FIELD
[0001] The present disclosure relates to optoelectronic devices.
BACKGROUND
[0002] Numerous types of optoelectronic devices that are based on semi-conductor devices
are known. For example, solar cells, light emitting diodes (LEDs), imaging devices,
and photo-detectors may be based on semi-conductor devices. Such optoelectronic devices
may be operated by forward biasing, reverse biasing, or no biasing. For example, an
LED may be operated by forward biasing a diode junction to cause light to be emitted.
Some photo-detectors or imaging devices may be operated by reverse biasing a diode
junction (note that the diode junction may not need to be reverse biased for detector
operation). Solar cells, otherwise known as photo-voltaic cells, may be operated without
applying any bias. Instead, photons absorbed by photo-active regions of the device
generate voltage or/and current.
[0003] The foregoing illustrates that such optoelectronic devices need two electrical contacts.
For many optoelectronic devices, the electrical contacts are placed at opposite sides
of the device, which may be referred to as a top and bottom electrical contact, respectively.
Moreover, at least one side of the optoelectronic device needs to be able to either
receive or emit light, at least for a relevant range of wavelengths. By a relevant
range of wavelengths it is meant a range of wavelengths that is either absorbed or
emitted by the photo-active regions.
[0004] For many optoelectronic devices, light is emitted or received through the top electrical
contact. For such optoelectronic devices, a trade-off is made between optical transparency
and electrical conductivity of the top electrical contact. For example, the top electrical
contact may be made from a material that has good optical transparency, at least in
the relevant range of wavelengths for the device. As one example, the top electrical
contact may be formed from indium-tin-oxide (ITO). However, optically transparent
materials may not be as electrically conductive as desired. Hence, operation of the
device may suffer. For example, when being operated as a solar cell, greater resistance
of the top electrical contact results in greater voltage drop across the top electrical
contact. On the other hand, electrically conductive materials may not be as optically
transparent as desired.
[0005] Note that some materials that may be used for top electrical contacts are optically
transparent for a relatively narrow range of wavelengths. Therefore, they may be suited
for optoelectronic devices that are intended to be operated over a narrow range of
wavelengths. However, it may be desirable to operate the device over a wider range
of wavelengths. For example, it may be desirable to operate a solar cell over a wide
range of wavelengths in order to capture energy present across a wide range the solar
spectrum. It may be desirable to operate some LED devices over a wide range of wavelengths
also. For example, it may be desirable to have an LED device that can produce light
of different colors. Also, imaging devices should be able to detect different colors.
[0006] Therefore, improvements are desired in the electrical contacts for optoelectronic
devices.
[0007] Semiconductor based solar cells pass solar radiation from a front side of the solar
cell through one or more photoactive regions to a back side of the solar cell. Charge
carriers are generated due to absorption of photons in the photoactive region. Each
photoactive region may be associated with one p-n junction. For some devices, a given
photoactive region absorbs light over only a limited range of wavelengths, depending
on the materials used to form the p-n junction. In order to increase the solar cell's
efficiency, the p-n junctions may be formed from different materials such that light
over a greater range of wavelengths can be absorbed. This is typically referred to
as a "multi-junction" design.
[0008] However, the charge carriers that are generated by each photoactive regions need
a path to flow. In some devices, "tunnel junctions" allow charge carriers to flow
through the solar cell. For example, a separate tunnel junction may join each part
of the solar cell that has a different photoactive region. Unfortunately, tunnel junctions
can be difficult to fabricate.
[0010] While such devices are known, further improvements are desired in optoelectronic
devices. For example, better control of the generated (or detected) color is desired.
[0011] The approaches described in this section are approaches that could be pursued, but
not necessarily approaches that have been previously conceived or pursued. Therefore,
unless otherwise indicated, it should not be assumed that any of the approaches described
in this section qualify as prior art merely by virtue of their inclusion in this section.
BRIEF DESCRIPTION OF THE DRAWINGS
[0012] The present disclosure is illustrated by way of example, and not by way of limitation,
in the figures of the accompanying drawings and in which like reference numerals refer
to similar elements and in which:
Figure 1A depicts one embodiment of an optoelectronic device having a top sidewall
electrical contact.
Figure 1B depicts one embodiment of an optoelectronic device having a top sidewall
electrical contact.
Figure 2A is a side sectional perspective view of one embodiment of an optoelectronic
device having a top sidewall electrical contact.
Figure 2B depicts an embodiment in which a portion of the photo-active region extends
above a top sidewall electrical contact.
Figure 2C is a side sectional perspective view of one embodiment of an optoelectronic
device having a top sidewall electrical contact.
Figure 3A depicts one embodiment of an optoelectronic device having an intermediate
sidewall electrical contact.
Figure 3B depicts a side perspective cross-sectional view of one embodiment of an
optoelectronic device having an intermediate sidewall electrical contact.
Figure 3C depicts one embodiment of an optoelectronic device having three sidewall
electrical contacts and exposed edges.
Figure 4A depicts one embodiment of an optoelectronic device having a bi-layer sidewall
electrical interconnect.
Figure 4B depicts a side sectional view of an optoelectronic device having a bi-layer
sidewall electrical interconnect.
Figure 4C depicts an example circuit schematic of one possible operation of the device
of Figure 4B.
Figure 5A is a flowchart depicting one embodiment of a process of fabricating an optoelectronic
device having one or more sidewall electrical contacts.
Figure 5B is a flowchart depicting one embodiment of a process of fabricating a sidewall
electrical contact.
Figure 5C is a flowchart depicting one embodiment of a process of fabricating a sidewall
electrical contact using angle deposited metal.
Figure 5D is a flowchart depicting one embodiment of a process of fabricating an optoelectronic
device that has at least one bi-layer sidewall electrical interconnect.
Figure 6A and Figure 6B show results after various steps in one embodiment of the
process of Figure 5A.
Figure 6C, Figure 6D, Figure 6E, Figure 6F, Figure 6G, and Figure 6H show results
after various steps in one embodiment of the process of Figure 5B.
Figure 7A, Figure 7B, and Figure 7C depict side section perspective views of the device
of Figures 3A and 3B.
Figure 8A is a flowchart of one embodiment of a process of independently controlling
different photo-active junctions of an optoelectronic device.
Figure 8B is a flowchart of one embodiment of a process of independently controlling
different photo-active junctions of an optoelectronic device.
Figure 8C is a flowchart of one embodiment of a process of independently controlling
different photo-active junctions of an optoelectronic device.
Figure 9 depicts one embodiment of a process of fabricating an optoelectronic device
that has active regions in a nanostructure array that can be independently controlled.
Figure 10A depicts one embodiment of a pixilated nanostructure optoelectronic device.
Figure 10B depicts a side cross sectional perspective view of a portion of the device
of Figure 10A.
Figure 10C depicts one embodiment of a biasing scheme for a pixilated device.
Figure 10D shows one example biasing scheme for photo-detector operation for a pixilated
device such as the example devices depicted in Figures 10A and 10B.
Figure 11 depicts a flowchart of embodiment of a process of operating an optoelectronic
device.
Figure 12A, Figure 12B, and Figure 12C depict one embodiment of a biasing scheme for
LED operation in which different color sub-pixels are operated simultaneously.
Figure 12D shows one possible biasing scheme for selecting two different colors of
sub-pixels in the same nanostructure for photo-detector operation.
Figures 13A, 13B, 13C, 13D, 13E, 13F, 13G, and 13H depict one embodiment of a biasing
scheme in which three different color sub-pixels are operated simultaneously for LED
operation.
Figure 13I depicts one embodiment of a biasing scheme in which three different color
sub-pixels are operated simultaneously for photo-detector operation.
Figure 14 depicts one embodiment of a process of fabricating a pixilated optoelectronic
device.
Figure 15A is a diagram of one embodiment of a pixilated nanostructure optoelectronic
device.
Figure 15B is a side perspective view of the device of Figure 15A.
Figure 16 is a block diagram of one embodiment of a computing system for use with
embodiments of technology disclosed herein.
DETAILED DESCRIPTION
[0013] In the following description, for the purposes of explanation, numerous specific
details are set forth in order to provide a thorough understanding of the present
invention. It will be apparent, however, that embodiments may be practiced without
these specific details. In other instances, well-known structures and devices are
shown in block diagram form in order to avoid unnecessarily obscuring the disclosure.
[0014] According to an aspect of the present invention, there is provided an optoelectronic
device as claimed in claim 1. According to an aspect of the present invention, there
is provided a method for forming an optoelectronic device as claimed in claim 7.
[0015] Optoelectronic devices having photo-active regions ("active regions") are disclosed
herein. The optoelectronic device comprises nanostructures. The nanostructures may
be nanocolumns, nanowires, nanorods, nanotubes, etc. In some embodiments, the nanostructures
are grouped in an array. For example, the nanostructures may be grown vertically on
a substrate. However, the nanostructures could also be formed from the top down by
patterning a stack of planar layers and subsequent etching. The nanostructures may
be formed from a variety of materials. In some embodiments, the nanostructures are
formed from one or more semiconductors.
[0016] Optoelectronic devices described herein may be used for solar photo-conversion devices
(also referred to as solar cells), photo-detectors (also referred to as light detectors),
imaging devices, monochrome LEDs, multi-constituent color LEDs, spectrometers, and
other devices not specifically mentioned.
[0017] The optoelectronic device has a top electrical contact that is physically and electrically
connected to sidewalls of the array of nanostructures (e.g., nanocolumns). The top
electrical contact may be located such that light can enter or leave the nanostructures
without passing through the top electrical contact. Therefore, the top electrical
contact can be opaque to light having wavelengths that are absorbed or generated by
active regions in the nanostructures. Moreover, the top electrical contact can be
made from a material that is highly conductive, as no tradeoff needs to be made between
optical transparency and electrical conductivity.
[0018] In some embodiments, the optoelectronic device has one or more intermediate electrical
contact that are physically and electrically connected to sidewalls of the array of
nanostructures. The contacts may allow different photo-active regions of the optoelectronic
device to be independently controlled. For example, a top and intermediate electrical
contact can be used to control an upper photo-active regions and the intermediate
and bottom electrical contact may be used to control lower photo-active regions. Note
that each nanostructure may have one of the lower- and one of the upper photo-active
regions.
[0019] In some embodiments, the optoelectronic device has a bi-layer electrical interconnect
that is physically and electrically connected to sidewalls of the array of nanostructures.
The optoelectronic device may be operated as a multi-junction solar cell, wherein
each junction is associated with one portion of the device. The bi-layer electrical
interconnect allows current to pass from one portion to the next. Thus, the bi-layer
electrical interconnect may serve as a replacement for a tunnel junction, which is
used in some conventional multi-junction solar cells.
[0020] In some embodiments, the optoelectronic device is a pixilated device that may serve
as an LED display or imaging sensor, for example. The optoelectronic device may have
an array of nanostructures with alternating rows and columns of sidewall electrical
contacts at different layers. In this embodiment, the electrical contacts may be long
strips. This allows a group of one or more nanostructures to serve as a pixel having
sub-pixels. For example, a pixel may be formed at the intersection of a row contact
and a column contact. In some embodiments, a single group of one or more nanostructures
has a blue sub-pixel, a green sub-pixel, and a red sub-pixel. Each pixel may have
any number of sub-pixels.
Nanostructure Array Optoelectronic Device with Top Sidewall Electrical Contact
[0021] Figure 1A depicts one embodiment of an optoelectronic device 100 having a top sidewall
electrical contact 104a. In one embodiment, the optoelectronic device 100 is a solar
cell. In one embodiment, the optoelectronic device 100 is an LED. In one embodiment,
the optoelectronic device 100 is a photo-detector. For example, the device 100 may
be a single junction solar cell. In other embodiments, the device 100 has multiple
junctions. The example device 100, in general, comprises an array of nanostructures
96, a top sidewall electrical contact 104a, a substrate 108, a bottom electrical contact
102, an optional window 105, and electrical leads 112. Note that the top sidewall
electrical contact 104a and the bottom electrical contact 102 may be externally accessible.
[0022] Each of the nanostructures 96 may have one or more photo-active regions (not depicted
in Figure 1A). Each of the nanostructures 96 has a top, a bottom, and sidewalls. In
one embodiment, the lateral width of the nanostructures 96 may range from about 5
nm - 500 nm. However, nanostructures 96 may have a lesser or greater lateral width.
The entire range of widths may be present in a single device. Thus, there may be considerable
variance in width of individual nanostructures 96. Also note that the width of an
individual nanostructures 96 may vary from top to bottom. For example, a nanostructure
96 could be narrower, or wider, at the top. Also note that nanostructures 96 are not
necessarily columnar in shape. As depicted, there are spaces or gaps between the nanostructures
96. These spaces may be filled with an insulator; however, the spaces may also be
left open such that there may be an air gap between nanostructures 96. The nanostructures
96 are not coalesced, in some embodiments. That is to say, that individual nanostructures
96 are not required to be joined together laterally at some level. For example, in
some conventional devices the nanostructures 96 are coalesced at the tops such that
a continuous sheet is formed. Note that although each nanostructure 96 is depicted
in Figure 1A as completely separate from others, some of the nanostructures 96 might
touch a neighbor at some point on the sidewalls.
[0023] The nanostructures 96 may include one or more segments. A given segment may be p-doped,
n-doped, co-doped, or intrinsic (not intentionally doped) for various purposes including,
but not limited to, creating photo-active junctions. A segment may be heavily doped
to create a tunnel junction. Different segments may be formed from different materials.
For example, different segments may be formed from different materials such that different
photo-active junctions emit or detect light different wavelengths of light. As another
example, the nanostructures 96 may be formed from a material that comprises a III
- V compound semiconductor and an element that alters the band gap of the III - V
compound semiconductor, such an indium. Different segments may have different amounts
of indium in order to create energy wells. Further details of solar cells having nanostructures
96 with energy wells are described in
U.S. Patent 7,629,532, filed on December 29, 2006, titled "Solar Cells having Active Region with Nanostructures having Energy Wells".
[0024] The top sidewall electrical contact 104a is in electrical and physical contact with
the sidewalls near the tops of the nanostructures 96. However, the top sidewall electrical
contact 104a leaves a top portion 96a of the nanostructures 96 exposed to allow light
to enter or leave the nanostructures 96 from the tops 96a without passing through
the top electrical contact 104a. Therefore, the top electrical contact 104a may be
substantially opaque to light having a wavelength that is absorbed or generated by
the photo-active regions. The top sidewall electrical contact 104a has a substantially
planar structure in some embodiments. However, note that the thickness of the top
sidewall electrical contact 104a is allowed to vary. Note that the top sidewall electrical
contact 104a may be formed substantially around the sidewalls of each of the nanostructures
96. The top electrical contact 104a may completely fill the spaces between the nanostructures
96 at a level near the tops 96a of the nanostructures 96.
[0025] The top electrical contact 104a may be formed from a different material than the
nanostructures 96. In some embodiments, the top sidewall electrical contact 104a is
formed from a metal. Example metals include, but are not limited to, nickel and aluminum.
Therefore, the top sidewall electrical contact 104a may have a very high conductivity.
For example, the top electrical contact 104a may have a higher electrical conductivity
than the nanostructures 96; although this is not required. In some embodiments, the
top electrical contact 104a forms an Ohmic contact with the nanostructures 96. Therefore,
a good electrical connection may be made to the nanostructures 96. In some embodiments,
the top electrical contact 104a forms a Schottky contact with the nanostructures 96.
[0026] The optional window 105 allows light to enter or leave the device 100. The window
105 protects the device 100 and may passivate the top surface. The window 105 may
be formed from a material that is highly transparent to light of the relevant wavelengths.
Because the window 105 does not need to pass an electrical current, the window 105
does not need to be electrically conductive. Therefore, no tradeoff between optical
transparency and electrical conductivity needs to be made for the window 105. Note
that another material, such as an insulator, may be present between the window 105
and the top electrical contact 104a.
[0027] Examples of suitable materials for the substrate 108 include, but are not limited
to, Si, germanium (Ge), silicon carbide (SiC), zinc oxide (ZnO), and sapphire. If
the substrate 108 is either Si, or Ge, the substrate 108 may be (111) plane oriented,
as one example. If the substrate 108 is SiC, or ZnO, the substrate 108 may be (0001)
plane oriented, as one example. The substrate 108 is doped with a p-type dopant, in
one embodiment. An example of a p-type dopant for Si substrates includes, but is not
limited to, boron (B). The p-type doping level may be p, p
+ or, p
++. The substrate 108 is doped with an n-type dopant, in one embodiment. Examples of
n-type dopants for Si substrates include, but are not limited to, arsenic (As) and
phosphorous (P). The n-type doping level may be n, n
+ or, n
++. Note that the substrate 108 is not required for device operation. In some embodiments,
the substrate 108 on which the nanostructures 96 were grown is removed (e.g., by etching),
which allows for a more flexible device.
[0028] The bottom electrical contact 102 may be made of a suitable metal, and does not need
to be optically transparent. The bottom electrical contact 102 is electrically connected
to the nanostructures 96. In some embodiments, the bottom electrical contact 102 is
in physical contact with the sidewalls of the nanostructures 96; however, sidewall
contact is not required. Thus, the bottom electrical contact 102 may, or may not be,
a sidewall electrical contact. As depicted in Figure 1A, the bottom electrical contact
102 is attached to the back side (or bottom) of the substrate 108. As mentioned, the
substrate 108 may be doped such that it is conductive. If desired, portions of the
substrate 108 may be etched away and filled with a conductive material, such as a
metal, to allow a better conductive contact between the bottom electrical contact
102 and the nanostructures 96. As mentioned, the substrate 108 is not an absolute
requirement. In this case, the bottom electrical contact 102 may be bonded to the
nanostructures 96. In one embodiment, the bottom electrical contact 102 is between
the substrate 108 and the nanostructures 96 (but is not a sidewall contact).
[0029] Overview of operation of an arrangement that is outside the scope of the claims in
which the device 100 is a solar cell will now be discussed. Solar radiation (e.g.,
photons) enters through the window 105 and into the top portions 96a of nanostructures
96 and may be absorbed in the active regions (not explicitly depicted in Figure 1A)
of nanostructures 96. Absorption of a photon promotes an electron to the conduction
band. Electrons promoted to a conduction band by the absorption of photons may conduct
to the electrical contacts 104a, 102. The electrons conduct through the electrical
leads 112. Typically, a bias voltage is not applied to the device 100 when being operated
as a solar cell.
[0030] Overview of operation of an embodiment in which the device 100 is an LED will now
be discussed. A bias voltage is applied through the leads 112 to forward bias a p-n
junction (not depicted in Figure 1A) in the nanostructures 96, resulting in emission
of photons through the top portions 96a of the nanostructures 96 and out the window
105 (note that the window 105 is optional). Note that the emitted photons need not
pass through the top sidewall electrical contact 104a.
[0031] Overview of operation of an embodiment in which the device 100 is a photo-detector
or imaging device will now be discussed. A bias voltage may be applied through the
leads 112 to reverse bias a p-n junction (not depicted in Figure 1A) in the nanostructures
96. Photons that enter through the window 105 (if present) are absorbed in the photo-active
regions of the nanostructures 96, which promotes electrons to the conduction band.
Electrons promoted to the conduction band may conduct to the contacts 104a, 102 and
through the electrical leads 1 12. The amount of current that conducts may be detected
to determine the intensity of light at the relevant wavelength of the photo-active
junctions.
[0032] Thus, electrical conduction may occur along the length of nanostructures 96 for the
various optoelectronic devices. For example, electrical conduction may occur along
the length of nanocolumns. Note that the device 100 may be used for other devices
than the examples provided.
[0033] Note that a portion of the sidewalls of the nanostructures 96 is not required to
be above the top sidewall electrical contact 104a. Figure IB depicts one embodiment
of an optoelectronic device 110 having a top sidewall electrical contact 104a. In
this embodiment, no portion of the sidewalls of the nanostructures 96 is above the
top sidewall electrical contact 104a. However, top portions 96a of the nanostructures
96 are exposed to allow light to enter or leave the nanostructures 96a from the tops
96a without passing through the top electrical contact 104a. Note that the top sidewall
electrical contact 104a may completely fill the spaces between the nanostructures
96 at a level near the tops 96a of the nanostructures.
[0034] Figure 2A depicts a side cross sectional showing one embodiment of how the top sidewall
electrical contact 104a is in physical contact with the sidewalls of the nanostructures
96. In this embodiment, the device 100 has a p-n junction and active region associated
therewith. The top sidewall electrical contact 104a is electrically and physically
connected to the p-type regions of the nanostructures 96. However, note that the top
electrical contact 104a may instead be in contact with a p-doped region, n-doped region,
intrinsic region, or co-doped region. In some embodiments, the material for the top
sidewall electrical contact 104a is selected such that it makes a good Ohmic contact
with the type of material (e.g., semiconductor and type of doping) of the nanostructures
96 that it contacts. However, other contacts such as a Schottky contact are also possible.
[0035] The bottom electrical contact 102 is electrically connected to the n-type regions
of the nanostructures 96. The bottom electrical contact 102 may be in physical contact
with the sidewalls of the nanostructures 96; however, that is not required. In another
embodiment, the n-type and p-type regions are switched, such that the top sidewall
electrical contact 104a is electrically and physically connected to an n-type region.
In some embodiments, there is an intrinsic region between the p-type region and n-type
region. In some embodiments, each of the nanostructures 96 has a photo-active region
associated with the p-n junction. The extent of one example photo-active region is
depicted; however, it will be appreciated that the extent of the photo-active region
does not necessarily have fixed boundaries.
[0036] Also, note that in some embodiments, a portion of the photo-active region may extend
above the top sidewall electrical contact 104a. Figure 2B depicts such an embodiment.
In some embodiments, the top surface of the top electrical contact 104a is at least
partially reflective to light of relevant wavelengths such that incoming light that
is not directly received by one of the nanostructures 96 is reflected off from the
top electrical contact 104a and into the sidewalls of the nanostructures 96 above
the top electrical contact 104a. Therefore, this reflected light may be absorbed by
the photo-active region above the top electrical contact 104a.
[0037] Note that the tops 96a of the nanostructures do not necessarily have a flat surface
at the very top. For example, one or more of the nanostructures 96 may have a point
or rounded top. Figure 2C is a side sectional perspective view of one embodiment of
an optoelectronic device 100 in which the tops 96a are not flat. In this example,
the tops 96a are somewhat pointed. The tops 96a may have other shapes. The tops 96a
extend above the top electrical contact 104a such that light may enter or leave the
nanostructures 96 through the tops 96a without passing through the top electrical
contact 104a.
[0038] In the embodiment of Figure 2C, the device 250 has a p-n junction. The device may
have a p-i-n junction instead. The top sidewall electrical contact 104a is electrically
and physically connected to the p-type regions of the nanostructures 96 in this example.
However, note that the top electrical contact may instead be in contact with a p-doped
region, n-doped region, intrinsic region, or co-doped region. In some embodiments,
the material for the top contact 104a is selected such that it makes a good Ohmic
contact with the type of material (e.g., semiconductor and type of doping) of the
nanostructures 96 that it contacts. However, other contacts such as a Schottky contact
are also possible.
[0039] Note that in the devices of Figures 2A, 2B and 2C the top sidewall electrical contact
104a and the bottom electrical contact 102 may be externally accessible by attaching
electrical leads 112 to the contacts.
Nanostructure Array Optoelectronic Device with Intermediate Sidewall Electrical Contacts
[0040] Note that the optoelectronic device may have one or more intermediate sidewall electrical
contacts. By an intermediate sidewall electrical contacts it is meant an electrical
contact that is neither a top electrical contact nor a bottom electrical contact and
is physically touching sidewalls of the nanostructures 96. Therefore, the device has
more than two electrical contacts in these embodiments. For example, the device may
have three, four, or more electrical contacts.
[0041] Figure 3A depicts one embodiment of an optoelectronic device 300 having three sidewall
electrical contacts 104a, 104b, 104c. Specifically, the device 300 has a top sidewall
electrical contact 104a, an intermediate sidewall electrical contact 104c, and a bottom
sidewall electrical contact 104b, in this embodiment. Note that each contact may have
an electrical lead 112 attached to it such that a voltage or current may be provided
or received.
[0042] Note that the bottom electrical contact is not required to be on the sidewalls. For
example, it could be below the substrate 108 or attached to the bottoms of the nanostructures
96. Moreover, the top electrical contact is not required to be on the sidewalls. For
example, it could be attached to the tops of the nanostructures 96. Other elements
of the device 300 (such as leads, insulation, front window) are not depicted so to
not obscure the diagram.
[0043] Figure 3B depicts a side perspective cross-sectional view of one embodiment of an
optoelectronic device 300 having an intermediate sidewall electrical contact 104c.
The device is similar to the one depicted in Figure 3A and also has a top sidewall
electrical contact 104a and a bottom sidewall electrical contact 104b. Electrical
leads 112 are not explicitly depicted, but may be attached to each electrical contact.
Figure 3B depicts an example in which each of the nanostructures 96 has, from top
to bottom, an n-type region 302, a p-type region 304 and an n-type region 306. Therefore,
the device has first and second photo-active regions (which are roughly depicted)
associated with the two p-n junctions. Note that there could be intrinsic regions
between the n-type regions and p-type regions.
[0044] Each photo-active region may have different bandgap energy. Therefore, each photo-active
region may emit or detect light of a different range of wavelengths. Alternatively,
the device could have a p-type region, an n-type region, and a p-type region. Thus,
in general, the nanostructures 96 each have an upper and lower region having one type
of conductivity and a middle region having the opposite type of conductivity.
[0045] In this example, the top sidewall electrical contact 104a makes electrical and physical
contact with upper n-type semiconductor regions of the nanostructures 96, the intermediate
sidewall electrical contact 104c makes electrical and physical contact with p-type
semiconductor regions of the nanostructures 96, and the bottom sidewall electrical
contact 104b makes electrical and physical contact with lower n-type semiconductor
regions of the nanostructures 96.
[0046] In some embodiments, the sidewall contacts 104a-104c each make Ohmic contact with
their region. Thus, sidewall contacts 104 that contact the n-type semiconductor regions
may be made of a suitable material to form an Ohmic contact with an n-type semiconductor.
Sidewall contacts 104 that contact the p-type semiconductor regions may be made of
a suitable material to form an Ohmic contact with a p-type semiconductor. Herein,
the term "n-type" contact will refer to a material that forms an Ohmic contact with
an n-type semiconductor. Herein, the term "p-type" contact will refer to a material
that forms an Ohmic contact with a p-type semiconductor.
[0047] Figure 3C depicts one embodiment of an optoelectronic device 300 having three sidewall
electrical contacts and exposed edges. The device 300 is similar to the ones depicted
in Figures 3A and 3B. Two layers of insulation 325 are depicted between the contacts.
Figure 3C only depicts a small portion of the device 300 near one edge. The device
300 has a contact pad 1032 attached to each electrical contact 104 and an electrical
lead 112 attached to each electrical contact 104. Control logic 725 connects to the
leads 112. The control logic 725 may be used to independently control different photo-active
regions in the nanostructures 96. Further details are discussed below. The edges can
be exposed using a wide variety of techniques such as photolithography and etching.
Bi-Layer Nanostructure Sidewall Electrical Interconnect
[0048] In some embodiments, the optoelectronic device has a bi-layer sidewall electrical
interconnect. A bi-layer sidewall electrical interconnect may include an n-type contact
and a p-type contact. Therefore, the bi-layer sidewall electrical interconnect may
make contact to both n-type semiconductor regions and p-type semiconductor regions
of the nanostructures 96.
[0049] Figure 4A depicts one embodiment of an optoelectronic device 400 having a bi-layer
sidewall electrical interconnect 104d. The optoelectronic device 400 also has a top
sidewall electrical contact 104a and a bottom sidewall electrical contact 104b. However,
top and bottom electrical contacts are not required to be on the sidewalls of the
nanostructures 96. The bi-layer sidewall electrical interconnect 104d includes a top
layer 404a and a bottom layer 404b. As mentioned, one layer is an n-type contact,
and the other is a p-type contact. Either layer may be n-type contact, depending on
the doping of the nanostructures 96.
[0050] In some embodiments, the optoelectronic device 400 of Figure 4A is a multi-junction
solar cell. The device 100 may have a first lead 112 electrically connected to the
top sidewall electrical contact 104a and a second lead 112 electrically connected
to the bottom sidewall electrical contact 104b. However, as will be explained below,
the device 100 does not necessarily have electrical leads 112 connected to the bi-layer
sidewall electrical interconnect 104d.
[0051] Figure 4B depicts a side sectional perspective view of an optoelectronic device 400
having a bi-layer sidewall electrical interconnect 104d. The device is similar to
the one of Figure 4A. Note that in this example the nanostructures 96 have p-type
regions 452, n-type regions 454, p-type regions 456, and n-type regions 458. In this
example, the top layer 404a of bi-layer sidewall electrical interconnect 104d contacts
n-type regions 454 and the bottom layer 404b of bi-layer sidewall electrical interconnect
104d contacts p-type regions 456. In one embodiment, the layer 404a makes Ohmic contact
with the n-type regions. For example, layer 404a may be aluminum and the nanostructures
96 may be nitride semiconductors. In one embodiment, layer 404b makes Ohmic contact
with the p-type regions. For example, layer 404b may be nickel and the nanostructures
96 may be nitride semiconductors. The top sidewall electrical contact 104a contacts
the top p-type regions 452 and the bottom sidewall electrical contact 104b contacts
the lower n-type regions 458. Note that the p-type and n-type regions could be reversed.
[0052] Also note that the junction between the top layer 404a and bottom layer 104b does
not need to be perfectly aligned with the p-n junction of regions 454 and 456. A reason
for this is that, in some embodiments, a given layer of the bi-layer interconnect
104d only makes Ohmic contact with semiconductor of the correct conductivity type.
For example, top layer 404a may be in physical contact with part of p-type region
456 (as well as n-type region 454). In this case, top layer 404a will still have Ohmic
contact with the n-type region 454 and the bottom layer 404b will still have Ohmic
contact with the p-type region 456. However, the top layer 404a should not have Ohmic
contact with the p-type region 456 even if there is some physical contact. Similarly,
bottom layer 404b may be in physical contact with part of n-type region 454 (as well
as p-type region 456). In this case, bottom layer 404b will still have Ohmic contact
with the p-type region 454 and the top layer 404a will still have Ohmic contact with
the n-type region 454. However, the bottom layer 404b should not have Ohmic contact
with the n-type region 454 even if there is some physical contact.
[0053] As mentioned, the optoelectronic device 400 of Figures 4A and 4B may be a multi-junction
solar cell. The p-n junction between p-type regions 452 and n-type regions 454 may
operate as a first p-n junction, whereas the p-n junction between p-type regions 456
and n-type regions 458 may operate as a second p-n junction. Note that p-i-n junctions
are also possible. The bi-layer sidewall electrical interconnect 104d may allow charge
to flow between the n-type regions 454 and the p-type regions 456 through the bi-layer
electrical interconnect. Each p-n junction may have different bandgap energy. Therefore,
the active region associated with each p-n junction may emit or detect light of a
different range of wavelengths.
[0054] Figure 4C depicts an example circuit schematic of one possible operation of the device
400 of Figures 4B. The optoelectronic device 400 may be considered to be two diodes
462a, 462b that are connected by the bi-layer sidewall electrical interconnect 104d.
Current that is generated by absorption of photons may flow from the upper diode 462a
to the upper portion 404a of the bi-layer interconnect 104d, then to the lower portion
404b of the bi-layer interconnect 104d. Then, the current flows through the lower
diode 462b and into the lower lead 112. The upper lead 112a completes the circuit.
Note that some multi-junction solar cell have a tunnel junction between diodes. However,
tunnel junctions are sometimes difficult to form. The bi-layer 104d sidewall electrical
interconnect may thus serve as a replacement for a tunnel junction.
Fabricating a Nanostructure Array Optoelectronic Device Having one or more Sidewall
Electrical Contacts
[0055] Figure 5A is a flowchart depicting one embodiment of a process 500 of fabricating
an optoelectronic device that has one or more sidewall electrical contacts. Process
500 may be used to fabricate a device such as those depicted in Figures 1A, 1B, 2A,
2B, 2C, 3A, 3B, 4A, and 4B. However, process 500 is not limited to fabricating those
devices. Not all process steps are depicted so as to simplify the explanation. Figures
6A-6B show results after various steps in one embodiment of process 500. Figures 6A-6B
show a side perspective view showing a cutaway portion of a few nanostructures 96.
[0056] In step 502, nanostructures 96 are formed. In one embodiment, an array of nanostructures
96 are grown vertically on a substrate 108. The nanostructures 96 may be grown either
by self-assembly or by patterned growth using epitaxial growth techniques such as
metalorganic chemical vapor deposition, molecular beam epitaxy and hydride vapor phase
epitaxy. In patterned growth, a portion of the substrate surface which is not covered
by mask material such as SiO
2, SiN
x, or metal is exposed to serve as nucleation sites for the nanostructures 96. The
nanostructures 96 may also be grown using nanoparticles such as gold (Au) and nickel
(Ni), which may act as nucleation sites for the nanostructures 96.
[0057] In some embodiments the nanostructures 96 are formed by patterning and etching. For
example, one or more planar layers of material for the nanostructures 96 is deposited.
Each layer may be doped appropriately in situ or by implantation. After depositing
and doping all layers, photolithography may be used to pattern and etch in order to
form the nanostructures 96.
[0058] In some embodiments, the nanostructures 96 are doped with one or more impurities
to create one or more p-type semiconductor regions and one or more n-type semiconductor
regions. Intrinsic regions may also be formed. Note that the substrate 108 may be
doped prior to forming the nanostructures 96. Figure 6A depicts results after step
502. Specifically, a few nanostructures 96 out of an array of nanostructures 96 are
depicted over a substrate 108.
[0059] In step 504, a bottom electrical contact (102, 104b) is formed. In one embodiment,
the bottom electrical contact surrounds the sidewalls of the nanostructures 96. In
such embodiments, the bottom electrical contact 104b may be formed by depositing a
material over the substrate 108 (after the nanostructures 96 have been formed) and
etching back the material. The material may be metal. In patterned growth employing
conductive material (such as metal) as mask material, the mask layer may serve as
a bottom sidewall electrical contact 104b. However, it is not required that the bottom
electrical contact is a sidewall electrical contact. Figure 6B depicts results after
step 504 for an embodiment in which the bottom electrical contact is a sidewall contact
104b. For some embodiments, the bottom electrical contact may be added below the substrate
108 later.
[0060] In step 505, one or more intermediate sidewall electrical contacts 104c are formed.
In step 506, a top sidewall electrical contact 104a is formed. Further details of
steps 505 and 506 are discussed below. Note that for some devices both steps 505 and
506 are performed. For other devices, only one of steps 505 and 506 is performed.
[0061] Figure 5B is a flowchart depicting one embodiment of a process 520 of fabricating
a sidewall electrical contact for an optical device that has one or more sidewall
electrical contacts. Process 520 is one embodiment of step 506 of Figure 5A. Process
520 may also be used for step 505 of Figure 5A. Figures 6C-6H show results after various
steps in one embodiment of the process of Figure 5B. Figures 6C-6H show a side perspective
view showing a cutaway portion of a few nanostructures 96 and continue from the processing
depicted in Figures 6A-6B. However, note that it is not that the bottom electrical
contact be a sidewall electrical contact as depicted in the Figures 6B-6H.
[0062] In step 507, an insulator is formed around the sidewalls of the nanostructures 96
above the substrate 108 (and above the bottom sidewall electrical contact 104b, if
formed). In one embodiment, spin-on-glass (SOG) is applied. In one embodiments, silicon
dioxide is sputtered. In another embodiment, photoresist is added. Note that more
than one type of material could be used. For example, layers of different materials
could be deposited or a single layer could include multiple materials. After depositing,
the insulator is etched back to expose tops 96a of the nanostructures 96. Note that
the insulator may serve purposes such as passivating the nanostructures 96, or modifying
the electrical or optical properties of the nanostructures 96. Figure 6C depicts results
after step 507 showing the insulator 602 surrounding the nanostructure sidewalls.
[0063] In step 508, metal is deposited over the insulator 602 such that it surrounds the
nanostructure sidewalls. At this stage, portions of the metal might cover the tops
of the nanostructure. Figure 6D depicts results after step 508 in which metal 604
forms a conformal layer around and over the tops of the nanostructures 96.
[0064] In step 510, a layer of photoresist, SOG, or other planarizing material is formed
over the metal 604 and planarized. Figure 6E depicts results after step 510 showing
planarizing material 606 over the metal 604.
[0065] In step 512, the planarizing material 606 is etched back to reveal tops of nanostructures
96 covered with the metal 604. Figure 6F depicts results after step 512 showing that
the planarizing material 606 has been etched back to reveal portions of the metal
604 over the tops of the nanostructures 96. However, some of the planarizing material
606 remains in regions between the nanostructures 96.
[0066] In step 514, the metal 604 is etched back with the remaining protective planarizing
material 606 in place in order to reveal tops of nanostructures 96. In step 516, the
planarizing material 606 is removed. Figure 6G depicts results after step 516. Figure
6G shows that the tops of the nanostructures 96 are exposed.
[0067] In step 518, the metal 604 is etched back to a position that leaves tops of the nanostructures
96 exposed. Figure 6H depicts results after step 518 showing the top sidewall electrical
contact 104a.
[0068] Note that steps similar to steps 507-518 may be performed to form metal contacts
at other levels. For example, steps similar to steps 507-518 may be used for form
an intermediate sidewall electrical contact. Thus, the process 520 may also be used
for step 505 of Figure 5A. Note that more than one intermediate sidewall electrical
104c contact may be formed.
[0069] Figure 5C is a flowchart depicting one embodiment of a process 550 of fabricating
a sidewall electrical contact for an optoelectronic device 100 that has one or more
sidewall electrical contacts. Process 550 is one embodiment of step 506 of Figure
5A. Not all process steps are depicted so as to simplify the explanation. In this
embodiment, an insulating layer is not formed around the nanostructures 96. However,
an insulating layer may be formed, if desired.
[0070] In step 552, metal is angle deposited such that it surrounds the nanostructure sidewalls
at the tops. The metal should coalesce such that a continuous region of metal is formed
at the tops of the nanostructure array. Note that the device may be rotated during
the angle deposition in order to coat all sidewalls of the nanostructures at the top
with metal. The angle of deposition may be selected in order to control the depth
of the metal (e.g., how far down the sidewalls of the nanostructures that the metal
extends).
[0071] Next steps 510-518 may be performed in order to etch the metal. Steps 510-518 may
be similar to steps 510-518 of Figure 5B and will not be discussed in detail.
[0072] Figure 5D is a flowchart depicting one embodiment of a process 580 of fabricating
an optoelectronic device that has at least one bi-layer electrical interconnect. Process
580 may be used to fabricate a device such as those depicted in Figures 4A and 4B.
However, process 580 is not limited to fabricating those devices. Not all process
steps are depicted so as to simplify the explanation. In step 582, nanostructures
96 are formed. Step 582 is similar to step 502 of Figure 5A. The nanostructures may
have first regions of a first conductivity type and second regions of a second conductivity
type to form first p-n junctions. The nanostructures may have third regions of the
first conductivity type and fourth regions of the second conductivity type to form
second p-n junctions.
[0073] In step 584, a bottom electrical contact (102, 104b) is formed. Forming bottom contacts
has been discussed in connection with Figure 5A
[0074] In step 586, one or more bi-layer sidewall electrical interconnects 104d are formed.
The bi-layer sidewall electrical interconnect 104d may have a first material in electrical
and physical contact with the second regions and a second material in electrical and
physical contact with the third regions. The first material and the second material
may be in electrical contact with each other to allow charge to flow between the second
regions and the third regions through the bi-layer electrical interconnect.
[0075] Forming the lower portion 404b of the bi-layer interconnect 104d may be similar to
forming an intermediate sidewall contact, which has already been discussed. After
forming the lower portion 404b, metal may be deposited for the upper portion 404a
and etched back. In some embodiments, forming the upper portion 404a is similar to
the process for forming an intermediate sidewall contact.
[0076] In step 588, a top sidewall electrical contact 104a is formed, which has already
been discussed. Note that the top contact is not required to be a sidewall contact.
Independently Controlling Different Photo-active Junctions
[0077] In some embodiments, different photo-active junctions of the optoelectronic device
are controlled independently. In some embodiments a device 300 such as the embodiment
depicted in Figures 3A and 3B has its junctions independently controlled. Figures
7A, 7B, and 7C depict a side sectional perspective view of a portion of the device
of Figures 3A and 3B with control logic 725 that independently controls different
photo-active junctions. The device 300 has a first photo-active junction 703 formed
by n-type semiconductor region 302 and p-type semiconductor region 304. The device
300 has a second photo-active junction 705 formed by p-type semiconductor region 304
and n-type semiconductor region 306. Note that only one nanostructure 96 has been
shown. However, typically there is an array of nanostructures 96.
[0078] In some embodiments, the device is an LED. Each photo-active junction may be able
to output light of a different range of wavelengths. For example, the first photo-active
junction 703 may output blue light and the second photo-active junction 705 may output
green light. In some embodiments, there are three or more photo-active junctions.
Therefore, the device may output three or more different colors.
[0079] Figure 7A shows the control logic 725 activating the first photo-active junction
703 and de-activating the second photo-active junction 705. Figure 7B shows the control
logic 725 activating the second photo-active junction 705 and de-activating the first
photo-active junction 703. Figure 7C shows the logic 725 controlling (e.g., activating/de-activating)
the photo-active junctions 703, 705 independently. Thus, the device 300 might output
blue light when the first photo-active junction 703 is active and red light when the
second photo-active junction 705 is active.
[0080] The control logic 725 may be implemented with hardware, software, or some combination
of hardware and software. The software used may be stored on one or more processor
readable storage devices including hard disk drives, CD-ROMs, DVDs, optical disks,
floppy disks, tape drives, RAM, ROM, flash memory, or other suitable storage devices.
The software can be used to program one or more processors to perform the functions
of the control logic 725 described herein. In alternative embodiments, some or all
of the control logic 725 can be implemented by dedicated hardware including custom
integrated circuits, gate arrays, FPGAs, PLDs, and special purpose computers.
[0081] Figure 8A is a flowchart of one embodiment of a process 800 of independently controlling
different photo-active junctions of an optoelectronic device. Process 800 may be performed
by the control logic 725. In step 802, the control logic 725 controls first photo-active
junctions 703 to generate or detect light having a first range of wavelengths. Note
that each nanostructure 96 may have its own photo-active junctions. Therefore, process
800 will refer to controlling photo-active "junctions" of different nanostructures
96. For example, the control logic 725 causes the first photo-active junctions 703
of different nanostructures 96 to output blue light. Alternatively, the control logic
725 causes the first photo-active junctions 703 of different nanostructures to detect
blue light. In step 804, the control logic 725 independently controls second photo-active
junctions 705 to generate or detect light having a second range of wavelengths. For
example, the control logic 725 causes the second photo-active junctions 703 of different
nanostructures 96 to output red light (or some other color). Alternatively, the control
logic 725 causes the second photo-active junctions 705 of different nanostructures
to detect red light.
[0082] Figure 8B is a flowchart of one embodiment of a process 815 of independently controlling
different photo-active junctions of an optoelectronic device. Figures 7A-7B will be
referred to when discussing process 815. Process 815 provides more details of one
embodiment of process 800. In step 820, the control logic 725 applies voltages to
second and third electrical contacts (e.g., contacts 104c, 104b) in order to de-activate
the second photo-active junctions 705. For example, the same magnitude voltage is
applied to each contact 104b, 104c. Such as strategy may de-activate a photo-active
junction for an LED. The junction might also be reverse biased to de-activate for
LED operation. Note that junctions of photo-detectors may be de-activated by breaking
a circuit in which the diode junction resides. Therefore, one way of activating/de-activating
photo-detector junctions is to reverse bias for activation and open the circuit for
de-activation.
[0083] In step 822, the control logic 725 applies voltages to first and second electrical
contacts to activate the first photo-active junctions 703. For example, the control
logic 725 applies a positive voltage to top sidewall electrical contact 104c while
grounding intermediate sidewall electrical contact 104a in order to forward bias the
first photo-active junctions 703 if the device of Figure 7A is being used as an LED.
If the device of Figure 7A is being used as a photo-detector (or imaging device),
the voltages may be reversed in order to reverse bias the first photo-active junctions
703. Note that detection of light may not require that the diode junction be biased.
However, the previously mentioned circuit should be closed such that current generated
by the photo-active junction may be detected. If the n-type regions 302 and p-type
regions 304 are switched the voltages applied to the contacts 104a, 104c may be reversed
for each case in order to activate the first junctions 703. If the n-type regions
302 and p-type regions 304 are switched the voltages applied to the contacts 104a,
104c may be reversed for each case in order to activate the first junctions 703.
[0084] Step 822 may be performed concurrently with step 820. As one example, the control
logic 725 applies the same voltage to the bottom sidewall electrical contact 104b
as is applied to the intermediate sidewall electrical contact 104c. Therefore, no
net voltage exists across the second photo-active junctions 705. However, a different
voltage might be applied to the bottom electrical contact 104b in order to de-activate
it. For example, for an LED the junction might be reversed biased to de-activate it.
Alternatively, for an LED, the junction might be biased with small voltage that is
not sufficient to generate much, if any, light. Together, steps 820 and 822 are one
embodiment of step 802 of process 800.
[0085] In step 824, the control logic 725 applies voltages to the first electrical contact
(e.g., contact 104a) and the second electrical contact (e.g., contact 104b) in order
to de-activate the first photo-active junctions 703. For example, the same magnitude
voltage is applied to each contact 104a, 104b. Such as strategy may de-activate a
photo-active junction for an LED. The junction might also be reverse biased to de-activate
for LED operation. Note that junctions of photo-detectors may be de-activated by breaking
a circuit in which the diode junction resides. Therefore, one way of activating/de-activating
photo-detector junctions is to reverse bias for activation and open the circuit for
de-activation.
[0086] In step 826, the control logic 725 applies voltages to the second and third electrical
contacts to activate the second photo-active junctions 705. For example, the control
logic 725 applies a positive voltage to intermediate sidewall electrical contact 104c,
while grounding the bottom sidewall electrical contact 104b in order to forward bias
the second photo-active junctions 705 if the device of Figure 7B is being used as
an LED. If the device of Figure 7B is being used as a photo-detector, the voltages
may be reversed in order to reverse bias the second photo-active junctions 705. As
mentioned, detection of light may not require that the diode junction be biased, but
the circuit should be closed. If the n-type regions 306 and p-type regions 304 are
switched, then the voltages applied to the contacts 104b, 104c may be reversed for
each case in order to activate the second junctions 705. If the n-type regions 306
and p-type regions 304 are switched, then the voltages applied to the contacts 104b,
104c may be reversed for each case in order to activate the second junctions 705.
[0087] Step 826 may be performed concurrently with step 824. As one example, the control
logic 725 applies the same voltage to the top sidewall electrical contact 104a as
is applied to the intermediate sidewall electrical contact 104c. Therefore, no net
voltage exists across the first photo-active junctions 703. However, a different voltage
might be applied to the top electrical contact 104a in order to de-activate the first
photo-active junctions 703. Together, steps 824 and 826 are one embodiment of step
804 of process 800.
[0088] In one embodiment, independently controlling the photo-active junctions includes
activating the junctions 703, 705 for different percentages of time. Each junction
703, 705 may or may not be active at the same time. Figure 8C is a flowchart of one
embodiment of a process 840 of independently controlling different photo-active junctions
of an optoelectronic device. Figure 7C will be referred to when discussing process
840. Process 840 provides more details of one embodiment of process 800.
[0089] In step 842, the control logic 725 applies some voltage to the intermediate electrical
contact 104b. As an example, a voltage that is sufficient to forward bias the junctions
is applied, assuming the other contacts are grounded.
[0090] In step 844, the control logic 725 controls the voltage to the top electrical contact
104a in order to activate the first photo-active junctions 703 for some percentage
of time. For example, the control logic 725 grounds top electrical contact 104a in
order to forward bias the first photo-active junctions 703 (assuming the device is
being used as an LED). The control logic 725 may de-activate the first photo-active
junctions 703 by applying Vbias to the top electrical contact 104a such that there
is no voltage across. Thus, by controlling the voltage to the top electrical contact
104a the percentage of time that the first photo-active junctions 703 are active can
be controlled. Note that other suitable voltages may be used if the device is being
used as a photo-detector or if the p-type and n-type regions are switched. Together,
steps 842 and 844 are one embodiment of step 802 of process 800.
[0091] In step 846, the control logic 725 controls the voltage to the bottom electrical
contact 104b in order to activate the second photo-active junctions 705 for some percentage
of time. For example, the control logic 725 grounds bottom electrical contact 104b
in order to forward bias the second photo-active junctions 705 (assuming the device
is being used as an LED). The control logic 725 may de-activate the second photo-active
junctions 705 by applying Vbias to the bottom electrical contact 104b such that there
is no voltage across. Together, steps 842 and 846 are one embodiment of step 802 of
process 800.
[0092] Note that the control logic 725 is able to control each junction 703, 705 by selecting
the amount of time that each junction is active. For example, the control logic 725
could activate the first photo-active junctions 703 for 50 percent of the time and
the second photo-active junctions 705 for 100 percent of the time. If the device is
being used as an LED, this may result in a brighter light intensity of the light that
is generated by the second photo-active junctions 705 than the light that is generated
by the first photo-active junctions 703.
[0093] Another option for independently controlling the junctions 703, 705 is to vary the
magnitude of the voltages across the junctions 703, 705. For example, a large voltage
may be applied to the first photo-active junctions 703 to heavily forward bias the
first junctions 703. On the other hand a relatively small voltage may be applied to
the second photo-active junctions 705 to weakly forward bias the second junctions
705. The control logic 725 may accomplish this by selecting the magnitude of the voltage
applied to the top 104a and bottom 104b contacts, respectively.
[0094] Figure 9 depicts one embodiment of a process 900 of fabricating an optoelectronic
device. Process 900 may be used to form a device such as devices depicted in Figures
3A, 3B, 7A, 7B, and 7C. In step 902, nanostructures are formed. Step 902 may be similar
to step 502 of process 500 and will not be discussed in detail. In step 904, a bottom
electrical contact 104b is formed. Step 904 may be similar to step 504 of process
500 and will not be discussed in detail. In one embodiment, the bottom electrical
contact is not a sidewall electrical contact. For example, the bottom electrical contact
could be located below the substrate or between the substrate and the nanostructures
96.
[0095] In step 906, an intermediate sidewall electrical contact 104b is formed. Step 906
may include depositing an insulator over the bottom electrical contact 104b, etching
back the insulator to a desired level, depositing a metal over the insulator, and
etching back the metal.
[0096] In step 908, a top electrical contact is formed. In one embodiment, the top electrical
contact is a top sidewall electrical contact 104a. A process similar to the ones in
either Figure 5B or 5C might be used to form a top sidewall electrical contact 104a.
In one embodiment, the top electrical contact is not a sidewall contact.
[0097] In step 910, edges of the electrical contacts are exposed. The edges may be exposed
using a wide variety of techniques including etching and photolithography. In step
912 leads are attached to the electrical contacts. Figure 3C depicts an example of
a device 300 having exposed edges with leads 112 attached.
[0098] In step 914, control logic 725 is provided. Step 725 may include forming switches
to connect the contacts 104 to different voltage sources, and providing hardware or
software to control the switches. Switches may be implemented by transistors, logic
gates, etc. The control logic 725 may be operable to perform functions such as those
discussed in connection with Figures 7A-7C and 8A-8C. The control logic 725 may include
any combination of hardware and/or software.
Pixilated Device
[0099] One embodiment includes a pixilated nanostructure optoelectronic device. Different
groups of one or more nanostructures 96 may be controlled separately as individual
pixels. Each pixel may have multiple photo-active junctions. Each junction may be
capable of generating or detecting light of a different range of wavelengths. For
example, one junction may be capable of blue light generation, another red light,
and still another green light. The different photo-active junctions in each nanostructure
96 may be independently controlled.
[0100] Figure 10A depicts one embodiment of a pixilated nanostructure optoelectronic device
1000. Only a small portion of the device 1000 is depicted. The device 1000 includes
a first layer of p-contacts 1012 that run in the y-direction, a first layer of n-contacts
1014 that run in the x-direction, a second layer of p-contacts 1016 that run in the
y-direction, and a second layer of n-contacts 1018 the run in the x-direction. Each
contact may be a long strip of metal, for example. Insulation 1025 between layers
of contacts is depicted in Figure 10A.
[0101] Note that the p-contacts 1012 may be one embodiment of top sidewall electrical contacts.
Note that tops 96a of the nanostructures 96 are exposed to allow light to enter or
leave the nanostructures 96 from the tops 96a without passing through the p-contacts
1012. In this case, the spaces between the nanostructures 96 are not completely filled
by the top sidewall electrical contacts. The region between contacts at a given layer
may be filled with insulation; however, this insulation is not depicted in Figure
10A so as to not obscure the diagram. Therefore, in some embodiments, the combination
of the top sidewall contacts and insulation completely fills the spaces between the
nanostructures at a level near the tops of the nanostructures 96. In some embodiments,
the top contacts are not sidewall contacts.
[0102] Each contact may have a contact pad 1032 at the end to which an electrical lead 112
is attached. Therefore, the control logic 725 may apply a separate voltage (or provide
a current) to each contact. In some cases, a contact may be electrically isolated
from the voltage source such that the contact is floated. Only some of the electrical
connections between the control logic 725 and the electrical leads 112 are explicitly
depicted so as to not obscure the diagram.
[0103] A sub-pixel corresponds to the intersection of certain p-contacts and n-contacts.
For example, a blue sub-pixel may correspond to the intersection of one of the p-contacts
1012 in the first layer of p-contacts 1012 and one of the n-contacts 1014 in the first
layer of n-contacts 1014. As another example, a green sub-pixel may correspond to
the intersection of one of the n-contacts 1014 in the first layer of n-contacts 1014
and one of the p-contacts 1016 in the second layer of p-contacts 1016. As a further
example, a red sub-pixel may correspond to the intersection of one of the p-contacts
1016 in the second layer of p-contacts 1016 and one of the n-contacts 1018 in the
second layer of n-contacts 1018. Note that the p-contacts may be switched with n-contacts.
[0104] Figure 10B depicts a side cross sectional perspective of a portion of the device
1000 of Figure 10A. Figure 10B shows a single nanostructure 96 and two p-contacts
1012, 1016, as well as two n-contacts 1014, 1018 that are physically and electrically
connected to the nanostructure sidewall. Note that a given contact may surround the
nanostructure 96. Figure 10B also depicts control logic 725 that controls switches
or other logic in order to bias the photo-junctions appropriately to activate each
photo junction separately.
[0105] The p-n junction of p-type region 1002 and n-type region 1004 may have a first band
gap energy. The p-n junction of p-type region 1006 and n-type region 1004 may have
a second band gap energy. The p-n junction of p-type region 1006 and n-type region
1008 may have a third band gap energy. Appropriate selection of the materials may
be used such that a blue sub-pixel, a green sub-pixel and a red sub-pixel may be formed
from a group of one or more nanostructures 96.
[0106] Returning again to Figure 10A, at the junction of a given p-contact 1012 and a given
n-contact 1014 there is a single nanostructure depicted (note that the single nanostructure
is also the junction of one of the p-contacts 1016 and one of the n-contacts 1018).
However, there may be a group of one or more nanostructures at the contact junction.
Herein, the term "nanostructure group" will be used to refer to a group of one or
more nanostructures that are being controlled by the same set of the p-contacts and
n-contacts. For example, referring to Figure 10A, each of the depicted nanostructures
96 is being controlled by its own set of p-contacts and n-contacts. For some embodiments,
a pixel may be defined as including a blue sub-pixel, a red sub-pixel and a green
sub-pixel. Therefore, a nanostructure group may function as a pixel.
[0107] Figure 10C depicts one embodiment of a biasing scheme for a pixilated device 1000
such as the example devices depicted in Figures 10A and 10B. The diagram shows three
p-contacts running in the y-direction and three n-contacts running in the x-direction.
For example, the contacts could be p-contacts 1012 and n-contacts 1014 from Figure
10A. As another example, the contacts could be p-contacts 1016 and n-contacts 1018
from Figure 10A. As still another example, the contacts could be n-contacts 1014 and
p-contacts 1016 from Figure 10A. Thus, the contacts may be on adjacent contact layers
of the device 1000 of Figure 10A. It will be understood that the p-contacts and n-contacts
are not physically touching. Each diode represents one sub-pixel 1050. Each diode
corresponds to a p-type region and an n-type region of a nanostructure group. Note
that the diode could be a p-i-n diode.
[0108] Example bias voltages are shown applied to the contacts for LED operation. One of
the sub-pixels (in the center) is selected and the others are un-selected. By selected
it is meant that the photo-active region is activated by the applied voltages. For
example, for an LED the sub-pixels may be biased to emit light.
[0109] Specifically, the selected sub-pixel 1050 has the voltage Vhigh applied to its p-contact
and Vlow is applied to its n-contact. As one example, Vhigh - Vlow is sufficient to
forward bias the diode for LED operation. As one example, Vlow may be a 0 Volts and
Vhigh may be a voltage that is above the turn on voltage of the diode. However, Vlow
is not required to be 0 Volts. Rather, Vlow could be greater or less than 0 Volts.
Therefore, Vhigh is not necessarily a voltage that is above the turn on voltage of
the diode.
[0110] Some of the unselected sub-pixels will have Vhigh - Vhigh across their diodes. Other
sub-pixels have Vlow - Vlow across their diodes. Therefore, no net voltage appears
across those diode junctions such that the sub-pixels are off. Some of the unselected
sub-pixels will have Vlow - Vhigh across their diodes. The voltage Vlow - Vhigh should
be one that does not activate the sub-pixels. For example, Vlow - Vhigh might reverse
bias the diode such that the sub-pixel is off.
[0111] Note that more than one sub-pixel in a given layer may be selected at the same time
by applying appropriate select voltages to the appropriate p-contact and n-contacts.
For example, any number of blue sub-pixels may be selected at the same time. As another
example, any number of red sub-pixels may be selected at the same time. In some embodiments,
when the blue sub-pixels are being controlled, the red and green sub-pixels are dormant.
For example, when the blue sub-pixels are being selected or unselected using a bias
scheme such as depicted in Figure 10C, all of the red and green sub-pixels are temporarily
off. Note that Figure 10C only shows contacts for two different levels. However, in
some embodiments, there are four levels of contacts (see, for example, Figure 10A).
In some embodiments, the other contacts are floated when Vhigh and Vlow are applied
to the contacts in Figure 10C in order to keep the other sub-pixels off. However,
other techniques may be used to keep the other sub-pixels off.
[0112] The foregoing biasing scheme of Figure 10C is just one example. Other biasing schemes
may be used. Modifications to the biasing scheme can be made for the case in which
the diode is facing the opposite direction.
[0113] Figure 10D shows one example biasing scheme for photo-detector operation for a pixilated
device 1000 such as the example devices depicted in Figures 10A and 10B. The diagram
shows three p-contacts running in the y-direction and three n-contacts running in
the x-direction. For example, the contacts could be p-contacts 1012 and n-contacts
1014 from Figure 10A. As another example, the contacts could be p-contacts 1016 and
n-contacts 1018 from Figure 10A. As still another example, the contacts could be n-contacts
1014 and p-contacts 1016 from Figure 10A. Thus, the contacts may be on adjacent contact
layers of the device 1000 of Figure 10A. It will be understood that the p-contacts
and n-contacts are not physically touching. Each diode represents one sub-pixel 1050.
Each diode corresponds to a p-type region and an n-type region of a nanostructure
group. Note that the diode could be a p-i-n diode.
[0114] Example bias voltages are shown applied to the contacts for photo-detector operation.
One of the sub-pixels (in the center) is selected and the others are un-selected.
By selected it is meant that the photo-active region is activated by the applied voltages.
For a photo-detector, the sub-pixel may be reversed biased to detect light. However,
note that the junction could be unbiased also. The amount of current that is generated
by the selected sub-pixel is detected by the circuit. For example, an ammeter (A)
detects the current. Leaving the circuit open is one way to de-select a sub-pixel.
Note that no voltages need to be applied to some of the n-contacts and p-contact,
as certain sub-pixels are not selected.
[0115] Specifically, the selected sub-pixel 1075 has the voltage Vhigh applied to its n-contact
and Vlow is applied to its p-contact. As already mentioned, it may not be necessary
to apply voltages so long as the circuit is closed. However, reverse biasing the junction
may improve operation. Some of the unselected sub-pixels will have a voltage applied
to one contact. However, the other contact may be floated (e.g., the circuit may be
open at the other contact). Therefore, the junction will not be active.
[0116] Note that additional sub-pixels could be selected for photo-detector operation by
reverse biasing diode junctions similar to how the selected sub-pixel 1075 is selected.
For example, suitable Vhigh and Vlow votlages may be applied to other n-contacts and
p-contacts.
[0117] In some embodiments, at least two of the three colors of sub-pixels are selected
(e.g., "on" or "active") at the same time. For example, both a red and a blue sub-pixel
in the same nanostructure group may be selected at the same time. As another example,
a red sub-pixel is selected in one nanostructure group while a blue sub-pixel is selected
in another nanostructure group.
[0118] In some embodiments, any color sub-pixel may be selected at one point in time. For
example, all sub-pixels in the same nanostructure group may be selected at the same
time. As another example, some nanostructure groups have their blue sub-pixel selected
at the same time that other nanostructure groups have their red sub-pixel selected
and at the same time that other nanostructure groups have their green sub-pixel selected.
Many other combinations are possible.
[0119] Figure 11 depicts a flowchart of embodiment of a process 1100 of operating an optoelectronic
device. The process 1100 may be used to operate a device 1000 such as the one depicted
in Figure 10A or 10B; however, the process is not limited to those devices. For example,
the process could be used to operate a three color LED display. The process 1100 might
also be used to operate a photo-detector, imaging device, or spectrometer. The optoelectronic
device may include a nanostructure array with groups of one or more nanostructures
in the array ("nanostructure groups") forming pixels having at least two sub-pixels.
[0120] In step 1102, first sub-pixels (e.g., blue sub-pixels) are controlled to generate
or detect light of a first range of wavelengths. For example, the control logic 725
applies appropriate Vhigh and Vlow voltages to p-contacts 1012 and n-contacts 1014
that are associated with the blue sub-pixels. Examples of LED and photo-detector operation
were described above. Other examples are described below. In one embodiment, the other
sub-pixels are off when the blue sub-pixels are being controlled. One technique for
keeping the other sub-pixels off is to float the other contacts. For example, p-contacts
1016 and n-contacts 1018 may be floated when Vhigh and Vlow are applied to the p-contacts
1012 and n-contacts 1014. However, other techniques can be used to keep the red and
green sub-pixels off when controlling the blue sub-pixels.
[0121] In step 1104, second sub-pixels (e.g., green sub-pixels) are controlled to generate
or detect light of a second range of wavelengths. For example, the control logic 725
applies appropriate Vhigh and Vlow voltages to n-contacts 1014 and p-contacts 1016
that are associated with the green sub-pixels. In one embodiment, the other sub-pixels
are off when the green sub-pixels are being controlled. For example, p-contacts 1012
and n-contacts 1018 may be floated when Vhigh and Vlow are applied to the p-contacts
1014 and p-contacts 1016. However, other techniques can be used to keep the red and
blue sub-pixels off when controlling the green sub-pixels.
[0122] In step 1106, third sub-pixels (e.g., red sub-pixels) are controlled to generate
or detect light of a third range of wavelengths. For example, the control logic 725
applies appropriate Vhigh and Vlow voltages to p-contacts 1016 and n-contacts 1018
that are associated with the red sub-pixels. In one embodiment, the other sub-pixels
are off when the red sub-pixels are being controlled. For example, p-contacts 1012
and n-contacts 1014 may be floated when Vhigh and Vlow are applied to the p-contacts
1016 and n-contacts 1018. However, other techniques can be used to keep the green
and blue sub-pixels off when controlling the red sub-pixels.
[0123] Note that the first, second, and third ranges of wavelengths are different ranges.
However, there may or may not be overlap in the ranges. For example, one sub-pixel
may be configured to absorb/emit photons from A nm to B nm, another sub-pixel may
be configured to absorb/emit photons from B nm to C nm, another sub-pixel may be configured
to absorb/emit photons from C nm to D nm. As another example, one sub-pixel may be
configured to absorb/emit photons from A nm to B nm, another may be configured to
absorb/emit photons from B+x nm to C nm, another may be configured to absorb/emit
photons from C+y nm to D nm (where x and y are positive values). As still another
example, one sub-pixel may be configured to absorb/emit photons from A nm to B nm,
another may be configured to absorb/emit photons from B-x nm to C nm, another may
be configured to absorb/emit photons from C-y nm to D nm. Other variations are possible;
the foregoing are intended as examples.
[0124] Note also that two or more of steps 1102, 1104, and 1106 may be performed simultaneously.
In some embodiments, different colors of sub-pixels may be controlled at the same
time. Therefore, a red sub-pixel could be selected at the same time that a blue sub-pixel
is selected, for example. Further details of selecting different colors of sub-pixels
at the same time are discussed below.
[0125] Using the process 1100 of Figure 11, essentially any color of light may be generated.
For example, white light could be generated by activating selected blue sub-pixels
for a period of time (while green and red sub-pixels are off), activating selected
green sub-pixels for a period of time (while green and blue sub-pixels are off), and
activating selected red sub-pixels for a period of time (while green and blue sub-pixels
are off). However, in some embodiments, two or more colors of sub-pixels are selected
at the same time. For example, white light could be generated by selecting a blue
sub-pixel, a green sub-pixel, and a red sub-pixel at the same time. Note that the
blue, green and red sub-pixels may be in the same nanostructure group. Further details
of such a technique are discussed below.
[0126] Another option for generating different colors is to select different color sub-pixels
from adjacent nanostructure groups. As mentioned, because a nanostructure group of
some embodiments has three colors of sub-pixels, a nanostructure group may be considered
to be a pixel. However, another option for forming a "pixel" is to use three adjacent
nanostructure groups. For example, a pixel could comprise the blue sub-pixel from
one nanostructure group, the green sub-pixel from an adjacent nanostructure group,
and the red sub-pixel from another adjacent nanostructure group. Thus, as one example,
white light could be formed by selecting a blue, red and green sub-pixel from adjacent
nanostructure groups at the same time.
Example Biasing Schemes for Operating Different Color Sub-pixels Simultaneously
[0127] Figures 12A-12C depict one embodiment of a biasing scheme in which different colors
of sub-pixels are controlled simultaneously. This scheme may be used for LED operation,
for example. This allows different color of sub-pixels to be selected at the same
time. In this embodiment, two sub-pixels in the same nanostructure group may be controlled
simultaneously. For example, the red sub-pixels and the green sub-pixels may be controlled
(or operated) at the same time. For example, a red sub-pixel and a green sub-pixel
in the same nanostructure group may be selected at the same time. As another example,
a red sub-pixel in one nanostructure group may be selected and at the same time that
a green sub-pixel in another nanostructure group is selected. In some embodiments,
steps 1102, 1104, and 1106 of Figure 11 are performed using the biasing scheme depicted
in Figures 12A-12C.
[0128] Figures 12A-12C depict three different levels of contacts. One set of p-contacts
1202 that run in the y-direction are shown as solid lines to depict they are at one
level. A second set of p-contacts 1204 that run in the y-direction are shown as dashed
lines to depict they are at another level. Also depicted as a set of n-contacts 1206
that run on the x-direction. The n-contacts are at a different level than the p-contacts.
The three levels of contacts may correspond to three of the four levels of contacts
from the device 1000 of Figure 10A. One set of diodes is depicted as being connected
between p-contacts 1202 and n-contacts 1206. Those diodes represent one color of sub-pixels.
Another set of diodes is depicted as being connected between p-contacts 1204 and n-contacts
1206. Those diodes represent another color of sub-pixels.
[0129] In Figure 12A, one sub-pixel of each color is circled to indicate that they are selected
sub-pixels 1210. All of the other sub-pixels are off (not selected) in this example.
The example voltages that are applied to the contacts are as follows. The voltage
Vhigh is applied to the selected p-contact 1202, 1204 of each of the selected sub-pixels,
while Vlow is applied to the selected n-contact 1206. Therefore, the diode junctions
are forward biased to select the sub-pixel. Note that this pertains to operation as
an LED, for example. All other diodes are either reverse biased or have no voltage
applied across the diode. Therefore, the other sub-pixels are off (not selected).
[0130] In Figure 12B, one sub-pixel is circled to indicate that it is the selected sub-pixel
1210. The example voltages that are applied to the contacts are as follows. The voltage
Vhigh is applied to the selected p-contact 1202 of the selected sub-pixel, while Vlow
is applied to the selected n-contact 1206. Therefore, the diode junction is forward
biased to select the sub-pixel. The p-contact 1204 for the other color sub-pixel has
Vlow applied such that its diode is un-biased. All other diodes are either reverse
biased or have no voltage applied across the diode. Therefore, the other sub-pixels
are off (not selected).
[0131] In Figure 12C, one sub-pixel is circled to indicate that it is the selected sub-pixel
1210. The example voltages that are applied to the contacts are as follows. The voltage
Vhigh is applied to the selected p-contact 1204 of the selected sub-pixel, while Vlow
is applied to the selected n-contact 1206. Therefore, the diode junction is forward
biased to select the sub-pixel. The p-contact 1202 for the other color sub-pixel has
Vlow applied such that its diode is un-biased. All other diodes are either reverse
biased or have no voltage applied across the diode. Therefore, the other sub-pixels
are off (not selected).
[0132] In one embodiment, while the two colors of sub-pixels in Figures 12A-12C are being
controlled (e.g., being selected or unselected), the sub-pixels for the other color
is kept off. Then, while the two colors of sub-pixels in Figures 12A-12C are off,
the sub-pixels for the other color are being controlled (e.g., being selected or unselected).
For example, 50 percent of the time red and green sub-pixels are being controlled
using the biasing scheme of Figures 12A-12C with blue sub-pixels off. The other 50
percent of the time blue sub-pixels are being controlled using the biasing scheme
of Figure 10C with red and green sub-pixels off.
[0133] Note that two different colors of sub-pixels may be simultaneously selected when
operating as a photo-detector. Figure 12D shows one possible biasing scheme for selecting
two different colors of sub-pixels in the same nanostructure for photo-detector operation.
As can be seen two sub-pixels are reversed biased and therefore, selected for photo-detector
operation. Un-selected sub-pixels have open circuits, and do not require a voltage
applied to each contact. As mentioned, operation may be possible without basing the
contacts, so long as the circuit is closed. Also note that one color sub-pixel can
be selected in one nanostructure, while selecting another color sub-pixel in another
nanostructure. For example, a red (but not green) sub-pixel could be selected in one
nanostructure while selecting a green (but not red) sub-pixel in the other nanostructure.
[0134] Figures 13A-13H depict one embodiment of a biasing scheme in which three different
color sub-pixels are operated or controlled simultaneously. The scheme may be used
for LED operation, for example. In this embodiment, three sub-pixels in the same nanostructure
group may be controlled simultaneously. For example, any combination of a blue sub-pixel,
a red sub-pixel and a green sub-pixel in the same nanostructure group may be selected
at the same time. Also note that a different nanostructure group may have a different
combination of sub-pixels selected at the same time. For example, one nanostructure
group may have its blue and green sub-pixels selected at the same time that another
nanostructure group has its red and blue sub-pixels selected. In some embodiments,
steps 1102, 1104, and 1106 of Figure 11 are performed using the biasing scheme depicted
in Figures 13A-13H.
[0135] Figures 13A-13H depict four different levels of contacts. These may correspond to
the contacts in Figure 10A. One set of p-contacts 1012 that run in the y-direction
are shown as solid lines to depict they are at one level. A second set of p-contacts
1016 that run in the y-direction are shown as dashed lines to depict they are at another
level. Also depicted as two sets of n-contacts 1014, 1018 that run in the x-direction.
[0136] One set of diodes is depicted as being connected between p-contacts 1012 and n-contacts
1014. Those diodes represent one color of sub-pixels (e.g., blue sub-pixels). Another
set of diodes is depicted as being connected between p-contacts 1016 and n-contacts
1014. Those diodes represent another color of sub-pixels (e.g., green sub-pixels).
Still another set of diodes, which represent a third color of sub-pixels (e.g., red
sub-pixels), is depicted as being connected between p-contacts 1016 and n-contacts
1018.
[0137] Figures 13A-13H show voltages that may be applied to the contacts in order to selectively
operate different combinations of sub-pixels in the center pixel 1310. All other sub-pixels
are off on each of Figures 13A-13H. However, note that the other sub-pixels could
be on if suitable voltages were applied to their contacts. In this example, the voltage
Vhigh may be a turn on voltage of a diode. The voltage Vlow may be -Vhigh. In general,
forward biasing the diode may be used to select the sub-pixel. Diodes that are either
un-biased or reverse biased result in off sub-pixels. The foregoing assumes operation
as an LED.
[0138] In Figure 13A all sub-pixels are off due to grounding all contacts. Note that even
the circled sub-pixels are off in Figure 13A; however, they are circled to highlight
that those three sub-pixels form the pixel that this discussion is focused upon. In
Figure 13B, the blue (circled) sub-pixel is on, whereas the green and red sub-pixels
are off. In Figure 13C, the green (circled) sub-pixel is on, whereas the blue and
red sub-pixels are off. In Figure 13D, the red sub-pixel (circled) is on, whereas
the green and red sub-pixels are off. In Figure 13E, the green and blue sub-pixels
are on, whereas the red sub-pixel is off. In Figure 13F, the green and red sub-pixels
(circled) are on, whereas the blue sub-pixel is off. In Figure 13G, the red and blue
sub-pixels are on, whereas the green sub-pixel is off. Note that this is the only
case in which the voltage Vlow is used. For example, the red sub-pixel is biased by
the applying GND to one terminal and Vlow to the other terminal to forward bias the
diode. In Figure 13H, the red, blue and green sub-pixels (circled) of the pixel under
discussion are all on.
[0139] Note that three different colors of sub-pixels may be simultaneously selected when
operating as a photo-detector. For example, Figure 13I shows one possible biasing
scheme for selecting three different colors of sub-pixels in the same nanostructure
for photo-detector operation. As can be seen three sub-pixels are reversed biased
and therefore, selected for photo-detector operation. Circuits for detecting the generated
currents are not explicitly shown in Figure 13I. Un-selected sub-pixels have open
circuits, and do not require a voltage applied to both of their contacts. As mentioned,
operation may be possible without basing the contacts, so long as the circuit is closed.
Also note that any combination of colors of sub-pixels can be selected in one nanostructure,
while selecting a different combination of colors of sub-pixels in another nanostructure.
For example, a red and a blue (but not green) sub-pixel could be selected in one nanostructure
while selecting a green and red (but not blue) sub-pixel in the other nanostructure.
Example Process of Fabricating a Pixilated Optoelectronic Device
[0140] Figure 14 depicts one embodiment of a process 1400 of fabricating an optoelectronic
device. Process 1400 may be used to form a device such as devices 1000 depicted in
Figures 10A and 10B. Reference will be made to those devices, but process 1400 is
not so limited. In step 1402, nanostructures are formed. Step 1402 may be similar
to step 502 of process 500 and will not be discussed in detail. In step 1404, a row
of electrical contacts that run in a first direction is formed. Step 1404 may be performed
by depositing metal, then patterning and etching to form rows of contacts. As one
example, n-contacts 1018 are formed. Note that this row could be p-contacts, depending
on the doping of the nanostructures 96.
[0141] In step 1406 insulation is formed. For example, SOG, silicon dioxide, photoresist
or another material is deposited. The insulation may fill spaces between the rows
of contacts and also may form a layer over the rows to serve as a base for the next
row of contacts.
[0142] In step 1408, a row of electrical contacts that run in a second direction is formed.
The second direction may be orthogonal to the first. Step 1408 may be performed by
depositing metal, then patterning and etching to form rows of contacts. As one example,
p-contacts 1016 are formed. In step 1410, additional insulation is formed. For example,
SOG, silicon dioxide, photoresist or another material is deposited. The insulation
may fill spaces between the rows of contacts 1016 and also may form a layer over the
rows of contacts 1016 to serve as a base for the next row of contacts.
[0143] In step 1412, another row of electrical contacts that run in the first direction
is formed. Step 1412 may be performed by depositing metal, then patterning and etching
to form rows of contacts. As one example, n-contacts 1014 are formed. In step 1414,
additional insulation is formed. For example, SOG, silicon dioxide, photoresist or
another material is deposited. The insulation may fill spaces between the rows of
contacts 1014 and also may form a layer over the rows of contacts 1014 to serve as
a base for the next row of contacts.
[0144] In step 1416, another row of electrical contacts that run in the second direction
is formed. Step 1416 may be performed by depositing metal, then patterning and etching
to form rows of contacts. As one example, p-contacts 1012 are formed. In step 1418,
additional insulation is formed (optional). For example, SOG, silicon dioxide, photoresist
or another material is deposited. The insulation may fill spaces between the rows
of contacts 1012.
[0145] In step 910, edges of the electrical contacts are exposed. The edges may be exposed
using a wide variety of techniques including etching and photolithography. In step
912 leads are attached to the electrical contacts. Figure 10A depicts an example of
a device 1000 having exposed edges with leads 112 attached.
[0146] In step 914, control logic 725 is provided. Step 725 may include forming switches
to connect the contacts 104 to different voltage sources, and providing hardware or
software to control the switches. The control logic 725 may be operable to perform
functions such as those discussed in connection with Figures 7A-7C, 8A-8C and 11.
The control logic 725 may include any combination of hardware and/or software.
Other Variations of Pixilated Nanostructure Optoelectronic Devices
[0147] Figure 15A is a diagram of one embodiment of a pixilated nanostructure optoelectronic
device. The device is similar to the one depicted in Figure 10A. However, it has an
additional set of p-contacts 1015 that run in the y-direction. There is also an additional
layer of insulation 1025, which is located between the p-contacts 1015 and p-contacts
1016.
[0148] Figure 15B is a side cross-sectional view of the device 1500 of Figure 15A. This
view shows how the contacts and insulation make connection to one of the nanostructures
96. Note that the p-type semiconductor 1006 is separated into two regions 1006a, 1006b
by a layer of insulation 1525. This may aid is allowing the red sub-pixel to be operated
independent of the green sub-pixel. The insulation 1525 may be an insulating semiconductor
that is formed during growth of the nanostructures 96. Therefore, the nanostructures
96 have a region having alternating layers of a semiconductor having a first type
of conductivity (e.g., region 1006a), an insulator (e.g., 1525), and a semiconductor
having the first type of conductivity (e.g., 1006b).
[0149] In this example, the n-contacts 1014 and 1018 are connected to ground. The control
logic 725 connects p-contact 1012 to Vhigh to select the blue sub-pixel. The control
logic 725 connects p-contact 1015 to Vhigh to select the green sub-pixel. The control
logic 725 connects p-contact 1016 to Vhigh to select the red sub-pixel. In one embodiment,
the control logic 725 connects the p-contact 1012 to GND to unselect (turn off) the
blue sub-pixel. In one embodiment, the control logic 725 connects the p-contact 1015
to GND to unselect (turn off) the green sub-pixel. In one embodiment, the control
logic 725 connects the p-contact 1016 to GND to unselect (turn off) the red sub-pixel.
Therefore, the control logic 725 is able to independently select any of the sub-pixels.
Note that a different biasing scheme may be used to select the sub-pixels.
[0150] Note that alternatives to the structure of Figures 15A and 15B is to have the extra
layer of insulation separate the blue and green sub-pixels instead of (or in addition
to) the insulation 1025 that separates the red and green sub-pixels. For example,
n-type semiconductor 1004 could be separated into two regions by an insulator. In
such an embodiment, the n-contact 1014 could be replaced by two contacts separated
by an insulator.
[0151] Note that numerous examples have been provided in which the devices have three colors
of sub-pixels. However, the device may have any number of sub-pixels. These sub-pixels
may correspond to many different wavelengths of light. It is not required that a sub-pixel
corresponds to a wavelength of visible light.
[0152] In some embodiment, an optoelectronic device with sidewall electrical contacts may
be operated as a spectrometer. For example, additional layers may be added to the
device 1000 of Figures 10A-10B or the device 300 of Figures 3A-3C to allow for detection
of light at many more distinct wavelength ranges. The control logic 725 may be configured
to separately control each layer to detect light of each distinct wavelength range.
Note that there may be some overlap in the range of wavelengths that two different
sub-pixels correspond to.
Example Computing Platform
[0153] In various embodiments, the control logic 725 executes computer readable instructions
that are stored on computer readable media. For example, process 800, 815, 840, and
1100 may be implemented at least in part by executing, on a processor, instructions
that are stored on a computer readable storage medium. Computer readable media can
be any available media that can be accessed by the electronic devices. By way of example,
and not limitation, computer readable media may comprise computer storage media. Computer
storage media includes volatile and nonvolatile, removable and non-removable media
implemented in any method or technology for storage of information such as computer
readable instructions, data structures, program modules or other data. Computer storage
media includes, but is not limited to, RAM, ROM, EEPROM, flash memory or other memory
technology, CD-ROM, digital versatile disks (DVD) or other optical storage, magnetic
cassettes, magnetic tape, magnetic disk storage or other magnetic storage devices,
or any other medium which can be used to store the computer readable instructions
and which can accessed by the electronic devices.
[0154] The computer executable instructions may include program modules. Generally, program
modules include routines, programs, objects, components, data structures, etc., that
perform particular tasks or implement particular abstract data types. Embodiments
may also be practiced in distributed computing environments where tasks are performed
by remote processing devices that are linked through a communication network. In a
distributed computing environment, program modules may be located in both local and
remote computer storage media including memory storage devices.
[0155] FIG. 16 is a block diagram of one embodiment of a computing system for use with the
present technology. Note that some embodiments do not require all of the elements
depicted in FIG. 16. In some embodiments, the output display/photo-detector 1666 is
an LED display. For example, technology described herein may be used to form pixels
of the LED. The computing device is able to implement the control logic 725 in order
to control the LED. In some embodiments, at least some of the functionality of the
control logic 725 is implemented by executing instructions on the processor 1650.
In some embodiments, the output display/photo-detector 1666 is able to function as
a photo-detector. For example, technology described herein may be used to form pixels
of a photo-detector.
[0156] The computer system includes one or more processors 1650 and main memory 1652 which
stores, in part, instructions and data for execution by processor unit 1650. If the
system of the present invention is wholly or partially implemented in software, main
memory 1652 can store the executable code when in operation. Also provided are a mass
storage device 1654, peripheral device(s) 1656, user input device(s) 1660, output
devices 1658, portable storage medium drive(s) 1662, a graphics subsystem 1664 and
an output display 1666. For simplicity, the components are depicted as being connected
via a single bus 1668. However, the components may be connected through one or more
data transport means. For example, processor unit 1650 and main memory 1652 may be
connected via a local microprocessor bus, and the mass storage device 1654, peripheral
device(s) 1656, portable storage medium drive(s) 1662, and graphics subsystem 1664
may be connected via one or more input/output (I/O) buses. Mass storage device 1654,
which may be implemented with a magnetic disk drive or an optical disk drive, is a
non-volatile storage device for storing data and instructions for use by processor
unit 1650. In one embodiment, mass storage device 1654 stores the system software
for implementing the present invention for purposes of loading to main memory 1652.
[0157] Portable storage medium drive 1662 operates with a portable non-volatile storage
medium, such as a floppy disk, to input and output data and code to and from the computer
system. In one embodiment, the system software for implementing the embodiments is
stored on such a portable medium, and is input to the computer system via the portable
storage medium drive 1662. Peripheral device(s) 1656 may include any type of computer
support device, such as an input/output (I/O) interface, to add additional functionality
to the computer system. For example, peripheral device(s) 1656 may include a network
interface for connecting the computer system to a network, a modem, a router, etc.
[0158] User input device(s) 1660 provides a portion of a user interface. User input device(s)
1660 may include an alpha-numeric keypad for inputting alpha-numeric and other information,
or a pointing device, such as a mouse, a trackball, stylus, or cursor direction keys.
In order to display textual and graphical information, the computer system includes
graphics subsystem 1664 and output display 1666. Graphics subsystem 1664 receives
textual and graphical information, and processes the information for output to output
display 1666. Additionally, the computer system includes output devices 1658. Examples
of suitable output devices include speakers, printers, network interfaces, monitors,
etc.
[0159] The components contained in the computer system are those typically found in computer
systems suitable for use with the embodiments, and are intended to represent a broad
category of such computer components that are well known in the art. Thus, the computer
system can be a personal computer, hand held computing device, telephone, mobile computing
device, workstation, server, minicomputer, mainframe computer, or any other computing
device. The computer system can also include different bus configurations, networked
platforms, multi-processor platforms, etc. Various operating systems can be used including
Unix, Linux, Windows, Macintosh OS, Palm OS, and other suitable operating systems.
[0160] One embodiment disclosed herein includes an optoelectronic device comprising a plurality
of nanostructures that include photo-active regions. The nanostructures have tops,
bottoms, and sidewalls. The device has a bottom electrical contact in electrical contact
with the bottoms of the plurality of nanostructures, and a top electrical contact
in electrical and physical contact with sidewalls of the plurality of nanostructures,
wherein the top electrical contact leaves a top portion of the plurality of nanostructures
exposed to allow light to enter or leave the plurality of nanostructures from the
tops of the plurality of nanostructures without passing through the top electrical
contact.
[0161] One embodiment disclosed herein includes a method for forming an optoelectronic device
comprising: forming a plurality of nanostructures, the nanostructures including photo-active
regions, the plurality of nanostructures having tops, bottoms, and sidewalls; forming
a bottom electrical contact in electrical contact with the bottoms of the plurality
of nanostructures; and forming a top electrical contact in electrical and physical
contact with sidewalls of the plurality of nanostructures, wherein the top electrical
contact leaves a top portion of the plurality of nanostructures exposed to allow light
to enter or leave the plurality of nanostructures from the tops of the plurality of
nanostructures without passing through the top electrical contact.
[0162] One embodiment disclosed herein includes an optoelectronic device comprising an array
of nanostructures formed from a material that includes one more semiconductors, the
nanostructures including one or more p-n junctions, the nanostructures including photo-active
regions associated with the p-n junctions, the plurality of nanostructures having
tops, bottoms, and sidewalls, the nanostructures have spaces between them; a bottom
electrical contact in electrical contact with the bottoms of the nanostructures; and
a top electrical contact in electrical and physical contact with the sidewalls of
the nanostructures, wherein the top electrical contact is substantially opaque to
light having a wavelength that is absorbed or generated by the photo-active regions.
[0163] One embodiment disclosed herein includes a multi-junction solar cell comprising a
plurality of nanostructures, the plurality of nanostructures having first regions
of a first conductivity type and second regions of a second conductivity type to form
first p-n junctions, the plurality of nanostructures having third regions of the first
conductivity type and fourth regions of the second conductivity type to form second
p-n junctions; and a bi-layer electrical interconnect having a first material in electrical
and physical contact with the second regions and a second material in electrical and
physical contact with the third regions, the first material and the second material
are in electrical contact with each other to allow charge to flow between the second
regions and the third regions through the bi-layer electrical interconnect.
[0164] One embodiment disclosed herein includes method for forming a multi-junction solar
cell comprising: forming a plurality of nanostructures, the plurality of nanostructures
having first regions of a first conductivity type and second regions of a second conductivity
type to form first p-n junctions, the plurality of nanostructures having third regions
of the first conductivity type and fourth regions of the second conductivity type
to form second p-n junctions; and forming a bi-layer electrical interconnect having
a first material in electrical and physical contact with the second regions and a
second material in electrical and physical contact with the third regions, the first
material and the second material are in electrical contact with each other to allow
charge to flow between the second regions and the third regions through the bi-layer
electrical interconnect.
[0165] One embodiment disclosed herein includes a multi-junction solar cell comprising:
an array of nanostructures, nanostructures in the array of nanostructures having a
plurality of photo-active regions, each photo-active regions is configured to absorb
light of a different range of frequencies; and a bi-layer electrical interconnect
providing a path for electrical current flow between adjacent ones of the photo-active
regions, each bi-layer electrical interconnect having a first layer that makes Ohmic
contact with a p-type semiconductor and a second layer that makes Ohmic contact with
an n-type semiconductor.
[0166] One embodiment disclosed herein includes an optoelectronic device comprising a plurality
of nanostructures, the plurality of nanostructures having first regions of a first
conductivity type and second regions of a second conductivity type associated with
first photo-active junctions, the plurality of nanostructures having third regions
of the first conductivity type, the second regions and third regions are associated
with second photo-active junctions; a first electrical contact in electrical contact
with the first regions; a second electrical contact in electrical and physical contact
with the second regions; a third electrical contact in electrical contact with the
third regions; and logic coupled to the first electrical contact, the second electrical
contact, and the third electrical contact, the logic controls the first photo-active
junctions independently of the second photo-active junctions.
[0167] One embodiment disclosed herein includes a method of operating an optoelectronic
device that includes a plurality of nanostructures, the plurality of nanostructures
having first regions of a first conductivity type and second regions of a second conductivity
type to form first photo-active junctions, the plurality of nanostructures having
third regions of the first conductivity type that form second photo-active junctions
with the second regions, a first electrical contact in electrical contact with the
first regions, a second electrical contact in electrical and physical contact with
the second regions, a third electrical contact in electrical contact with the third
regions. The method comprises: controlling the first photo-active junctions to either
generate or detect light of a first range of wavelengths; and controlling the second
photo-active junctions to either generate or detect light of a second range of wavelengths,
controlling the first photo-active junctions and the second photo-active junctions
are performed independently of each other.
[0168] One embodiment disclosed herein includes a method of forming an optoelectronic device,
the method comprising: forming a plurality of nanostructures, the plurality of nanostructures
having first regions of a first conductivity type and second regions of a second conductivity
type to form first photo-active junctions, the plurality of nanostructures having
third regions of the first conductivity type that form second photo-active junctions
with the second regions; forming a first electrical contact in electrical contact
with the first regions; forming a second electrical contact in electrical and physical
contact with the second regions; forming a third electrical contact in electrical
contact with the third regions; and providing logic coupled to the first electrical
contact, the second electrical contact, and the third electrical contact, the logic
controls the first photo-active junctions independently of the second photo-active
junctions.
[0169] One embodiment disclosed herein includes an optoelectronic device comprising: a nanostructure
array, the nanostructures having sidewalls, groups of one or more nanostructures in
the array forming pixels; a first group of electrical contacts physically and electrically
connected to the sidewalls, the first group of electrical contacts are aligned in
a first direction; and a second group of electrical contacts physically and electrically
coupled to the sidewalls, the second group of electrical contacts are aligned in a
second direction that is orthogonal to the first direction; wherein the pixels are
individually controllable by applying appropriate voltages to the first group of electrical
contacts and to the second group of electrical contacts.
[0170] One embodiment disclosed herein includes a method of operating an optoelectronic
device that includes a nanostructure array, groups of one or more nanostructures in
the array forming pixels having at least two sub-pixels, the method comprising: controlling
first sub-pixels to generate or detect light of a first range of wavelengths; and
controlling second sub-pixels to generate or detect light of a second range of wavelengths.
The first and second sub-pixels are controlled independently.
[0171] In the foregoing specification, several examples have been provided in which active
regions of devices are associated with p-type and n-type regions. Note that there
may be an unintentionally doped region between the type and n-type regions. Also note
that p-type and n-type regions may be switched with suitable adjustments to operation
of the device (such as reversing the polarity of applied voltages). Further note that
example shapes of nanostructures having been depicted for illustrative purposes. However,
other shapes are possible. Thus, embodiments are not to be limited to columnar shapes,
for example. Also note that different shaped tops of nanostructures have been provided
for illustration. Other top shapes are possible.