[0001] The present invention relates to an additive concentrate comprising a base oil and
a viscosity modifier, for the incorporation into a lubricant composition.
[0002] Lubricant compositions, in particular for automotive crankcase or transmissions,
are employed to reduce wear at metal-to-metal contact between moving parts, as well
as to remove heat. In many applications, the lubricant compositions require the presence
of polymeric viscosity modifier additives to obtain the desired viscometric properties
over a broad range of shear and/or temperatures. These additives are usually highly
viscous liquids or solids at room temperature. In order to be able to achieve homogenous
distribution, avoid handling of solids and to be able to administer the amounts of
additives added into lubricant compositions and thus ensure consistent product quality,
these additives are usually added as an additive concentrate.
[0003] As acknowledged in
WO 2009/074572, Fischer-Tropsch derived base oils are usually not suitable as base oils to prepare
additive concentrates for additives such as polymeric viscosity modifiers due to the
low solvency of these Fischer-Tropsch derived base oils. Therefore,
WO 2009/074572 suggests to include an alkylated aromatic compound (e.g. "KR 008", commercially available
from King Industries) as a solvency booster in the additive concentrate. According
to
WO 2009/074572, the solvency booster is preferably present in an amount of from 25 wt.% to 75 wt.%,
based on the weight of the additive concentrate.
[0004] The present applicant has now surprisingly found that it is possible to prepare additive
concentrates containing a viscosity modifier using Fischer-Tropsch derived base oils,
which additive concentrates are suitable for use in e.g. transmission oils and engine
oils and other lubricants (including industrial lubricants such as hydraulic oils)
for which a viscosity modifier is desired, but without the need of significant amounts
of solvency boosters, or even without the need of solvency boosters at all.
[0005] To this end the present invention provides an additive concentrate comprising:
- a Fischer-Tropsch derived base oil;
- at least 3.0 wt.% of a viscosity modifier, based on the total weight of the additive
concentrate; and
- less than 5.0 wt.% of a solvency booster, based on the total weight of the additive
concentrate.
[0006] Fischer-Tropsch derived base oils are known in the art. In the present context, the
term "Fischer-Tropsch derived" means that a material is, or derives from, a synthesis
product of a Fischer-Tropsch condensation process. The term "non-Fischer-Tropsch derived"
may be interpreted accordingly. A Fischer-Tropsch derived base oil will therefore
be a hydrocarbon stream of which a substantial portion, except for added hydrogen,
is derived directly or indirectly from a Fischer-Tropsch condensation process. A Fischer-Tropsch
derived base oil may also be referred to as a GTL (Gas-To-Liquids) base oil. The term
"base oil" may refer to a mixture containing more than one base oil.
[0007] For further information on the Fischer-Tropsch derived base oil and the preparation
thereof reference is made to the above-mentioned
WO 2009/074572, the teaching of which is hereby incorporated by specific reference.
[0008] Typically, the aromatics content of a Fischer-Tropsch derived base oil, suitably
determined by ASTM D 4629, will typically be below 1 wt.%, preferably below 0.5 wt.%
and more preferably below 0.1 wt.%. Suitably, the base oil has a total paraffin content
of at least 80 wt.%, preferably at least 85, more preferably at least 90, yet more
preferably at least 95 and most preferably at least 99 wt.%. It suitably has a saturates
content (as measured by IP-368) of greater than 98 wt.%. Preferably the saturates
content of the base oil is greater than 99 wt.%, more preferably greater than 99.5
wt.%. It further preferably has a maximum n-paraffin content of 0.5 wt.%. The base
oil preferably also has a content of naphthenic compounds of from 0 to less than 20
wt.%, more preferably of from 0.5 to 10 wt.%.
[0009] Typically, the Fischer-Tropsch derived base oil has a kinematic viscosity at 100°C
(as measured by ASTM D 7042) of from 1 to 25 mm
2/s (cSt), preferably above 2.5 more preferably above 3.0 mm
2/s. Preferably, the Fischer-Tropsch derived base oil has a kinematic viscosity at
100°C of below 5.0 mm
2/s, preferably below 4.5 mm
2/s, more preferably below 4.2 mm
2/s.
[0010] Further, the Fischer-Tropsch derived base oil typically has a kinematic viscosity
at 40°C (as measured by ASTM D 7042) of from 10 to 100 mm
2/s (cSt), preferably from 15 to 50 mm
2/s.
[0011] Also, the Fischer-Tropsch derived base oil preferably has a pour point (as measured
according to ASTM D 5950) of below -30°C, more preferably below -40°C, and most preferably
below -45°C.
[0012] The flash point (as measured by ASTM D92) of the Fischer-Tropsch derived base oil
is preferably greater than 120°C, more preferably even greater than 140 °C.
[0013] The Fischer-Tropsch derived base oil preferably has a viscosity index (according
to ASTM D 2270) in the range of from 100 to 200. Preferably, the Fischer-Tropsch derived
base oil has a viscosity index of at least 125, preferably 130. Also it is preferred
that the viscosity index is below 180, preferably below 150.
[0014] In the event the Fischer-Tropsch derived base oil contains a blend of two or more
Fischer-Tropsch derived base oils, the above values apply to the blend of the two
or more Fischer-Tropsch derived base oils.
[0015] In addition to the Fischer-Tropsch derived base oil, the additive concentrate may
comprise one or more non-Fischer-Tropsch derived base oils, such as mineral derived
base oils and so-called synthetic base oils (such as PAOs) including Group I-V base
oils according to the definitions of American Petroleum Institute (API). These API
categories are defined in API Publication 1509, 15th Edition, Appendix E, July 2009.
[0016] Preferably the additive concentrate according to the present invention comprises
at least 80 wt.% of the Fischer-Tropsch derived base oil, preferably at least 90 wt.%,
based on the total weight of the additive concentrate. Also it is preferred that the
additive concentrate comprises less than 10.0 wt.% of a non-FT-derived base oil, preferably
less than 5.0 wt.%, more preferably less than 2.0 wt.%, even more preferably less
than 1.0 wt.%, based on the total weight of the additive concentrate. Most preferably
the additive concentrate comprises no non-Fischer-Tropsch derived base oils at all.
[0017] There are no particular limitations regarding the viscosity modifier as used in the
additive concentrate according to the present invention. As a person skilled in the
art is familiar with the term "viscosity modifier", this is not further discussed
in detail. Viscosity modifiers (also known as VI improvers, viscosity index improvers
or viscosity improvers) provide lubricants with high- and low-temperature operability;
these additives impart acceptable viscosity at low temperatures and are preferably
shear stable. Typically, and as meant according to the present invention, a viscosity
modifier improves (e.g. by at least 5 units) the viscosity index (e.g. as determined
by ASTM D 2270) by its incorporation in the additive concentrate (and/or a fully formulated
lubricant composition in which the viscosity modifier is incorporated).
[0018] According to the present invention, the additive concentrate comprises at least 3.0
wt.% of a viscosity modifier, based on the total weight of the additive concentrate.
Preferably, the additive concentrate comprises from 5.0 to 25.0 wt.%, preferably from
6.0 to 20.0 wt.% of the viscosity modifier, based on the total weight of the additive
concentrate.
[0019] Non-limiting Examples of viscosity modifiers are linear or star-shaped olefin copolymers,
polyisobutylenes, polymethacrylates, polymers of a diene such as isoprene or butadiene,
or a copolymer of such a diene with optionally substituted styrene. These copolymers
are preferably hydrogenated to such an extent as to saturate most of the olefinic
unsaturation. A number of other types of viscosity modifier are known in the art,
and many of these are described in
Proceedings of Conference "Viscosity and flow properties of multigrade engine oils",
Esslingen, Germany, December 1977. It is also known in the art that viscosity modifiers can be functionalised to incorporate
dispersancy (e.g. dispersant viscosity index improvers based on block copolymers,
or polymethacrylates) and/or antioxidant functionality as well as viscosity modification
and they can also have pour point depressants mixed in to give handleable products
in cold climates.
[0020] Preferably, the viscosity modifier is selected from the group consisting of olefin
copolymers, polyisoprene polymers and diene-styrene copolymers. Olefin copolymers,
are commercially available from Chevron Oronite Company LLC under the trade designation
"PARATONE®" (such as "PARATONE® 8921" and "PARATONE® 8941"); from Afton Chemical Corporation
under the trade designation "HiTEC®" (such as "HiTEC® 5850B"; and from The Lubrizol
Corporation under the trade designation "Lubrizol® 7067C". Polyisoprene polymers are
commercially available from Infineum International Limited, e.g. under the trade designation
"SV200"; diene-styrene copolymers are commercially available from Infineum International
Limited, e.g. under the trade designation "SV 260".
[0021] The additive concentrate according to the present invention comprises less than 5.0
wt.% of a solvency booster, based on the total weight of the additive concentrate.
Preferably, the additive concentrate comprises less than 2.0 wt.%, preferably less
than 1.0 wt.%, more preferably less than 0.5 wt.%, of the solvency booster, based
on the total weight of the additive concentrate. It is even more preferred that the
additive concentrate contains no solvency booster at all.
[0022] There are no particular limitations regarding the solvency booster as meant according
to the present invention. As a person skilled in the art is familiar with the term
"solvency booster", this is not further discussed in detail. Typically, and as meant
according to the present invention, a solvency booster is a compound having an aniline
point (according to ASTM D 611) of less than 100°C.
[0023] Preferably, the solvency booster is an alkylated aromatic compound. Alkylated aromatic
compounds include alkylated benzenes, alkylated anthracenes, alkylated phenanthrenes,
alkylated biphenyls, and alkylated naphthalenes or any mixtures thereof. For further
description of the alkylated naphthalenes, reference is made to
WO 2009/074572.
[0024] The additive concentrate may further contain a pour point depressant to improve pumpability.
If present, the pour point depressant preferably is present in a range of from 0.5
to 3 wt.%, more preferably from 1 to 2 wt.%, and most preferably from 1.1. to 1.4
wt.%.
[0025] The additive concentrate preferably has - when normalized at a concentration of viscosity
modifier of 1.0 wt.% - a dynamic viscosity at -30°C (according to ASTM D 5293) of
below 3000 cP and a kinematic viscosity at 100°C (according to ASTM D 7042) of at
least 5.5 cSt. Preferably the dynamic viscosity at -30°C is below 2000 cP, more preferably
below 1500 cP. Additive concentrates containing different amounts of viscosity modifier
can be normalized to a concentration of 1.0 wt.% by diluting the concentrate with
the appropriate amount of the same base oil (or base oil blend) used to make the additive
concentrate.
[0026] Further it is preferred that the additive concentrate comprises from 5 to 500 ppm
of an anti-oxidant, preferably selected from a phenolic and an aminic anti-oxidant,
or a mixture thereof.
[0027] In a further aspect the present invention provides a lubricant composition comprising
a base oil, one or more additives other than a viscosity modifier and the additive
concentrate according to the present invention.
[0028] There are no particular limitations regarding the base oil as used in the lubricant
composition according to the present invention. This base oil may be a Fischer-Tropsch
derived base oil, a non-Fischer-Tropsch derived base oil or a mixture thereof.
[0029] The one or more additives other than a viscosity modifier may be selected from a
broad range of additives such as anti-oxidants, anti-wear additives, dispersants,
detergents, over-based detergents, extreme pressure additives, friction modifiers,
pour point depressants, metal passivators, corrosion inhibitors, demulsifiers, anti-foam
agents, seal compatibility agents and additive diluent base oils, etc. As the person
skilled in the art is familiar with the above and other additives, these are not further
discussed here in detail. Specific examples of such additives are described in for
example
Kirk-Othmer Encyclopedia of Chemical Technology, third edition, volume 14, pages 477-526.
[0030] The present invention is described below with reference to the following Examples,
which are not intended to limit the scope of the present invention in any way.
EXAMPLES
Additive Concentrates
[0031] Various additive concentrates were formulated. Table 1 indicates the properties for
the base oils used in the additive concentrates. Tables 2-5 indicate the composition
and properties of the formulated additive concentrates that were tested; the amounts
of the components are given in wt.%, based on the total weight of the additive concentrate.
Table 6 exemplifies the storage stability properties of an additive concentrate according
to the present invention. Further, Table 7 exemplifies a fully formulated lubricating
compositions (i.c. a SAE 5W-30 engine oil), comprising the additive concentrate according
to the present invention.
[0032] The viscosities and Viscosity Index as measured for the additive concentrates were
all measured at a normalized Viscosity Modifier concentration of 1.0 wt.% by dilution
with the same base oil used to blend the additive concentrate (as the neat concentrates
were too thick and therefore outside the testing range of the indicated test methods).
[0033] All tested additive concentrates contained a combination of a base oil and a viscosity
modifier, and optionally an anti-oxidant.
[0034] "Base oil 1" was a Fischer-Tropsch derived base oil ("GTL 4") having a kinematic
viscosity at 100°C (ASTM D 7042) of approx. 4 cSt (mm
2/s) . This GTL 4 base oil may be conveniently manufactured by the process described
in e.g.
WO-A-02/070631, the teaching of which is hereby incorporated by reference.
[0035] "Base oil 2" was a commercially available Group I base oil having a kinematic viscosity
at 100°C (ASTM D 7042) of approx. 4 cSt. Base oil 2 is commercially available from
ExxonMobil Corporation under the trade designation "Americas SN 115".
[0036] "Base oil 3" was a commercially available Group II base oil having a kinematic viscosity
at 100°C (ASTM D 7042) of approx. 4.7 cSt. Base oil 3 is commercially available from
Motiva Enterprises LLC under the trade designation "Star 5+".
[0037] "Base oil 4" was a commercially available Group II base oil having a kinematic viscosity
at 100°C (ASTM D 7042) of approx. 6.5 cSt. Base oil 4 is commercially available from
Motiva Enterprises LLC under the trade designation "Star 6".
[0038] "VM1" was a commercially available olefin copolymer viscosity modifier available
from Chevron Oronite Company LLC (Richmond, California, USA) under the trade designation
"PARATONE® 8921".
[0039] "VM2" was a commercially available olefin copolymer viscosity modifier available
from Afton Chemical Corporation (Richmond, Virginia, USA) under the trade designation
"HiTEC® 5850B".
[0040] "VM3" was a commercially available olefin copolymer viscosity modifier available
from The Lubrizol Corporation (Wickliffe, Ohio, USA) under the trade designation "Lubrizol®
7067C".
[0041] "VM4" was a commercially available polyisoprene polymer viscosity modifier available
from Infineum International Limited (Linden, New Jersey, USA) under the trade designation
"SV 200".
[0042] "VM5" was a commercially available diene-styrene copolymer viscosity modifier available
from Infineum International Limited under the trade designation "SV 260".
[0043] "Anti-oxidant" was a commercially available aminic anti-oxidant available from Cuba
Corporation (Houston, Texas, USA) under the trade designation " Ciba® IRGANOX® L57".
[0044] The compositions of Example 1-8 and Comparative Examples 1-8 were obtained by mixing
the base oils with the viscosity modifier using a Silverson high shear mixer and following
(conventional) blending procedures recommended by the suppliers of the Viscosity Modifiers.
TABLE 1
|
Base oil 1 |
Base oil 2 |
Dynamic viscosity at -25°C1 [cP] |
520 |
1645 |
Dynamic viscosity at -30°C1 [cP] |
850 |
3155 |
Dynamic viscosity at -35°C1 [cP] |
1390 |
6600 |
Kinematic viscosity at 40°C2 [cSt] |
16.94 |
21.30 |
Kinematic viscosity at 100°C2 [cSt] |
3.93 |
4.20 |
Viscosity Index3 |
130 |
99 |
Aniline point4 [°C] |
120 |
97 |
pour point5 [°C] |
-30 |
-18 |
Noack volatility6 [wt.%] |
11.7 |
26.6 |
Saturates7 [wt.%] |
99.9 |
80.0 |
1According to ASTM D 5293
2According to ASTM D 7042
3According to ASTM D 2270
4According to ASTM D 611
5According to ASTM D 5950
6According to ASTM D 5800B
7According to IP 368 (modified) |
TABLE 2 - Additive concentrates containing VM1
Component [wt.%] |
Example 1 |
Example 2 |
Comp. Ex. 1 |
Comp. Ex. 2 |
Base oil 1 [GTL 4] |
90.91 |
90.87 |
- |
- |
Base oil 2 [Group I] |
- |
- |
90.91 |
90.87 |
VM1 |
9.09 |
9.09 |
9.09 |
9.09 |
Antioxidant |
- |
0.04 |
- |
0.04 |
TOTAL |
100 |
100 |
100 |
100 |
Properties of the additive concentrate (at normalized VM concentration of 1.0 wt.%) |
Dynamic viscosity at -25°C1 [cP] |
750 |
760 |
2220 |
2290 |
Dynamic viscosity at -30°C1 [cP] |
1180 |
1200 |
4170 |
4260 |
Dynamic viscosity at -35°C1 [cP] |
1920 |
1940 |
8460 |
8550 |
Kinematic viscosity at 40°C2 [cSt |
37.30 |
37.85 |
53.43 |
55.35 |
Kinematic viscosity at 100°C2 [cSt] |
7.83 |
7.94 |
9.48 |
9.75 |
VI3 |
188 |
189 |
163 |
163 |
1According to ASTM D 5293. NB 1 cP (centi Poise) = 1 mPa.s
2According to ASTM D 7042
3According to ASTM D 2270 |
TABLE 3 - Additive concentrates containing VM2
Component [wt. %] |
Example 3 |
Example 4 |
Comp. Ex. 3 |
Comp. Ex. 4 |
Base oil 1 [GTL 4] |
92.59 |
92.55 |
- |
- |
Base oil 2 [Group I] |
- |
- |
92.59 |
92.55 |
VM2 |
7.41 |
7.40 |
7.41 |
7.40 |
Antioxidant |
- |
0.05 |
- |
0.05 |
TOTAL |
100 |
100 |
100 |
100 |
Properties of the additive concentrate (at normalized VM concentration of 1.0 wt.%) |
Dynamic viscosity at -25°C1 [cP] |
840 |
830 |
2400 |
2390 |
Dynamic viscosity at -30°C1 [cP] |
1280 |
1270 |
4420 |
4370 |
Dynamic viscosity at -35°C1 [cP] |
2040 |
2000 |
8960 |
8750 |
Kinematic viscosity at 40°C2 [cSt |
45.12 |
44.64 |
63.30 |
62.14 |
Kinematic viscosity at 100°C2 [cSt] |
9.22 |
9.15 |
10.90 |
10.78 |
VI3 |
193 |
193 |
165 |
166 |
1According to ASTM D 5293
2According to ASTM D 7042
3According to ASTM D 2270 |
TABLE 4 - Additive concentrates containing VM3
Component [wt.%] |
Example 5 |
Example 6 |
Comp. Ex. 5 |
Comp. Ex. 6 |
Base oil 1 [GTL 4] |
88.50 |
88.46 |
- |
- |
Base oil 2 [Group I] |
- |
- |
88.50 |
88.46 |
VM3 |
11.50 |
11.50 |
11.50 |
11.50 |
Antioxidant |
- |
0.04 |
- |
0.04 |
TOTAL |
100 |
100 |
100 |
100 |
Properties of the additive concentrate (at normalized VM concentration of 1.0 wt.%) |
Dynamic viscosity at -25°C1 [cP] |
760 |
750 |
2210 |
2170 |
Dynamic viscosity at -30°C1 [cP] |
1200 |
1190 |
4160 |
4070 |
Dynamic viscosity at -35°C1 [cP] |
1950 |
1920 |
8480 |
8230 |
Kinematic viscosity at 40°C2 [cSt |
32.30 |
32.09 |
43.62 |
43.29 |
Kinematic viscosity at 100°C2 [cSt] |
6.89 |
6.84 |
7.90 |
7.82 |
VI3 |
191 |
180 |
154 |
152 |
1According to ASTM D 5293
2According to ASTM D 7042
3According to ASTM D 2270 |
TABLE 5 - Additive concentrates containing VM4 or VM5
Component [wt.%] |
Example 7 |
Example 8 |
Camp. Ex. 7 |
Comp. Ex. 8 |
Base oil 1 [GTL 4] |
87.68 |
90.87 |
- |
- |
Base oil 2 [Group I] |
- |
- |
87.68 |
90.87 |
VM4 |
12.27 |
- |
12.27 |
- |
VM5 |
- |
9.09 |
- |
9.09 |
Antioxidant |
0.05 |
0.04 |
0.05 |
0.04 |
TOTAL |
100 |
100 |
100 |
100 |
Properties of the additive concentrate (at normalized VM concentration of 1.0 wt.%) |
Dynamic viscosity at -25°C1 [cP] |
660 |
660 |
1940 |
2010 |
Dynamic viscosity at -30°C1 [cP] |
1030 |
1050 |
3640 |
3830 |
Dynamic viscosity at -35°C1 [cP] |
1660 |
1710 |
7360 |
8000 |
Kinematic viscosity at 40°C2 [cSt |
31.95 |
37.84 |
44.02 |
53.51 |
Kinematic viscosity at 100°C2 [cSt] |
6.92 |
8.02 |
8.07 |
9.55 |
VI3 |
186 |
192 |
158 |
164 |
1According to ASTM D 5293
2According to ASTM D 7042
3According to ASTM D 2270 |
Storage Stability
[0045] In order to demonstrate the storage stability properties of the additive concentrates
according to the present invention, separate samples of the additive concentrate of
Example 1 were stored for 30 days at temperatures of 70°C, ambient (20°C), 0°C and
-20°C, respectively. The measured viscosities after 30 days of storage are indicated
in Table 6 below. Similar good stability properties were obtained for the additive
concentrates of Examples 2-8.
TABLE 6 - Storage stability of additive concentrate of Example 1
|
When prepared (see Table 2) |
After 30 days storage at 70°C |
After 30 days storage at 20°C |
After 30 days storage at 0°C |
After 30 days storage at -20°C |
Properties of the additive concentrate (at normalized VM concentration of 1.0 wt.%) |
Kinematic viscosity at 40°C2 [cSt |
37.30 |
33.25 |
37.15 |
37.08 |
36.85 |
Kinematic viscosity at 100°C2 [cSt] |
7.83 |
7.06 |
7.80 |
7.78 |
7.75 |
VI3 |
188 |
182 |
187 |
187 |
187 |
1According to ASTM D 5293
2According to ASTM D 7042
3According to ASTM D 2270 |
SAE 5W30 engine oils
[0046] Whilst using the additive concentrates of Example 2 and 4 above and a conventional
additive package, two SAE 5W-30 engine oil formulations (Examples 9 and 10) were prepared
meeting the so-called SAE J300 Specifications (as revised in January 2009). SAE stands
for Society of Automotive Engineers.
[0047] The amounts of the components and the properties of the 5W-30 engine oil are indicated
in Table 7 below.
[0048] The additive package contained a pour point depressant and other typical additives
for use in a SAE 5W-30 engine oil.
TABLE 7 - SAE 5W-30 engine oils
Component [wt.%] |
5W-30 specification |
Example 9 |
Example 10 |
Base oil 3 |
- |
75.9 |
76.8 |
Base oil 4 |
- |
5.6 |
5.4 |
Additive package |
- |
10.5 |
10.4 |
Additive concentrate of Example 2 |
- |
8.0 |
- |
Additive concentrate of Example 4 |
- |
- |
7.4 |
TOTAL |
- |
100 |
100 |
Properties of the 5W-30 engine oil |
Dynamic viscosity at -30°C1 [cP] |
<6600 |
5500 |
5370 |
Kinematic viscosity at 40°C2 [cSt |
- |
58.73 |
57.32 |
Kinematic viscosity at 100°C2 [cSt] |
9.3 to 12.5 |
10.09 |
9.95 |
VI3 |
- |
160 |
161 |
MRV4 at -35°C [cP] |
<60000 |
21100 |
19900 |
HTHS5 at 150°C [cP] |
>2.9 |
2.976 |
2.955 |
1According to ASTM D 5293
2According to ASTM D 7042
3According to ASTM D 2270
4According to ASTM D 4684
5According to ASTM D 4683 |
Discussion
[0049] As can be learned from Tables 2-5, the present invention now surprisingly provides
the possibility to prepare additive concentrates containing a viscosity modifier using
Fischer-Tropsch derived base oils, but without significant amounts of solvency boosters
or even without the use of solvency boosters at all. Also, it can be seen that the
additive concentrates according to the present invention show, when compared with
conventional additive concentrates using mineral derived Group I (i.e. non-Fischer-Tropsch
derived) base oils, significantly better low temperature properties, which is highly
desirable for formulating multi-grade lubricants.
[0050] Furthermore, as exemplified by Table 6, the additive concentrates according to the
present invention have excellent storage stability at various temperatures for extended
periods of time.
[0051] The additive concentrates according to the present invention are suitable for use
in a wide range of lubricants, such as in e.g. engine oils and transmission fluids
and other lubricants for which a viscosity modifier is desired. As shown in Table
7, SAE 5W-30 formulations can be formulated when using the additive concentrates according
to the present invention.
1. An additive concentrate comprising:
- a Fischer-Tropsch derived base oil;
- at least 3.0 wt.% of a viscosity modifier, based on the total weight of the additive
concentrate; and
- less than 5.0 wt.% of a solvency booster, based on the total weight of the additive
concentrate.
2. Additive concentrate according to claim 1, wherein the additive concentrate comprises
at least 80 wt.% of the Fischer-Tropsch derived base oil, preferably at least 90 wt.%,
based on the total weight of the additive concentrate.
3. Additive concentrate according to claim 1 or 2, wherein the additive concentrate comprises
less than 10.0 wt.% of a non-Fischer-Tropsch derived base oil, preferably less than
5.0 wt.%, more preferably less than 2.0 wt.%, even more preferably less than 1.0 wt.%,
based on the total weight of the additive concentrate.
4. Additive concentrate according to any one of claims 1 to 3, wherein the Fischer-Tropsch
derived base oil has a kinematic viscosity at 100°C (according to ASTM D7042) of below
5.0 mm2/s, preferably below 4.5 mm2/s, more preferably below 4.2 mm2/s.
5. Additive concentrate according to any one of claims 1 to 4, wherein the Fischer-Tropsch
derived base oil has a Viscosity Index (according to ASTM D 2270) of at least 125,
preferably at least 130.
6. Additive concentrate according to any one of claims 1 to 5, wherein the additive concentrate
comprises from 5.0 to 25 wt.%, preferably from 6.0 to 20.0 wt.% of the viscosity modifier,
based on the total weight of the additive concentrate.
7. Additive concentrate according to any one of claims 1 to 6, wherein the additive concentrate
comprises less than 2.0 wt.%, preferably less than 1.0 wt.%, more preferably less
than 0.5 wt.%, of the solvency booster, based on the total weight of the additive
concentrate.
8. Additive concentrate according to any one of claims 1 to 7, wherein the solvency booster
has an aniline point (according to ASTM D 611) of less than 100°C.
9. Additive concentrate according to any one of claims 1 to 8, wherein the solvency booster
is an alkylated aromatic component.
10. Additive concentrate according to claim 9, wherein the alkylated aromatic component
is selected from alkylated benzenes, alkylated anthracenes, alkylated phenanthrenes,
alkylated biphenyls, and alkylated naphthalenes, or any mixtures thereof.
11. Additive concentrate according to any one of claims 1 to 10, wherein the additive
concentrate when normalized at a concentration of viscosity modifier of 1.0 wt.% has
a dynamic viscosity at -30°C (according to ASTM D 5293) of below 3000 cP and a kinematic
viscosity at 100°C (according to ASTM D 7042) of at least 5.5 cSt.
12. Additive concentrate according to any one of claims 1 to 11, further comprising 5
to 500 ppm of an anti-oxidant, preferably selected from a phenolic and aminic anti-oxidant,
or a mixture thereof.
13. A lubricant composition comprising a base oil, one or more additives other than a
viscosity modifier and the additive concentrate according to any one of claims 1 to
12.