BACKGROUND OF THE INVENTION
Field of the invention
[0001] The invention concerns an optical system, in particular an optical system of a microlithographic
projection exposure apparatus.
State of the art
[0002] Microlithography is used for the production of microstructured components such as
for example integrated circuits or LCDs. The microlithography process is carried out
in what is referred to as a projection exposure apparatus having an illumination system
and a projection objective. The image of a mask illuminated by means of the illumination
system (= reticle) is in that case projected by means of the projection objective
onto a substrate (for example a silicon wafer) which is coated with a light-sensitive
layer (photoresist) and arranged in the image plane of the projection objective to
transfer the mask structure onto the light-sensitive coating on the substrate.
[0003] Various approaches are known for specifically targetedly implementing adjustments
or corrections in respect of polarization distribution in the illumination system
or in the projection objective for optimizing the imaging contrast.
[0004] WO 2005/069081 A2 discloses inter alia a polarization-influencing optical element comprising an optically
active crystal and a thickness profile which varies in the direction of the optical
axis of the crystal.
[0005] It is known inter alia from
US 2007/0146676 A1 to arrange in the illumination system a polarization manipulator for conversion of
the polarization state, comprising a multiplicity of variable optical rotator elements
by which the polarization direction of impinging linearly polarized light can be rotated
with variably adjustable rotational angles.
[0006] WO 2005/031467 A2 discloses inter alia in a projection exposure apparatus, influencing the polarization
distribution by means of one or more polarization manipulator devices which can also
be arranged at a plurality of positions and which can be in the form of polarization-influencing
optical elements which can be introduced into the beam path, wherein the effect of
those polarization-influencing elements can be varied by altering the position, for
example rotation, decentering or tilting of the elements.
[0007] US 6 252 712 B1 discloses inter alia a polarization compensator comprising two birefringent elements
which are each provided with a free-form surface and which involve mutually rotated
optical crystal axes.
[0008] It is known inter alia from
US 6 104 472 to use optical elements of quartz glass or calcium fluoride for controlling axial
astigmatism, which elements have mutually complementary aspheric surfaces and are
arranged displaceably relative to each other in respect of their relative position.
Publication US 4 643 534 A discloses a birefringent lens of particular interest. In practice however the problem
which further arises is that changes in the polarization distribution can occur in
dependence on time and possibly varying at high frequency, as is the case for example
in regard to stress birefringence effects, which vary over the service life, in optical
elements, or in the case of changes in the desired polarization distribution in the
optical system as a consequence of a change in the illumination setting (for example
from what is referred to as x-dipole-illumination setting to what is referred to as
y-dipole-illumination setting). A further example is polarization-induced birefringence
("PBR") which increases in its amplitude in the course of time with illumination with
the same illumination setting.
SUMMARY OF THE INVENTION
[0009] It is an object of the present invention to provide an optical system which permits
effective compensation of disturbances which are variable in time in polarization
distribution.
[0010] That object is attained by the features of independent claim 1.
[0011] An optical system which has an optical axis comprises
- at least one polarization manipulator having a first subelement which has a non-planar,
optically effective surface and for light passing therethrough causes a change in
the polarization state, wherein a maximum effective retardation introduced by the
first subelement along the optical axis is less than a quarter of the working wavelength
of the optical system, and a second subelement, wherein said first subelement and
said second subelement have mutually facing surfaces which are mutually complementary;
and
- a position manipulator for manipulation of the relative position of said first subelement
and said second subelement.
[0012] The term retardation is used to denote the difference in the optical paths of two
orthogonal (mutually perpendicular) polarization states. In addition the reference
to an effective retardation which is introduced along the optical axis is used to
denote the "modulo λ" retardation (that is to say instead of a retardation of for
example a fifth of the working wavelength λ of the optical system, it is also possible
to set a retardation λ + 0.2*λ, 2λ + 0.2*λ etc., which differs only by an integral
multiple of the working wavelength λ). In addition, as is also stated in greater detail
hereinafter, manipulation of the position of that subelement in relation to the optical
axis can involve both any rotation and also displacement of the subelement as well
as a combination of such movements.
[0013] By the manipulation in accordance with the invention of the position of the subelement,
the amplitude of the retardation set by the subelement can be specifically targetedly
manipulated and it is thus possible in particular to compensate for a disturbance,
which varies in respect of time, in the polarization distribution. In that respect
the position of the subelement is defined by the positional coordinates (x, y and
z) as well as the rotary angles with respect to a coordinate system which contains
the optical axis as the z-axis.
[0014] According to a further aspect, the invention also concerns an optical system which
has an optical axis and comprises at least one polarization manipulator having at
least one subelement which has a non-planar, optically effective surface and for light
passing therethrough causes a change in the polarization state, wherein a maximum
effective retardation introduced by the subelement along the optical axis is less
than a quarter of the working wavelength of the optical system, and a position manipulator
for manipulation of the position of that subelement.
[0015] In accordance with an embodiment the non-planar surface is an aspheric surface.
[0016] According to an embodiment the polarization manipulator in addition to the first
subelement has at least one second subelement, wherein the position manipulator is
adapted to change the relative position of the first and second subelements.
[0017] The invention makes use of the realization that, in the polarization manipulator
according to the invention, upon a change in the relative position of the two mutually
facing surfaces which in particular can both be aspheric and mutually complementary
or mutually inverse, the polarization action on the light passing through the two
subelements can be described as a good approximation by way of the derivative of a
function describing the aspheric surface, in accordance with that relative movement,
wherein the degree of the polarization manipulation implemented, within a certain
linearity range, scales substantially linearly with the amplitude of the relative
movement. Accordingly, the amplitude of a retardation set by the polarization manipulator
can be manipulated and thus a disturbance, which varies in respect of time, in the
polarization distribution can be specifically compensated, by relative displacement
of the two subelements.
[0018] In accordance with an embodiment the mutually facing surfaces are both of an aspheric
configuration. Furthermore preferably the mutually facing aspheric surfaces are mutually
complementary. In particular the two subelements, when the other surfaces are in the
form of plane surfaces, can supplement each other thereby to form an overall plane-parallel
geometry.
[0019] In accordance with an embodiment of the invention at least one of said subelements
causes a change in the polarization state by linear birefringence, circular birefringence
and/or by transmission splitting between orthogonal polarization states (that is to
say, by a change in the amplitude relationship of orthogonal polarization states in
dependence on the orientations thereof).
[0020] In accordance with an embodiment the polarization manipulator is arranged in a plane
in which the paraxial subaperture ratio is at least 0.8. In accordance with a further
embodiment the polarization manipulator is arranged in a plane in which the paraxial
subaperture ratio is at a maximum 0.2. In that respect the paraxial subaperture ratio
S is defined as:

wherein r denotes the paraxial marginal ray height and h denotes the paraxial principal
ray height. In the equation sgn(x) denotes what is referred to as the signum function,
wherein by definition sgn(0) = 1 can be set.
[0021] The term principal ray is used to denote a ray which comes from an object point which
in the object plane is at the greatest distance relative to the optical axis and which
in the pupil plane intersects the optical axis. The term marginal ray is used to denote
a ray from the point of intersection of the object field plane with the optical axis
and which with maximum aperture opening passes through the edge of the aperture stop.
In the case of extra-axial object fields this involves a notional ray which does not
contribute to imaging of the object in the image space.
[0022] The paraxial subaperture ratio S represents a parameter that includes a sign, being
a measurement in respect of the field or pupil proximity of a plane in the optical
system. In that respect, in accordance with its definition, the subaperture ratio
is standardized to values between -1 and +1, wherein a zero point of the paraxial
subaperture ratio corresponds to each field plane and wherein a discontinuity point
with a leap in the paraxial subaperture ratio from -1 to +1 or from +1 to -1 corresponds
to each pupil plane. Accordingly planes with a paraxial subaperture ratio of at least
0.8 represent planes near the pupil whereas planes with a paraxial subaperture ratio
of a maximum 0.2 represent planes near the field. In that case the sign of the paraxial
subaperture ratio specifies the arrangement of the plane in front of or behind a reference
plane. It is possible for example to involve the sign of the point of intersection
of a coma ray in the plane in question, for definition purpose.
[0023] In accordance with an embodiment the optical system has at least two of the above-described
polarization manipulators. That design configuration has the advantage that it is
possible to limit the displacement travel of the respective individual polarization
manipulators. In accordance with an embodiment the polarization manipulators are arranged
in such a way that the paraxial subaperture ratios at the locations of those polarization
manipulators differ from each other by at least 0.1 and preferably at least 0.15.
Such a design configuration has the advantage that it is possible to influence both
field-constant pupil effects and also field variations or to achieve compensation
in that respect, by one of the polarization manipulators being arranged comparatively
closer to the field than the other of the polarization manipulators.
[0024] In accordance with an embodiment the optical system further has a wave front compensator,
that is to say an element for altering the wave front. That takes account of the fact
that, besides the desired influence on the polarization state of the light passing
therethrough, the polarization manipulator according to the invention additionally
has a scalar action or a wave front contribution which is generally undesired and
which can be compensated by the additional wave front compensator. The wave front
compensator can be a conventional, so-called Alvarez manipulator, a deformable mirror,
a deformable refractive element or an optical element which can be locally heated
and/or cooled for example by means of a flow of liquid or gas, by means of irradiation
of light of typically differing wavelength (for example infrared radiation) or by
way of heating wires.
[0025] Preferably that additional wave front compensator is arranged at a position with
a paraxial subaperture ratio which involves a sign and which is similar relative to
the polarization manipulator (for example with a paraxial subaperture ratio differing
by a maximum of 20%), whereby good wave front correction can be achieved. The inclusion
of a wave front compensator is not limited to a wave front compensator which is variable
in respect of time in its setting but it is also possible for a suitable interchangeable
element to be appropriately aspherized as the wave front compensator and to be respectively
interchanged upon adjustment of the polarization manipulator.
[0026] In accordance with an embodiment at least one of the mutually facing surfaces has
a coating. Preferably at least one of those surfaces has a reflectivity of less than
2%, preferably less than 1%. In that way it is possible to reduce or minimize unwanted
interference effects.
[0027] In accordance with an embodiment disposed between the first subelement and the second
subelement is a gap which for example can be filled with air or another (for example
inert) gas or also with a liquid medium. Preferably the gap is filled with a liquid
medium which is adapted in respect of its refractive index, that is to say the liquid
medium in the gap has a refractive index which, at a working wavelength of the optical
system, differs by less than 0.2 and preferably less than 0.15 from a mean refractive
index of the first and second subelements. Such a refractive index-adapted medium
makes it possible to reduce or minimize any unwanted wave front action on the part
of the polarization manipulator so that additional wave front compensators can be
of a simple design in their structure or can even be entirely omitted.
[0028] In accordance with a configuration the optical system has an optical axis, wherein
the position manipulator is adapted to effect one of the following changes in the
relative position of the subelements or a combination of such changes:
- displacement of at least one of the subelements in a direction perpendicular to the
optical axis;
- displacement of at least one of the subelements in a direction parallel to the optical
axis;
- rotation of at least one of the subelements about an axis of rotation parallel to
the optical axis; or
- rotation of at least one of the subelements about an axis of rotation which is not
parallel to the optical axis.
[0029] The term optical axis of an optical system is used to denote that axis (or a succession
of straight axis portions) which passes through the center points of the rotationally
symmetrical optical components of the system. In that respect an axis of rotation
which is parallel to the optical axis can coincide with or also be different from
the optical axis of the system. Furthermore an axis of rotation which is not parallel
to the optical axis of the system (that is to say an axis of rotation tilted relative
to that optical axis) can extend through a center of one of the subelements or both
subelements, or can also not extend through such a center. If the optical system is
what is referred to as an extra-axial system the axis of rotation can in particular
also pass through the center of the optically used region of the extra-axial system.
[0030] In accordance with an embodiment there can be provided a device for heating and/or
cooling at least one of the subelements. That affords an additional degree of freedom
for setting the mean refractive index of the subelements, and in particular it is
possible to set a desired effect on the wave front and it is also possible to minimize
a wave front action on the part of the polarization manipulator due to a change in
temperature.
[0031] In accordance with an embodiment the spacing between the first subelement and the
second subelement along the optical axis of the system is at a maximum 0.5 mm, preferably
at a maximum 0.4 mm, further preferably at a maximum 0.3 mm.
[0032] In accordance with an embodiment provided between the first subelement and the second
subelement is a gap which is at least partially filled with a fluid. In that case
the fluid can be both a liquid fluid and also a (possibly high-refraction) gaseous
fluid. In accordance with a preferred embodiment the fluid is a liquid medium.
[0033] In accordance with an embodiment the first subelement and the second subelement can
be made from the same material.
[0034] In accordance with a further embodiment of the invention the first subelement and
the second subelement can also be made from different materials. For example the first
subelement can be made from magnesium fluoride (MgF
2) and the second subelement can be made from sapphire (Al
2O
3). In this example therefore the first and second subelements have different signs
in their birefringence.
[0035] In particular the first subelement and the second subelement can be respectively
made from a crystal material, in which case the orientation of a crystal axis of the
first subelement can differ from the orientation of a crystal axis of the second subelement
by an angle of more than 5°, preferably by an angle of more than 10°. Insofar as in
that case different retardation distribution are mutually superposed, as a result
it is possible to set a desired integral birefringence distribution, by suitable superpositioning.
[0036] In accordance with an embodiment the polarization manipulator in a predetermined
starting position of the at least one subelement leaves unchanged the polarization
state of light passing therethrough (in particular light incident in parallel relationship
with the optical axis on the polarization manipulator).
[0037] The polarization manipulator can have both at least one subelement of positively
birefringent crystal material and also at least one subelement of negatively birefringent
crystal material. In that respect in the present case the term positively birefringent
crystal material denotes a crystal material in which the extraordinary refractive
index n
e is greater than the ordinary refractive index n
o, that is to say the value n
e-n
o is greater than zero (for example magnesium fluoride (MgF
2)). The term negatively birefringent crystal material denotes crystal material in
which the extraordinary refractive index n
e is smaller than the ordinary refractive index n
o, that is to say the value n
e-n
o is smaller than zero (for example sapphire (Al
2O
3)).
[0038] In that case, a suitable choice of the total thicknesses of positively birefringent
material on the one hand and negatively birefringent material on the other hand in
the polarization manipulator in dependence on the respective refractive indices of
the subelements, for example in a starting position of the polarization manipulator,
makes it possible to achieve a behavior which overall is substantially polarization-neutral,
wherein the variation according to the invention in the relative position of the two
subelements leads to polarization influencing which can be adjusted in the desired
manner.
[0039] In accordance with further embodiments which can be implemented in combination with
the above-specified design configurations or alternatively thereto, the two subelements
can be mechanically stressed to different or identical degrees, they can be doped
in identical or different ways and/or they can be coated in identical or different
ways. In particular such a coating can be an anti-reflection coating whereby it is
possible to reduce or minimize unwanted interference effects.
[0040] In accordance with an embodiment the polarization manipulator can be arranged interchangeably,
whereby optimum adaptation to the respective factors involved can be achieved under
different conditions of use.
[0041] In accordance with an embodiment the polarization manipulator, in a predetermined
starting position of said subelements, leaves the polarization state of light passing
therethrough unchanged.
[0042] In accordance with an embodiment the polarization manipulator is configured such
that a wave front for p-polarized light passing therethrough and a wave front for
s-polarized light passing therethrough are manipulated by said polarization manipulator
different from each other, wherein the manipulation of the mean value of the wave
fronts for p-polarized light and for s-polarized light is different from zero.
[0043] The invention further concerns a polarization manipulator comprising a first subelement
and at least one second subelement which respectively cause a change in the polarization
state for light passing therethrough and have mutually complementary aspheric surfaces,
wherein by manipulation of the relative position of the first and second subelements
relative to each other it is possible to set a change in the polarization state, that
varies with said manipulation, and wherein the polarization manipulator in a predetermined
starting position of the first and second subelements leaves the polarization state
of light passing therethrough unchanged (in particular of light incident parallel
to an element axis of the polarization manipulator or relative to the optical system
axis thereon).
[0044] In principle the system according to the invention can be any optical system, for
example a mask testing device, an illumination system, or a respective subsystem thereof.
In accordance with a preferred use the optical system is such an optical system of
a microlithographic projection exposure apparatus, in particular a projection objective
or an illumination system of the microlithographic projection exposure apparatus or
a subsystem thereof.
[0045] In accordance with a further aspect the invention also concerns a polarization manipulator,
wherein said polarization manipulator is configured such that a wave front for p-polarized
light passing therethrough and a wave front for s-polarized light passing therethrough
are manipulated by said polarization manipulator different from each other, wherein
the manipulation of the mean value of the wave fronts for p-polarized light and for
s-polarized light is different from zero.
[0046] According to this approach, the wave front for p-polarized light may in particular
be manipulated in the optical system comprising the polarization manipulator independently
and/or different (i.e. to another extent) compared to the wave front for s-polarized
light. While the mean value of the two wave fronts for p- and s-polarized light represents
what is usually referred to as the "wave front", the difference value of these two
wave fronts represents what is usually referred to as birefringence or retardation
of the system. Accordingly, the different manipulation of the wave front for p-polarized
light, on the one hand, and of the wave front for s-polarized light, on the other
hand, implies a change also in the mean value of the wave fronts for p- and s-polarized
light. Furthermore, a change in the relative positions of the first and second subelement
not only affects the birefringence, i.e. the difference between the wave fronts for
p- and s-polarized light, but also affects the mean value of the wave fronts for p-
and s-polarized light.
[0047] By deliberately exploiting a change also of the mean value of the wave fronts for
p- and s-polarized light (i.e. not only a change of birefringence), the invention
in the foregoing approach deviates from conventional approaches for polarization manipulators
where only the birefringence is manipulated and where a modification of the mean value
of the wave fronts for p- and s-polarized light is not desired and therefore avoided
(since said mean value is usually manipulated by further, additional wave front manipulators).
[0048] According the above described approach, the invention in particular enables to account
for effects such as degradation of material(s) in the optical components. Such degradations
usually have effects to both the birefringence and the mean value of the wave fronts
for p- and s-polarized light. The manipulator according to the invention may now be
configured to account for, or correct, respectively, both of these properties/quantities.
More specifically, a change in the relative positions of the first and second subelement
may be realized such that undesired changes in both the mean value and the difference
value of the wave fronts for p- and s-polarized light due to degradation of material(s)
in the optical components are at least partially compensated. Such an approach is
particularly advantageous in situations where the aforesaid degradation of material(s)
in the optical components occur in a specific and application-dependent manner as
a result of using specific illumination settings, specific mechanical stresses and
accompanying compaction effects, or other specific operating conditions. Since these
effects result in undesired changes of both the mean value and the difference value
of the wave fronts for p- and s-polarized light, the inventive approach makes it possible
to account for both of these values in a flexible manner adapted to the specific operating
conditions.
[0049] Furthermore, the foregoing inventive approach makes it possible to e.g. dynamically
enhance the correction amount concerning the mean value and the difference value of
the wave fronts for p- and s-polarized light to account for an increasing degradation
of material(s) in the optical components which may e.g. result from a continuing load
in irradiation. If W_p denotes the wave front (or "phase surface") for p-polarized
light and W_s denotes the wave front (or "phase surface") for s-polarized light, a
relative displacement of the first and second subelement by e.g. 1 mm may be given
as α*W_p + β*W_s, wherein the ratio of α and β is a specific ratio for the given manipulator.
Further, a relative displacement of the first and second subelement by e.g. 2 mm may
be given as 2α*W_p + 2β*W_s, etc.. Thereby, a dynamically increasing manipulation
of W_p and W_s may be realized to e.g. account for an increasing degradation of material(s)
in the optical components.
[0050] In accordance with a further aspect the invention concerns a microlithographic projection
exposure apparatus having an illumination system and a projection objective, wherein
the illumination system or the projection objective has an optical system having the
above-described features.
[0051] In accordance with an embodiment the projection objective has a numerical aperture
of more than 0.85, preferably more than 1.1. With numerical apertures of that kind
an essential part in the microlithographic imaging process is attributed to the polarization
effects which are correctable in accordance with the invention. The projection exposure
apparatus can be designed in particular for immersion mode of operation. The term
immersion mode is used to mean that an immersion liquid is disposed between the last
surface of the projection objective and the layer to be exposed.
[0052] In accordance with an embodiment the exposure apparatus comprises a first disturbance
of the mean value of the wave fronts for p- and s-polarized light and a second disturbance
of the difference value of the wave fronts for p- and s-polarized light, wherein said
first disturbance and said second disturbance are each at least partially compensated
by said polarization manipulator.
[0053] The invention further concerns a process for the microlithographic production of
microstructured components.
[0054] Further configurations of the invention are to be found in the description and the
appendant claims.
[0055] The invention is described in greater detail hereinafter by means of embodiments
by way of example illustrated in the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
[0056] In the drawings:
- Figure 1
- shows a diagrammatic view of a polarization manipulator according to the invention
in a first embodiment,
- Figure 2
- shows a diagrammatic view of a polarization manipulator according to the invention
in a further embodiment,
- Figures 3a-b
- show a distribution by way of example of a retardation to be compensated (in nm) by
virtue of polarization-induced birefringence and the associated orientation of the
fast axis of said birefringence (Figure 3b),
- Figure 4
- shows a configuration, suitable for compensation of the retardation distribution in
Figure 3a, in respect of the amplitude of the separation asphere in the polarization
manipulator of Figure 2,
- Figures 5a-b
- show the distribution of the respective orientations of the fast axis of the birefringence
for a predetermined disturbance to be compensated (Figure 5a) and for the polarization
manipulator according to the invention as shown in Figure 2 (Figure 5b),
- Figure 6
- shows a structure in principle by way of example of a microlithographic projection
exposure apparatus,
- Figures 7-12
- show by way of example embodiments of projection objectives in meridional section,
and
- Figures 13a-e
- show diagrammatic views of embodiments by way of example of one or more subelements
which can be used in an optical system according to the invention.
DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
[0057] Reference is made to Figure 1 to firstly describe the structure in principle of a
polarization mar
iipulator 100 according to the invention. It has a first subelement 110 and a second
subelement 120 which in the illustrated embodiment are each made from magnesium fluoride
(MgF
2) and have mutually facing aspheric surfaces 110a and 120a respectively, those aspheric
surfaces 110a and 120a being mutually complementary. As in this embodiment the other
surfaces of the subelements 110 and 120 are each planar surfaces the two subelements
110 and 120 thus supplement each other to afford an overall plane-parallel geometry.
[0058] The relative position of the two subelements 110 and 120 of the polarization manipulator
100 is variable, wherein that variation, as shown in Figure 1, can be implemented
in the x-direction in the illustrated coordinate system by way of an only diagrammatically
illustrated position manipulator 150. In that respect it is assumed in Figure 1 that
the optical axis of the optical system arid the light propagation direction extend
in the z-direction so that the relative displacement of the optical elements 110 and
120 here occurs perpendicularly to that optical axis. The invention however is not
limited thereto, in which respect the change in the relative position of the subelements
110 and 120 can alternatively or additionally also include displacement of at least
one of the subelements 110, 120 in a direction along the optical axis (z-direction),
rotation of at least one of the subelements 110, 120 abut an axis of rotation parallel
to the optical axis or rotation of at least one of the subelements 110, 120 about
an axis of rotation which is not parallel to the optical axis.
[0059] The orientation of the optical crystal axis in the crystal material of the subelements
110 and 120 in the illustrated embodiment extends in each case in the plane perpendicular
to the optical axis of the optical system, for example in the y-direction, so that
the retardation caused by the respective subelement is proportional to the thickness
of that subelement. In that respect the orientation of the optical crystal axis of
the first subelement 110 preferably differs from the orientation of the optical crystal
axis of the second subelement 120 by an angle of more than 5°, preferably by an angle
of more than 10°.
[0060] The invention is not limited to the configuration of the subelements of a crystal
material with linear birefringence as shown in Figure 1. Rather one or both subelements
in alternative embodiments can also be made from an optically active material involving
circular birefringence (for example crystalline quartz with orientation of the optical
crystal axis parallel to the light propagation direction) and/or a material which
causes a change in the polarization state by transmission splitting between orthogonal
polarization states, that is to say by a change in the amplitude relationship of orthogonal
polarization states in dependence on the orientations thereof. Materials suitable
for that purpose are those which, at the working wavelength of for example 193 nm,
have natural dichroism (similar to turmalin), for example crystalline quartz, calcite
(CaCO
3) or Ba
3(B
3O
6)
2(BBO).
[0061] Furthermore the possibly linear birefringence in one or both subelements 110, 120
can also be implemented using cubically crystalline material which can be put under
compression or tensile stress (for example (CaF
2, BaF
2, LiBaF
3, Lu
3Al
5O
12, Y
3Al
5O
12 or MgAl
2O
4), by using amorphous material which can be put under compression or tensile stress
(for example quartz glass (SiO
2)) or by using another optically uniaxial crystalline material than MgF
2 (for example LaF
3, Al
2O
3 or SiO
2 with a crystal axis which is not parallel to the light propagation direction).
[0062] Figures 13a - e diagrammatically show embodiments by way of example of a subelement
which can be used in an optical system according to the invention, wherein the illustrated
double-headed arrows respectively indicate the manipulation of the position of the
subelement in relation to the optical axis OA of the optical system, which manipulation
can be achieved by means of the position manipulator (not shown in Figures 13a through
13e).
[0063] In that respect the subelement can be for example a subelement 51 having an aspheric
optical active surface (Figure 13a). Furthermore the subelement can also be a subelement
having a non-planar but spherical optical active surface (Figure 13b). Figures 13c
and 13d show arrangements 53 and 54 comprising two subelements 53a, 53b and 54a, 54b
respectively having respectively mutually facing optical active surfaces which are
complementary to each other and of a spherical configuration, wherein the change in
the relative position of those subelements can be implemented both by displacement
(Figure 13c, in which the displacement is effected only by way of example in a plane
perpendicular to the optical axis OA) and also by rotation (Figure 13d in which the
rotation is effected only by way of example about the optical axis OA). In that respect
a respective maximum effective retardation introduced by the subelement along the
optical axis is less than a quarter of the working wavelength of the optical system.
[0064] Figure 13e, in accordance with another also possible approach, shows an arrangement
55 comprising two subelements 55a and 55b in respect of which the birefringence distribution
respectively varies within the subelements in a direction perpendicular to the optical
axis OA, wherein that variation is here produced not by means of a thickness variation
of the subelements but by means of a positional variation of the birefringence (for
example a varying stress birefringence).
[0065] Figure 2 shows a further embodiment of a polarization manipulator 200 according to
the invention. Firstly, in a structure similar to Figure 1, this polarization manipulator
200 includes two subelements 210 and 220 which are each made from magnesium fluoride
(MgF
2) and have mutually facing aspheric and mutually complementary surfaces 210a and 220a
respectively, a position manipulator 250 for changing the relative position and in
addition a plane plate 230 which is made from sapphire (Al
2O
3) and which is arranged with its light entrance and light exit surfaces parallel to
the light entrance and light exit surfaces respectively of the subelements 210 and
220. As magnesium fluoride (MgF
2) is an optically positive material (n
e-n
o= 0.0135 > 0) and sapphire (Al
2O
3) is a negatively birefringent material (n
e-n
o = -0.0133 < 0), a suitable choice of the (marginal) thicknesses d
1, d
2 and d
3 can provide that, in the starting position shown in Figure 2 of the polarization
manipulator, for light which is propagated in the z-direction, there is not a resulting
birefringent effect on the part of the overall arrangement. By way of example it is
possible for that purpose to select the thicknesses d
1 = d
2 = 2.5 mm and d
3 = 5.973 mm. Then, as described hereinafter, polarization influencing can be adjusted
in the desired fashion by way of a variation in the relative position of the two subelements.
[0066] In terms of the specific configuration of the aspheric surfaces 210a and 220a, the
positional dependency of which is described by a function T(x,y) referred to hereinafter
as the separation asphere, the basic starting point adopted hereinafter is a predetermined
disturbance to be compensated in the optical system or a suitably selected thickness
profile in the magnesium fluoride material, wherein the last-mentioned thickness profile
can be described by a thickness function D(x,y). The aforementioned separation sphere
T(x,y) is then given by the antiderivative or the integral of the desired thickness
function D(x,y), that, is to say the following applies:

[0067] The amplitude of the retardation afforded by the polarization manipulator 100 or
200 respectively is now proportional to the relative displacement of the subelements
110, 120 and 210, 220 respectively and proportional to the amplitude of the separation
asphere T(x,y).
[0068] Figure 3a shows the example of a retardation distribution (in nm) to be compensated,
which is caused by polarization-induced birefringence in the optical system, wherein
respectively standardized pupil coordinates are plotted on the axes of the diagram
and also in the further diagrams in Figure 3b and Figures 5a - b. Figure 3b shows
the associated orientation of the fast axis of that birefringence. Figure 4 shows
a variation, which is suitable in accordance with equation (2) for compensation of
the disturbance of Figure 3a, in the amplitude of the separation asphere T(x,y) in
the polarization manipulator of Figure 2. As can be seen from a comparison of Figure
5a and 5b the respective orientations of the fast axis of the birefringence for a
predetermined disturbance to be compensated (Figure 5a) and for the polarization manipulator
according to the invention (Figure 5b) are mutually perpendicular.
[0069] The concrete calculation shows that, for the relative displacements of the two subelements
210 and 220 of up to 250 µm, the maximum amplitude of the separation asphere T(x,y)
is at about ± 193 µm to afford a retardation of about 10 nm.
[0070] Figure 6 is an only diagrammatic view to illustrate the structure in principle of
a microlithographic projection exposure apparatus in accordance with an embodiment
of the invention. In this case the concept of the invention can be applied equally
both in the illumination system and also in the projection objective. Positions by
way of example, which are suitable for the arrangement of polarization manipulators
according to the invention (namely positions near the pupil, near the image or near
the intermediate image, or intermediate positions) are only diagrammatically indicated
by arrows in Figure 6.
[0071] The microlithographic projection exposure apparatus has am illumination system 301
and a projection objective 302. The illumination system 301 serves for the illumination
of a structure-bearing mask (reticle) 303 with light from a light source unit 304
which for example includes an ArF laser for a working wavelength of 193 nm and a beam-shaping
optical means for producing a parallel light beam. The parallel light beam from the
light source unit 304 is firstly incident on a diffractive optical element 305 which
produces a desired intensity distribution (for example dipole or quadrupole distribution)
in a pupil plane P1 by way of an angle beam radiation characteristic defined by the
respective diffractive surface structure. Disposed downstream of the diffractive optical
element 305 in the light propagation direction is an optical unit 306 having a zoom
objective for producing a parallel light beam of variable diameter and an axicon lens.
Different illumination configurations are produced in the pupil plane P1 depending
on the respective zoom setting and position of the axicon elements, by means of the
zoom objective in conjunction with the upstream-disposed diffractive optical element
305. The optical unit 306 in the illustrated embodiment further includes a deflection
mirror 307. Disposed downstream of the pupil plane P1 in the beam path in the light
propagation direction is a light mixing device 308 which for example in per se known
manner can have an arrangement of microoptical elements, that is suitable for achieving
a light mixing effect. The light mixing device 308 is followed in the light propagation
direction by a lens group 309, downstream of which is disposed a field plane F1 with
a reticle masking system (REMA) which is projected by an REMA objective 310 that follows
in the light propagation direction onto the structure-bearing mask (reticle) 303 in
the field plane F2, and thereby delimits the illuminated region on the reticle. The
structure-bearing mask 303 is now projected onto a substrate 311 or wafer provided
with a light-sensitive layer with the projection objective 302 which in the illustrated
example has two pupil planes PP1 and PP2.
[0072] In addition Figures 7 through 12 show specific designs by way of example of projection
objectives in which one or more polarization manipulators can be arranged as described
hereinbefore.
[0073] Figure 7 shows a projection objective 400 in meridional section, which is disclosed
in
WO 2003/075096 A2 (see therein Figure 8 and Table 8). The projection objective 400 is of a purely refractive
structure with a waist and a first positive lens group, a second negative lens group
and a third positive lens group.
[0074] Figure 8 shows a projection objective 500 in meridional section, which is disclosed
in
WO 2004/019128 A2 (see therein Figure 19 and Tables 9 and 10). The projection objective 500 includes
a first refractive subsystem 510, a second catadioptric subsystem 530 and a third
refractive subsystem 540 and is therefore also referred to as an "RCR system". In
that respect the term "subsystem" is always used to denote such an arrangement of
optical elements, by which a real object is imaged as a real image or intermediate
image. In other words, each subsystem, starting from a given object or intermediate
image plane, always includes all optical elements to the next real image or intermediate
image.
[0075] The first refractive subsystem 510 includes refractive lenses 511 through 520, after
which a first intermediate image IMI1 is produced in the beam path. The second subsystem
530 includes a double-fold mirror with two mirror surfaces 531 and 532 arranged at
an angle relative to each other, wherein light incident from the first subsystem 510
is firstly reflected at the mirror surface 531 in the direction towards the lenses
533 and 534 and a subsequent concave mirror 535. The concave mirror 535 in per se
known manner permits effective compensation of the image field curvature produced
by the subsystems 510 and 540. The light reflected at the concave mirror 535 is reflected
after again passing through the lenses 534 and 533 at the second mirror surface 532
of the double-fold mirror so that as a result of the optical axis OA is folded twice
through 90°. The second subsystem 530 produces a second intermediate image IMI2 and
the light therefrom is incident on the third refractive subsystem 540 including refractive
lenses 541 through 555. The second intermediate image IMI2 is projected onto the image
plane IP by the third refractive subsystem 540.
[0076] Referring to Figure 9 shown therein is a projection objective 600 in meridional section,
which is disclosed in
WO 2005/069055 A2 (see therein Figure 32). The design data of that projection objective 400 are set
out in Table 1. In that respect column 1 gives the number of the respective refractive
or otherwise distinguished optical surface, column 2 gives the radius of that surface
(in mm), column 3 optionally includes a reference to an asphere at that surface, column
4 gives the spacing, identified as thickness, of that surface relative to the following
surface (in mm), column 5 gives the material following the respective surface and
column 6 gives the optically useable free half diameter (in mm) of the optical component.
[0077] The aspheric constants are to be found in Table 2. The surfaces identified by thick
dots in Figure 9 and specified in Tables 1 and 2 are aspherically curved, the curvature
of those surfaces being given by the following asphere formula:

[0078] Therein P denotes the camber height of the surface in question parallel to the optical
axis, h denotes the radial spacing from the optical axis, r denotes the radius of
curvature of the surface in question, cc denotes the conical constant (identified
by K in Table 7) and C
1, C
2, ... denote the asphere constants set forth in Table 2.
[0079] Referring to Figure 9 the projection objective 600 in a catadioptric structure has
a first optical subsystem 610, a second optical subsystem 620 and a third optical
subsystem 630. The first optical subsystem 610 includes an arrangement of refractive
lenses 611 through 617 and projects the object plane "OP" into a first intermediate
image IMI1, the approximate position of which is indicated by an arrow in Figure 9.
That first intermediate image IMI1 is projected through the second optical subsystem
620 into a second intermediate image IMI2, the approximate position of which is also
indicated by an arrow in Figure 9. The second optical subsystem 620 includes a first
concave mirror 621 and a second concave mirror 622 which are each "cut off" in a direction
perpendicular to the optical axis, in such a way that light propagation can respectively
occur from the reflecting surfaces of the concave mirrors 621, 622 to the image plane
IP. The second intermediate image IMI2 is projected into the image plane IP by the
third optical subsystem 630. The third optical subsystem 630 includes an arrangement
of refractive lenses 631 through 643.
[0080] Referring to Figure 10 shown therein is a further catadioptric projection objective
700 in meridional section, which is disclosed in
WO 2005/069055 A2 (see therein Figure 39 and Tables 39, 39A) and which has a total of four mirrors.
Referring to Figure 11 shown therein is a further catadioptric projection objective
800 in meridional section, which is disclosed in
WO 2005/069055 A2 (see therein Figure 21 and Tables 21, 21A) and which has two mirrors with lenses
disposed therebetween. Referring to Figure 12 shown therein is a further catadioptric
projection objective 900 in meridional section which is disclosed in
EP 1 480 065 A2 (see therein Figure 19) and which has telecentric deflection mirrors, such telecentry
being afforded by a positive group between those deflection mirrors. Further designs
for catadioptric projection objectives with an intermediate image are disclosed for
example in
US 6 665 126 B2.
[0081] Even if the invention has been described by reference to specific embodiments numerous
variations and alternative embodiments will be apparent to the man skilled in the
art, for example by combination and/or exchange of features of individual components.
Accordingly it will be apparent to the man skilled in the art that such variations
and alternative embodiments are also embraced by the present invention and the scope
of the invention is limited only in the sense of the accompanying claims and equivalents
thereof.
Table 1 (DESIGN DATA FOR Fig. 9):
| Surface |
Radius |
Sphere |
Thickness |
Material |
Half diameter |
| 1 |
0.000000 |
|
-0.011620 |
LV193975 |
75.462 |
| 2 |
585.070331 |
AS |
17.118596 |
SIO2V |
76.447 |
| 3 |
-766.901651 |
|
0.890161 |
HEV19397 |
78.252 |
| 4 |
145.560665 |
|
45.675278 |
SIO2V |
85.645 |
| 5 |
2818.543789 |
AS |
40.269525 |
HEV19397 |
83.237 |
| 6 |
469.396236 |
|
29.972759 |
SIO2V |
75.894 |
| 7 |
-193.297708 |
AS |
21.997025 |
HEV19397 |
73.717 |
| 8 |
222 509238 |
|
27 666363 |
SIO2V |
57.818 |
| 9 |
-274.231957 |
|
31.483375 |
HEV19397 |
52.595 |
| 10 |
0.000000 |
|
10.117766 |
SIO2V |
44.115 |
| 11 |
0.000000 |
|
15.361487 |
HEV19397 |
47.050 |
| 12 |
26971.109897 |
AS |
14.803554 |
SIO2V |
54.127 |
| 13 |
-562.070426 |
|
45.416373 |
HEV19397 |
58.058 |
| 14 |
-510.104298 |
AS |
35.926312 |
SIO2V |
76.585 |
| 15 |
-118.683707 |
|
36.432152 |
HEV19397 |
80.636 |
| 16 |
0.000000 |
|
199.241665 |
HEV19397 |
86.561 |
| 17 |
-181.080772 |
AS |
-199.241665 |
REFL |
147.684. |
| 18 |
153.434246 |
AS |
199.241665 |
REFL |
102.596 |
| 19 |
0.000000 |
|
36.432584 |
HEV19397 |
105.850 |
| 20 |
408.244008 |
|
54.279598 |
SIO2V |
118.053 |
| 21 |
-296.362521 |
|
34.669451 |
HEV19397 |
118.398 |
| 22 |
-1378.452784 |
|
22.782283 |
SIO2V |
106.566 |
| 23 |
-533.252331 |
AS |
0.892985 |
HEV19397 |
105.292 |
| 24 |
247.380841 |
|
9.992727 |
SIO2V |
92.481 |
| 25 |
103.088603 |
|
45.957039 |
HEV19397 |
80.536 |
| 26 |
-1832.351074 |
|
9.992069 |
SIO2V |
80.563 |
| 27 |
151.452362 |
|
28.883857 |
HEV19397 |
81.238 |
| 28 |
693.739003 |
|
11.559320 |
SIO2V |
86.714 |
| 29 |
303.301679 |
|
15.104783 |
HEV19397 |
91.779 |
| 30 |
1016.426625 |
|
30.905849 |
SIO2V |
95:900 |
| 31 |
-258.080954 |
AS |
10.647394 |
HEV19397 |
99.790 |
| 32 |
-1386.614747 |
AS |
24.903261 |
SIO2V |
108.140 |
| 33 |
-305.810572 |
|
14.249112 |
HEV19397 |
112.465 |
| 34 |
-11755.656826 |
AS |
32.472684 |
SIO2V |
124.O75 |
| 35 |
-359.229865 |
|
16.650084 |
HEV19397 |
126.831 |
| 36 |
1581.896158 |
|
51.095339 |
SIO2V |
135.151 |
| 37 |
-290.829022 |
|
-5.686977 |
HEV19397 |
136.116 |
| 38 |
0.000000 |
|
0.000000 |
HEV19397 |
131.224 |
| 39 |
0.000000 |
|
28.354383 |
HEV19397 |
131.224 |
| 40 |
524.037274 |
AS |
45.835992 |
SIO2V |
130.144 |
| 41 |
-348.286331 |
|
0.878010 |
HEV19397 |
129.553 |
| 42 |
184.730622 |
|
45.614622 |
SIO2V |
108.838 |
| 43 |
2501.302312 |
AS |
0.854125 |
HEV19397 |
103.388 |
| 44 |
89.832394 |
|
38.416586 |
SIO2V |
73.676 |
| 45 |
209.429378 |
|
0.697559 |
HEV19397 |
63.921 |
| 46 |
83.525032 |
|
37.916651 |
CAF2V193 |
50.040 |
| 47 |
0.000000 |
|
0.300000 |
SIO2V |
21.480 |
| 48 |
0.000000 |
|
0.000000 |
SIO2V |
21.116 |
| 49 |
0.000000 |
|
3.000000 |
H2OV193B |
21.116 |
| 50 |
0.000000 |
|
0.000000 |
AIR |
16.500 |

[0082] The present invention further comprises the aspects defined in the following clauses,
which form part of the present description but are not claims, in accordance with
decision J15/88 of the European Patent Office legal board of appeal.
- 1. An optical system which has an optical axis (OA), comprising
- at least one polarization manipulator (100, 200) having a first subelement, (110,
210) which has a non-planar, optically effective surface and for light passing therethrough
causes a change in the polarization state, wherein a maximum effective retardation
introduced by the first subelement along the optical axis (OA) is less than a quarter
of the working wavelength of the optical system, and a second subelement (120, 220),
wherein said first subelement and said second subelement have mutually facing surfaces
(110a, 120a; 210a, 220a) which are mutually complementary; and
- a position manipulator (150, 250) for manipulation of the relative position of said
first subelement (110, 210) and said second subelement (120, 220).
- 2. An optical system as set forth in clause 1, characterized in that at least one
of said mutually facing surfaces (110a, 120a; 210a, 220a) is aspheric.
- 3. An optical system as set forth in clause 1 or 2, characterized that at least one
subelement (110, 210, 120, 220) for light passing therethrough causes a change in
the polarization state by linear birefringence, circular birefringence and/or by a
change in the amplitude relationship of orthogonal polarization states in dependence
on the orientations thereof.
- 4. An optical system as set forth in one of the clauses 1 through 3, characterized
in that the polarization manipulator (100, 200) is arranged in a plane in which the
paraxial subaperture ratio is at least 0.8.
- 5. An optical system as set forth in one of the clauses 1 through 3, characterized
in that the polarization manipulator (100, 200) is arranged in a plane in which the
paraxial subaperture ratio is at a maximum 0.2.
- 6. An optical system as set forth in one of the preceding clauses, characterized in
that it has at least two such polarization manipulators.
- 7. An optical system as set forth in clause 6, characterized in that the polarization
manipulators are arranged in such a way that the paraxial subaperture ratios at the
locations of those polarization manipulators differ from each other by at least 0.1
and preferably at least 0.15.
- 8. An optical system as set forth in one of the preceding clauses, characterized in
that it further has a wave front compensator for at least partial compensation of
a change, caused by the polarization compensator (100, 200), in the wave front of
light passing through the optical system.
- 9. An optical system as set forth in one of the preceding clauses, characterized in
that at least one of the mutually facing surfaces has a coating.
- 10. An optical system as set forth in one of the preceding clauses, characterized
in that at least one of the mutually facing surfaces has a reflectivity of less than
2%, preferably less than 1%.
- 11. An optical system as set forth in one of the preceding clauses, characterized
in that at least one subelement is produced from a material selected from the group
which contains:
- a cubically crystalline material which is put under compression or tensile stress,
- an amorphous material which is put under compression or tensile stress, or
- an optically uniaxial crystalline material.
- 12. An optical system as set forth in clause 11, characterized in that the cubically
crystalline material which is put under compression or tensile stress is selected
from the group which contains: calcium fluoride (CaF2), barium fluoride (BaF2), lithium barium fluoride (LiBaF3), garnets, in particular lutetium aluminum garnet (Lu3Al5O12) and yttrium aluminum garnet (Y3Al5O12) and spinel, in particular magnesium spinel (MgAl2O4).
- 13. An optical system as set forth in clause 11 or clause 12, characterized in that
the optically uniaxial crystalline material is selected from the group which contains:
magnesium fluoride (MgF2), lanthanum fluoride (LaF3), sapphire (Al2O3) and crystalline quartz (SiO2).
- 14. An optical system as set forth in one of the preceding clauses, characterized
in that the position manipulator (150, 250) is adapted to effect one of the following
changes in the position of at least one subelement (110, 120; 210, 220) or a combination
of such changes:
- displacement of at least one subelement (110, 120; 210, 220) in a direction perpendicular
to the optical axis;
- displacement of at least one subelement (110, 120; 210, 220) in a direction parallel
to the optical axis; and
- rotation of at least one subelement (110, 120; 210, 220).
- 15. An optical system as set forth in clause 14, characterized in that the rotation
is about an axis of rotation which is parallel to the optical axis.
- 16. An optical system as set forth in clause 14, characterized in that the rotation
is about an axis of rotation which is not parallel to the optical axis.
- 17. An optical system as set forth in one of the preceding clauses, characterized
in that the maximum spacing between the first subelement (110, 210) and the second
subelement (120, 220) is at a maximum 0.5 mm, preferably at a maximum 0.4 mm, further
preferably at a maximum 0.3 mm.
- 18. An optical system as set forth in one of the preceding clauses, characterized
in that provided between the first subelement (110, 210) and the second subelement
(120, 220) is a gap which is at least partially filled with a fluid.
- 19. An optical system as set forth in clause 18, characterized in that the fluid is
a liquid medium.
- 20. An optical system as set forth in clause 19, characterized in that said liquid
medium has a refractive index which at a working wavelength of the optical system
differs by less than 0.2, preferably by less than 0.15, from a mean refractive index
of the first and second subelements.
- 21. An optical system as set forth in one of the clauses 1 through 20, characterized
in that the first subelement (110, 210) and the second subelement (120, 220) are made
from the same material.
- 22. An optical system as set forth in one of the clauses 1 through 20, characterized
in that the first subelement (110, 210) and the second subelement (120, 220) are made
from different materials.
- 23. An optical system as set forth in clause 22, characterized in that the polarization
manipulator has both positively birefringent crystal material and also negatively
birefringent crystal material.
- 24. An optical system as set forth in one of the preceding clauses, characterized
in that the first subelement (110, 210) and the second subelement (120, 220) are respectively
made from an optically uniaxial crystal material, in which case the orientation of
a crystal axis of the first subelement (110, 210) differs from the orientation of
a crystal axis of the second subelement (120, 220) by an angle of more than 5°, preferably
by an angle of more than 10°.
- 25. An optical system as set forth in one of the preceding clauses, characterized
in that there is provided an interchange device for interchange of the polarization
manipulator (100, 200).
- 26. An optical system as set forth in one of the preceding clauses, characterized
in that the polarization manipulator in a predetermined starting position of the at
least one subelement leaves the polarization state of light passing therethrough unchanged.
- 27. An optical system as set forth in one of the preceding clauses, characterized
in that it is designed for a working wavelength of less than 400 nm, preferably less
than 250 nm.
- 28. An optical system as set forth in one of the preceding clauses, characterized
in that it is an optical system of a microlithographic projection exposure apparatus
- 29. An optical system as set forth in one of the preceding clauses, characterized
in that the polarization manipulator is configured such that a wave front for p-polarized
light passing therethrough and a wave front for s-polarized light passing therethrough
are manipulated by said polarization manipulator different from each other, wherein
the manipulation of the mean value of the wave fronts for p-polarized light and for
s-polarized light is different from zero.
- 30. A polarization manipulator comprising:
- a first subelement and at least one second subelement which respectively cause a change
in the polarization state for light passing therethrough and have mutually complementary
aspheric surfaces,
- wherein by manipulation of the relative position of the first and second subelements
relative to each other it is possible to set a change in the polarization state, that
varies with said manipulation, and wherein the polarization manipulator in a predetermined
starting position of the first and second subelements leaves the polarization state
of light passing therethrough unchanged.
- 31. A polarization manipulator, wherein said polarization manipulator is configured
such that a wave front for p-polarized light passing therethrough and a wave front
for s-polarized light passing therethrough are manipulated by said polarization manipulator
different from each other, wherein the manipulation of the mean value of the wave
fronts for p-polarized light and for s-polarized light is different from zero.
- 32. A polarization manipulator as set forth in clause 31, comprising
- a first subelement and at least one second subelement which respectively cause a change
in the polarization state for light passing therethrough and have mutually complementary
surfaces,
- wherein by manipulation of the relative position of the first and second subelements
relative to each other it is possible to set a change in the polarization state of
light passing through said polarization manipulator, that varies with said manipulation.
- 33. A microlithographic projection exposure apparatus comprising an illumination system
(301) and a projection objective (302), wherein the illumination system (301) and/or
the projection objective (302) has an optical system as set forth in one of clauses
1 through 29 or a polarization manipulator as set forth in one of the clauses 30 through
32.
- 34. A microlithographic projection exposure apparatus as set forth in clause 33, characterized
in that the projection objective (302) has a numerical aperture of more than 0.85,
preferably more than 1.1.
- 35. A microlithographic projection exposure apparatus as set forth in clause 33 or
34, characterized in that it is adapted for an immersion mode of operation.
- 36. A microlithographic projection exposure apparatus as set forth in one of the clauses
33 through 35, characterized in that it comprises a first disturbance of the mean
value of the wave fronts for p- and s-polarized light and a second disturbance of
the difference value of the wave fronts for p- and s-polarized light, wherein said
first disturbance and said second disturbance are each at least partially compensated
by said polarization manipulator.
- 37. A process for the microlithographic production of microstructured components comprising
the following steps:
- providing a substrate (311) to which a layer of a light-sensitive material is at least
partially applied;
- providing a mask (303) having structures to be reproduced;
- providing a microlithographic projection exposure apparatus as set forth in one of
clauses 33 through 36; and
- projecting at least a part of the mask (303) onto a region of the layer by means of
the projection exposure apparatus.
1. An optical system which has an optical axis (OA), comprising
• at least one polarization manipulator (100, 200) having a first subelement (110,
210) which has a non-planar, optically effective surface and for light passing therethrough
causes a change in the polarization state, wherein a maximum effective retardation
introduced by the first subelement along the optical axis (OA) is less than a quarter
of the working wavelength of the optical system, and a second subelement (120, 220),
wherein said first subelement and said second subelement have mutually facing surfaces
(110a, 120a; 210a, 220a) which are mutually complementary, and
• a position manipulator (150, 250) for manipulation of the relative position of said
first subelement (110, 210) and said second subelement (120, 220); characterized in that the position manipulator (150, 250) is adapted to effect one of the following changes
in the position of at least one subelement (110, 120; 210, 220) or a combination of
such changes:
- displacement of at least one of said subelelments (110, 120; 210, 220) in a direction
perpendicular to the optical axis; and
- rotation of at least one of said subelements (110, 120; 210, 220).
2. An optical system as set forth in claim 1, characterized in that at least one of said mutually facing surfaces (110a, 120a; 210a, 220a) is aspheric.
3. An optical system as set forth in claim 1 or 2, characterized that at least one of
said subelements (110, 210, 120, 220) for light passing therethrough causes a change
in the polarization state by linear birefringence, circular birefringence and/or by
a change in the amplitude relationship of orthogonal polarization states in dependence
on the orientations thereof.
4. An optical system as set forth in one of the preceding claims, characterized in that it has at least two such polarization manipulators, wherein the polarization manipulators
are arranged in such a way that the paraxial subaperture ratios at the locations of
those polarization manipulators differ from each other by at least 0.1 and preferably
at least 0.15.
5. An optical system as set forth in one of the preceding claims, characterized in that it further has a wave front compensator for at least partial compensation of a change,
caused by the polarization manipulator (100, 200), in the wave front of light passing
through the optical system.
6. An optical system as set forth in one of the preceding claims,
characterized in that at least one of said subelements is produced from a material selected from the group
which contains:
- a cubically crystalline material which is put under compression or tensile stress,
- an amorphous material which is put under compression or tensile stress, or
- an optically uniaxial crystalline material.
7. An optical system as set forth in one of the preceding claims,
characterized in that the position manipulator (150, 250) is further adapted to effect the following change
in the position of at least one subelement (110, 120; 210, 220):
- displacement of at least one of said subelements (110, 120; 210, 220) in a direction
parallel to the optical axis.
8. An optical system as set forth in one of the claims 1 through 7, characterized in that the rotation is about an axis of rotation which is parallel to the optical axis.
9. An optical system as set forth in one of the claims 1 through 7, characterized in that the rotation is about an axis of rotation which is not parallel to the optical axis.
10. An optical system as set forth in one of the preceding claims, characterized in that provided between the first subelement (110, 210) and the second subelement (120,
220) is a gap which is at least partially filled with a fluid.
11. An optical system as set forth in claim 10, characterized in that the fluid is a liquid medium, wherein said liquid medium has a refractive index which
at a working wavelength of the optical system differs by less than 0.2, preferably
by less than 0.15, from a mean refractive index of the first and second subelements.
12. An optical system as set forth in one of the claims 1 through 11, characterized in that the first subelement (110, 210) and the second subelement (120, 220) are made from
the same material.
13. An optical system as set forth in one of the claims 1 through 11, characterized in that the first subelement (110, 210) and the second subelement (120, 220) are made from
different materials, wherein the polarization manipulator has both positively birefringent
crystal material and also negatively birefringent crystal material.
14. An optical system as set forth in one of the preceding claims, characterized in that the polarization manipulator in a predetermined starting position of the at least
one subelement leaves the polarization state of light passing therethrough unchanged.
15. An optical system as set forth in one of the preceding claims, characterized in that the polarization manipulator is configured such that a wavefront for p-polarized
light passing therethrough and a wavefront for s-polarized light passing therethrough,
are manipulated by said polarization manipulator differently from each other, wherein
the manipulation of the mean value of the wave fronts for p-polarized light and for
s-polarized light is different from zero.
1. Optisches System, das eine optische Achse (OA) aufweist, aufweisend
• mindestens einen Polarisationsmanipulator (100, 200) mit einem ersten Unterelement
(110, 210), das eine nicht plane, optisch effektive Oberfläche aufweist und für Licht,
das dort hindurchdringt, eine Änderung des Polarisationszustands bewirkt, wobei eine
maximale effektive Verzögerung, die durch das erste Unterelement entlang der optischen
Achse (OA) eingeleitet ist, geringer als ein Viertel der Arbeitswellenlänge des optischen
Systems ist, und mit einem zweiten Unterelement (120, 220), wobei das erste Unterelement
und das zweite Unterelement einander zugekehrte Oberflächen (110a, 120a; 210a, 220a)
aufweisen, die komplementär zueinander sind; und
• einen Positionsmanipulator (150, 250) zur Manipulation der relativen Position des
ersten Unterelements (110, 210) und des zweiten Unterelements (120, 220); dadurch gekennzeichnet, dass der Positionsmanipulator (150, 250) dazu geeignet ist, eine der folgenden Änderungen
der Position von mindestens einem Unterelement (110, 120; 210, 220) oder eine Kombination
derartiger Änderungen auszuführen:
- Verschiebung von mindestens einem der Unterelemente (110, 120; 210, 220) in einer
senkrecht zur optischen Achse verlaufenden Richtung; und
- Drehung von mindestens einem der Unterelemente (110, 120; 210, 220).
2. Optisches System nach Anspruch 1, dadurch gekennzeichnet, dass mindestens eine der einander zugekehrten Oberflächen (110a, 120a; 210a, 220a) asphärisch
ist.
3. Optisches System nach einem der Ansprüche 1 oder 2, dadurch gekennzeichnet, dass mindestens eines der Unterelemente (110, 210, 120, 220) für Licht, das dort hindurchdringt,
eine Änderung des Polarisationszustands durch lineare Doppelbrechung, kreisförmige
Doppelbrechung und/oder durch eine Änderung der Amplitudenbeziehung von orthogonalen
Polarisationszuständen in Abhängigkeit von Ausrichtungen derselben bewirkt.
4. Optisches System nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass es mindestens zwei derartige Polarisationsmanipulatoren aufweist, wobei die Polarisationsmanipulatoren
derart angeordnet sind, dass die paraxialen Subaperturverhältnisse an den Standorten
dieser Polarisationsmanipulatoren um mindestens 0,1 und bevorzugt mindestens 0,15
voneinander abweichen.
5. Optisches System nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass es ferner einen Wellenfrontkompensator zur mindestens Teilkompensation einer Änderung,
die durch den Polarisationsmanipulator (100, 200) bewirkt ist, in der Wellenfront
von Licht, das das optische System durchdringt, aufweist.
6. Optisches System nach einem der vorhergehenden Ansprüche,
dadurch gekennzeichnet, dass mindestens eines der Unterelemente aus einem Material erzeugt ist, das aus der Gruppe
ausgewählt ist, die Folgendes enthält:
- ein kubisch kristallines Material, das unter Kompression oder Zugspannung gesetzt
ist,
- ein amorphes Material, das unter Kompression oder Zugspannung gesetzt ist, oder
- ein optisch einachsiges kristallines Material.
7. Optisches System nach einem der vorhergehenden Ansprüche,
dadurch gekennzeichnet, dass der Positionsmanipulator (150, 250) ferner zum Ausführen der folgenden Änderung der
Position von mindestens einem Unterelement (110, 120; 210, 220) geeignet ist:
- Verschiebung von mindestens einem der Unterelemente (110, 120; 210, 220) in einer
parallel zur optischen Achse verlaufenden Richtung.
8. Optisches System nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass die Drehung um eine Drehachse verläuft, die parallel zur optischen Achse ist.
9. Optisches System nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass die Drehung um eine Drehachse verläuft, die nicht parallel zur optischen Achse ist.
10. Optisches System nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass zwischen dem ersten Unterelement (110, 210) und dem zweiten Unterelement (120, 220)
ein Spalt vorgesehen ist, der mindestens teilweise mit einem Fluid gefüllt ist.
11. Optisches System nach Anspruch 10, dadurch gekennzeichnet, dass das Fluid ein flüssiges Medium ist, wobei das flüssige Medium einen Brechungsindex
aufweist, der bei einer Arbeitswellenlänge des optischen Systems um weniger als 0,2,
bevorzugt um weniger als 0,15, von einem mittleren Brechungsindex des ersten und zweiten
Unterelements abweicht.
12. Optisches System nach einem der Ansprüche 1 bis 11, dadurch gekennzeichnet, dass das erste Unterelement (110, 210) und das zweite Unterelement (120, 220) aus demselben
Material hergestellt sind.
13. Optisches System nach einem der Ansprüche 1 bis 11, dadurch gekennzeichnet, dass das erste Unterelement (110, 210) und das zweite Unterelement (120, 220) aus verschiedenen
Materialien hergestellt sind, wobei der Polarisationsmanipulator sowohl positiv doppelbrechendes
kristallines Material als auch negativ doppelbrechendes kristallines Material aufweist.
14. Optisches System nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass der Polarisationsmanipulator in einer vorgegebenen Startposition des mindestens einen
Unterelements den Polarisationszustand von Licht, das dort hindurchdringt, unverändert
lässt.
15. Optisches System nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass der Polarisationsmanipulator derart konfiguriert ist, dass eine Wellenfront für p-polarisiertes
Licht, das dort hindurchdringt, und eine Wellenfront für s-polarisiertes Licht, das
dort hindurchdringt, unterschiedlich voneinander durch den Polarisationsmanipulator
manipuliert werden, wobei die Manipulation des Mittelwerts der Wellenfronten für p-polarisiertes
Licht und für s-polarisiertes Licht von null abweicht.
1. Système optique qui a un axe optique (OA), comprenant
• au moins un manipulateur de polarisation (100, 200) ayant un premier sous-élément
(110, 210) qui a une surface non plane, optiquement efficace et pour faire traverser
la lumière provoque un changement d'état de polarisation, un retard maximal effectif
introduit par le premier sous-élément le long de l'axe optique (OA) étant inférieur
à un quart de la longueur d'onde de travail du système optique, et un deuxième sous-élément
(120, 220), ledit premier sous-élément et ledit deuxième sous-élément ayant des surfaces
se faisant mutuellement face (110a, 120a ; 210a, 220a) qui sont mutuellement complémentaires
; et
• un manipulateur de position (150, 250) pour la manipulation de la position relative
dudit premier sous-élément (110, 210) et dudit deuxième sous-élément (120, 220) ;
caractérisé en ce que le manipulateur de position (150, 250) est adapté pour appliquer un des changements
suivants dans la position d'au moins un sous-élément (110, 120 ; 210, 220) ou une
combinaison de ces changements :
- déplacement d'au moins un desdits sous-éléments (110, 120 ; 210, 220) dans une direction
perpendiculaire à l'axe optique ; et
- rotation d'au moins un desdits sous-éléments (110, 120 ; 210, 220).
2. Système optique selon la revendication 1, caractérisé en ce qu'au moins une desdites surfaces se faisant mutuellement face (110a, 120a ; 210a, 220a)
est asphérique.
3. Système optique selon la revendication 1 ou 2, caractérisé en ce qu'au moins un desdits sous-éléments (110, 210, 120, 220), pour faire traverser la lumière,
provoque un changement d'état de polarisation par biréfringence linéaire, biréfringence
circulaire et/ou par un changement dans la relation d'amplitude d'états de polarisation
orthogonaux dépendant des orientations de ceux-ci.
4. Système optique selon une des revendications précédentes, caractérisé en ce qu'il comporte au moins deux tels manipulateurs de polarisation, les manipulateurs de
polarisation étant agencés de telle sorte que les facteurs de sous-ouverture paraxiale
aux emplacements de ces manipulateurs de polarisation diffèrent l'un de l'autre d'au
moins 0,1 et de préférence au moins 0,15.
5. Système optique selon une des revendications précédentes, caractérisé en ce qu'il comporte en outre un compensateur de front d'onde pour la compensation au moins
partielle d'un changement, provoqué par le manipulateur de polarisation (100, 200),
dans le front d'onde de la lumière traversant le système optique.
6. Système optique selon une des revendications précédentes,
caractérisé en ce qu'au moins un desdits sous-éléments est produit à partir d'un matériau choisi dans le
groupe qui contient :
- un matériau cristallin cubique qui est mis sous contrainte de compression ou de
traction,
- un matériau amorphe qui est mis sous contrainte de compression ou de traction, ou
- un matériau cristallin optiquement uniaxial.
7. Système optique selon une des revendications précédentes,
caractérisé en ce que le manipulateur de position (150, 250) est également adapté pour appliquer le changement
suivant dans la position d'au moins un sous-élément (110, 120 ; 210, 220) :
- déplacement d'au moins un desdits sous-éléments (110, 120 ; 210, 220) dans une direction
parallèle à l'axe optique.
8. Système optique selon une des revendications 1 à 7, caractérisé en ce que la rotation se fait autour d'un axe de rotation qui est parallèle à l'axe optique.
9. Système optique selon une des revendications 1 à 7, caractérisé en ce que la rotation se fait autour d'un axe de rotation qui n'est pas parallèle à l'axe optique.
10. Système optique selon une des revendications précédentes, caractérisé en ce qu'un espace qui est au moins partiellement rempli par un fluide est prévu entre le premier
sous-élément (110, 210) et le deuxième sous-élément (120, 220).
11. Système optique selon la revendication 10, caractérisé en ce que le fluide est un milieu liquide, ledit milieu liquide ayant un indice de réfraction
qui, à une longueur d'onde de travail du système optique, diffère de moins de 0,2,
de préférence de moins de 0,15, d'un indice de réfraction moyen des premier et deuxième
sous-éléments.
12. Système optique selon une des revendications 1 à 11, caractérisé en ce que le premier sous-élément (110, 210) et le deuxième sous-élément (120, 220) sont constitués
du même matériau.
13. Système optique selon une des revendications 1 à 11, caractérisé en ce que le premier sous-élément (110, 210) et le deuxième sous-élément (120, 220) sont constitués
de matériaux différents, le manipulateur de polarisation ayant à la fois un matériau
cristallin à biréfringence positive et un matériau cristallin à biréfringence négative.
14. Système optique selon une des revendications précédentes, caractérisé en ce que le manipulateur de polarisation, dans une position de départ prédéterminée de l'au
moins un sous-élément, laisse l'état de polarisation de la lumière le traversant inchangé.
15. Système optique selon une des revendications précédentes, caractérisé en ce que le manipulateur de polarisation est configuré de telle sorte qu'un front d'onde pour
la lumière polarisée p le traversant et un front d'onde pour la lumière polarisée
s le traversant sont manipulés par ledit manipulateur de polarisation différemment
l'un de l'autre, la manipulation de la valeur moyenne des fronts d'onde pour la lumière
polarisée p et la lumière polarisée s étant différente de zéro.