SOIL REMEDIATION BY TREATING SOIL WITH SURFACTANT FOLLOWED BY ALIPHATIC OR AROMATIC HYDROCARBON

Description

FIELD OF THE INVENTION

[0001] The present invention relates broadly to a method of remediating soil including organic contaminants. The invention relates particularly, although not exclusively, to soil bioremediation and is understood to extend to include remediation of soils, fills, sediments and non-liquid wastes.

BACKGROUND OF THE INVENTION

[0002] In the field of soil bioremediation there are three (3) generally recognised techniques. The first is referred to as biopiling and involves stockpiling contaminated soil, covered in plastic and periodically treating it with air and nutrients via pipes placed within the stockpile. The second of these techniques, known as landfarming, involves spreading the soil or leaving it in-situ and after the addition of nutrients tilling the soil at regular intervals. The last of these known techniques involves composting of the contaminated soil by the addition of organic matter where its temperature and/or surrounding humidity is monitored and the composted material is occasionally turned in line with known techniques.

[0003] Document D1 = NEUMAIER HERMANN and Hans Weber : "ALTLASTEN - Erkennen, Bewerten, Sanieren, Biologische Verfahren", XP002638561 is directed to soil decontamination on site using pits specifically constructed for this purpose. The pits are relatively large and in cross-section usually of a trapezoidal shape of a height ranging from around 0.6 to 2 meters. D1 describes the following steps in the processing of contaminated soil to be treated within the pit: the contaminated soil is mixed with relatively coarse refuse such as soil clumps, stones, and building rubble; this mixture of the contaminated soil is homogenised with an organic or mineral material such as bark, straw, sawdust, sand, or alumina; nutrients and microbe cultures are added to the homogenised mixture of the soil. D1 then discusses the control and regulation of air, water and temperature conditions by forced ventilation, water sprinkling, milling or covering within the pit. The nutrient or microbe supply may also be controlled dependent on results of contaminant analysis. D1 reports a reduction in contaminants of between 80% to 99% within two to 28 months. These results are attributed to three factors, namely: the stripping effect in the soil preparation process; the dilution effect from the addition of loosening material such as the organic or mineral material; rapid biodegradation from the forced ventilation or aeration, homogenisation and surface enlargement by additives such as the nutrients and microbe cultures.

[0004] Document D2 = DE 203 11 607 U1 is directed to a compost process undertaken in an engineered pit. This process includes bioaugmentation where water and microbes are regulated to control a composting process. D2 mentions the use of an agent in mobilizing deposits in for example soil treatment where the agent includes a surfactant.

[0005] Document D3 = EP 0 962 492 A1 is directed to a bioremediation process dependent on the addition of chitin and its derivatives as a biostimulant. The process uses chitin and/or microbes to drive the bioremediation process using bioaugmentation. The chitin of D3 is used as colonising surface and is also useful as a fungicide. The process of D3 is thus based on biostimulation which relies solely on bacteria. D3 also describes a bioreactor used to grow organisms for the bioaugmentation. The process of D3 describes decontamination of soil by the addition of chitin using microbes to control the bioremediation process.

[0006] Document D4 = US 5 593 888 A is directed to a windrow system using a windrow turner. The windrow turner is in the form of a mixing and aerating machine. D4 describes an apparatus for air injection following the addition of "chemical and/or biological amendments" which promote bioremediation of the contaminated material. The chemical amendment exemplified in D4 is a proprietary product used in "the surfactant system of choice for use in petroleum hydrocarbon contaminated soil". The process of D4 operates at relatively low temperatures of between 20 to 30°Celcius relying on "microentractionation" which involves continuous turning and aeration of the treated contaminated soil.

[0007] Document D5 = WO 90/06795 A1 is directed to a process where inorganic contaminants as metal or metal salts or organic contaminants such as PCBs are removed from water-wet soil and sludge whereby a surfactant containing solvent is used to form a dispersed mixture of the solids, contaminants and water whereby the contaminants are extractable into the solvent and then separated from the solvent. In this document, the amount of solvent used is usually between the amount needed for saturation of the solid containing mixture, such as a soil, 500% by weight of the total weight of solid containing mixture being treated or cleaned.

SUMMARY OF THE INVENTION

[0008] According to the present invention there is provided a method as claimed in claim 1.

[0009] It is to be understood that the soil in having a relatively low concentration of the separated organic contaminants is considered fit for use.

[0010] The step of treating the soil with an aliphatic hydrocarbon preferably includes controlled treatment with a hydrocarbon distillate or a derivative or mixture thereof with the range seven to twenty carbon atoms, such as kerosene.

[0011] The method of remediating soil preferably also comprises the step of treating the surfactant treated soil with an alcohol which is effective in increasing the void space of the soil. This can be added to the soil before, during or after the further treatment with the aliphatic or aromatic hydrocarbon.

[0012] The step of treating the soil, according to the invention, with a chemical surfactant involves controlled treatment with natural oils and/or terpenes. This controlled treatment is effective in degrading the bond between some of the organic contaminants and the soil.

[0013] This degradation of the bonds is also effective in liberating the organic contaminants and solubilising aquaphobic organic contaminants.

[0014] The step of stockpiling the soil treated with the chemical surfactant preferably includes a period of between about 1 to about 7 days for gradual miscibilisation of the organic contaminants. More preferably this stockpiling step includes the step of adding organic matter, manure, nutrients and/or soil ameliorants before or after treatment with the chemical surfactant.

[0015] The method of remediating soil preferably further comprises the step of secondary stockpiling of the soil after treatment with the chemical surfactant in the primary stockpiling step. This secondary stockpiling step preferably includes a period of several weeks to several months for gradual degradation of surfactant liberated of the organic contaminants from the soil. This period of secondary stockpiling preferably further includes the step of turning the stockpile approximately every 1 to 6 weeks for aeration and/or homogenisation. More preferably the step of turning the stockpile includes the step of adjusting the level of nutrients and moisture for microbial growth.

[0016] The method preferably still further comprises the step of stockpiling the soil after the further treatment step with the aliphatic or aromatic hydrocarbon. This stockpiling step preferably occurs after resting the soil for a limited period following the step of treating the soil with the chemical surfactant. This stockpiling step preferably includes a period of between about 2 to about 6 weeks for gradual degradation of aliphatic hydrocarbon liberated of the organic contaminants from the soil. This period of stockpiling preferably further comprises the step of turning the stockpile approximately every 1 to 4 weeks for aeration and/or homogenisation. More preferably the level of nutrients and moisture is adjusted for microbial growth during the step of stockpile turning.

[0017] The steps of stockpiling the soil preferably include the step of separating the soil into two or more separate stockpiles.

BRIEF DESCRIPTION OF THE FIGURES

[0018] A preferred embodiment of the present invention will now be described, by way of example only, with reference to the following drawings:

Figure 1 is a schematic flow diagram showing steps, according to a preferred form of the present invention, for soil bioremediation;

Figure 2 is a schematic elevational view of one example of a mobile unit for soil treatment (MUST); and

Figures 3a to 3c are graphs showing degradation in organic contaminants over time for different contaminated soils treated according to the methodology of figure 1.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

[0019] Figure 1 shows a preferred form of a method of soil remediation according to the present invention in the form of soil bioremediation 10 or as coined by the applicant dynamic biopiles. This soil bioremediation 10 method generally comprises the steps of:

(i) 12, treating contaminated soil with a chemical surfactant in a primary treatment stage;

(ii) 16, stockpiling the treated soil in a first maturation period;

(iii) 14, further treating the soil with an aliphatic or aromatic hydrocarbon;

(iv) 17, stockpiling the treated soil in a second maturation period;

(v) 18, continuing the stockpile based remediation, where necessary until remediation criteria is close to being achieved; and

(vi) 20, implementing final soil remediation processes where necessary until remediation criteria is achieved.

[0020] These steps are described in more detail below. The contaminated soil includes organic contaminants including, among other things, polycyclic aromatic hydrocarbons (PAH).

[0021] In order to perform step 12 of treating the soil with a surfactant the soil is excavated from the ground 28 as shown in step 24. The excavated soil 40 is then stockpiled into stockpile 44 which may be covered in a biofilter such as straw, if left exposed for a period of time.

[0022] Soil from the stockpile 44 is ultimately fed into a mobile unit for soil treatment (MUST) 48 by a loader 52. The soil may be screened prior to loading in the MUST 48. The loader 52 may also be used to remove steel and other objects greater than around 30cm square. The MUST 48 performs step 12 to treat the soil with a liquid surfactant 32.

[0023] Referring to figure 2, the MUST 48 generally comprises a raw material hopper 54, a solidifying material hopper 58, a soil cutter 62, a rotary hammer 66, a discharge conveyor belt 70 and an after cutter 74. The MUST 48 also comprises a scraping rotor 78, a raw material measuring sensor 80 and a solidifying material feeder 82. Nutrients and ameliorants such as fertilisers and gympsum may be added into the solidifying material hopper 58. Referring to figure 1, the liquid surfactant 32 is added as the processed soil passes along the discharge conveyor belt 70. The liquid surfactant 32 such as natural oils and terpenes are effective in liberating the contaminates from the soil, 40,so that they can be biodegraded.

[0024] Organic matter such as straw may be added before or after the initial processing in the MUST.

[0025] Material discharged from the MUST 48 is moved by a loader 92 into a primary stockpile 96 for curing the discharged material. The stockpile 96 includes in addition to the discharged material, layers of organic matter, manure, nutrients and/or soil ameliorants. Material discharged by the MUST 48 is cured for a period of time ranging from about 1 to about 7 days.

[0026] Cured soil 100 may then be loaded by a loader 102 onto a MUST or a vibrating coarse screen which mixes the soil prior to its first maturation period 16. During this secondary stockpiling or first maturation period the soil is turned every 1 to 6 weeks and soil and stockpile conditions monitored. The stockpile may be turned 1 to 6 times for a typical maturation or secondary stockpiling period of several weeks to several months. The soil is reloaded into the MUST which performs step 14 by treating the matured soil 100 with an aliphatic or aromatic hydrocarbon which, in this particular example, comprises a hydrocarbon distillate such as kerosene 108. The soil may also be treated with an alcohol such as ethanol which increases the void space of the soil by swelling of the organic matter.

[0027] The hydrocarbon distillate 108 in this second maturation period at least partially separates more tightly held of the organic contaminants of the soil allowing further biodegradation. Separation of the organic contaminants from the soil is facilitated by step 17 which involves further stockpiling of the soil 101 into stockpiles 113. Loader 115 forms the stockpiles 113.

[0028] Soil 101 rests for a limited period (say 3 to5 weeks) before it is stockpiled in the stockpiles 113 for a period of time ranging from about 2 to about 6 weeks. Stockpiles 113 are turned every 1 to 6 weeks during this second maturation period to aerate the soil.

[0029] Soil of the stockpiles 113 is also further treated throughout the maturation periods as appropriate. For example, soil may be reprocessed by the MUST 104. Any observable residual contaminant lumps such as tar lumps are returned for reprocessing through the MUST 104. Reprocessed material is then incorporated into the stockpiles 113 or 112 to undergo maturation, or a portion thereof.

[0030] During the maturation period(s) the organic contaminants such as PAH and total petroleum hydrocarbons (TPH) are measured along with process parameters such as temperature and moisture. These measurements are assessed against soil remediation criteria. Once the concentrations are approaching those required, soil from the stockpiles 112 or 113 is returned to the site 120 from where it was excavated.

[0031] When the addition of liquid bond breakers (surfactants, distillate and/or alcohol) is no longer having any effect the stockpiles are knocked flat. If the remediation criteria has not been achieved a polishing phase involving phytoremediation is necessary. Continued bioremediation is facilitated by tilling 124 with seed and distillate and cropping 128. Cropping 128 comprises, for example, sowing of green fodder or a crop, including rye grass, canola and oats. Following sowing the soil is kept moist. Fertiliser can be added when the soil is tilled During the tilling and cropping steps the soil is routinely tested until the soil remediation criteria is achieved. Degradation of the those remaining organic contaminants, which are difficult to access is achieved by the root exudates and root microbes associated with certain crops and grasses. The soil is then no longer required to be tilled or cropped specifically for remediation purposes and can be returned to the excavation 120.

[0032] Figures 3a to 3c graphically represent different contaminated soils and the degradation of organic contaminants, in this example PAHs of various ring lengths, following treatment with surfactants and solvents in accordance with the preferred methodology of the invention. During this treatment period, it can be clearly seen that the concentrations of PAH reduce with addition of the chemical surfactant, and then reduce further with the addition of the aliphatic or aromatic hydrocarbon in the form of the preferred solvent, and optionally alcohol.

[0033] Soil bioremediation 10 such as that depicted in figure 1 provides advantages over traditional soil bioremediation techniques including:

(a) improving the rate of remediation;

(b) improving the effectiveness of remediation by decreasing concentrations of PAH; and

(c) enabling soil contaminated with lower bioavailable PAH to be more effectively remediated.

Claims

1. A method (10) of remediating soil (40) including organic contaminants, the method comprising the steps of:

excavating (24) soil (40) from the ground (28);

treating (12) the excavated soil (40) with a chemical surfactant (32) such as natural oils or terpenes;

primary stockpiling the excavated soil (40) treated with the chemical surfactant to promote liberation of any organic contaminants from the excavated soil (40) by microbial degradation of the bond between the organic contaminants and the excavated soil (40) to provide cured soil (100);

further treating (14) the cured soil (100) with an aliphatic or aromatic hydrocarbon (108) to degrade bonds between the cured soil (100) and at least some of the remaining organic contaminants to separate said organic contaminants from the cured soil (100); and

after treatment, recovering or providing soil (101) having a reduced concentration of organic contaminants.

2. A method as defined in claim 1, wherein the step of further treating (14) the cured soil (100) with an aliphatic hydrocarbon (108) includes controlled treatment of the cured soil (100) with a hydrocarbon distillate or a derivative or mixture thereof with the range of seven to twenty carbon atoms.

3. A method as defined in either of claims 1 or 2, wherein the method also comprises the step of treating the cured soil (100) with an alcohol which is effective in swelling organic matter within the cured soil (100) to liberate tightly bound organic contaminants for the subsequent microbial degradation thereof.

4. A method as defined in claim 3, wherein the step of treating the cured soil (100) with the alcohol includes the step of adding alcohol to the cured soil (100) before, during or after the further treatment (14) of the cured soil (100) with the aliphatic or aromatic hydrocarbon (108).

5. A method as defined in claim 4, wherein the controlled treatment is effective in degrading the bond between some of the organic contaminants and the excavated soil (40).

6. A method as defined in claim 5, wherein the degradation of the bonds is effective in liberating the organic contaminants and solubilising aquaphobic organic contaminants.

7. A method as defined in any one of the preceding claims, wherein the step of primary stockpiling the excavated soil (40) treated with the chemical surfactant (32) involves stockpiling the excavated soil (40) treated with the chemical surfactant (32) for a period of between about 1 day to about 7 days for gradual miscibilisation of the organic contaminants.

8. A method as defined in claim 7, wherein the step of primary stockpiling the excavated soil (40) includes the step of adding organic matter, manure, nutrients or soil ameliorants before or after treatment of the excavated soil (40) with the chemical surfactant (32).

9. A method as defined in either of claims 7 or 8, wherein the method further comprises the step of secondary stockpiling (16) of the cured soil (100) into a stockpile (112) of said cured soil (100) after the step of primary stockpiling the excavated soil (40) treated with the chemical surfactant (32).

10. A method as defined in claim 9, wherein the step of secondary stockpiling (16) further includes the step of turning the stockpile (112) approximately every 1 to 6 weeks for aeration or homogenisation.

11. A method as defined in any one of the preceding claims wherein the method further comprises the step of further stockpiling (17) of the soil (101) into a stockpile (113) of said soil (101) after the step of further treating the cured soil (100) with the aliphatic or aromatic hydrocarbon (108).

12. A method as defined in claim 11, wherein the step of further stockpiling (17) of the soil (101) into a stockpile (113) of said soil (101) includes a period of between about 2 weeks to about 6 weeks for gradual degradation of aliphatic hydrocarbon-liberated organic contaminants from the cured soil (100).

13. A method as defined in claim 12, wherein the step of further stockpiling (17) of the soil (101) into a stockpile (113) of said soil (101) includes the step of turning the stockpile (113) approximately every 1 to 4 weeks for aeration or homogenisation.

Ansprüche

1. Verfahren (10) zur Sanierung von organische Verunreinigungen aufweisendem Boden (40), wobei das Verfahren die folgenden Schritte umfasst:

Ausheben (24) des Bodens (40) aus dem Erdboden (28);

Behandeln (12) des ausgehobenen Bodens (40) mit einer oberflächenaktiven Chemikalie (32) wie natürlichen Ölen oder Terpenen;

erste Einlagerung des mit der oberflächenaktiven Chemikalie behandelten ausgehobenen Bodens (40), um die Freisetzung organischer Verunreinigungen aus dem ausgehobenen Boden (40) durch mikrobiellen Abbau der Bindung zwischen den organischen Verunreinigungen und dem ausgehobenen Boden (40) zu fördern und einen behandelten Boden (100) bereitzustellen;

Weiterbehandlung (14) des behandelten Bodens (100) mit einem aliphatischen oder aromatischen Kohlenwasserstoff (108), um Bindungen zwischen dem behandelten Boden (100) und mindestens einigen der verbleibenden organischen Verunreinigungen abzubauen, um die organischen Verunreinigungen vom behandelten Boden (100) zu trennen; und

nach der Behandlung Rückgewinnung oder Bereitstellung von Boden (101) mit einer verringerten Konzentration an organischen Verunreinigungen.

2. Verfahren nach Anspruch 1, wobei der Schritt der weiteren Behandlung (14) des behandelten Bodens (100) mit einem aliphatischen Kohlenwasserstoff (108) eine kontrollierte Behandlung des behandelten Bodens (100) mit einem Kohlenwasserstoffdestillat oder einem Derivat oder einer Mischung davon mit sieben bis zwanzig Kohlenstoffatomen umfasst.

3. Verfahren nach einem der Ansprüche 1 oder 2, wobei das Verfahren auch den Schritt des Behandelns des behandelten Bodens (100) mit einem Alkohol umfasst, der beim Quellen von organischer Substanz innerhalb des behandelten Bodens (100) wirksam ist, um fest gebundene organische Verunreinigungen freizusetzen für deren anschließenden mikrobiellen Abbau.

4. Verfahren nach Anspruch 3, wobei der Schritt des Behandelns des behandelten Bodens (100) mit dem Alkohol den Schritt des Hinzufügens von Alkohol zu dem behandelten Boden (100) vor, während oder nach der weiteren Behandlung (14) des behandelten Bodens (100) mit dem aliphatischen oder aromatischen Kohlenwasserstoff (108) umfasst.

5. Verfahren nach Anspruch 4, wobei die kontrollierte Behandlung die Bindung zwischen einigen der organischen Verunreinigungen und dem ausgehobenen Boden (40) abbaut.

6. Verfahren nach Anspruch 5, wobei der Abbau der Bindungen die organischen Verunreinigungen freisetzt und aquaphobe organische Verunreinigungen aufschließt.

7. Verfahren nach einem der vorhergehenden Ansprüche, wobei der Schritt der ersten Einlagerung des mit der oberflächenaktiven Chemikalie (32) behandelten ausgehobenen Bodens (40) die Einlagerung des mit der oberflächenaktiven Chemikalie (32) behandelten ausgehobenen Bodens (40) für einen Zeitraum zwischen etwa 1 Tag bis etwa 7 Tagen zur fortschreitenden Mischbarkeit der organischen Verunreinigungen umfasst.

8. Verfahren nach Anspruch 7, wobei der Schritt der ersten Einlagerung des ausgehobenen Bodens (40) den Schritt des Hinzufügens von organischer Substanz, Dünger, Nährstoffen oder Bodenverbesserungsmitteln vor oder nach der Behandlung des ausgehobenen Bodens (40) mit der oberflächenaktiven Chemikalie (32) umfasst.

9. Verfahren nach einem der Ansprüche 7 oder 8, wobei das Verfahren ferner den Schritt einer zweiten Einlagerung (16) des behandelten Bodens (100) in eine Lagerhalde (112) des behandelten Bodens (100) nach dem Schritt der ersten Einlagerung des mit der oberflächenaktiven Chemikalie (32) behandelten ausgehobenen Bodens (40) umfasst.

10. Verfahren nach Anspruch 9, wobei der Schritt der zweiten Einlagerung (16) ferner den Schritt des Wendens der Lagerhalde (112) ungefähr alle 1 bis 6 Wochen zur Belüftung oder Homogenisierung umfasst.

11. Verfahren nach einem der vorhergehenden Ansprüche, wobei das Verfahren ferner den Schritt einer weiteren Einlagerung (17) des Bodens (101) in eine Lagerhalde (113) des Bodens (101) nach dem Schritt der weiteren Behandlung des behandelten Bodens (100) mit dem aliphatischen oder aromatischen Kohlenwasserstoff (108) umfasst.

12. Verfahren nach Anspruch 11, wobei der Schritt der weiteren Einlagerung (17) des Bodens (101) in eine Lagerhalde (113) des Bodens (101) einen Zeitraum zwischen ungefähr 2 Wochen bis ungefähr 6 Wochen zum allmählichen Abbau von durch aliphatische Kohlenwasserstoffe freigesetzten organischen Verunreinigungen aus dem behandelten Boden (100) umfasst.

13. Verfahren nach Anspruch 12, wobei der Schritt der weiteren Einlagerung (17) des Bodens (101) in eine Lagerhalde (113) des Bodens (101) den Schritt des Wendens der Lagerhalde (113) ungefähr alle 1 bis 4 Wochen zur Belüftung oder Homogenisierung umfasst.

Revendications

1. Procédé (10) de réhabilitation d'un sol (40) comprenant des contaminants organiques, le procédé comprenant les étapes consistant à :

excaver (24) du sol (40) du sol (28) ;

traiter (12) le sol excavé (40) avec un agent tensioactif chimique (32) tel que des huiles naturelles ou des terpènes ;

procéder à un stockage primaire du sol excavé (40) traité avec l'agent tensioactif chimique pour favoriser la libération de tout contaminant organique du sol excavé (40) par dégradation microbienne de la liaison entre les contaminants organiques et le sol excavé (40) pour fournir un sol durci (100) ;

traiter ensuite (14) le sol durci (100) avec un hydrocarbure aliphatique ou aromatique (108) pour dégrader les liaisons entre le sol durci (100) et au moins certains des contaminants organiques restants pour séparer lesdits contaminants organiques du sol durci (100) ; et

après traitement, récupérer ou fournir un sol (101) ayant une concentration réduite de contaminants organiques.

2. Procédé selon la revendication 1, dans lequel l'étape consistant à traiter ensuite (14) le sol durci (100) avec un hydrocarbure aliphatique (108) comprend un traitement contrôlé du sol durci (100) avec un distillat d'hydrocarbure ou un dérivé ou mélange de ceux-ci avec la gamme de sept à vingt atomes de carbone.

3. Procédé selon l'une quelconque des revendications 1 ou 2, dans lequel le procédé comprend également l'étape de traitement du sol durci (100) avec un alcool qui est efficace pour gonfler la matière organique dans le sol durci (100) pour libérer les contaminants organiques étroitement liés pour leur dégradation microbienne ultérieure.

4. Procédé selon la revendication 3, dans lequel l'étape de traitement du sol durci (100) avec l'alcool comprend l'étape consistant à ajouter de l'alcool au sol durci (100) avant, pendant ou après l'étape consistant à traiter ensuite (14) le sol durci (100) avec l'hydrocarbure aliphatique ou aromatique (108).

5. Procédé selon la revendication 4, dans lequel le traitement contrôlé est efficace pour dégrader la liaison entre certains des contaminants organiques et le sol excavé (40).

6. Procédé selon la revendication 5, dans lequel la dégradation des liaisons est efficace pour libérer les contaminants organiques et solubiliser les contaminants organiques aquaphobes.

7. Procédé selon l'une quelconque des revendications précédentes, dans lequel l'étape de stockage primaire du sol excavé (40) traité avec l'agent tensioactif chimique (32) implique le stockage du sol excavé (40) traité avec l'agent tensioactif chimique (32) pendant une période comprise entre environ 1 jour et environ 7 jours pour une miscibilisation progressive des contaminants organiques.

8. Procédé selon la revendication 7, dans lequel l'étape de stockage primaire du sol excavé (40) comprend l'étape consistant à ajouter de la matière organique, du fumier, des nutriments ou des agents améliorant le sol avant ou après le traitement du sol excavé (40) avec l'agent tensioactif chimique (32).

9. Procédé selon l'une quelconque des revendications 7 ou 8, dans lequel le procédé comprend en outre l'étape de stockage secondaire (16) du sol durci (100) dans un tas de stockage (112) dudit sol durci (100) après l'étape de stockage primaire du sol excavé (40) traité avec l'agent tensioactif chimique (32).

10. Procédé selon la revendication 9, dans lequel l'étape de stockage secondaire (16) comprend en outre l'étape consistant à retourner le tas de stockage (112) environ toutes les 1 à 6 semaines pour une aération ou une homogénéisation.

11. Procédé selon l'une quelconque des revendications précédentes, dans lequel le procédé comprend en outre l'étape de stockage supplémentaire (17) du sol (101) dans un tas de stockage (113) dudit sol (101) après l'étape de traitement supplémentaire du sol durci (100) avec l'hydrocarbure aliphatique ou aromatique (108).

12. Procédé selon la revendication 11, dans lequel l'étape de stockage supplémentaire (17) du sol (101) dans un tas de stockage (113) dudit sol (101) comprend une période comprise entre environ 2 semaines et environ 6 semaines pour une dégradation progressive des contaminants organiques libérés d'hydrocarbures aliphatiques du sol durci (100).

13. Procédé selon la revendication 12, dans lequel l'étape de stockage supplémentaire (17) du sol (101) dans un tas de stockage (113) dudit sol (101) comprend l'étape consistant à retourner le tas de stockage (113) environ toutes les 1 à 4 semaines pour une aération ou une homogénéisation.

Drawing