Technical Field
[0001] The present invention relates to a tobacco filter capable of selectively and efficiently
eliminating aldehydes (in particular, formaldehyde) and to tobacco provided with the
tobacco filter.
Background Arts
[0002] As an adsorbent for filtering a component in a tobacco smoke, a variety of constituent
components are proposed. In
JP-B 3 895327, equivalent to
WO-A2003/056947, a cigarette is disclosed that is characterized by containing a tobacco rod and a
filter being connected to the tobacco rod and containing compounds of hydrotalcites
of 48.3 to 146.7 mg.
Summary of the Invention
[0003] An object of the present invention is to provide a tobacco filter capable of selectively
and efficiently eliminating aldehydes (in particular, formaldehyde) and provide tobacco
provided with the tobacco filter.
[0004] The present invention provides a tobacco filter containing magnesium aluminometasilicate
of 0.5 to 95 % by mass and tobacco having the tobacco filter or a tobacco product
having the tobacco filter or a cigarette having the tobacco filter or a filter product.
Brief Description of the Drawings
[0005]
Fig. 1 is an illustrative drawing of a testing method for confirming an adsorption
effect of formaldehyde.
[0006] In Fig. 1, the numeral reference 1 represents tobacco, 2 represents filter, 3 represents
cut surface, 4 represents sealing tape, 5 represents magnesium aluminometasilicate
layer, 6 represents glass tube, and 7 represents sealing tape.
Detailed Description of the Invention
[0007] A tobacco filter of the present invention is excellent in a selective adsorption
property for aldehydes, in particular for formaldehyde.
[0008] A tobacco filter of the present invention contains magnesium aluminometasilicate
in a filter material. As the filter material, filter tow conventionally used in tobacco
filters, non-woven fabrics or the like can be used.
[0009] Magnesium aluminometasilicate used in the present invention is a known component
used as an antacid, a filler, and the like.
[0010] Although the particle size of magnesium aluminometasilicate is not limited in particular,
the particle size range of 100 µm to 1000 µm is preferred from the perspective of
containing magnesium aluminometasilicate in a predetermined ratio in the tobacco filter
and enhancing the adsorption effect of aldehydes.
[0011] Although the specific surface area of magnesium aluminometasilicate is not limited
in particular, the range of 100 m
2/g to 300 m
2/g is preferred from the perspective of enhancing the adsorption effect of aldehydes.
[0012] Although it is preferable that the pH of a 4% by mass slurry of such magnesium aluminometasilicate
is in an alkaline region (from 8.5 to 10), the pH may also be in a neutral region
(from 6 to 8).
[0013] In addition, the tobacco filter can also contain known various components blended
in tobacco filters such as perfumes.
[0014] The ratio of magnesium aluminometasilicate in the tobacco filter is from 0.5% by
mass to 95% by mass of magnesium aluminometasilicate, is preferably from 2% by mass
to 85% by mass, and is more preferably from 5% by mass to 70% by mass.
[0015] The tobacco filter of the present invention preferably has an either embodiment of:
- (I) the one having a filter divided into two or three or more segments and having
a layer containing magnesium aluminometasilicate in one spot or two or more spots
between the adjacent segments; or
- (II) the one containing magnesium aluminometasilicate in a dispersed state in the
filter.
[0016] In the embodiment of (I), in a case where the filter includes three or more segments,
it is also possible to have one segment of a layer containing magnesium aluminometasilicate
and the rest of layers containing a perfume and the like.
[0017] The tobacco of the present invention is one provided with the tobacco filter mentioned
above, which is effective in reducing aldehydes in the mainstream smoke of tobacco.
Examples
Examples and Comparative Example
[0018] A tobacco filter shown in Fig. 1 (b) was produced in a manner described below to
test the adsorption effect for aldehydes.
[0019] A filter of Peace Lights, trade name, (produced by Japan Tobacco, Inc.) was cut at
a position 14 mm away from the end portion to separate it into filters 2a and 2b.
[0020] After removing the filter 2a, a glass tube 6 was fitted onto the remaining filter
2b to fill a predetermined amount of magnesium aluminometasilicate 5 (trade name Neusilin;
Fuji Chemical Industry Co., Ltd.). The types and properties of magnesium aluminometasilicate
used in each Example are shown in Table 1.
[0021] The magnesium aluminometasilicate was treated with sieves having openings (JIS Z8801-1
2006) of 1.0 mm and 0.1 mm, respectively, to obtain that having a particle size of
passing through the openings of 1.0 mm, but not passing through the openings of 0.1
mm. The filter was filled with the magnesium aluminometasilicate.
[0022] After that, the filter 2a was fitted into the glass tube 6 so as to sandwich the
magnesium aluminometasilicate 5 with the filter 2b.
[0023] After that, resultant item was tightly sealed with a sealing tape 7 so as to completely
cover contact surfaces of the glass tube 6 and the filters 2a and 2b to fabricate
tobacco for testing. Fig. 1 (a) is tobacco as a control, in which a filter was cut
in the same manner as in Fig. 1(b) to make filters 2a and 2b and then they were tightly
sealed with a sealing tape 4 so as to completely cover cut surfaces.
[0024] Through the use of the tobacco for testing shown in Figs. 1(a), (b), measurement
was carried out in a method described below by using a measuring device shown in Fig.
2 of
JP-B 3895327. Results are shown in Table 1.
(Retention Rate of Formaldehyde)
[0025] Through the use of the tobacco for testing (Fig. 1b) and the tobacco as the control
(Fig. 1a), smoking was carried out by a constant volume automatic smoking machine
of a piston type (RM20/CS manufactured by Borgwaldt KC GmbH) under the conditions
of a flow rate of 17.5 ml/second, a smoking time period of 2 seconds/time, and a smoking
frequency of 1 time/minute. Formaldehyde in the mainstream smoke was collected in
a DNPH (dinitrophenylhydrazine) solution and was derivatized with the DNPH, and then
was measured by using a gas chromatograph (G-3000 manufactured by Hitachi, Ltd.) using
the UV (ultraviolet) absorbance.
[0026] By defining an amount of formaldehyde collected by using the tobacco as the control
as Tf and an amount of formaldehyde collected by using the tobacco for testing of
Comparative Example and Examples as Cf, a formaldehyde retention rate was calculated
by the following equation.

[0027] A smaller retention rate of formaldehyde shows a more excellent adsorption performance
for formaldehyde. Other aldehydes were also evaluated in a method similar to the above.
Table 1
| |
Type of Magnesium Aluminometasilicate |
Content of Magnesium Aluminometasilicate (% by mass) |
Residual Ratio of Aldehydes (%) |
| Type |
Specific Surface Area (m2/g) |
pH of 4% by mass slurry |
Formaldehyde |
Acetaldehyde |
Propionaldehyde |
Crotonaldehyde |
| Comparative Example 1 (Control) |
(Not Used) |
0 |
100 |
100 |
100 |
100 |
| Example 1 |
Neusilin SG2 |
110 |
9.2 |
33.8 |
26 |
90 |
61 |
37 |
| Example 2 |
Neusilin SG2 |
110 |
9.2 |
16.9 |
34 |
97 |
82 |
71 |
| Example 3 |
Neusilin US2 |
300 |
7.3 |
16.6 |
30 |
89 |
81 |
46 |
1. A tobacco filter, comprising magnesium aluminometasilicate in an amount of 0.5 to
95 % by mass.
2. The tobacco filter according to Claim 1, wherein the filter has a layer comprising
magnesium aluminometasilicate therein.
3. The tobacco filter according to Claim 1, wherein the filter comprises magnesium aluminometasilicate
in a dispersed state therein.
4. A tobacco, comprising the tobacco filter according to any one of Claims 1 to 3.