49.1 |
1.90 |
0.040 |
118.0 |
5.0 |
104.0 |
-44.1 |
| 5:00 |
-50.2 |
1.95 |
0.040 |
118.0 |
5.1 |
104.0 |
-44.4 |
[0015] Hereinafter, change of interior room temperature of the embodiment in the case of
using four capillary tubes is shown in Table 3.
Interior temperature was measured at upper point of interior storage room. The electromagnetic
valves were closed one by the other at each switching temperature for four capillary
tubes was 0°C, -10°C, -25°C, under such temperature, one capillary tube was always
open. The result is shown in Table 3. The required time to reach set temperature of
- 50°C was about 4 hours.
[0016]
Table 3
| Operating condition in the case of four capillary tubes(Room temperature : 31-33°C) |
| Hours of operation |
Interior room Temperature (°C) |
Exhaling pressure of compressor (MPa) |
Inhaling pressure of compressor (MPu) |
Exhaling temperature of compressor (°C) |
Inhaling temperature of compressor (°C) |
Inlet temperature of heat exchanger (°C) |
Outlet temperature of heat exchanger (°C) |
| 0:00 |
|
|
|
|
|
|
|
| 0:30 |
-15.3 |
2.20 |
0.25 |
101.0 |
-3.8 |
78.4 |
-21.0 |
| 1:00 |
-30.6 |
2.40 |
0.070 |
114.0 |
15.6 |
98.0 |
-33.8 |
| 1:30 |
-38.2 |
2.20 |
0.060 |
122.1 |
10.9 |
105.0 |
-38.6 |
| 2:00 |
-41.8 |
2.20 |
0.060 |
122.0 |
10.5 |
10.4 |
-39.5 |
| 2:30 |
-45.1 |
20.5 |
0.060 |
122.0 |
10.0 |
104.0 |
-41.4 |
| 3:00 |
-47.9 |
20.0 |
0.050 |
125.0 |
10.7 |
104.0 |
-42.0 |
| 3:30 |
-48.5 |
19.0 |
0.050 |
123.0 |
10.2 |
105.0 |
-43.3 |
| 4:00 |
-50.2 |
19.0 |
0.050 |
119.0 |
10.6 |
105.0 |
-43.2 |
| 4:30 |
-50.0 |
19.0 |
0.040 |
125.0 |
9.0 |
111.0 |
-44.0 |
| 5:00 |
-50.2 |
19.0 |
0.040 |
120.0 |
6.2 |
101.0 |
-45.1 |
[0017] The above results as change of interior room temperature for hours of operation is
shown in Fig.2. As shown in Fig. 2, in the case of using four capillary tubes closing
one by the other corresponding to interior room temperature in order to control amount
of refrigerant and pressure, it is recognized that interior room temperature from
room temperature rapidly falls and starting up is very large.
What starting up is very large does mean required operation hours are less to reach
- 50°C of usual operating temperature, and it also means that response against temperature
change is rapid.
To temperature change from set temperature by input and output of goods under usual
operating condition, interior storage room wall and inside cooled goods in advance
are at set temperature, greatly rising interior atmosphere by effect of ventilation
of air by open doors and new storage goods become object for cooling. Consequently,
it relates that load on cooling from the aspect of heat capacity relatively small,
but range of cooling temperature is large. The present invention of refrigerating
system has quick response for interior storage room temperature change. It is possible
to recover to usual operating condition temperature rapidly and it is also preferable
for conventional usage of refrigerator.