Background of the Invention
[0001] The invention relates to implementing a thermodynamic cycle to convert heat to useful
form.
[0002] Thermal energy can be usefully converted into mechanical and then electrical form.
Methods of converting the thermal energy of low temperature heat sources into electric
power present an important area of energy generation. There is a need for increasing
the efficiency of the conversion of such low temperature heat to electric power.
[0003] Thermal energy from a heat source can be transformed into mechanical and then electrical
form using a working fluid that is expanded and regenerated in a closed system operating
on a thermodynamic cycle. The working fluid can include components of different boiling
temperatures, and the composition of the working fluid can be modified at different
places within the system to improve the efficiency of operation. Systems that convert
low temperature heat into electric power are described in Alexander I. Kalina's
U.S. Pat. Nos. 4,346,561;
4,489,563;
4,982,568; and
5,029,444 . In addition, systems with multicomponent working fluids are described in Alexander
I.
Kalina's U.S. Pat. Nos. 4,548,043;
4,586,340,
4,604,867;
4,732,005;
4,763,480,
4,899,545;
5,095,708;
5,440,882;
5,572,871 and
5,649,426.
[0004] US-A-4,573,321 discloses a multi-step process for generating energy from a source heat flow, comprising
passing a heated media having a mixture of a low volatility component and a high volatility
component into a phase separator. The vaporous working fluid is withdrawn from the
phase separator and passed into a work zone, such as a turbine, wherein the fluid
is expanded. The expanded vaporous working fluid is withdrawn from the work zone and
passed into a direct contact condenser or absorber. The separated weak solution is
withdrawn from the phase separator and passed into counter-current heat exchange relationship
in an interchanger with a portion of media from the direct contact condenser or absorber.
The media from the direct contact condenser or absorber is withdrawn and passed into
a fluid pressurizing zone. A portion of the media is then pumped into the interchanger
where the media is heated and passed into counter-current heat exchange relationship
in a trim heater with a portion of the source heat flow. The remaining portion of
the media from the fluid pressurizing zone is pumped into counter-current heat exchange
relationship in a regenerator with the remaining portion of the source heat flow.
The heated media flows from the trim heater and the regenerator are combined to form
the heated media and the cycle repeated.
[0005] EP-A-0,649,985 discloses a thermal power generator for generating electric power by utilizing a
high heat source and a low heat source, comprising an evaporator, a vapor-liquid separator,
and an absorber and a regenerator, to increase thermal efficiency of an evaporator
and a condenser, and to reduce cost for building apparatuses
[0006] US-A-4,756,162 discloses method for utilising sensible heat energy supplied by a high-temperature
heating fluid, employing a multi-component working fluid thermodynamic cycle, wherein
a solution rich in a lower boiling component is heated in a vapor generator in counter-current
heat exchange with the heating fluid to produce a vapor-fluid mixture which is separated
in a rectifier into a lean solution and a vapor mixture. The enthalpy of the vapor
mixture is optionally increased in a superheater by counter-current heat exchange
with said heating fluid at its highest temperature; the vapor mixture is then expanded
thereby to perform the function of the cycle; and the spent vapor mixture is dissolved
in said lean solution in an absorber so as to regenerate the rich solution. The rich
solution leaving the absorber is compressed and divided into a first and second parts.
The first part is heated by counter-current heat exchange with said lean solution
drawn from the rectifier, whereafter said first part of the rich solution is recycled
to the vapor generator, whereas the second part of the rich solution extracts additional
heat from the heating fluid leaving the vapor generator, by counter-current heat exchange,
and is then fed into the rectifier for counter-current mass and heat exchange with
the vapor-liquid mixture formed in the vapor generator.
Summary of the Invention
[0007] In accordance with a first aspect of the invention, there is provided a method for
implementing a thermodynamic cycle, having the features of claim 1.
[0008] In accordance with a second aspect of the invention, there is provided an apparatus
for implementing a thermodynamic cycle, having the features of claim 9.
[0009] Embodiments of the invention may include one or more of the following advantages.
Embodiments of the invention can achieve efficiency of conversion of low temperature
heat to electric power that exceeds the efficiency of standard Rankine cycles.
[0010] Other advantages and features of the invention will be apparent from the following
detailed description of particular embodiments and from the claims.
Brief description of the drawings
[0011] The accompanying Figures 1 and 2 and the description thereof, illustrate the invention
by way of example. In the drawings:-
Fig. 1 is a diagram of a thermodynamic system for converting heat from a low temperature
source to useful form.
Fig. 2 is a diagram of another embodiment of the Fig. 1 system which permits an extracted
stream and a completely spent stream to have compositions which are different from
the high pressure charged stream.
Fig. 3 is a diagram of a simplified embodiment that does not form part of the invention
in which there is no extracted stream.
Fig. 4 is a diagram of a further simplified embodiment that does not form part of
the invention.
Detailed Description of the Invention
[0012] Referring to Fig. 1, a system for implementing a thermodynamic cycle to obtain useful
energy (e.g., mechanical and then electrical energy) from an external heat source
is shown. In the described example, the external heat source is a stream of low temperature
waste-heat water that flows in the path represented by points 25-26 through heat exchanger
HE-5 and heats working stream 117-17 of the closed thermodynamic cycle. Table 1 presents
the conditions at the numbered points indicated on Fig. 1. A typical output from the
system is presented in Table 5.
[0013] The working stream of the Fig. 1 system is a multicomponent working stream that includes
a low boiling component and a high boiling component. Such a preferred working stream
may be an ammonia-water mixture, two or more hydrocarbons, two or more freons, mixtures
of hydrocarbons and freons, or the like. In general, the working stream may be mixtures
of any number of compounds with favorable thermodynamic characteristics and solubility.
In a particularly preferred embodiment, a mixture of water and ammonia is used. In
the system shown in Fig. 1, the working stream has the same composition from point
13 to point 19.
[0014] Beginning the discussion of the Fig. 1 system at the exit of turbine T, the stream
at point 34 is referred to as the expanded, spent rich stream. This stream is considered
"rich" in lower boiling point component. It is at a low pressure and will be mixed
with a leaner, absorbing stream having parameters as at point 12 to produce the working
stream of intermediate composition having parameters as at point 13. The stream at
point 12 is considered "lean" in lower boiling point component.
[0015] At any given temperature, the working stream (of intermediate composition) at point
13 can be condensed at a lower pressure than the richer stream at point 34. This permits
more power to be extracted from the turbine T, and increases the efficiency of the
process.
[0016] The working stream at point 13 is partially condensed. This stream enters heat exchanger
HE-2, where it is cooled and exits the heat exchanger HE-2 having parameters as at
point 29. It is still partially, not completely, condensed. The stream now enters
heat exchanger HE-1 where it is cooled by stream 23-24 of cooling water, and is thereby
completely condensed, obtaining parameters as at point 14. The working stream having
parameters as at point 14 is then pumped to a higher pressure obtaining parameters
as at point 21. The working stream at point 21 then enters heat exchanger HE-2 where
it is recuperatively heated by the working stream at points 13-29 (see above) to a
point having parameters as at point 15. The working stream having parameters as at
point 15 enters heat exchanger HE-3 where it is heated and obtains parameters as at
point 16. In a typical design, point 16 may be precisely at the boiling point but
it need not be. The working stream at point 16 is split into two substreams; first
working substream 117 and second working substream 118. The first working substream
having parameters as at point 117 is sent into heat exchanger HE-5, leaving with parameters
as at point 17. It is heated by the external heat source, stream 25-26. The other
substream, second working substream 118, enters heat exchanger HE-4 in which it is
heated recuperatively, obtaining parameters as at point 18. The two working substreams,
17 and 18, which have exited heat exchangers HE-4 and HE-5, are combined to form a
heated, gaseous working stream having parameters as at point 19. This stream is in
a state of partial, or possibly complete, vaporization. In the preferred embodiment,
point 19 is only partially vaporized. The working stream at point 19 has the same
intermediate composition which was produced at point 13, completely condensed at point
14, pumped to a high pressure at point 21, and preheated to point 15 and to point
16. It enters the separator S. There, it is separated into a rich saturated vapor,
termed the "heated gaseous rich stream" and having parameters as at point 30, and
a lean saturated liquid, termed the "lean stream" and having parameters as at point
7. The lean stream (saturated liquid) at point 7 enters heat exchanger HE-4 where
it is cooled while heating working stream 118-18 (see above) . The lean stream at
point 9 exits heat exchanger HE-4 having parameters as at point 8. It is throttled
to a suitably chosen pressure, obtaining parameters as at point 9.
[0017] Returning now to point 30, the heated gaseous rich stream (saturated vapor) exits
separator S. This stream enters turbine T where it is expanded to lower pressures,
providing useful mechanical energy to turbine T used to generate electricity. A partially
expanded stream having parameters as at point 32 is extracted from the turbine T at
an intermediate pressure (approximately the pressure as at point 9) and this extracted
stream 32 (also referred to as a "second portion" of a partially expanded rich stream,
the "first portion" being expanded further) is mixed with the lean stream at point
9 to produce a combined stream having parameters as at point 10. The lean stream having
parameters as at point 9 serves as an absorbing stream for the extracted stream 32.
The resulting stream (lean stream and second portion) having parameters as at point
10 enters heat exchanger HE-3 where it is cooled, while heating working stream 15-16,
to a point having parameters as at point 11. The stream having parameters as at point
11 is then throttled to the pressure of point 34, obtaining parameters as at point
12.
[0018] Returning to turbine T, not all of the turbine inflow was extracted at point 32 in
a partially expanded state. The remainder, referred to as the first portion, is expanded
to a suitably chosen low pressure and exits the turbine T at point 34. The cycle is
closed.
[0019] In the embodiment shown in Fig. 1, the extraction at point 32 has the same composition
as the streams at points 30 and 34. In the embodiment shown in Fig. 2, the turbine
is shown as first turbine stage T-1 and second turbine stage T-2, with the partially
expanded rich stream leaving the higher pressure stage T-1 of the turbine at point
31. Conditions at the numbered points shown on Fig. 2 are presented in Table 2. A
typical output from the Fig. 2 system is presented in Table 6.
[0020] Referring to Fig. 2, the partially expanded rich stream from first turbine stage
T-1 is divided into a first portion at 33 that is expanded further at lower pressure
turbine stage T-2, and a second portion at 32 that is combined with the lean stream
at 9. The partially expanded rich stream enters separator S-2, where it is separated
into a vapor portion and a liquid portion. The composition of the second portion at
32 may be chosen in order to optimize its effectiveness when it is mixed with the
stream at point 9. Separator S-2 permits stream 32 to be as lean as the saturated
liquid at the pressure and temperature obtained in the separator S-2; in that case,
stream 33 would be a saturated vapor at the conditions obtained in the separator S-2.
By choice of the amount of mixing at stream 133, the amount of saturated liquid and
the saturated vapor in stream 32 can be varied.
[0021] Referring to Fig. 3, this embodiment does not form part of the invention and differs
from the embodiment of Fig. 1, in that the heat exchanger HE-4 has been omitted, and
there is no extraction of a partially expanded stream from the turbine stage. In the
Fig. 3 embodiment, the hot stream exiting the separator S is admitted directly into
heat exchanger HE-3. Conditions at the numbered points shown on Fig. 3 are presented
in Table 3. A typical output from the system is presented in Table 7.
[0022] Referring to Fig. 4, this embodiment does not form part of the invention and differs
from the Fig. 3 embodiment in omitting heat exchanger HE-2.
Conditions at the numbered points shown on Fig. 4 are presented in Table 4. A typical
output from the system is presented in Table 8. While omitting heat exchanger HE-2
reduces the efficiency of the process, it may be economically advisable in circumstances
where the increased power given up will not pay for the cost of the heat exchanger.
[0023] In general, standard equipment may be utilized in carrying out the method of this
invention. Thus, equipment such as heat exchangers, tanks, pumps, turbines, valves
and fittings of the type used in a typical Rankine cycles, may be employed in carrying
out the method of this invention.
[0024] In the described embodiments of the invention, the working fluid is expanded to drive
a turbine of conventional type. However, the expansion of the working fluid from a
charged high pressure level to a spent low pressure level to release energy may be
effected by any suitable conventional means known to those skilled in the art. The
energy so released may be stored or utilized in accordance with any of a number of
conventional methods known to those skilled in the art.
[0025] The separators of the described embodiments can be conventionally used gravity separators,
such as conventional flash tanks. Any conventional apparatus used to form two or more
streams having different compositions from a single stream may be used to form the
lean stream and the enriched stream from the fluid working stream.
[0026] The condenser may be any type of known heat rejection device. For example, the condenser
may take the form of a heat exchanger, such as a water cooled system, or another type
of condensing device.
[0027] Various types of heat sources may be used to drive the cycle of this invention.
Table 1
| # |
P Mpa (psiA) |
X |
T°C (°F) |
H KJ/kg (BTU/lb) |
G/G30 |
Flow kg/hr (lb/hr) |
Phase |
| 7 |
2.24 (325.22) |
.5156 |
94.9 (202.81) |
191.4 (82.29) |
.5978 |
125,544 (276,778) |
SatLiquid |
| 8 |
2.10 (305.22) |
.5156 |
76.4 (169.52) |
103.6 (44.55) |
.5978 |
125,544 (276,778) |
Liq 28° |
| 9 |
1.48 (214.26) |
.5156 |
76.4 (169.50) |
103.6 (44.55) |
.5978 |
125,544 (276,778) |
Wet .9997 |
| 10 |
1.48 (214.26) |
.5533 |
76.4 (169.52) |
210.0 (90.30) |
.6513 |
136,780 (301,549) |
Wet .9191 |
| 11 |
1.34 (194.26) |
.5533 |
37.7 (99.83) |
-69.3 (-29.79) |
.6513 |
136,780 (301,549) |
Liq 53° |
| 12 |
0.59 (85.43) |
.5533 |
37.5 (99.36) |
-69.3 (-29.79) |
.6513 |
136,780 (301,549) |
Wet .9987 |
| 13 |
0.59 (85.43) |
.7000 |
37.6 (99.83) |
405.7 (174.41) |
1 |
210,021 (463,016) |
Wet.6651 |
| 14 |
0.58 (84.43) |
.7000 |
22.4 (72.40) |
-88.7 (-38.12) |
1 |
210,021 (463,016) |
SatLiquid |
| 15 |
2.41 (350.22) |
.7000 |
34.9 (94.83) |
-30.4 (-13.08) |
1 |
210,021 (463,016) |
Liq 73° |
| 16 |
2.31 (335.22) |
.7000 |
73.6 (164.52) |
151.5 (65.13) |
1 |
210,021 (463,016) |
SatLiquid |
| 117 |
2.31 (335.22) |
.7000 |
73.6 (164.52) |
151.5 (65.13) |
.8955 |
210,021 (463,016) |
SatLiquid |
| 17 |
2.24 (325.22) |
.7000 |
95.2 (203.40) |
704.6 (302.92) |
.8955 |
188,068 (414,621) |
Wet .5946 |
| 118 |
2.31 (335.22) |
.7000 |
73.6 (164.52) |
151.5 (65.13) |
.1045 |
210,021 (463,016) |
SatLiquid |
| 18 |
2.24 (325.22) |
.7000 |
92.1 (197.81) |
653.6 (281.00) |
.1045 |
21,952 (48,395) |
Wet .6254 |
| 19 |
2.24 (325.22) |
.7000 |
94.9 (202.81) |
699.2 (300.63) |
1 |
210,021 (463,016) |
Wet .5978 |
| 21 |
2.45 (355.22) |
.7000 |
22.9 (73.16) |
-85.5 (-36.76) |
1 |
210,021 (463,016) |
Liq 96° |
| 29 |
0.59 (84.93) |
.7000 |
35.0 (95.02) |
350.6 (150.73) |
1 |
210,021 (463,016) |
Wet .6984 |
| 30 |
2.24 (325.22) |
.9740 |
94.9 (202.81) |
1454.0 (625.10) |
.4022 |
84,476 (186,238) |
SatVapor |
| 32 |
1.48 (214.69) |
.9740 |
76.8 (170.19) |
1399.2 (601.53) |
.0535 |
11,236 (24,771) |
Wet .0194 |
| 34 |
0.59 (85.43) |
.9740 |
40.3 (104.60) |
1292.7 (555.75) |
.3487 |
73,240 (161,467) |
Wet .0467 |
| 23 |
• |
Water |
18.0 (64.40) |
75.4 (32.40) |
9.8669 |
2,072,245 (4,568,519) |
|
| 24 |
• |
Water |
28.6 (83.54) |
119.9 (51.54) |
9.8669 |
2,072,245 (4,568,519) |
|
| 25 |
• |
Water |
98.0 (208.40) |
410.3 (176,40) |
5.4766 |
1,150,196 (2,535,750) |
|
| 26 |
• |
Water |
76.4 (169.52) |
319.9 (137.52) |
5.4766 |
1,150,196 (2,535,750) |
|
Table 2
| # |
P Mpa (psiA) |
X |
T°C (°F) |
H KJ/kg (BTU/lb) |
G/G30 |
Flow kg/hr (lb/hr) |
Phase |
| 7 |
2.24 (325.22) |
.5156 |
94.9 (202.81) |
191.4 (82.29) |
.5978 |
125,544 (276,778) |
SatLiquid |
| 8 |
2.10 (305.22) |
.5156 |
76.4 (169.52) |
103.6 (44.55) |
.5978 |
125,544 (276,778) |
Liq 28° |
| 9 |
1.48 (214.19) |
.5156 |
76.4 (169.48) |
103.6 (44.55) |
.5978 |
125,544 (276,778) |
Wet.997 |
| 10 |
1.48 (214.19) |
.5523 |
76.4 (169.52) |
207.5 (89.23) |
.6570 |
137,990 (304,216) |
Wet .921 |
| 11 |
1.34 (194.19) |
.5523 |
37.6 (99.74) |
-69.3 (-29.96) |
.6570 |
137,990 (304,216) |
Liq 53° |
| 12 |
0.59 (85.43) |
.5523 |
37.5 (99.53) |
-69.3 (-29.96) |
.6570 |
137,990 (304,216) |
Wet .9992 |
| 13 |
0.59 (85.43) |
.7000 |
37.6 (99.74) |
404.6 (173.96) |
1 |
210,021 (463,016) |
Wet.6658 |
| 14 |
0.58 (84.43) |
.7000 |
22.4 (72.40) |
-88.7 (-38.12) |
1 |
210,021 (463,016) |
SatLiquid |
| 15 |
2.41 (350.22) |
.7000 |
34.9 (94.74) |
-30.7 (-13.18) |
1 |
210,021 (463,016) |
Liq 73° |
| 16 |
2.31 (335.22) |
.7000 |
73.6 (164.52) |
15.15 (65.13) |
1 |
210,021 (463,016) |
SatLiquid |
| 117 |
2.31 (335.22) |
.7000 |
73.6 (164.52) |
151.5 (65.13) |
.8955 |
210,021 (463,016) |
SatLiquid |
| 17 |
2.24 (325.22) |
.7000 |
95.2 (203.40) |
704.6 (302.92) |
.8955 |
188,068 (414,621) |
Wel.5946 |
| 118 |
2.31 (335.22) |
.7000 |
73.6 (164.52) |
151.5 (65.13) |
.1045 |
210,021 (463,016) |
SatLiquid |
| 18 |
2.24 (325.22) |
.7000 |
92.1 (197.81) |
653.6 (281.00) |
.1045 |
21,952 (48,395) |
Wet.6254 |
| 19 |
2.24 (325.22) |
.7000 |
94.9 (202.81) |
699.2 (300.63) |
1 |
210,021 (463,016) |
Wet .5978 |
| 21 |
2.31 (355.22) |
.7000 |
22.9 (73.16) |
-85.5 (-36.76) |
1 |
210,021 (463,016) |
Liq 96° |
| 29 |
0.59 (84.93) |
.7000 |
35.0 (94.96) |
349.8 (150.38) |
1 |
210,021 (463,016) |
Wet.6989 |
| 30 |
2.24 (325.22) |
.9740 |
94.9 (202.81) |
1454.0 (625.10) |
.4022 |
84,476 (186,238) |
SatVapor |
| 31 |
1.48 (214.69) |
.9740 |
77.0 (170.63) |
1400.5 (602.12) |
.4022 |
84,476 (186,238) |
Wet .0189 |
| 32 |
1.48 (214.69) |
.9224 |
77.0 (170.63) |
1255.9 (539.93) |
.0593 |
11,236 (27,437) |
Wel.1285 |
| 33 |
1.48 (214.69) |
.9829 |
77.0 (170.63) |
1425.5 (612.87) |
.3430 |
72,030 (158,800) |
SatVapor |
| 34 |
0.59 (85.43) |
.9829 |
39.0 (102.18) |
1313.3 (564.60) |
.3430 |
72,030 (158,800) |
Wet.0294 |
| 35 |
1.48 (214.69) |
.5119 |
77.0 (170.63) |
105.7 (45.44) |
.0076 |
1,600 (3,527) |
SatLiquid |
| 23 |
• |
Water |
18.0 (64.40) |
75.4 (32.40) |
9.8666 |
2,072,245 (4,568,371) |
|
| 24 |
• |
Water |
28.6 (83.50) |
119.8 (51.50) |
9.8666 |
2,072,245 (4,568,371) |
|
| 25 |
• |
Water |
98.0 (208.40) |
410.3 (176.40) |
5.4766 |
1,150,196 (2,535,750) |
|
| 26 |
• |
Water |
76.4 (169.52) |
319.9 (137,52) |
5.4766 |
1,150,196 (2,535,750) |
|
Table 3
| # |
P Mpa (psiA) |
X |
T°C (°F) |
H KJ/kg (BTU/1b) |
G/G30 |
Flow kg/hr (lb/hr) |
Phase |
| 10 |
2.01 (291.89) |
.4826 |
95.2 (203.40) |
187.8 (80.72) |
.6506 |
133,576 (294,484) |
SatLiquid |
| 11 |
1.87 (271.89) |
.4826 |
42.8 (109.02) |
-54.8 (-23.56) |
.6506 |
133,576 (294,484) |
Liq 89° |
| 12 |
0.52 (75.35) |
.4826 |
42.8 (109.07) |
-54.8 (-23.56) |
.6506 |
133,576 (294,484) |
Wet .9994 |
| 13 |
0.52 (75.35) |
.6527 |
42.8 (109.02) |
418.7 (180.50) |
1 |
205,317 (452,648) |
Wet .6669 |
| 14 |
0.51 (74.35) |
.6527 |
22.4 (72.40) |
-110.3 (-47.40) |
1 |
205,317 (452,648) |
SatLiquid |
| 15 |
2.18 (316.89) |
.6527 |
40.0 (103.99) |
-28.9 (-12.43) |
1 |
205,317 (452,648) |
Liq 64° |
| 16 |
2.08 (301.89) |
.6527 |
73.6 (164.52) |
128.9 (55.41) |
1 |
205,317 (452,648) |
SatLiquid |
| 17 |
2.01 (291.89) |
.6527 |
95.2 (203.40) |
635.5 (273.22) |
1 |
205,317 (452,648) |
Wet .6506 |
| 21 |
2.22 (321.89) |
.6527 |
22.8 (73.04) |
-107.4 (-46.18) |
1 |
205,317 (452,648) |
Liq 97° |
| 29 |
0.51 (74.85) |
.6527 |
38.2 (100.84) |
341.4 (146.74) |
1 |
205,317 (452,648) |
Wet.7104 |
| 30 |
2.01 (291.89) |
.9693 |
95.2 (203.40) |
1469.2 (631.64) |
.3494 |
71,741 (158,164) |
SatVapor |
| 34 |
0.52 (75.35) |
.9693 |
42.55 (108.59) |
1303.6 (560.44) |
.3494 |
71,741 (158,164) |
Wet .0474 |
| 23 |
• |
Water |
18.0 (64.40) |
75.4 (32.40) |
8.1318 |
1,669,606 (3,680,852) |
|
| 24 |
• |
Water |
31.2 (88.27) |
130.9 (56.27) |
8.1318 |
1,669,606 (3,680,852) |
|
| 25 |
• |
Water |
98 (208.40) |
410.3 (176.40) |
5.6020 |
1,150,196 (2,535,750) |
|
| 26 |
• |
Water |
76.4 (169.52) |
319.9 (137.52) |
5.6020 |
1,150,196 (2,535,750) |
|
Table 4
| # |
P Mpa (psiA) |
X |
T°C (°F) |
H KJ/kg (BTU/lb) |
G/G30 |
Flow kg/hr (lb/hr) |
Phase |
| 10 |
1.48 (214.30) |
.4059 |
95.2 (203.40) |
186.5 (80.05) |
.7420 |
179,411 (395,533) |
SatLiquid |
| 11 |
1.34 (194.30) |
.4059 |
25.4 (77.86) |
-128.6 (-55.30) |
.7420 |
179,411 (395,533) |
Liq 118° |
| 12 |
0.36 (52.48) |
.4059 |
25.7(78.17) |
-128.6 (-55.30) |
.7420 |
179,411 (395,533) |
Liq 32° |
| 29 |
0.36 (52.48) |
.5480 |
40.3 (104.46) |
247.6 (106.44) |
1 |
241,801 (533.080) |
Wet .7825 |
| 14 |
0.36 (51.98) |
.5480 |
22.4 (72.40) |
-139.7 (-60.06) |
1 |
241,801 (533.080) |
SatLiquid |
| 21 |
1.68 (244.30) |
.5480 |
22.7 (72.83) |
-137.6 (-59.16) |
1 |
241,801 (533.080) |
Liq 98° |
| 16 |
1.55 (224.30) |
.5480 |
73.6 (164.52) |
96.0 (41.26) |
1 |
241,801 (533.080) |
SatLiquid |
| 17 |
1.48 (214.30) |
.5480 |
95.2 (203.40) |
526.1 (226.20) |
1 |
241,801 (533.080) |
Wet .742 |
| 30 |
1.48 (214.30) |
.9567 |
95.2 (203.40) |
1503.7 (646.49) |
.2580 |
62,389 (137,546) |
SatVapor |
| 34 |
0.36 (52.48) |
.9567 |
45.7 (114.19) |
1329.4 (571.55) |
.2580 |
62,389 (137,546) |
Wet.0473 |
| 23 |
• |
Water |
18 (64.40) |
75.4 (32.40) |
5.7346 |
1,386,640 (3,057,018) |
|
| 24 |
• |
Water |
34.2 (93.43) |
142.9 (61.43) |
5.7346 |
1,386,640 (3,057,018) |
|
| 25 |
• |
Water |
98 (208.40) |
410.3 (176.40) |
4.7568 |
1,150,197 (2,535,750) |
|
| 26 |
• |
Water |
76.4 (169.52) |
319.9 (137.52) |
4.7568 |
1,150,197 (2,535,750) |
|
Table 5
| Performance Summary KCS34 Case 1 |
| Heat in |
28893.87 kW |
553.08 KJ/kg (237.78 BTU/lb) |
| Heat rejected |
25638.63 kW |
490.76 KJ/kg (210.99 BTU/lb) |
| ∑ Turbine enthalpy drops |
3420.86 kW |
65.48 KJ/kg (28.15 BTU/lb) |
| Turbine Work |
3184.82 kW |
60.96 KJ/kg (26.21 BTU/lb) |
| Feed pump ΔH 1.36, power |
175.97 kW |
3.37 KJ/kg (1.45 BTU/lb) |
| Feed + Coolant pump power |
364.36 kW |
6.978 KJ/kg (3.00 BTU/lb) |
| Net Work |
2820.46 kW |
53.99 KJ/kg (23.21 BTU/lb) |
| |
|
|
| Gross Output |
3184.82 kWe |
|
| Cycle Output |
3008.85 kWe |
|
| Net Output |
2820.46 kWe |
|
| |
|
|
| Net thermal efficiency |
9.76% |
|
| Second law limit |
17.56% |
|
| Second law efficiency |
55.58% |
|
| Specific Brine Consumption |
407.73 kg/kW hr (899.05 1b/kW hr) |
|
| Specific Power Output |
2.45 Watt hr/kg (1.11 Watt hr/lb) |
|
Table 6
| Performance Summary KCS34 Case 2 |
| Turbine mass flow |
58.34 kg/s 463016 lb/hr |
| Pt 30 Volume flow |
4044.45 l/s 514182 ft^3/hr |
| Heat in |
28893.87 kW |
212.93 BTU/lb |
| Heat rejected |
25578.48 kW |
188.50 BTU/lb |
| ∑ Turbine enthalpy drops |
3500.33 kW |
25.80 BTU/lb |
| Turbine Work |
3258.81 kW |
24.02 BTU/lb |
| Feed pump ΔH 1.36, power |
196.51 kW |
1.45 BTU/lb |
| Feed + Coolant pump power |
408.52 kW |
3.01 BTU/lb |
| Net Work |
2850.29 kW |
21.00 BTU/lb |
| Gross Output |
3258.81 kWe |
|
| Cycle Output |
3062.30 kWe |
|
| Net Output |
2850.29 kWe |
|
| Net thermal efficiency |
9.86 % |
|
| Second law limit |
17.74 % |
|
| Second law efficiency |
55.60 % |
|
| Specific Brine Consumption |
889.65 lb/kW hr |
|
| Specific Power Output |
1.12 Watt hr/lb |
|
Table 7
| Performance Summary KCS34 Case 3 |
| Turbine mass flow |
57.03 kg/s 452648 lb/hr |
| Pt 30 Volume flow |
4474.71 l/s 568882 ft^3/hr |
| Heat in |
28893.87 kW |
217.81 BTU/lb |
| Heat rejected |
25754.18 kW |
194.14 BTU/lb |
| ∑ Turbine enthalpy drops |
3300.55 kW |
24.88 BTU/lb |
| Turbine Work |
3072.82 kW |
23.16 BTU/lb |
| Feed pump ΔH 1.21, power |
170.92 kW |
1.29 BTU/lb |
| Feed + Coolant pump power |
341.75 kW |
2.58 BTU/lb |
| Net Work |
2731.07 kW |
20.59 BTU/lb |
| Gross Output |
3072.82 kWe |
|
| Cycle Output |
2901.89 kWe |
|
| Net Output |
2731.07 kWe |
|
| Net thermal efficiency |
9.45 % |
|
| Second law limit |
17.39 % |
|
| Second law efficiency |
54.34 % |
|
| Specific Brine Consumption |
928.48 lb/kW hr |
|
| Specific Power Output |
1.08 Watt hr/lb |
|
| Heat to Steam Boiler |
15851.00 kW |
577.22 BTU/lb |
| Heat Rejected |
10736.96 kW |
390.99 BTU/lb |
Table 8
| Performance Summary KCS34 Case 4 |
| Turbine mass flow |
67.17 kg/s 533080 lb/hr |
| Pt 30 Volume flow |
7407.64 l/s 941754 ft^3/hr |
| Heat in |
28893.87 kW |
184.94 BTU/lb |
| Heat rejected |
26012.25 kW |
166.50 BTU/lb |
| ∑ Turbine enthalpy drops |
3020.89 kW |
19.34 BTU/lb |
| Turbine Work |
2812.45 kW |
18.00 BTU/lb |
| Feed pump ΔH .89, power |
147.99 kW |
0.95 BTU/lb |
| Feed + Coolant pump power |
289.86 kW |
1.86 BTU/lb |
| Net Work |
2522.59 kW |
16.15 BTU/lb |
| Gross Output |
2812.45 kWe |
|
| Cycle Output |
2664.46 kWe |
|
| Net Output |
2522.59 kWe |
|
| Net thermal efficiency |
8.73 % |
|
| Second law limit |
17.02 % |
|
| Second law efficiency |
51.29 % |
|
| Specific Brine Consumption |
1005.22 lb/kW hr |
|
| Specific Power Output |
0.99 Watt hr/lb |
|
1. A method for implementing a thermodynamic cycle comprising:
separating a heated gaseous working stream at a first separator(S)including a low
boiling point component and a higher boiling point component to provide a heated gaseous
rich stream having relatively more of said low boiling point component and a lean
stream having relatively less of said low boiling point component,
expanding said heated gaseous rich stream to transform the energy of the stream into
useable form and to provide an expanded, spent rich stream (34),
combining said lean stream and said expanded, spent rich stream (34)to provide said
working stream,
wherein, after said combining and before said separating, said working stream is condensed
by transferring heat to a low temperature source at a first heat exchanger (HE-1),
and said working stream is thereafter pumped to a higher pressure,
splitting said working stream into a first working substream (117) and a second working
substream (118), and heating said first working substream (117) with an external source
of heat (HE-5) to provide a heated first working substream (17),
characterised in that the method comprises heating the second working substream (118) with heat from said
lean stream thereby producing a heated second working substream (18) having a first
set of thermodynamic characteristics, and
combining said heated first working substream (17) with said heated second working
substream (18) having the first set of thermodynamic characteristics to form the heated
gaseous working stream.
2. A method as claimed in claim 1, further comprising transferring, at a second heat
exchanger (HE-2), heat from said working stream, prior to said working stream being
condensed, to said working stream after said working stream has been pumped to said
higher pressure and prior to said heating with said external source of heat.
3. A method as claimed in claim 2, further comprising transferring, at a third heat exchanger
(HE-3), heat from said lean stream to said working stream after said working stream
has received heat at said second heat exchanger (HE-2) and prior to said splitting.
4. A method as claimed in any one of the preceding claims, wherein said expanding takes
place in a first expansion step and a second expansion step,
said heated gaseous rich stream being partially expanded to provide a partially expanded
rich stream in said first expansion step,
further comprising dividing said partially expanded rich stream into a first portion
and a second portion (34),
wherein said first portion (33)is expanded to provide said expanded, spent rich stream
in said second expansion step, and
further comprising combining said second portion (34) with said lean stream before
said combining of said lean stream and said expanded, spent rich stream.
5. A method as claimed in claim 4, wherein said dividing includes separating said partially
expanded rich stream into a vapor portion and a liquid portion, said first portion
(33) including at least some of said vapor portion, and said second portion (34) including
said liquid portion.
6. A method as claimed in claim 4, further comprising combining some of said vapor portion
with said liquid portion to provide said second portion (34).
7. A method as claimed claim 6, further comprising transferring, at a heat exchanger
(HE-3), heat from said lean stream and said second portion (34) to said working stream
before said working stream has been split into the first working substream (117) and
the second working substream (118).
8. A method as claim in any of the preceding claims, further comprising extracting a
partially expanded stream from a turbine (T) and mixing said partially expanded stream
with said lean stream to produce a mixed lean stream.
9. Apparatus for implementing a thermodynamic cycle comprising:
a separator(S) to divide a heated gaseous working stream including a low boiling point
component and a higher boiling point component, to provide a heated gaseous rich stream
having relatively more of said low boiling point component and a lean stream having
relatively less of said low boiling point component,
an expander that is connected to receive at least a portion of said heated gaseous
working stream and transform the energy of the stream into useable form and to output
an expanded stream,
a mixer that combines said expanded rich stream and said lean stream (12)
a first heat exchanger (HE-1) and a pump that are connected between said expander
and said separator(S), said first heat exchanger (HE-1) condensing said expanded stream
by transferring heat to a low temperature source, and said pump thereafter pumping
said expanded stream to a higher pressure to form the working stream,
a stream splitter (16) connected to split said working stream, after said pumping
into a first working substream (117) and a second working substream (118), a heat
exchanger to heat the first working substream with an external source of heat (HE-5),
a heat exchanger (HE-4) to heat the second working substream with the lean stream
from the separator(s),
a second mixer that combines the first heated working substream with the second working
substream, and
a second heat exchanger (HE-2) connected to transfer heat from said working stream
(13), prior to said working stream being fully condensed , to said working stream
(21) after said working stream has been pumped to said higher pressure at said pump
and prior to said working stream being split at said stream splitter,
characterised in that the heated second working substream has a first set of thermodynamic characteristics,
and that the combined heated first working substream and heated second working substream
having the first set of thermodynamic characteristics form the gaseous working stream.
10. An apparatus as claimed in claim 9 , further comprising a third heat exchanger (HE-3)
connected to transfer heat from said lean stream to said working stream after said
working stream has received heat at said second heat exchanger (HE-2) and prior to
said working stream being split at said stream splitter.
11. The apparatus as claimed in claim 9, wherein said expander includes a first expansion
stage and a second expansion stage,
said first expansion stage being connected to receive said heated gaseous rich stream
and to output a partially expanded rich stream,
further comprising a second separator (S-2) that is connected to receive said partially
expanded rich stream and divide it into a first portion (33) and a second portion
(32),
wherein said second stage is connected to receive said first portion and expands said
first portion to provide said expanded, spent rich stream (34), and
further comprising a third stream mixer that is connected to combine said second portion
(32) with said lean stream before said lean stream is combined with said expanded,
spent rich stream at said first stream mixer.
12. An apparatus as claimed in claim 11, wherein said second separator (S-2) is connected
to receive said partially expanded rich stream and to separate it into a vapor portion
and a liquid portion, said first portion (33) including at least some of said vapor
portion, and said second portion (32) including said liquid portion.
13. An apparatus as claimed in claim 11, wherein said second separator (S-2) includes
a fourth stream mixer connected to combine some of said vapor portion from said second
separator (S-2) with said liquid portion from said second separator (S-2) to provide
said second portion (32).
14. An apparatus as claimed in claim 11, further comprising a heat exchanger (HE-3) connected
to transfer heat from said lean stream and said second portion (32) to said working
stream prior to said working stream being split at said stream splitter.
1. Verfahren zum Implementieren eines thermodynamischen Zyklus, das Folgendes umfasst:
Trennen eines erwärmten, gasförmigen Arbeitsstroms an einer ersten Trennvorrichtung
(S), der eine Komponente mit niedrigem Siedepunkt und eine Komponente mit höherem
Siedepunkt umfasst, um einen erwärmten, gasförmigen fetten Strom mit relativ mehr
der Komponente mit niedrigem Siedepunkt und einen mageren Strom mit relativ weniger
der Komponente mit niedrigem Siedepunkt bereitzustellen,
Expandieren des erwärmten, gasförmigen fetten Stroms, um die Energie des Stroms in
nutzbare Form zu wandeln und einen expandierten, erschöpften fetten Strom (34) bereitzustellen,
Zusammenführen des mageren Stroms und des expandierten, erschöpften fetten Stroms
(34), um den Arbeitsstrom bereitzustellen,
wobei, nach dem Zusammenführen und vor dem Trennen, der Arbeitsstrom kondensiert wird,
indem Wärme an einem ersten Wärmetauscher (HE-1) auf eine Niedertemperaturquelle übertragen
wird und der genannte Arbeitsstrom danach auf einen höheren Druck gepumpt wird,
Spalten des Arbeitsstroms in einen ersten Arbeitsunterstrom (117) und einen zweiten
Arbeitsunterstrom (118), und
Erwärmen des ersten Arbeitsunterstroms (117) mit einer externen Wärmequelle (HE-5),
um einen erwärmten ersten Arbeitsunterstrom (17) bereitzustellen,
dadurch gekennzeichnet, dass das Verfahren das Erwärmen des zweiten Arbeitsunterstroms (118) mit Wärme von dem
mageren Strom umfasst, wodurch ein erwärmter zweiter Arbeitsunterstrom (18) mit einem
ersten Satz von thermodynamischen Eigenschaften erzeugt wird, und
Zusammenführen des erwärmten ersten Arbeitsunterstroms (17) mit dem erwärmten zweiten
Arbeitsunterstrom (18) mit dem ersten Satz von thermodynamischen Eigenschaften, um
den erwärmten, gasförmigen Arbeitsstrom zu bilden.
2. Verfahren nach Anspruch 1, weiter umfassend das Übertragen, an einem zweiten Wärmetauscher
(HE-2), von Wärme von dem Arbeitsstrom, bevor der Arbeitsstrom kondensiert wird, auf
den Arbeitsstrom, nachdem der Arbeitsstrom auf den höheren Druck gepumpt wurde und
vor dem Erwärmen mit der externen Wärmequelle.
3. Verfahren nach Anspruch 2, weiter umfassend das Übertragen, an einem dritten Wärmetauscher
(HE-3), von Wärme von dem mageren Strom auf den Arbeitsstrom, nachdem der Arbeitsstrom
Wärme an dem zweiten Wärmetauscher (HE-2) empfangen hat und vor dem Spalten.
4. Verfahren nach einem der vorangehenden Ansprüche, wobei das Expandieren in einem ersten
Expansionsschritt und einem zweiten Expansionsschritt stattfindet,
wobei der erwärmte, gasförmige fette Strom teilweise expandiert wird, um einen teilweise
expandierten fetten Strom in dem ersten Expansionsschritt bereitzustellen,
weiter umfassend das Teilen des teilweise expandierten fetten Stroms in einen ersten
Anteil und einen zweiten Anteil (34),
wobei der erste Anteil (33) expandiert wird, um den expandierten, erschöpften fetten
Strom in dem zweiten Expansionsschritt bereitzustellen, und
weiter umfassend das Zusammenführen des zweiten Anteils (34) mit dem mageren Strom
vor dem Zusammenführen des mageren Stroms und des expandierten, erschöpften fetten
Stroms.
5. Verfahren nach Anspruch 4, wobei das Teilen das Trennen des teilweise expandierten
fetten Stroms in einen Dampfanteil und einen Flüssiganteil umfasst, wobei der erste
Anteil (33) mindestens einen Teil des Dampfanteils umfasst und der zweite Anteil (34)
den Flüssiganteil umfasst.
6. Verfahren nach Anspruch 4, weiter umfassend das Zusammenführen eines Teils des Dampfanteils
mit dem Flüssiganteil, um den zweiten Anteil (34) bereitzustellen.
7. Verfahren nach Anspruch 6, weiter umfassend das Übertragen, an einem Wärmetauscher
(HE-3), von Wärme von dem mageren Strom und dem zweiten Anteil (34), auf den Arbeitsstrom,
bevor der Arbeitsstrom in den ersten Arbeitsunterstrom (117) und den zweiten Arbeitsunterstrom
(118) gespalten wurde.
8. Verfahren nach einem der vorangehenden Ansprüche, weiter umfassend das Extrahieren
eines teilweise expandierten Stroms von einer Turbine (T) und das Mischen des teilweise
expandierten Stroms mit dem mageren Strom, um einen gemischten mageren Strom zu erzeugen.
9. Vorrichtung zum Implementieren eines thermodynamischen Zyklus, die Folgendes umfasst:
eine Trennvorrichtung (S) zum Trennen eines eine Komponente mit niedrigem Siedepunkt
und eine Komponente mit höherem Siedepunkt umfassenden erwärmten, gasförmigen Arbeitsstroms,
um einen erwärmten, gasförmigen fetten Strom mit relativ mehr der Komponente mit niedrigem
Siedepunkt und einen mageren Strom mit relativ weniger der Komponente mit niedrigem
Siedepunkt bereitzustellen,
eine Expansionsvorrichtung, die dazu angeschlossen ist, mindestens einen Anteil des
erwärmten, gasförmigen Arbeitsstroms zu empfangen und die Energie des Stroms in nutzbare
Form zu wandeln und einen expandierten Strom auszugeben,
eine Mischvorrichtung, die den expandierten fetten Strom und den mageren Strom (12)
zusammenführt,
einen ersten Wärmetauscher (HE-1) und eine Pumpe (P), die zwischen der Expansionsvorrichtung
und der Trennvorrichtung (S) angeschlossen sind, wobei der erste Wärmetauscher (HE-1)
den expandierten Strom kondensiert, indem er Wärme auf eine Niedertemperaturquelle
überträgt und die Pumpe danach den expandierten Strom auf einen höheren Druck pumpt,
um den Arbeitsstrom zu bilden,
einen Stromspalter (16), der dazu angeschlossen ist, den Arbeitsstrom nach dem Pumpen
in einen ersten Arbeitsunterstrom (117) und einen zweiten Arbeitsunterstrom (118)
zu spalten,
einen Wärmetauscher zum Erwärmen des ersten Arbeitsunterstroms mit einer externen
Wärmequelle (HE-5),
einen Wärmetauscher (HE-4) zum Erwärmen des zweiten Arbeitsunterstroms mit dem mageren
Strom von der Trennvorrichtung (S),
eine zweite Mischvorrichtung, die den ersten erwärmten Arbeitsunterstrom mit dem zweiten
Arbeitsunterstrom zusammenführt, und
einen zweiten Wärmetauscher (HE-2), der dazu angeschlossen ist, bevor der Arbeitsstrom
vollständig kondensiert ist, Wärme von dem Arbeitsstrom (13) auf den Arbeitsstrom
(21) zu übertragen, nachdem der Arbeitsstrom an der Pumpe auf einen höheren Druck
gepumpt wurde und bevor der Arbeitsstrom an dem Stromspalter gespalten wird,
dadurch gekennzeichnet, dass der erwärmte zweite Arbeitsunterstrom einen ersten Satz von thermodynamischen Eigenschaften
aufweist und dass der zusammengeführte, erwärmte erste Arbeitsunterstrom und der erwärmte
zweite Arbeitsunterstrom, die den gleichen Satz von thermodynamischen Eigenschaften
aufweisen, den gasförmigen Arbeitsstrom bilden.
10. Vorrichtung nach Anspruch 9, weiter umfassend einen dritten Wärmetauscher (HE-3),
der dazu angeschlossen ist, Wärme von dem mageren Strom auf den Arbeitsstrom zu übertragen,
nachdem der Arbeitsstrom Wärme an dem zweiten Wärmetauscher (HE-2) empfangen hat und
bevor der Arbeitsstrom an dem Stromspalter gespalten wird.
11. Vorrichtung nach Anspruch 9, wobei die Expansionsvorrichtung eine erste Expansionsstufe
und eine zweite Expansionsstufe umfasst,
wobei die erste Expansionsstufe dazu angeschlossen ist, den erwärmten, gasförmigen
fetten Strom zu empfangen und einen teilweise expandierten fetten Strom auszugeben,
weiter umfassend eine zweite Trennvorrichtung (S-2), die dazu angeschlossen ist, den
teilweise expandierten fetten Strom zu empfangen und ihn in einen ersten Anteil (33)
und einen zweiten Anteil (32) zu teilen,
wobei die zweite Stufe dazu angeschlossen ist, den ersten Anteil zu empfangen und
den ersten Anteil expandiert, um den expandierten, erschöpften fetten Strom (34) bereitzustellen,
und
weiter umfassend eine dritte Strommischvorrichtung, die dazu angeschlossen ist, den
zweiten Anteil (32) mit dem mageren Strom zusammenzuführen, bevor der magere Strom
mit dem expandierten, erschöpften fetten Strom an der ersten Strommischvorrichtung
zusammengeführt wird.
12. Vorrichtung nach Anspruch 11, wobei die zweite Trennvorrichtung (S-2) dazu angeschlossen
ist, den teilweise expandierten fetten Strom zu empfangen und ihn in einen Dampfanteil
und einen Flüssiganteil zu trennen, wobei der erste Anteil (33) mindestens einen Teil
der Dampfanteils umfasst und der zweite Anteil (32) den Flüssiganteil umfasst.
13. Vorrichtung nach Anspruch 11, wobei die zweite Trennvorrichtung (S-2) eine vierte
Strommischvorrichtung umfasst, die dazu angeschlossen ist, einen Teil des Dampfanteils
von der zweiten Trennvorrichtung (S-2) mit dem Flüssiganteil von der zweiten Trennvorrichtung
(S-2) zusammenzuführen, um den zweiten Anteil (32) bereitzustellen.
14. Vorrichtung nach Anspruch 11, weiter umfassend einen Wärmetauscher (HE-3), der dazu
angeschlossen ist, Wärme von dem mageren Strom und dem zweiten Anteil (32) auf den
Arbeitsstrom zu übertragen, bevor der Arbeitsstrom an dem Stromspalter gespalten wird.
1. Procédé pour mettre en oeuvre un cycle thermodynamique comprenant les opérations consistant
à :
séparer un flux de travail gazeux chauffé au niveau d'un premier séparateur (S) incluant
un composant à faible point d'ébullition et un composant à point d'ébullition plus
élevé afin de fournir un flux riche gazeux chauffé ayant une quantité relativement
plus importante dudit composant à faible point d'ébullition et un flux pauvre ayant
une quantité relativement moins importante dudit composant à faible point d'ébullition,
effectuer la détente dudit flux riche gazeux chauffé afin de transformer l'énergie
du flux en une forme utilisable, et de fournir un flux riche épuisé détendu (34),
combiner ledit flux pauvre et ledit flux riche épuisé détendu (34) afin de fournir
ledit flux de travail,
dans lequel, après ladite combinaison et avant ladite séparation, ledit flux de travail
est condensé par suite du transfert de chaleur vers une source à basse température
au niveau d'un premier échangeur de chaleur (HE-1), et ledit flux de travail est ensuite
pompé jusqu'à une pression plus élevée,
fractionner ledit flux de travail en un premier sous-flux de travail (117) et en un
deuxième sous-flux de travail (118), et
chauffer ledit premier sous-flux de travail (117) à l'aide d'une source externe de
chaleur (HE-5) afin de fournir un premier sous-flux de travail chauffé (17),
caractérisé en ce que le procédé comprend le chauffage du deuxième sous-flux de travail (118) à l'aide
de la chaleur en provenance dudit flux pauvre, permettant par conséquent de produire
un deuxième sous-flux de travail chauffé (18) ayant un premier ensemble de caractéristiques
thermodynamiques, et
combiner ledit premier sous-flux de travail chauffé (17) avec ledit deuxième sous-flux
de travail chauffé (18) ayant le premier ensemble de caractéristiques thermodynamiques
afin de former le flux de travail gazeux chauffé.
2. Procédé tel que revendiqué dans la revendication 1, comprenant en outre l'opération
consistant à transférer, au niveau d'un deuxième échangeur de chaleur (HE-2), de la
chaleur en provenance dudit flux de travail, avant que ledit flux de travail ne soit
condensé, vers ledit flux de travail après que ledit flux de travail ait été pompé
jusqu'à ladite pression plus élevée et avant ledit chauffage à l'aide de ladite source
externe de chaleur.
3. Procédé tel que revendiqué dans la revendication 2, comprenant en outre l'opération
consistant à transférer, au niveau d'un troisième échangeur de chaleur (HE-3), de
la chaleur en provenance dudit flux pauvre vers ledit flux de travail après que ledit
flux de travail ait reçu de la chaleur au niveau dudit deuxième échangeur de chaleur
(HE-2) et avant ledit fractionnement.
4. Procédé tel que revendiqué dans l'une quelconque des revendications précédentes, dans
lequel ladite détente a lieu dans une première étape de détente et une deuxième étape
de détente,
ledit flux riche gazeux chauffé étant partiellement détendu afin de fournir un flux
riche partiellement détendu dans ladite première étape de détente,
comprenant en outre la division dudit flux riche partiellement détendu en une première
portion et en une deuxième portion (34),
dans lequel ladite première portion (33) est soumise à une détente afin de fournir
ledit flux riche épuisé détendu dans ladite deuxième étape de détente, et
comprenant en outre la combinaison de ladite deuxième portion (34) avec ledit flux
pauvre avant ladite combinaison dudit flux pauvre et dudit flux riche épuisé détendu.
5. Procédé tel que revendiqué dans la revendication 4, dans lequel ladite division inclut
la séparation dudit flux riche partiellement détendu en une portion vapeur et une
portion liquide, ladite première portion (33) incluant au moins une certaine quantité
de ladite portion vapeur, et ladite deuxième portion (34) incluant ladite portion
liquide.
6. Procédé tel que revendiqué dans la revendication 4, comprenant en outre la combinaison
d'une certaine quantité de ladite portion vapeur avec ladite portion liquide afin
de fournir ladite deuxième portion (34).
7. Procédé tel que revendiqué dans la revendication 6, comprenant en outre l'opération
consistant à transférer, au niveau d'un échangeur de chaleur (HE-3), la chaleur en
provenance dudit flux pauvre et de ladite deuxième portion (34) vers ledit flux de
travail avant que ledit flux de travail ne soit fractionné dans le premier sous-flux
de travail (117) et le deuxième sous-flux de travail (118).
8. Procédé tel que revendiqué dans l'une quelconque des revendications précédentes, comprenant
en outre les opérations consistant à extraire un flux partiellement détendu en provenance
d'une turbine (T), et à mélanger ledit flux partiellement détendu avec ledit flux
pauvre afin de produire un flux pauvre mélangé.
9. Appareil pour mettre en oeuvre un cycle thermodynamique comprenant :
un séparateur (S) pour diviser un flux de travail gazeux chauffé incluant un composant
à faible point d'ébullition et un composant à point d'ébullition plus élevé, afin
de fournir un flux riche gazeux chauffé ayant une quantité relativement plus importante
dudit composant à faible point d'ébullition et un flux pauvre ayant une quantité relativement
moins importante dudit composant à faible point d'ébullition,
un dispositif de détente qui est raccordé de façon à recevoir au moins une portion
dudit flux de travail gazeux chauffé et à transformer l'énergie du flux en une forme
utilisable et à délivrer en sortie un flux détendu,
un mélangeur qui combine ledit flux riche détendu et ledit flux pauvre (12),
un premier échangeur de chaleur (HE-1) et une pompe qui sont raccordés entre ledit
dispositif de détente et ledit séparateur (S), ledit premier échangeur de chaleur
(HE-1) condensant ledit flux détendu grâce au transfert de chaleur vers une source
de température faible, et ladite pompe pompant ultérieurement ledit flux détendu jusqu'à
une pression plus élevée afin de former le flux de travail,
un dispositif de fractionnement de flux (16) raccordé de façon à fractionner ledit
flux de travail, après ledit pompage en un premier sous-flux de travail (117) et un
deuxième sous-flux de travail (118), un échangeur de chaleur étant destiné à chauffer
le premier sous-flux de travail à l'aide d'une source externe de chaleur (HE-5),
un échangeur de chaleur (HE-4) pour chauffer le deuxième sous-flux de travail à l'aide
du flux pauvre en provenance du séparateur (S),
un deuxième mélangeur qui combine le premier sous-flux de travail chauffé avec le
deuxième sous-flux de travail, et
un deuxième échangeur de chaleur (HE-2) raccordé de façon à transférer la chaleur
en provenance dudit flux de travail (13), avant que ledit flux de travail ne soit
entièrement condensé, vers ledit flux de travail (21) après que ledit flux de travail
ait été pompé jusqu'à ladite pression plus élevée au niveau de ladite pompe et avant
que ledit flux de travail ne soit fractionné au niveau dudit dispositif de fractionnement
de flux,
caractérisé en ce que le deuxième sous-flux de travail chauffé a un premier ensemble de caractéristiques
thermodynamiques, et que le premier sous-flux de travail chauffé et le deuxième sous-flux
de travail chauffé combinés ayant le premier ensemble de caractéristiques thermodynamiques
forment le flux de travail gazeux.
10. Appareil tel que revendiqué dans la revendication 9, comprenant en outre un troisième
échangeur de chaleur (HE-3) raccordé de façon à transférer la chaleur en provenance
dudit flux pauvre vers ledit flux de travail après que ledit flux de travail ait reçu
de la chaleur au niveau dudit deuxième échangeur de chaleur (HE-2) et avant que ledit
flux de travail ne soit fractionné au niveau dudit dispositif de fractionnement de
flux.
11. Appareil tel que revendiqué dans la revendication 9, dans lequel ledit dispositif
de détente inclut un premier étage de détente et un deuxième étage de détente,
ledit premier étage de détente étant raccordé de façon à recevoir ledit flux riche
gazeux chauffé et à délivrer en sortie un flux riche partiellement détendu,
comprenant en outre un deuxième séparateur (S-2) qui est raccordé de façon à recevoir
ledit flux riche partiellement détendu et à le diviser en une première portion (33)
et en une deuxième portion (32),
dans lequel ledit deuxième étage est raccordé de façon à recevoir ladite première
portion et effectue la détente de ladite première portion afin de fournir ledit flux
riche épuisé détendu (34), et
comprenant en outre un troisième mélangeur de flux qui est raccordé de façon à combiner
ladite deuxième portion (32) avec ledit flux pauvre avant que ledit flux pauvre ne
soit combiné avec ledit flux riche épuisé détendu au niveau dudit premier mélangeur
de flux.
12. Appareil tel que revendiqué dans la revendication 11, dans lequel ledit deuxième séparateur
(S-2) est raccordé de façon à recevoir ledit flux riche partiellement détendu et à
le séparer en une portion vapeur et une portion liquide, ladite première portion (33)
incluant au moins une certaine quantité de ladite portion vapeur, et ladite deuxième
portion (32) incluant ladite portion liquide.
13. Appareil tel que revendiqué dans la revendication 11, dans lequel ledit deuxième séparateur
(S-2) inclut un quatrième mélangeur de flux raccordé de façon à combiner une certaine
quantité de ladite portion vapeur en provenance dudit deuxième séparateur (S-2) avec
ladite portion liquide en provenance dudit deuxième séparateur (S-2) afin de fournir
ladite deuxième portion (32).
14. Appareil tel que revendiqué dans la revendication 11, comprenant en outre un échangeur
de chaleur (HE-3) raccordé de façon à transférer la chaleur en provenance dudit flux
pauvre et de ladite deuxième portion (32) vers ledit flux de travail avant que ledit
flux de travail ne soit fractionné au niveau dudit dispositif de fractionnement de
flux.