(19)
(11) EP 2 025 660 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
04.03.2009 Bulletin 2009/10

(43) Date of publication A2:
18.02.2009 Bulletin 2009/08

(21) Application number: 08161461.2

(22) Date of filing: 30.07.2008
(51) International Patent Classification (IPC): 
C07C 5/333(2006.01)
C07C 67/38(2006.01)
C07C 5/42(2006.01)
C07C 11/04(2006.01)
(84) Designated Contracting States:
AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR
Designated Extension States:
AL BA MK RS

(30) Priority: 14.08.2007 US 964733 P

(71) Applicant: Rohm and Haas Company
Philadelphia, PA 19106-2399 (US)

(72) Inventors:
  • Benderly, Abraham
    Elkins Park, PA 19027 (US)
  • Han, Scott
    Lawrenceville, NJ 08648 (US)
  • Silvano, Mark, Anthony
    New Hope, PA 18938 (US)
  • Zolotorofe, Donald, Lee
    Ivyland, PA 18974 (US)

(74) Representative: Kent, Venetia Katherine 
Rohm and Haas Europe Services ApS - UK Branch European Patent Department 4th Floor, 22 Tudor Street
London EC4Y 0AY
London EC4Y 0AY (GB)

   


(54) Processes for producing ethylene and carbon monoxide mixtures from ethane


(57) A method for producing a mixture of ethylene and carbon monoxide by contacting ethane and an oxygen source at a temperature of at least 500°C to produce ethylene and carbon monoxide. A method for producing an alkyl propionate by steps of: (a) contacting ethane and an oxygen source at a temperature of at least 500°C to produce ethylene; (b) contacting an alcohol, ethylene and carbon monoxide with an ethylene carbonylation catalyst to produce the alkyl propionate; and (c) separating the alkyl propionate from byproducts and starting materials. The method further comprises condensing the alkyl propionate with formaldehyde to produce an alkyl methacrylate.





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