Field of the Invention
[0001] The present invention pertains to the field of nonferrous metal materials, in particular
to an aluminum alloy material with high elongation for cables and a preparation method
for the same.
Background of the Invention
[0002] Presently, most wires and cables employ copper as the conductor. However, owing to
the rare copper resource, high price of copper material, and high installation cost
of copper cables, the development of wires and cables is limited. Due to the fact
of abundant aluminum resource and low cost of aluminum material, it will be a trend
to replace copper with aluminum as the conductor for wires and cables.
Disclosure of the Invention
Technical Problem
[0003] However, if conventional EC-aluminum is used as conductor to replace copper, the
elongation, flexibility, and creep resistance of wires and cables are poor, and the
safety and stability of use are unsatisfactory. Therefore, replacing copper with conventional
EC-aluminum as conductor cannot meet the demand for development of wires and cables.
Summary of the Invention
[0004] The object of the present invention is to provide an aluminum alloy material with
high elongation for cables. With the aluminum alloy material according to the present
invention as conductor, the wires and cables have high elongation, and can be used
safely and stably.
[0005] To achieve the above object, the present invention employs the following technical
solution: an aluminum alloy material with high elongation for cables, comprising the
following components: Fe: 0.30∼1.20wt%, Si: 0.03∼0.10wt%, rare earth elements (i.e.
Ce and La): 0.01∼0.30wt%, and the rest are Al and inevitable impurities.
[0006] Another object of the present invention is to provide a method for preparing the
aluminum alloy material with high elongation, comprising the following steps:
1) Fusion casting
[0007] First, adding Al alloy containing Si and Fe in 92∼98 parts by weight (pbw) and Al-Fe
alloy in 0.73∼5.26 pbw, and heating to 710∼750°C to melt; then, heating to 720∼760°C,
adding rare earth-Al alloy in 1∼3 pbw and B-Al alloy in 0.17∼0.67 pbw, wherein, said
rare earth-Al alloy is the alloy of Al and rare earth elements (Ce and La); next,
adding a refining agent in 0.04∼0.06 pbw and refining for 8∼20 minutes; then, holding
at the temperature for 20∼40 minutes, and then casting;
2) Semi-annealing treatment
[0008] Holding the aluminum alloy obtained by casting at 280∼380°C for 4∼10 hours, and then
taking out and cooling naturally to ambient temperature.
[0009] Said aluminum alloy material further comprises inevitable impurity elements, the
total content of which in the aluminum alloy material is lower than 0.3 wt%.
[0010] Furthermore, the content of Ca in the impurities is lower than 0.02 wt%, and the
content of any other impurity element is lower than 0.01%, so as to reduce the influence
of the impurity elements on the conductivity of the aluminum alloy material.
[0011] The aluminum alloy material with high elongation for cables provided in the present
invention is a new type Al-Fe alloy material with the following advantages:
- 1) The content of Fe according to the present invention is controlled within the range
of 0.30∼1.20%; thus the strength of the aluminum alloy can be increased, and the creep
resistance and thermal stability of the aluminum alloy can also be improved. The creep
resistance is improved by 300% when compared to the conventional EC-aluminum material;
furthermore, Fe can improve the toughness of the aluminum alloy, and the compression
factor of the aluminum alloy material in the compression and twisting process can
be as high as 0.93 or above, which cannot be achieved by the conventional EC-aluminum
material. Compared to the conductor made of EC-aluminum material, the compacted conductor
made of the aluminum alloy in the same outside diameter has larger sectional area,
higher electrical conductivity and higher stability, and is lower in production cost.
- 2) The content of Si according to the present invention is controlled within the range
of 0.03∼0.10%, which ensures the enhancement effect of Si to the strength of the aluminum
alloy.
- 3) The rare earth elements according to the present invention can reduce the content
of Si, and thereby reduce the influence of Fe, in particular Si on the conductivity
of aluminum alloy to a very low level; moreover, the addition of rare earth elements
improves the crystal structure of the aluminum alloy material and thereby improves
the processing properties of the aluminum alloy material, and is favorable for processing
of the aluminum alloy material.
- 4) The rare earth elements according to the present invention are mainly Ce and La,
which can well attain the performance described in 3).
- 5) The element B according to the present invention can react with impurity elements
such as Ti, V, Mn, Cr, etc., and form chemical compounds, which deposit and then can
be removed; therefore, the influence of impurity elements (e.g., Ti, V, Mn, Cr, etc.)
on the conductivity of aluminum alloy can be reduced; thus, the conductivity of aluminum
alloy can be improved.
- 6) The alloy material is conducted by semi-annealing treatment when the aluminum alloy
is prepared in the present invention; therefore, the adverse effect of stress to the
structure of the conductor during the drawing and twisting process can be reduced,
so that the conductivity can be up to or even higher than 61 % IACS (the criterion
for conductivity of conductors made of conventional EC-aluminum is 61 % IACS); in
addition, the annealing treatment can greatly improve the elongation and flexibility
of the aluminum alloy material. Cables made of the aluminum alloy material provided
in the present invention can have the elongation as high as 30%, and the flexibility
25% higher than that of the copper cables, and a bending radius as small as 7 times
of the outside diameter, while the bending radius of copper cable is 15 times of the
outside diameter.
Embodiments
Embodiment 1
[0012]
- I. Fusion casting process
- 1. Material proportioning
5100kg aluminum ingot (contains 0.07% Si and 0.13% Fe), 40.4kg Al-Fe alloy (contains
22% Fe), 5.6kg rare earth alloy (contains 10% rare earth elements), 8.8kg B-Al alloy
(contains 3.5% B), and 2.3kg refining agent (23% Na3Al·F6 + 47% KCl +30% NaCl).
- 2. Feeding method
During material feeding, feed the Al-Fe alloy into the cupola furnace in batches evenly
with the aluminum ingots, to ensure the components can be distributed evenly as far
as possible.
- 3. Heat preservation process
When the aluminum alloy liquid flows into the holding furnace, control the furnace
temperature at 710∼750°C; when rare earth-Al alloy and B-Al alloy are added into the
aluminum alloy liquid, the furnace temperature is increased to 720∼760°C, and not
higher than 760°C. Here, increasing the temperature is favorable for melting of the
rare earth-Al alloy and B-Al alloy, and thereby the treatment effect of rare earth
elements and element B can be improved.
- 4. Rare earth treatment and boronizing treatment
4.1 Add 1/3 rare earth-Al alloy at 30 minutes before the holding furnace is filled
up with the aluminum alloy liquid.
4.2 Add the remaining 2/3 rare earth-Al alloy and B-Al alloy at 5 minutes before the
holding furnace is filled up with the aluminum alloy liquid.
Adding rare earth-Al alloy and B-Al alloy in different time periods is to allow the
rare earth elements and element B to play a full part, so as to improve the effect.
4.3 The feeding positions of rare earth-Al alloy and B-Al alloy can be evenly distributed
in the holding furnace.
- 5. Refining (slag removal, gas removal, agitation, and slag-off)
5.1 To ensure the composition of the aluminum alloy liquid is homogeneous in the entire
furnace, the aluminum alloy liquid including which is located at the corner positions
in the furnace should be agitated for 5 minutes.
5.2 When the furnace is filled up with the aluminum alloy liquid, blow 2.3kg powder
of refining agent (23% Na3Al·F6 + 47% KCl + 30% NaCl) into the bottom of the aluminum alloy liquid through high-purity
nitrogen gas for 3∼5 minutes, with the blow nozzle kept moving in the bottom of the
aluminum alloy liquid, to force the included slag to flow up with the gas uniformly
along the surface of the aluminum alloy liquid. The floating aluminum oxide slag should
be completely removed from the furnace, so as to reduce new impurity carried with
the refining agent as far as possible.
- 6. Quick analysis on-the-spot sample and holding and heat preservation
When the Fe content in the aluminum alloy liquid meets the requirements after slag
is removed, hold the aluminum alloy liquid for 20∼40 minutes.
- 7. Control of continuous casting and rolling process
7.1 Temperature control
7.1.1 Temperature of casting ladle: 720∼730°C
7.1.2 Temperature of strips fed into the rolling machine: 450∼490°C
7.1.3 Final rolling temperature of aluminum rods: about 300°C
7.2 Control of cooling water in conticaster
The volume of water inside the casting wheels to that outside the casting wheels:
3: 2; the volume of secondary cooling water should be adjusted according to the temperature
of the cast strips.
7.3 Voltage of casting machine: 60-90V
7.4 Current through the rolling machine: 200∼280A; speed of rolling machine: 7.5∼8.5m/min.
- II. Semi-annealing process
Hold the aluminum alloy rods made of aluminum alloy material in an annealing furnace
for 10 hours at 280∼300°C, and then take out and cool down the rods to the ambient
temperature naturally.
The aluminum alloy material obtained in that way contains the following components
measured by weight percentage: Fe: 0.3%, Si: 0.03%, Ce: 0.008%, La: 0.002%, B: 0.005%,
Ca: 0.015%, Cu: 0.002%, Mg: 0.005%, Zn: 0.002%, Ti: 0.002%, V: 0.005%, Mn: 0.002%,
Cr: 0.001%, Al: the remaining part.
Since element B reacts with impurity elements such as Ti, V, Mn, Cr, etc., and forms
chemical compounds, which deposit and can be removed, the content of element B in
the resulting aluminum alloy material is lower than the amount added actually.
It is seen that the total impurity content in the aluminum alloy material is lower
than 0.3%, wherein, the content of any other impurity element is lower than 0.01%,
except for the content of Ca, which is lower than 0.02%.
The performance test data of the aluminum alloy material with high elongation in this
embodiment is as follows:
Tensile strength and elongation are tested according to the method described in ASTM
B577; conductivity is tested according to the method described in ASTM B 193, flexibility
is tested according to the method of "Partial Discharge Test after Bending Test" described
in GB 12706.1, and creep property is tested according to the creep test method described in the
manual "Wires and Cables".
The performance data of the aluminum alloy material with high elongation in this embodiment
is: tensile strength: 106MPa; elongation: 28%; conductivity: 63.0% IACS; partial discharge
test after 6x bending radius test: passed; creep resistance: higher than EC-aluminum
by 310%.
Embodiment 2
[0013]
- I. Fusion casting process
- 1. Material proportioning
5110kg aluminum ingot (contains 0.10% Si and 0.13% Fe), 258kg Al-Fe alloy (contains
23.2% Fe), 166.5kg rare earth alloy (contains 9.8% rare earth elements), 10kg B-Al
alloy (contains 3.3% B), and 2.3kg refining agent (23% Na3Al•F6 + 47% KCl + 30% NaCl).
- 2. Feeding method
During material feeding, feed the Al-Fe alloy into the cupola furnace in batches evenly
with the aluminum ingots, to ensure the components can be distributed evenly as far
as possible.
- 3. Heat preservation process
When the aluminum alloy liquid flows into the holding furnace, control the furnace
temperature at 710∼750°C; when rare earth-Al alloy and B-Al alloy are added into the
aluminum alloy liquid, the furnace temperature is increased to 720∼760°C, and not
higher than 760°C. Here, increasing the temperature is favorable for melting of the
rare earth-Al alloy and B-Al alloy, and thereby the treatment effect of rare earth
elements and element B can be improved.
- 4. Rare earth treatment and boronizing treatment
4.1 Add 1/3 rare earth-Al alloy at 30 minutes before the holding furnace is filled
up with the aluminum alloy liquid.
4.2 Add the remaining 2/3 rare earth-Al alloy and B-Al alloy at 5 minutes before the
holding furnace is filled up with the aluminum alloy liquid.
Adding rare earth-Al alloy and B-Al alloy in different time periods is to allow to
the rare earth elements and element B to play a full part, so as to improve the effect.
4.3 The feeding positions of rare earth-Al alloy and B-Al alloy can be evenly distributed
in the holding furnace.
- 5. Refining (slag removal, gas removal, agitation, and slag-off)
5.1 To ensure the composition of the aluminum alloy liquid is homogeneous in the entire
furnace, the aluminum alloy liquid including which is located at the corner positions
in the furnace should be agitated for 5 minutes.
5.2 When the furnace is filled up with the aluminum alloy liquid, blow 2.3kg powder
of refining agent (23% Na3Al•F6 + 47% KCl + 30% NaCl) into the bottom of the aluminum alloy liquid through high-purity
nitrogen gas for 3∼5 minutes, with the blow nozzle kept moving in the bottom of the
aluminum alloy liquid, to force the included slag to flow up with the gas uniformly
along the surface of the aluminum alloy liquid. The floating aluminum oxide slag should
be completely removed from the furnace, so as to reduce new impurity carried with
the refining agent as far as possible.
- 6. Quick analysis on-the-spot sample and holding and heat preservation
When the Fe content in the aluminum alloy liquid meets the requirements after slag
is removed, hold the aluminum alloy liquid for 20∼40 minutes.
- 7. Control of continuous casting and rolling process
7.1 Temperature control
7.1.1 Temperature of casting ladle: 720∼730°C
7.1.2 Temperature of strips fed into the rolling machine: 450∼490°C
7.1.3 Final rolling temperature of aluminum rods: about 300°C
7.2 Control of cooling water in conticaster
The volume of water inside the casting wheels to that outside the casting wheels:
3: 2; the volume of secondary cooling water should be adjusted according to the temperature
of the cast strips.
7.3 Voltage of casting machine: 60-90V
7.4 Current through the rolling machine: 200∼280A; speed of rolling machine: 7.5∼8.5
m/min.
- II. Semi-annealing process
Hold the aluminum alloy rods made of aluminum alloy material in an annealing furnace
for 4 hours at 360∼380°C, and then take out and cool down the rods to the ambient
temperature naturally.
The aluminum alloy material obtained in that way contains the following components
measured by weight percentage: Fe: 1.2%, Si: 0.08%, Ce: 0.019%, La: 0.10%, B: 0.004%,
Ca: 0.01%, Cu: 0.002%, Mg: 0.004%, Zn: 0.003%, Ti: 0.002%, V: 0.002%, Mn: 0.005%,
Cr: 0.002%, Al: the remaining part.
Since element B reacts with impurity elements such as Ti, V, Mn, Cr, etc., and forms
chemical compounds, which deposit and can be removed, the content of element B in
the resulting aluminum alloy material is lower than the amount added actually. It
is seen that the total impurity content in the aluminum alloy material is lower than
0.3%, wherein, the content of any other impurity element is lower than 0.01%, except
for the content of Ca, which is lower than 0.02%.
The performance test data of the aluminum alloy material with high elongation in this
embodiment is as follows:
Tensile strength and elongation are tested according to the method described in ASTM
B577; conductivity is tested according to the method described in ASTM B 193, flexibility
is tested according to the method of "Partial Discharge Test after Bending Test" described
in GB 12706.1, and creep property is tested according to the creep test method described in the
manual "Wires and Cables".
The performance data of the aluminum alloy material with high conductivity, high elongation,
high flexibility, and high creep resistance in this embodiment is: tensile strength:
92MPa; elongation: 36%; conductivity: 61.0% IACS; partial discharge test after 7x
bending radius test: passed; creep resistance: higher than EC-aluminum by 330%.
Embodiment 3
[0014]
- I. Fusion casting process
- 1. Material proportioning
5125kg aluminum ingot (contains 0.12% Si and 0.12% Fe), 107kg Al-Fe alloy (contains
21.9% Fe), 118kg rare earth alloy (contains 10.1% rare earth elements), 14.8kg B-Al
alloy (contains 3.0% B), and 2.8kg refining agent (23% Na3Al•F6 + 47% KCl + 30% NaCl).
- 2. Feeding method
During material feeding, feed the Al-Fe alloy into the cupola furnace in batches evenly
with the aluminum ingots, to ensure the components can be distributed evenly as far
as possible.
- 3. Heat preservation process
When the aluminum alloy liquid flows into the holding furnace, control the furnace
temperature at 710∼750°C; when rare earth-Al alloy and B-Al alloy are added into the
aluminum alloy liquid, the furnace temperature is increased to 720∼760°C, and not
higher than 760°C. Here, increasing the temperature is favorable for melting of the
rare earth-Al alloy and B-Al alloy, and the treatment effect of rare earth elements
and element B can be improved.
- 4. Rare earth treatment and boronizing treatment
4.1 Add 1/3 rare earth-Al alloy at 30 minutes before the holding furnace is filled
up with the aluminum alloy liquid.
4.2 Add the remaining 2/3 rare earth-Al alloy and B-Al alloy at 5 minutes before the
holding furnace is filled up with the aluminum alloy liquid.
4.3 The feeding positions of rare earth-Al alloy and B-Al alloy can be evenly distributed
in the holding furnace.
- 5. Refining (slag removal, gas removal, agitation, and slag-off)
5.1 To ensure the composition of the aluminum alloy liquid is homogeneous in the entire
furnace, the aluminum alloy liquid including which is located at the corner positions
in the furnace should be agitated for 5 minutes.
5.2 When the furnace is filled up with the aluminum alloy liquid, blow 2.8kg powder
of refining agent (23% Na3Al•F6 + 47% KCl + 30% NaCl) into the bottom of the aluminum alloy liquid through high-purity
nitrogen gas for 3∼5 minutes, with the blow nozzle kept moving in the bottom of the
aluminum alloy liquid, to force the included slag to flow up with the gas uniformly
along the surface of the aluminum alloy liquid. The floating aluminum oxide slag should
be completely removed from the furnace, so as to reduce new impurity carried with
the refining agent as far as possible.
- 6. Quick analysis on-the-spot sample and holding and heat preservation
When the Fe content in the aluminum alloy liquid meets the requirements after slag
is removed, hold the aluminum alloy liquid for 20∼40 minutes.
- 7. Control of continuous casting and rolling process
7.1 Temperature control
7.1.1 Temperature of casting ladle: 720∼730°C
7.1.2 Temperature of strips fed into the rolling machine: 450∼490°C
7.1.3 Final rolling temperature of aluminum rods: about 300°C
7.2 Control of cooling water in conticaster
The volume of water inside the casting wheels to that outside the casting wheels:
3: 2; the volume of secondary cooling water should be adjusted according to the temperature
of the cast strips.
7.3 Voltage of casting machine: 60-90V
7.4 Current through the rolling machine: 200∼280A; speed of rolling machine: 7.5∼8.5
m/min.
- II. Semi-annealing process
Hold the aluminum alloy rods made of aluminum alloy material in an annealing furnace
for 8 hours at 300∼320°C, and then take out and cool down the rods to the ambient
temperature naturally.
The aluminum alloy material obtained in that way contains the following components
measured by weight percentage: Fe: 0.55%, Si: 0.10%, Ce: 0.15%, La: 0.06%, B: 0.007%,
Ca: 0.013%, Cu: 0.003%, Mg: 0.004%, Zn: 0.004%, Ti: 0.002%, V: 0.004%, Mn: 0.003%,
Cr: 0.002%, Al: the remaining part.
Since element B reacts with impurity elements such as Ti, V, Mn, Cr, etc., and forms
chemical compounds, which deposit and can be removed, the content of element B in
the resulting aluminum alloy material is lower than the amount added actually.
It is seen that the total impurity content in the aluminum alloy material is lower
than 0.3%, wherein, the content of any other impurity element is lower than 0.01%,
except for the content of Ca, which is lower than 0.02%.
The performance test data of the aluminum alloy material with high elongation in this
embodiment is as follows:
Tensile strength and elongation are tested according to the method described in ASTM
B577; conductivity is tested according to the method described in ASTM B193, flexibility
is tested according to the method of "Partial Discharge Test after Bending Test" described
in GB 12706.1, and creep property is tested according to the creep test method described in the
manual "Wires and Cables".
The performance data of the aluminum alloy material with high elongation in this embodiment
is: tensile strength: 106MPa, elongation: 30.2%; conductivity: 62.6% IACS; partial
discharge test after 6x bending radius test: passed; creep resistance: higher than
EC-aluminum by 330%.
Embodiment 4
[0015]
- I. Fusion casting process
- 1. Material proportioning
5005kg aluminum ingot (contains 0.08% Si and 0.13% Fe), 182kg Al-Fe alloy (contains
21% Fe), 90.5kg rare earth alloy (contains 9.8% rare earth elements), 30kg B-Al alloy
(contains 3.5% B), and 2.0kg refining agent (23% Na3Al•F6 + 47% KCl + 30% NaCl).
- 2. Feeding method
During material feeding, feed the Al-Fe alloy into the cupola furnace in batches evenly
with the aluminum ingots, to ensure the components can be distributed evenly as far
as possible.
- 3. Heat preservation process
When the aluminum alloy liquid flows into the holding furnace, control the furnace
temperature at 710∼750°C; when rare earth-Al alloy and B-Al alloy are added into the
aluminum alloy liquid, the furnace temperature is increased to 720∼760°C, and not
higher than 760°C. Here, increasing the temperature is favorable for melting of the
rare earth-Al alloy and B-Al alloy, and the treatment effect of rare earth elements
and element B can be improved.
- 4. Rare earth treatment and boronizing treatment
4.1 Add 1/3 rare earth-Al alloy at 30 minutes before the holding furnace is filled
up with the aluminum alloy liquid.
4.2 Add the remaining 2/3 rare earth-Al alloy and B-Al alloy at 5 minutes before the
holding furnace is filled up with the aluminum alloy liquid.
4.3 The feeding positions of rare earth-Al alloy and B-A1 alloy can be evenly distributed
in the holding furnace.
- 5. Refining (slag removal, gas removal, agitation, and slag-off)
5.1 To ensure the composition of the aluminum alloy liquid is homogeneous in the entire
furnace, the aluminum alloy liquid including which is located at the corner positions
in the furnace should be agitated for 5 minutes.
5.2 When the furnace is filled up with the aluminum alloy liquid, blow 2.0kg powder
of refining agent (23% Na3Al•F6 + 47% KCl + 30% NaCl) into the bottom of the aluminum alloy liquid through high-purity
nitrogen gas for 3∼5 minutes, with the blow nozzle kept moving in the bottom of the
aluminum alloy liquid, to force the included slag to flow up with the gas uniformly
along the surface of the aluminum alloy liquid. The floating aluminum oxide slag should
be completely removed from the furnace, so as to reduce new impurity carried with
the refining agent as far as possible.
- 6. Quick analysis on-the-spot sample and holding and heat preservation
When the Fe content in the aluminum alloy liquid meets the requirements after slag
is removed, hold the aluminum alloy liquid for 20∼40 minutes.
- 7. Control of continuous casting and rolling process
7.1 Temperature control
7.1.1 Temperature of casting ladle: 720∼730°C
7.1.2 Temperature of strips fed into the rolling machine: 450∼490°C
7.1.3 Final rolling temperature of aluminum rods: about 300°C
7.2 Control of cooling water in conticaster
The volume of water inside the casting wheels to that outside the casting wheels:
3: 2; the volume of secondary cooling water should be adjusted according to the temperature
of the cast strips.
7.3 Voltage of casting machine: 60∼90V
7.4 Current through the rolling machine: 200∼280A; speed of rolling machine: 7.5∼8.5m/min.
- II. Semi-annealing process
Hold the aluminum alloy rods made of aluminum alloy material in an annealing furnace
for 6 hours at 340∼360°C, and then take out and cool down the rods to the ambient
temperature naturally.
The aluminum alloy material obtained in that way contains the following components
measured by weight percentage: Fe: 0.80%, Si: 0.04%, Ce: 0.10%, La: 0.06%, B: 0.008%,
Ca: 0.011%, Cu: 0.005%, Mg: 0.004%, Zn: 0.006%, Ti: 0.003%, V: 0.003%, Mn: 0.005%,
Cr: 0.002%, Al: the remaining part.
Since element B reacts with impurity elements such as Ti, V, Mn, Cr, etc., and forms
chemical compounds, which deposit and can be removed, the content of element B in
the resulting aluminum alloy material is lower than the amount added actually.
It is seen that the total impurity content in the aluminum alloy material is lower
than 0.3%, wherein, the content of any other impurity element is lower than 0.01%,
except for the content of Ca, which is lower than 0.02%.
The performance test data of the aluminum alloy material with high elongation in this
embodiment is as follows:
Tensile strength and elongation are tested according to the method described in ASTM
B577; conductivity is tested according to the method described in ASTM B193, flexibility
is tested according to the method of "Partial Discharge Test after Bending Test" described
in GB 12706.1, and creep property is tested according to the creep test method described in the
manual "Wires and Cables".
The performance data of the aluminum alloy material with high elongation in this embodiment
is: tensile strength: 97MPa; elongation: 35.2%; conductivity: 62.0% IACS; partial
discharge test after 6x bending radius test: passed; creep resistance: higher than
EC-aluminum by 330%.
1. An aluminum alloy material with high elongation for cables, comprising the following
components measured by weight percentage: Fe: 0.30∼1.20%, Si: 0.03∼0.10%, rare earth
elements (i.e. Ce and La): 0.01∼0.30%, and the rest are Al and inevitable impurities.
2. The aluminum alloy material with high elongation for cables according to claim 1,
wherein, the total content of impurities in the aluminum alloy measured by weight
percentage is lower than 0.3%.
3. The aluminum alloy material with high elongation for cables according to claim 2,
wherein, measured by weight percentage, the content of Ca in the impurities is lower
than 0.02%, and the content of any other element in the impurities is lower than 0.01%.
4. The aluminum alloy material with high extensibility for cables according to claim
1, wherein, measured by weight percentage, the content of Ce is 0.005∼0.20%, and the
content of La is 0.001∼0.15%.
5. A method for preparing the aluminum alloy material with high elongation for cables
according to claim 1, comprising the following steps:
1) Fusion casting
First, adding Al alloy containing Si and Fe in 92∼98 parts by weight (pbw) and Al-Fe
alloy in 0.73∼5.26 pbw, and heating to 710∼750°C to melt state; then, heating to 720∼760°C,
adding rare earth-Al alloy in 1∼3 pbw and B-Al alloy in 0.17∼0.67 pbw, wherein, the
rare earth-Al alloy is the alloy of Al and rare earth elements (Ce and La); next,
adding a refining agent in 0.04∼0.06 pbw and refining for 8∼20 minutes; then, holding
at the temperature for 20∼40 minutes, and then casting;
2) Semi-annealing treatment
Holding the resulting aluminum alloy at 280∼380°C for 4∼10 hours, and then taking
out and cooling naturally to ambient temperature.
6. The method for preparing the aluminum alloy material with high elongation for cables
according to claim 5, wherein, the content of Si in said aluminum alloy that contains
Si and Fe is 0.07∼0.12%, and the content of Fe in said aluminum alloy that contains
Si and Fe is 0.12∼0.13%; the content of Fe in the Al-Fe alloy is 20∼24%, the content
of B in the B-Al alloy is 3∼4%, and the content of Ce and La in the rare earth-Al
alloy is 9∼11%.
7. The method for preparing the aluminum alloy material with high elongation for cables
according to claim 5, wherein, the Al and Al-Fe alloy melt and flow into a holding
furnace, 1/3 rare earth-Al alloy is added at 30 minutes before the holding furnace
is filled up with the aluminum alloy liquid, and B-Al alloy and the remaining 2/3
rare earth-Al alloy are added at 5 minutes before the holding furnace is filled up
with the aluminum alloy liquid.
8. The method for preparing the aluminum alloy material with high elongation for cables
according to claim 5, wherein, the powder of refining agent comprises 23% Na3Al·F6 + 47% KCl + 30% NaCl.
9. The method for preparing the aluminum alloy material with high elongation for cables
according to claim 5, wherein, in the casting process, the temperature of casting
ladle is 720∼730°C, the temperature of cast strips fed into the rolling machine is
450∼490°C, and the temperature of final rolling is 300°C.