Composition of water-soluble metal working fluid using distillation residue generated in production of biodiesel

Description

BACKGROUND OF THE INVENTION

1. Field of the Invention

[0001] The present invention relates to a water-soluble metalworking fluid used in metal machining, and more particularly, to a composition of a water-soluble metalworking fluid produced by adding 5 to 70wt% of additives to 20 to 95wt% of distillation residues that is generated in production of biodiesel and used as lubricating base oil, and 0 to 40wt% of ion exchange water.

2. Description of the Related Art

[0002] Metalworking fluids are fluids which are used to assist metal machining operations. Traditional metal machining requires a machine tool, a cutting tool, a worked metal, and a machining fluid. Metalworking fluids were first used to increase the lifespan of an instrument for metal processing in the early 1900s. The original metalworking fluids were mainly formed of base oil refined from crude oil, and contained a large amount of polyaromatic hydrocarbons (PAHs) that are now known to be carcinogens due to non-development of refinement techniques. Workers can be exposed to these metalworking fluids via many forms and paths while in use, and the fluids may be a cause of cancer, non-malignant respiratory disease, dermatosis, microbial disease, etc. for the workers. Problems caused by oil mists and metalworking fluids were so significant for industrial health that they were even one of the priorities chosen by the U.S. Occupational Safety and Health Administration (OSHA) in 1996.

[0003] These days, according to the characteristics of metal machining, various kind of metalworking fluids are produced and various kind of additives are used. The amount and composition of the additives depend on the kind of the metalworking fluids and the characteristics of the product.

[0004] The metalworking fluids reduce friction and abrasion between a cutting tool and a worked metal, improve machining surface characteristics, reduce adhesion or melting of the surface, remove generated heat, prevent deformation caused by heat, and wash cut pieces, fine powder and residues. In addition, the metalworking fluids also prevent corrosion of machined surfaces, and cool the heated machined surfaces down so as to be more easily handled.

[0005] Functions of the water-soluble metalworking fluids include cooling, prevention of welding between the cutting tool and the machined surfaces, prevention of abrasion at high temperature, and prevention of distortion caused by remaining heat. The water-soluble metalworking fluids are diluted with a water of about 60 to 85% just before using base oil that is more highly refined than cycloparaffin or paraffin-based oils used in a non-water-soluble environment. Since an available concentration of the water-soluble fluid ranges from 1 to 10%, characteristics of water that is used as a base material are important to performance of the fluid. Water is the best cooling agent due to high specific heat, good thermal conductivity and high latent heat. However, water rusts metal, and thus has less wettability and lubrication than oil. To overcome these disadvantages, the water-soluble metalworking fluids include a rust inhibitor or a surfactant, thereby increasing lubrication. A recently developed additive can prevent corrosion for approximately several days to a week, which thus overcomes the poor rust inhibition and poor metal corrosion inhibition of the water-soluble metalworking fluids.

[0006] The water-soluble metalworking fluids are nonflammable like water and non-sticky, so it is preferred by workers due to a clean work environment, but it is corruptible.

[0007] The advantages of the water-soluble metalworking fluids are as follows. It can be used for fast cutting due to good cooling properties, and cleansing, thereby providing safe conditions for workers. Also, it is economical because of the use of water.

[0008] The water-soluble metalworking fluids are classified into two types, which are an emulsion type which is translucent to an emulsion like a milky liquid when diluted with water, and a semi-synthetic and synthetic type. The milky white residue of the dilution indicates that an emulsion particle has a sufficient size to reflect transmitted light, and the clear dilution indicates that the particle is so small that the transmitted light mostly penetrates between the particles. Components and ratios of the conventional water-soluble metalworking fluids are listed below.

Kind of Additive	Emulsion Type	Semi-Synthetic Type	Synthetic Type
Emulsifier	20 ~ 30%	20 ~ 30 %	-
Lubricating Additive/ Extreme Pressure Additive	0 ~ 40%	0 ~ 10%	0 ~ 30%
pH booster (Amines, etc.)	3 ~ 10%	3 ~ 10%	10 ~ 25%
Metal Corrosion Inhibitor	1 ~ 5%	1 ~ 5%	1 ~ 8%
Preservative	0 ~ 3%	2 ~ 4%	0 ~ 3%
Defoamer	0 ~ 2%	0 ~ 2%	0 ~ 0.5%
Lubricating Base Oil	~ 100%	5 ~ 30%	-
Ion Exchange Water	-	~ 100%	~ 100%

[0009] Recently, as interest in the importance of environmental protection and health and safety for workers has been increasing around the whole world, research on environmentally-acceptable lubricating base oil which will substitute for hydrocarbon-based lubricating base oil among the metalworking fluids is progressing in North American and Western European nations.

[0010] The present invention is directed to developing a composition of a water-soluble metalworking fluid using a distillation residue generated in production of biodiesel as environmentally-friendly lubricating base oil.

[0011] Biodiesel refers to an alternative energy processed from elemental lipid in vegetables and animals to have similar properties to gasoline, which can be used as a diesel equivalent or for diesel engines by being mixed with the gasoline. In general, biodiesel refers to fatty acid methyl esters having a purity of 95% made from the transesterification between alcohols (generally, methanol) and vegetable oil (rice bran, waste cooking oil, soybean oil, rape oil, etc.). (Ministry of Commerce, Industry and Economy (MOCIE) Announcement No. 2000-57)

[0012] The vegetable oil described above, that is, a compound including a hydrophobic group insoluble in water, is generally composed of triglycerides represented as the following chemical structural formula.

[0013] The vegetable oil is commonly characterized by the content of the fatty acid, and the length, content and saturation degree of the fatty acid become critical factors in determining physical and chemical characteristics of the oil. Animal oil is less useful than the vegetable oil, and only that made from a pig, a cow and a sheep among land animals, and herring and menhaden among fishes are considered as being commercially important. The animal oils are composed of saturated and unsaturated triglycerides like the vegetable oils, but include a wide distribution of fatty acids and some odd-numbered chain fatty acids, unlike the vegetable oils.

[0014] When methyl ester made from vegetable oil, that is, biodiesel, is spilled on soil, the soil is less polluted than by hydrocarbon-base lubricating base oil, because of lower toxicity and higher biodegradation. Also, corresponding to United Nations Framework Convention on Climate Change (UNFCCC) (Life cycle CO₂: 1/4 of gasoline), one(1) ton of the methyl ester from vegetable oil cuts 2.2 tons of CO₂, which contributes to an increase in global competitiveness. The methyl ester from vegetable oil is mainly made of methyl oleate and methyl linoleate as main components, and exhibits excellent performance in machinability or detergency due to low viscosity (40 °C, 1.9 to 6.0 cSt.) and good lubrication when used instead of petroleum-based hydrocarbon lubricating base oil.

         CH₃-(CH₂)₁₄-COO-CH₃ : Methyl Palmitate

         CH₃-(CH₂)₆-CH₂-CH=CH-CH₂-(CH₂)₆-COO-CH₃ : Methyl Oleate

         CH₃-(CH₂)₃-CH₂-CH=CH-CH₂-CH=CH-CH₂-(CH₂)₆-COO-CH3 : Methyl Linoleate

[0015] The methyl ester from vegetable oil is made by the following processes.

<Transesterification>

[0016] 

<Esterification>

[0017] 

[0018] Here, R, R' and R" are saturated or unsaturated hydrocarbons with alkyl groups. The methyl ester made from vegetable oil has various components and composition ratios depending on components of fatty acid in the vegetable oil and its ratio. Each of the methyl esters of the fatty acids listed in the following table is a component of the methyl ester made from vegetable oil.

<Chemical Structure of Fatty Acid Used in Water-Soluble Metalworking Fluid and Formation of Methyl Ester Made From Vegetable Oil>

[0019] 

Name of Fatty Acid	Carbon Number/ Double Bond Number	Chemical Structure
Caprylic	C8	CH3(CH2)6COOH
Capric	C10	CH3(CH2)8COOH
Lauric	C12	CH3(CH2)10COOH
Myristric	C14	CH3(CH2)12COOH
Palmitic	C16:0	CH3(CH2)14COOH
Palmitoleic	C16:1	CH3(CH2)5CH=CH(CH2)7COOH
Stearic	C18:0	CH3(CH2)16COOH
Oleic	C18:1	CH3(CH2)7CH=CH(CH2)7COOH
Linoleic	C18:2	CH3(CH2)4CH=CHCH2CH=CH(CH2)7COOH
Linolenic	C18:3	CH3(CH2)2CH=CHCH2CH=CHCH2CH=CH(CH2)7COOH
Arachidic	C20:0	CH3(CH2)18COOH
Eicosenoic	C20:1	CH3(CH2)7CH=CH(CH2)9COOH
Behenic	C22:0	CH3(CH2)20COOH
Erucic	C22:1	CH3(CH2)7CH=CH(CH2)11COOH

[0020] Vegetable oils capable of synthesizing the methyl esters from vegetable oil which may be used in the present invention are listed in the following table.

<Fatty Acid Components of Vegetable Oil Used in Formation of Biodiesel>

[0021] 

Fatty acid, Fatty oil and oil	C8:0	C10:0	C14:0	C16:0	C16:1	C18:0	C18:1	C18:2	C18:3	C20:0 C22:0	C20:1 C22:1
Coconut oil	5-9	4-10	44-51	13-18	7-10	-	1-4	5-8	1-3	-	-	-
Palm Kernal Oil	2-4	3-7	45-52	14-19	6-9	0-1	1-3	10-18	1-2	-	1-2	-
Palm Oil	-	-	-	1-6	32-47	-	1-6	40-52	2-11	-	-	-
Soybean Oil	-	-	-	0.3	7-11	0-1	3-6	22-34	50-60	2-10	5-10	-
Jatropha Oil	-	-	-	35-50	-	0-10	30-40	5-15	-	-	-	-
Canola Oil	-	-	-	-	2-5	0.2	1-2	10-15	10-20	5-10	0.9	50-60

[0022] Biodiesel may be mixed with gasoline and then used, or 100% pure biodiesel may be used. BD5 refers to a mixture of 95% gasoline and 5% biodiesel, and BD20 refers to a mixture including 20% biodiesel. Biodiesel attracts attention around the world as a future energy source in the aspects of recycling of waste resources, reduction of greenhouse gas (CO₂), and low emission of air pollutants. Recently, biodiesel is in exemplary use or is expanding its supply through model projects all over the world. Europe, which is very positive towards the use of alternative energy, first established a system for biodiesel. Europe recognizes that biodiesel can be used within a range satisfying the standard of general gasoline, and according to European Fuel Standard (EN590) taken effect in January, 2004, gasoline including 5% biodiesel or less (BD5) is recognized as general gasoline (satisfying the requirements of the EN14214 standard). In the U.S., after National Biodiesel Board was founded in 1992, the Congress and EPA approved BD20 as a fuel for diesel engine vehicles in 1998, and President Bush declared the expansion of new recycled energy including biodiesel in 2001. According to the active announcement of the government, the supply of biodiesel is increasing every year, and biodiesel is used in official vehicles of state governments and buses in addition to the U.S. Army, the U.S. Air Force, the Department of Energy and NASA. In Korea, based on the announcement regarding a model supply project for biodiesel by MOCCC in May, 2002, the government performed the project for two years, and now is investigating market reaction to and problems with biodiesel. The major advantage of biodiesel is a reduction of smoke emitted from vehicles. Although biodiesel also emits the greenhouse gas CO₂, when viewed from an overall cycle of the process (from production to consumption) it yields very low amounts of CO₂, and emits relatively low amounts of sulfur oxide (Sox) and particulate matters (PMs). Biodiesel made from vegetable resources may be self-produced domestically, which is an advantage for energy security, and may reduce environmental pollution by recycling waste resources, such as waste cooking oil. Also, in the aspect of infrastructure, diesel engine or gas station networks may be used, and thus less additional cost is required. However, although such advantages can be expected, biodiesel has several problems in substituting for conventional gasoline and volatile oils. Although biodiesel has to be mixed in a high ratio to reduce toxic chemicals in exhaust gases from vehicles, it may break down engines due to corrosion, and become denatured in long-term storage.

[0023] For these reasons, high purity products are required for methyl esters made from vegetable oil to be used as fuel oils for vehicles, and thus a separate vacuum distillation process is performed after the reaction of methyl esters. The vacuum distillation is performed at 2 to 3 torrs and a maximum temperature of 240 °C. After the vacuum distillation process, the distilled result is used as biodiesel fuel oil, and a distillation residue of about 10% is scrapped. Such a distillation residue generated in the production of biodiesel is a reactant of the vegetable oil with a structure of ester, and may be used as environmentally friendly lubricating base oil.

SUMMARY OF THE INVENTION

[0024] An embodiment of the invention provides a composition of a water-soluble metalworking fluid which uses a distillation residue generated in production of biodiesel as lubricating oil, and is mixed with other additives. The additives include a surfactant, a lubricating additive, a metal corrosion inhibitor, a rust inhibitor, a pH booster, a defoamer, a preservative, a pigment, etc., of which all are less harmful to the environment, and do not include any one of components which have use restrictions, such as nitrite, formaldehyde, boron and derivatives thereof, and an extreme pressure agent.

[0025] In one aspect, the present invention is directed to a composition of a water-soluble metalworking fluid produced by adding 5 to 70wt% of additives to 20 to 95wt% of distillation residues that is generated in production of biodiesel and used as lubricating base oil, and 0 to 40wt% of ion exchange water. The distillation residue of the biodiesel is generated from canola oil, soybean oil, palm oil or jatropha oil.

[0026] The additive used in the present invention is at least one selected from the group consisting of a surfactant, a lubricating additive, a metal corrosion inhibitor, a rust inhibitor, a pH booster, a defoamer and a preservative. The surfactant used in the present invention is selected from ethoxide of lauryl alcohol or oleyl alcohol, ethoxide of castor oil, ethoxide of laurylamine or oleylamine, amine salt of oleic acid, amine salt of tall oil, amine salt of erucic acid, sulfonate, succinic acid derivatives, amine salt of succinic acid and PEG-fatty acid ester. The lubricating base oil used in the present invention is at least one selected from the group consisting of petroleum-based hydrocarbon, vegetable oil and synthetic ester. Here, the petroleum-based hydrocarbon is a distilled mineral oil and has a kinematic viscosity of about 5 to 1000 cSt at 40 , and the vegetable oil and the synthetic ester are soybean oil, canola oil, sunflower oil, jatropha oil, palm oil, neopentyl glycol dioleate, trimethylolpropane trioleate, pentaerythritol tetraoleate, propylene glycol dioleate, ricinoleic acid condensate, or methyl ester of soybean oil, canola oil, jatropha oil or palm oil. The pH booster used in the present invention includes monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, triisopropanolamine, aminomethyl propanol or diglycolamine. The metal corrosion inhibitor used in the present invention includes benzotriazol, tolytriazol or derivatives thereof. The rust inhibitor used in the present invention includes sebacic acid, dicarboxylic acid, triazine tridicarboxylic acid or derivatives thereof. The defoamer used in the present invention includes polydimethyl siloxane, denatured polydimethyl siloxane, organic silicon derivatives or a silicon-based defoamer of silica. The preservative used in the present invention includes thiazoline, pyridine, morpholine, phenol, a nitro- or IPBC-based preservative.

DETAILED DESCRIPTION OF THE INVENTION

[Exemplary Embodiment 1]

[0027] Water-soluble metalworking fluids were manufactured from a distillation residue generated in production of biodiesel, ion exchange water, a lubricating additive 1 (soybean oil, canola oil, palm oil, trimethylolpropane trioleate, pentaerythritol tetraoleate, or ricinoleic acid condensate), a surfactant, a metal corrosion inhibitor, a rust inhibitor, a pH booster, a defoamer and a preservative.

[0028] Contents of the water and the biodiesel distillation residue depend on application ranges of the product. As the product has a higher content of water, the diluted solution is clearer, while as the product has a higher content of the distillation residue, the diluted solution is milky white and has better lubrication performance.

Table 1. Composition of Water-soluble Metalworking Fluid

Name	S-1	S-2	S-3	S-4	S-5
Biodiesel distillation residue	51.3	67.8	37.3	61.0	91.0
Ion exchange water	17.5	5.0	28.0	9.0	0
Lubricating additive 1	4.5	1.5	6.0	3.5	0.7
Surfactant	15.0	15.6	17.0	16.3	6.3
pH booster	8.0	6.5	8.0	5.5	1.5
Metal corrosion inhibitor	0.5	0.2	0.5	0.5	-
Rust inhibitor	2.0	2.2	2.0	3.0	0.5
Preservative	1.0	1.0	1.0	1.0	-
Defoamer	0.2	0.2	0.2	0.2	-

[Exemplary Embodiment 2]

[0029] Water-soluble metalworking fluids were produced from a distillation residue generated in production of biodiesel, a lubricating additive 2 (petroleum-based hydrocarbon, methyl ester of soybean oil or canola oil, soybean oil, canola oil, or palm oil), a surfactant, a metal corrosion inhibitor, a rust inhibitor, a pH booster, a defoamer and a preservative.

Table 2. Composition of Water-soluble Metalworking Fluid

Name	S-6	S-7	S-8	S-9	S-10
Biodiesel distillation residue	43.0	44.8	25.3	40.8	52.0
Ion exchange water	13.6	10.0	28.5	16.5	0
Lubricating additive 2	18.0	19.5	18.3	12.0	16.0
Surfactant	15.8	15.6	15.7	15.5	20.3
pH booster	6.5	6.5	8.0	11.5	9.0
Metal corrosion inhibitor	0.3	0.2	0.5	0.5	0.1
Rust inhibitor	2.2	2.2	2.0	2.0	.0
Preservative	0.5	1.0	1.5	1.0	0.5
Defoamer	0.1	0.2	0.2	0.2	0.1

[Exemplary Embodiment 3]

[0030] Water-soluble metalworking fluids were produced from a distillation residue generated in production of biodiesel, a lubricating additive 3 (petroleum-based hydrocarbon, methyl ester of soybean oil, canola oil or palm oil, trimethylolpropane trioleate, pentaerythritol tetraoleate or ricinoleic acid condensate), a surfactant, a metal corrosion inhibitor, a rust inhibitor, a pH booster, a defoamer and a preservative.

Table. 3 Composition of Water-soluble Metalworking Fluid

Name	S-11	S-12	S-13	S-14	S-15
Biodiesel distillation residue	23.0	56.8	25.3	39.8	50.0
Ion exchange water	18.6	10.0	32.0	17.5	5.0
Lubricating additive 3	30.8	7.0	14.1	15.0	16.0
Surfactant	16.9	15.2	13.9	13.5	16.3
pH booster	6.5	7.0	10.5	10.5	9.0
Metal corrosion inhibitor	0.3	0.3	0.5	0.5	0.5
Rust inhibitor	2.2	2.5	2.0	2.0	2.0
Preservative	1.5	1.0	1.5	1.0	1.0
Defoamer	0.2	0.2	0.2	0.2	0.2

[Exemplary Embodiment 4]

[0031] Water-soluble metalworking fluids were produced from a distillation residue generated in production of biodiesel, a lubricating additive 4 (methyl ester of soybean oil, canola oil, jatropha oil or palm oil, soybean oil, canola oil, palm oil, jatropha oil or sunflower oil), a surfactant, a metal corrosion inhibitor, a rust inhibitor, a pH booster, a defoamer and a preservative.

Table. 4 Composition of Water-soluble Metalworking Fluid

Name	S-16	S-17	S-18	S-19	S-20
Biodiesel distillation residue	62.3	57.7	42.9	40.0	67.3
Ion exchange water	10.0	10.0	18.0	24.0	0
Lubricating additive 4	4.0	2.5	6.0	5.0	4.0
Surfactant	15.0	16.4	15.7	13.0	20.0
pH booster	6.0	10.0	14.0	14.6	6.0
Metal corrosion inhibitor	0.1	0.2	0.2	0.2	0.1
Rust inhibitor	2.0	2.0	2.0	2.0	2.0
Preservative	0.5	1.0	1.0	1.0	0.5
Defoamer	0.1	0.2	0.2	0.2	0.1

Example 1

[0032] 

Table 5. Characteristics of Water-soluble Metalworking Fluid

Item		S-1	S-2	S-3	S-4	S-5
Color/ Clearness	Crude Liquid	Dark Brown Translucent	Dark Brown Translucent	Brown Translucent	Dark Brown Translucent	Dark Brown Translucent
	Diluted Liquid	White opaque	White opaque	White opaque	White opaque	White opaque
pH (10%)		9.8	9.5	9.7	9.5	9.1
Rust Inhibition		24 hrs	24 hrs	24 hrs	24 hrs	24 hrs

(brix 3 %)		No rust	No rust	No rust	No rust	No rust
Nonferrous Metal discoloration Test (3 %)	Al	None	None	None	None	None
	Cu	None	None	None	None	None

Example 2

[0033] 

Table 6. Characteristics of Water-soluble Metalworking Fluid

Item		S-6	S-7	S-8	S-9	S-10
Color/ Clearness	Crude Liquid	Dark Brown Translucent	Dark Brown Translucent	Brown Translucent	Dark Brown Translucent	Dark Brown Translucent
	Diluted Liquid	White opaque	White opaque	White opaque	White opaque	White opaque
pH (10%)		9.5	9.6	9.5	9.8	9.7
Rust Inhibition (brix 3 %)		24 hrs No rust	24 hrs No rust	24 hrs No rust	24 hrs No rust	24 hrs No rust
Nonferrous Metal discoloration Test (3%)	Al	None	None	None	None	None
	Cu	None	None	None	None	None

Example 3

[0034] 

Table 7. Characteristics of Water-soluble Metalworking Fluid

Item		S-11	S-12	S-13	S-14	S-15
Color/ Clearness	Crude Liquid	Dark Brown Translucent	Dark Brown Translucent	Brown Translucent	Dark Brown Translucent	Dark Brown Translucent
Color/ Clearness	Crude Liquid	Dark Brown Translucent	Dark Brown Translucent	Brown Translucent	Dark Brown Translucent	Dark Brown Translucent
	Diluted Liquid	White opaque	White opaque	White opaque	White opaque	White opaque
pH (10%)		9.4	9.5	9.8	9.8	9.7
Rust Inhibition (brix 3 %)		24 hrs No rust	24 hrs No rust	24 hrs No rust	24 hrs No rust	24 hrs No rust
Nonferrous Metal discoloration Test (3%)	Al	None	None	None	None	None
	Cu	None	None	None	None	None

Example 4

[0035] 

Table 8. Characteristics of Water-soluble Metalworking Fluid

Item		S-16	S-17	S-18	S-19	S-20
Color/ Clearness	Crude Liquid	Dark Brown Translucent	Dark Brown Translucent	Dark Brown Translucent	Dark Brown Translucent	Dark Brown Translucent
	Diluted Liquid	White opaque	White opaque	White opaque	White opaque	White opaque
pH (10%)		9.6	9.6	9.7	9.7	9.4
Rust Inhibition (brix 3 %)		24 hrs No rust	24 hrs No rust	24 hrs No rust	24 hrs No rust	24 hrs No rust
Nonferrous Metal discoloration Test (3%)	Al	None	None	None	None	None
	Cu	None	None	None	None	None

[0036] A composition of a water-soluble metalworking fluid, using a biodiesel distillation residue that can be used as environmentally acceptable lubricating base oil, has good biodegradation, excellent lubrication and less toxicity bionomically. The water-soluble metalworking fluid may be very useful in business and recycling resources.

Claims

1. A composition of a water-soluble metalworking fluid prepared by adding 5 to 70wt% of additives to 20 to 95wt% of distillation residues that is generated in production of biodiesel and used as lubricating base oil, and 0 to 40wt% of ion exchange water.

2. The composition according to claim 1, wherein the distillation residue of the biodiesel is produced from canola oil, soybean oil, palm oil or jatropha oil.

3. The composition according to claim 1, wherein the additive comprises one or more selected from the group consisting of petroleum-based hydrocarbon, vegetable oil and synthetic ester.

4. The composition according to claim 3, wherein the petroleum-based hydrocarbon is a refined mineral oil, and has a kinematic viscosity of 5 to 1000 cSt at 40°C.

5. The composition according to claim 3, wherein the vegetable oil and the synthetic ester comprise:

a lubricating additive selected from the group consisting of soybean oil, canola oil, sunflower oil, jatropha oil, palm oil, neopentyl glycol dioleate, trimethylolpropane trioleate, pentaerythritol tetraoleate, propylene glycol dioleate, ricinoleic acid condensate, and methyl ester of soybean oil, canola oil, jatropha oil or palm oil;

a surfactant selected from the group consisting of ethoxide of lauryl alcohol or oleyl alcohol, ethoxide of castor oil, ethoxide of laurylamine or oleylamine, amine salt of oleic acid, amine salt of tall oil, amine salt of erucic acid, sulfonate, succinic acid derivatives, amine salt of succinic acid and PEG-fatty acid ester,

a pH booster selected from the group consisting of monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, triisopropanolamine, aminiomethyl propanol and diglycolamine;

a metal corrosion inhibitor selected from the group consisting of benzotriazol, tolytriazol and derivatives thereof;

a rust inhibitor selected from the group consisting of sebacic acid, dicarboxylic acid, triazine tridicarboxylic acid and derivatives thereof;

a defoamer selected from the group consisting of polydimethyl siloxane, denatured polydimethyl siloxane, organic silicon derivatives and a silicon-based defoamer of silica; and

a preservative selected from the group consisting of thiazoline, pyridine, morpholine, phenol, nitro- and IPBC-based preservatives.

Ansprüche

1. Zusammensetzung eines wasserlöslichen Metallbearbeitungsfluids, die dadurch zubereitet wird, dass man 5 bis 70 Gew.-% Additive zu 20 bis 95 Gew.-% Destillationsrückständen, die bei der Herstellung von Biodiesel erzeugt werden und als Basisschmieröl verwendet werden, und 0 bis 40 Gew.-% Ionenaustauschwasser zusetzt.

2. Zusammensetzung nach Anspruch 1, bei welcher der Destillationsrückstand des Biodiesels aus Rapsöl, Sojabohnenöl, Palmöl oder Purgiernussöl erzeugt wird.

3. Zusammensetzung nach Anspruch 1, bei der das Additiv eines oder mehrere aufweist, die aus der Gruppe gewählt sind, welche aus Petroleum-basierten Kohlenwasserstoffen, Pflanzenöl und synthetischem Ester besteht.

4. Zusammensetzung nach Anspruch 3, wobei es sich bei den Petroleum-basierten Kohlenwasserstoffen um raffiniertes Mineralöl handelt und sie eine kinematische Viskosität von 5 bis 1000 cSt bei 40°C aufweisen.

5. Zusammensetzung nach Anspruch 3, bei der das Pflanzenöl und der synthetische Ester aufweisen:

ein Schmieradditiv, das aus der Gruppe gewählt ist, die aus Sojabohnenöl, Rapsöl, Sonnenblumenöl, Purgiernussöl, Palmöl, Neopenthyl-glycol-dioleat, Trimethylolpropan-Trioleat, Pentaerythritol-tetraoleat, Propylen-glycol-dioleat, Rizinolsäure-Kondensat und Methylester von Sojabohnenöl, Rapsöl, Purgiernussöl oder Palmöl besteht;

einen oberflächenaktiven Stoff, der aus der Gruppe gewählt ist, die aus Ethoxid von Laurylalkohol oder Oleylalkohol, Ethoxid von Rizinussöl, Ethoxid von Laurylamin oder Oleylamin, Aminsalzen von Ölsäure, Aminsalzen von Tallöl, Aminsalzen von Erucasäure, Sulfonat, Succinylsäurederivaten, Aminsalzen von Succinylsäure und einem PEG-Fettsäureester besteht;

einen pH-Erhöher, der aus der Gruppe gewählt ist, die aus Monoethanolamin, Diethanolamin, Triethanolamin, Monoisopropanolamin, Düsopropanolamin, Triisopropanolamin, Aminomethylpropanol und Diglycolamin besteht;

einen Metallkorrosionshemmer, der aus der Gruppe gewählt ist, die aus Benzotriazol, Tolytriazol und Derivaten von diesen besteht;

einen Rosthemmer, der aus der Gruppe gewählt ist, die aus Sebacinsäure, Dicarbonsäure, Triazin-Tricarbonsäure und Derivaten von diesen besteht;

einen Entschäumer, der aus der Gruppe gewählt ist, die aus Polydimethyl-Siloxan, denaturiertem Polydimethyl-Siloxan, organischen Siliciumderivaten und einem Siliciumbasierten Entschäumer aus Silica besteht; und

einen Konservierungsstoff, der aus der Gruppe gewählt ist, die aus Thiazolin, Pyridin, Morpholin, Phenol, Nitro- und IPBC-basierten Konservierungsstoffen gewählt ist.

Revendications

1. Composition d'un fluide hydrosoluble pour le travail des métaux préparée en ajoutant 5 % à 70 % en poids d'additifs à 20 % à 95 % en poids de résidus de distillation qui sont générés lors de la production de biodiesel et utilisés en tant qu'huile lubrifiante de base, et de 0 % à 40 % en poids d'eau désionisée.

2. Composition selon la revendication 1, dans laquelle le résidu de distillation du biodiesel est produit à partir d'huile de colza, d'huile de soja, d'huile de palme ou d'huile de jatropha.

3. Composition selon la revendication 1, dans laquelle l'additif comprend un ou plusieurs additifs choisis dans le groupe constitué par un hydrocarbure à base de pétrole, une huile végétale et un ester synthétique.

4. Composition selon la revendication 3, dans laquelle l'hydrocarbure à base de pétrole est une huile minérale raffinée et possède une viscosité cinématique de 5 à 1000 cSt à 40 °C.

5. Composition selon la revendication 3, dans laquelle l'huile végétale et l'ester synthétique comprennent :

un additif lubrifiant choisi dans le groupe constitué par l'huile de soja, l'huile de colza, l'huile de tournesol, l'huile de jatropha, l'huile de palme, le dioléate de néopentyle glycol, le trioléate de triméthylolpropane, le tétraoléate de pentaérythritol, le dioléate de propylène glycol, un condensat d'acide ricinoléique et un ester méthylique d'huile de soja, d'huile de colza, d'huile de jatropha ou d'huile de palme ;

un tensioactif choisi dans le groupe constitué par un éthoxyde d'alcool laurique ou d'alcool oléique, un éthoxyde d'huile de ricin, un éthoxyde de laurylamine ou d'oléylamine, un sel d'amine d'acide oléique, un sel d'amine d'huile de tall, un sel d'amine d'acide érucique, un sulfonate, les dérivés de l'acide succinique, un sel d'amine de l'acide succinique et un ester de PEG d'acide gras ;

un élévateur de pH choisi dans le groupe constitué par la monoéthanolamine, la diéthanolamine, la triéthanolamine, la monoisopropanolamine, la diisopropanolamine, la triisopropanolamine, l'aminométhyl propanol et la diglycolamine ;

un inhibiteur de corrosion des métaux choisi dans le groupe constitué par le benzotriazole, le tolytriazole et leurs dérivés ;

un inhibiteur de rouille choisi dans le groupe constitué par l'acide sébacique, un acide dicarboxylique, un acide triazine tridicarboxylique et leurs dérivés ;

un agent antimousse choisi dans le groupe constitué par un polydiméthyl siloxane, un polydiméthyl siloxane dénaturé, les dérivés de silicium organique et un agent antimousse de silice à base de silicium ; et

un conservateur choisi dans le groupe constitué par la thiazoline, la pyridine, la morpholine, le phénol, les conservateurs nitrés et les conservateurs à base d'IPBC.