(19)
(11) EP 1 944 332 A8

(12) CORRECTED EUROPEAN PATENT APPLICATION
Note: Bibliography reflects the latest situation

(15) Correction information:
Corrected version no 1 (W1 A2)

(48) Corrigendum issued on:
30.06.2010 Bulletin 2010/26

(88) Date of publication A3:
21.10.2009 Bulletin 2009/43

(43) Date of publication:
16.07.2008 Bulletin 2008/29

(21) Application number: 08007363.8

(22) Date of filing: 31.03.2000
(51) International Patent Classification (IPC): 
C08J 7/06(2006.01)
C08J 7/12(2006.01)
(84) Designated Contracting States:
DE FR GB

(30) Priority: 31.03.1999 JP 9103899

(62) Application number of the earlier application in accordance with Art. 76 EPC:
00913042.8 / 1179558

(71) Applicants:
  • National Institute of Advanced Industrial Science and Technology
    Tokyo 100-8921 (JP)
  • DAINICHISEIKA COLOR & CHEMICALS MFG. CO. LTD.
    Chuo-ku, Tokyo 103-8383 (JP)

(72) Inventors:
  • Hiraga, Takashi
    Ideka-shi Osaka 563-8577 (JP)
  • Moriya, Tetsuo
    Amagasaki-shi Hyogo 661-0974 (JP)
  • Chen, Qiying
    Tsukuba-city Ibaraki 305-8562 (JP)
  • Tominaga, Junji
    Tsukuba-city Ibaraki 305-8562 (JP)
  • Atoda, Nobufumi
    Tsukuba-city Ibaraki 305-8562 (JP)
  • Tanaka, N. Dainichiseika C. & Chem. Mfg. Co., Ltd.
    Tokyo 103-8383 (JP)
  • Yanagimoto, H. Dainichiseika C. & Mfg. Co., Ltd.
    Tokyo 103-8383 (JP)
  • Ueno, Ichiro ictor Company of Japan, Ltd.
    Yokohoma-shi Kanagawa 221-8528 (JP)
  • Tsujita, Koji Victor Company of Japan, Ltd.
    Yokohama-shi Kanagawa 221-8528 (JP)

(74) Representative: HOFFMANN EITLE 
Patent- und Rechtsanwälte Arabellastrasse 4
81925 München
81925 München (DE)

 
Remarks:
This application was filed on 15-04-2008 as a divisional application to the application mentioned under INID code 62.
 


(54) Method of modifying surface layer of molded resin


(57) A modification method of the surface layer of a molded resin article which comprises the steps of:
placing, in a first closed space, an organic compound having sublimation properties and an affinity for a resin of a molded resin article to be coated;
on the other hand, placing the molded resin article in a second closed space;
controlling a temperature in the second closed space so as to be equal to or higher than the temperature in the first closed space;
bringing a pressure in the first closed space to a saturated sublimation pressure state of the organic compound;
controlling a pressure in the second closed space so as to be equal to or lower than the pressure in the first closed space;
subsequently, connecting the first closed space to the second closed space to form a third closed space in which the first closed space is combined with the second closed space, and further controlling the temperature and the pressure so that the whole of the third closed space may be in the saturated sublimation pressure state of the organic compound;
allowing a vapor of the organic compound with which the first closed space before the connection is filled to diffuse into the second closed space before the connection;
uniformly depositing the vapor of the organic compound on the surface of the molded resin article; and
allowing the deposited organic compound to penetrate/disperse from the surface of the molded resin article into its inside.