[0001] The present invention relates to a method and an apparatus for treating a pipeline
for other welded structure under tensile stress to increase resistance to stress corrosion
cracking.
[0002] Stress corrosion cracking can occur in stainless steel or high nickel process piping
during operational service, particularly in nuclear, chemical, oil and gas operational
environments. There are three factors which predominantly control the stress corrosion
cracking (SCC) mechanism: tensile residual stress fields in the material, high temperature,
and high chloride ion concentrations. High tensile residual stress fields arise across
welds due to the heat cycle and shrinkage stress associated with welding. The SCC
mechanism therefore predominantly occurs in the weld and heat affected zones.
[0003] In a first aspect, the present invention provides a method of treating a pipeline
(or other welded structure under tensile stress) to increase resistance to stress
corrosion cracking, the method comprising heating the outside surface of a weld of
the pipeline, and cooling the inside surface of the weld of the pipeline with a cryogenic
coolant during and/or after the heating step to provide a tensile stress-relieved
layer on the inside of the pipeline
[0004] In a further aspect, the present invention provides an apparatus for treating a pipeline
(or other welded structure under tensile s tress) to increase resistance to stress
corrosion cracking (SCC), comprising at least one heat source arranged to be adjacent
to the outside surface of a weld of a pipeline; and at least one nozzle dimensioned
to be received within the pipeline and to be located adjacent to the inside surface
of a weld, in which the at least one nozzle is adapted to provide a cryogenic coolant
to the inside surface of the weld of a pipeline.
[0005] "Cryogenic coolant" is herein defined as a coolant having a temperature of less than
-50°C. A "pipeline" is herein defined as at least two pipe sections having at least
one welded joint there between. The "weld" may include both the weld (or fusion) zone
and the heat affected zone.
[0006] It will be appreciated that the stress-relieved layer comprises an area of the pipe
in which the tensile residual stress is decreased in comparison to a like pipe section
on which the method of the invention has not been applied. Typically the stress-relieved
layer starts at the inner surface of the pipe (upon which the cryogenic coolant may
have impinged) and extends through the thickness of the pipe towards the outer surface
(which has been heated). The stress-relieved layer may extend partially through the
thickness of the pipe. The stress-relieved layer preferably includes an innermost
region of compressive residual stress.
[0007] The heating and/or cooling is preferably applied for a sufficient duration to provide
a tensile stress-relieved layer of a desired depth. The tensile stress relieved layer
preferably includes a region of compressive residual stress. The duration of the cryogenic
treatment should be sufficient to provide an adequate treatment depth. The stress-relieved
layer may cover approximately the innermost third of the thickness of the pipeline,
for example if the pipeline has a wall thickness of at least 10 mm, then the depth
of the tensile stress-relieved layer should be at least 3 mm. Thinner layers will
suffice for thinner pipelines.
[0008] All weld zones have tensile stress fields and are therefore susceptible to SCC. It
has been found that super-cooling the inside surface of the weld zone on a pipeline
with a cryogenic coolant results in a modification of the tensile residual stress
field to a compressive residual stress field. The compressive residual stress field
has the benefit of resisting SCC as SCC only occurs in tensile stress fields. By modifying
the stress field the resistance to SCC is dramatically improved in piping, such as
for example in austenitic stainless alloys, including austentic stainless steel piping,
and high nickel piping, such as for example alloy 625, alloy 725, alloy C276, alloy
C22, monel, alloy 905L, alloy 304L, alloy 316L.
[0009] The cryogenic coolant is preferably selected from one or more of solid carbon dioxide
particles, liquid nitrogen, liquid air and liquid argon, or a mixture thereof.
[0010] The cryogenic coolant is preferably applied from at least one cooling nozzle. For
example cooling the inside surface of the weld zone of the pipeline with a cryogenic
coolant may comprises expanding a liquid coolant through a nozzle proximal to the
inside surface. The expansion of the coolant may advantageously result in a change
of state of the coolant from liquid to solid.
[0011] Preferably the coolant is applied around the full internal circumferential surface
of the pipeline. For example the cooling nozzle can be a 360° radial cooling nozzle,
for example a spray ring. The spray ring may be positioned within the pipeline to
effect the cooling. The cooling nozzle may for example comprise a circumferentially
distributed array of nozzles, for example the cooling nozzle may comprise at least
12 nozzles.
[0012] The weld is preferably heated to a temperature of between about 600°C and about 700°C
using a suitable heat source, such as for example induction heating or oxy fuel heating
burners.
[0013] It has been found that the method of the invention can extend plant life by delaying
or eliminating stress corrosion cracking in existing pipelines, for example in situ
process plant pipelines. This method can be used on existing process pipelines, such
as for example pipelines in nuclear, chemical, oil and gas operational environments.
Accordingly, a further aspect of the invention provides a method of improving the
life of a pipeline comprising treating welds in the pipeline to increase resistance
to stress corrosion cracking, the method comprising heating the outside surface of
a weld of a pipeline, and cooling the inside surface of the weld of the pipeline with
a cryogenic coolant during and/or after the heating step to provide a tensile stress-relieved
layer on the inside of the pipeline.
[0014] The method and apparatus may be suitable for use either on an existing weld zone
or during the formation of a new weld zone. Accordingly, a further aspect of the invention
provides a method of assembling a pipeline comprising forming a root weld between
adjacent pipe sections; and treating the weld to increase resistance to stress corrosion
cracking, the method comprising heating the outside surface of a weld of a pipeline,
and cooling the inside surface of the weld of the pipeline with a cryogenic coolant
during and/or after the heating step to provide a tensile stress-relieved layer on
the inside of the pipeline. The step of treating the weld may be performed while simultaneously
forming a capping weld. The capping weld may be a high heat input weld, for example
the capping weld may be a Last Pass Heat Sink Weld.
[0015] The pipeline/pipe is preferably composed of austenitic stainless steel or high nickel
alloys, such as for example alloy 625, alloy 725, alloy C276, alloy C22, monel, alloy
905L, alloy 316L.
[0016] Although illustrative embodiments of the invention are described in detail herein
with reference to the accompanying drawings, it is to be understood that the invention
is not limited to these precise embodiments. As such, many modifications and variations
will be apparent to practitioners skilled in the art. Furthermore, it is contemplated
that a particular feature described either individually or as part of an embodiment
can be combined with other individually described features, or parts of other embodiments,
even if the other features and embodiments make no mention of the particular feature.
Thus, the invention extends to such specific combinations not already described.
[0017] The invention may be performed in various ways, and by way of example only embodiments
thereof will now be described, reference being made to the accompanying figures in
which:
Figure 1 is a schematic cross-sectional view of a pipeline comprising an apparatus
according to one embodiment of the invention;
Figure 2 is a schematic cross-sectional view of a pipeline comprising an apparatus
according to a further embodiment of the invention;
Figure 3 is an image of the cooling apparatus according to an embodiment of the invention;
and
Figure 4 is an image of the cooling apparatus of figure 3 in use.
[0018] As seen in figures 1 and 2, an austenitic stainless steel pipeline 4 comprises first
and second pipe sections 4a and 4b joined by a weld 3. A heat source 5 is arranged
around the outside surface 2 of the pipeline 4. A cooling apparatus 6 is provided
within the pipeline 4 for delivering cryogenic coolant to the inside surface 12 of
the weld 3 of the pipeline 4. The cooling apparatus 6 is inserted into the pipeline
4 at a free end or via an access opening (not shown) and moved into alignment with
the weld 3 prior to use. For long pipelines, such as in situ pipelines in processing
plants, the cooling apparatus may be attached to a pipe pig (not shown) for positioning
within the pipeline (such pipe pigs are well known in the art and commercially available
and are not, therefore, described herein).
[0019] The cooling apparatus 6 comprises an inlet 8 for delivering coolant, which in the
preferred embodiment is provided as liquid carbon dioxide, along the pipeline 4. The
cooling apparatus is provided with multiple radial passageways 7 to distribute the
coolant around the inner circumference of the pipeline 4. Each passageway terminates
at a nozzle 10 arranged to eject coolant towards the inside surface 12 of the pipeline
4. By providing a plurality of nozzles 10 at circumferentially distributed locations
around the pipeline the cooling apparatus 6 enables coolant to be delivered to the
entire internal circumference of the pipeline simultaneously.
[0020] In use, the heat sources 5 in the form of an array of induction heaters 5 are arranged
adjacent to the outside surface 2 of the pipeline 4 so as to heat the weld 3 to be
treated. The cooling apparatus 6 is inserted inside pipeline 4 and moved along the
pipeline 4 until the nozzles 10 are adjacent to the inside surface 12 of the weld
3.
[0021] The heat sources 5 raise the temperature of the outside surface to between approximately
600°C and 700°C. Simultaneously or immediately after heating, liquid carbon dioxide
is pumped into the cooling apparatus 6 through inlet 8. The liquid carbon dioxide
is pumped out of the nozzles 10 under high pressure. The liquid carbon dioxide turns
into solid carbon dioxide snow, having a temperature of approximately -70°C, as it
expands out of nozzles 10. The carbon dioxide snow 14 sublimes immediately on contact
with the inside surface 12 of the hot weld 3. Advantageously, such sublimation means
that spent coolant does not accumulate in the area of the weld 3. at high pressure
to transform the liquid carbon dioxide to solid snow and gas.
[0022] This rapid cooling of the inside surface 12 of the hot weld 3 results in a modification
of the tensile residual stress field to a compressive residual stress field. The compressive
residual stress field is able to resist SCC.
[0023] Figure 2 shows an alternative embodiment of the invention. This embodiment is identical
to the embodiment of Figure 1 but uses an alternate heat source 5' in the form of
an array of oxy fuel gas burners 50 arranged along the outer surface 2 of the pipeline
4.
[0024] As seen in figure 3, the cooling apparatus 6 can comprise a body portion 62 having
twelve radially extending nozzles 10. The nozzles 10 are evenly distributed about
the circumference of the body 62. The cooling apparatus 6 comprises an inlet 64 which
has a threaded connector 66 for receiving a pipe to provide a source of cryogenic
coolant (not shown).
[0025] As seen in figure 4, in use the inlet 64 of the cooling apparatus 6 is connected
to a source of liquid carbon dioxide 68. The liquid carbon dioxide is pumped out of
the twelve radially extending nozzles 10 under high pressure. Due to the even distribution
of the nozzles around the entire circumference of the body 62 the cooling apparatus
ensures that coolant is delivered simultaneously and evenly to the entire internal
circumferential surface of the weld 3. As the liquid carbon dioxide expands under
pressure through the nozzles 10 it transforms into solid carbon dioxide snow 70.
[0026] The method is performed for a duration which is sufficient to transform the weld
zone such that there is an adequate treatment depth. By way of example pipeline having
a 10mm wall thickness may be treated such that the tensile stress relieved layer is
at least 3mm thick.
[0027] In experimental pipeline sections to verify the effectiveness of embodiments of the
invention it was found that the residual tensile stress on the outer surface of a
pipeline could be reduced from 67 microstrain to 17 microstrain by application of
the treatment of the invention.
[0028] The skilled person will appreciate that other cryogenic coolants are available with
significantly lower temperatures that carbon dioxide snow. However, carbon dioxide
has been found to have the highest heat transfer characteristics due to the immediate
sublimation of the carbon dioxide snow upon contact with the hot weld surface. In
contrast, other coolants may vaporise without contacting the weld surface.
1. A method of treating a pipeline (or other welded structure under tensile stress) to
increase resistance to stress corrosion cracking, the method comprising heating the
outside surface of the weld of a pipeline, and cooling the inside surface of the weld
of the pipeline with a cryogenic coolant during and/or after the heating step to provide
a tensile stress-relieved layer on the inside of the pipeline.
2. A method as claimed in claim 1, in which the heating and/or cooling is applied for
a sufficient duration to provide a tensile stress-relieved layer of a desired depth.
3. A method as claimed in claim 2, in which the stress-relieved layer includes a region
of compressive residual stress.
4. A method as claimed in any preceding claim, in which the cryogenic coolant is selected
from one or more of solid carbon dioxide particles, liquid nitrogen, liquid air and
liquid argon.
5. A method as claimed in claim 4, in which the cryogenic coolant is solid carbon dioxide
snow.
6. A method as claimed in any preceding claim, in which the outside surface of the weld
of the pipeline is heated to a temperature between approximately 600 and 700°C.
7. A method as claimed in any preceding claim, in which the heating is carried out using
oxy-fuel heating burners.
8. A method as claimed in any preceding claim, in which the pipeline is composed of austenitic
stainless steel or high nickel alloys.
9. A method as claimed any preceding, in which the heating step is carried out on an
existing weld.
10. A method as claimed in any one of claims 1 to 8, in which the method is carried out
on existing pipelines.
11. A method as claimed in any preceding claim, in which the cooling is applied to the
full internal circumferential surface of the weld of the pipeline.
12. A method of improving the life of a pipeline comprising treating welds in the pipeline
according to the method of any of claims 1 to 11.
13. A method of assembling a pipeline comprising:
a. forming a root weld between adjacent pipe sections; and
b. treating the weld according to the method of any of claims 1 to 11.
14. A method as claimed in claim 14, in which the step of treating the weld further comprises
simultaneously forming a capping weld.
15. An apparatus for treating a pipeline (or other welded structure under tensile stress)
to increase resistance to stress corrosion cracking, comprising at least one heat
source arranged to be adjacent to the outside surface of a weld of a pipeline; and
at least one nozzle dimensioned to be received within the pipeline and to be located
adjacent to the inside surface of a weld, in which the at least one nozzle is adapted
to provide a cryogenic coolant to the inside surface of the weld of a pipeline.
16. An apparatus as claimed in claim 11, in which the at least one nozzle is a 360° radial
cooling nozzle.