Field of the Invention
[0001] The present invention relates to a method for operating a blast furnace using a carbon
iron composite (ferrocoke) produced by briquetting and carbonizing a mixture of coal
and iron ore.
Description of the Related Art
[0002] A technique for lowering the temperature of a thermal reserve zone formed in a blast
furnace is effective in lowering the reducing agent rate of the blast furnace (see,
for example, Non-Patent Literature 1).
[0003] An example of the technique for lowering the thermal reserve zone temperature is
to lower the beginning temperature of a coke gasification reaction (endothermic reaction)
represented by the following equation:
CO
2 + C → 2CO (1).
If the beginning temperature of the coke gasification reaction is lowered, then a
temperature region where this reaction occurs is expanded and therefore the reaction
rate of gasification is increased. A carbon iron composite produced by carbonizing
briquettes obtained by briquetting a mixture of coal and iron ore can increase the
reactivity of coke by the catalytic action of reduced iron ore and can lower the reducing
agent rate because of the lowering of the thermal reserve zone temperature (see, for
example, Patent Literature 1).
[0004] A method for producing a carbon iron composite is supposed to be, for example, a
process including a step of mixing coal, iron ore, and several mass percent of a binder
to homogenize the mixture, a step of producing briquettes by pressing the mixture
with a double-roll press having a dimple, and a step of carbonizing the briquettes
in a vertical furnace. In this case, the carbon iron composite has a shape suitable
for the above roll pressing as shown in Fig. 2.
[0005] The carbon iron composite is supposed to be produced by a method, similar to a method
for producing conventional coke, using a mixture of coal and iron ore. Since an ordinary
chamber coke oven is made of silica bricks, iron ore charged thereinto reacts with
silica, which is a major component of the silica bricks, to produce fayalite, which
has a low melting point. This may possibly damage the silica bricks. In this case,
particles of the carbon iron composite have an irregular shape and the range of the
particle size is determined by sieving.
[0006] Coke gasification reactions occurring in a blast furnace include the following reactions
represented by Equations (2) to (5) below in addition to the reaction represented
by Equation (1):
the reaction of carbon with oxygen in a tuyere zone as represented by Equation (2);
the reaction of carbon with FeO as represented by Equation (3);
the reaction of carbon with steam in a shaft zone as represented by Equation (4);
and
the reaction of carbon with a non-ferrous oxide as represented by Equation (5). In
Equation (5), M is Si, Mn, Ti, P, or the like.
In the operation of blast furnaces, the amount of carbon consumed in the gasification
reactions other than the reaction represented by Equation (2) is conventionally referred
to as the amount of solution loss carbon (hereinafter referred to as the solution
loss amount) and is given by Equation (6) below. The amount of carbon gasified in
front of a tuyere is calculated from the amount of oxygen in an air blow by Equation
(2). The amount of carbon in a top gas is calculated from the amount of the top gas,
the concentration of each of CO and CO
2 in the top gas. In the case of using a carbon iron composite, the reaction represented
by Equation (1) is promoted and the reaction represented by Equation (3) is, however,
significantly suppressed because the reduction of iron oxide by gas, that is, a reaction
represented by Equation (7) is promoted. As a result, the solution loss amount is
probably lowered. The contribution of the reaction represented by Equation (4) to
the solution loss amount is small and therefore the solution loss amount is usually
supposed to be the amount of coke gasified in a region close to a furnace top and
a cohesive zone.
C + 1/2O
2 = CO (2)
FeO + C = Fe + CO (3)
H
2O + C = H
2 + CO (4)
MO
n + C = M + CO
n (5)

solution loss
FeO + CO = Fe + CO
2 (7)
[0007] In the case of lowering the temperature of a thermal reserve zone by increasing the
amount of the carbon iron composite used, the solution loss amount, that is, the amount
of coke gasified in the region close to the furnace top and the cohesive zone is lowered
and it is predicted that the amount of carbon in the carbon iron composite exceeds
the solution loss amount under certain conditions. A so-called dropping zone located
below the cohesive zone is filled with coke that is not gasified nor lost by a solution
loss reaction in the region close to the furnace top and the cohesive zone. Even if
the carbon iron composite is gasified prior to conventional coke because the carbon
iron composite is higher in reactivity than conventional coke, a portion of the carbon
iron composite is not lost by gasification and therefore remains in the dropping zone
when the amount of carbon in the charged carbon iron composite exceeds the amount
of gasified carbon. The term "conventional coke" refers to coke which is produced
by carbonizing coal in a coke oven or the like, which is usually charged into a blast
furnace, and which is used as a coke source material. When the carbon iron composite
has a particle size less than that of conventional coke or strength less than that
of conventional coke, the excessive presence of the carbon iron composite in the dropping
zone may possibly deteriorate the gas or liquid permeability of a furnace bottom section.
Therefore, there is probably an upper limit to the amount of the carbon iron composite
used.
Citation List
Patent Literature
[0008]
PTL 1: Japanese Unexamined Patent Application Publication No. 2006-28594
Non Patent Literature
Summary of the Invention
Technical Problem
[0010] There is probably an upper limit to the amount of a carbon iron composite used as
described above.
Accordingly, it is an object of the present invention to solve such a conventional
technical problem and to provide a stable operation in such a manner that when a carbon
iron composite is used in a blast furnace, the amount of the carbon iron composite
used is appropriately adjusted. Solution to Problem
[0011] The present invention has features below for the purpose of solving such a problem.
- (1) A method for operating a blast furnace includes charging ore and coke including
a carbon iron composite and conventional coke into the blast furnace, wherein the
percentage of the carbon iron composite used is 2% to 50% by mass of the coke.
- (2) In the blast furnace-operating method specified in Item (1), the carbon iron composite
has a particle size of 15 mm to 40 mm.
- (3) In the blast furnace-operating method specified in Item (2), the carbon iron composite
has a particle size of 20 mm to 35 mm.
- (4) In the blast furnace-operating method specified in Item (1), the percentage of
the carbon iron composite used is 25% to 50% by mass of the coke.
- (5) In the blast furnace-operating method specified in Item (4), the percentage of
the carbon iron composite used is 30% to 50% by mass of the coke.
- (6) In the blast furnace-operating method specified in Item (1), the carbon iron composite
has an iron content of 10% to 40% by mass.
[0012] The above problem can be solved by inventions below.
(7) A method for operating a blast furnace using a carbon iron composite includes
charging a coke source material containing the carbon iron composite and conventional
coke into the top of the blast furnace, wherein the percentage of the carbon iron
composite used is 2% to 50% by mass of the amount of the coke source material used.
(8) In the blast furnace-operating method specified in Item (7), the percentage of
the carbon iron composite used is 35% by mass or less of the amount of the coke source
material used.
(9) In the blast furnace-operating method specified in Item (7) or (8), the carbon
iron composite has a particle size less than the particle size of conventional coke
that is charged into the blast furnace alone without being mixed with ore.
[0013] The term "ore" as used herein collectively refers to sintered ores produced from
iron ores, lump ores, and mixtures containing one or more of iron-containing materials,
such as pellets, charged into blast furnaces. Ore layers stacked in blast furnaces
contain an auxiliary material, such as limestone, for adjusting a slug component in
addition to ores in some cases.
Advantageous Effects of Invention
[0014] According to the present invention, a stable operation can be achieved in such a
manner that when a carbon iron composite is used as a portion of a coke material in
the operation of a blast furnace, the upper limit of the amount of the carbon iron
composite used is set.
Brief Description of the Drawings
[0015]
Fig. 1 is a graph showing the relationship between the percentage of a carbon iron
composite used and the pressure drop (relative pressure drop).
Fig. 2 is a schematic view showing the shape of a carbon iron composite.
Fig. 3 is a graph showing the relationship between the percentage of a carbon iron
composite used and a reduction in reducing agent rate.
Fig. 4 is a graph showing the relationship between the percentage of a carbon iron
composite used and the difference between the amount of carbon in a carbon iron composite
and the solution loss carbon amount.
Fig. 5 is a graph showing the relationship between the percentage of a carbon iron
composite used and percentage of the carbon iron composite remaining in a dropping
zone.
Fig. 6 is a schematic view of a pressure drop-measuring unit.
Fig. 7 is a graph showing the relationship between the percentage of a carbon iron
composite used and the pressure drop (relative pressure drop) of a packed bed of a
mixture of conventional coke and a carbon iron composite.
Fig. 8 is a graph showing the particle size distribution of ore.
Fig. 9 is a graph showing the relationship between the particle size of a carbon iron
composite and the pressure drop of an ore + carbon iron composite-mixed layer.
Fig. 10 is a graph showing reaction test conditions for measuring the reaction rate
of coke.
Fig. 11 is a graph showing the relationship between the percentage of a carbon iron
composite used and the relative reaction rate of carbon.
Fig. 12 is a schematic view showing the distribution of a material charged in a blast
furnace in the case of using a carbon iron composite.
Embodiments for carrying out the invention
[0016] A carbon iron composite is produced in such a manner that briquettes are produced
by briquetting a material principally containing coal and iron ore and the coal in
the briquettes is carbonized by heating the briquettes. The term "principally containing
coal and iron ore" means that main raw materials of the carbon iron composite are
coal and iron ore. A material containing 70% by mass or more of a mixture of coal
and iron ore is used to produce the carbon iron composite and a material containing
80% by mass or more of a mixture of coal and iron ore is usually used.
[0017] The higher the content of iron in the carbon iron composite, the more likely the
effect of increasing the reactivity of coke is to occur. When the content of iron
is 10% by mass or more, the effect is significant. When the content of iron is 40%
by mass or more, the effect is saturated. Therefore, the content of iron is preferably
10% to 40% by mass.
[0018] The inventors have predicted changes in conditions for operating a blast furnace
during the use of a carbon iron composite using a heat and material balance model
based on a Rist operation diagram (see, for example, Non-Patent Literature 2) and
have estimated the amount of the carbon iron composite remaining in a dropping zone
from the solution loss amount and the amount of the carbon iron composite charged
into the blast furnace.
[0019] If the carbon iron composite is gasified prior to conventional coke because the carbon
iron composite is higher in reactivity than conventional coke, the amount of the carbon
iron composite remaining in the dropping zone can be given by the following equation
(8):

Herein, when the amount of carbon in the carbon iron composite charged into the blast
furnace is less than or equal to the solution loss carbon, the amount of the carbon
iron composite remaining in the dropping zone is regarded as zero. Preconditions to
determine the balance of these materials are as follows: the content of iron in each
carbon iron composite used is 10%, 30%, or 40% by mass (the remainder is coke) and
the content of carbon in coke is 87.5% by mass.
[0020] The percentage of the carbon iron composite remaining in the dropping zone is given
by the following formula (9):

Results of investigations performed using these formulas are shown in Tables 1 to
3 and Figs. 3 to 5. Table 1 shows examples in which the content of iron in a carbon
iron composite is 10% by mass. Table 2 shows examples in which the content of iron
in a carbon iron composite is 30% by mass. Table 3 shows examples in which the content
of iron in a carbon iron composite is 40% by mass.
In Table 1, Base outlines a case where no carbon iron composite is used, Case 1 outlines
a case where the carbon iron composite is used and the amount of carbon in the carbon
iron composite charged into the blast furnace is less than the solution loss carbon
amount, and Cases 2 and 3 each outline a case where the amount of carbon in the carbon
iron composite charged into the blast furnace is more than the solution loss carbon
amount. An increase in the content of iron in the carbon iron composite increases
the reactivity of the carbon iron composite and the effect of lowering the temperature
of a thermal reserve zone. Thus, the thermal reserve zone temperature and the amount
of carbon derived from the carbon iron composite vary depending on the iron content
thereof even at the same percentage of the carbon iron composite used. These variations
affect the reducing agent rate and solution loss carbon. These phenomena are reflected
in the results shown in Tables 1 to 3.
Fig. 3 is a graph showing the relationship between the percentage of the carbon iron
composite used and a reduction in reducing agent rate. As is clear from Fig. 3, the
higher the content of iron in the carbon iron composite and the higher the percentage
of the carbon iron composite used, the lower the reducing agent rate. For example,
in the case of using 25% by mass of the carbon iron composite with an iron content
of 30% by mass, the reducing agent rate can be expected be lowered by 30 kg/t-p. In
the case of using 30% by mass of the carbon iron composite with an iron content of
10% by mass, the reducing agent rate can be expected be lowered by 20 kg/t-p. The
percentage of the carbon iron composite used (the percentage of the charged carbon
iron composite) is the ratio of the mass of the carbon iron composite charged into
the blast furnace to the sum of the mass of the carbon iron composite charged thereinto
and the mass of conventional coke as given by the following equation and the mass
of the carbon iron composite including iron is used:

[0021]
Table 1
|
|
Base |
Case 1 |
Case 2 |
Case 3 |
Carbon iron composite rate |
kg/t |
0 |
101 |
167 |
204 |
Carbon in carbon iron composite |
kg/t |
0 |
80 |
132 |
161 |
Conventional coke rate |
kg/t |
359 |
247 |
174 |
131 |
Percentage of carbon iron composite |
% |
0 |
29 |
49 |
61 |
Pulverized coal rate |
kg/t |
126 |
126 |
126 |
126 |
Reducing agent rate |
kg/t |
485 |
464 |
450 |
441 |
Thermal reserve zone temperature |
°C |
1000 |
920 |
867 |
833 |
Solution loss carbon |
kg/t |
75 |
70 |
67 |
65 |
Carbon iron composite remaining in dropping zone |
kg/t |
0 |
12 |
81 |
122 |
Percentage of carbon iron composite in dropping zone |
% |
0 |
4 |
32 |
48 |
[0022]
Table 2
|
|
Base |
Case 1 |
Case 2 |
Case 3 |
Carbon iron composite rate |
kg/t |
0 |
104 |
171 |
212 |
Carbon in carbon iron composite |
kg/t |
0 |
64 |
105 |
130 |
Conventional coke rate |
kg/t |
359 |
251 |
181 |
130 |
Percentage of carbon iron composite |
|
0 |
29 |
49 |
61 |
Pulverized coal rate |
kg/t |
126 |
126 |
126 |
126 |
Reducing agent rate |
kg/t |
485 |
450 |
426 |
412 |
Thermal reserve zone temperature |
°C |
1000 |
880 |
800 |
750 |
Solution loss carbon |
kg/t |
75 |
67 |
61 |
57 |
Carbon iron composite remaining in dropping zone |
kg/t |
0 |
0 |
72 |
120 |
Percentage of carbon iron composite in dropping zone |
|
0 |
0 |
28 |
47 |
[0023]
Table 3
|
|
Base |
Case 1 |
Case 2 |
Case 3 |
Carbon iron composite rate |
kg/t |
0 |
105 |
179 |
223 |
Carbon in carbon iron composite |
kg/t |
0 |
55 |
94 |
117 |
Conventional coke rate |
kg/t |
359 |
257 |
186 |
143 |
Percentage of carbon iron composite |
% |
0 |
29 |
49 |
61 |
Pulverized coal rate |
kg/t |
126 |
126 |
126 |
126 |
Reducing agent rate |
kg/t |
485 |
445 |
419 |
403 |
Thermal reserve zone temperature |
°C |
1000 |
872 |
787 |
733 |
Solution loss carbon |
kg/t |
75 |
65 |
58 |
54 |
Carbon iron composite remaining in dropping zone |
kg/t |
0 |
0 |
67 |
121 |
Percentage of carbon iron composite in dropping zone |
% |
0 |
0 |
27 |
46 |
[0024] As is clear from Figs. 4 and 5, when the percent of the charged carbon iron composite
is about 30% by mass, the amount of carbon in the carbon iron composite is equal to
the solution loss amount. When the carbon iron composite charged into the blast furnace
is more than 30% by mass, the amount of carbon in the carbon iron composite exceeds
the solution loss amount and therefore the carbon iron composite remains in the dropping
zone. The percentage of the carbon iron composite that is located at the intersection
of the abscissa in Fig. 5 and each graphic line corresponds to the percentage of the
carbon iron composite at an ordinate value of zero in Fig. 4.
[0025] The pressure drop of a packed bed of a mixture of conventional coke and a carbon
iron composite was measured with a pressure drop-measuring unit shown in Fig. 6. The
pressure drop-measuring unit 1 had a diameter of 400 mm and a height of 2,000 mm.
Measurement was performed in such a manner that a pressure drop-measuring sample 2
was stacked to a height of 1,000 mm. The following materials were used: conventional
coke with a particle size of 40 mm to 60 mm, a carbon iron composite with a size of
18 mm x 16 mm x 12 mm (a particle size of 15 mm), and a carbon iron composite with
a size of 30 mm x 25 mm x 18 mm (a particle size of 24 mm). In the present invention,
the size of each carbon iron composite is expressed in the form of A × B × C shown
in Fig. 2 and the particle size of the carbon iron composite is calculated by the
formula (A x B x C)
1/3. Fig. 7 shows pressure drop measurement results obtained by varying the percentage
of the blended carbon iron composite. When the percentage of the blended carbon iron
composite is more than 30% by mass, the pressure drop increases significantly. This
is probably because the carbon iron composite has a smaller particle size and fewer
irregularities as compared with the conventional coke and therefore has the effect
of lowering the voidage of the packed bed.
[0026] The results shown in Fig. 7 are used as results obtained by simulating a dropping
zone and the relationship between the amount of each carbon iron composite shown in
Tables 1 to 3 and the percentage of the carbon iron composite remaining in the dropping
zone is entered in Fig. 7, whereby Fig. 1 is obtained.
As is clear from Fig. 1, the pressure drop (relative pressure drop) increases when
the percentage of the carbon iron composite remaining in the dropping zone is about
10% by mass or more and the pressure drop increases sharply when the percentage of
the carbon iron composite having an iron content of 10% by mass and a particle size
of 15 mm is 50% by mass or more, that is, the percentage of the carbon iron composite
remaining in the dropping zone is 30% by mass or more. Thus, the pressure drop does
not increase even when the percentage of the following carbon iron composite is 50%
by mass: a carbon iron composite having an iron content of more than 10% by mass and/or
a particle size of more than 15 mm. From the above, the inventors have found that
in the case of using a carbon iron composite having an iron content of 10% to 40%
by mass and a particle size of 15 mm or more, the upper limit of the percentage of
the carbon iron composite used is 50% by mass in order to avoid a sharp increase in
pressure drop.
[0027] From the above, the following conclusion is obtained: a conclusion that the pressure
drop of the dropping zone is significantly deteriorated when the percentage of the
amount of the carbon iron composite in the amount of coke used, that is, the sum of
the amount of the carbon iron composite and the amount of the conventional coke exceeds
50% by mass. Thus, a blast furnace needs to be operated in such a manner that the
amount of the carbon iron composite charged into the blast furnace is adjusted such
that the percentage of the carbon iron composite is 50% by mass or less of the total
amount of coke, including conventional coke, charged into the blast furnace. On the
other hand, in order to achieve the effect of lowering the reducing agent rate by
20 kg/t or more, the percentage thereof is preferably 25% by mass or more and more
preferably 30% by mass or more.
[0028] A carbon iron composite is preferably used in such a manner that the carbon iron
composite is mixed with ore (an iron-containing material containing such as sintered
ore, pellets, lump ore and the like) (see, for example, Patent Literature 1). In this
case, it is operationally important that the gas permeability of a mixed layer of
ore and the carbon iron composite is well maintained. Therefore, the inventors have
investigated the influence of the size of the carbon iron composite on the gas permeability
of the mixed layer of ore and the carbon iron composite (hereinafter referred to as
"ore + carbon iron composite-mixed layers"). Fig. 8 shows the particle size distribution
of ore used. The inventors have calculated the influence of the particle size of the
carbon iron composite mixed in an ore layer on the gas permeability thereof using
the following equation (11) on the assumption that the percentage of the carbon iron
composite in the ore layer is 21% by volume (which corresponds to a carbon iron composite
percentage of 35% by mass):

wherein Φ is the shape factor (which is 0.7), d
p is the average particle size of the ore + carbon iron composite-mixed layer, and
ε is the voidage of the ore + carbon iron composite-mixed layer. The average particle
size of the ore + carbon iron composite-mixed layer was calculated in such a manner
that the particle size distribution shown in Fig. 8 was corrected depending on the
predicted size of the carbon iron composite. The voidage thereof was estimated from
the particle size distribution (see Non-Patent Literature 3). Results are shown in
Fig. 9. It is clear that the change in pressure drop is small when the particle size
of the carbon iron composite is between 15 mm to 40 mm. When the particle size of
the carbon iron composite falls below 15 mm, the average particle size of the ore
+ carbon iron composite-mixed layer lowers and therefore the pressure drop increases.
On the other hand, the pressure drop increases even under such a condition that the
size of the carbon iron composite is large. This is due to that the particle size
distribution expands and therefore the voidage lowers. From the above, it is clear
that the particle size of the carbon iron composite is 15 mm to 40 mm for the purpose
of avoiding an increase in pressure drop. A carbon iron composite, produced with a
press, having such a shape as shown in Fig. 2 preferably has a particle size (= (A
x B x C)
1/3) of 15 mm to 40 mm as defined above. A carbon iron composite, having an irregular
shape, produced in a current coke oven is preferably used in such a manner that this
carbon iron composite is sieved so as to have a particle size of 15 mm to 40 mm before
being charged into a blast furnace.
[0029] The amount of a carbon iron composite effective in promoting a reaction was investigated
by a gasification reaction test simulating blast furnace conditions. The carbon iron
composite and conventional coke were packed into a crucible with an inner diameter
of 76 mm at a predetermined ratio and were tested under gas-temperature conditions
shown in Fig. 10, whereby the reaction rate of carbon in tested coke was measured.
Fig. 11 shows the relative reaction rate of carbon (the relative carbon reaction rate)
determined in such a manner that a conventional coke percentage of 100% by mass (a
carbon iron composite percentage of 0% by mass) is set to a base and the percentage
of the carbon iron composite used is varied. The relative carbon reaction rate is
herein the sum of the reaction rate of the carbon iron composite and the reaction
rate of conventional coke. There is no clear difference from the base when the percentage
of the carbon iron composite used is about 1% by mass, the reaction rate increases
from the base when the percentage of the carbon iron composite used is 2% by mass,
and the reaction rate increases with an increase in the percentage of the carbon iron
composite used when the percentage of the carbon iron composite used is further increased.
When the amount of the mixed carbon iron composite is extremely small, the unevenness
of a mixed packed layer is significant; hence, a reaction-promoting effect is probably
unlikely to occur.
Thus, the percentage of the carbon iron composite used needs to be 2% by mass or more
of the amount of coke used, that is, the total amount of coke including conventional
coke.
[0030] For the particle size of carbon iron composites, the present invention is preferably
applied to a case where a carbon iron composite with a particle size less than the
particle size of conventional coke charged into a blast furnace alone without being
mixed with ore is used. In the case of using the carbon iron composite with a particle
size less than the particle size of conventional coke charged into a blast furnace
alone, the gas or liquid permeability of a furnace bottom section may possibly be
deteriorated and effects of the present invention are significant. When the particle
size of the carbon iron composite is greater than that of conventional coke, the gas
or liquid permeability of the furnace bottom section is unlikely to be deteriorated.
The term "ore" as used herein refers to an iron source material, such as lump ore
or sintered ore, charged into a blast furnace.
EXAMPLE 1
[0031] A carbon iron composite was tested in a blast furnace. The carbon iron composite
was produced in such a manner that a mixture of coal and iron ore was briquetted with
a briquetting machine, was charged into a vertical shaft furnace, and was then carbonized.
The carbon iron composite had a size of 30 mm x 25 mm x 18 mm (a particle size of
24 mm). The rate of reduction of iron ore in carbon iron composite was 80% to 85%
and the drum index DI
150/15 of the carbon iron composite was 82. The carbon iron composite contained 30% by mass
iron and 70% by mass coke with a carbon content of 87.5% by mass. Raw materials were
charged into the blast furnace in such a manner that mixed layers of the carbon iron
composite 10 and ore 20 and layers of conventional coke 30 alone were alternately
stacked as shown in Fig. 12. With reference to Fig. 8, the left end is the furnace
center and reference numeral 40 represents a furnace wall. The conventional coke 30
had an average particle size of 45 mm. With reference to Fig. 12, the left end is
the furnace center and reference numeral 40 represents a furnace wall. Five percent
by mass of the conventional coke was small-size coke with a particle size of 10 mm
to 25 mm and was mixed with the ore. The layers of conventional coke 30 alone had
an average particle size of 45 mm.
[0032] An operation test was performed in such a manner that the percentage of the mixed
carbon iron composite was varied when the raw materials were charged into the blast
furnace as described above. Table 4 shows variations in the reducing agent rate and
pressure drop index (the relative pressure drop index of a furnace bottom section)
of the blast furnace. In Table 4, Base is a case where no carbon iron composite is
used and Cases 1 to 3 are cases where the percentage of the carbon iron composite
used is increased within a range of 50% by mass or less.
[0033]
Table 4
|
|
Base |
Case 1 |
Case 2 |
Case 3 |
Carbon iron composite rate |
kg/t |
0 |
104 |
171 |
180 |
Carbon in carbon iron composite |
kg/t |
0 |
73 |
120 |
126 |
Conventional coke rate |
kg/t |
379 |
271 |
201 |
183 |
Percentage of carbon iron composite |
mass % |
0 |
28 |
46 |
50 |
Pulverized coal rate |
kg/t |
126 |
126 |
126 |
120 |
Reducing agent rate |
kg/t |
505 |
470 |
446 |
430 |
Relative pressure drop index of furnace bottom section |
- |
1 |
1.01 |
1.03 |
1.05 |
[0034] Although the pressure drop increased with an increase in the percentage of the carbon
iron composite used, a stable operation was capable of being continued because the
percentage of the carbon iron composite was adjusted to 50% by mass or less. When
the percentage of the carbon iron composite used was temporarily increased to 55%
by mass, it was difficult to continue a stable operation because of an increase in
the pressure drop of a furnace bottom section. Reference Signs List
[0035]
- 1
- pressure drop-measuring unit
- 2
- pressure drop-measuring sample
- 10
- carbon iron composite
- 20
- ore
- 30
- conventional coke
- 40
- furnace wall