[0001] This invention relates to ferrous metallurgy, in particular to devices for steel
refining by rare gas in the pony ladle.
[0002] Known is the device for EBT (external bottom tapping) discharge metal from EAF [1],
where the outlet pot of the EBT in the profile is rectangular oval shaped and has
conidial form.
Known are the schemes and devices for steel refining by rare gas in the pony ladle
[2, 3].
[0003] The period of single portion of metal in pony ladles is extremely limited and insufficient
for effective removal of basic mass of inclusions. Fall in temperature results in
steel self - deoxidation and formation of the sufficient quantity of exogenous nonmetallic
inclusions. At the same time small pieces of lining are washed away by metal convection
current. This leads to formation of exogenous nonmetallic inclusions. Besides, the
whirl metal movement in the form of crater occurs during outflow of the metal stream
from pony ladle above nonswirl nozzle and nonmetallic inclusions and small pieces
of slag are swallowed in. The above known schemes and devices have complex construction
and do not provide competence of outlet of nonmetallic inclusions and small parts
of slag from metal.
[0004] The most similar to the claimed device is the device for metal refining in pony ladle
[4] which contains ceramic tuyere placed in the pony ladle axially to a flow of metal
flowing to the mold and done in such a way as to allow creation of bubbles flow of
rare gas axially to mentioned flow of effluent metal. The mounting of the ceramic
tuyere in the close proximity to the zone of accumulation of nonmetallic inclusions
allows to increase the effectiveness of refining and the curtain of rare gas bubbles
causes certain braking of radial speed in metal flow. However the above-mentioned
device recognized as a prototype does not provide sufficient fall of radial speed
in metal flow flowing through a pony ladle and consequently competence outlet of inclusions
to refining slag is not achieved as the prototype does not disclose the impact of
the geometric form of the inner surface of the tuyere on decrease in radial speed
in the metal flow. Besides according to the prototype the porous insert included to
the tuyere frame for making bubbles flow of rare gas is ring - shaped in sections.
The indicated ring shape is not the best one from the point of view of increasing
the quantity the bubbles of rare gas. Activity of the curtain from rare gas penetrating
into metal can be enhanced by increasing a quantity of bubbles that will consequently
result in further decrease in radial speed in metal flow which is flowing through
the pony ladle.
[0005] The technical result achieved by this device is that maximum outlet of inclusions
to the refining slag is provided.
[0006] The achievement of the technical result allows solving the assigned task by means
of the proposed device for metal refining in the pony ladle containing the tuyere
which is placed axially to the flow of effluent metal and made in such a way as to
allow creation of a flow of rare gas bubble. According to the invention the inner
surface of the receiving cone for metal flowing is configured in the form of rectangular
prism (parallelepiped) converting to a truncated cone. The body of the tuyere is provided
with the porous refractory insert covering the inner surface of the receiving cone
in order to resist the whirl metal movement occurring above nonswirl nozzle. The geometrical
form of the insert in cross section duplicates the form of the inner surface of the
receiving cone for metal flowing.
[0007] According to the invention the body of the tuyere is made predominantly of gas proof
concrete material; the external face of the body of the tuyere in cross cut along
long axis has the form of truncated cone and besides the mentioned body of the tuyere
is supplied with connector with holes (one or more) for rare gas admission.
[0008] The essence of the invention is exposed in the figures.
Fig. 1 discloses the device for metal refining in the pony ladle.
Fig. 2 discloses the scheme for setting the refining device in the pony ladle and
the scheme of rare gas admission.
[0009] The drawings contain the following elements:
- 1 - the body of the tuyere for metal refining; 2 - porous refractory insert; 3 - the
inner surface of the body of the tuyere serving as receiving cone; 4 - the pony ladle;
5 - an effluent flow of metal; 6 - the flow of rare gas bubbles; 7 - the outlets for
rare gas admission; 8 - the nonswirl nozzle.
[0010] The device for metal refining from nonmetallic inclusions and gases contains tuyere,
body 1 of which is made of gas proof refractory material and has the form of a truncated
cone.
The porous refractory setting is placed into the body 2, which allows creating a flow
of rare gas bubbles 6, predominantly argon, with diameter up to 3mm.
[0011] The inner surface 3 of the body of the tuyere serving as a receiving cone is configured
as rectangular prism (parallelepiped), converting to truncated cone to let metal in.
The rectangular prism form of the inner part of device allows to resist metal whirl
movement over the nonswirl nozzle 8.
There are some holes 7 for rare gas admission in the inner part of the body 1 which
is connected with porous refractory insert 2.
Fig.2 represents the variant of mounting the refining device where metal flows to
the pony ladle and farther to the mold.
The mounting the device for metal refining in the pony ladle (as figure 2 represents),
is realized directly close to outgoing metal flow 5 and pony ladle 4 to the mold (figure
2 does not represent), that means the body 1 of the device is mounted in the pony
ladle 4 axially to the flow 5 of metal flowing from pony ladle to the mold.
The functioning of the device is fulfilled in the following way.
The metal flow 5 enters to the inner part of the body of the tuyere 3 acting as a
receiving cone. By means of holes 7 connected with porous mass of refining insert
2 covering the inner surface 3 in the form of rectangular prism, the flow of inputted
rare gas (for example argon) is changing into flow 6 of bubbles penetrating liquid
metal. The rare gas converting in the pony ladle is fulfilled in the bubble flow in
order to prevent exposure of the metal surface.
The refractory insert 2 covering the inner surface 3 has the same form in the cross-section
as the inner surface 3 which is rectangular. During the converting process the inputted
rare gas is heated at the expense of heat loss through the lining of pony ladle.
The principle of refining by rare gas is based on the flotation method that is adhesion
of nonmetallic inclusions to rare gas bubbles and outflow of the inclusions to the
slag.
[0012] The inner part of the device is in the form of rectangular prism (parallelepiped)
allowing resisting metal whirl movements above the nonswirl nozzle and reducing considerably
the kinetic energy of nonmetallic inclusions, excluding entering to the outgoing flow.
That can guarantee maximum flowing out of nonmetallic inclusions by the bubbles of
rare gas to refinery slag.
[0013] The form of refractory insert 2 is also in the form of rectangular prism and duplicates
the form of the inner surface of the tuyere. Such characteristics allow increasing
the quantity of outgoing rare gas bubbles by extending the area of porous mass insert
emitting the flow relative to prototype and as the result to increase effectiveness
of the flotation process.
[0014] The rare gas converting directly before crystallization allows not only to reduce
the quantity of nonmetallic inclusions that are already in metal as well as to prevent
ingress to the ingot of endogenous inclusions which are a result of steel self - deoxidation
by fall in temperature in the pony ladle in the process of casting. Rare gas converting
just prior to crystallization has an additional positive effect which is the decay
of hydrogen content to extremely low values and partial removal of nitrogen according
to Sivert's law
[0015] Argon bubbles contain neither nitrogen nor hydrogen and they are evacuated chambers.
As hydrogen has a high diffusion rate and practically does not come into strong chemical
link in contrast to nitrogen that determines high degree of hydrogen removal. Hydrogen
moves away insignificantly because of low degree of diffusion and property to form
strong chemical bonds with some metals.
1. Device for metal refining in pony ladle containing the tuyere placed axially to flow
of effluent metal and made in such a way as to allow creation of a flow of rare gas
bubble, characterized in that in order to resist whirl metal movements occurring above nonswirl nozzle, the inner
surface of the receiving cone for metal flowing is configured in the form of rectangular
prism converting to truncated cone, creation of rare gas bubbles flow is provided
by a porous refractory insert placed in the body of the tuyere in such a way that
the form thereof in cross section duplicates the form of the inner surface of the
receiving cone.
2. Device for metal refining according to claim 1 characterized in that the body of the tuyere is made of gas proof concrete.
3. Device for metal refining according to claims 1 or 2 characterized in that the external face of the body of the tuyere in cross cut along long axis has the
form of truncated cone.
4. Device for metal refining according to any claims 1 - 3 characterized in that the body of the tuyere is supplied with holes for rare gas admission.
REFERENCES CITED IN THE DESCRIPTION
This list of references cited by the applicant is for the reader's convenience only.
It does not form part of the European patent document. Even though great care has
been taken in compiling the references, errors or omissions cannot be excluded and
the EPO disclaims all liability in this regard.
Patent documents cited in the description
Non-patent literature cited in the description
- G.V. EFIMOVPhysico - Technological Institute of Metals and Ferro-alloys of The Ukraine National
Academy of ScienceThe process of steel refining in a pony ladle, 2001, [0016]
- V. Y. SAKULINV. P. MIGALPublic corporation ''Borovichy refractory plantProduction and application of refractory
devices for steel refining out of furnace. Electrometallurgy, 2003, [0016]