Technical field
[0001] The present invention relates to a system comprising a device for the utilisation
of a residual heat of flue gases having a temperature, which exceeds their dew point
and containing aggressive constituents, in particular of flue gases discharged from
solid fuel firing boilers. The present invention also relates to a system for increasing
a thermal efficiency of a boiler as well as that of a steam cycle during a generation
of an electrical energy of a steam.
State of the art
[0002] At the present time, the major portion of the global electrical energy production
is covered by solid fuel firing boilers, in particular by coal boilers and also biomass
boilers. Such boilers generate a steam which serves as a motive medium for condensing
steam turbines, particularly for double-extraction condensing steam turbines used
in heating plants. In this connection, there is a continuing effort to increase the
efficiency of the thermal to electric energy conversion. This is mostly accomplished
by increasing the parameters of steam, i.e. the pressure and the temperature of the
same, which often reach their, so called, critical values. In particular, such approach
is adopted for power-plant boiler having outputs in the order of hundreds of Megawatts.
For the boilers having outputs under 100 MW, the above way is not yet applicable because
economic and technical reasons have to be considered. No other approach than increasing
the values of steam parameters have been adopted so far.
[0003] Thus, the contemporary method of steam generation consists in that stem having high
parameter values is extracted by a steam turbine and condenses inside the same under
low pressure of about 0,008 MPa and under a temperature, which usually ranges between
30 and 45°C, thus turning to water having approximately the same temperature. The
condensed water has to be reheated to reach the temperature of the so called feedwater,
usually at least about 105°C. At the present, such reheating of water from about 30
- 45°C up to 105°C is accomplished by means of the intermediate steam extraction.
Thus, the so called regeneration of feedwater occurs. As a result, the steam used
for reheating the feedwater is lost and cannot contribute to the output power of the
turbine any more. Such solid fuel fired boilers used for steam generation work, depending
on their size, with the thermal efficiency ranging between 87 and 92,5%. The temperature
of the flue gases discharged from such boilers typically range between 120 and 170°C.
The residual heat contained of such flue gases is not utilized for any purpose. The
utilization of that residual heat would require the installation of a heat exchanger
using a low-potential cooling medium, i.e. a so called flue gas condenser. The main
reason why such flue gas condensers are not used consists in that the fuel, particularly
coal, contains sulphur and may also contain HCl as well as water. One of the combustion
products is sulphur dioxide which would react with water. Such reaction would produce
sulphurous acid causing an accelerated degradation of the flue gas condenser. In addition,
flue gases often contain a mixture of several acids, thus making the circumstances
even more unfavourable. Besides that, dust would also adhere to the heat-exchanging
surfaces of the condenser which would result both in the destruction of the latter
and in the reduction of the necessary heat transfer. In the case that biomass is fired,
sulphur is accompanied by chlorine, which is present in high concentrations in the
form of HCl and reacts with water to produce hydrochloric acid having an even stronger
caustic potential. If the flue gases were cooled under the temperature corresponding
to their dew point, the vapours of the mixture of various oxides and those of HCl
would condense simultaneously with water vapours and subsequently produce a mixture
of corrosive acids. This would cause the heat exchanger to be subjected to a very
strong corrosion supported by relatively high temperatures. No ordinary material used
for heat-exchanging surfaces can withstand the action of an acidic mixture, in particular
the mixture of sulphurous, sulphuric and hydrochloric acids or, as the case may be,
the mixture enriched by carbonic and hydrofluoric acids or the like, the above listing
being not exhaustive. The usual service life is shorter than one year. The above ordinary
materials are absolutely unsuitable for the construction of heat exchangers. Lead
is not acceptable due to its environmental impact, glass and plastic materials are
unsuitable due to their poor thermal conductivity. Alloy having increased corrosion
resistance (such as those containing Ni, Cr, Mo) may withstand corrosive attacks for
a certain period of time but still their service life is limited to a couple of years.
Furthermore, such alloys are extremely expensive and difficultly workable.
[0004] The solid fuel fired boilers, which constitute the prior art, produce aggressive
flue gases and that is why they discharge residual heat that cannot be economically
utilized. Usually, such low-potential heat does not even occur or is only present
in negligible amounts in large heating systems comprising industrial-grade boilers,
such as long-distance heating systems.
[0005] Nevertheless, no one has yet tried to make use of the fact that the above low-potential
heat typically exists in heating systems and power plants equipped with double-extraction
condensing turbines, not to mention the additional fact that such heat exists in sufficient
amounts. But still the utilization of that heat could significantly contribute to
the increase of the thermal efficiency of a steam cycle and, at the same time, to
the increase of the overall thermal efficiency of the corresponding boiler. The proposed
system (constituting the main aspect of the present invention) can increase the thermal
efficiency of a steam cycle in comparison with the commonly used technical solutions
(according to the size of the respective unit) by a value ranging between about 5%
and about 8.5%. This means that it is possible to save about 5 - 8.5% of fuel with
the same production of electricity.
[0006] Hence, it is possible to increase the thermal efficiency of the smaller (1 - 15 MWe)
contemporary combined electricity and heat sources by a value ranging between 5 and
8.5%, i.e. up to a efficiency level that is typical for large power plants. In large
power plants, the achievable increase of efficiency is slightly lower but the contribution
still remains significant. For example, the implementation of the technical solution
according to the invention, as described below, in a 1,000 MWe unit may result in
an annual saving totalling more than 200,000 tons of fuel (more than CZK 100 million/year).
[0007] US 4,489,679 discloses a control system for economic operation of a steam generator, where there
is a closed system using a heat of flue gases to warm up a feedwater of the boiler.
There is a temperature sensor in a flue gas stream and a system of valves that either
enables the flue gases to escape or to enter a venturi to warm up a feedwater of the
boiler. This patent does not solve a steam condensate that could have been used as
cooling
[0008] US 4,660,511 discloses a method and apparatus for recovery of heat from the flue gas of a combustion
furnace of a steam boiler or power generation plant which combined with a heat pump
system. The flue gas is passed through an economizer to preheat the boiler feed water.
The flue gas then passes to a direct contact gas cooler where a second stream of cooling
water extracts heat from the flue gas.
[0009] US 4,340,572 discloses a process for recovering heat from stack or flue gas. The gas stream is
countercurrently contacted with a liquid medium in two stages in order to obtain a
wanned liquid medium and a cooled gas stream. The warmed liquid medium is passed in
indirect heat exchange with eg. a process fluid. This patent discloses how to use
a heat from stack or flue gas, but a use of the heat of steam condensate used as a
cooling water is not mentioned there.
[0010] WO 2010/149173 A2 discloses a method and system for cleaning of and heat recovery from hot gases. An
exhaust gas is cooled in a gas cooler which produces a condensate that is further
cooled in a condensate cooler which produces energy. This patent does not disclose
exploitation of a condensate originating from a steam cycle during a generation of
an electrical energy of a steam.
Summary of the invention
[0011] The above mentioned drawbacks of the prior art are also largely eliminated by the
system as defined in the appended claims. The system according to the invention comprises
a direct-contact heat exchanger for extracting heat from the flue gases and transferring
it to the process water, The flue-gas inlet of the direct-contact heat exchanger is
connected to the flue-gas outlet of a solid fuel fired boiler and/or to that of an
incineration plant producing flue gases that contain aggressive constituents, said
flue gases being led through the direct-contact heat exchanger. On the opposite end
of the direct-contact heat exchanger, the water inlet is arranged for contact heat
transfer between the flue gases and the process water. The process-water outlet of
the direct-contact heat exchanger is connected to the process-water inlet of the second
heat exchanger for extracting heat from the process water and transferring it to the
cooling water while the process-water outlet of the second heat exchanger is connected
to the process-water inlet of the direct-contact heat exchanger. The process-water
circuit comprises the inlet for connecting an apparatus for replenishing alkali into
the process water in order to maintain the pH value of the process water at a level
enabling the corrosive effect of the acids, which are produced during the condensation
of flue gases, to be neutralized. The second heat exchanger is provided with a dedicated
cooling water inlet connected to a steam condenser located downstream of the condensing
section of a steam turbine and/or downstream of a steam turbine itself and/or downstream
of a steam healing system, the cooling water being a steam condensate having a temperature
ranging between 0 and 80°C, or between 0 and 70°C, or between 0 and 60°C, or between
0 and 50°C, or between 0 and 40 °C. A cooling water outlet from the second heat exchanger
is connected to a feedwater inlet of the steam boiler.
[0012] In a preferred embodiment of the device according to the invention, the direct-contact
heat exchanger is equipped with a built-in structure for increasing the heat transfer
efficiency, in particular for increasing the efficiency of the heat transfer between
flue gases and process water, and/or for rinsing the interior surfaces of the exchanger
and/or for increasing the efficiency of the neutralization the corrosive effect of
the acids produced during the condensation of flue gases. The flue-gas inlet, which
is connected to the flue-gas outlet of a solid fuel fired boiler and/or to that of
another source of aggressive flue gases, is preferably arranged in the bottom portion
of the direct-contact heat exchanger, while the process-water inlet for rinsing the
interior surfaces of the direct-contact heat exchanger and for receiving the heat
extracted from flue gases is arranged in the top portion of the direct-contact heat
exchanger.
[0013] In another preferred embodiment of the device according to the invention, the heated-up
condensate is used as feedwater for a steam boiler and/or for another heat source
and/or for another heating circuit.
[0014] In another preferred embodiment, the device according to the invention further comprises
a sedimentation vessel for settling of the solid particles flushed out from the direct-contact
heat exchanger, said vessel being arranged between the direct-contact heat exchanger
and the second heat exchanger and preferably provided with a ploughing apparatus for
removing sediments from the sedimentation vessel. In another preferred embodiment,
the device according to the invention further comprises a process water pump which
is arranged between the sedimentation vessel for settling of the solid particles flushed
out from the direct-contact heat exchanger and the second heat exchanger for extracting
heat from the process water and transferring it to the cooling water.
[0015] The apparatus for replenishing alkali into the process water in order to maintain
the pH value of the process water at a level enabling the corrosive effect of the
acids, which are produced during the condensation of flue gases, to be neutralized,
is preferably adjusted to maintain the pH value of the process water at a level greater
than 5.0, particularly greater than 6.5, more preferably greater than 6.9 and most
preferably greater than 7.5. The apparatus for replenishing alkali into the process
water is preferably incorporated into the process-water circuit between the process-water
inlet of the direct-contact heat exchanger and a process-water pump.
[0016] In another referred embodiment of the invention, the device further comprises a third
heat exchanger which is arranged between the flue-gas outlet of the heat source and
the flue-gas inlet of the direct-contact heat exchanger. The second heat exchanger
is provided with the cooling water outlet, which is connected to the cooling water
inlet of the third heat exchanger for extracting heat from the flue gases and transferring
it to the cooling water, while the cooling water outlet of the third heat exchanger
is connected to the feed tank of a heat source and/or to the heating circuit of a
boiler and/or to another heating circuit.
[0017] In order to increase the outlet temperature of flue gases and/or to enable the final
temperature of flue gases to be regulated and/or to enable the amount of the heat
output being transferred to the heat exchangers to be regulated, another preferred
embodiment envisages that the device according to the invention further comprises
a branch which is arranged upstream of the flue-gas inlet of the direct-contact heat
exchanger, said branch being provided with a regulating member and routed to the flue-gas
outlet of the direct-contact heat exchanger.
[0018] In another exemplary preferred embodiment, the device according to the invention
further comprises an apparatus for replenishing the supply of process water and/or
for draining the latter, said apparatus being arranged between the process-water outlet
of the second heat-exchanger and the process-water inlet of the direct-contact heat
exchanger.
[0019] In another preferred embodiment of the device according to the invention, the cooling
water outlet of the third heat exchanger and/or the cooling water outlet of the second
heat exchanger are connected to a thermal circuit, in particular to a thermal circuit
incorporating a boiler.
[0020] Finally, in yet another preferred embodiment of the device according to the invention,
the cooling water outlet of the third heat exchanger and/or the cooling water outlet
of the second heat exchanger are connected to the feedwater inlet of a steam boiler
and/or another heat source and/or another heating circuit.
[0021] The above described device can be also used in case that the dew point is exceeded
and acids are produced having a lower level of aggressiveness in comparison with the
flue gases containing the sulphurous, sulphuric or hydrochloric acids.
Brief description of the drawings
[0022] For more detail, the invention will be further described by means of the accompanying
drawings wherein Fig. 1 shows the first exemplary embodiment of the device according
to the invention and Fig. 2 shows the second exemplary embodiment of the device according
to the invention.
Exemplifying embodiments of the invention
[0023] Hereinafter, an exemplifying embodiment of the system comprising a device for the
utilisation of the residual heat of flue gases will be described, wherein the flue
gases have a temperature, which exceeds their dew point, and contain aggressive constituents.
Such flue gases are particularly those discharged from solid fuel fired boilers, in
particular by coal boilers and also biomass boilers. In this exemplifying embodiment,
the flue gases discharged from a heat source, e.g. from a solid fuel fired boiler,
are blown along the process water causing the thermal energy of the flue gases to
be transferred to the process water in order to heat the latter at most up to the
boiling temperature of the same under given ambient atmospheric and pressure conditions.
Simultaneously, the pH value of the process water is adjusted to enable the neutralization
of the corrosive action of the condensing flue gas constituents and is maintained
at a level higher than 5, preferably at a level higher than 7.5. After the process
water is heated up by the flue gases, its heat is transferred to the cooling water.
Then, the cooled process water re-enters the flue gas flow in order to extract thermal
energy from it.
[0024] In this system, the thermal energy of the flue gases, which would otherwise escape
into the outside environment, is transferred to the process water which flows in a
opposite direction with respect to that of the flue gases, neutralizes the flue gases
and is further heated up by the same. Thus, the neutralized process water becomes
a heat transport medium that prevents the corrosion of the heat-exchanging surfaces,
particularly those of the second heat exchanger, from developing. The process water
flows along the outer surface of the built-in structure of the heat exchanger which
means that a direct heat transfer from flue gas to process water takes place and heat
does not permeate through the material of the built-in structure of the heat exchanger.
Therefore, the direct-contact heat exchanger can be made of materials which are not
typical for heat exchangers, i.e. materials having poor thermal conductivity, in particular
plastic materials, such as polypropylene, polyethylene, PVDF etc., the above listing
being not exhaustive. Such materials are cheap and exist in an unlimited number of
types. Besides that, such plastic materials may be used for the fabrication of a louver-type
or tubular built-in structure that enlarges the overall contact surface areas of the
heat exchanger, thus increasing the efficiency of the flue-gases to process water
thermal energy conversion. Since the process water flows through the built-in structure
of the heat exchanger over a prolonged time, it has increased time for absorbing the
heat and neutralizes the flue gases more efficiently. If treated processed water with
a higher pH value was used, it would be possible to use ordinary metallic materials
for the built-in structure of the heat exchanger, particularly for a louver-type one.
In this case, the process water would flow along such metal surfaces and continuously
neutralize the acids produced during the condensation of flue gases, thus protecting
those surfaces from corrosion. In such case, the flue gases cause the built-in metal
structure of the heat exchanger to be heated up from below, thus allowing the thermal
energy to be directly transferred to the process water flowing along the built-in
metal structure of the heat exchanger. In this way, the process water can absorb additional
heat to that gained through the blowing action of the flue gases.
[0025] Fig. 1 shows a schematical view of an exemplifying embodiment of a device for the
utilisation of the residual heat of flue gases according to the invention. The device
comprises a direct-contact heat exchanger
1 for extracting heat from the flue gases and transferring it to the process water
and a second heat exchanger
6 for extracting heat from the process water and transferring it into the cooling water.
The direct-contact heat exchanger 1 comprises a flue-gas inlet
8, a process water inlet 7 and a process water outlet
14. The process water inlet
7 of the direct-contact heat exchanger
1 is connected to the process water outlet 9 of the second heat exchanger 6 while the
process water outlet
14 of the direct-contact heat exchanger
1 is connected to the first process water inlet
10 of the second heat exchanger
6, The device further comprises the apparatus
5 for replenishing alkali into the process water in order to maintain the pH value
of the process water at a level enabling to neutralize the corrosive effect of the
acids, which are produced during the condensation of flue gases. The apparatus
5 is connected to the process-water circuit through the sedimentation vessel
3. The direct-contact heat exchanger
1 is equipped with the built-in structure
2 for increasing the heat transfer efficiency. The built-in structure
2 may be e.g. a honeycomb one, through which the flue gases flow from below and along
which the process water having a suitably adjusted pH value flows from above. The
built-in structure
2 is also useful for increasing the efficiency of the heat transfer between flue gases
and process water or, as the case may be, for increasing the efficiency of the neutralization
the corrosive effect of the acids produced during the condensation of flue gases.
Nevertheless, the built-in structure does not necessarily be a honeycomb one. Instead,
a tubular built-in structure or a another structure acting similarly to a honeycomb
one may be used.
[0026] The cooling water is typically the condensate produced in a steam condenser located
downstream of the condensing section of a steam turbine and/or downstream of a steam
turbine itself and/or downstream of a steam heating system, and having a temperature
ranging between 0 and 80°C. or preferably between 0 and 50°C, or more preferably between
0 and 40°C. The heated-up condensate may be then used as feedwater for a steam boiler
and/or for another heat source and/or for another heating circuit.
[0027] The device further comprises the sedimentation vessel
3 for settling of the solid particles flushed out from the direct-contact heat exchanger
1, said vessel being arranged between the direct-contact heat exchanger
1 and the second heat exchanger
6 and connected to the same. The device further comprises the apparatus
5 for replenishing alkali into the process water in order to maintain the pH value
of the process water at a level enabling the corrosive effect of the acids, which
are produced during the condensation of flue gases, to be neutralized. The apparatus
5 is connected to the process-water circuit through the sedimentation vessel
3. The sedimentation vessel
3 is further provided with the pH meter
27 and with the ploughing apparatus
16 for removing sediments from the sedimentation vessel
3.
[0028] The apparatus
5 for replenishing alkali into the process water is connected to the sedimentation
vessel
3. The device further comprises the first process water pump
4 which is arranged between the first process-water outlet
17 of the sedimentation vessel
3 and the first process water inlet
10 of the second heat exchanger
6. However, the apparatus
5 for replenishing alkali into the process water may be incorporated into the process
water circuit between the process water outlet
14 of the direct-contact heat exchanger
1 and the first process water pump
4, the outlet of the latter being in turn connected to the first process water inlet
10 of the second heat exchanger
6, The apparatus
5 for replenishing alkali into the process water maintains the pH value of the process
water at a level enabling the corrosive effect of the acids produced during the condensation
of flue gases to be neutralized. A sufficient level may correspond to a pH value greater
than 5.0, under different circumstances a pH value greater than 6.5 or 6.6 may be
required. However, a pH value greater than 7.5 is considered most favourable for the
operation of the device.
[0029] In this exemplary embodiment, the device according to the invention further comprises
the third heat exchanger
18 which is arranged between the flue-gas outlet of the heat source and the flue-gas
inlet
8 of the direct-contact heat exchanger
1. The second heat exchanger
6 is provided with the cooling water inlet
19 and the cooling water outlet
20, which is connected to the cooling water inlet
21 of the third heat exchanger
18 for extracting heat from the flue gases and transferring it to the cooling water.
The cooling water outlet
22 of the third heat exchanger
18 is connected to the feed tank of a heat source and/or to the heating circuit of a
boiler and/or to another heating circuit. The third heat exchanger
18 does not suffer from corrosion because the temperature of its heated-up inlet water
exceeds the dew point of the flue gases. Thus, the flue gases do not condense on the
surface of the third heat exchanger
18 along which they are blown and no acids are produced.
[0030] In order to increase the outlet temperature of flue gases and/or to enable the final
temperature of flue gases to be regulated and/or to enable the amount of the heat
output being transferred to the heat exchangers
1,
6, and - to a certain extent - to the heat exchanger
18 to be controlled, the device according to the invention further comprises the branch
24 which is arranged upstream of the flue-gas inlet
8 of the direct-contact heat exchanger
1, said branch being provided with the regulating member
23 and routed to the flue-gas outlet
25 of the direct-contact heat exchanger
1 which may optionally comprise the regulating flap
26.
[0031] The device according to the invention further comprises the apparatus
29 for replenishing the supply of process water and/or for draining the latter, said
apparatus being arranged between the process-water outlet
9 of the second heat-exchanger 6 and the process-water inlet
7 of the direct-contact heat exchanger
1.
[0032] When the latter apparatus is in operation, the flue gases have the initial temperature
T1 upon entering the third heat exchanger
18 and the temperature T2 upon leaving the third heat exchanger
18. The temperature T2 is then the initial one of the flue gases upon entering the direct-contact
heat exchanger
1. Upon leaving the direct-contact heat exchanger
1 the flue gases having the temperature T3 are discharged into the ambient atmosphere.
This means that if the flue gases pass through the heat exchangers
18 and
1, their temperature will decrease from T1 over T2 up to T3. Since the temperature
T2 still exceeds the dew point of the flue gases, the third heat exchanger
18 can be made of a material without any special requirements regarding corrosion resistance.
During the passage through the direct-contact heat exchanger
1, the temperature of the flue gases is dropping below the dew point of the flue gases
but the acids produced in the built-in structure
2 of the direct-contact heat exchanger
1 are immediately neutralized by the process water that has a suitably adjusted pH
value and continuously flows along the surfaces of the built-in structure
2. Thus, the flue gases being discharged into the ambient atmosphere are cooled below
their dew point and cannot cause the corrosion of the heat-exchanging surfaces to
develop.
[0033] The process water is fed to the process-water inlet
7 in the upper portion of the direct-contact heat exchanger
1, flows down along the surfaces of the built-in structure
2 of the direct-contact heat exchanger
1, where it encounters the flue gases being blown in the opposite direction and is heated
up by the same, then it flows down through the process-water outlet
14 of the direct-contact heat exchanger
1 into the sedimentation vessel
3 where solid particles which have been flushed out from the direct-contact heat exchanger
1 settle. Subsequently, these sediments are removed by the ploughing apparatus
16 from the sedimentation vessel
3 and thus eliminated from further circulation. The process water is pumped by the
first process water pump
4 from the first process-water outlet
17 of the sedimentation vessel
3 into the first process-water-inlet
10 of the second heat exchanger
6.
[0034] In the second heat exchanger
6, the thermal energy of the process water is transferred to the cooling water, the
latter entering the second heat exchanger
6 through its first cooling water inlet
19 and having the initial temperature t1 typically ranging between about 35 and 40 °C.
Upon leaving the outlet
20, the cooling water has the temperature t2 typically ranging between 90 and 95°C.
The cooling water is led into the cooling water inlet
21 of the third heat exchanger
18 for extracting heat from the flue gases and transferring it to the cooling water.
Then, the cooling water having the temperature t3, typically between 105 - 135°C,
leaves the cooling water outlet
22 of the third heat exchanger
18 and flows to the feed tank of a heat source and/or to the heating circuit of a boiler
and/or to another heating circuit.
[0035] In order to enable the temperature of the cooling water to be regulated, the branch
24, which is arranged upstream of the flue-gas inlet
8 of the direct-contact heat exchanger
1, is provided with the regulating member
23 and routed to the flue-gas outlet
25 of the direct-contact heat exchanger
1, thus allowing a certain amount of flue gas to be directly discharged into the ambient
atmosphere after passing through the third heat exchanger
18. The flue-gas outlet
25 of the direct-contact heat exchanger
1 is routed into the ambient atmosphere through the regulating flap
26. In the case of need, the temperature of the cooling water can be decreased through
partly opening the regulating member
23 and throttling the regulating flap
26. Thus, a certain amount of the flue gases can be discharged from the third heat exchanger
18 directly into the ambient atmosphere without having to pass through the direct-contact
heat exchanger
1 and without losing any part of the thermal energy which would be otherwise transferred
to the process water.
[0036] Fig. 2 shows another exemplifying embodiment of the device according to the invention.
The flue-gas circuit is identical to that of the device shown in Fig, 1. The section
of the process-water circuit, in which the process water flows from the sedimentation
vessel
3 through the second heat exchanger
6 into the process-water inlet
7 of the direct-contact heat exchanger
1, is complemented by the parallel section leading from the second process-water outlet
11 of the sedimentation vessel
3 through the second process water pump
28 into the process-water inlet
12 of the fourth heat exchanger
13 and then from the fourth heat exchanger
13 into the second process-water inlet
15 of the second heat exchanger
6. After passing through the fourth heat exchanger
13 and the second heat exchanger
6 the process water is cooled and its temperature drops to tp3 (typically 61°C) and
tp2 (typically 40°C). respectively. When passing through the direct-contact heat exchanger
1, the process water is reheated and its temperature is increased to tp1, typically
ranging between 90 and 95°C. In this exemplary embodiment, there are also two cooling
water circuit, the first one being identical with that described with reference to
Fig. 1 and the second one containing e.g. circulating water of a heating system. In
this embodiment, the circulating water of a heating system, which passes through the
fourth heat exchanger
13, may have, for example, the typical inlet temperature t4 = 60°C and the typical outlet
temperature t5 = 90°C.
[0037] The required cooling water having the temperature t1 = 35°C can be supplied in the
form of the condensate produced in a steam condenser located downstream of a condensing
steam turbine having the same temperature. Such condensate can be heated up during
the passage through the second heat exchanger
6 to the temperature t2 = 90°C and, subsequently, during the passage through the third
heat exchanger
18 to the temperature of 135°C. Then, the heated-up condensate is led into a boiler
feed tank from where it can be supplied into a boiler in which steam is generated
to serve as the motive medium for a condensing steam turbine.
[0038] Alternatively, the condensate may be the cooled one returning from the heating circuit
of a drying plant, e.g. a malt drying kiln, wherein such returning condensed water
may be aftercooled by a stream of drying air entering the malt drying kiln on order
that the temperature of the same drops to about 40°C. Subsequently, the condensate
is heated in the second heat exchanger 6 up to 90°C and then, during the passage through
the third heat exchanger
18 up to 105°C. Afterwards, the condensate flows into a boiler feed tank from where
it is be supplied into a boiler in which it turns to steam. Such steam is fed into
a steam-to-air heat exchanger of the drying plant where it turns to condensed water.
Then, the latter is aftercooled by the air taken into the drying plant. Thus, the
temperature of the condensed water drops to about 40°C and the complete cycle will
be repeated.
[0039] In still another exemplifying embodiment, the cooling water may be cold water returning
from the heating circuit and having the temperature t1 = 45°C. This water is heated
up to the temperature t2 = 85°C in the second heat exchanger
6 and to the temperature 110°C in the third heat exchanger
18 from where it may be led into the working circuit of a heating system, such as a
swimming pool. Alternatively, this water may be led a hot-water boiler where its temperature
is further increased, e.g. to 150°C. Such boiler may supply a municipal heating system
with hot water.
Industrial applicability
[0040] The invention may be particularly useful in block-type thermal power stations where
electrical energy is generated by means of steam condensing turbines, preferably by
means of double-extraction condensing steam turbines, and where low-potential cooling
media are used, such as condensates produced in condensing steam turbo-sets which
are supplied by solid fuel filed boilers or gas fired boilers. The advantages of the
invention are especially considerable in those turbo-sets where the heat-exchanging
surfaces of the condensers are more or less subject to corrosion attacks. Furthermore,
the invention is useful whenever a low-potential medium can be found that requires
to be heated up to the boiling temperature of the process liquid of a direct-contact
heat exchanger under given ambient atmospheric and pressure conditions.
List of reference signs
[0041]
- 1- direct-contact heat exchanger
- 2- built-in structure of the direct-contact heat exchanger
- 3- sedimentation vessel
- 4- first process water pump
- 5- apparatus for replenishing alkali in process water
- 6- second heat exchanger
- 7- process-water inlet of the direct-contact heat exchanger
- 8- flue-gas inlet of the direct-contact heat exchanger
- 9- process-water outlet of the second heat exchanger
- 10- process-water inlet of the second heat exchanger
- 11- second process-water outlet of the sedimentation vessel
- 12- process-water inlet of the fourth heat exchanger
- 13- fourth heat exchanger
- 14- process-water outlet of the direct-contact heat exchanger
- 15- second process-water inlet of the second heat exchanger
- 16- ploughing apparatus
- 17- first process-water outlet of the sedimentation vessel
- 18- third heat exchanger
- 19- first cooling water inlet of the second heat exchanger
- 20- cooling water outlet of the second heat exchanger
- 21- cooling water inlet of the third heat exchanger
- 22- cooling water outlet of the third heat exchanger
- 23- regulating member
- 24- branch
- 25- flue-gas outlet of the direct-contact heat exchanger
- 26- regulating flap
- 27- pH meter
- 28- second process water pump
- 29- apparatus for replenishing the supply of process water and/or for draining process
water
1. A system comprising a device for a utilisation of a residual heat of flue gases having
a temperature, which exceeds their dew point, and containing aggressive constituents,
in particular flue gases discharged from solid fuel firing boilers, that comprises
a steam boiler for generating steam for steam turbine and/or condensation steam turbine,
a direct-contact heat exchanger (1) for extracting the heat from the flue gases and
transferring it to process water, the direct-contact heat exchanger (1) having a flue-gas
inlet (8), which is connected to a flue-gas outlet of the solid fuel firing boiler
and/or to that of an incineration plant producing the flue gases that contain aggressive
constituents, said flue gases being led through the direct-contact heat exchanger
(1), and a process-water inlet (7), which is arranged on an opposite end, for a contact
heat transfer between the flue gases and the process water inside the direct-contact
heat exchanger (1), wherein the device further comprises a second heat exchanger (6),
a process-water outlet (14) of the direct-contact heat exchanger (1) being connected
to a first process-water inlet (10) of the second heat exchanger (6) for extracting
heat from the process water and transferring it to a cooling water, a process-water
outlet (9) of the second heat exchanger (6) being connected to the process-water inlet
(7) of the direct-contact heat exchanger (1), wherein the system further comprises
a steam condenser and further comprises a steam turbine or steam condensation turbine
connected to the steam boiler, characterized in that the system further comprises an apparatus (5) for replenishing alkali into the process
water, wherein the process-water circuit further comprises an inlet for connecting
the apparatus (5) for replenishing alkali into the process water in order to maintain
the pH value of the process water at a level enabling a corrosive effect of acids,
which are produced during the condensation of the flue gases, to be neutralized, wherein
the second heat exchanger (6) is provided with a cooling water inlet (19) connected
to the steam condenser located downstream of the condensing section of the steam turbine
and/or downstream of the steam turbine itself, the cooling water being the steam condensate
from the steam condenser having a temperature ranging between 0 and 80°C, or between
0 and 70°C, or between 0 and 60°C, or between 0 and 50°C, or between 0 and 40 °C,
wherein a cooling water outlet (20) from the second heat exchanger (19) is connected
to a feedwater inlet of the steam boiler.
2. The system according to claim 1, characterized in that the second heat exchanger (6) cooling water outlet (20), is connected to a cooling
water inlet (21) of a third heat exchanger (18) for extracting heat from the flue
gases and transferring it to the cooling water, the third heat exchanger (18) being
arranged between the flue-gas outlet of a heat source and the flue-gas inlet (8) of
the direct-contact heat exchanger (1), while a cooling water outlet (22) of the third
heat exchanger (18) is connected to a feed tank of a heat source and/or to a heating
circuit of the boiler and/or to another heating circuit, the device further comprising
a branch (24), which is arranged upstream of the flue-gas inlet (8) of the direct-contact
heat exchanger (1), said branch being provided with a regulating member (23) and routed
to a flue-gas outlet (25) of the direct-contact heat exchanger (1), in order to increase
the outlet temperature of the flue gases and/or to enable the final temperature of
the flue gases to be regulated and/or to enable the amount of the heat output being
transferred to the heat exchangers (1, 6, 18) to be regulated.
3. The system according to claim 2, characterized in that it further comprises a regulating flap (26), which is arranged in the flue-gas outlet
(25) of the direct-contact heat exchanger (1), in order to increase the outlet temperature
of the flue gases and/or to enable the final temperature of the flue gases to be regulated
and/or to enable the amount of the heat output being transferred to the heat exchangers
(26, 6, 18) to be regulated.
4. The system according to any of the claims 1 to 3, characterized in that the apparatus (5) for replenishing alkali into the process water in order to maintain
the pH value of the process water at a level enabling the corrosive effect of the
acids, which are produced during the condensation of the flue gases, to be neutralized,
is connected to the process-water circuit through a sedimentation vessel (3).
5. The system according to claim 1, characterized in that the direct-contact heat exchanger (1) is equipped with a built-in structure (2) for
increasing a heat transfer efficiency, in particular for increasing the efficiency
of the heat transfer between the flue gases and the process water, and/or for rinsing
interior surfaces of the direct-contact heat exchanger (1) and/or for an increasing
an efficiency of a neutralization of a corrosive effect of the acids produced during
the condensation of the flue gases.
6. The system according to claim 1, characterized in that the flue-gas inlet (8) of the direct-contact heat exchanger (1) is arranged in a
bottom portion of the direct-contact heat exchanger (1) while the process-water inlet
(7) for rinsing the interior surfaces of the direct-contact heat exchanger (1) and
for receiving the heat extracted from the flue gases is arranged in a top portion
of the direct-contact heat exchanger (1).
7. The system according to claim 1, characterized in that it further comprises a sedimentation vessel (3) for settling of the solid particles
flushed out from the direct-contact heat exchanger (1), said vessel being arranged
between the direct-contact heat exchanger (1) and the second heat exchanger (6) and
connected to the same.
8. The system according to claim 7, characterized in that the sedimentation vessel (3) for settling of the solid particles flushed out from
the direct-contact heat exchanger (1) is provided with a ploughing apparatus (16)
for removing the sediments from the sedimentation vessel (3).
9. The system according to claim 1, characterized in that the apparatus (5) for replenishing alkali into the process water in order to maintain
the pH value of the process water at a level enabling the corrosive effect of the
acids, which are produced during the condensation of the flue gases, to be neutralized,
is adjusted to maintain the pH value of the process water at a level greater than
5.0, particularly greater than 6.5, preferably greater than 6.9 and most preferably
greater than 7.5.
10. The system according to claim 7, characterized in that it further comprises a first process water pump (4) which is arranged between the
sedimentation vessel (3) for settling of the solid particles flushed out from the
direct-contact heat exchanger (1) and the second heat exchanger (6) for extracting
heat from the process water and transferring it to the cooling water.
11. The system according to claim 1, characterized in that it further comprises an apparatus (29) for replenishing the supply of process water
and/or for draining the latter, said apparatus being arranged between the process-water
outlet (9) of the second heat-exchanger (6) and the process-water inlet (7) of the
direct-contact heat exchanger (1).
12. The system according to claim 2, characterized in that the cooling water outlet (22) of the third heat exchanger (18) and/or the cooling
water outlet (20) of the second heat exchanger (6) are connected to the feedwater
inlet of the steam boiler and/or another heat source and/or another heating circuit.
13. The system according to claim 2, characterized in that the cooling water outlet (22) of the third heat exchanger (18) and/or the cooling
water outlet (20) of the second heat exchanger (6) are connected to a thermal circuit,
in particular to a thermal circuit incorporating a boiler.
1. Ein System, umfassend eine Anlage zur Rückgewinnung der Wärme aus Abgasen, deren Temperatur
deren Taupunkt überschreitet und die aggressive Bestandteile enthalten, insbesondere
aus Abgasen, die aus Kesseln zur Verbrennung von festen Brennstoffen abgelassen werden,
welche Anlage einen Dampfkessel zur Erzeugung von Dampf für eine Dampfturbine und/oder
eine Kondensationsdampfturbine, einen Direktkontakt-Wärmetauscher (1) zur Wärmeübertragung
von den Abgasen und auf Prozesswasser, wobei der Direktkontakt-Wärmetauscher (1) einen
Abgaseinlass (8), der mit einem Abgasauslass des zur Verbrennung von festen Brennstoffen
vorgesehenen Kessels und/oder mit einem Abgasauslass einer aggressive Bestandteile
enthaltenden Abgase ablassenden Verbrennungsanlage verbunden ist, wobei die Abgase
durch den Direktkontakt-Wärmetauscher (1) geführt werden, sowie einen Prozesswassereinlass
umfasst, der am gegenüberliegenden Ende angeordnet und zur Kontaktwärmeübergabe zwischen
den Abgasen und dem innerhalb des Direktkontakt-Wärmetauschers (1) befindlichen Prozesswasser
vorgesehen ist, wobei die Anlage ferner einen zweiten Wärmetauscher (6) umfasst, wobei
der Prozesswasserauslass (14) des Direktkontakt-Wärmetauschers (1) mit dem ersten
Prozesswassereinlass (10) des zweiten Wärmetauschers (6) zur Wärmeübertragung von
dem Prozesswasser auf Kühlwasser verbunden ist, wobei der Prozesswasserauslass (9)
des zweiten Wärmetauschers (6) mit dem Prozesswassereinlass (7) des Direktkontakt-Wärmetauschers
(1) verbunden ist, wobei das System ferner einen Dampfkondensator sowie eine Dampfturbine
und/oder eine Kondensationsdampfturbine umfasst, der bzw. die mit dem Dampfkessel
verbunden ist, dadurch gekennzeichnet, dass das System ferner eine Vorrichtung (5) zur Zugabe von Alkalisierungsmitteln dem Prozesswasser
umfasst, wobei der Prozesswasserkreislauf ferner einen Einlass zum Anschließen der
Vorrichtung (5) zur Zugabe von Alkalisierungsmitteln dem Prozesswasser umfasst, um
den pH-Wert des Prozesswassers auf einer Ebene zu halten, die es möglich macht, korrosive
Einwirkungen der sich während der Kondensation der Abgase bildenden Säuren zu neutralisieren,
wobei der zweite Wärmetauscher (6) mit einem Kühlwassereinlass (19) versehen ist,
der mit dem stromab der Kondensationsstufe der Dampfturbine und/der stromab der eigentlichen
Dampfturbine angeordneten Dampfkondensator verbunden ist, wobei Kühlwasser das aus
dem Dampfkondensator bezogene Dampfkondensat ist, dessen Temperatur zwischen 0 und
80 °C oder zwischen 0 und 80 °C oder zwischen 0 und 60 °C oder zwischen 0 und 50 °C
oder zwischen 0 und 40 °C liegt, wobei der Kühlwasserauslass (20) des zweiten Wärmetauschers
(6) mit dem Speisewassereinlass des Dampfkessels verbunden ist.
2. Das System nach Anspruch 1, dadurch gekennzeichnet, dass der Kühlwasserauslass (20) des zweiten Wärmetauschers (6) mit einem Kühlwassereinlass
(21) eines dritten Wärmetauschers (18) zur Wärmeübertragung von den Abgasen auf Kühlwasser
verbunden ist, wobei der dritte Wärmetauscher (18) zwischen dem Abgasauslass einer
Wärmequelle und dem Abgaseinlass (8) des Direktkontakt-Wärmetauschers (1) angeordnet
ist, wobei ein Kühlwasserauslass (22) des dritten Wärmetauschers (18) mit dem Einspeisebehälter
der Wärmequelle und/oder mit einem Heizkreis des Kessels und/oder mit einem anderen
Heizkreis verbunden ist, wobei die Anlage ferner eine stromauf hinsichtlich dem Abgaseinlass
(8) des Direktkontakt-Wärmetauscher (1) angeordnete Abzweigleitung (24) umfasst, die
mit einem Regelglied (23) versehen und zu dem Abgasauslass (25) des Direktkontakt-Wärmetauschers
(1) geführt ist, um die Auslasstemperatur der Abgase zu steigern und/oder um die Regelung
der Endtemperatur der Abgase möglich zu machen und/oder um die Regelung der von dem
Auslass zu den Wärmetäuschern (1, 6, 18) zu übertragender Wärmemenge möglich zu machen.
3. Das System nach Anspruch 2, dadurch gekennzeichnet, dass es ferner eine Regelklappe (26) umfasst, die in dem Abgasauslass (25) des Direktkontakt-Wärmetauschers
(1) angeordnet ist, um die Auslasstemperatur der Abgase zu steigern und/oder um die
Regelung der Endtemperatur der Abgase möglich zu machen und/oder um die Regelung der
von dem Auslass zu den Wärmetäuschern (1, 6, 18) zu übertragender Wärmemenge möglich
zu machen.
4. Das System nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Vorrichtung (5) zur Zugabe von Alkalisierungsmitteln dem Prozesswasser, um den
pH-Wert des Prozesswassers auf einer Ebene zu halten, die es möglich macht, korrosive
Einwirkungen der sich während der Kondensation der Abgase bildenden Säuren zu neutralisieren,
mit dem Prozesswasserkreislauf mittels eines Absetzbehälters (3) verbunden ist.
5. Das System nach Anspruch 1, dadurch gekennzeichnet, dass der Direktkontakt-Wärmetauscher (1) mit einer eingebauten Struktur (2) zur Steigerung
des Wirkungsgrads der Wärmeübertragung, insbesondere zur Steigerung des Wirkungsgrads
der Wärmeübertragung zwischen den Abgasen und dem Prozesswasser, und/oder zur Spülung
der inneren Oberflächen des Direktkontakt-Wärmetauschers (1) und/oder zur Steigerung
des Wirkungsgrads der Neutralisierung der sich während der Kondensation der Abgase
bildenden Säuren ausgestattet ist.
6. Das System nach Anspruch 1, dadurch gekennzeichnet, dass der Abgaseinlass (8) des Direktkontakt-Wärmetauschers (1) in dem unteren Abschnitt
des Direktkontakt-Wärmetauschers (1) angeordnet ist, wohingegen der Prozesswassereinlass
(7) zur Spülung der inneren Oberflächen des Direktkontakt-Wärmetauschers (1) und zur
Zuführung der aus den Abgasen ausgekoppelten Wärme in dem oberen Abschnitt des Direktkontakt-Wärmetauschers
(1) angeordnet ist.
7. Das System nach Anspruch 1, dadurch gekennzeichnet, dass es ferner einen Absetzbehälter (3) zur Absetzung der aus dem Direktkontakt-Wärmetauscher
(1) ausgespülten festen Partikeln umfasst, wobei der besagte Absetzbehälter zwischen
dem Direktkontakt-Wärmetauscher (1) und dem zweiten Wärmetauscher (6) angeordnet und
mit den beiden Wärmetauschern verbunden ist.
8. Das System nach Anspruch 7, dadurch gekennzeichnet, dass der Absetzbehälter (3) zur Absetzung der aus dem Direktkontakt-Wärmetauscher (1)
ausgespülten festen Partikeln mit einer Wegräumvorrichtung (16) versehen ist, die
zum Entfernen von abgesetzten Ablagerungen aus dem Absetzbehälter (3) vorgesehen ist.
9. Das System nach Anspruch 1, dadurch gekennzeichnet, dass die Vorrichtung (5) zur Zugabe von Alkalisierungsmitteln dem Prozesswasser, um den
pH-Wert des Prozesswassers auf einer Ebene zu halten, die es möglich macht, korrosive
Einwirkungen der sich während der Kondensation der Abgase bildenden Säuren zu neutralisieren,
zum Halten des pH-Wertes des Prozesswassers auf einer Ebene angepasst ist, die höher
ist als 5,0, insbesondere als 6,5, vorzugsweise als 6,9 und am meisten bevorzugt als
7,5.
10. Das System nach Anspruch 7, dadurch gekennzeichnet, dass es ferner eine erste Prozesswasserpumpe (4) umfasst, die zwischen dem Absetzbehälter
(3) zur Absetzung der aus dem Direktkontakt-Wärmetauscher (1) ausgespülten festen
Partikeln und dem zweiten Wärmetäuscher (6) zur Wärmeübertragung von dem Prozesswasser
auf Kühlwasser angeordnet ist.
11. Das System nach Anspruch 1, dadurch gekennzeichnet, dass es ferner eine Vorrichtung (29) zur Ergänzung des Vorrats vom Prozesswasser und/oder
zum Ablassen des letzteren umfasst, wobei die besagte Vorrichtung zwischen dem Prozesswasserauslass
(9) des zweiten Wärmetauschers (6) und dem Prozesswassereinlass (7) des Direktkontakt-Wärmetauschers
(1) angeordnet ist.
12. Das System nach Anspruch 2, dadurch gekennzeichnet, dass der Kühlwasserauslass (22) des dritten Wärmetauschers (18) und/oder der Kühlwasserauslass
(20) des zweiten Wärmetauschers (6) mit dem Speisewassereinlass des Dampfkessels und/oder
einer anderen Wärmequelle und/oder eines anderen Heizkreises verbunden sind.
13. Das System nach Anspruch 2, dadurch gekennzeichnet, dass der Kühlwasserauslass (22) des dritten Wärmetauschers (18) und/oder der Kühlwasserauslass
(20) des zweiten Wärmetauschers (6) mit einem Wärmekreislauf verbunden sind, insbesondere
mit einem Wärmekreislauf, der einen Kessel umfasst.
1. Système comprenant un dispositif pour l'utilisation de la chaleur résiduelle des gaz
de combustion ayant une température dépassant leur point de rosée et comprenant des
composants agressifs, en particulier des gaz combustibles provenant de chaudières
à combustible solide, comprenant une chaudière à vapeur pour générer de la vapeur
pour turbine à vapeur et/ou turbine à condensation à vapeur, un échangeur (1) de chaleur
à contact direct pour extraire la chaleur des gaz de combustion et la transférer dans
l'eau de traitement, l'échangeur (1) de chaleur à contact direct ayant une entrée
(8) de gaz de combustion qui est raccordée à la sortie de gaz de combustion de la
chaudière à combustible solide et / ou à celle d'une installation d'incinération produisant
les gaz de combustion contenant des constituants agressifs, lesdits gaz de combustion
étant conduits à travers l'échangeur (1) de chaleur à contact direct, et une entrée
(7) de l'eau de traitement, qui est agencée à l'extrémité opposée, pour un transfert
de chaleur par contact entre les gaz de combustion et l'eau de traitement au dedans
de l'échangeur (1) de chaleur à contact direct, l'appareil comprenant en outre un
seconde échangeur (6) de chaleur, une sortie (14) de l'eau de traitement de l'échangeur
(1) de chaleur à contact direct étant raccordée à la première entrée (10) de l'eau
de traitement du seconde échangeur (6) de chaleur afin d'extraire la chaleur de l'eau
de traitement et la transférer à l'eau de refroidissement, une sortie de l'eau (9)
de traitement du second échangeur (6) de chaleur étant raccordée à l'entrée (7) de
l'eau de traitement de l'échangeur (1) de chaleur à contact direct, dans lequel le
système comprend en outre un condenseur de vapeur et comprend en outre une turbine
à vapeur ou une turbine à condensation à vapeur raccordée à la chaudière à vapeur,
caractérisé en ce que le système comprend en outre un appareil (5) pour remplir l'alcalin dans l'eau de
traitement, le circuit de l'eau de traitement comprenant en outre une entrée pour
raccorder l'appareil (5) pour remplir l'alcalin dans l'eau de traitement afin de maintenir
la valeur de pH de l'eau de traitement au niveau permettant la neutralisation des
effets corrosifs des acides produits au cours de la condensation des gaz de combustion,
le seconde échangeur (6) de chaleur étant pourvu d'une entrée (19) d'eau de refroidissement
raccordée au condenseur de vapeur situé en aval de la section de condensation de la
turbine à vapeur et / ou en aval de la turbine à vapeur elle-même, l'eau de refroidissement
étant le condensat de vapeur provenant du condenseur de vapeur ayant une température
comprise entre 0 et 80 °C ou entre 0 et 70 °C ou entre 0 et 60 °C ou entre 0 et 50
°C ou entre 0 et 40 °C, une sortie (20) d'eau de refroidissement du seconde échangeur
(19) de chaleur étant reliée à une entrée d'eau d'alimentation de la chaudière à vapeur.
2. Le système selon la revendication 1, caractérisé en ce que la sortie (20) d'eau de refroidissement du second échangeur (6) de chaleur est reliée
à l'entrée (21) d'eau de refroidissement du troisième échangeur (18) de chaleur afin
d'extraire la chaleur des gas de combustion et la transférer à l'eau de refroidissement,
le troisième échangeur (18) de chaleur étant disposés entre la sortie de gaz de combustion
de la source de chaleur et l'entrée (8) de gaz de combustion de l'échangeur (1) de
chaleur à contact direct, tandis que la sortie (22) d'eau de refroidissement du troisième
échangeur (18) de chaleur est reliée à un réservoir d'alimentation de la source de
chaleur et / ou au circuit de chauffage de la chaudière et / ou à un autre circuit
de chauffage, le dispositif comprenant en outre un branchement (24) qui est agencé
en amont de l'entrée (8) de gaz de combustion de l'échangeur (1) de chaleur à contact
direct, ledite branchement étant munie d'un membre (23) de réglage et acheminée vers
la sortie (25) des gaz de combustion de l'échangeur (1) de chaleur à contact direct,
afin d'augmenter la température de sortie des gaz de combustion et / ou de permettre
de réguler la température finale des gaz de combustion et / ou de permettre de réguler
la quantité de la sortie de la chaleur étant transférée aux échangeurs (1, 6, 18)
de chaleur.
3. Le système selon la revendication 2, caractérisé en ce qu'il comprend en outre un clapet (26) de réglage disposé dans la sortie (25) de gaz
de combustion de l'échangeur de chaleur à contact direct (1) afin d'augmenter la température
de sortie des gaz de combustion et / ou pour permettre la régulation de la température
finale des gaz de combustion et / ou pour permettre la régulation de la quantité de
la sortie de la chaleur étant transferée aux échangeurs (1, 6, 18) de chaleur.
4. Le système selon l'une quelconque des revendications 1 à 3, caractérisé en ce que l'appareil (5) pour remplir l'alcalin dans l'eau de traitement afin de maintenir
la valeur pH de l'eau de traitement au niveau permettant de neutraliser des effets
corrosifs des acides qui sont produites lors de la condensation des gaz de combustion,
est raccordé au circuit de l'eau de traitement par un récipient (3) de sédimentation.
5. Le système selon la revendication 1, caractérisé en ce que l'échangeur (1) de chaleur à contact direct est muni d'une structure (2) intégrée
pour augmenter l'efficacité de transfert de chaleur, en particulier pour augmenter
l'efficacité de transfert de chaleur entre les gaz de combustion et l'eau de traitement
et / ou pour rincer les surfaces intérieures de l'échangeur (1) de chaleur à contact
direct et / ou pour augmenter l'efficacité de la neutralisation des effets corrosifs
des acides produits lors de la condensation des gaz de combustion.
6. Le système selon la revendication 1, caractérisé en ce que l'entrée (8) des gaz de combustion de l'échangeur (1) de chaleur à contact direct
est agencé dans la partie inférieure de l'échangeur (1) de chaleur à contact direct,
tandis que l'entrée (7) d'eau de traitement servant à rincer les surfaces intérieures
de l'échangeur (1) de chaleur à contact direct et à recevoir la chaleur extraite des
gaz de combustion est disposée dans la partie supérieure de l'échangeur (1) de chaleur
à contact direct.
7. Le système selon la revendication 1, caractérisé en ce qu'il comprend en outre un récipient (3) de sédimentation pour la décantation des particules
solides évacuées de l'échangeur (1) de chaleur à contact direct, ledit récipient étant
disposé entre l'échangeur (1) de chaleur à contact direct et le second échangeur (6)
de chaleur et connecté à celui-ci.
8. Le système selon la revendication 7, caractérisé en ce que le récipient (3) de sédimentation destiné à la décantation des particules solides
évacuées de l'échangeur (1) de chaleur à contact direct est pourvu d'un appareil (16)
de balayage destiné à retirer les sédiments de récipient (3) de sédimentation.
9. Le système selon la revendication 1, caractérisé en ce que l'appareil (5) pour remplir les alcalis dans l'eau de traitement afin de maintenir
la valeur de pH de l'eau de traitement au niveau permettant de neutraliser les effets
corrosifs des acides produits lors de la condensation des gaz de combustion, est ajusté
pour maintenir la valeur de pH de l'eau de traitement à un niveau supérieur à 5,0,
en particulier supérieur à 6,5, de préférence supérieur à 6,9 et de manière la plus
préférée supérieur à 7,5.
10. Le système selon la revendication 7, caractérisé en ce qu'il comprend en outre une première pompe (4) à l'eau de traitement agencée entre le récipient
(3) de sédimentation pour la décantation des particules solides évacuées de l'échangeur
(1) de chaleur à contact direct et le second échangeur (6) de chaleur pour extraire
la chaleur de l'eau de traitement et la transférer dans l'eau de refroidissement.
11. Le système selon la revendication 1, caractérisé en ce qu'il comprend en outre un appareil (29) pour remplir l'alimentation en eau de traitement
et / ou pour décharger celle-ci, ledit appareil étant disposé entre la sortie (9)
d'eau de traitement de l'échangeur (6) de chaleur et l'entrée (7) d'eau de traitement
de l'échangeur (1) de chaleur à contact direct.
12. Le système selon la revendication 2, caractérisé en ce que la sortie (22) d'eau de refroidissement du troisième (18) échangeur de chaleur et
/ ou la sortie (20) d'eau de refroidissement du second échangeur (6) de chaleur sont
reliées à l'entrée de l'eau d'alimentation de la chaudière à vapeur et / ou une autre
source de chaleur et / ou un autre circuit de chauffage.
13. Le système selon la revendication 2, caractérisé en ce que la sortie (22) de l'eau de refroidissement du troisième échangeur (18) de chaleur
et / ou la sortie (20) de l'eau de refroidissement du second échangeur (6) de chaleur
sont reliées au circuit thermique, en particulier au circuit thermique intégrant une
chaudière.