Electric lamp and metal foil

Abstract

 The invention relates to a lamp with a molybdenum foil which is resistant to oxidation and corrosion comprising dopes of between 0.01 and 0.1 wt % of Ce or dopes of between 0.01 and 1 wt% of Al, Co, Fe, Hf, Ir, and/or Y, or dopes of between 0.01 and 5 wt % of Cr. The invention further relates to a molybdenum foil which is resistant to oxidation and corrosion.

Description

FIELD OF THE INVENTION

[0001] The invention relates to an electric lamp comprising a quartz-glass envelope having at least one sealed end, a thin foil comprising molybdenum at least partly embedded within said sealed end, a first current conductor connected to said foil extending interiorly of said envelope, and a second current conductor connected to said foil extending exteriorly of said envelope. The invention further relates to a metal foil.

BACKGROUND OF THE INVENTION

[0002] In lamps having an envelope of a quartz-glass, i.e. glass having a SiO₂ content of at least 95% by weight, a molybdenum foil is frequently used as a current lead-through conductor. In spite of the considerably different coefficients of thermal expansion of the quartz-glass (approximately 7×10^-7 per deg. C.) and of molybdenum (54×10^-7 per deg. C.) lamps having vacuum-tight seals are nevertheless obtained. This is due to the ductility of molybdenum, to the shape of the foil, knife edges of the foil extending in the longitudinal direction of the seal, and to the small thickness of the foil, which is a few tens of µm.

[0003] The material and shape of the current lead-through conductor or current feeder of electrical lamps having a glass bulb quite substantially determine the manufacture, function and quality of such lamps. The term "lamps" especially comprises halogen filament lamps and discharge lamps such as mercury vapour high-pressure lamps, halogen-metal vapour lamps, and xenon-HP-discharge lamps.

[0004] Much attention has been paid in the past to this technical field. Electrical conductors for feeding current in lamps with or without gas filling are, as a rule, fused in quartz glass or squeezed into the latter, depending on the pressure in the lamp. This results in a collapsed seal, respectively a pinched seal. Molybdenum, owing to its high melting point and its favourable coefficient of thermal expansion as compared to quartz-glass, has been found to be a suitable conductor material for feeding current.

[0005] Other material requirements a molybdenum conductor is expected to satisfy are ductility, good mouldability, weldability, and optimised mechanical strength, resistance to oxidation and/or corrosion, especially against halides, and fusibility with the current conductors.

[0006] In order to achieve a vacuum-tight sealing of the molybdenum foil in the glass despite the very different coefficients of thermal expansion in particular of silica glass or glass materials with a high SiO₂ content and molybdenum, the foil is configured to be very thin (typically 15 to 50 µm), with a high width-to-thickness ratio (typically >50), and has side edges which taper in the form of a cutting blade.

[0007] The current conductors, which are significantly thicker than the foil, have to be welded onto this thin molybdenum foil. The first current conductor is in many cases formed of tungsten. Particularly with current conductors made of tungsten, this entails very high welding temperatures, which may result in embrittlement and consequently a fracturing of the molybdenum foil. Cracks in the foil can also occur during the sealing process. Such cracks may be caused by the relative movement between the glass and the foil or by a buildup of tensile stresses during the cooling process, at temperatures which are below the stress relaxation temperature of the glass.

[0008] In order to improve the mechanical strength of the molybdenum foil, doped molybdenum alloys have been used instead of pure molybdenum.

[0009] According to U.S. Pat. No. 4,254,300 small quantities of yttrium oxide considerably increase the strength of the foil both before and after welding operations have been performed, as well as the force which has to be exerted on a weld to break it. Before being pinched in the lamp envelope, the foil according to the invention with the current conductors welded thereto may be heated, if desired, in a reducing atmosphere, up to temperatures of approximately 1300° C without losing mechanical strength of the current lead-through conductor.

[0010] In U.S. Pat. No. 4,559,278 an intermediate metal coating is applied onto the current lead-through conductor in order to ensure high weldability and hermetic sealing with the vitreous material used around the current lead-through conductor. The basic metal of the current lead-through conductor is molybdenum, the whole surface of which or the surface part which is to be welded, is covered with an intermediate metal coating made of rhenium.

[0011] According to EP-A-0 275 580, it is proposed to manufacture current lead-through conductors for lamps from molybdenum, doped with 0.01 to 2% by weight yttrium oxide, and 0.01 to 0.8% by weight molybdenum boride. This dope was intended as an improvement over potassium-silicon-doped molybdenum; however, it does not offer any improvements, especially not with respect to the resistance to oxidation. A serious drawback of this material is that it frequently causes socket cracks in the glass within the zone where it is fused or squeezed in, such cracking being caused by changes in the strength of the material in the course of recrystallization of the latter in the fusing step.

[0012] A doped molybdenum used for current lead-through conductors in lamps is further known from AT-B 395 493, wherein the dope consists of 0.01 to 5% by weight of one or several oxides of the lanthanides, the balance being Mo.

[0013] In U.S. Pat. No. 5,606,141 it is recognized that cracking in the pinched zone is frequently caused by changes in the strength of the material in the course of recrystallization in the fusing step and that this problem can be solved by incorporating an electrical conductor made of etched strip material based on molybdenum-yttrium oxide as current feeder in lamps with a metal/glass sealing. In addition to Mo-Y₂O₃, the strip material contains up to 1.0% by weight cerium oxide, whereby the cerium oxide:yttrium oxide ratio amounts to 0.1 to 1.

[0014] German Patent Application No. DE-A-196 03 300 describes a molybdenum foil which is doped with 0.01 to 1% by weight of alkali-rich and alkaline earth-rich silicates and/or aluminates and/or borates of one or more elements selected from groups IIIb and/or IVb of the periodic system. This doping prevents the formation of cracks in the pinch seal, caused by the high mechanical stresses in the molybdenum/quartz glass composite. However, this does not improve foil adhesion compared to foils which are doped with Y₂O₃ mixed oxide or Y mixed oxide.

[0015] Moreover, it has also been attempted to improve the SiO₂ /Mo adhesion by roughening the foil for example by sand blasting, as described in Published European Patent Application No. EP-A-0 871 202. However, this process is highly complex and leads to internal stresses being introduced in the molybdenum foil.

[0016] U.S. Pat. No. 6,753,650 describes a method which includes a post-treating of the unfinished foil such that substantially non-contiguous, insular regions of material agglomerates are formed. The material agglomerates are formed of molybdenum, molybdenum alloys, titanium, silicon, an oxide, a mixed oxide and/or an oxide comprising compound, with a vapour pressure of less than 10 mbar at 2000° C in each case. The substantially non-contiguous, insular regions are formed on at least 5 percent and at most 60 percent of the area of the foil surface. In this way, the adhesive strength between the foil and the glass and therefore also the service life of the lamp are improved significantly.

[0017] However, an important limitation of the present electric lamps and in particular of UHP lamps is the maximum pressure that can be obtained in a burner. Higher pressures in the burner are important to improve the lumen output. A limitation of the maximum pressure, however, is caused by increased sensitivity to explosion.

[0018] SU702427, EP495588A2 and US3848151 disclose alloys of molybdenum with a rhenium, tungsten or titanium + zirconium metal dope, the chemical composition and the mechanical properties of said alloys being remote from the composition and favorable properties of the alloys of the invention.

SUMMARY OF THE INVENTION

[0019] The invention has for its object to provide a lamp of the kind mentioned in the opening paragraph, which has not only a high luminance and a satisfactory light output, but also low sensitivity to explosion.

[0020] According to the invention a lamp of the kind as defined in the opening paragraph for this purpose has the characterizing features of claim 1.

[0021] A significantly improved resistance against corrosion to a metal vapour, especially to a metal halide gas, is obtained in molybdenum comprising dopes between 0.01 and 0.1 wt. % of Ce, or between 0.01 and 1 wt % of Al, Co, Fe, Hf, Ir, or Y, or between 0.01 and5wt%ofCr.

[0022] As is usual in lamps having molybdenum foils in pinched or collapsed seals, the thickness of molybdenum foils which are used in lamps according to the invention depends on the kind of lamp, and is between approximately 15 and approximately 80 µm, preferably between 25 and 50 µm. Within these ranges the best balance between strength and yield performance of the foil is obtained. In order to avoid the existence of a capillary passage on either side of the foil in the longitudinal direction of the seal, the molybdenum foil, as is usual in the art, is etched so that knife edges are formed so that the quartz-glass of the seal readily embraces the foil.

[0023] The doped molybdenum used in the lamp of the invention can be prepared by methods for doping of metals well known in the field.

[0024] Improved welding properties can be obtained when the molybdenum further comprises dopes of up to 1 wt % of one or several of the following oxides: Y₂O₃, SiO₂, HfO₂, ZrO₂, TiO₂, Al₂O₃, or an oxide of one of the lanthanides.

Claims

1. Electric lamp comprising a quartz-glass envelope having at least one sealed end, a thin foil comprising molybdenum at least partly embedded within said sealed end, a first current conductor connected to said foil extending interiorly of said envelope, and a second current conductor connected to said foil and extending exteriorly of said envelope, characterized in that the molybdenum is doped with between 0.01 and 0.1 wt % of Ce, or doped with between 0.01 and 1 wt% of Al, Co, Fe, Hf, Ir, and/or Y, or doped with between 0.01 and 5 wt % of Cr.

2. Lamp according to claim 1, wherein the molybdenum also comprises a dope of up to 1 wt % of one or several of the following oxides: Y₂O₃, SiO₂, HfO₂, ZrO₂, TiO₂, Al₂O₃, or an oxide of one of the lanthanides.

3. Foil comprising molybdenum, characterized in that the molybdenum is doped with between 0.01 and 0.1 wt % of Ce, or doped with between 0.01 and 1 wt% of Al, Co, Fe, Hf, Ir, and/or Y, or doped with between 0.01 and 5 wt % of Cr.

4. Foil according to claim 3, wherein the molybdenum also comprises a dope of up to 1 wt % of one or several of the following oxides: Y₂O₃, SiO₂, HfO₂, ZrO₂, TiO₂, Al₂O₃, or an oxide of one of the lanthanides.

Drawing