Technical Field
[0001] The present invention relates to a nonwoven fabric composed of filament fibers.
Background Art
[0002] Spun-bonded nonwoven fabric is frequently used in absorbent articles, such as disposable
diapers, for its high breaking strength, excellent processability, and good economy.
However, spun-bonded nonwoven fabric lacks overall fluffiness in nature of the production
process and has been difficult to impart improved feel to the touch (hand).
[0003] For example, patent literature 1 below describes a nonwoven fabric having arcuate
loops of fibers in relief on its surface, which is obtained by airlaying staple fibers
on a spun-bonded nonwoven base and needle-punching the resulting structure. However,
when the nonwoven fabric having arcuate loops of fibers in relief is used in an absorbent
article, like a disposable diaper, the arcuate loops of fibers feel rough and scratchy
and cause reduction in wearer comfort on the contrary. Moreover, patent literature
1 gives no mention of the shape of the tip of the constituent fibers.
[0004] Patent literature 2 below discloses a fluffed textured nonwoven fabric obtained by
stretching a continuous filament nonwoven fabric and separating the stretched filament
nonwoven fabric into halves along the middle in the thickness direction. The nonwoven
fabric disclosed has on its one side fibers torn at the fiber bonds and fibers drawn
into loop form. However, the fluffed nonwoven fabric of patent literature 2 is considered
to have many fibers drawn into loop form on its surface in nature of the production
process described. When such a nonwoven fabric is used in an absorbent article, such
as a disposable diaper, the loops will feel scratchy against the skin to cause reduction
in wearer comfort. Patent literature 2 also gives no mention about the shape of the
tip of constituent fibers.
Patent literature 3 below describes a flocked sheet having flocks (short fibers) fixed
via an adhesive. The tip of the flocks of the sheet is not thickened but is angular
as a result of cutting, which can provide poor feel to the touch. Furthermore, because
flocks are fixed to a nonwoven fabric base using an adhesive, a chemical used in the
adhesive and the like can adversely affect or irritate the skin. The flocked sheet
has additional problems, such as fall-off of flocks during use and resultant exposure
of the adhesive.
[0005] Techniques available for obtaining nonwoven fabrics with raised fibers include needle
punching, emerizing a nonwoven fabric, and depositing short fibers on a nonwoven fabric
by flocking.
[0006] For example, patent literature 4 below discloses a process for producing a nonwoven
fabric including the steps of applying a mechanical force to a nonwoven fabric by
contact processing to form weakened portions in the constituent fibers, passing the
nonwoven fabric having the weakened portions on a roller covered with sand paper,
and further processing the nonwoven fabric on a raising machine to raise the constituent
fibers. Patent literature 5 below teaches a method for treating a fluffed textured
sheet including the steps of exerting a dynamic effect on a fluffed textured sheet
and abrading the resulting sheet with sand paper.
[0007] Patent literature 6 describes a method for producing nonwoven fabric including shrinking
a web and needle-punching the shrunken web. Patent literature 7 proposes a method
for making a nonwoven fabric sheet by simply stretching a nonwoven fabric sheet until
the constituent fibers break. The nonwoven fabrics produced by the methods according
to patent literatures 4 to 7 cited above certainly have soft touch (hand).
[0008] Nevertheless, the method of patent literature 4 for producing a fluffed nonwoven
fabric and the method of patent literature 5 for treating a fluffed textured sheet
both involve emerizing (processing using sand paper). Processing with sand paper considerably
damages nonwoven fabric, making it difficult to minimize reduction in breaking strength
of the fluffed nonwoven fabric. The method of patent literature 6 for producing nonwoven
fabric includes needle punching, so that the production speed is low, making it difficult
to reduce the production cost. The method for making a nonwoven fabric sheet according
to patent literature 7 achieves fiber raising merely by a stretch process that gives
the nonwoven fabric a great damage, making it difficult to reduce the reduction in
strength of the resulting raised nonwoven fabric.
Citation List
Patent Literature
Summary of Invention
[0010] The invention provides a nonwoven fabric having high breaking strength and yet feeling
fluffy as a whole with improved feel to the touch. The invention also relates to the
provision of a nonwoven fabric that has a reduced amount of fibers in loop form and
is therefore less likely to feel scratchy against the skin and has improved feel to
the touch.
[0011] The invention relates to a nonwoven fabric including a web of filament fibers consolidated
by bonding at fusion bonds. The nonwoven fabric contains fibers only one end of each
of which has a fixed end fixed at the fusion bond with the other end free as a result
of breaking part of the filament fibers. The free end has an increased thickness.
[0012] The invention also provides a method for making a nonwoven fabric having raised fibers
and thereby exhibiting a pleasant feel to the touch while minimizing reduction in
breaking strength of the resulting raised nonwoven fabric. The invention also provides
a method for making a nonwoven fabric having raised fibers at a high production speed
and a reduced cost.
[0013] The invention relates to a method for making a nonwoven fabric including the steps
of partially stretching a plurality of regions of a nonwoven fabric at 50°C or a lower
temperature and raising the constituent fibers of the partially stretched nonwoven
fabric.
Brief Description of Drawings
[0014]
[Fig. 1] Fig. 1 is a perspective of a nonwoven fabric according to an embodiment of
the invention.
[Fig. 2] Fig. 2 is a perspective of a fiber of the nonwoven fabric shown in Fig. 1,
the free end of which is thickened.
[Fig. 3] Fig. 3 schematically illustrates a unit suitably used in the production of
the nonwoven fabric of Fig. 1.
[Fig. 4] Fig. 4 schematically illustrates a unit suitably used in the production of
the nonwoven fabric of Fig. 1.
[Fig. 5] Fig. 5(a), Fig. 5(b), and Fig. 5(c) schematically demonstrate a method for
measuring the fiber tip diameter of a nonwoven fabric of the invention.
[Fig. 6] Fig. 6(a), Fig. 6(b), and Fig. 6(c) schematically demonstrate a method for
counting the number of raised fibers of a nonwoven fabric of the invention.
[Fig. 7] Fig. 7 is a plan of a disposable pull-on diaper in its flat-out, uncontracted
state, showing a use of a nonwoven fabric of the invention.
[Fig. 8] Fig. 8 is a cross-section taken along line X1-X1 in Fig. 7.
[Fig. 9] Fig. 9 schematically illustrates a processing apparatus suitably used in
the method for making a nonwoven fabric according to the invention.
[Fig. 10] Fig. 10 is a schematic perspective of a partially stretching part of the
processing apparatus shown in Fig. 9.
[Fig. 11] Fig. 11 is an enlarged cross-section of an essential part of the partially
stretching part shown in Fig. 10.
[Fig. 12] Fig. 12 is a schematic perspective of a raising part of the processing apparatus
shown in Fig. 9.
[Fig. 13] Fig. 13(a), Fig. 13(b), and Fig. 13(c) schematically demonstrate a method
for counting the number of raised fibers of a nonwoven fabric of the invention.
Description of Embodiments
[0015] The nonwoven fabric according to the invention will be described generally based
on its preferred embodiment with reference to Figs. 1 through 5.
[0016] As shown in Fig. 1, a nonwoven fabric 1 of the present embodiment is a web of filament
fibers 2 consolidated at discrete fusion bonds 3. The nonwoven fabric 1 has fibers
21 fixed at one end thereof 20a at the fusion bond 3 with the other end 20b free as
a result of partly breaking the filament fibers 2. The free end 20b of each fiber
21 has an increased thickness. As shown in Fig. 1, the nonwoven fabric 1 has a longitudinal
direction designated Y direction and a transverse direction designated X direction.
The machine direction (MD) of the nonwoven fabric 1 which is a direction of orientation
of constituent fibers is taken as the longitudinal direction (Y direction), and the
cross-machine direction (CD) perpendicular to the MD is taken as the transverse direction
(X direction). Accordingly, in the following description the longitudinal direction
(Y direction) is the same as the MD, and the transverse direction (X direction) is
the same as the CD.
[0017] In more detail, the nonwoven fabric 1 of the present embodiment is made by starting
with a spun-bonded nonwoven fabric, which is a web of filament fibers 2 consolidated
at discrete fusion bonds 3 where the filament fibers are press bonded or fusion bonded
to one another. This spun-bonded nonwoven fabric will hereinafter be referred to as
a starting nonwoven fabric. Having part of the filament fibers broken, the nonwoven
fabric 1, even with a small thickness, provides fluffiness as compared with general
spun-bonded nonwoven fabrics.
As used herein, the term "filament fibers" refers to fibers with a length of at least
30 mm. To obtain nonwoven fabrics having high breaking strength, the filament fibers
are preferably what we call continuous filaments with a length of 150 mm or longer.
[0018] The nonwoven fabric 1 preferably has a basis weight of 5 to 100 g/m
2, more preferably 5 to 25 g/m
2, in the interests of competitive price, good feel to the touch, and processability.
[0019] The nonwoven fabric 1 preferably has a breaking strength of 5.00 N/50 mm or more,
more preferably 8 to 30 N/50 mm, from the viewpoint of prevention of tear during use
and processability. The starting nonwoven fabric preferably has a breaking strength
of 7 N/50 mm or more, more preferably 10 to 50 N/50 mm, in order to secure the breaking
strength of the nonwoven fabric 1. The nonwoven fabric 1 of the invention which is
obtained by the hereinafter described raising technique shows a smaller reduction
in breaking strength from the breaking strength of the starting spun-bonded nonwoven
fabric than a nonwoven fabric obtained by other raising techniques. It is preferred
for the nonwoven fabric 1 and the starting spun-bonded nonwoven fabric to have a breaking
strength within the above recited respective ranges in the X direction (CD). The ratio
of the breaking strength of the nonwoven fabric 1 to that of the starting nonwoven
fabric (nonwoven fabric 1/starting nonwoven fabric) is preferably 0.5 to 1.0, more
preferably 0.7 to 1.0. The breaking strength is measured by the method described below.
Method for measuring breaking strength:
[0020] A rectangular specimen measuring 50 mm by 200 mm is cut out of the nonwoven fabric
1 or the starting spun-bonded nonwoven fabric, with the length coincide with the X
direction (transverse direction) and the width coincide with the Y direction (longitudinal
direction), in an environment of 22°C and 65% RH. The specimen is set on a tensile
tester (e.g., Tensilon tensile tester RTA-100 from Orientec) at an initial jaw separation
of 150 mm with its X direction coincide with the pulling direction and pulled at a
rate of 300 mm/min. The maximum load reached until the specimen breaks is taken as
a breaking strength in the X direction. Another rectangular specimen measuring 50
mm in the X direction and 200 mm in the Y direction is cut out and set on the tensile
tester with its Y direction coincide with the pulling direction. The breaking strength
in the Y direction is measured in the same manner as for the measurement in the X
direction.
[0021] The nonwoven fabric 1 of the present embodiment is also characterized by good feel
to the touch.
There are many characteristic values heretofore known to represent feel to the touch.
Particularly well-known are characteristic values determined using a KES system available
from Kato Tech Co., Ltd. (Tokio Kawabata, Fuaihyoukano Hyoujunka to Kaiseki, 2nd Ed.,
July 10, 1980). Of the KES values three values called compression characteristics,
i.e., LC (linearity of compression load-strain curve), WC (work of compression), and
RC (resilience of compression) are known for representation of fluffiness. These compression
characteristic values are calculated from the displacement in applying a load of from
0.5 up to 50 gf/cm
2 (or 0.5 to 10 gf/cm
2 for high sensitivity measurement). However, these values do not largely change among
very thin cloths, such as nonwoven fabrics having a small basis weight (5 to 25 g/m
2), giving no significant correlation with the feel to the touch. Moreover, a human
feels an absorbent article on light touch under a small load of about 1 g/cm
2. Then, the inventors thought that a characteristic value as measured under a smaller
load than has been adopted in conventional evaluation systems would be useful and
found a new characteristic value derived from a displacement under a load ranging
from 0.3 to 1 gf/cm
2. This characteristic value provides a parameter capable of clearly demonstrating
a difference in feel to the touch between a spun-bonded nonwoven fabric and an air-through
nonwoven fabric. That is, the feel to the touch of a spun-bonded nonwoven fabric can
be represented by this new characteristic value.
Compression characteristic value under small load:
[0022] In the invention, a compression characteristic value under a small load is defined
to be a new characteristic value representing feel to the touch. The measurement is
taken in an environment of 22°C and 65% RH. The data from which a compression characteristic
value under a small load is calculated is obtained using KES FB3-AUTO-A (trade name)
available from Kato Tech Co., Ltd. Three specimens measuring 20 cm by 20 cm are cut
out of the nonwoven fabric 1. Every one of the specimens is placed on a stage with
its raised side up. When the sample is not raised on either side or is raised on both
sides, both sides of the specimen are tested, and a smaller one of the resulting values
is adopted. The specimen is then compressed between circular flat steel plates having
an area of 2 cm
2 at a rate of 20 µm/sec to a maximum load of 10 gf/cm
2 and recovered at the same rate. The displacement between the steel plates is taken
as x (mm), and the load as y (gf/cm
2). The position at which a load is first detected is x=0, from which the measurement
is taken in the direction of compression. The value x increases with the progress
of compression.
[0023] The compression characteristic value under small load is calculated by extracting
the displacement in the thickness direction under small load from the resulting x-y
data. Specifically, the load vs. displacement data in a range of load from 0.30 to
1.00 gf/cm
2 in the first loading mode (not in the unloading mode) are extracted, and an approximate
straight line of the x-y relation is obtained by the method of least squares. The
slope of the approximate straight line (in a unit of (gf/cm
2)/mm) is taken as the above discussed characteristic value. Measurement is made at
three different points per specimen to give a total of nine values per sample, an
average of which is taken as a compression characteristic value under small load of
the nonwoven fabric.
[0024] There is a correlation, the inventors found, between a compression characteristic
value under small load and feel to the touch, particularly when the starting nonwoven
fabrics are the same. A smaller compression characteristic value indicates higher
liability to collapse under a small load, i.e., better feeling perceptible by humans,
especially fluffiness. For example, the above-identified compression characteristic
value of an ordinary spun-bonded nonwoven fabric having a basis weight of 5 to 25
g/m
2 (starting nonwoven fabric), which has not been subjected to the hereinafter process,
is 20.0 to 30.0 (gf/cm
2)/mm. In contrast, the compression characteristic value of the nonwoven fabric 1 obtained
by subjecting the same spun-bonded nonwoven fabric with a basis weight of 5 to 25
g/m
2 to the hereinafter described processing treatment is 18.0 (gf/cm
2)/mm or less, indicating a more collapsible surface thereof. In other words, the above
identified compression characteristic value of the nonwoven fabric 1 which is obtained
by subjecting the starting spun-bonded nonwoven fabric to the hereinafter described
process is preferably 18.0 (gf/cm
2)/mm or less, more preferably 15.0 (gf/cm
2)/mm or less, in the interest of feel to the touch, and even more preferably 10.0
(gf/cm
2)/mm or less in terms of obtaining a pleasant feel to the touch like that of air-through
nonwovens. The lower limit of the compression characteristic value of the nonwoven
fabric 1 which is obtained by processing the starting spun-bonded nonwoven fabric
with a basis weight of 5 to 25 g/m
2 is not particularly limited. In view of manufacturing advantages, the lower limit
would be about 1.00 (gf/cm
2)/mm. It is noteworthy that it has been conventionally difficult to raise or otherwise
process a starting spun-bonded nonwoven fabric with a small basis weight of, e.g.,
5 to 25 g/m
2 to provide a processed nonwoven fabric having the above identified characteristic
value falling within the recited range without involving a great reduction in breaking
strength.
[0025] The filament fiber 2 making up the nonwoven fabric 1, which is the fiber making up
the starting spun-bonded nonwoven fabric, contains a thermoplastic resin as a main
component. Examples of the thermoplastic resin include polyolefin resins, polyester
resins, polyamide resins, acrylonitrile resins, vinyl resins, and vinylidene resins.
Examples of the polyolefin resins are polyethylene, polypropylene, and polybutene.
Examples of the polyester resins are polyethylene terephthalate and polybutylene terephthalate.
Examples of the polyamide resin include nylon. The vinyl resins are exemplified by
polyvinyl chloride. An example of the vinylidene resins is polyvinylidene chloride.
These resins may be used either individually or as a mixture of two or more thereof.
Modification products of these resins are useful as well. Conjugate fibers are also
useful as the filament fibers making up the nonwoven fabric 1. Examples of the conjugate
fibers include side-by-side conjugate fibers, sheath-core conjugate fibers, crimped
eccentric sheath-core conjugate fibers, and splittable conjugate fibers. Of the conjugate
fibers described, sheath-core conjugate fibers composed of a polyethylene sheath and
a polypropylene core are preferred in terms of softness of the resulting raised nonwoven
fabric. The filament fibers 2 may be those given a small amount of a colorant, an
antistatic, a lubricant, a hydrophilizing agent, or a like additive. The diameter
of the filament fiber 2 is desirably 5 to 30 µm, more desirably 10 to 20 µm, at a
stage before being subjected to the hereinafter described processing step.
[0026] The starting spun-bonded nonwoven fabric, from which the nonwoven fabric 1 is obtained,
is preferably made of a polypropylene resin, a kind of polyolefin resins, in the interest
of spinnability. The polypropylene resin is preferably a resin containing 5% to 100%,
more preferably 25% to 80%, by weight of at least one of a random copolymer, a homopolymer,
and a block copolymer in terms of surface smoothness, better feel to the touch, and
ease of breaking. While the recited propylene copolymer and homopolymer may be used
as a mixture thereof or combined with other resins, a mixture of a propylene homopolymer
and a propylene random copolymer is preferred in terms of strength against being broken
when spun. Fibers made of the mixture of a propylene homopolymer and a propylene random
copolymer have reduced crystallinity. Therefore, raised fibers per se feel soft and
comfortable to the skin and yet retain strength when converted to the form of nonwoven
fabric. On being raised, the fibers are easily broken at fusion bonds (e.g., debossed
or otherwise fused portions), so that the fibers are not debonded at the bonds, such
as debossed fusion bonds. As a result, the raised fibers are short enough not to form
pills and to provide a good appearance. Furthermore, such fibers have a broad range
of melting point, which provides good sealability. A random copolymer including a
propylene unit as a main unit and ethylene or an α-olefin as a comonomer is preferred,
with an ethylene-propylene copolymer resin being more preferred. From the same viewpoint,
it is preferred for the polypropylene resin to contain 5% by weight or more, more
preferably 25% by weight or more, of an ethylene-propylene copolymer resin. The ethylene-propylene
copolymer resin preferably has an ethylene content of 1% to 20% by weight. The ethylene
content is more preferably 3% to 8% in term of non-stickiness, drawability, non-shedding
of fuzz, and breaking strength retention. From the environmental consideration, the
polypropylene resin preferably contains 25% by weight or more, more preferably 50%
by weight or more, of a recycled polypropylene resin. The same applies when the nonwoven
fabric 1 starts from a complex nonwoven fabric composed of a spun-bonded layer and
a melt-blown layer.
[0027] The individual fusion bonds 3 formed by debossing preferably have an area of 0.05
to 10 mm
2 , more preferably 0.1 to 1 mm
2, in terms of feel to the touch and processability. The number of the fusion bonds
3 is preferably 10 to 250 per square centimeter, more preferably 35 to 65 per square
centimeter. The center-to-center distance between X-directionally adjacent fusion
bonds 3 is preferably 0.5 to 10 mm, more preferably 1 to 3mm, and that between Y-directionally
adjacent fusion bonds is preferably 0.5 to 10 mm, more preferably 1 to 3mm.
[0028] The fusion bonds 3 may be formed by discretely applying heat and pressure using a
debossing roller combined with a flat roller, ultrasonic fusion bonding, or discretely
applying hot air to cause fusion bonding. The fusion bonds 3 are preferably formed
by applying heat and pressure in terms of ease of breaking the fibers. The fusion
bond 3 is not particularly limited in shape and may have a circular, a rhombic, a
triangular, or a like shape. The fusion bonds 3 preferably have a total area ratio
of 5% to 30% per side. The total area ratio of the fusion bonds 3 is more preferably
10% to 20% per side to prevent pilling.
[0029] The nonwoven fabric 1 of the present embodiment is obtained from a spun-bonded nonwoven
fabric made of filament fibers 2. In the nonwoven fabric 1, the filament fibers 2
are partly broken to form fibers 20 each of which has a fixed end 20a fixed at the
fusion bond 3 with the other end 20b free. The fibers 20 include fibers 21 the free
end of each of which has a thickened tip. The thickened tip of the fibers 21 preferably
has a flattened cross-section, i.e., an oval or a squeezed circular cross-section.
Such raised fibers have a soft tip and provide a nonwoven fabric non-irritant to the
skin. As shown in Figs. 1, the fibers 20 only one end 20a of each of which is fixed
at the fusion bond 3 include the fibers 21 each having a thickened free end 20b at
the other end and fibers 22 each having a non-thickened free end 20b at the other
end. As used herein, the term "free end" means the end opposite to the fixed end 20a
fixed at the fusion bond 3. In other words, the term "free end" means the tip of each
broken fiber. Whether or not the free end 20b is thickened is judged by measuring
the diameters of a fiber by the method below and calculating the increase ratio of
the tip diameter of the fiber.
Method for measuring fiber diameter:
[0030] A specimen measuring 2 cm in X direction and 2 cm in Y direction is cut out of a
nonwoven fabric 1 to be evaluated using a sharp razor in an environment of 22°C and
65% RH as shown in Fig. 5(a). The specimen is folded along a folding line Z that passes
through a plurality of fusion bonds 3 in the X direction as shown in Fig. 5(b). As
shown in Fig. 5(c), the folded specimen is fixed onto an aluminum mount for a scanning
electron microscope (SEM) via double-sided carbon tape. Ten fibers 20 only one end
20a of each of which is fixed at the fusion bond 3 are randomly chosen from an SEM
image at a magnification of about 750 times. The vicinity of the free end of each
chosen fiber 20 is micrographed, and the diameter of the fiber 20 is measured at a
position 120 µm away from the tip of the free end 20b on the micrograph (see Fig.
2) to give the diameter 21a of the fiber 20 at other than the free end 20b. The line
along which the diameter 21a is measured is translated toward the free end 20b until
it reaches a position where the fiber 20 is thickest between the tip of the free end
20b and a position 20 µm away from the tip, and the diameter of the fiber 21 is measured
along the line to give the diameter 21b of the fiber 21 at the free end 20b. Even
when the tip of a fiber has a flattened shape and does not look thick at some viewing
angles, the diameter 21b is measured on the micrograph.
[0031] The fiber 21 with a thickened free end 20b is defined to be a fiber, out of the randomly
chosen ten fibers 20, having an increase ratio of a tip diameter of 15% or more, the
increase ratio being calculated from the diameter 21b (the diameter at the free end
20b) and the diameter 21 a (the diameter at other than the free end 20b) according
to formula (1) below. The increase ratio is preferably 20% or more, more preferably
25% or more, from the standpoint of avoiding fiber break between adjacent fusion bonds
3 (excluding the boundaries between a fusion bond 3 and the fiber, i.e., in the region
where the fiber retains the fibrous form), minimizing reduction in breaking strength,
and obtaining pleasant feel to the touch.

[0032] To obtain a good balance between feel to the touch and breaking strength, the ratio
of the fibers 21 having a thickened free end 20b to the total number of fibers 20
only one end (20a) of each of which is fixed at the fusion bond 3 (i.e., the sum of
the fibers 21 with a thickened free end 20b and the fibers 22 whose free end 20b is
not thickened) is preferably 20% or more, more preferably 30% or more, even more preferably
40% or more. The ratio of the fibers 21 with a thickened free end 20b is obtained
by calculating the increase ratio of fiber tip diameter for each of the randomly chosen
ten fibers 20 on their SEM image (about 750X) as described above with respect to the
measurement of fiber diameter and calculating the ratio of the fibers 21 with a thickened
free end 20b.
The nonwoven fabric 1 contains fibers cut in the peripheral portion of the fusion
bonds. When a peripheral portion of a randomly chosen fusion bond 3, specifically
a portion sandwiched between lines 100 µm inwardly and outwardly away from the boundary
line between the fusion bond 3 and the filament fibers 2 is observed under an electron
microscope, and the number of the signs of fibers' having been cut (discontinuities
between a fiber segment having been debossed and therefore having a collapsed shape
and a fiber segment not having been debossed and therefore remaining in a fibrous
shape) is counted. If there are many fiber discontinuities, then that means that the
nonwoven fabric has only the fibers on the very surface raised and will exhibit high
breaking strength for the amount of fiber raising. From this viewpoint, the number
of such discontinuities is preferably at least 3, more preferably 5 to 15 per fusion
bond.
[0033] As shown in Fig. 1, the nonwoven fabric 1 has loop fibers 23 projecting in loop form
between fusion bonds 3. The term projecting "loop fiber 23" as used herein denotes
a fiber having no free end 20b and projecting at least 0.5 mm away from the folding
line Z when observed in the manner shown in Fig. 5(c) as in the measurement of fiber
diameter. The term "loop fiber 23" as used in the present embodiment refers to the
above described projecting loop fiber. The fibers constituting the nonwoven fabric
1 of the present embodiment include the fibers 20 only one end of each of which is
fixed at the fusion bond 3 and the loop fibers 23 projecting between fusion bonds
3, the fibers 20 including the fibers 21 with a thickened free end 20b and the fibers
22 with a non-thickened free end 20b. In order for the nonwoven fabric 1 not to feel
uncomfortably scratchy and to have improved feel to the touch, the ratio of the loop
fibers 23 to the total number of the fibers 20 only one end of each of which is fixed
at the fusion bond 3 and the loop fibers 23 is preferably less than 50%, more preferably
less than 45%, and even more preferably less than 40%. The ratio of the loop fibers
23 is obtained in the above described measurement of fiber diameter as follows. Ten
fibers are chosen at random on an SEM image at about 50X. Fibers 20 having only one
end 20a fixed at the fusion bond 3 (fibers 21 with a thickened free end 20b + fibers
22 with a non-thickened free end 20b) and loop fibers 23 are extracted from the 10
fibers, and the ratio of the loop fibers 23 to the total number of the fibers 21,
22, and 23 is calculated. The ratio is obtained for a total of ten points on the respective
SEM images taken per sample, and an average of the ten measurements is calculated.
When the randomly chosen ten fibers include one loop fiber 23, the loop fiber 23 is
counted as one.
[0034] Fibers having relatively high freedom fill the interfiber spaces in the nonwoven
fabric 1 to make the surface less rough and smoother. While a broader distribution
(distribution index) of fiber diameter is more desirable, a sufficiently satisfactory
effect on feel to the touch is obtained with a distribution of 0.33 or greater. A
more satisfactory effect is obtained with a distribution of 0.35 or greater. There
is no particular upper limit of the fiber diameter distribution (distribution index),
a preferred upper limit is 100. A more preferred fiber diameter distribution (distribution
index) is 0.35 to 0.9. As used herein, the term "fiber diameter distribution (distribution
index)" refers to the distribution (distribution index) of the diameter of all the
fibers constituting the nonwoven fabric 1, i.e., all of the fibers 20 only one end
20a of each of which is fixed at the fusion bond 3, the loop fibers 23, and fibers
each having both ends thereof fixed at the respective fusion bonds 3 and not projecting
in loop form (fibers not having been influenced by the hereinafter described processing
treatment). The fiber diameter distribution (distribution index) is determined as
follows.
Method for determining fiber diameter (method for determining fiber diameter distribution
(distribution index)):
[0035] A specimen measuring 2 cm in X direction and 2 cm in Y direction is cut out of a
nonwoven fabric 1 to be evaluated using a sharp razor in an environment of 22°C and
65% RH. The specimen (not folded) is fixed onto an aluminum mount for a scanning electron
microscope (SEM) via double-sided carbon tape. Ten fibers are randomly chosen from
an SEM image at a magnification of about 750X, and the diameter of each fiber is measured
at other than the free end 20b. When the starting nonwoven fabric from which the nonwoven
fabric 1 is obtained is a complex nonwoven fabric composed of a spun-bonded layer
and a melt-blown layer, the fibers should be chosen not from the melt-blown layer
but the spun-bonded layer. The diameters of the ten fibers are measured on a single
aluminum mount as described above, and an average d
ave is obtained from the resulting fiber diameters d
1 to d
10 of the ten fibers. A distribution of the randomly chosen ten fibers' diameters is
calculated from the resulting 10 fibers' diameters d1 to d10 and their average value
d
ave according to formula (2) below. The measurements are in micrometers with a resolution
of 0.1 µm. A distribution of ten fibers' diameters is determined for six specimens
on the respective aluminum mounts per sample (nonwoven fabric 1), and an average of
the six distributions of the ten fibers' diameters as calculated according to formula
(3) below is the fiber diameter distribution of the nonwoven fabric 1. The VARPA function
in Microsoft's spreadsheet software, Excel 2003 is used in the computation of the
ten fibers' diameter distribution.

[0036] The number of the raised fibers of the nonwoven fabric 1 is preferably 8 or greater,
more preferably 12 or greater, per centimeter in terms of good feel to the touch and
100 or fewer per centimeter in terms of sufficient breaking strength, more preferably
40 or fewer per centimeter in the interest of non-fuzzy appearance. The number of
raised fibers is measured as follows.
Method for measuring the number of raised fibers:
[0037] Fig. 6 schematically illustrates how to count the number of raised fibers out of
the fibers constituting the nonwoven fabric 1 in an environment of 22°C and 65% RH.
A piece measuring 20 cm by 20 cm is cut out of the nonwoven fabric to be evaluated
with a sharp razor and folded with the raised side out to make a specimen 104 as shown
in Fig. 6(a). The specimen 104 is placed on a black sheet of A4 size. Another black
sheet of A4 size having a hole 107 measuring 1 cm (vertical) by 1 cm (horizontal)
is put thereon as shown in Fig. 6(b) such that the folded edge 105 of the specimen
104 may be seen through the hole 107 of the upper black sheet as shown. The two black
sheets are of KENRAN KURO (ream weight: 265 g) available from Fujikyowa Seishi K.K.
A 50 g weight is put on the upper sheet at a position 5 cm outward from each lateral
side of the hole 107 along the folded edge 105 to ensure that the specimen 104 is
completely folded. Then, as shown in Fig. 6(c), the specimen 104 seen through the
hole 107 is observed using a microscope (VHX-900 from Keyence) at a magnification
of 30 times. An imaginary line 108 is drawn in the micrograph in parallel to and 0.2
mm above the folded edge 105 of the specimen 104. The number of the fibers projecting
above the imaginary line 108 per centimeter is counted. The measurement is taken at
a total of 9 points per sample nonwoven fabric. The average (rounded off to the whole
number) of the nine measurements is taken as the number of raised fibers.
[0038] In counting the number of raised fibers, when there is a fiber intersecting the imaginary
line 108 (0.2 mm above the folded edge 105) twice, like the fiber 106a shown in Fig.
6(c), that fiber is counted as two. More concretely, the specimen shown in Fig. 6(C)
has four fibers intersecting the imaginary line 108 once and one fiber 106a intersecting
the imaginary line 108 twice. So, the number of the raised fibers is six, the fiber
106a intersecting twice being counted as two.
[0039] From the viewpoint of improving the feel to the touch of the nonwoven fabric 1, it
is preferred that the raised fibers (the fibers intersecting the imaginary line 108)
have a smaller average diameter than the surface fibers at the non-raised site on
the same side (fibers not intersecting nor reaching the imaginary line 108). As used
herein, the term "average (fiber) diameter" refers to an average of diameters measured
at 12 points of each of a raised fiber and a non-raised fiber using a microscope (an
optical microscope, an SEM, etc.). It is preferred for better feel to the touch that
the diameter of a raised fiber be 40% to 97%, more preferably 40% to 90%, of the diameter
of a non-raised fiber.
[0040] In order for the nonwoven fabric 1 to have pilling resistance, resistance to fuzz
shedding, and a soft-looking good appearance, the height of the raised fiber is preferably
1.5 mm or less, more preferably 0.8 mm or less. While a smaller height is more favorable
from the above standpoint, sufficiently satisfactory feel to the touch will be obtained
with a height of 0.2 mm or more. From the standpoint of providing breaking strength
as well as the above standpoint, it is more preferred that the height of the raised
fibers be 1.5 mm or less and that the number of the raised fibers be 8 or more per
centimeter. It is also preferred in terms of pleasant feel to the touch with less
cling to the skin that the height of the raised fibers be 0.5 mm or less and that
the number of the raised fibers be 15 or more per centimeter. As used herein, the
term "height of a fiber" means the height of a fiber measured in its natural relaxed
state without being pulled unlike the measurement of the length of a fiber. A raised
fiber tends to have a greater height when it has a larger length or higher stiffness.
The height of a raised fiber is measured as follows.
[0041] The height of a raised fiber is measured at the same time of measuring the number
of raised fibers. Specifically, as shown in Fig. 6(c), the inside of the hole 107
is observed, and lines are drawn in parallel with the folded edge 105 at an interval
of 0.05 mm away from the folded edge 105 until there are no more intersecting raised
fibers. Then one of the parallel lines is selected which intersects half as many raised
fibers as the number of the raised fibers as determined by the above described method
(the fibers intersecting the imaginary line 108 drawn 0.2 mm above the folded edge
105). The distance from the folded edge to the thus selected line is taken as the
raised fiber height. Three specimens cut out of the nonwoven fabric sample to be evaluated
are evaluated at tree positions per specimen to provide a total of nine measurements,
which are averaged to give the height of raised fibers of the sample.
[0042] In addition to the above discussed height and number of raised fibers, it is preferred
for the nonwoven fabric 1 to have a bulk softness of 8.0 cN or less in terms of flexibility
and excellent feel to the touch. The bulk softness is more preferably 0.5 to 3.0 cN
in terms of providing pliable fabric like baby clothes. Bulk softness is measured
by the following method.
Method for measuring bulk softness:
[0043] A specimen measuring 30 mm along the CD and 150 mm along the MD is cut out of the
nonwoven fabric 1 in an environment of 22°C and 65% RH. Both longitudinal ends of
the specimen are joined with an overlap, and the overlap is stapled at both longitudinal
ends thereof to make a cylinder of 45 mm in diameter. Each of the staples is affixed
in parallel with the MD. The cylindrical specimen is set upright on the mount of a
tensile tester (Tensilon tensile tester RTA-100, supplied by Orientec) and axially
compressed by a compression plate substantially parallel with the mount at a rate
of 10 mm/min. The maximum load applied during the compression is recorded as a bulk
softness in the CD. A cylindrical specimen is prepared and tested in the same manner,
except for exchanging the CD for the MD to determine a bulk softness in the MD. The
measurement is taken in duplicate for each direction. The average of the bulk softness
in the CD and that in the MD is taken as a bulk softness of the nonwoven fabric 1.
[0044] Internally or externally (by coating) adding a softener to the starting spun-bonded
nonwoven fabric from which the nonwoven fabric 1 is obtained is effective to bring
out the effects of the invention. Useful softeners include wax emulsions, reactive
softeners, silicones, and surfactants. Amino-containing silicones, oxyalkylene-containing
silicones, and surfactants are particularly preferred. Examples of the surfactants
include anionic surfactants, such as carboxylic acid salts, sulfonic acid salts, sulfuric
ester salts, and phosphoric ester salts (especially alkylphosphoric ester salts);
nonionic surfactants, such as sorbitan fatty acid esters, polyhydric alcohol fatty
acid monoesters (e.g., diethylene glycol monostearate, diethylene glycol monooleate,
glycerol monostearate, glycerol monooleate, and propylene glycol monostearate), N-(3-oleyloxy-2-hydroxypropyl)diethanolamine,
polyoxyethylene hydrogenated castor oil, polyoxyethylene sorbitol beeswax, polyoxyethylene
sorbitan sesquistearate, polyoxyethylene monooleate, polyoxyethylene sorbitan sesquistearate,
polyoxyethylene glycerol monooleate, polyoxyethylene monostearate, polyoxyethylene
monolaurate, polyoxyethylene monooleate, polyoxyethylene cetyl ether, and polyoxyethylene
lauryl ether; cationic surfactants, such as quaternary ammonium salts, amine salts,
and amines; and amphoteric surfactants, such as aliphatic derivatives of secondary
or tertiary amines containing a carboxylate, sulfonate, or sulfate group and aliphatic
derivatives of heterocyclic secondary or tertiary amines. If desired, a known agent
may be added to the softeners as a secondary additive (a trace component).
The softener when used in the invention exhibits particularly high effects in providing
good feel to the touch, little shedding of fuzz, low surface friction against human
skin, and high breaking strength.
When combined with the random copolymer described in paragraph [0021], the softener
produces further enhanced effects. In particular, the softener is effective in reducing
the slimy texture of the raised fibers caused by the random copolymer thereby to provide
a comfortable dry feel to the touch.
[0045] In the case when the nonwoven fabric 1 is obtained from a hereinafter described complex
nonwoven fabric composed of a plurality of spun-bonded layers and a melt-blown layer,
such as a spun-bonded/melt-blown/spun-bonded complex nonwoven fabric or a spun-bonded/spun-bonded/melt-blown/spun-bonded
complex nonwoven fabric, the softener is preferably internally incorporated into only
one spun-bonded layer, or the softener may be incorporated into all the spun-bonded
layers. When the softener is incorporated into one spun-bonded layer, it is preferred
for providing good feel to the touch and high breaking strength that the hereinafter
described processing treatment for forming raised fibers with a thickened free end
be performed on the softener-added side of the starting complex nonwoven fabric. Thus,
a complex nonwoven fabric composed of a spun-bonded layer and a melt-blown layer is
preferred to a single-layered spun-bonded nonwoven fabric as the starting nonwoven
fabric from which the nonwoven fabric 1 is to be obtained in the interests of easy
control of the balance between feel to the touch and the breaking strength of the
resulting nonwoven fabric 1.
[0046] A preferred method for making the nonwoven fabric 1 of the invention will then be
described with reference to Figs. 3 and 4. An apparatus preferably used in the production
of the nonwoven fabric 1 is largely divided into a preprocessing part 4 and a raising
part 5 downstream of the preprocessing part 4.
[0047] As shown in Fig. 3, the preprocessing part 4 has a steel-to-steel matched embossing
unit 43 composed of a pair of rollers, one having a plurality of projections 410 and
the other having a plurality of recesses 420 intermeshing with the projections 410
on their peripheral surfaces. As shown, the steel/steel matched embossing unit 43
is configured such that the projections 410 formed on the peripheral surface of the
roller 41 and the recesses 420 formed on the peripheral surface of the roller 42 are
matched. The projections 410 are uniformly and regularly arranged in both the axial
direction and the circumferential direction of the roller 41. The pair of rollers
41 and 42 rotate in mesh with each other on being driven by a driving force transmitted
from an unshown driving means to the axis of rotation of either one of them. The preprocessing
part 4 also has transport rollers upstream and downstream from the steel/steel matched
embossing unit 43, for example, rollers 44 and 45 as shown in Fig. 3.
[0048] Each projection 410 of the roller 41 preferably has a height (distance from the peripheral
surface of the roller 41 to the top of the projection 410) of 1 to 10 mm, more preferably
2 to 7 mm. The distance between adjacent projections 410 (the pitch of the projections
410) in the axial direction is preferably 0.01 to 20 mm, more preferably 1 to 10 mm,
and that in the circumferential direction is preferably 0.01 to 20 mm, more preferably
1 to 10 mm. The shape of the top of each projection 410 of the roller 41 is not particularly
limited and may be, for example, a circular, polygonal, or oval shape. The area of
the top of each projection 410 is preferably 0.01 to 500 mm
2, more preferably 0.1 to 10 mm
2. The individual recesses 420 of the roller 42 are arranged at positions corresponding
to the individual projections 410 of the roller 41. The depth of engagement between
the projections 410 of the roller 41 and the recesses 420 of the roller 42 (the length
of the overlap between the projection 410 and the recess 420) is preferably 0.1 to
10 mm, more preferably 1 to 5 mm.
[0049] As shown in Fig. 4, the raising part 5 includes an engraved roller 51 having projections
510 on its peripheral surface and transport rollers 52 and 53 upstream and downstream,
respectively, of the engraved roller 51 for transporting a starting nonwoven fabric
10. The engraved roller 51 is rotated by a driving force transmitted from an unshown
driving means to its axis of rotation.
[0050] The height of each projection 510 of the engraved roller 51 (the distance from the
peripheral surface of the engraved roller 51 to the top of the projection 510) is
preferably 0.001 to 3 mm, more preferably 0.001 to 0.1 mm. The distance between adjacent
projections 510 (the pitch of the projections 510) in the axial direction is preferably
0.1 to 50 mm, more preferably 0.1 to 3 mm, and that in the circumferential direction
is preferably 0.1 to 50 mm, more preferably 0.1 to 3 mm. The shape of the top of each
projection 510 of the roller 51 is not particularly limited and may be, for example,
a circular, polygonal, or oval shape. The area of the top of each projection 510 is
preferably 0.001 to 20 mm
2, more preferably 0.01 to 1 mm
2.
[0051] The apparatus having so configured preprocessing part 4 and raising part 5 operates
as follows. A starting nonwoven fabric 10 of the nonwoven fabric 1, for example, a
spun-bonded nonwoven fabric is unwounded from an unshown stock roll and fed by the
transport rollers 44 and 45 into the nip of the pair of rollers 41, 42 of the steel/steel
matched embossing unit 43. In the preprocessing part 4, the starting nonwoven fabric
10 is nipped between the pair of rollers 41, 42 to be given damage as shown in Fig.
3. In order not to cause the fibers of the spun-bonded nonwoven fabric to fuse and
bond to one another during giving damage, it is preferred that the pair of rollers
41, 42 of the steel/steel matched embossing unit 43 not be positively heated or be
at a temperature not higher than the melting point of the component the melting temperature
of which is lower than any other components of the fibers making up the starting nonwoven
fabric 10, more preferably at a temperature lower than that melting point by 70°C
or more.
[0052] The damaged starting nonwoven fabric 10' is transported by the transport rollers
52, 53 to the engraved roller 51 having the projections 510 on its peripheral surface.
In this raising part 5, a surface of the damaged starting nonwoven fabric 10' is processed
by the engraved roller 51. As a result, part of the filament fibers 2 making up the
spun-bonded nonwoven fabric are broken to provide a nonwoven fabric 1 having fibers
20 only one end 20a of each of which is fixed at the fusion bond 3 of the spun-bonded
nonwoven fabric (see Fig. 1). In order to effectively break part of the filament fibers
2 to effectively form the fibers 20 shown in Fig. 1, the direction of rotation of
the engraved roller 51 is preferably the reverse of the transport direction of the
starting nonwoven fabric 10', and the rotational speed of the engraved roller 51 is
preferably 0.3 to 10 times the transport speed of the starting nonwoven fabric 10'.
In the case when the engraved roller 51 rotates in the same direction as the transport
direction of the starting nonwoven fabric 10', the rotational speed is preferably
1.5 to 20 times the transport speed of the starting nonwoven fabric 10'. As used herein,
the term "rotational speed" of the engraved roller 51 is the circumferential speed
measured on the periphery of the engraved roller 51.
[0053] In order to more effectively break part of the filament fibers 2 to more effectively
form the fibers 20 shown in Fig. 1, it is preferred that the position of the transport
roller 53 be higher than that of the engraved roller 51 as shown in Fig. 4 so that
the damaged starting nonwoven fabric 10' may be partially wrapped around the engraved
roller 51 at a wrap angle α of 10° to 180°. To reduce width reduction of the nonwoven
fabric, the wrap angle α is more preferably 30° to 120°C.
[0054] In making a nonwoven fabric 1 having the fibers 20 only the end 20a of which is fixed
at the fusion bond 3 on both sides thereof, the starting nonwoven fabric 10' having
been processed with the engraved roller 51 on one side thereof is further processed
with another engraved roller 51 on the opposite side (reverse side) thereof.
[0055] The inventors consider that the mechanism of the formation of the above-identified
fibers 20 is as follows. On stretching the spun-bonded nonwoven fabric (starting nonwoven
fabric 10) using the steel/steel matched embossing unit 43, a weakened point is formed
in the fusion bonds 3 of the spun-bonded nonwoven fabric (starting nonwoven fabric
10). Subsequently, a filament fiber 2 on the very surface of a fusion bond 3 is cut
by the engraved roller 51 at the weakened point to provide a fiber broken at the fusion
bond 3. The fiber cut at the fusion bond 3, the inventors assume, is the fiber 21
the free end 20b of which is thickened. The inventors also assume that a filament
fiber 2 is pulled apart from the weakened point of the fusion bond 3 by the engraved
roller 51 and becomes a loop fiber 23 projecting into a loop form between the fusion
bonds 3. The inventors assume that a filament fiber 2 is cut between the fusion bonds
3 by the engraved roller 51 to become a fiber 22 the free end 20b of which is not
thickened. The nonwoven fabric produced by the aforementioned preferred method for
producing the nonwoven fabric 1 according to the invention is characterized in that
the ratios of the loop fibers 23 and the non-thick-tipped fibers 22 are smaller than
those of the nonwoven fabrics obtained by conventional raising/napping techniques.
If there are many non-thick-tipped fibers 22 as in the nonwoven fabrics obtained by
conventional raising techniques, the nonwoven fabric would break between fusion bonds
3 (for example, between debossed portions), which can cause the nonwoven fabric to
tear or bore a hole between the fusion bonds 3. Hence, the aforementioned characteristic
allows for raising fibers without damaging the base fibers to provide a nonwoven fabric
retaining high breaking strength. If a nonwoven fabric with no weakened points is
subjected to the raising process, the fibers will not easily be raised unless a strong
abrading force is applied to the surface of the fibers, which will damage not only
the fibers on the very surface but the base fibers of the starting nonwoven fabric,
only to provide a nonwoven fabric liable to tear on account of the failure to retain
the strength. Because a nonwoven fabric obtained by the above described preferred
method for producing the nonwoven fabric 1 of the invention has a smaller ratio of
the non-thick-tipped fibers 22, a breaking strength is retained. When used as an outer
cover material of, for example, a disposable pull-on diaper, the nonwoven fabric of
the invention provides an advantage of resistance against being pierced or broken
by a finger when the diaper is pulled up in fixing onto a wearer (high piercing strength).
When used in side seals of a disposable pull-on diaper which are to be torn apart
in removing the diaper from the wearer, the nonwoven fabric of the invention is easy
to torn along the side seals without being torn in the lateral direction of the diaper.
If a starting nonwoven fabric having no weakened points is subjected to the raising
process, the fibers tend to be just debonded and liberated from the fusion bonds.
As a result, the number of the raised fibers tends to decrease, and the height of
the raised fibers tends to increase. This can lead to problems, such as fuzz formation.
[0056] As a result of the processing by the steel/steel matched embossing unit 43, the fibers
are stretched between fusion bonds, and weakened points are predominantly formed around
the periphery of the fusion bonds. Formation of the weakened points is controllable
by the depth of engagement between the meshing rollers 41 and 42 of the steel/steel
matched embossing unit 43. A weakened point is easily formed in a region where the
bond-to-bond length of fibers is short in the stretch direction. The thus formed weakened
point provides a vulnerable region, where the fiber is easily cut at the weakened
point on being processed in the raising part 5. As a result, there is obtained to
advantage a raised nonwoven fabric having short raised fibers, excellent feel to the
touch, seemingly unnoticeable fuzz, resistance to pilling, and high breaking strength.
At the same time, stretching the fibers between fusion bonds 3 makes the fibers finer
and also softens the fusion bonds 3, whereby a nonwoven fabric with good feel to the
touch is obtained. On being processed with the steel/steel matched embossing unit
43, the fibers are drawn and made finer to have an increased fiber-to-fiber distance,
leading to improved air permeability. In addition to this, the raising process in
the raising part 5 reduces the bulk density of the raised surface fibers. As a result,
the raised nonwoven fabric has improved air permeability as compared with a non-raised
nonwoven fabric having the same basis weight. The air permeability of a nonwoven fabric
is preferably increased to 1.2 to 2.0 times, more preferably 1.3 to 1.8 times, that
of the starting nonwoven fabric by combining fiber stretch and raising as described.
Air permeability is represented by a reciprocal of an air resistance determined using
an automatic air permeability tester KES-F8-AP1 from Kato Tech Co., Ltd. The resulting
nonwoven fabric preferably has an air permeability of 24 m/(kPa·s) or more. A spun-bonded
complex nonwoven fabric containing no melt-blown layer, such as a spun-bonded/spun-bonded
nonwoven fabric, is preferably used as a starting nonwoven fabric 10 having good feel
to the touch and good air permeability.
[0057] The effect and advantage of using the nonwoven fabric 1 of the above discussed embodiment
will be described.
The nonwoven fabric 1 of the present embodiment has part of the filament fibers 2
broken to form fibers 20 only one end 20a of each of which is fixed at the fusion
bond 3. The fibers 20 impart fluffiness to the whole nonwoven fabric 1. Since the
filament fibers 2 are broken only partly, the nonwoven fabric 1 still retains high
breaking strength similarly to the starting spun-bonded nonwoven fabric. The nonwoven
fabric 1 of the present embodiment contains fibers 21 each having a thickened free
end 20b as shown in Fig. 1. The presence of the fibers 21 with a thickened free end
20b makes the nonwoven fabric 1 feel pleasant with no itchy or scratchy feeling on
the skin. Furthermore, the fibers 21 with a thickened free end 20b tend to bow their
free end 20b to make the nonwoven fabric 1 feel smooth and pleasant to the skin.
Spun-bonded nonwoven fabrics or spun-bonded complex nonwoven fabrics essentially lack
a fluffy feel and are inferior to air-through nonwoven fabrics in feel to the touch.
According to the present embodiment, the nonwoven fabric 1 exhibits greatly improved
feel to the touch in terms of Japanese paper-like smoothness essential to a spun-bonded/melt-blown
complex nonwoven fabric combined with a fluffy feel.
[0058] The nonwoven fabric 1 is suited chiefly for use as a member making up absorbent articles,
such as disposable diapers and sanitary napkins. Suitable members include a topsheet,
a backsheet, and an outer cover-forming sheet. The nonwoven fabric 1 is also suited
as a cleaning sheet. The application of the nonwoven fabric 1 will be described more
concretely taking a disposable diaper for instance.
[0059] As shown in Fig. 7, a disposable pull-on diaper 100 includes an absorbent assembly
50 containing an absorbent member 40 and an outer cover 60 located on the non-skin
contact side of the absorbent assembly 50 and having the absorbent assembly 50 fixed
thereto.
As shown in Fig. 8, the absorbent assembly 50 includes a liquid permeable topsheet
70, a liquid impermeable (or water repellent) backsheet 80, and the liquid retentive
absorbent member 40 interposed between the sheets 70 and 80. The absorbent assembly
50 is substantially oblong.
The outer cover 60 has a rear portion A to be located on the back side of a wearer,
a front portion B to be located on the front side of a wearer, and a crotch portion
C located between the rear portion A and the front portion B and adapted to be worn
about the crotch of the wearer. Both lateral side edges 6a of the rear portion A and
both lateral side edges 6b of the front portion B are joined together to form a pair
of side seals (not shown), a pair of leg openings (not shown), and a waist opening
(not shown). The outer cover 60 has an outer sheet 62 forming the exterior surface
of the diaper and an inner sheet 61 located on and partly joined to the skin facing
of the outer sheet 62. The outer cover 60 has waist elastic members 63 and leg elastic
members 64 disposed between the two sheets 61 and 62 to form gathers along a waist
portion forming the waist opening and along leg portions 6d forming the leg openings.
[0060] As shown in Fig. 7, the absorbent assembly 50 extends to straddle the rear portion
A and the front portion B, with its longitudinal ends inward from the corresponding
longitudinal ends of the outer cover 60. As shown in Fig. 8, the absorbent assembly
50 is bonded on the non-skin facing side of its backsheet 80 to the skin facing side
of the inner sheet 61 of the outer cover 60 via an adhesive or by heat sealing, ultrasonic
sealing, or otherwise.
As shown in Fig. 7, the absorbent assembly 50 has a pair of side cuffs 55, 55 formed
of a liquid impermeable or water repellent and breathable material along both lateral
side portions thereof. A side-cuff-forming elastic member 56 is fixed in its stretched
state along near the free edge of each side cuff 55. While worn, each side cuff 55
rises with its free edge up to block the lateral flow of bodily exudates. As shown
in Fig. 8, a side portion 55a with a prescribed width of the side cuff-forming sheet
extending laterally outward from the absorbent assembly 50 is folded over the non-skin
facing side of the absorbent member 40 and fixed between the absorbent member 40 and
the backsheet 80. The side portion 55a may be fixed between the backsheet 30 and the
outer cover 60.
[0061] The nonwoven fabric according to the invention is preferably used as the outer sheet
62. The raised nonwoven fabric of the invention is also useful as the topsheet 70,
the backsheet 80, the side cuff-forming sheet, and the inner sheet 61. When these
members are formed of other than the nonwoven fabric of the invention, any materials
usually used in absorbent articles, such as disposable diapers, may be used. For example,
the topsheet 70 may be formed of liquid permeable nonwoven fabric, perforated film,
or a laminate thereof. The backsheet 80 may be formed of resin film or a laminate
composed of resin film and nonwoven fabric. The side cuff-forming sheet may be of
stretch film, nonwoven fabric, woven fabric, or a laminate sheet thereof. The inner
sheet 61 and the outer sheet 62 may be formed, e.g., of water repellent nonwoven fabric.
[0062] The absorbent member 40 may be of any type conventionally used in absorbent articles,
such as disposable diapers. For example, the absorbent member may be an aggregate
of fibrous materials, such as pulp, with or without a superabsorbent polymer incorporated
therein, the aggregate being wrapped in a wrapper, such as tissue or water pervious
nonwoven fabric.
The side cuff-forming elastic members 56, the waist elastic members 63, and the leg
elastic members 64 may be of any materials commonly used in absorbent articles, such
as disposable diapers. For example, extensible and contractible materials made of
natural rubber, polyurethane, a styrene-isoprene copolymer, a styrene-butadiene copolymer,
an ethylene-α-olefin copolymer (e.g., ethyl acrylate-ethylene copolymer), and so on
may be used.
[0063] The nonwoven fabric of the invention is not limited to the nonwoven fabric 1 of the
above discussed embodiment, and various changes and modifications can be added to
the nonwoven fabric 1.
[0064] For example, while the nonwoven fabric 1 of the present embodiment is prepared starting
from a spun-bonded nonwoven fabric as shown in Fig. 2, it may be obtained from a complex
nonwoven fabric composed of a spun-bonded layer and a melt-blown layer. In the case
of using the complex nonwoven fabric, the spun-bonded layer is preferably disposed
on the surface side and/or the reverse side of the melt-blown layer. In particular,
it is preferred that the spun-bonded/melt-blown complex nonwoven fabric contain at
least 25% by weight of an ethylene-propylene random copolymer resin (hereinafter "random
copolymer") and that the melt-blown layer be made of a propylene homopolymer resin
in terms of overall smoothness, improved feel to the touch, and fiber breakability
during raising process. A spun-bonded layer formed of a resin containing the random
copolymer, which is a soft layer, is preferably disposed as an outermost layer so
that the complex nonwoven fabric may have reduced bending stiffness and improved pliability.
From the standpoint of cost performance, a complex nonwoven fabric only the skin-contact
side of which is a spun-bonded layer made of the random copolymer-containing resin
is advantageous in that the properties providing a good feel to the touch (the properties
exhibited by the random copolymer-containing layer) and the properties providing breaking
strength may be performed by the respective sides to achieve efficient improvement
on feel to the touch. From the standpoint of environmental friendliness, the complex
nonwoven fabric is preferably made of a polypropylene resin containing at least 25%
by weight of a recycled polypropylene resin in place of the random copolymer.
Examples of the starting nonwoven fabrics used to provide the nonwoven fabric 1 include
nonwoven fabrics (e.g., a spun-bonded nonwoven fabric), complex nonwoven fabrics (e.g.,
a laminate obtained by joining a spun-bonded layer and a melt-blown layer by heat
debossing and a laminate obtained by joining a nonwoven fabric and an unconsolidated
web by heat application), and a nonwoven fabric obtained by consolidating 30 mm or
longer staple fibers by applying heat and pressure using a heat roller or through-air
thermal bonding, followed by debossing. The fibers constituting the nonwoven fabric
include single fibers, conjugate fibers (side-by-side or concentric or eccentric sheath/core
configuration), crimped fibers, heat shrunken fibers, heat extended fibers, and fibers
splittable on stretch. Single fibers are preferred for inexpensiveness. Composite
nonwoven fabrics composed of the nonwoven fabric described and another nonwoven fabric
or film joined together with an adhesive or by heat are also useful. In using a composite
nonwoven fabric, the raising may be carried out either before or after joining another
nonwoven fabric or film.
Because the raising process in the raising part 5 is carried out by rotating the engraved
roller 51 in the direction parallel to the running direction (MD) of the nonwoven
fabric, the degree of fiber orientation (MD/CD) is preferably 1.1 to 1.8, more preferably
1.2 to 1.5, so that the fibers are easily caught on the projections 510 to achieve
a large amount of fiber raising. The degree of fiber orientation is represented by
an MOR value determined on a square specimen measuring 95 mm in the MD and 95 mm in
the CD using a microwave molecular orientation analyzer MOA-6004 from Oji Scientific
Instruments. The determination was done in quintuplicate per sample to obtain an average
MOR value.
[0065] The nonwoven fabric produced using the above described apparatus has an advantage
over a flocked sheet, such as the one disclosed in patent literature 3, in that the
production does not involve the step of bonding separate fibers (flocks) to a base
nonwoven fabric using an adhesive or a like chemical so that the risk of adversely
affecting the skin caused by a chemical, such as an adhesive, is reduced. In addition
to this, there are no problems associated with a flocked sheet, such as fall-off of
flocks during use and resultant exposure of the adhesive layer. A spun-bonded nonwoven
fabric, one type of nonwoven fabrics used in absorbent articles, is thin and difficult
to make fluffy by a general raising process without the likelihood of being broken.
According to the production method using the above described apparatus, there is produced
a raised spun-bonded nonwoven fabric having a high raised fiber density and good feel
to the touch.
[0066] The method for making a nonwoven fabric according to the invention will then be described
based on its preferred embodiment with reference to the accompanying drawing.
In the following description, the directions of a nonwoven fabric are defined based
on the direction of constituent fibers. In general, the direction along the fiber
orientation direction is referred to as an MD or a longitudinal direction, and the
direction perpendicular to that direction is referred to as a CD or a transverse direction.
In what follows, the MD (longitudinal direction) of a nonwoven fabric is the transport
direction of the nonwoven fabric, which is the same as the direction of transporting
the nonwoven fabric by the rotation of rollers, and the CD (transverse direction)
of the nonwoven fabric is the same as the axial direction of the rollers.
Figs. 9 through 12 schematically illustrate an embodiment of a processing apparatus
used to carry out the method for making a nonwoven fabric according to the invention
(hereinafter simply referred to as the processing apparatus).
[0067] As shown in Fig. 9, the processing apparatus 1 of the present embodiment is largely
divided into a partial stretching part 2 and a raising part 3 downstream of the partial
stretching part 2.
[0068] The partial stretching part 2 is a part in which a nonwoven fabric 4 is stretched
in a plurality of regions. The partial stretching part 2 of the processing apparatus
1 according to the present embodiment has a pair of engraved rollers 21, 22 as shown
in Figs. 9 and 10. As used herein, the term "partial stretching" does not refer to
a generally practiced stretch process in which a nonwoven fabric is totally stretched
utilizing a difference in rotational speed between pairs of rollers but a process
resulting in the formation of stretched regions and non-stretched regions. The term
"non-stretched region" means a region of a nonwoven fabric that is not subjected to
stretching, and the expression "not subjected to stretching" is intended to mean "not
positively subjected to stretching".
[0069] In the paired engraved rollers 21 and 22, the roller 21 has projections 210 on its
peripheral surface, and the roller 22 has on its peripheral surface recesses 220 for
receiving the projections 210 of the roller 21 at positions corresponding to the projections
210. The paired engraved rollers 21 and 22 are cylindrical members made of metal,
such as an aluminum alloy or steel. The processing apparatus 1 of the present embodiment
has a steel-to-steel matched embossing unit 23 composed of the pair of engraved rollers
21 and 22 having the projections 210 and the recesses 220, respectively, on their
peripheral surface in meshing engagement with each other. As shown in Fig. 11, the
steel/steel matched embossing unit 23 is configured such that the projections 210
on the peripheral surface of the roller 21 and the recesses 220 on the peripheral
surface of the roller 22 are in matched engagement. The projections 210 are uniformly
and regularly arranged in both the axial direction and the circumferential direction
of the roller 21. The pair of rollers 21 and 22 rotate on being driven by a driving
force transmitted from an unshown driving means using unshown gears. A driving force
from the unshown driving means may be transmitted to only one of the two rollers 21
and 22, and the other roller is driven by the engagement of the rollers. However,
it is preferred to drive the two rollers not only by the engagement but by using gears
to transmit the driving force so that the nonwoven fabric may be stretched at the
centers of mutual grooves to accomplish effective partial stretch. The rotational
speed (peripheral velocity V2) of the paired rollers 21 and 22 is controlled by the
controller (not shown) of the processing apparatus 1. The peripheral velocity V2 is
obtained as a velocity of the circumference from the number of rotation of the rollers
taking [the outside diameter of the roller 21 - the depth of engagement D) as a diameter.
[0070] The shape of the individual projections 210 of the roller 21 when viewed from above
may be circular, square, elliptic, rhombic, or rectangular (oblong in the MD or the
CD) and is preferably circular in view of minimizing reduction in breaking strength
of the nonwoven fabric 4. The shape of the individual projections 210 when viewed
from the side may be trapezoidal, square, or convex and is preferably trapezoidal
in view of reduced abrasion during rotation. The bottom angle of a trapezoidal projection
preferably ranges from 70° to 89°.
[0071] In the partial stretching part 2, the nonwoven fabric 4 (i.e., the nonwoven fabric
before being processed) is preferably stretched to a mechanical stretch ratio of 1.05
to 20, more preferably 2 to 10, in every region to be stretched in order to obtain
high effects in improving flexibility and the like while retaining satisfactory breaking
strength after the stretching. As used herein, the term "mechanical stretch ratio"
means a value obtained from the engagement geometry between the projections 210 of
the roller 21 and the recesses 220 of the roller 22. The mechanical stretch ratio
of each stretched region is calculated according to the Math. 1 or Math. 2 described
below, wherein (see Fig. 11) P
1 is the distance between the tops of adjacent projections 210 (pitch P
1 of the projections 210) in the circumferential direction of the roller 21; P
2 is the distance between the tops of adjacent projections 210 (pitch P
2 of the projections 210) in the axial direction of the roller 21; D is the depth of
engagement between the individual projections 210 of the roller 21 and the individual
projections of the roller 22; A
1 is the length of the top of the individual projections 210 of the roller 21 measured
in the circumferential direction of the roller 21 (dot diameter A
1); and A
2 is the length of the top of the individual projections 210 of the roller 21 measured
in the axial direction of the roller 21 (dot diameter A
2). In the case when the projections 210 of the roller 21 and the projections of the
roller 22 are different in shape, the dot diameter A
1 is obtained as an average of the circumferential length of the top of the projections
of the roller 21 and that of the top of the projections of the roller 22. Similarly,
the dot diameter A
2 is obtained as an average of the axial length of the top of the projections of the
roller 21 and that of the top of the projections of the roller 22. In the cases where
the top of the projections (dots) has other than a rectangular shape (e.g., circular,
elliptic, or polygonal), the dot diameters A
1 and A
2 are obtained in the same manner. The mechanical stretch ratio thus calculated is
taken as the stretch ratio of the regions having the highest stretch ratio (the regions
via which the projection 210 of the roller 21 and the projection of the roller 22
come closest to each other), which is taken as the mechanical stretch ratio. The mechanical
stretch ratio is obtained in the same manner even when the stretching means is other
than the pair of rollers, such as a plate type or a caterpillar belt type stretching
means as described in
JP 2007-22066A.
[0072] Mechanical stretch ratio in circumferential direction:

[0073] Mechanical stretch ratio in axial direction:

[0074] It suffices that either one of the mechanical stretch ratios in the circumferential
and the axial directions satisfies the above recited range.
[0075] The pair of engraved rollers of the partial stretching part 2 are preferably designed
to achieve partial stretch processing on 10% to 80%, more preferably 40% to 80%, of
the total area of the nonwoven fabric 4 introduced therein, taking into consideration
minimizing reduction in breaking strength of the nonwoven fabric while attaining the
above recited range of mechanical stretch ratio. The plurality of stretched regions
of the nonwoven fabric 4 are parts stretched by the engagement between the individual
projections 210 of the roller 21 and the individual recesses 220 of the roller 22,
more specifically parts stretched between the edge 210a of the individual projections
210 of the roller 21 and the edge 220a (at which recessing starts) of the individual
recesses 220 of the roller 22 as shown in Fig. 11. The regions of the nonwoven fabric
that are applied to the top of the individual projections are less positively subject
to a stretching action. Accordingly, the total area of the stretched regions of the
nonwoven fabric is the area obtained by subtracting the total area of the top surface
of the projections 210 of the roller 21 and the total area of the bottom between adjacent
projections 210 of the roller 21 from the total area of the nonwoven fabric 4. In
evaluating the practical effect of the stretch process, the overall stretch ratio
of the nonwoven fabric is calculated based on the value obtained by multiplying the
area ratio of the regions to be stretched by the stretch ratio applied to these regions
and adding to the product the area ratio of the non-stretched regions (inclusive of
the regions that are not substantially stretched), the stretch ratio applied to the
non-stretched regions being 1. The stretch ratio applied to the regions to be stretched
of the nonwoven fabric includes the stretch ratio in the circumferential direction
(MD) and that in the rotational axial direction (CD). Accordingly, the overall stretch
ratio of the nonwoven fabric is calculated by formula (1):

[0076] Because the stretch ratio of the nonwoven fabric in the circumferential direction
(MD) varies with the nonwoven fabric feed rate, the term "stretch ratio of the nonwoven
fabric in the circumferential direction (MD)" as used herein denotes the value obtained
by multiplying the above-identified mechanical stretch ratio in the circumferential
direction by the ratio of the peripheral velocity of the roller 21 (or the roller
22) to the feed rate (peripheral velocity of the roller/ feed rate). Because the width
of the nonwoven fabric can decrease due to longitudinal wrinkling, the term "stretch
ratio of the nonwoven fabric in the axial direction (CD)" as used herein denotes the
value obtained by multiplying the above-identified mechanical stretch ratio in the
axial direction by the ratio of change in nonwoven fabric width between before and
after the passage between the pair of the rollers 21 and 22, the width after the passage/the
width before the passage. When the nonwoven fabric is stretched in both the MD and
CD (when stretched in an oblique direction), the mechanical stretch ratio is obtained
as a vector sum of MD and CD. When the projections have a circular or a similar shape
when viewed from above, the mechanical stretch ratio is obtained as a value of integral
of the mechanical stretch ratio at the individual dots. In order to obtain nonwoven
fabric with good feel to the touch without largely reducing the breaking strength
of the starting nonwoven fabric by the partial stretching, the overall stretch ratio
is preferably 1.3 to 4, more preferably 1.5 to 3. When the overall stretch ratio of
the nonwoven fabric is within that range, the following advantages are obtained: the
fibers become finer between heat and pressure bonds (hereinafter "heat/pressure bonds")
of the starting nonwoven fabric as a result of the partial stretching; a crack develops
in the peripheral portion of each heat/pressure bond (i.e., the vicinities of the
boundary line between the heat/pressure bond and the fibers) by the stretching, from
which crack the fiber is easily cut at the peripheral portion when subjected to the
raising process; the heat/pressure bonds are deformed and softened by the stretching
so that the fibers are easily cut to provide short raised fibers without being debonded
from the heat/pressure bonds; and therefore the resulting nonwoven fabric is easily
raised and exhibits excellent feel to the touch. The ratio of the area ratio of the
heat/pressure bonds to the overall stretch ratio, {area ratio of heat/pressure bonds
(%)/(overall stretch ratio × 100)}, is preferably 0.02 to 0.12, more preferably 0.04
to 0.10, in the interests of breaking strength retention, moderate destruction of
the heat/pressure bonds, and increased amount of fiber raising. The starting nonwoven
fabric has discrete heat/pressure bonds regularly spaced in planar directions. As
used herein, the term "heat/pressure bond" includes not only thermal pressure bonds
of the constituent fibers but ultrasonic pressure bonds of constituent fibers.
[0077] In order to achieve the above recited ranges of the mechanical stretch ratio and
the area ratio of the stretched regions, it is preferred that the height h of each
projection 210 measured from the peripheral surface of the roller 21 to the top of
the projection 210 be 1 to 10 mm, more preferably 2 to 7 mm; the pitch P
1 of the adjacent projections 210 in the circumferential direction be 0.01 to 20 mm,
more preferably 1 to 10 mm; and the pitch P
2 (unshown) of the adjacent projections 210 in the axial direction be 0.01 to 20 mm,
more preferably 1 to 10 mm. The shape of the top of each projection 210 of the roller
21 is not particularly limited and may be, for example, a circular, polygonal, or
oval shape. The area of the top of each projection 210 is preferably 0.01 to 500 mm
2, more preferably 0.1 to 10 mm
2. The area of the bottom between adjacent projections 210 is preferably 0.01 to 500
mm
2, more preferably 0.1 to 10 mm
2. Each projection 210 preferably has a rounded edge to avoid tearing the nonwoven
fabric during processing. The curvature radius (R) of the edge is preferably 0.2 mm
to (0.5 × dot diameter A
1) or (0.5 × dot diameter A
2). In this case, the area of the top of the projection 210 is obtained as a projected
area of the shape delineated by the centerline of the width of the curved edge viewed
from above. In the calculation of a partial mechanical stretch ratio, the same shape
is used.
[0078] The ratio of the pitch of the heat/pressure bonds (e.g., fusion bonds formed by,
for example, debossing) of the nonwoven fabric to the pitch of the projections 210
of the pair of rollers 21 and 22 (pitch of heat/pressure bonds/pitch of projections)
is preferably 0.05 to 0.7, more preferably 0.1 to 0.4. When this ratio is satisfied,
there is a high probability of existence of the heat/pressure bonds of the nonwoven
fabric in the regions being stretched. The heat/pressure bonds in the regions being
stretched are deformed and softened, which ensures the formation of weakened points
in the peripheral portion of the heat/pressure bonds of the nonwoven fabric. As a
result, the surface of the nonwoven fabric is easily raised with a light force to
make short raised fibers that hardly pill and provide good feel to the touch. The
ratio of the pitch of the heat/pressure bonds of the nonwoven fabric to the pitch
of the projections 210 of the pair of rollers 21 and 22 includes (1) the ratio of
the pitch of the heat/pressure bonds of the nonwoven fabric in the MD to the pitch
of the projections 210 of the pair of rollers 21 and 22 in the circumferential direction
and (2) the ratio of the pitch of the heat/pressure bonds of the nonwoven fabric in
the CD to the pitch of the projections 210 of the pair of rollers 21 and 22 in the
axial direction. Although it suffices that either one of these ratios falls within
the range recited, it is preferred that both of them fall within the range.
[0079] The individual recesses 220 of the roller 22 are arranged at positions corresponding
to the individual projections 210 of the roller 21 as shown in Figs. 10 and 11. In
order to achieve the above recited ranges of the mechanical stretch ratio and the
area ratio of the regions to be stretched, it is preferred that the depth of engagement
D (see Fig. 11) between the individual projections 210 of the roller 21 and the individual
projections of the roller 22 (the length of the overlap between the projection 210
and the recess 220) is preferably 0.1 to 10 mm, more preferably 1 to 8 mm. It is preferred
that there be a clearance between the top of the projection 210 of the roller 21 and
the bottom of the recess 220 of the roller 22 so as not to press the nonwoven fabric
4 passing therebetween to prevent the nonwoven fabric 4 from getting hard.
[0080] As shown in Fig. 10, the partial stretching part 2 has transport rollers 24 and 25
upstream and downstream, respectively, of the steel/steel matched embossing unit 23
for transporting the nonwoven fabric 4. The transport rate V1 of the nonwoven fabric
4 is controlled by the controller (not shown) of the processing apparatus 1. As used
herein, the term "transport rate V1" of the nonwoven fabric 4 means the speed of the
surface of the nonwoven fabric 4 being unrolled from the stock roll of the nonwoven
fabric 4.
[0081] The raising part 3 is a part in which the constituent fibers 41 of the partially
stretched nonwoven fabric 4' are raised. The raising part 3 of the processing apparatus
1 according to the present embodiment has an engraved roller 31 having projections
310 on its peripheral surface. The engraved roller 31 is a cylindrical member made
of metal, such as an aluminum alloy or steel. The engraved roller 31 rotates by a
driving force transmitted from an unshown driving means to its shaft of rotation.
The rotational speed (peripheral velocity V4) of the engraved roller 31 is controlled
by the unshown controller of the processing apparatus 1. As used herein, the term
"peripheral velocity V4" of the engraved roller 31 means the velocity of the surface
of the engraved roller 31 similarly to the peripheral velocity V2 of the rollers 21
and 22.
[0082] As shown in Fig. 12, the raising part 3 has transport rollers 32 and 33 upstream
and downstream, respectively, of the engraved roller 31 for transporting the nonwoven
fabrics 4'. The transport rate V3 of the stretched nonwoven fabric 4' is controlled
by the unshown controller of the processing apparatus 1. As used herein, the term
"transport rate V3" of the stretched nonwoven fabric 4' means the speed of the surface
of the nonwoven fabric 4' being fed to the engraved roller 31 similarly to the transport
rate V1 of the nonwoven fabric 4 to be stretched.
[0083] The height of each projection 310 of the engraved roller 31 (the distance from the
peripheral surface of the engraved roller 31 to the top of the projection 310) is
preferably 0.01 to 3 mm, more preferably 0.01 to 1 mm. The distance between adjacent
projections 310 (the pitch of the projections 310) in the circumferential direction
is preferably 0.01 to 50 mm, more preferably 0.01 to 3 mm, and that in the axial direction
is preferably 0.01 to 30 mm, more preferably 0.01 to 3 mm. The density of the projections
is preferably 500 to 5000 projections per cm
2 in terms of providing many points of raising action to give a nonwoven fabric with
many raised fibers. The shape of the top of each projection 310 of the roller 31 is
not particularly limited and may be, for example, a circular, polygonal, or oval shape.
The area of the top of each projection 310 is preferably 0.001 to 20 mm
2, more preferably 0.01 to 1 mm
2.
[0084] In order to raise the fibers 41 of the partially stretched nonwoven fabric 4' more
effectively with the processing apparatus 1 of the present embodiment, it is preferred
that the position of the transport roller 33 downstream of the engraved roller 31
be higher than that of the engraved roller 31 so that the stretched nonwoven fabric
4' may be partially wrapped around the engraved roller 31 at a wrap angle α of 10°
to 180°, more preferably 30° to 120°. While in the processing apparatus 1 of the present
embodiment a difference is provided in position between the engraved roller 31 and
the transport roller 33 to give a wrap angle α, such a difference does not need to
be provided.
[0085] As earlier described, the processing apparatus 1 of the present embodiment has a
controller (not shown) which controls the peripheral velocity V2 of the pair of rollers
21 and 22 based on the driving means, the peripheral velocity V4 of the engraved roller
31 based on the driving means, the transport rate V1 of the nonwoven fabric 4 based
on the tension detected using a tension sensor, and the transport rate V3 of the stretched
nonwoven fabric 4' based on the tension detected using a tension sensor in accordance
with a prescribed sequence of operations.
[0086] The method for making a nonwoven fabric according to the invention will then be described
based on an embodiment in which the above described processing apparatus 1 is used.
Figs. 9 through 12 are referred to.
[0087] The method for making a nonwoven fabric according to the invention includes the step
of stretching a plurality of regions of a nonwoven fabric 4 at or below 50°C. In the
present embodiment, a continuous length of a starting nonwoven fabric 4 unrolled from
a stock roll is introduced by the transport rollers 24 and 25 into the nip between
the pair of rollers 21 and 22 of the steel/steel matched embossing unit 23 to be partially
stretched as shown in Fig. 9. More specifically, the nonwoven fabric 4 fed by the
transport rollers 24 and 25 is pressed between a plurality of the projections 210
of the roller 21 and a plurality of the recesses 220 of the roller 22 (partial stretching)
shown in Figs. 10 and 11 to conduct stretch at every pressed part of the nonwoven
fabric 4 in the transport direction and a direction perpendicular to the transport
direction. By this stretching in the transport direction and a direction perpendicular
to the transport direction, reduction in breaking strength of the nonwoven fabric
4 is controllable for each direction. The expression "at or below 50°C" as used above
is intended to mean that heat is not positively applied to the rollers 21 and 22 and
that the stretch process is carried out at ambient temperature. In other words, the
stretch process should be performed at a temperature lower than the melting point
of every kind of fibers that make up the nonwoven fabric 4. Otherwise, the fibers
making up the nonwoven fabric would be thermally fused and bonded to one another to
make the nonwoven fabric 4 harder. As used herein, the term "a direction perpendicular
to the transport direction" means the same direction as the rotational axial direction
of the rollers.
[0088] In the present embodiment, the feed rate V1 in feeding the nonwoven fabric 4 into
the nip of the pair of rollers 21 and 22 is preferably higher than the peripheral
velocity V2 of the pair of rollers 21 and 22 (V1>V2) to achieve the partial stretch
processing satisfactorily. The V1/V2 is more preferably 1.05 or greater, even more
preferably 1.1 or greater. To avoid causing a slack of the nonwoven fabric 4 being
transported, the V1/V2 is preferably smaller than 10. With the V1/V2 being smaller
than 10, the amount of fiber raising increases, and the feel to the touch improves.
In the case of commonly practiced overall stretch processing, such as uniaxial stretching,
the peripheral velocity of a pair of smooth rollers is greater than the feed rate,
i.e., V1/V2<1, unlike the above discussed partial stretching. If, for example, an
ordinary spun-bonded nonwoven fabric is stretched to an overall stretch ratio of 1.3
or greater (which is obtained as V2/V1 in the case of uniaxial stretching), it will
tear. Therefore, it is unfeasible to stretch nonwoven fabrics to an increased overall
stretch ratio. According to the present embodiment, in contrast, the nonwoven fabric
hardly suffers from tearing or otherwise being damaged even if there are regions showing
an overall stretch ratio of 1.3 or greater.
[0089] According to the method of the invention, the partially stretched nonwoven fabric
4' is then subjected to a raising process for raising the fibers of the nonwoven fabric
4'. In the present embodiment, as shown in Fig. 9, the partially stretched nonwoven
fabric 4' is transported by the transport rollers 32 and 33 to the engraved roller
31 having the projections 310 on its peripheral surface, where the fibers of the partially
stretched nonwoven fabric 4' are raised from the surface of the nonwoven fabric 4'
by the engraved roller 31 shown in Fig. 12.
[0090] In the present embodiment, in order to effectively raise fibers from the surface
of the nonwoven fabric 4', the direction of rotation of the engraved roller 31 is
preferably the reverse of the transport direction of the partially stretched nonwoven
fabric 4' as shown in Fig. 12. In this counter-rotation mode, V4/V3 is preferably
0.3 to 10, more preferably V4>V3, and even more preferably V4/V3 ranges from 1.1 to
10. A particularly preferred V4/V3 is 1.5 to 5 in terms of sufficient fiber raising
and reduced clinging of fibers to the roller. The counter-rotation mode combined with
the difference between the peripheral velocity and the feed rate ensures further increase
of fiber raising and further improvement on feel to the touch. In the case when the
engraved roller 31 rotates in the same direction as the transport direction of the
stretched nonwoven fabric 4', it is preferred that the transport rate V3 of the partially
stretched nonwoven fabric 4' and the peripheral velocity V4 of the engraved roller
31 satisfy the relationship that V4/V3 ranges from 1.1 to 20, more preferably 1.5
to 10, even more preferably 2 to 8.
[0091] The nonwoven fabric 4 to be subjected to the above described processing steps may
be a spun-bonded nonwoven fabric, a complex nonwoven fabric composed of a spun-bonded
layer and a melt-blown layer, or a nonwoven fabric made of continuous fibers in tow
form. Among them preferred is a spun-bonded nonwoven fabric for its inexpensiveness,
high breaking strength and thinness. In the case of using a complex nonwoven fabric,
the spun-bonded layer is preferably disposed on the surface side and/or the reverse
side of the melt-blown layer. In particular, it is preferred that the spun-bonded/melt-blown
complex nonwoven fabric be made of a polypropylene resin containing 50% by weight
or more of a recycled polypropylene resin. The continuous fibers in tow form as referred
to above each preferably have a thickness of 5 to 30 µm, more preferably 10 to 20
µm.
[0092] The nonwoven fabric 4 preferably has a basis weight of 10 to 100 g/m
2, 10 to 25 g/m
2, in terms of inexpensiveness, good feel to the touch, and processability. A plurality
of fusion bonds which are heat/pressure bonds of the nonwoven fabric 4 may be formed
by discretely applying heat and pressure using a debossing roller combined with a
flat roller, ultrasonic fusion bonding, or discretely applying hot air. The fusion
bonds are preferably formed by applying heat and pressure in terms of ease of fiber
raising. The fusion bond is not particularly limited in shape and may have a circular,
a rhombic, a triangular, or a like shape. The fusion bonds preferably have a total
area ratio of 5% to 30% per side. The total area ratio of the fusion bonds is more
preferably 10% to 20% per side to prevent pilling.
In the case of using a spun-bonded nonwoven fabric, the individual fusion bonds formed
by debossing preferably have an area of 0.05 to 10 mm
2, more preferably 0.1 to 1 mm
2. The number of the fusion bonds is preferably 10 to 250/cm
2, more preferably 35 to 65/cm
2. The fusion bond is not particularly limited in shape and may have a circular, a
rhombic, a triangular, or a like shape. The total area ratio of the fusion bonds is
preferably 5% to 30%, more preferably 10% to 20%, per side of the spun-bonded nonwoven
fabric.
The spun-bonded nonwoven fabric may have a single layer structure or a multilayered
structure composed of a plurality of layers.
[0093] The spun-bonded nonwoven fabric used in the present embodiment is made of thermoplastic
resin fibers. Examples of the thermoplastic resin include polyolefin resins, polyester
resins, polyamide resins, acrylonitrile resins, vinyl resins, and vinylidene resins.
Examples of the polyolefin resins are polyethylene, polypropylene, and polybutene.
Examples of the polyester resins are polyethylene terephthalate and polybutylene terephthalate.
Examples of the polyamide resin include nylon. The vinyl resins are exemplified by
polyvinyl chloride. An example of the vinylidene resins is polyvinylidene chloride.
Modification products of these resins or mixtures of these resins are useful as well.
The diameter of the fibers is preferably 5 to 30 µm, more preferably 10 to 20 µm,
at a stage before being subjected to the partial stretching.
[0094] As described, since the method of the present embodiment using the processing apparatus
1 includes the step of preprocessing in which a plurality of discrete regions of the
nonwoven fabric 4 are stretched at or below 50°C, the fibers are not fused together
during the partial stretching and are easily raised in the subsequent raising step.
As a result, there is obtained a soft nonwoven fabric 4" having fibers raised to provide
a good feel to the touch. Since the stretch process is performed in only the plurality
of discrete regions of the starting nonwoven fabric 4, the other regions of the nonwoven
fabric 4, which are not stretched, retain the strength of the starting nonwoven fabric
and serve to minimize the reduction in strength due to the stretching. This means
that the nonwoven fabric is allowed to be transported at an increased rate so as to
reduce the production cost of the nonwoven fabric 4" when, in particular, an essentially
strong nonwoven fabric, such as a spun-bonded nonwoven fabric, is used. In the present
embodiment, since both the partial stretch process and the raising process are implemented
using rollers, specifically the pair of rollers 21 and 22 and the engraved roller
31, it is feasible to increase the rate of producing the nonwoven fabric 4" thereby
to reduce the production cost of the nonwoven fabric 4".
[0095] When, in particular, the aforesaid spun-bonded nonwoven fabric is used as the nonwoven
fabric 4, the reduction in breaking strength due to the partial stretching can be
limited to 50% or less. That is, when a starting nonwoven fabric 4 is a spun-bonded
nonwoven fabric having a breaking strength of 10 to 30 N/50 mm with a basis weight
of 20 g/m
2, the breaking strength after the processing is 5 to 20 N/50 mm. Thus, the breaking
strength of the processed spun-bonded nonwoven fabric is almost equal to that of the
starting spun-bonded nonwoven fabric. It is preferred that the starting spun-bonded
nonwoven fabric or the processed spun-bonded nonwoven fabric satisfy the range recited
above in either one of the X direction and the Y direction, more preferably in both
directions. The breaking strength is measured by the following method.
Method for measuring breaking strength:
[0096] A rectangular specimen measuring 50 mm by 200 mm is cut out of a starting spun-bonded
nonwoven fabric or a processed nonwoven fabric, with the length coincide with the
X direction (transverse direction or CD) and the width coincide with the Y direction
(longitudinal direction or MD). The specimen is set on a tensile tester (e.g., Tensilon
tensile tester RTA-100 from Orientec) at an initial jaw separation of 150 mm with
its X direction coincide with the pulling direction and pulled at a rate of 300 mm/min.
The maximum load reached until the specimen breaks is taken as a breaking strength
in the X direction. Another rectangular specimen measuring 50 mm in the X direction
(transverse direction or CD) and 200 mm in the Y direction (longitudinal direction
or MD) is cut out and set on the tensile tester with its Y direction coincide with
the pulling direction. The breaking strength in the Y direction is measured in the
same manner as for the measurement in the X direction.
[0097] When in using the above described spun-bonded nonwoven fabric as the nonwoven fabric
4, the fibers raised from the surface of the resulting processed nonwoven fabric are
short enough not to impair the appearance. As used herein, the term "fibers raised
from the surface of a nonwoven fabric" is defined to be those fibers the tip of each
of which is located at least 0.2 mm above the surface of a nonwoven fabric.
The inventors consider that the reason why the fibers raised from the surface of a
spun-bonded nonwoven fabric are short is as follows. On stretching a spun-bonded nonwoven
fabric using the steel/steel matched embossing unit 23 in the partial stretching part
2, a weakened point is formed in the fusion bond of the spun-bonded nonwoven fabric.
Subsequently, on processing the surface of the nonwoven fabric using the engraved
roller 31 in the raising part 3, a continuous fiber constituting the spun-bonded nonwoven
fabric is cut at the weakened point of the fusion bond to form a fiber cut at the
fusion bond.
The number of the raised fibers of the nonwoven fabric is preferably 8 or greater,
more preferably 12 or greater, per centimeter in terms of good feel to the touch and
100 or fewer per centimeter in terms of sufficient breaking strength, more preferably
40 or fewer per centimeter in terms of non-fuzzy appearance. The number of raised
fibers is measured as follows.
Method for measuring the number of raised fibers:
[0098] Fig. 13 schematically illustrates how to count the number of raised fibers. Sampling
and measurement are carried out in an environment of 22°C and 65% RH. A piece measuring
20 cm by 20 cm is cut out of the nonwoven fabric to be evaluated with a sharp razor
and folded with the raised side out to make a specimen 104 as shown in Fig. 13(a).
The specimen 104 is placed on a black sheet of A4 size. Another black sheet of A4
size having a hole 107 measuring 1 cm (vertical) by 1 cm (horizontal) is put thereon
as shown in Fig. 13(b) such that the folded edge 105 of the specimen 104 may be seen
through the hole 107 of the upper black sheet as shown. The two black sheets are of
KENRAN KURO (ream weight: 265 g) available from Fujikyowa Seishi K.K. A 50 g weight
is put on the upper sheet at a position 5 cm outward from each lateral side of the
hole 107 along the folded edge 105 to ensure that the specimen 104 is completely folded.
Then, as shown in Fig. 13(c), the specimen 104 seen through the hole 107 is observed
using a microscope (VHX-900 from Keyence) at a magnification of 30 times. An imaginary
line 108 is drawn in the micrograph in parallel to and 0.2 mm above the folded edge
105 of the sample 104. The number of the fibers projecting above the imaginary line
108 is counted. When the width of the raised region of the nonwoven fabric to be evaluated
is 1 cm or more, three specimens each measuring 20 cm by 20 cm and containing the
raised region are cut out from the nonwoven fabric. When the width of the raised region
of the nonwoven fabric is 1 cm or less, three specimens each measuring 20 cm by 20
cm are randomly cut out of the nonwoven fabric. Three specimens are prepared from
a nonwoven fabric to be evaluated, and measurements are taken at three positions per
specimen. The average of nine measurements is taken as the number of raised fibers.
[0099] In counting the number of raised fibers, when there is a fiber intersecting the imaginary
line 108 (0.2 mm above the folded edge 105) twice, like the fiber 106a shown in Fig.
13(c), that fiber is counted as two. More concretely, the specimen shown in Fig. 13(C)
has four fibers intersecting the imaginary line 108 once and one fiber 106a intersecting
the imaginary line 108 twice. So, the number of the raised fibers is six, the fiber
106a intersecting twice being counted as two.
[0100] The raised nonwoven fabric produced by the method of the invention has an advantage
over a flocked sheet in that the production does not involve the step of bonding separate
fibers (flocks) to a base nonwoven fabric using an adhesive or a like chemical so
that the risk of adversely affecting the skin caused by a chemical, such as an adhesive,
is reduced. In addition to this, there are no problems associated with a flocked sheet,
such as fall-off of flocks during use and resultant exposure of the adhesive layer.
A spun-bonded nonwoven fabric, one type of nonwoven fabrics used in absorbent articles,
is thin and difficult to make fluffy by a general raising process without the likelihood
of being broken. According to the production method of the invention, there is obtained
a raised, spun-bonded nonwoven fabric having a high raised fiber density and good
feel to the touch.
[0101] The nonwoven fabric obtained by the method of the invention is also characterized
by pleasant fluffiness for its thickness. While there is almost no difference in thickness
between the starting nonwoven fabric and the nonwoven fabric obtained by the method
of the invention when a high load is applied thereon, there is a difference in thickness
between them when a low load is applied. For example, with a load of 10 gf/cm
2 applied, the thickness of the spun-bonded nonwoven fabric obtained by the method
of the invention and that of an ordinary, starting spun-bonded nonwoven fabric both
having a basis weight of 15 g/m
2 are not so different, ranging from about 0.15 to 0.18 mm. When a load of 0.05 gf/cm
2 is applied, in contrast, the thickness of the starting spun-bonded nonwoven fabric
is 0.41 to 0.46 mm, while the spun-bonded nonwoven fabric obtained by the method of
the invention is 0.5 to 0.6 mm, showing a difference. The load of 0.05 gf/cm
2 corresponds to the load applied when one lightly presses the nonwoven fabric with
his or her finger(s). One is able to feel fluffiness by perceiving such a small difference
in thickness on touching.
[0102] The method for making a nonwoven fabric according to the invention is by no means
limited to the above discussed embodiment, and various changes and modifications can
be added thereto as exemplified as follows.
[0103] The processing apparatus 1 used in the present embodiment of the method has the steel/steel
matched embossing unit 23 composed of a meshing pair of engraved rollers 21 and 22
in the partial stretching part 2 as shown in Fig. 9 and 10. In a modification, the
steel/steel matched embossing unit 23 may be replaced with a pair of corrugated rollers
having intermeshing corrugations on their peripheral surface. The meshing engagement
may be along either the transport direction or a direction crossing the transport
direction. In the latter case, because the pair of corrugated rollers are rotatable
even when the depth of engagement is increased, a high mechanical stretch ratio is
achieved to provide a nonwoven fabric with better feel to the touch. The steel/steel
matched embossing unit is preferred, nevertheless, in view of the following advantages:
non-stretched regions are distributed discretely, by which the reduction in breaking
strength of the nonwoven fabric is minimized, and the nonwoven fabric being processed
hardly suffers wrinkling; and the nonwoven fabric is stretched in both the MD and
CD thereby to be provided with excellent feel to the touch.
It is also desirable preferred embodiment that the raising is performed in stripes
or in a pattern for decorative purposes.
[0104] The processing apparatus 1 used in the present embodiment of the method has the engraved
roller 31 with the projections 310 around its periphery in the raising part 3 as shown
in Figs. 9 and 12. In a modification, the engraved roller 31 may be replaced with
a pair of corrugated rollers having intermeshing corrugations on their peripheral
surface, a knurled roller, a thermal sprayed roller, a carding wire, or a roller covered
on its periphery with a material having friction resistant properties. The material
having friction resistant properties is exemplified by rubber or emery paper. The
partial stretching and the raising may each be carried out continuously or successively.
The method of the present embodiment has an additional advantage in that, if the raised
fibers of the raised nonwoven fabric are once collapsed when the nonwoven fabric is
wound into a stock roll, they will rise again after being unwounded simply by touching
with a hand or passing on a guide roller to provide a nonwoven fabric or an absorbent
article having a good feel to the touch.
Examples
[0105] The invention will now be illustrated in greater detail with reference to Examples,
but it should be understood that the invention is not limited thereto.
Example 1
[0106] A spun-bonded/melt-blown/spun-bonded complex nonwoven fabric (hereinafter referred
to as SMS nonwoven fabric) having a basis weight of 15 g/m
2 and each spun-bonded layer of which was made of ethylene-propylene copolymer resin
fibers having a fiber diameter of 14.7 µm was used as a starting nonwoven fabric.
This nonwoven fabric was used as such in Comparative Example 5 hereinafter given.
The SMS nonwoven fabric was treated in two stages: first passed through the steel/steel
matched embossing unit 43 shown in Fig. 3 and then surface-treated by the engraved
roller 51 shown in Fig. 4 to obtain a nonwoven fabric. The individual projections
410 of the roller 41 of the steel/steel matched embossing unit 43 had a height of
2.8 mm. The depth of engagement between the individual projections 410 of the roller
41 and the individual recesses 420 of the roller 42 was 2.7 mm. The distance between
adjacent projections 410 (the pitch of the projections 410) in the axial direction
was 7 mm, and that in the circumferential direction was 7 mm. The height of the individual
projections 510 of the engraved roller 51 was 0.6 mm. The distance between adjacent
projections 510 (the pitch of the projections 510) in the axial direction was 1.4
mm, and that in the circumferential direction was 2.1 mm. The engraved roller 51 was
rotated in the direction reverse to the transport direction of the nonwoven fabric
at a rotational speed four times the feed rate of the nonwoven fabric. The wrap angle
was 130°. The nonwoven fabric feed rate in each of the two stages was 10 m/min.
Example 2
[0107] A spun-bonded/melt-blown/spun-bonded complex nonwoven fabric (hereinafter "SMS nonwoven
fabric") having a basis weight of 15 g/m
2 and each spun-bonded layer of which was made of propylene resin fibers having a diameter
of 17.7 µm was used as a starting nonwoven fabric. This SMS nonwoven fabric was processed
in two stages under the same conditions as in Example 1.
Example 3
[0108] A spun-bonded/spun-bonded/melt-blown/spun-bonded complex nonwoven fabric (hereinafter
"SSMS nonwoven fabric") having a basis weight of 18 g/m
2 of which every spun-bonded layer was made of ethylene-propylene copolymer resin fibers
having a diameter of 12.9 µm was used as a starting nonwoven fabric. The outermost
spun-bonded layers of this SSMS nonwoven fabric contained a softener. The SSMS nonwoven
fabric was processed in two stages under the same conditions as in Example 1.
Example 4
[0109] A spun-bonded/melt-blown/melt-blown/spun-bonded complex nonwoven fabric (hereinafter
"SMMS nonwoven fabric") having a basis weight of 12 g/m
2 of which each spun-bonded layer was made of propylene resin fibers having a diameter
of 14.6 µm was used as a starting nonwoven fabric. The SMMS nonwoven fabric was processed
in two stages under the same conditions as in Example 1.
Example 5
[0110] A spun-bonded/melt-blown/spun-bonded complex nonwoven fabric (hereinafter "SMS nonwoven
fabric") having a basis weight of 18 g/m
2 of which each spun-bonded layer was made of ethylene-propylene copolymer resin fibers
having a diameter of 14.9 µm was used as a starting nonwoven fabric. The spun-bonded
layer on one side of this SMS nonwoven fabric contained a softener. The SMS nonwoven
fabric was processed on its softener-containing side in two stages under the same
conditions as in Example 1.
Example 6
[0111] A spun-bonded/spun-bonded/spun-bonded complex nonwoven fabric (hereinafter "SSS nonwoven
fabric") having a basis weight of 18 g/m
2 of which every spun-bonded layer was made of ethylene-propylene copolymer resin fibers
having a diameter of 15.0 µm was used as a starting nonwoven fabric. The SSS nonwoven
fabric contained a softener. The SSS nonwoven fabric was processed in two stages under
the same conditions as in Example 1.
Example 7
[0112] A spun-bonded/spun-bonded/spun-bonded complex nonwoven fabric (hereinafter "SSS nonwoven
fabric") having a basis weight of 18 g/m
2 of which every spun-bonded layer was made of propylene resin fibers having a diameter
of 14.9 µm was used as a starting nonwoven fabric. The SSS nonwoven fabric was processed
in two stages under the same conditions as in Example 1.
Comparative Example 1
[0113] The same spun-bonded/melt-blown/spun-bonded complex nonwoven fabric (SMS nonwoven
fabric) as used in Example 1 (the basis weight was 15 g/m
2, and each spun-bonded layer was made of ethylene-propylene copolymer resin fibers
having a diameter of 14.7 µm) was used as a starting nonwoven fabric. To imitate needle-punching,
the upper surface of the SMS nonwoven fabric measuring 5 cm by 5 cm was scratched
by the pointed tips of a pair of tweezers K-14 in a manner that the fibers on the
surface of the nonwoven fabric were pulled out and cut. The scratching and cutting
operation was repeated 30 times in total to obtain a nonwoven fabric with surface
fibers raised.
Comparative Example 2
[0114] The same spun-bonded/melt-blown/spun-bonded complex nonwoven fabric (SMS nonwoven
fabric) as used in Example 1 (the basis weight was 15 g/m
2, and each spun-bonded layer was made of ethylene-propylene copolymer resin fibers
having a diameter of 14.7 µm) was used as a starting nonwoven fabric. The SMS nonwoven
fabric was subjected to a cutting process to obtain a nonwoven fabric. The cutting
process was carried out by soaking the SMS nonwoven fabric in liquid nitrogen for
5 minutes and cutting the frozen nonwoven fabric with a razor.
Comparative Example 3
[0115] The same spun-bonded/melt-blown/spun-bonded complex nonwoven fabric (SMS nonwoven
fabric) as used in Example 1 (the basis weight was 15 g/m
2, and each spun-bonded layer was made of ethylene-propylene copolymer resin fibers
having a diameter of 14.7 µm) was used as a starting nonwoven fabric. Sand paper (240
grit; from Trusco Nakayama Corp.) was wrapped around the whole periphery of a 110
diameter roller via double-sided adhesive tape. The SMS nonwoven fabric ran in contact
with the sand paper-covered roller at a wrap angle of 8.5° at a velocity of 10 m/min,
while the roller rotated at a velocity of 50 m/min in the direction reverse to the
running direction of the nonwoven fabric. There was thus obtained a nonwoven fabric
having fibers broken.
Comparative Example 4
[0116] The same spun-bonded/melt-blown/spun-bonded complex nonwoven fabric (SMS nonwoven
fabric) as used in Example 1 (the basis weight was 15 g/m
2, and each spun-bonded layer was made of ethylene-propylene copolymer resin fibers
having a diameter of 14.7 µm) was used as such without conducting raising.
Comparative Example 5
[0117] The same spun-bonded/melt-blown/spun-bonded complex nonwoven fabric (SMS nonwoven
fabric) as used in Example 2 (the basis weight was 15 g/m
2, and each spun-bonded layer was made of propylene resin fibers having a diameter
of 17.7 µm) was used as a starting nonwoven fabric. To imitate needle-punching, the
upper surface of the SMS nonwoven fabric measuring 5 cm by 5 cm was scratched with
the pointed tips of a pair of tweezers K-14 in a manner that the fibers on the surface
of the nonwoven fabric were pulled out and cut. The scratching and cutting operation
was repeated 30 times in total to obtain a nonwoven fabric with surface fibers napped.
Comparative Example 6
[0118] The same spun-bonded/melt-blown/spun-bonded complex nonwoven fabric (SMS nonwoven
fabric) as used in Example 2 (the basis weight was 15 g/m
2, and each spun-bonded layer was made of propylene resin fibers having a diameter
of 17.7 µm) was used as such without conducting raising.
Comparative Example 7
[0119] The same spun-bonded/spun-bonded/melt-blown/spun-bonded complex nonwoven fabric (SSMS
nonwoven fabric) as used in Example 3 (the basis weight was 18 g/m
2, every spun-bonded layer was made of ethylene-propylene copolymer resin fibers having
a diameter of 12.9 µm, and the outermost spun-bonded layers of this SSMS nonwoven
fabric contained a softener) was used as such without conducting raising.
Comparative Example 8
[0120] The same spun-bonded/melt-blown/melt-blown/spun-bonded complex nonwoven fabric (SMMS
nonwoven fabric) as used in Example 4 (the basis weight was 12 g/m
2, and each spun-bonded layer was made of propylene resin fibers having a diameter
of 14.6 µm) was used as such without conducting raising.
Comparative Example 9
[0121] The same spun-bonded/melt-blown/spun-bonded complex nonwoven fabric (SMS nonwoven
fabric) as used in Example 5 (the basis weight was 18 g/m
2, and each spun-bonded layer was made of propylene resin fibers having a diameter
of 14.9 µm) was used as such. The spun-bonded layer on one side of this SMS nonwoven
fabric contained a softener. The SMS nonwoven fabric was not subjected to raising.
Comparative Example 10
[0122] The same spun-bonded/spun-bonded/spun-bonded complex nonwoven fabric (SSS nonwoven
fabric) as used in Example 6 (the basis weight was 18 g/m
2, and every spun-bonded layer was made of ethylene-propylene copolymer resin fibers
having a diameter of 15.0 µm) was used. The SSS nonwoven fabric contained a softener.
The SSS nonwoven fabric was not subjected to raising.
Comparative Example 11
[0123] The same spun-bonded/spun-bonded/spun-bonded complex nonwoven fabric (SSS nonwoven
fabric) as used in Example 7 (the basis weight was 18 g/m
2, and every spun-bonded layer was made of ethylene-propylene copolymer resin fibers
having a diameter of 14.9 µm) was used. The SSS nonwoven fabric was not subjected
to raising.
Evaluation of performance:
[0124] The nonwoven fabrics obtained in Examples 1 to 7 and Comparative Examples 1 to 3
and 5 were evaluated by measuring the fiber diameters by the method for measuring
fiber diameter described supra and calculating the increase ratio of the tip diameter
of the fiber. If the increase ratio of the fiber tip diameter was 15% or higher, it
was considered a pass (P). If it was lower than 15%, the nonwoven fabric was rated
a fail (F). The results obtained are shown in Tables 1 to 4.
The nonwoven fabrics obtained in Examples 1 to 7 and Comparative Examples 1 to 3 and
5 were evaluated by obtaining the ratio of the fibers 21 having a thickened free end
20b to the total number of the fibers 20 only one end 20a of each of which was fixed
at the fusion bond 3 (i.e., the sum of the fibers 21 with a thickened free end 20b
and the fibers 22 whose free end 20b was not thickened) by the method for measuring
fiber diameter described supra. If the ratio of the fibers 21 with a thickened end
was 20% or higher, the nonwoven fabric was given a pass (P). If it was lower than
20%, the nonwoven fabric was given a fail (F). The results are shown in Tables 1 to
4.
The nonwoven fabrics obtained in Examples 1 to 7 and Comparative Examples 1 to 3 and
5 were evaluated by obtaining the ratio of the loop fibers 23 to the total number
of the fibers constituting the nonwoven fabric (i.e., the total of the fibers 20 only
one end 20a of each of which is fixed at the fusion bond 3 (including the fibers 21
with a thickened free end 20b and the fibers 22 whose free end 20b is not thickened)
and the loop fibers 23) by the method for measuring fiber diameter described supra.
If the ratio of the loop fibers 23 was lower than 50%, the nonwoven fabric was given
a pass (P). If it was 50% or higher, the nonwoven fabric was rated a fail (F). The
results are shown in Tables 1 to 4.
The nonwoven fabrics obtained in Examples 1 to 7 and Comparative Examples 1 to 11
were evaluated by obtaining the fiber diameter distribution by the method for determining
fiber diameter distribution described supra. If the distribution was 0.33 or greater,
the nonwoven fabric was rated a pass (P). If the distribution was less than 0.33,
it was rated a fail (F). The results are shown in Tables 1 to 4.
Sensory evaluation on feel to the touch:
[0125] The nonwoven fabrics obtained in Examples 1 to 7 and Comparative Examples 1 to 3
and 5 to 11 were sensorily evaluated on a scale of 1 to 10 using the nonwoven fabric
of Comparative Example 4 as a reference given a value of 3. The greater the value,
the better the feel to the touch. Each nonwoven fabric was tested in triplicate, and
the average was rounded off to the whole number. The nonwoven fabrics of Examples
1 to 7 and Comparative Examples 1 to 3 and 5 which had been subjected to any raising
process were compared with their respective starting nonwoven fabrics that had not
been subjected to raising (i.e., between Example 1 and Comparative Example 5, between
Example 2 and Comparative Example 6, between Comparative Examples 5 and 6, between
Example 3 and Comparative Example 7, between Example 4 and Comparative Example 8,
between Example 5 and Comparative Example 9, between Example 6 and Comparative Example
10, between Example 7 and Comparative Example 11, and between Comparative Examples
1 to 4 and Comparative Example 5). If there was an increase of the average value in
the sensory evaluation over the corresponding starting nonwoven fabric, the raised
nonwoven fabric was deemed a pass (P). If there was no change, the raised nonwoven
fabric was deemed a fail (F). The results obtained are shown in Tables 1 to 4.
Evaluation on breaking strength ratio:
[0126] In accordance with the method for measuring breaking strength described supra, a
specimen measuring 200 mm in the X direction (transverse direction) and 50 mm in the
Y direction (longitudinal direction) was cut out of each of the nonwoven fabrics obtained
in Examples 1 to 7 and Comparative Examples 1 to 11. The specimen was pulled on a
tensile tester from Shimadzu Corp. starting from an initial jaw separation of 150
mm at a rate of 300 mm/min to determine the strength in the X direction (transverse
direction). An average of the measurements on four specimens per sample was obtained.
Then, the strength in the X direction (transverse direction) of the corresponding
starting nonwoven fabric (e.g., Comparative Example 5 corresponds to Example 1) for
each of Examples 1 to 7 and Comparative Examples 1 to 3 and 5 was determined. The
ratio of the breaking strength of the raised nonwoven fabric of each of Examples 1
to 7 and Comparative Examples 1 to 3 and 5 to that of the corresponding non-raised
starting nonwoven fabric was obtained. If the ratio was 50% or higher, the raised
nonwoven fabric was given a pass (P). If the ratio was less than 50%, the raised nonwoven
fabric was given a fail (F). The results are shown in Tables 1 to 4.
Evaluation on shedding of fuzz:
[0127] A specimen measuring 200 mm in the X direction (transverse direction) and 200 mm
in the Y direction (longitudinal direction) was cut out of each of the nonwoven fabrics
obtained in Examples 1 to 7 and Comparative Examples 1 to 11. One side of the specimen
was evaluated. Specifically, the specimen was fixed with the side to be evaluated
up to a plate at its four corners with packing tape. A friction plate wrapped in sponge
(Moltoprene MF-30) was placed on the specimen to give a load of 240 g and given 15
cycles of turns, each cycle consisting of three clockwise turns followed by three
counterclockwise turns, taking 3 seconds for each turn. Then, all the fibers adhering
to the sponge were transferred to transparent pressure-sensitive adhesive tape, and
the adhesive tape was attached to a black paper. The surface condition of the specimen
and the fibers adhering to the adhesive tape were observed with naked eyes to evaluate
the degree of fuzz shedding according to the following rating system. The results
obtained are shown in Tables 1 through 4.
- A: The specimen has substantially no fuzz nor pills. There are substantially no fibers
adhering to the adhesive tape.
- B: The specimen has fuzz or pills, but there are no lumps of fibers adhering to the
adhesive tape.
- C: The specimen has fuzz or pills, and there are many lumps of fibers adhering to
the adhesive tape.
[0128] The nonwoven fabrics of Examples 1 to 7 and Comparative Examples 1 to 11 were evaluated
by determining a compression characteristic value under a small load by the method
for determining compression characteristic value under small load described supra.
If the compression characteristic value was 18.0 (gf/cm
2)/mm or smaller, the nonwoven fabric was deemed a pass (P). If it was greater than
18.0 (gf/cm
2)/mm, the nonwoven fabric was deemed a fail (F). The results obtained are shown in
Tables 1 to 4.
The nonwoven fabrics of Examples 1 to 7 and Comparative Examples 1 to 11 were evaluated
by determining the number of raised fibers by the method for measuring the number
of raised fibers described supra. If the number of the raised fibers was 8 or greater
per cm, the nonwoven fabric was rated as a pass (P). If the number was fewer than
8 per cm, the nonwoven fabric was rated as a fail (F). The results are shown in Tables
1 through 4.
The nonwoven fabrics of Examples 1 to 7 and Comparative Examples 1 to 11 were evaluated
by determining the height of raised fibers by the method for measuring the height
of raised fibers described supra. If the height of the raised fibers was 1.5 mm or
less, the nonwoven fabric was rated as a pass (P). If the height was larger than 1.5
mm, the nonwoven fabric was rated as a fail (F). The results are shown in Tables 1
through 4.
[0129]
Table 1
|
unit |
Example 1 |
Compara. Example 1 |
Compara. Example 2 |
Compara. Example 3 |
Compara. Example 4 |
Ratio of Fiber Diameter at Free End (increase ratio of fiber tip diameter) |
% |
37 |
2 |
-1 |
6 |
- |
P |
F |
F |
F |
- |
Ratio of Fibers with Thickened Free End |
% |
60 |
10 |
0 |
30 |
|
P |
F |
F |
P |
- |
Ratio of Loop Fibers |
% |
38 |
68 |
0 |
33 |
- |
P |
F |
P |
P |
- |
Fiber Diameter Distribution |
- |
0.408 |
0.308 |
0.248 |
0.953 |
0.248 |
P |
F |
F |
P |
|
Feel to the Touch |
point |
6 |
3 |
3 |
6 |
3 |
P |
F |
F |
P |
- |
Breaking Strength in X direction |
cN |
910 |
1510 |
1510 |
671 |
1510 |
P (60%) |
P(100%) |
P(10%) |
F(11%) |
- |
Fuzz Shedding |
|
A |
A |
A |
C |
A |
Compression Characteristic Value under Small Load |
(gf/cm2)/mm |
10.4 |
22 |
22.3 |
11.3 |
23.7 |
P |
F |
F |
P |
F |
Number of Raised Fibers |
number/cm |
20 |
3 |
5 |
41 |
0 |
P |
F |
F |
P |
F |
Height of Raised Fibers |
mm |
0.66 |
1.1 |
0.3 |
0.5 |
0 |
P |
P |
P |
P |
P |
[0130]
Table 2
|
unit |
Example 2 |
Compara. Example 5 |
Compara. Example 6 |
Example 3 |
Compara. Example 7 |
Ratio of Fiber Diameter at Free End (increase ratio of fiber tip diameter) |
% |
15 |
-5 |
- |
32 |
- |
P |
F |
- |
P |
- |
Ratio of Fibers with Thickened Free End |
% |
50 |
0 |
- |
60 |
- |
P |
F |
- |
P |
- |
Ratio of Loop Fibers |
% |
45 |
75 |
- |
20 |
- |
P |
F |
- |
P |
- |
Fiber Diameter Distribution |
- |
2.48 |
1.89 |
0.310 |
0.447 |
0.318 |
P |
P |
F |
P |
F |
Feel to the Touch |
point |
3 |
2 |
2 |
8 |
4 |
P |
F |
- |
P |
- |
Breaking Strength in X direction |
cN |
832 |
1550 |
1628 |
1415 |
1777 |
P(51%) |
P (95%) |
- |
P (80%) |
- |
Fuzz Shedding |
|
A |
A |
A |
A |
A |
Compression Characteristic Value under Small Load |
(gf/cm2)/mm |
11.9 |
22.1 |
23.8 |
10.8 |
25.8 |
P |
F |
F |
P |
F |
Number of Raised Fibers |
number/cm |
15 |
10 |
0 |
18 |
0 |
P |
P |
F |
P |
F |
Height of Raised Fibers |
mm |
0.5 |
1.64 |
0 |
0.57 |
0 |
P |
F |
P |
P |
P |
[0131]
Table 3
|
unit |
Example 4 |
Compara. Example 8 |
Example 5 |
Compara. Example 9 |
Ratio of Fiber Diameter at Free End (increase ratio of fiber tip diameter) |
% |
50 |
- |
26 |
- |
P |
- |
P |
- |
Ratio of Fibers with Thickened Free End |
% |
90 |
- |
90 |
- |
P |
- |
P |
- |
Ratio of Loop Fibers |
% |
23 |
- |
43 |
- |
P |
- |
P |
- |
Fiber Diameter Distribution |
- |
0.951 |
0.299 |
1.204 |
0.303 |
P |
F |
P |
F |
Feel to the Touch |
point |
3 |
2 |
9 |
4 |
P |
- |
P |
- |
Breaking Strength in X direction |
cN |
788 |
1394 |
1416 |
1888 |
P(57%) |
- |
P(75%) |
- |
Fuzz Shedding |
|
A |
A |
A |
A |
Compression Characteristic Value under Small Load |
(gf/cm2)/mtn |
12.3 |
16.6 |
10.9 |
25.8 |
P |
F |
P |
F |
Number of Raised Fibers |
number/cm |
10 |
0 |
11 |
0 |
p |
F |
P |
F |
Height of Raised Fibers |
mm |
0.38 |
0 |
0.44 |
0 |
P |
P |
P |
P |
[0132]
Table 4
|
unit |
Example 6 |
Compara. Example 10 |
Example 7 |
Compara. Example 11 |
Ratio of Fiber Diameter at Free End (increase ratio of fiber tip diameter) |
% |
43 |
- |
40 |
- |
P |
- |
P |
- |
Ratio of Fibers with Thickened Free End |
% |
60 |
- |
50 |
- |
P |
- |
P |
- |
Ratio of Loop Fibers |
% |
39 |
- |
37 |
- |
P |
- |
P |
- |
Fiber Diameter Distribution |
- |
1.18 |
0.104 |
0.606 |
0.179 |
P |
F |
P |
F |
Feel to the Touch |
point |
9 |
5 |
6 |
4 |
P |
- |
P |
- |
Breaking Strength in X direction |
cN |
1330 |
1540 |
1260 |
1450 |
P (86%) |
- |
P (87%) |
- |
Fuzz Shedding |
|
A |
A |
A |
A |
Compression Characteristic Value under Small Load |
(gf/cm2)/mm |
7.58 |
19.1 |
9.78 |
19.2 |
P |
F |
P |
F |
Number of Raised Fibers |
number/cm |
24 |
0 |
14 |
0 |
P |
F |
P |
F |
Height of Raised Fibers |
mm |
0.69 |
0 |
032 |
0 |
P |
P |
P |
P |
[0133] It is apparently seen from the results in Table 1 that the nonwoven fabric of Example
1 has a higher ratio of the fibers 21 with a thickened free end 20b and a higher increase
ratio of fiber tip diameter than those of Comparative Examples 1 to 3. It is also
seen that the nonwoven fabric of Example 1 has a smaller ratio of the loop fibers
23 and a broader fiber diameter distribution than those of Comparative Examples 1
to 3. The nonwoven fabric of Example 1, compared with its starting non-processed nonwoven
fabric (Comparative Example 4), exhibits improved feel to the touch with a minimized
reduction in breaking strength, still has resistance to fuzz shedding and pilling,
and is not scratchy against skin.
The nonwoven fabrics of Comparative Examples 1 and 2 show no improvement in feel to
the touch over their starting nonwoven fabric (Comparative Example 4). The nonwoven
fabric of Comparative Example 3 enjoys improvement in feel to the touch over its starting
nonwoven fabric (Comparative Example 4) but, in return, shows a considerable reduction
in breaking strength. The fact that the nonwoven fabric of Example 1 is superior to
the non-processed starting nonwoven fabric of Comparative Example 4 can be confirmed
by the lower compression characteristic value under small load and a larger number
of raised fibers than those of the non-processed nonwoven fabric of Comparative Example
4.
[0134] As is apparent from the results in Tables 2, 3, and 4, even in Examples 2 to 7 in
which the resin making up the nonwoven fabric was different from that used in Example
1, the basis weight was changed from that of the nonwoven fabric used in Example 1,
or a softener was incorporated into the nonwoven fabric, there were obtained nonwoven
fabrics showing improvement in feel to the touch over the non-processed nonwoven fabrics
of Comparative Examples 6 to 9 with small reduction in breaking strength similarly
to Example 1. The fact that the nonwoven fabrics of Examples 2 to 7 are superior in
feel to the touch can be confirmed by the lower compression characteristic values
under small load and greater numbers of raised fibers than those of the non-processed
nonwoven fabrics of Comparative Examples 6 to 11. Although the nonwoven fabric of
Comparative Example 5 has an increased number of raised fibers compared with the non-processed
nonwoven fabric of Comparative Example 6, it proves to rank low in feel to the touch
because of the too large height of its raised fibers. Using an ethylene propylene
copolymer or incorporating a softener proves to further improve the feel to the touch.
The nonwoven fabrics of Examples 6 and 7 exhibit good feel to the touch by virtue
of their satisfactory compression characteristic values under small load.
Example 8
[0135] An SMS nonwoven fabric including a spun-bonded layer of an ethylene-propylene copolymer
resin and having a basis weight of 15g/m
2, a fiber diameter of 1.3 dtex, and a heat/pressure bond (fusion bond formed by debossing)
area ratio of 15% was used as a starting nonwoven fabric. The SMS nonwoven fabric
was subjected to raising by the above described processing method shown in Figs. 9
through 12 to obtain a nonwoven fabric of Example 8. The individual projections 210
of the roller of the steel/steel matched embossing unit 23 had a height of 2.8 mm.
The depth D of engagement between the individual projections 210 of the roller 21
and the individual projections of the roller 22 was 2.7 mm. The mechanical stretch
ratio was 2.9. The distance between axially adjacent projections 210 (pitch P
2 of the projections 210 in the axial direction) was 7 mm, and the distance between
circumferentially adjacent projections 210 (pitch P
1 of the projections 210 in the circumferential direction) was 7 mm. The peripheral
velocity V2 of the rollers of the steel/steel matched embossing unit was 20 m/min,
and the transport rate V1 of the nonwoven fabric was 26 m/min. The individual projections
310 of the engraved roller 31 used for fiber raising had a height of 0.6 mm and were
arranged at a pitch of 1.4 mm in the axial direction and at a pitch of 2.1 mm in the
circumferential direction. The transport rate V3 of the nonwoven fabric was 20 m/min.
The engraved roller 31 was rotated in the direction reverse to the transport direction
of the nonwoven fabric at a peripheral velocity V4 four times the transport rate of
the nonwoven fabric. The wrap angle was 130°. In Example 8, only one side of the nonwoven
fabric was raised. The total stretch ratio of the nonwoven fabric was 1.7. The ratio
of the pitch of the heat/pressure bonds of the nonwoven fabric to the pitch of the
projections of the engraved rollers was 0.43 in the MD (the circumferential direction
of the rollers) and 0.37 in the CD (the rotational axial direction). The ratio of
the total heat/pressure bond area ratio to the total stretch ratio of the nonwoven
fabric was 0.088.
Example 9
[0136] An SMS nonwoven fabric including a spun-bonded layer of a propylene resin and having
a basis weight of 13 g/m
2, a fiber diameter of 15.9 µm, and a heat/pressure bond (fusion bond formed by debossing)
area ratio of 13% was used as a starting nonwoven fabric. The SMS nonwoven fabric
was processed under the same conditions as in Example 8 to obtain a nonwoven fabric
of Example 9. The total stretch ratio of the nonwoven fabric was 1.7. The ratio of
the pitch of the heat/pressure bonds of the nonwoven fabric to the pitch of the projections
of the engraved rollers was 0.41 in the MD (the circumferential direction of the rollers)
and 0.24 in the CD (the rotational axial direction). The ratio of the total heat/pressure
bond area ratio to the total stretch ratio of the nonwoven fabric was 0.076.
Example 10
[0137] A nonwoven fabric including a spun-bonded layer of a propylene layer, not including
a melt-blown layer, and having a basis weight of 18 g/m
2, a fiber diameter of 1.8 dtex, and a heat/pressure bond (fusion bond formed by debossing)
area ratio of 12% was used as a starting nonwoven fabric. The nonwoven fabric was
processed under the same conditions as in Example 8 to obtain a nonwoven fabric of
Example 10. The total stretch ratio of the nonwoven fabric was 1.7. The ratio of the
pitch of the heat/pressure bonds of the nonwoven fabric to the pitch of the projections
of the engraved rollers was 0.3 in the MD (the circumferential direction of the rollers)
and 0.3 in the CD (the rotational axial direction). The ratio of the total heat/pressure
bond area ratio to the total stretch ratio of the nonwoven fabric was 0.071.
Example 11
[0138] The same SMS nonwoven fabric as used in Example 8, which included a spun-bonded layer
of an ethylene-propylene copolymer resin and had a basis weight of 15 g/m
2 and a fiber diameter of 1.3 dtex, was used as a starting nonwoven fabric. The SMS
nonwoven fabric was processed on the steel/steel matched embossing unit in the same
manner as in Example 8. The total stretch ratio of the nonwoven fabric was 1.7. The
ratio of the pitch of the heat/pressure bonds of the nonwoven fabric to the pitch
of the projections of the engraved rollers was 0.43 in the MD (the circumferential
direction of the rollers) and 0.37 in the CD (the rotational axial direction). The
ratio of the total heat/pressure bond area ratio to the total stretch ratio of the
nonwoven fabric was 0.088. Thereafter, the nonwoven fabric was raised using an engraved
roller having projections with the maximum height of about 0.07 mm at a density of
about 2000/cm
2. The transport rate V3 of the nonwoven fabric was 20 m/min. The engraved roller 31
was rotated at a peripheral velocity V4 four times the transport rate of the nonwoven
fabric in the direction reverse to the transport direction of the nonwoven fabric.
The wrap angle was 60°. In Example 11, too, only one side of the nonwoven fabric was
raised.
Comparative Example 12
[0139] The same SMS nonwoven fabric as used in Example 8, which included a spun-bonded layer
of an ethylene-propylene copolymer resin and had a basis weight of 15 g/m
2 and a fiber diameter of 1.3 dtex, was used as a nonwoven fabric of Comparative Example
12.
Comparative Example 13
[0140] The same SMS nonwoven fabric as used in Example 8, which included a spun-bonded layer
of an ethylene-propylene copolymer resin and had a basis weight of 15 g/m
2 and a fiber diameter of 1.3 dtex, was used as a starting nonwoven fabric. Sand paper
(240 grit; from Trusco Nakayama Corp.) was wrapped around the whole periphery of a
110 diameter roller via double-sided adhesive tape. The SMS nonwoven fabric ran in
contact with the sand paper-covered roller at a wrap angle of 8.5° at a velocity of
10 m/min, while the roller rotated at a velocity of 40 m/min in the direction reverse
to the running direction of the nonwoven fabric. There was thus obtained a raised
nonwoven fabric of Comparative Example 13.
Comparative Example 14
[0141] The same SMS nonwoven fabric as used in Example 9, which included a spun-bonded layer
of propylene resin and had a basis weight of 13 g/m
2 and a fiber diameter of 15.9 µm, was used as a nonwoven fabric of Comparative Example
14.
Comparative Example 15
[0142] The same SMS nonwoven fabric as used in Example 9, which included a spun-bonded layer
of propylene resin and had a basis weight of 13 g/m
2 and a fiber diameter of 15.9 µm, was used as a starting nonwoven fabric. The nonwoven
fabric was processed under the same conditions as in Example 13 to obtain a nonwoven
fabric of Comparative Example 15.
Comparative Example 16
[0143] The same nonwoven fabric as used in Example 10 having only a spun-bonded layer of
a propylene layer, not having a melt-blown layer, and having a basis weight of 18
g/m
2 and a fiber diameter of 1.8 dtex, was used as a nonwoven fabric of Comparative Example
16.
Comparative Example 17
[0144] The same nonwoven fabric as used in Example 10 having only a spun-bonded layer of
a propylene layer, not having a melt-blown layer, and having a basis weight of 18
g/m
2 and a fiber diameter of 1.8 dtex, was processed under the same conditions as in Comparative
Example 13 to obtain a nonwoven fabric of Comparative Example 17.
Evaluation of Performance
Sensory evaluation on feel to the touch:
[0145] The nonwoven fabrics obtained in Examples 8 to 11 and Comparative Examples 12 to
16 were sensorily evaluated on a scale of 1 to 10 using the nonwoven fabric of Comparative
Example 12 as a reference given a value of 3. The greater the value, the better the
feel to the touch. Each nonwoven fabric was tested in triplicate, and the average
was rounded off to the whole number. The nonwoven fabrics of Examples 8 to 11 and
Comparative Examples 12 to 16 were compared with their respective starting nonwoven
fabrics that had not been processed at all (i.e., between Example 8 and Comparative
Example 12, between Example 9 and Comparative Example 14, between Example 10 and Comparative
Example 16, between Comparative Examples 13 and 12, between Comparative Examples 15
and 14, and between Comparative Examples 17 and 16). If there was an increase of the
average value in the sensory evaluation over the corresponding starting nonwoven fabric,
the raised nonwoven fabric was rated a pass (P). If there was no change, the raised
nonwoven fabric was rated a fail (F). The results obtained are shown in Tables 5 through
7.
Evaluation of raised fibers:
[0146] The nonwoven fabrics of Examples 8 to 11 and Comparative Examples 12 to 16 were evaluated
by determining the number of raised fibers by the method for measuring the number
of raised fibers described supra. If the number of the raised fibers was 10 or greater,
the nonwoven fabric was rated "good". If the number was 20 or greater, the nonwoven
fabric was rated "very good". If the number was fewer than 10, the nonwoven fabric
was rated as a fail (F). The results are shown in Tables 5 through 7.
Evaluation on breaking strength:
[0147] In accordance with the method for measuring breaking strength described supra, a
specimen measuring 200 mm in the X direction (transverse direction or CD) and 50 mm
in the Y direction (longitudinal direction or MD) was cut out of each of the nonwoven
fabrics obtained in Examples 8 to 11 and Comparative Examples 12 to 16. The specimen
was pulled on a tensile tester from Shimadzu Corp. starting from an initial jaw separation
of 150 mm at a rate of 300 mm/min to determine the strength in the X direction (transverse
direction or CD). An average of the measurements on four specimens per sample was
obtained. Then, a ratio of the thus determined strength in the X direction (transverse
direction or CD) to that of the corresponding starting nonwoven fabric (i.e., Example
8/Comparative Example 12, Example 9/Comparative Example 14, Example 10/Comparative
Example 16, Comparative Examples 13/12, Comparative Examples 15/14, and Comparative
Examples 17/16). If the ratio of the strength in the X direction (transverse direction
or CD) was 50% or higher, the raised nonwoven fabric was given a pass (P). If the
ratio was less than 50%, the raised nonwoven fabric was rated a fail (F). The results
are shown in Tables 5 to 7.
[0148]
Table 5
|
|
Example 8 |
Compara. Example 12 |
Compara. Example 13 |
Example 11 |
Feel to the Touch |
point |
7 |
3 |
6 |
8 |
P |
F |
P |
P |
Amount of Raising |
number/cm |
20.2 |
|
48.7 |
14.7 |
very good |
F |
very good |
good |
Breaking Strength in X direction |
cN |
1120 |
1520 |
750 |
1180 |
P (73%) |
P(100%) |
F (49%) |
P (77%) |
[0149]
Table 6
|
|
Example 9 |
Compara. Example 14 |
Compara. Example 15 |
Feel to the Touch |
point |
3 |
1 |
1 |
P |
F |
F |
Amount of Raising |
number/cm |
23.7 |
- |
14.8 |
very good |
F |
good |
Breaking Strength in X direction |
cN |
750 |
1150 |
1040 |
P (65%) |
P(100%) |
P (90%) |
[0150]
Table 7
|
|
Example 10 |
Compara. Example 16 |
Compara. Example 17 |
Feel to the Touch |
point |
3 |
1 |
1 |
P |
F |
F |
Amount of Raising |
number/cm |
16.3 |
- |
19.2 |
good |
F |
good |
Breaking Strength in X direction |
cN |
1120 |
1730 |
1760 |
P (65%) |
P (100%) |
P(102%) |
[0151] As is apparent from the results in Table 5, the nonwoven fabric of Example 8 had
excellent feel to the touch and a small reduction in breaking strength. Specifically,
the nonwoven fabric of Example 8 proved to have markedly improved feel to the touch
as compared with that of Comparative Example 12. On the other hand, although the nonwoven
fabric of Comparative Example 13 shows an improvement in feel to the touch as compared
with that of Comparative Example 12, it shows a great reduction in breaking strength.
In Example 8, the most of the raised fibers were not loop fibers but had a cut end
and was therefore non-scratchy against fingertip, and the raising roller was observed
satisfactory with no lint clinging thereto. In contrast, the sand paper used in the
raising of the nonwoven fabric in Comparative Example 13 was observed having lint
clinging thereto, and the sand paper itself had durability problem.
[0152] It is apparent from the results in Table 6 that the nonwoven fabric of Example 9
had improved feel to the touch with a small reduction in breaking strength similarly
to that of Example 8. The nonwoven fabric of Comparative Example 15 showed only a
small reduction in breaking strength but enjoyed no improvement in feel to the touch
as compared with the starting nonwoven fabric of Comparative Example 14. That is,
it is only the nonwoven fabric of Example 9 that enjoyed improvement in feel to the
touch with a small reduction in breaking strength as compared with the starting nonwoven
fabric of Comparative Example 14.
[0153] It is seen from the results in Table 7 that the nonwoven fabric of Example 10 had
improved feel to the touch with a small reduction in breaking strength similarly to
that of Example 8. The nonwoven fabric of Comparative Example 17 showed only a small
reduction in breaking strength but enjoyed no improvement in feel to the touch as
compared with the starting nonwoven fabric of Comparative Example 16. That is, it
is only the nonwoven fabric of Example 10 that enjoyed improvement in feel to the
touch with a small reduction in breaking strength as compared with the starting nonwoven
fabric of Comparative Example 16.
Industrial Applicability
[0154] The nonwoven fabric of the invention has high breaking strength and yet feels fluffy
as a whole with improved feel to the touch. The nonwoven fabric of the invention has
a reduced amount of loop fibers and is therefore less likely to feel scratchy against
the skin and has improved feel to the touch.
[0155] The method for making a nonwoven fabric according to the invention provides a nonwoven
fabric having raised fibers and thereby exhibiting a pleasant feel to the touch while
minimizing reduction in breaking strength. The method for making a nonwoven fabric
according to the invention provides a nonwoven fabric having raised fibers at a high
production speed and a reduced cost.