FIELD OF THE INVENTION
[0001] The present invention relates to tobacco products, such as smoking articles, and
in particular, to cigarettes.
BACKGROUND OF THE INVENTION
[0002] Popular smoking articles, such as cigarettes, have a substantially cylindrical rod
shaped structure and include a charge, roll or column of smokable material, such as
shredded tobacco (e.g., in cut filler form), surrounded by a paper wrapper, thereby
forming a so-called "smokable rod" or "tobacco rod." Normally, a cigarette has a cylindrical
filter element aligned in an end-to-end relationship with the tobacco rod. Typically,
a filter element comprises plasticized cellulose acetate tow circumscribed by a paper
material known as "plug wrap," and is attached to one end of the tobacco rod using
a circumscribing wrapping material known as "tipping paper." It also has become desirable
to perforate the tipping material and plug wrap, in order to provide dilution of drawn
mainstream smoke with ambient air. Descriptions of cigarettes and the various components
thereof are set forth in
Tobacco Production, Chemistry and Technology, Davis et al. (Eds.) (1999). A cigarette is employed by a smoker by lighting one end thereof and burning the
tobacco rod. The smoker then receives mainstream smoke into his/her mouth by drawing
on the opposite end (e.g., the filter end) of the cigarette.
[0003] Numerous references propose various types of cigarettes possessing various types
of paper wrapping materials. See, for example,
U.S. Patent Nos. 1,909,924 to Schweitzer;
4,489,650 to Weinert;
3,030,963 to Cohn;
4,146,040 to Cohn;
4,489,738 to Simon;
4,615,345 to Durocher;
4,607,647 to Dashley;
5,060,675 to Milford et al.;
4,924,888 to Perfetti et al.; 5,143,098 to Rogers et al.; 4,998,543 to Goodman;
5,220,930 to Gentry; and
5,271,419 to Arzonico et al. Some paper wrapping materials are so-called "banded papers" and possess segments
defined by the composition, location and properties of the various materials within
those wrapping materials. Numerous references contain disclosures suggesting various
banded wrapping material configurations. See, for example,
U.S. Patent Nos. 1,996,002 to Seaman;
2,013,508 to Seaman;
4,452,259 to Norman et al.; 5,417,228 to Baldwin et al.; 5,878,753 to Peterson et al., 5,878,754 to Peterson et al.; and
6,198,537 to Bokelman et al.; and
PCT WO 02/37991. Methods for manufacturing banded-type wrapping materials also have been proposed.
See, for example,
U.S. Patent Nos. 4,739,775 to Hampl, Jr.;
5,474,095 to Allen et al.; and
PCT WO 02/44700 and
PCT WO 02/055294. Some references further describe banded papers having segments of paper, fibrous
cellulosic material or particulate material adhered to a paper web. See, for example,
U.S. Patent Nos. 5,191,906 to Myracle, Jr.;
5,263,999 to Baldwin et al.; 5,417,228 to Baldwin et al.; 5,450,863 to Collins et al.; and
6,502,613 to Suzuki. See also
U.S. Patent No. 6,609,999 to Crooks et al.
[0004] Reconstituted tobacco materials have been used as a wrapping material, particularly
as an inner wrapping material (e.g., in regions that are overwrapped with at least
one further layer of wrapping material), and representative reconstituted tobacco
materials useful as wrapping materials for smokable rods are set forth in
U.S. Patent Nos. 5,074,321 to Gentry et al.;
5,159,944 to Arzonico et al.;
5,261,425 to Raker;
5,462,073 to Bowen; and
5,699,812 to Bowen
[0005] Reconstituted tobacco sheets, particularly cast reconstituted tobacco sheets, have
been proposed for use as a discontinuous inner wrapper for a cigarette as a means
for modifying the burn rate of the cigarette. Such sheet materials, smoking articles
made therefrom, and methods of forming such sheet materials are described in
U.S. Patent Nos. 6,705,325 to Hicks et al.; 6,827,087 to Wanna et al.; and
U.S. Patent Application Publication Nos. 2004/0177856 to Monsalud, Jr. et al. and
2005/0056294 to Wanna et al., or
WO 2005/096850.
[0006] It would be desirable to provide a cigarette manufacturer with a manner or method
to produce a cigarette that possesses controlled burn characteristics resulting from
alterations to the wrapping material of the tobacco rod of that cigarette.
SUMMARY OF THE INVENTION
[0007] The present invention provides a cigarette or other smoking article comprising one
or more inner wrapping strips positioned between a tobacco rod and the outer wrapping
material circumscribing the tobacco rod. The inner wrapping strips extend longitudinally
along the tobacco rod and contribute to greater control of the burn characteristics
of the smoking article. The inner wrapping strips comprise a binder in the form of
an alkali metal salt, such as a sodium salt (e.g., sodium alginate or sodium carboxymethyl
cellulose). Further, the inner wrapping strips of the invention comprise a total alkali
metal content of at least about 30,000 µg/g, based on the total weight of the inner
wrapping strips. More preferably, the total alkali metal content is at least about
32,000 µg/g, and most preferably at least about 34,000 or at least about 36,000 µg/g.
It is believed that increases in alkali metal content of the inner wrapping strips
correlate to higher self-extinction rates.
[0008] The binder present in the inner wrapping materials may vary in concentration, but
is typically present in an amount of about 2 to about 40 weight percent, based on
the total weight of the inner wrapping strips. In certain preferred embodiments, the
alkali metal salt binder is present in the amount of about 30 to about 40 weight percent.
[0009] According to the invention, the inner wrapping strips further comprise a second alkali
metal additive, such as a second additive increasing the sodium content or other alkali
metal content. Exemplary alkali metal additives include sodium phosphate, sodium hydroxide,
potassium hydroxide, sodium carbonate, sodium acetate, sodium oxalate, sodium malate,
sodium chloride, and sodium levinulate.
[0010] The smoking articles of the invention preferably exhibit a minimum ignition temperature,
such as an ignition temperature of at least about 625°C. In particularly preferred
embodiments, the ignition temperature of the inner wrapping strips is at least about
650°C or at least about 675°C. It is believed that higher ignition temperatures correlate
to improved ability to meet certain cigarette extinction criteria.
[0011] The smoking articles of the invention may comprise one or more wrapping strip, and
preferably comprise a plurality of inner wrapping strips, each strip having a width
of about 2 to about 10 mm, more preferably a width of about 2 to about 6 mm. In certain
embodiments, the number of inner wrapping strips can be in the range of 1 to about
8, more preferably 2 to about 5.
BRIEF DESCRIPTION OF THE DRAWINGS
[0012] In order to assist the understanding of embodiments of the invention, reference will
now be made to the appended drawings, which are not necessarily drawn to scale. The
drawings are exemplary only, and should not be construed as limiting the invention.
Fig. 1 is an exploded perspective view of a smoking article having the form of a cigarette,
showing the smokable material, the outer wrapping material components, and the filter
element of the cigarette;
Fig. 2 is a perspective view of a smoking article having a the form of a cigarette,
wherein the smoking article includes at least one inner wrapping strip according to
the invention;
Fig. 3 is a cross-sectional view of the cigarette of Fig. 2 taken along line A-A,
the cross-section illustrating the presence of two inner wrapping strips according
to the invention; and
Fig. 4 is a perspective view of an outer wrapping material adapted for circumscribing
a tobacco rod and a plurality of inner wrapping strips placed thereon prior to application
of the wrapping material to a tobacco rod.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0013] The present inventions now will be described more fully hereinafter with reference
to the accompanying drawing. The invention may be embodied in many different forms
and should not be construed as limited to the embodiments set forth herein; rather,
these embodiments are provided so that this disclosure will satisfy applicable legal
requirements. Like numbers refer to like elements throughout. As used in this specification
and the claims, the singular forms "a," "an," and "the" include plural referents unless
the context clearly dictates otherwise.
[0014] Referring to Fig. 1, there is shown a smoking article 10 in the form of a cigarette
and possessing certain representative components of a smoking article of the present
invention. The cigarette 10 includes a generally cylindrical rod 12 of a charge or
roll of smokable filler material contained in a circumscribing wrapping material 16.
The rod 12 is conventionally referred to as a "tobacco rod." The ends of the tobacco
rod 12 are open to expose the smokable filler material. The cigarette 10 is shown
as having one optional band 22 (e.g., a printed coating including a film-forming agent,
such as starch, ethylcellulose, or sodium alginate) applied to the wrapping material
16, and that band circumscribes the cigarette rod in a direction transverse to the
longitudinal axis of the cigarette. That is, the band 22 provides a cross-directional
region relative to the longitudinal axis of the cigarette. The band 22 can be printed
on the inner surface of the wrapping material (i.e., facing the smokable filler material),
or less preferably, on the outer surface of the wrapping material. Although the cigarette
can possess a wrapping material having one optional band, the cigarette also can possess
wrapping material having further optional spaced bands numbering two, three, or more.
[0015] At one end of the tobacco rod 12 is the lighting end 18, and at the other end is
positioned a filter element 20. The filter element 20 is positioned adjacent to one
end of the tobacco rod 12 such that the filter element and tobacco rod are axially
aligned in an end-to-end relationship, preferably abutting one another. Filter element
20 may have a generally cylindrical shape, and the diameter thereof may be essentially
equal to the diameter of the tobacco rod. The ends of the filter element 20 permit
the passage of air and smoke therethrough.
[0016] During use, the smoker lights the lighting end 18 of the cigarette 10 using a match
or cigarette lighter. As such, the tobacco rod 12 begins to burn. The mouth end of
the cigarette 10 is placed in the lips of the smoker. Thermal decomposition products
(e.g., components of tobacco smoke) generated by the burning smokable material are
drawn through the cigarette 10, through the filter element 26, and into the mouth
of the smoker.
[0017] The filter element 20 comprises a filter material 26 circumscribed along its outer
circumference or longitudinal periphery by a layer of outer plug wrap 28. The filter
element 20 may comprise one or more filter segments and may comprise adsorbent materials
therein. The production of filter rods, filter segments and filter elements, and the
manufacture of cigarettes from those filter rods, filter segments and filter elements
can be carried out using the types of rod-forming units that have been employed to
provide cigarette filters, multi-segment cigarette filters and filtered cigarettes.
Multi-segment cigarette filter rods can be manufactured using a cigarette filter rod
making device available under the brand name Mulfi from Hauni-Werke Korber & Co. KG
of Hamburg, Germany. Other representative types of commercially available filter rod
making equipment that can suitably modified for use include the KDF-2 unit available
from Hauni-Werke Korber & Co. KG and the Decoufle unit available from Decoufle of
France.
[0018] A ventilated or air diluted smoking article can be provided with an optional air
dilution means, such as a series of perforations 30, each of which extend through
the plug wrap 28. The optional perforations 30 can be made by various techniques known
to those of ordinary skill in the art, such as laser perforation techniques. Alternatively,
so-called off-line air dilution techniques can be used (e.g., through the use of porous
paper plug wrap and pre-perforated tipping paper).
[0019] The dimensions of a representative cigarette 10 can vary. Preferred cigarettes are
rod shaped, and can have diameters of about 7.5 mm (e.g., circumferences of about
20 mm to about 27 mm, often about 22.5 mm to about 25 mm); and can have total lengths
of about 70 mm to about 120 mm, often about 80 mm to about 100 mm. The length of the
filter element 20 can vary. Typical filter elements can have lengths of about 15 mm
to about 40 mm, often about 20 mm to about 35 mm.
[0020] In the present invention, the cigarette 10 further includes one or more inner wrapping
strips 34 between the tobacco rod and the outer wrapping paper 16, as shown in Fig.
2. The inner wrapping strips 34 preferably extend along the entire length of the tobacco
rod. The inner wrapping strip or strips 34 in the cigarette 10 of the invention can
extend continuously around the entire circumference of the tobacco rod. However, it
is preferable for the inner wrapping strips 34 to be discontinuous. In one embodiment,
the inner wrapping strips 34 comprise 1 to about 8 strips spaced along the periphery
of the tobacco rod. The exact location of the individual wrapping strips 34 may vary,
but is preferable to space one or more of the inner wrapping strips away from the
seam 38 of the cigarette, as shown in Fig. 2.
[0021] A cross-sectional view of Fig. 2 is shown in Fig. 3, where two inner wrapping strips
34 are visible between the tobacco rod 12 and the outer wrapping 16. Fig. 4 illustrates
one embodiment of the invention wherein four inner wrapping strips (designated 34a,
34b, 34c, and 34d) arc utilized. As shown in Fig. 4, prior to placing the outer wrapper
16 around the tobacco rod 12, the inner wrapping strips can be placed at spaced intervals
on a surface of the outer wrapper. The use of inner wrapping strips 34 can be incorporated
into the cigarette manufacturing process using equipment and methods described, for
example, in
U.S. Pat. No. 6,705,325 to Hicks et al.
[0022] The inner wrapping strips 34 are preferably constructed of a reconstituted tobacco
sheet material formed using any of various reconstituted tobacco processes known in
the art, such as paper-making processes and cast sheet processes. Preferred embodiments
of the inner wrapping strips comprise a binder material, a tobacco material, wood
pulp, glycerin, and water. In particular, the preferred embodiments of the inner wrapping
strips 34 comprise about 2 to about 40 percent binder, based on the total weight of
the inner wrapping strips, about 25 to about 65 percent tobacco material (e.g., tobacco
scraps or dust), about 10 to about 15 percent wood pulp, about 13 to about 17 percent
glycerin, and the balance water. If a cast sheet method of production is used, the
binder content will typically be about 10 to about 40 weight percent, more preferably
about 30 to about 40 weight percent. If a paper-making process is utilized, the binder
content could be as low as about 2 to about 5 weight percent.
[0023] Preferably, the reconstituted sheet material used as the inner wrapping material
is constructed using a cast sheet process, such as the process described in
U.S. Patent Application Publication No. 2004/0177856 Monsalud, Jr. et al. The process generally involves forming a mixture having the composition described
above and optionally subjecting the mixture to a heat treatment process, such as by
heating the mixture to a temperature of about 140°F (60°C) to about 200°F (93°C) for
a period of time of about 30 min. to about 60 min. The heating step may further include
an addition of about 1.5 to about 3.5 weight percent potassium hydroxide, based on
the weight of the tobacco material, which can facilitate the release of pectin from
the tobacco material. The release of pectin can be desirable because pectin helps
to maintain adequate cohesiveness within the cast sheet material. Following the optional
heating step and treatment with potassium hydroxide, the reconstituted sheet mixture
is cast on a steel belt and dried to a desired moisture level, such as about 8 to
about 16% moisture. Thereafter, the dried cohesive sheet material can be captured
on a roll and cut into desired widths.
[0024] The width of the inner wrapping strips 34 used in the invention can vary. Typically,
the width of each strip will be between about 2 and about 10 mm, more preferably between
about 2 and about 6 mm. The overall thickness of the inner wrapping materials may
vary, but the inner wrapping strips are typically thicker than the outer wrapper 16.
Exemplary thicknesses range from about 80 to about 120 µm.
[0025] The inner wrapping strips 34 of the invention are characterized by the use of a binder
in the form of an alkali metal salt, such as an alkali metal salt of alginate or a
cellulose derivative (e.g., carboxymethyl cellulose). Examples of alkali metal salt
binder materials include sodium alginate, potassium alginate, sodium carboxymethyl
cellulose and mixtures thereof. The term "alkali metal" is used herein to refer to
metallic elements of Group IA of the Periodic Table of the Elements, including lithium,
sodium, potassium, rubidium, cesium, and francium.
[0026] The use of the alkali metal salt binder contributes to a desired total level of alkali
metal in the inner wrapping strips 34. It is believed that elevated alkali metal content
is desirable in the inner wrapping strips 34 in order to achieve desirable self-extinction
rates according to certain test criteria in smoking articles incorporating the strips.
As indicated by the examples described below, as alkali metal content of the inner
wrapping strips 34 increase, self-extinction rates according to certain test criteria
also increase. Embodiments of the inner wrapping strips 34 of the present invention
exhibit a total alkali metal content of at least about 30,000 µg/g, more preferably
at least about 32,000, most preferably at least about 34,000 or at least about 36,000
µg/g, based on the total weight of the inner wrapping strips. Expressed in terms of
weight percentage based on total weight of the inner wrapping strips, preferred embodiments
contain a total alkali metal content of at least about 3 percent, more preferably
at least about 3.2 percent, most preferably at least about 3.4 or at least about 3.6
weight percent. In one preferred embodiment, the total alkali metal content is about
30,000 to about 50,000 µg/g (about 3 to about 5 weight percent), more preferably about
32,000 to about 40,000 µg/g (about 3.2 to about 4 weight percent).
[0027] The desired total alkali metal content of the inner wrapping strips 34 can be reached
using the alkali metal salt binder alone, but in certain embodiments, the alkali metal
salt binder is supplemented with one or more alkali metal additives that also contribute
alkali metal content to the inner wrapping strips. Exemplary additives include sodium
phosphate, sodium hydroxide, potassium hydroxide, sodium carbonate, sodium acetate,
sodium oxalatc, sodium malatc, sodium chloride, and sodium levinulate. The exact amount
of secondary alkali metal additives added to the inner wrapping strips will vary depending
on the amount of alkali metal salt binder that is present and the desired total alkali
metal content. In one embodiment, the secondary alkali metal additive is present at
a concentration of about 1 to about 20 weight percent, more preferably about 1 to
about 10 weight percent, based on the total weight of the strips 34.
[0028] The inner wrapping strips 34 of the invention preferably exhibit a high ignition
temperature, which is believed to correlate favorably to high self-extinction rates
as measured using certain test criteria described below. In the preferred embodiments,
the inner wrapping strips 34 of the invention exhibit an ignition temperature of at
least about 625°C, more preferably at least about 650°C, and most preferably at least
about 675°C. The examples appended to this application show that inner wrapping materials
34 having higher ignition temperatures also exhibit higher self-extinction rates according
to certain test criteria.
[0029] The overall density of the inner wrapping strips 34 may vary, but typically the basis
weight of the inner wrapping strip is between about 70 to about 125 g/m
2, and preferably about 80 to about 100 g/m
2. The resulting porosity of the inner wrapping strips 34 is typically less than about
10 Coresta, more preferably less than about 8 Coresta, and most preferably less than
about 5 Coresta. The porosity of the inner wrapping strips 34 is preferably very low,
and most preferably, the inner wrapping strips exhibit essentially no gas transport
properties (i.e., a diffusion capacity of essentially zero).
[0031] Certain preferred inner wrapping strips 34 used in carrying out the present invention
are useful for the manufacture of cigarettes designed to exhibit reduced ignition
propensity. That is, cigarettes incorporating certain inner wrapping materials, when
placed on a flammable substrate, tend to self extinguish before burning that substrate.
Of particular interest are those cigarettes possessing tobacco rods manufactured using
an appropriate number and configuration of inner wrapping strips 34, having sufficient
sodium or other alkali metal content, so as to have the ability to meet certain cigarette
extinction criteria. Certain cigarettes of the present invention possessing tobacco
rods manufactured using inner wrapping strips 34 of the present invention, when tested
using the methodology set forth in ASTM E 2187-02b,
Standard Method for Measuring the Ignition Strength of Cigarettes (ASTM Int. 2002), using 10 layers of Whatman No. 2 filter paper, meet criteria requiring
extinction of greater than about 50 percent, preferably greater than about 75 percent,
more preferably greater than about 80 percent, most preferably greater than about
85 percent, and in some cases, greater than about 90 or about 95 percent or even about
100 percent, of cigarettes tested. This percentage is also referred to herein as the
"self-extinction rate."
[0032] Smokable materials and other associated materials useful for carrying out certain
aspects of the present invention can vary. Smokable materials are materials that can
be incorporated into the smokable segment or rod, and provide mass and bulk to some
region within that smokable segment. Smokable materials undergo some type of destruction
during conditions of normal use of the smoking article into which they are incorporated.
Destruction of the smokable material, due at least in part to thermal decomposition
of at least some component of that smokable material, results in the formation of
an aerosol having the form normally characterized as "smoke." For example, smokable
materials incorporating tobacco materials are intended to bum, or otherwise undergo
thermal decomposition, to yield tobacco smoke. The selection of tobacco types and
tobacco blends can determine the chemical composition of, and the sensory and organoleptic
characteristics of, that aerosol produced when that tobacco material or blend of tobacco
materials is burned. The tobacco materials described below can be used in the tobacco
rod 12 portion of the smoking articles of the invention, or as the tobacco portion
of the reconstituted sheet materials used to form the inner wrapping strips 34.
[0033] It is most highly preferred that smokable materials of the smokable segment incorporate
tobacco of some form. Preferred smokable materials are composed predominantly of tobacco
of some form, based on the dry weights of those materials. That is, the majority of
the dry weight of those materials, and the majority of the weight of a mixture incorporating
those materials (including a blend of materials, or materials having additives applied
thereto or otherwise incorporated therein) can be provided by tobacco of some form.
For example, those materials can be processed tobaccos that incorporate minor amounts
non-tobacco filler materials (e.g., calcium carbonate particles, carbonaceous materials,
grains or wood pulp) and/or binding agents (e.g., guar gum, sodium alginate or ammonium
alginate); and/or a blend of those materials can incorporate tobacco substitutes or
extenders. Those materials, and blends incorporating those materials, frequently are
composed of greater than about 70 percent tobacco, often are greater than about 80
percent tobacco, and generally are greater than about 90 percent tobacco, on a dry
weight basis, based on the combined weights of the tobacco, non-tobacco filler material,
and non-tobacco substitute or extender. Those materials also can be composed of virtually
all tobacco material, and not incorporate any non-tobacco fillers, substitutes or
extenders.
[0034] The smokable material can be treated with tobacco additives of the type that are
traditionally used for the manufacture of cigarettes, such as casing and/or top dressing
components. See, for example,
U.S. Patent Nos. 3,419,015 to Wochnowski;
4,054,145 to Berndt et al.;
4,887;619 to Burcham, Jr. et al.;
5,022,416 to Watson;
5,103,842 to Strang et al.; and
5,711,320 to Martin. Typical casing materials include water, sugars and syrups (e.g., sucrose, glucose
and high fructose corn syrup), humectants (e.g. glycerin or propylene glycol), and
flavoring agents (e.g., cocoa and licorice). Those added components also include top
dressing materials (e.g., flavoring materials, such as menthol). See, for example,
U.S. Patent No. 4,449,541 to Mays et al. Additives also can be added to the smokable materials using the types of equipment
described in
U.S. Patent No. 4,995,405 to Lettau, or that are available as Menthol Application System MAS from Kohl Maschinenbau GmbH.
The selection of particular casing and top dressing components is dependent upon factors
such as the sensory characteristics that are desired, and the selection and use of
those components will be readily apparent to those skilled in the art of cigarette
design and manufacture. See,
Gutcho, Tobacco Flavoring Substances and Methods, Noyes Data Corp. (1972) and
Leffingwell et al., Tobacco Flavoring for Smoking Products (1972).
[0035] Smokable materials typically are used in forms, and in manners, that are traditional
for the manufacture of smoking articles, such as cigarettes. Those materials can incorporate
shredded or particulate pieces of tobacco (e.g., as lamina and/or stem), and/or those
materials can be tobacco materials that are in processed forms. For example, those
materials normally are used in cut filler form (e.g., shreds or strands of tobacco
filler cut into widths of about 1/10 inch to about 1/60 inch, preferably about 1/20
inch to about 1/35 inch, and in lengths of about 1/8 inch to about 3 inches, usually
about 1/4 inch to about 1 inch). Alternatively, though less preferred, those materials,
such as processed tobacco materials, can be employed as longitudinally extending strands
or as sheets formed into the desired configuration, or as compressed or extruded pieces
formed into a desired shape.
[0036] Tobacco materials can include, or can be derived from, various types of tobaccos,
such as flue-cured tobacco, burley tobacco, Oriental tobacco or Maryland tobacco,
dark tobacco, dark-fired tobacco and
Rustica tobaccos, as well as other rare or specialty tobaccos, or blends thereof. Descriptions
of various types of tobaccos, growing practices, harvesting practices and curing practices
are set for in
Tobacco Production, Chemistry and Technology, Davis et al. (Eds.) (1999). See, also,
U.S. Pat. Application Publication No. 2004/0084056 to Lawson et al. Most preferably, the tobacco materials are those that have been appropriately cured
and aged.
[0037] Typically, tobacco materials are used in a so-called "blended" form. For example,
certain popular tobacco blends, commonly referred to as "American blends," comprise
mixtures of flue-cured tobacco, burley tobacco and Oriental tobacco. Such blends,
in many cases, contain tobacco materials that have processed forms, such as processed
tobacco stems (e.g., cut-rolled stems, cut-rolled-expanded stems or cut-puffed stems),
volume expanded tobacco (e.g., puffed tobacco, such as dry ice expanded tobacco (DIET),
preferably in cut filler form). Tobacco materials also can have the form of reconstituted
tobaccos (e.g., reconstituted tobaccos manufactured using paper-making type or cast
sheet type processes). Tobacco reconstitution processes traditionally convert portions
of tobacco that normally might be wasted into commercially useful forms. For example,
tobacco stems, recyclable pieces of tobacco and tobacco dust can be used to manufacture
processed reconstituted tobaccos of fairly uniform consistency. The precise amount
of each type of tobacco within a tobacco blend used for the manufacture of a particular
cigarette brand can vary, is a manner of design choice, depending upon factors such
as the sensory characteristics desired. See, for example,
Tobacco Encyclopedia, Voges (Ed.) p. 44-45 (1984),
Browne, The Design of Cigarettes, 3rd Ed., p.43 (1990) and
Tobacco Production, Chemistry and Technology, Davis et al. (Eds.) p. 346 (1999). Various representative tobacco types, processed types of tobaccos, types of tobacco
blends, cigarette components and ingredients, and tobacco rod configurations, also
are set forth in
U.S. Patent Nos. 4,836,224 to Lawson et al.;
4,924,883 to Perfetti et al.;
4,924,888 to Perfetti ct al.;
5,056,537 to Brown ct al.;
5,159,942 to Brinklcy ct al.;
5,220,930 to Gentry;
5,360,023 to Blakley et al.;
5,714,844 to Young et al.;
6,730,832 to Dominguez et al.; and
6,701,936 to Shafer et al.;
U.S. Patent Application Publication Nos. 2003/0075193 to Li et al.;
2003/0131859 to Li et al.;
2004/0084056 to Lawson et al.;
2004/0255965 to Perfetti et al.;
2005/0066984 to Crooks et al.; and
2005/0066986 to Nestor et al.;
PCT WO 02/37990 to Bereman; and
Bombick et al., Fund. Appl. Toxicol., 39, p. 11-17 (1997).
[0038] The outer wrapping material 16 of the tobacco rod 12 can have a wide range of compositions
and properties. The selection of a particular wrapping material will be readily apparent
to those skilled in the art of cigarette design and manufacture. Preferably, the outer
wrapping material is a paper material, such as the type of paper material typically
used in cigarette manufacture. The outer wrapping material can be composed of materials,
or be suitably treated, in order that the wrapping material does not experience a
visible staining as a result of contact with components of the smokable material (e.g.,
aerosol forming material). The porosity of the wrapping material can vary, and frequently
is between about 5 CORESTA units and about 100 CORESTA units, often is between about
10 CORESTA units and about 90 CORESTA units, and frequently is between about 20 CORESTA
units and about 80 CORESTA units. Exemplary types of wrapping materials, wrapping
material components and treated wrapping materials are described in
U.S. Patent Nos. 5,105,838 to White et al.;
5,271,419 to Arzonico et al.;
5,220,930 to Gentry;
6,874,508 to Shafer et al.; and
6,908,874 to Woodhead et al.;
U.S. Pat. Application Publication Nos. 2004/0134631 to Crooks et al.;
2005/0005947 to Hampl, Jr. et al.;
2005/0005947 to Hampl, Jr. et al.;
2005/0016556 to Ashcraft et al.; and
2005/0076929 to Fitzgerald et al.;
PCT WO 01/08514 to Fournier et al.;
WO 03/043450 to Hajaligol et al; and
WO 2005/039326 to Rasouli et al.. Representative wrapping materials are commercially available as R. J. Reynolds Tobacco
Company Grades 119, 170, 419, 453, 454, 456, 465, 466, 490, 525, 535, 557, 652, 664,
672, 676 and 680 from Schweitzer-Maudit International. Colored wrapping materials
(e.g., brown colored papers) can be employed.
[0039] Both the outer wrapping material and the inner wrapping strips may comprise additives
or fillers imbedded or dispersed therein. Exemplary fillers or additives are in the
form of essentially water insoluble particles. The filler or additive materials may
incorporate inorganic components. The fillers or additives may comprise catalysts
or adsorbent materials capable of adsorbing or reacting with vapor phase components
of mainstream smoke. Calcium salts are particularly preferred. One exemplary filler
material has the form of calcium carbonate, and the calcium carbonate most preferably
is used in particulate form. See, for example,
U.S. Pat. No. 4,805,644 to Hampl;
U.S. Pat. No. 5,161,551 to Sanders; and
U.S. Pat. No. 5,263,500 to Baldwin et al.; and
PCT WO 01/48,316. Other filler or additive materials include agglomerated calcium carbonate particles,
calcium tartrate particles, magnesium oxide particles, iron oxide particles, magnesium
hydroxide gels; magnesium carbonate-type materials, clays, diatomaceous earth materials,
titanium dioxide particles, gamma alumina materials and calcium sulfate particles.
The filler can be selected so as to impart certain beneficial characteristics to the
wrapping material, such as modification of combustion properties or the ability to
adjust the character and content of mainstream smoke (e.g., by adsorption of certain
compounds).
[0040] The configuration and content of the filter element 20 can vary. Representative filter
elements can incorporate the types of filter element components, designs and formats
set forth in
Browne, The Design of Cigarettes, 3rd Ed. (1990); Tobacco Production, Chemistry and
Technology, Davis et al. (Eds.) 1999;
US Pat. Nos. 4,508,525 to Berger;
4,807,809 to Pryor et al.;
4,903,714 to Barnes et al.;
4,920,990 to Lawrence et al.;
5,012,829 to Thesing et al.;
5,025,814 to Raker;
5,074,320 to Jones, Jr. et al.;
5,076,295 to Saintsing et al.;
5,101,839 to Jakob et al.;
5,105,834 to Saintsing et al.;
5,105,838 to White et al.;
5,271,419 to Arzonico et al.;
5,137,034 to Perfetti et al.;
5,396,909 to Gentry et al.;
5,595,218 to Koller et al.;
5,718,250 to Banerjee et al.;
6,530,377 to Lesser et al.;
6,615,842 to Cerami et al.;
6,631,722 to MacAdam et al.;
6,792,953 to Lesser et al.; and
6,848,450 to Lilly, Jr. et al.;
U.S. Patent Application Publication Nos. 2004/0261807 to Dube et al.; and
2005/0133052 to Fournier et al.; and
U.S. Pat. Application Serial No. 10/901,662, filed July 29, 2004, to Gonterman et
al. Representative filter materials can be manufactured from tow materials (e.g., cellulose
acetate or polypropylene tow) or gathered web materials (e.g., gathered webs of paper,
reconstituted tobacco, cellulose acetate, polypropylene or polyester).
[0041] The plug wrap 28 can vary. See, for example,
U.S. Patent No. 4,174,719 to Martin. Typically, the plug wrap is a porous or non-porous paper material. Plug wrap materials
arc commercially available. Exemplary porous plug wrap papers arc available from Schweitzer-Maudit
International as Porowrap Plug Wrap 17-M1, 33-M1, 45-M1, 65-M9, 95-M9, 150-M4, 260-M4
and 260-M4T. Non-porous plug wraps exhibit porosities of less than about 10 CORESTA
units, and preferably less than about 5 CORESTA units. Exemplary non-porous plug wrap
papers are available as Ref. No. 646 Grade from Olsany Facility (OP Paprina) of the
Czech Republic (Trierenberg Holding). Plug wrap paper can be coated, particularly
on the surface that faces the filter material, with a layer of a film-forming material.
Such a coating can be provided using a suitable polymeric film-forming agent (e.g.,
ethylcellulose, ethylcellulose mixed with calcium carbonate, or a so-called lip release
coating composition of the type commonly employed for cigarette manufacture). Alternatively,
a plastic film (e.g., a polypropylene film) can be used as a plug wrap material. For
example, non-porous polypropylene materials that are available as ZNA-20 and ZNA-25
from Treofan Germany GmbH & Co. KG can be employed as plug wrap materials.
[0042] For cigarettes of the present invention that are air diluted or ventilated, the amount
or degree of air dilution or ventilation can vary. Frequently, the amount of air dilution
for an air diluted cigarette is greater than about 10 percent, generally is greater
than about 20 percent, often is greater than about 30 percent, and sometimes is greater
than about 40 percent. Typically, the upper level for air dilution for an air diluted
cigarette is less than about 80 percent, and often is less than about 70 percent.
As used herein, the term "air dilution" is the ratio (expressed as a percentage) of
the volume of air drawn through the air dilution means to the total volume and air
and aerosol drawn through the cigarette and exiting the extreme mouth end portion
of the cigarette. Higher air dilution levels can act to reduce the transfer efficiency
of aerosol forming material into mainstream aerosol.
[0043] Preferred cigarettes of the present invention exhibit desirable resistance to draw.
For example, an exemplary cigarette exhibits a pressure drop of between about 50 and
about 200 mm water pressure drop at 17.5 cc/sec. air flow. Preferred cigarettes exhibit
pressure drop values of between about 60 mm and about 180, more preferably between
about 70 mm to about 150 mm, water pressure drop at 17.5 cc/sec. air flow. Typically,
pressure drop values of cigarettes are measured using a Filtrona Cigarette Test Station
(CTS Series) available from Filtrona Instruments and Automation Ltd. or a Quality
Test Module (QTM) available from the Cerulean Division of Molins, PLC.
[0044] Cigarettes of the present invention, when smoked, yield an acceptable number of puffs.
Such cigarettes normally provide more than about 6 puffs, and generally more than
about 8 puffs, per cigarette, when machine smoked under FTC smoking conditions. Such
cigarettes normally provide less than about 15 puffs, and generally less than about
12 puffs, per cigarette, when smoked under FTC smoking conditions. FTC smoking conditions
consist of 35 ml puffs of 2 second duration separated by 58 seconds of smolder.
[0045] Cigarettes of the present invention, when smoked, yield mainstream aerosol. The amount
of mainstream aerosol that is yielded per cigarette can vary. When smoked under FTC
smoking conditions, an exemplary cigarette yields an amount of FTC "tar" that normally
is at least about 1 mg, often is at least about 3 mg, and frequently is at least about
5 mg. When smoked under FTC smoking conditions, an exemplary cigarette yields an amount
of FTC "tar" that normally does not exceed about 20 mg, often does not exceed about
15 mg, and frequently does not exceed about 12 mg.
EXPERIMENTAL
[0046] The following example is provided to illustrate embodiments of the present invention,
and should not be considered to limit the scope thereof. Unless otherwise noted, all
parts and percentages are by weight. In Example 3, coal temperatures of various cigarettes
are measured. Coal temperature of smoking articles are discussed in the art, such
as in
U.S. Patent Application Publication No. 2005/0066986 to Nestor et al.;
The Chemistry of Tobacco and Tobacco Smoke, Schmeltz (ed.) (1972);
Baker, Prog. Ener. Combust. Sci., 7: 135-153 (1981);
Proceedings of the International Conference on the Physical and Chemical Processes
Occurring in a Burning Cigarette (Apr. 26-29, 1987);
Tobacco Production, Chemistry and Technology, Davis et al. (Eds.) p. 398-439 (1999); and
Lyman et al., Beitr. Tabakforsch. Int., 20: 381-388 (2003).
Example 1
[0047] Reconstituted tobacco cast sheet materials with target sodium alginate content ranging
from 15% to 35% are made. Cigarettes are made with each sheet material with two split
inner wrap strips of 4 mm width. The strips are located longitudinally along the tobacco
rod opposite one another and oriented 90 degrees from the side scam. All other cigarette
construction details arc held constant.
[0048] The sheet materials are tested for sodium content and for ignition temperature (as
measured by differential scanning calorimetry). Self-extinction (SE) rates are measured
for finished cigarettes by the ASTM E 2187-02b test procedure (20 cigarettes per test).
The results from these tests are set forth in Table 1 below, and show a fairly strong
correlation between the split inner wrap sodium content and the cigarette self-extinction
rate. That is, as the sodium content increases, self-extinction rates increase. The
results in Table 1 also show a strong correlation between the sodium content and the
ignition temperature of the sheet materials. This suggests that sheets with high ignition
temperatures yield high cigarette self-extinction rates.
Table 1
| Cigarette ID |
Target Binder Content (%) |
Measured Sodium Content (µg/g) |
Sheet Ignition Temperature (°C) |
SE Rate per ASTM Test (%) |
| 1* |
none |
306 |
422 |
45 |
| 2 |
15 |
13650 |
558 |
30 |
| 3 |
15 |
15340 |
575 |
20 |
| 4 |
15 |
17190 |
570 |
50 |
| 5 |
15 |
19590 |
599 |
33 |
| 6 |
15 |
20880 |
603 |
18 |
| 7 |
20 |
21520 |
605 |
15 |
| 8 |
25 |
20170 |
489 |
90 |
| 9 |
25 |
20550 |
617 |
40 |
| 10 |
25 |
24340 |
601 |
80 |
| 11 |
25 |
25390 |
627 |
75 |
| 12 |
25 |
26400 |
639 |
90 |
| 13 |
25 |
26460 |
624 |
48 |
| 14 |
25 |
27190 |
652 |
80 |
| 15 |
25 |
27810 |
619 |
60 |
| 16 |
25 |
34550 |
631 |
90 |
| 17 |
30 |
26070 |
636 |
55 |
| 18 |
30 |
33240 |
686 |
85 |
| 19 |
30 |
38370 |
641 |
53 |
| 20 |
35 |
24580 |
626 |
75 |
| 21 |
35 |
34200 |
649 |
95 |
| 22 |
35 |
37580 |
676 |
100 |
Example 2
[0049] This experiment determines if the "alginate anion" content causes some (or all) of
the self-extinction rate variation found in Example 1. In this experiment, sheet materials
are made with 15% sodium alginate, with additions of 1.5%, 2.5% and 3.5% sodium phosphate.
The resulting materials are tested for sodium content and cigarettes are made as described
above. The results from these tests are set forth in Table 2 below, and show a small
increase in self-extinction rate with the amount of added sodium phosphate. This suggests
that the sodium content of the sheet material is moderating the cigarette self-extinction
rate. Analysis of the sodium content and self-extinction data in Tables 1 and 2 suggests
that the split inner wrap sodium content should exceed about 30,000 µg/g to yield
acceptable cigarette self-extinction rates and, thus, reliably conform to current
regulations for low ignition propensity cigarettes. The requisite sodium content can
be obtained by the use of sodium alginate, another sodium salt, or a combination thereof.
Table 2
| Cigarette ID |
Target Binder Content |
Added Sodium Phosphate |
Measured Sodium Content |
SE Rate per ASTM Test |
| (%) |
(%) |
(µg/g) |
(%) |
| 1 |
15 |
0.0 |
14210 |
-- |
| 2 |
15 |
1.5 |
22280 |
53 |
| 3 |
15 |
2.5 |
25990 |
48 |
| 4 |
15 |
3.5 |
30780 |
68 |
Example 3
[0050] An experiment is conducted to investigate the relationships between cigarette coal
temperatures and the split inner wrap ignition temperature. For this work, six cigarette
examples are chosen for testing, including five from the list shown in Table 1. Three
of these have low self-extinction rates (18% - 30%), and low split inner wrap ignition
temperatures (558°C - 603°C). The other three have high self-extinction rates (85%
- 100%), and high split inner wrap ignition temperatures (649°C - 686°C). A control
cigarette without split inner wrap is also tested.
[0051] Cigarette coal temperatures are measured during smolder while suspended in air, and
while resting on the ASTM test substrate (ten layers of Whatman filter paper) using
a thermal imaging system comprising an infrared camera (Agema Thermovision 900). The
results of these measurements are summarized in Table 3 below. As is evident from
the data in Table 3, the coal temperatures are higher during free-air smolder than
during smolder on the ASTM substrate. This indicates that cigarette contact with the
substrate results in lowered coal temperatures due to either a heat sink effect, reduced
air flow to the coal, or a combination of these effects. During smolder on the ASTM
substrate the coal temperatures of the cigarettes with low self-extinction rates are
98°C - 134°C below the ignition temperatures of the sheet materials. Coal temperatures
of the cigarettes with high self-extinction rates are 234°C - 338°C below the sheet
material ignition temperatures.
[0052] These data suggest that the sheet materials used in the cigarettes with high self-extinction
rates probably do not ignite during smolder. Examination of the ash from the cigarettes
show charred but substantially intact split inner wrap in the examples with high self-extinction
rates. The ash from cigarettes that had low self-extinction rates did not contain
recognizable split inner wrap. This suggests that providing a split inner wrap material
that does not ignite during smolder conditions is important in obtaining high cigarette
self-extinction rates. The data also provide evidence of a strong correlation between
sodium content, ignition temperature, and SE rate.
Table 3
| Sample |
Target Binder Content |
Measured Sodium Content |
Sheet Ignition Temperature |
Average Maximum Coal Temperature |
SE Rate per ASTM Test |
| Free-Air |
ASTM |
| |
(%) |
(µg/g) |
(°C) |
(°C) |
(°C) |
(%) |
| 1* |
N/A |
N/A |
-- |
555 |
471 |
-- |
| 2 |
15 |
13650 |
558 |
558 |
460 |
30 |
| 3 |
15 |
15340 |
575 |
556 |
476 |
20 |
| 4 |
15 |
20880 |
603 |
561 |
469 |
18 |
| 5 |
30 |
33240 |
686 |
496 |
348 |
85 |
| 6 |
-- |
36370 |
649 |
520 |
415 |
93 |
| 7 |
35 |
37580 |
676 |
538 |
366 |
100 |
[0053] Many modifications and other embodiments of the inventions set forth herein will
come to mind to one skilled in the art to which these inventions pertain having the
benefit of the teachings presented in the foregoing descriptions and the associated
drawing. Therefore, it is to be understood that the inventions are not to be limited
to the specific embodiments disclosed and that modifications and other embodiments
are intended to be included within the scope of the appended claims. Although specific
terms are employed herein, they are used in a generic and descriptive sense only and
not for purposes of limitation.
1. A cigarette comprising:
(a) a tobacco rod having a smokable filler material contained within a circumscribing
outer wrapping material; and
(b) one or more inner wrapping strips positioned between said tobacco rod and said
outer wrapping material and extending longitudinally along said tobacco rod,
wherein said one or more inner wrapping strips comprise a binder in the form of an
alkali metal salt and a second alkali metal additive, and wherein said one or more
inner wrapping strips comprise a total alkali metal content of at least about 30,000
µg/g, based on the total weight of the inner wrapping strips.
2. The cigarette of Claim 1, wherein the total alkali metal content of said one or more
inner wrapping strips is at least about 32,000 µg/g, or at least about 34,000 µg/g,
or at least about 36,000 µg/g.
3. The cigarette of Claim 1 or 2, wherein the binder is an alkali metal salt of alginate
or a cellulose derivative or a mixture thereof.
4. The cigarette of Claim 3, wherein the binder is selected from the group consisting
sodium alginate, potassium alginate, sodium carboxymethyl cellulose, and mixtures
thereof.
5. The cigarette of one of Claims 1 to 4, wherein the binder is present in said one or
more inner wrapping strips in an amount of about 2 to about 40 weight percent, based
on the total weight of the inner wrapping strips, or the binder is present in said
one or more inner wrapping strips in an amount of at least about 30 to about 40 weight
percent.
6. The cigarette of one of Claims 1 to 5, wherein the second alkali metal additive is
selected from the group consisting of sodium phosphate, sodium hydroxide, potassium
hydroxide, sodium carbonate, sodium acetate, sodium oxalate, sodium malate, sodium
chloride, and sodium levinulate.
7. The cigarette of one of Claims 1 to 6, wherein the inner wrapping strips have an ignition
temperature of at least about 625°C, or of at least about 650°C, or of at least about
675°C.
8. The cigarette of one of Claims 1 to 7, wherein the inner wrapping strips further comprise
tobacco, wood pulp, glycerin, and water.
9. The cigarette of one of Claims 1 to 8, wherein the inner wrapping strips have a basis
weight of about 70 to about 125 g/m2, or of about 80 to about 100 g/m2.
10. The cigarette of one of Claims 1 to 9, wherein the inner wrapping strips have a porosity
of less than about 10 Coresta.
11. The cigarette of one of Claims 1 to 10, wherein said one or more inner wrapping strips
comprise 1 to 8 strips, each strip having a width of about 2 to about 10 mm, or said
one or more inner wrapping strips comprise 2 to 5 strips, each strip having a width
of about 2 to about 6 mm.
12. The cigarette of one of Claims 1 to 11, further comprising a filter element connected
to the tobacco rod at one end of the tobacco rod.
13. The cigarette of one of Claims 1 to 12, wherein the amount of the alkali metal salt
binder and the second alkali metal additive are selected so as to provide a total
alkali metal content of at least about 32,000 µg/g, based on the total weight of the
inner wrapping strips.
14. The cigarette of one of Claims 1 to 13, wherein said inner wrapping strips comprise
an amount of alkali metal sufficient to enable the cigarette to exhibit a self-extinction
rate of at least 75 percent according to ASTM E 2187-02b.
15. The cigarette of one of Claims 1 to 14, wherein the second alkali metal additive is
present in the inner wrapping strips in an amount of about 1 to about 20 weight percent,
based on the total weight of the inner wrapping strips, or the second alkali metal
additive is present in the inner wrapping strips in an amount of about 1 to about
10 weight percent, based on the total weight of the inner wrapping strips.
1. Zigarette, umfassend:
(a) ein Tabakstäbchen mit einem rauchbaren Füllermaterial, welches innerhalb eines
umschreibenden Außenumhüllungsmaterials enthalten ist; und
(b) einen oder mehrere Innenumhüllungsstreifen, welche zwischen dem Tabakstäbchen
und dem Außenumhüllungsmaterial positioniert sind und sich longitudinal entlang dem
Tabakstäbchen erstrecken,
wobei der eine oder die mehreren Innenumhüllungsstreifen einen Binder in der Form
eines Alkalimetallsalzes und ein zweites Alkalimetalladditiv umfassen und wobei der
eine oder die mehreren Innenumhüllungsstreifen einen Gesamtalkalimetallgehalt von
mindestens ungefähr 30 000 µg/g umfassen, basierend auf dem Gesamtgewicht der Innenumhüllungsstreifen.
2. Zigarette nach Anspruch 1, wobei der Gesamtalkalimetallgehalt des einen oder der mehreren
Innenumhüllungsstreifen mindestens ungefähr 32 000 µg/g oder mindestens ungefähr 34
000 µg/g oder mindestens ungefähr 36 000 µg/g beträgt.
3. Zigarette nach Anspruch 1 oder 2, wobei der Binder ein Alkalimetallsalz von Alginat
oder einem Cellulosederivat oder eine Mischung hiervon ist.
4. Zigarette nach Anspruch 3, wobei der Binder ausgewählt ist aus der Gruppe, welche
aus Natriumalginat, Kaliumalginat, Natriumcarboxymethylcellulose und Mischungen hiervon
besteht.
5. Zigarette nach einem der Ansprüche 1 bis 4, wobei der Binder in dem einen oder in
den mehreren Innenumhüllungsstreifen in einer Menge von ungefähr 2 bis ungefähr 40
Gew.% vorliegt, basierend auf dem Gesamtgewicht der Innenumhüllungsstreifen, oder
wobei der Binder in dem einen oder in den mehreren Innenumhüllungsstreifen in einer
Menge von mindestens ungefähr 30 bis ungefähr 40 Gew.% vorliegt.
6. Zigarette nach einem der Ansprüche 1 bis 5, wobei das zweite Alkalimetalladditiv ausgewählt
ist aus der Gruppe, welche aus Natriumphosphat, Natriumhydroxid, Kaliumhydroxid, Natriumcarbonat,
Natriumacetat, Natriumoxalat, Natriummalat, Natriumchlorid und Natriumlävinulat besteht.
7. Zigarette nach einem der Ansprüche 1 bis 6, wobei die Innenumhüllungsstreifen eine
Zündtemperatur von mindestens ungefähr 625 °C oder von mindestens ungefähr 650 °C
oder von mindestens ungefähr 675 °C aufweisen.
8. Zigarette nach einem der Ansprüche 1 bis 7, wobei die Innenumhüllungsstreifen ferner
Tabak, Holzpulpe, Glycerin und Wasser umfassen.
9. Zigarette nach einem der Ansprüche 1 bis 8, wobei die Innenumhüllungsstreifen ein
Flächengewicht von ungefähr 70 bis ungefähr 125 g/m2 oder von ungefähr 80 bis ungefähr 100 g/m2 aufweisen.
10. Zigarette nach einem der Ansprüche 1 bis 9, wobei die Innenumhüllungsstreifen eine
Porosität von weniger als ungefähr 10 Coresta aufweisen.
11. Zigarette nach einem der Ansprüche 1 bis 10, wobei der eine oder die mehreren Innenumhüllungsstreifen
1 bis 8 Streifen umfassen, wobei jeder Streifen eine Breite von ungefähr 2 bis ungefähr
10 mm aufweist, oder wobei der eine oder die mehreren Innenumhüllungsstreifen 2 bis
5 Streifen umfassen, wobei jeder Streifen eine Breite von ungefähr 2 bis ungefähr
6 mm aufweist.
12. Zigarette nach einem der Ansprüche 1 bis 11, ferner umfassend ein Filterelement, welches
mit dem Tabakstäbchen an einem Ende des Tabakstäbchens verbunden ist.
13. Zigarette nach einem der Ansprüche 1 bis 12, wobei die Menge des Alkalimetallsalzbinders
und des zweiten Alkalimetalladditivs so gewählt ist, dass ein Gesamtalkalimetallgehalt
von mindestens ungefähr 32 000 µg/g, basierend auf dem Gesamtgewicht der Innenumhüllungsstreifen,
bereitgestellt wird.
14. Zigarette nach einem der Ansprüche 1 bis 13, wobei die Innenumhüllungsstreifen eine
Menge an Alkalimetall umfassen, die ausreichend ist, um die Zigarette zu befähigen,
eine Selbstlöschrate von mindestens 75 % nach ASTM E 2187-02b zu zeigen.
15. Zigarette nach einem der Ansprüche 1 bis 14, wobei das zweite Alkalimetalladditiv
in den Innenumhüllungsstreifen in einer Menge von ungefähr 1 bis ungefähr 20 Gew.%
vorliegt, basierend auf dem Gesamtgewicht der Innenumhüllungsstreifen, oder wobei
das zweite Alkalimetalladditiv in den Innenumhüllungsstreifen in einer Menge von ungefähr
1 bis ungefähr 10 Gew.% vorliegt, basierend auf dem Gesamtgewicht der Innenumhüllungsstreifen.
1. Cigarette comprenant :
(a) une tige de tabac ayant un matériau de charge susceptible d'être fumé contenu
à l'intérieur d'un matériau enveloppant externe limitant ; et
(b) une ou plusieurs bandes enveloppantes internes positionnées entre ladite tige
de tabac et ledit matériau enveloppant externe et s'étendant longitudinalement le
long de la tige de tabac,
où lesdites une ou plusieurs bandes enveloppantes internes comprennent un liant sous
la forme d'un sel d'un métal alcalin et un additif en un second métal alcalin et où
lesdites une ou plusieurs bandes enveloppantes internes comprennent une teneur totale
en métal alcalin d'au moins environ 30 000 µg/g, par rapport au poids total des bandes
enveloppantes internes.
2. Cigarette selon la revendication 1, où la teneur totale en métal alcalin desdites
une ou plusieurs bandes enveloppantes internes est d'au moins environ 32 000 µg/g
ou d'au moins environ 34 000 µg/g ou d'au moins environ 36 000 µg/g.
3. Cigarette selon la revendication 1 ou 2, où le liant est un sel de métal alcalin de
type alginate ou un dérivé cellulosique ou un mélange de ceux-ci.
4. Cigarette selon la revendication 3, où le liant est sélectionné dans le groupe constitué
de l'alginate de sodium, l'alginate de potassium, la carboxyméthylcellulose sodique
et leurs mélanges.
5. Cigarette selon l'une quelconque des revendications 1 à 4, où le liant est présent
dans lesdites une ou plusieurs bandes enveloppantes internes en une quantité d'environ
2 à environ 40 % en poids, par rapport au poids total des bandes enveloppantes internes,
ou le liant est présent dans lesdites une ou plusieurs bandes enveloppantes internes
en une quantité d'au moins environ 30 à environ 40 % en poids.
6. Cigarette selon l'une quelconque des revendications 1 à 5, où l'additif en second
métal alcalin est sélectionné dans le groupe constitué du phosphate de sodium, de
l'hydroxyde de sodium, de l'hydroxyde de potassium, du carbonate de sodium, de l'acétate
de sodium, de l'oxalate de sodium, du malate de sodium, du chlorure de sodium et du
lévinulate de sodium.
7. Cigarette selon l'une quelconque des revendication 1 à 6, où les bandes enveloppantes
internes ont une température de calcination d'au moins environ 625°C ou d'au moins
environ 650°C ou d'au moins environ 675°C.
8. Cigarette selon l'une quelconque des revendications 1 à 7, où les bandes enveloppantes
internes comprennent en outre du tabac, de la pulpe de bois, du glycérol et de l'eau.
9. Cigarette selon l'une quelconque des revendications 1 à 8, où les bandes enveloppantes
internes ont un poids de base d'environ 70 à environ 125 g/m2 ou d'environ 80 à environ 100 g/m2.
10. Cigarette selon l'une quelconque des revendications 1 à 9,
où les bandes enveloppantes internes ont une porosité inférieure à environ 10 Coresta.
11. Cigarette selon l'une quelconque des revendications 1 à 10,
où lesdites une ou plusieurs bandes enveloppantes internes comprennent 1 à 8 bandes,
chaque bande ayant une largeur d'environ 2 à environ 10 mm, ou lesdites une ou plusieurs
bandes enveloppantes internes comprennent 2 à 5 bandes, chaque bande ayant une largeur
d'environ 2 à environ 6 mm.
12. Cigarette selon l'une quelconque des revendications 1 à 11, comprenant en outre un
élément filtrant relié à la tige de tabac à une extrémité de la tige de tabac.
13. Cigarette selon l'une quelconque des revendications 1 à 12,
où la quantité de liant de type sel de métal alcalin et l'additif en second métal
alcalin sont sélectionnés de façon à fournir une teneur totale en métal alcalin d'au
moins environ 32 000 µg/g, par rapport au poids total des bandes enveloppantes internes.
14. Cigarette selon l'une quelconque des revendications 1 à 13,
où lesdites bandes enveloppantes internes comprennent une quantité de métal alcalin
suffisante pour permettre à la cigarette de faire preuve d'un taux d'auto-extinction
d'au moins 75 % selon la norme ASTM E 2187-02b.
15. Cigarette selon l'une quelconque des revendications 1 à 14,
où l'additif en second métal alcalin est présent dans les bandes enveloppantes internes
en une quantité d'environ 1 à environ 20 % en poids, par rapport au poids total des
bandes enveloppantes internes, ou l'additif en second métal alcalin est présent dans
les bandes enveloppantes internes en une quantité d'environ 1 à environ 10 % en poids
par rapport au poids total des bandes enveloppantes internes.